KR20160052066A - Method for Purification of Saponin from Soapberry and Cleanser Composition Containing Saponin - Google Patents

Abstract

The present invention relates to a method for extracting saponin from soapberries and a cleanser composition containing the extracted saponin. More specifically, the present invention relates to a method for extracting saponin from soapberries and a cleanser composition containing the saponin, wherein the cleanser composition has effects of treating dead skin cells on the scalp and the inflammation on the skin and the scalp, and improving the quality of hair. The method of the present invention comprises the following steps: A) subjecting a mixture of soapberry powder, inorganic powder, and water, to an ultrasound treatment to extract saponin therefrom; and B) isolating the extracted saponin.

Description

FIELD OF THE INVENTION The present invention relates to a method for extracting saponin from fruit juice and to a cleaning composition comprising the saponin.

The present invention relates to a method for extracting saponin from fruit juice and a detergent composition comprising the saponin. More particularly, the present invention relates to a method for extracting saponin from mung bean tree fruit which can improve the keratin and inflammation of the scalp, the hair, and the saponin-containing shampoo and body cleanser composition.

Humans and animals are always exposed to various pollution environments. Such a contaminated environment particularly affects the human body or animal body, that is, it contaminates the skin, hair, etc. forming the outer surface of the body, basically damages the sensation of refreshing, If left in a state for a long time, various diseases such as skin and hair are caused.

Further, human hair is soiled by heavy metal contaminants or sebum secreted from the scalp itself due to contact with the ambient air, and a composition for cleaning hair, such as shampoo, is used for removing contaminants or scalp sebum as described above. However, most of the effective ingredients of the hair cleansing compositions such as shampoos are composed of chemical components such as surfactants and silicon. Therefore, in case of skin-sensitive people, seborrheic dermatitis or inflammatory diseases are caused, In addition, there is a problem in that side effects such as dandruff and itching caused by skin horny are caused. Therefore, efforts have been made to solve these problems by using natural materials.

In recent years, researches and developments have been actively conducted on shampoos having a protective function and a nutritional supply function to scalp and hair, and in particular, extracts of plants obtained from nature can be used as additives for shampoo raw materials such as surfactants and foam promoters Are added to the mixed raw materials to produce shampoos. Most of consumers prefer shampoos which are rich in foam, and in order to satisfy consumers, a shampoo composition containing most natural materials may be classified into one or two natural materials And there is a problem that a surfactant which is not suitable for the human body is used.

To solve these problems, a natural amino-based shampoo has been developed. However, the shampoo has a problem in that it can not satisfy consumers because of low foaming power and weak cleaning power.

In addition, conventional shampoo was applied to the hair before applying hair, then applied shampoo liquid and rubbed the hair to remove the foreign substance while generating bubbles. At this time, by using the shampoo liquid, environmental pollution and hair and scalp bubble were removed Therefore, there was a problem of waste of water.

In addition, a purification method for extraction and extraction of natural materials is not easy and technically difficult.

Disclosure of the Invention An object of the present invention is to provide a method for extracting saponin which does not cause toxicity to the naked fruit and can minimize human harmful substances. The present invention also provides a detergent composition comprising a saponin extract.

Another object of the present invention is to provide a detergent composition comprising a saponin extract extracted from a mushroom fruit which can improve the keratin and inflammation of the scalp, the hair, and the skin as it becomes dry and itch and keratin can be improved.

Yet another object of the present invention is to provide a detergent composition comprising saponin extracted from a nutmeg tree which is environmentally friendly and capable of cleaning scalp, hair and body without using water.

It is a further object of the present invention to provide a detergent composition comprising fine bubbles and comprising the saponin extracted from the nutrient tree fruit which is not easily broken by the bubbles.

The present invention relates to a method for extracting saponins from fruit juice, comprising the steps of: A) extracting saponin by ultrasonication in a mixed liquid comprising A) fruit juice, fruit powder, and water; and B) separating the extract.

The present invention also relates to a method for the production of soybean oil, which comprises extracting saponin, 1,3-butylene glycol, a cationic surfactant, nymph oil, cinnamon extract, cinnabar extract, green tea extract, The present invention relates to a detergent composition comprising a saponin extract comprising purified water.

The present invention also relates to a shampoo comprising the detergent composition.

The present invention also relates to a body cleanser comprising the cleanser composition of the present invention.

The present invention also relates to a dog cleaner comprising the detergent composition.

The present invention also relates to a laundry detergent comprising the detergent composition.

Hereinafter, a method for extracting saponin from the fruit juice of the present invention will be described in detail.

The method of extracting saponin from the fruit juice of the present invention comprises:

A) extracting saponin by ultrasonication into a mixed liquid containing fruit juice, fruit powder, and water;

B) separating the extract.

The present invention is characterized in that toxic substances do not occur and harmful substances to the human body can be minimized by ultrasonic treatment and low temperature extraction of a mixed liquid containing the heat-resistant fruit powder, inorganic powder and water.

As an example of a method for extracting saponin from the mugwort fruit of the present invention,

a) a step of preparing a mixed liquid for mixing the powdery mildew powder, inorganic powder and water,

b) stirring the prepared mixed solution at a temperature of 25 to 80 캜 for 0.1 to 20 hours at 10 to 100 rpm,

c) extracting saponin by ultrasonication at a power of 5 to 30 hz and a power of 100 to 500 watts for 0.5 to 3 hours,

d) extracting the supernatant using a 2 ~ 5 [mu] m filter and then centrifuging at 3,000 ~ 4,000 rpm to separate saponin;

But is not necessarily limited thereto.

The step (a) is a step of preparing a mixed solution. However, the above-mentioned moisture-free fruit powder may be in the form of a powder obtained by removing seeds from a dried seasoning and then pulverizing the seeds. However, no.

The inorganic powder is used to enable a high content of saponin extraction and to further improve the surfactant function and deodorizing effect. The inorganic powder may be, for example, any one or a mixture of powders selected from the group consisting of tourmaline, cerium oxide, titanium oxide, talc, aluminum oxide, iron oxide and mica, but is not limited thereto .

The use of tourmaline preferably improves the surfactant function and deodorization effect of the inorganic powder, and when the temperature is raised by 10 캜, the inorganic powder has an effect of doubling the generation of anion, and is preferably contained in the detergent composition. Specifically, for example, it is best to add to the shampoo composition, the dog cleaner composition, and the laundry detergent composition, but is not necessarily limited thereto. The content of the inorganic powder is preferably 0.1 to 40 parts by weight based on 100 parts by weight of the moisture-free fruit powder so as to minimize skin irritation when used as a proper surfactant function and a detergent or a shampoo composition. The inorganic powder preferably has a particle size of 1 to 100 nm, more preferably 10 to 50 nm. When the inorganic powder is used in the above range, it can be extracted at low temperature from the fruit tree, A high content of saponin can be extracted, but it is not necessarily limited to the above range.

The extraction of saponin from the fruit juice by adding the inorganic powder makes it possible to extract a high content of saponin compared to extracting saponin from the fruit juice without adding the inorganic powder and more specifically, % Of the extract can be obtained, and when contained in the cleaning agent, the surfactant function and the deodorizing effect can be further improved.

The water can be used without limitation as long as it is purified water through tap water, purified water and purified water through an ion exchange resin. The content of the water may be 400 to 800 parts by weight per 100 parts by weight of the moisture-free fruit powder, But is not limited thereto.

By extracting saponin from the mixture of the mixture of the non-treated fruit tree powder, inorganic powder and water in the step a), it is possible to extract at low temperature, and toxic substances are not generated during extraction, so that harmful substances to the human body can be minimized.

The step b) is preferably a step of stirring the mixed solution prepared in the step a) at a low temperature and stirring at a temperature of 25 to 80 ° C for 0.1 to 20 hours at 10 to 100 rpm, It is preferable that no precipitate is formed and mixed evenly. When the temperature is out of the above range, particularly when the temperature is outside 80 ° C, the foam of the mixed solution overflows, making it difficult to extract saponin for the purpose of the present invention, and stirring in the above range is preferable, but not always limited thereto .

In the step c), ultrasonic extraction is performed for 0.5-3 hours at a power of 5 to 30 hz and 100 to 500 watts as a condition for extracting saponin from the fruit juice. However, But it is not necessarily limited thereto.

In the step d), the mixed solution having been subjected to ultrasonic extraction is filtered using a 2 to 5 탆 filter, and then centrifuged at 3,000 to 4,000 rpm to obtain a saponin extract, which is not necessarily limited to the above range.

Hereinafter, the detergent composition comprising the saponin extract of the present invention will be described in more detail.

The detergent composition containing the saponin extract of the present invention can be obtained by mixing the above saponin extract, 1,3-butylene glycol, a cationic surfactant, nymph oil, cinnamon extract, cinnabar extract, green tea extract, Cis ethanol and purified water.

The detergent composition of the present invention is characterized by being able to improve hair and keratin and inflammation of the scalp when used as a shampoo at the same time as improving the keratin and itching of dry skin and being environmentally friendly.

In addition, the cleaning composition of the present invention can form fine bubbles without using water at the time of cleaning, and is characterized in that the bubbles formed are not easily broken.

In addition, the detergent composition of the present invention can remove bubbles with paper or towel without washing process to remove bubbles after cleansing scalp and body, and can remove bubbles with no surfactant components left on skin without washing, It is characterized by.

The saponin extract is used for prevention of dandruff of the scalp, inflammation, improvement of itching of the skin and prevention of hair loss. The content thereof is not limited to, but is not necessarily limited to, 0.1 to 30% by weight of the total detergent composition in order to produce a rich foam, which is a consumer's desire, without adverse effects when it comes in contact with the scalp and skin.

The 1,3-butylene glycol has less feeling of use than glycerin, that is, less sticky, less irritating and toxic to the skin, and can increase the wettability and antibacterial property. The content thereof is not limited, but it can be adjusted as necessary. The specific content is preferably 0.1 to 30% by weight of the total detergent composition to improve the irritation to the skin and the sense of touch to the hair.

Specific examples of the cationic surfactant include a quaternary ammonium salt, an alkylpyridinium salt, an alkylimidazolinium salt, and a primary to tertiary aliphatic amine salt. , Preferably cetyltrimethylammonium chloride, can be used. The content is preferably 0.01 to 10 wt% of the total detergent composition for the purpose of increasing the amount of foam, generating fine bubbles, improving the retention of the foam, and preventing static electricity, but is not limited thereto.

The present invention can improve the moisturizing and hair touch of the skin and scalp by mixing the above-mentioned saponin extract, 1,3-butylene glycol and a cationic surfactant in an appropriate amount, and can form a rich and fine foam, The bubbles are not easily broken during cleaning.

The nymph oil and cinnamon extract can be used for insect pest control and improvement of inflammation of the scalp and promoting hair growth. The content of nymph oil and cinnamon extract is 0.01 to 5 wt% of nymph oil and 0.01 to 5 wt% of cinnamon extract But is not necessarily limited thereto.

The extract is used for blood circulation and antimicrobial action. Extracts obtained by extracting rootstocks of Angelicae radix with ethanol, purified water or a mixture thereof can be used. The content thereof is not limited, but is preferably 0.01 to 5% by weight based on the total detergent composition.

The green tea extract is used as a vitamin c component to prevent hair loss, to remove active oxygen, to sterilize and remove heavy metals, and to increase the moisture retention of the scalp and skin outer layer, 0.01% to 5% by weight of the composition, but not always limited thereto.

The iris extract is used for imparting radiance to the hair and further improving the hair growth. The content of the iris extract may be 0.01 to 5% by weight of the total detergent composition, but is not limited thereto.

The above-mentioned Moringa oil has an antioxidant ability that is 50 times or more higher than that of vitamins, and has an excellent effect for enhancing the health of skin, hair and scalp. It is also used for improving inflammation of scalp and skin and removing dandruff of scalp. The content thereof may be 0.01 to 3% by weight of the total detergent composition to appropriately remove antioxidant ability and inflammation and dandruff of skin and scalp, but is not necessarily limited to the above content.

The phenoxyethanol may be contained in an amount of 0.1 to 3% by weight of the total shampoo composition, and the purified water may include 60 to 85% by weight, but is not limited thereto.

Shampoo, body cleanser, dog cleaner and laundry detergent containing the detergent composition containing the saponin extract described above are also included in the scope of the present invention.

When the detergent composition of the present invention is used as a shampoo, it can improve the keratin and inflammation of the scalp simultaneously with the improvement of the hair. When the body detergent is used, it can improve the itching and keratinization, It is characterized by being environmentally friendly.

In addition, the cleaning composition of the present invention can form fine bubbles without using water at the time of cleaning skin, scalp, dog, and laundry, and is characterized in that the bubbles formed are not easily broken.

In addition, the detergent composition of the present invention can remove bubbles with paper or towel without washing process to remove bubbles after washing the skin, scalp, dog and laundry, and it is possible to remove the surfactant components without washing, It is characterized by not letting.

The present invention can extract saponin at a low temperature by extracting saponin at low temperature from a mixture of a mixture of fruit juice powder, inorganic powder and water to minimize toxic substances, minimize human harmful substances, and extract a high amount of saponin have.

The detergent compositions of the present invention are environmentally friendly and can improve the keratin and inflammation of the scalp, and improve hair and skin.

The present invention can form a foam that does not break easily and long lasting without using water, and can be foamed using a towel or paper without washing process to remove foam after cleaning the scalp and body using the foam , It is easy to carry, easy to carry, and can be used regardless of place, since it does not generate surfactant component because it does not generate inflammation and keratinosis without washing process.

By not using water, the present invention can significantly reduce the drying time of scalp and hair.

The present invention can improve moisturizing and hair touch by mixing an appropriate amount of saponin extract, 1,3-butylene glycol and a cationic surfactant, and it is possible to improve the feel of hair by forming a rich and fine foam, It is not easily broken.

The present invention can improve the insect repellence and inflammation of the skin and scalp and the stimulation of hair growth of scalp by using a detergent containing nematic oil and cinnamon extract.

Best Mode for Carrying Out the Invention Hereinafter, advantages and features of the present invention and methods of achieving them will be described in detail with reference to Examples and Comparative Examples.

It is to be understood that the present invention is not limited to the disclosed embodiments, but may be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the concept of the invention to those skilled in the art. Is provided to fully convey the scope of the invention to those skilled in the art, and the invention is only defined by the scope of the claims. Like reference numerals refer to like elements throughout the specification.

The terminology used herein is for the purpose of illustrating Examples and Comparative Examples, and is not intended to limit the present invention.

Hereinafter, the method of extracting saponin from the fruit juice of the present invention and the detergent composition comprising the saponin according to the present invention will be described.

[Example 1]

Extraction method of saponin from mulberry fruit

After removing the seeds from the dried fruit of the mulberry tree, 100 g of fruit powder, 20 g of gray tourmaline powder (particle size: 30 nm) and 630 g of purified water were pulverized by a pulverizer and mixed in a 2 L beaker. The mixture was stirred at 80 rpm at 20 rpm for 4 hours and then dispersed for 1 hour at a power of 20 hz and 200 watts by using an ultrasonic wave extender (sonifier 450). After the dispersion was completed, the solution was filtered with a 0.45 μm filter, and the filtered solution was centrifuged at 3,000 to 4,000 rpm for 10 minutes to extract 480 g of the solution. Drying oven A hot-air drying was performed at 80 ° C for 7 hours to obtain a 12% powdery saponin extract. Secondary extraction was carried out using the residue remaining on the filter in the same manner to obtain a 6% powdery saponin extract.

Detergent containing saponin extract

5 g of the saponin extract obtained above, 20 g of 1,3-butylene glycol, 1 g of cetyltrimethylammonium chloride, 0.1 g of nematic oil, 0.1 g of cinnamon extract (concentrated by extraction with water) 0.1 g of green tea extract (concentrated by extraction with propylene glycol), 0.1 g of iris extract (concentrated by extraction with water), 0.8 g of phenoxyethanol, 0.5 g of moringa oil and 71.5 g of purified water were mixed and mixed And a saponin-containing detergent was prepared. The results of using the detergent thus prepared as a shampoo are shown in Table 4. < tb > < TABLE >

The prepared detergent was used as a body cleaner, a dog cleaner and a laundry cleaner, and the results are shown in Tables 7, 8 and 9.

[Examples 2 to 10]

As shown in the following Table 1, the method of extracting saponin from the mushroom was extracted in the same manner as in Example 1, and the saponin-containing detergent was extracted with saponin extract, 1,3-butylene glycol, a cationic surfactant, Saponin-containing detergent was prepared in the same manner as in Example 1 except that the contents of nymph oil, cinnamon extract, cinnabar extract, green tea extract, moringa oil, iris extract, phenoxyethanol and purified water were changed , And the result of using the prepared detergent as a shampoo is shown in Table 4.

The prepared detergent was used as a body cleaner, a dog cleaner and a laundry cleaner, and the results are shown in Tables 7, 8 and 9.

[Comparative Example 1]

Extraction method of saponin from mulberry tree

After the seeds were removed from the dried fruit of the alfalfa, 100 g of powdered fruit juice powder and 630 g of purified water were pulverized and mixed in a 2 L beaker. The mixture was stirred at 80 rpm at 20 rpm for 4 hours and then dispersed for 1 hour at a power of 20 hz and 200 watts by using an ultrasonic wave extender (sonifier 450). After the dispersion was completed, the solution was filtered with a 0.45 μm filter, and the filtered solution was centrifuged at 3,000 to 4,000 rpm for 5 minutes to extract 480 g of the solution. Dried in an oven at 80 ° C for 7 hours to obtain 8% powdery saponin extract. Secondary extraction was performed in the same manner using the residue remaining on the filter to obtain a 3% powdery saponin extract.

In the case of Comparative Example 1, when saponin was extracted from the mushroom tree fruit, it was impossible to proceed with the experiment because saponin extraction was difficult because no inorganic powder was added. A saponin-free detergent was prepared and the prepared detergent was shampooed The results are shown in Table 5.

The prepared detergent was used as a body cleaner, a dog cleaner and a laundry cleaner, and the results are shown in Tables 7, 8 and 9.

[Comparative Examples 2 to 10]

As shown in the following Table 2, the saponin extracts were not used, but 1,3-butylene glycol, cationic surfactants, nymph oil, cinnamon extract, cynomolium extract, green tea extract, moringa oil, And the content of purified water was changed. The results are shown in Table 5. The results are shown in Table 5. [Table 5] < tb > < TABLE >

The prepared detergent was used as a body cleaner, a dog cleaner and a laundry cleaner, and the results are shown in Tables 7, 8 and 9.

[Comparative Example 11]

10 g of sodium lauryl sulfate, 2 g of cocamidopropyl betaine, 1 g of potassium cocoyl glycinate, 5 g of sodium carbonate, 3 g of citric acid, 1 g of glycerin, 0.5 g of propylene glycol, 20 g of ethanol, 0.08 g of ethanol and 57.42 g of purified water were mixed and mixed to prepare a cleaning agent. The results of using the prepared cleaning agent as a shampoo are shown in Table 6.

The prepared detergent was used as a body cleaner, a dog cleaner and a laundry cleaner, and the results are shown in Tables 7, 8 and 9.

[Comparative Examples 12 to 20]

As shown in Table 3 below, the content of sodium lauryl sulfate, cocamidopropyl betaine, potassium cocoyl glycinate, sodium carbonate, citric acid, glycerin, propylene glycol, ethanol, phenoxyethanol and purified water The cleaning agent was prepared in the same manner as in Comparative Example 11, and the cleaning agent thus prepared was used as a shampoo.

The prepared detergent was used as a body cleaner, a dog cleaner and a laundry cleaner, and the results are shown in Tables 7, 8 and 9.

[Table 1] The content in Table 1 is g.

[Table 2] The content in Table 2 is g.

[Table 3] The content in Table 3 is g.

Experimental evaluation was carried out as follows.

1) Evaluation of bubble amount

The foaming amount was measured with a container satisfying the following conditions.

Product Material: PET

Product specification: height × diameter = 130 × 48 ㎜ ± 5

Overall height: 171 ㎜ ± 1

Neck size: 43 mm

Contents: 150 ml

The shampoo solution prepared in each of the Examples and Comparative Examples was placed in a container and discharged onto the palm of the hand, and the amount of foam was measured. After the palm was pointed toward the sky, the bubbles were ejected. Then, the palm was observed on the floor, and the time for the foam to fall was confirmed. The amount of bubbles was kept in the palm for about 10 seconds, but dropped in the palm with less than 10 bubbles.

2) Evaluation of moisturizing properties

The moisturizing property was evaluated by whether the scalp was pulled or dried after using the shampoo.

The subjects who participated in the experiment were teenagers, 30s, and 50s or older. The number of people who were in each age group was 30, totaling 10 people.

3) Evaluation of spreadability

The rinseability was determined by measuring the time at which the discharged bubbles collapsed. The amount of foam is good, but if you apply foam to the body, it may turn into water quickly, which may make you feel uncomfortable.

After the foam was applied to the human body, the bubbles were evaluated to be maintained for 10 seconds or longer and to be kept at 10 seconds or less.

4) Evaluation of skin improvement

The evaluation of skin improvement was evaluated by whether or not the scalp had keratin.

Participants in the experiment were evaluated for skin improvement with 10 patients with high keratin, 10 with normal keratin and 10 without keratin.

Each skin condition was tested to confirm the inhibition of keratin.

People who did not develop keratin produced no keratin even when using the shampoo of the above Examples and Comparative Examples.

People with normal keratin and those with keratin affected the occurrence of keratin due to differences in surfactant content or extract content. In addition, the difference was clearly indicated by the presence of tourmaline.

The presence or absence of keratin was evaluated by observing the scalp with an electron microscope.

5) Evaluation of pest control

Pest control ingredients include theophylline, pyrene, pitiline, and parasitic nerve paralysis to help fight pests and protect them from insects.

Evaluation of insect pest was carried out by putting the cleaner of the above-mentioned Examples and Comparative Examples on the arm and putting the arm into a transparent square pail containing pests.

Twenty mosquitoes were placed in each of the transparent square boxes 1 and 2, the arm with the detergent applied to the transparent square barrel 1 was placed in the barrel, and the armless barrel 2 was placed in the barrel to evaluate whether the insect pest was eliminated.

It was confirmed that mosquitoes were avoided in the arm of the transparent rectangular barrel 1 and the insect repellent ability was confirmed, and it was confirmed that the insecticide was not able to be exterminated with a mosquito attached to the arm which did not apply the cleaning agent of the square barrel 2.

Nymph oil, and cinnamon extract, respectively.

6) Evaluation of hair improvement

The evaluation of hair improvement was conducted on people with damaged hair.

Participants in the experiment were as follows.

It has been found that hair remediation improves hair in the detergent of the examples comprising saponin extracted from a moth tree. If the hair is too large, the hair becomes more flaky. If the hair is too small, the effect is insignificant and the effect can not be confirmed.

7) Evaluation of survival

The evaluation of the residual was carried out as an evaluation of whether the detergent could remain on the skin, scalp or hair after using the detergent.

After using the cleaning agents prepared in Examples and Comparative Examples, it was confirmed whether they remained in the scalp or hair using an optical microscope.

8) Evaluation of sense of hair volume

The evaluation of the sensation of hair volume was performed by 20 participants in the evaluation of the sensory evaluation after the shampooing before shampooing, and the hair was evaluated to have a volume feeling after using the shampoo.

9) Evaluation of inflammation removal

Scalp inflammation assessments were conducted on people with inflammation, acne, or spots on the scalp.

Participants in the experiment were as follows.

The inflammation of the scalp was removed by using polyphenol components of saponin, green tea, and Moringa. Using a cleanser, the scalp was gently massaged and evaluated based on the responses and effects of the participants with scalp acne and red spots.

10) Evaluation of dandruff removal

The evaluation of dandruff removal was conducted on people with dandruff on the scalp.

Participants in the experiment were as follows.

The dandruff removal was visually and microscopically confirmed by using the cleanser of Examples and Comparative Examples of the present invention as if lightly massaging the cleanser of the present invention and the comparative example was applied to people with severe dandruff and those with dandruff like scabs.

11) Evaluation of cleaning power

The evaluation of detergency showed the satisfaction of participants and washing of hair.

Twenty participants participated in the experiment. After washing as if lightly massage the detergent without water, the satisfaction and the hairs of the participants were confirmed by microscope and evaluated based on the reaction.

Hereinafter, the results regarding the amounts of foam, moisturizing, spreading, skin improvement, insect repellent, hair improvement, residual feeling, stickiness, hair volume, irritation and dandruff removal according to Examples and Comparative Examples of the present invention are shown ,

Very good: Good: Good: Fair: Fair: Fair: Fair: Fairly poor: Very poor:

Respectively.

[Table 5]

[Table 6]

[Table 7]

[Table 8] When used as a body cleanser

When five subjects were used as a body cleanser,

Very good: Good: Good: Fair: Fair: Fair: Fair: Fair: Fair: Not good: Not marked.

[Table 9] When used as a dog cleaner

When the dog cleaner was used in five dogs, the satisfaction was tabulated. Very good: ⊚, good: ◯, slightly good: ○ △, medium: △, slightly poor: Δ ×, poor: .

[Table 10] When used as washing detergent

Good: O: Good: O: Fair: Fair: Fair: Not satisfactory: Not good: Indicated as X: Good: Good Good: Good Good:

Claims (7)

A) extracting saponin by ultrasonication into a mixed liquid containing fruit juice, fruit powder, and water;
B) separating the extract,
And extracting saponin from the fruit juice. The method according to claim 1,
Wherein the inorganic powder has a particle size of 1 to 100 nm. 3. The method of claim 2,
Wherein the inorganic powder is any one or two or more mixed powders selected from the group consisting of tourmaline, cerium oxide, titanium oxide, talc, aluminum oxide, iron oxide and mica. The method according to claim 1,
Wherein the ultrasound treatment is carried out at a power of 5 to 30 hz at a power of 100 to 500 watts for 0.5 to 3 hours. The method according to claim 1,
Wherein 0.1 to 40 parts by weight of an inorganic powder and 400 to 800 parts by weight of water are contained per 100 parts by weight of the fruit juice. A detergent composition comprising saponin extracted from the non-treated tree fruit according to any one of claims 1 to 5. The method according to claim 6,
Wherein the detergent composition comprises from 0.1 to 30% by weight of saponin extracted from the fruit juice, from 0.1 to 30% by weight of 1,3-butylene glycol, from 0.01 to 10% by weight of a cationic surfactant, from 0.01 to 5% 0.01 to 5% by weight of an extract, 0.01 to 5% by weight of a celeste extract, 0.01 to 5% by weight of a green tea extract, 0.01 to 5% by weight of an iris extract, 0.01 to 3% by weight of a meringue oil, 0.1 to 3% by weight of a phenoxyethanol, 60 to 85% by weight of the detergent composition.