KR20160012598A - Air distribution function and a method of manufacturing a coating solution Gloves - Google Patents

Air distribution function and a method of manufacturing a coating solution Gloves Download PDF

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KR20160012598A
KR20160012598A KR1020140094227A KR20140094227A KR20160012598A KR 20160012598 A KR20160012598 A KR 20160012598A KR 1020140094227 A KR1020140094227 A KR 1020140094227A KR 20140094227 A KR20140094227 A KR 20140094227A KR 20160012598 A KR20160012598 A KR 20160012598A
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coating solution
weight
glove
gloves
coating
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KR1020140094227A
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Korean (ko)
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KR101683767B1 (en
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양두환
이병식
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주식회사 에이치세븐
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/02—Polyureas
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D19/00—Gloves
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D109/00—Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
    • C09D109/02—Copolymers with acrylonitrile
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/80—Processes for incorporating ingredients

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Paints Or Removers (AREA)
  • Gloves (AREA)

Abstract

The present invention relates to a glove coating solution using nitrile butadiene rubber (NBR) resin and polyurea resin, and more specifically, to a method for manufacturing a glove coating solution with an air ventilation function, which prevents sweat from being generated and enables work to be done conveniently without poor feelings of wearing by ventilating air in the gloves when a worker wears the gloves for a long time due to having micropores on a coated side, and to coated gloves manufactured by the method. The method of preparing a glove coating solution with an air ventilation function includes the steps of: preparing a mixed coating solution by mixing 100 to 150 parts by weight of water and 0.5 to 2.0 parts by weight of a foaming agent with respect to 100 parts by weight of a resin mixture mixed by 50 to 70 wt% of NBR resin and 30 to 50 wt% of polyurea resin; putting the mixed coating solution into a stirrer to stir the mixed coating solution for 24 hours; aging the stirred coating solution for 24 hours in a state that stirring of the mixed coating solution is stopped; stirring the aged coating solution in a stirrer to generate bubbles; and coating gloves with the bubble-generated coating solution in a glove coating device.

Description

공기유통 기능을 갖는 장갑 코팅액 제조방법 및 코팅장갑{Air distribution function and a method of manufacturing a coating solution Gloves} TECHNICAL FIELD [0001] The present invention relates to a method of manufacturing a glove coating liquid having an air distribution function and a coating glove,

본 발명은 NBR수지와 폴리 우레아수지를 이용한 장갑 코팅액을 제조하여 장갑의 코팅제로 사용함으로 장갑 착용시 공기가 유통되어 작업자가 오랫동안 착용하더라도 땀이 나지않고 답답하지 않으며 작업이 편리하도록 한 환경친화적인 코팅액을 제공할 수 있도록 한 공기유통 기능을 갖는 코팅액 제조방법 및 그 코팅장갑에 관한 것이다.
The present invention relates to a glove coating solution using NBR resin and polyurea resin and is used as a coating agent for gloves, so that air is circulated when a glove is worn and an environmentally friendly coating solution The present invention relates to a method for manufacturing a coating liquid having an air distribution function and a coating glove thereof.

일반적으로 산업현장에서 근무하는 작업자는 손을 보호하거나 작업물의 오염을 방지하기 위해 장갑을 착용하게 된다.In general, workers at industrial sites wear gloves to protect their hands or to prevent contamination of workpieces.

이와 같이 작업자가 착용하는 장갑은 일의 종류에 따라서 통상적인 직물장갑을 착용하거나, 직물장갑의 손바닥부에 코팅된 장갑을 사용하고 있다.As such, the gloves worn by workers wear conventional fabric gloves or gloves coated on the palms of fabric gloves depending on the type of work.

또한, 직물류의 장갑은 그 목적에 따라 면이나 나일론 등의 다양한 종류의 섬유를 이용하여 제조된다. Also, gloves of fabrics are manufactured using various kinds of fibers such as cotton or nylon according to the purpose.

따라서 섬유를 단순 직조하여 제조된 직물장갑은 미끄러운 물건의 잡거나 기계기구를 취급할 때는 미끄러지는 형상이 발생하여 작업자가 매우 불편한 문제점이 있다.Therefore, the fabric glove made by simple weaving of fibers has a problem that a slippery shape is generated when a slippery object is handled or a machine tool is handled, and the operator is very inconvenient.

상기와 같이 기존의 면 장갑, 직물장갑 등의 섬유로 직조된 장갑은 필요에 따라서 손바닥부와 손가락부 표면에 고무액을 코팅하여 사용하여 왔으나, 고무액을 코팅한 경유 작업대상물을 잡을 때 미끄러지지 않은 장점은 있으나, 오래 작업하거나. 여름철의 경의 공기의 유통이 이루어지지 않아 손바닥에 땀이 발생하여 작업의 능율을 저하시키는 문제점이 있다.As described above, conventional gloves woven with fibers such as cotton gloves, fabric gloves, etc. have been coated with rubber liquid on the palm and fingertip surface as needed. However, in the case of gripping a light oil object coated with a rubber liquid, It has advantages, but it works long. There is a problem that sweat is generated in the palm of the hand because the circulation of the air in the summer is not performed and the efficiency of the work is lowered.

이 분야의 선행기술을 살펴보면, 등록특허공보 제0717975호(2007년05월08일)의 "폴리우레탄 코팅 장갑 및 이의 제조방법"은 면사로 직조된 장갑을 적정의 수분이 함유된 상태에서 코팅액에 디핑하여 건식방식 또는 습식방식으로 코팅막을 형성시켜 제조함에 따라, 수분의 작용에 의해 손바닥부의 내면에는 코팅막이 전혀 형성되지 않고 손바닥부의 외면에만 코팅막이 형성됨으로써, 착용시 부드러운In the prior art of this field, "Polyurethane-coated gloves and method of manufacturing thereof" of Patent Publication No. 0717975 (May 08, 2007) discloses a glove woven with cotton yarn, The coating film is formed only on the outer surface of the palm of the hand without forming a coating film on the inner surface of the palm due to the action of water by forming the coating film by dipping and dry or wet method,

촉감을 제공할 수 있고 땀의 흡수도 원활하게 이루어질 수 있도록 한 폴리우레탄 코팅 장갑 및 이의 제조방법이 개시되었다.A polyurethane-coated glove and a method for producing the same are disclosed.

이와 같이 코팅된 폴리우레탄에 의해 물건을 용이하게 운반할 수 있고 쉽게 떨어지지 않는 등의 장점을 발휘하여 작업의 효율성을 향상시킬 수 있게 된 장점은 있으나, 이러한 폴리우레탄 코팅 장갑은 제조시 습식방식으로 코팅막을 형성시켜 제조함에 따라, 수분의 작용에 의해 손바닥부의 내면에는 코팅막이 전혀 형성되지 않고 손바닥부의 외면에만 코팅막이 형성되도록 하고 있으나, 이는 실제 제작공정에 있어서 수분작용이 손바닥부 내면에만 유지되지 않고 수 분이 외부로 유출됨으로 오부로 유출된 부분은 코팅막을 형성하지 못함으로 코팅의 불량율이 증가되는 문제점이 있다.
The polyurethane coated gloves are advantageous in that they can easily transport objects with the coated polyurethane and are not easily detached, thereby improving the efficiency of the work. However, such polyurethane- A coating film is formed only on the outer surface of the palm and no coating film is formed on the inner surface of the palm due to the action of water. However, in the actual manufacturing process, the water activity is not maintained only on the inner surface of the palm, The part that flows out to the outside due to the leakage of the powder to the outside can not form a coating film, thereby increasing the defective rate of the coating.

대한민국 등록특허공보 제0717975호Korean Patent Registration No. 0717975

본 발명은 상기와 같은 문제점을 해결하기 위한 것으로서, NBR수지와 폴리 우레아수지, 물을 교반하여 제조한 장갑 코팅액을 제조하여 장갑의 코팅제로 사용함으로 장갑 착용시 공기가 유통되어 작업자가 오랫동안 착용하더라도 땀이 발생하지 않고, 착용감이 답답하지 않아 작업이 편리하도록 한 공기 통풍 기능을 갖는 코팅액 제조방법 및 그 코팅장갑을 제공함을 목적으로 한 것이다.
The present invention has been made to solve the above problems, and it is an object of the present invention to provide a glove coating solution prepared by stirring NBR resin, polyurea resin, and water, and used as a coating agent for gloves, so that when the gloves are worn, And an air ventilation function for preventing an unfavorable wearing feeling and making the operation easy, and a coating glove thereof.

본 발명의 목적을 달성하기 위한 것으로서,In order to achieve the object of the present invention,

NBR수지 50∼70중량%와 폴리 우레아(poly urea)수지 30∼50중량%를 혼합한 수지혼합물 100 중량부에 대하여 물 100∼150중량부, 기포제 0.5∼2.0중량부를 혼합하는 코팅액 혼합 단계; 100 to 150 parts by weight of water and 0.5 to 2.0 parts by weight of a foaming agent are mixed with 100 parts by weight of a resin mixture comprising 50 to 70% by weight of an NBR resin and 30 to 50% by weight of a polyurea resin,

상기 혼합된 코팅액을 교반기에 넣고 24시간 교반하는 단계;Stirring the mixed coating solution in a stirrer for 24 hours;

상기 교반된 코팅액을 교반을 멈춘 상태에서 24시간 동안 숙성시키는 단계;Aging the agitated coating solution for 24 hours while stopping stirring;

상기 숙성된 코팅액을 교반기에서 교반하여 기포를 발생시키는 단계;Stirring the aged coating liquid in an agitator to generate bubbles;

상기 기포를 발생시킨 코팅액을 이용하여 장갑코팅장치로 장갑을 코팅하는 단계로 이루어진다. And coating the glove with a glove coating apparatus using the coating liquid generating the bubbles.

이와 같이 된 본 발명은 기존에 NBR 수지 코팅만을 사용하여 장갑을 코팅할 경우 물 또는 기름이 묻으면 미끄러움이 발생되나 본 발명은 NBR 수지, 폴리 우레아(poly urea)수지, 물, 기포제를 이용하여 코팅액을 제조하되 이의 코팅액에 미세한 기포가 형성되도록 함으로 장갑에 코팅시 물의 유통은 차단하고 공기는 유통되도록한 것이다.In the present invention, when the glove is coated using only the NBR resin coating, slip occurs when water or oil is applied. However, the present invention can be applied to the case where water or oil is added to the glove, and the present invention uses NBR resin, polyurea resin, A coating liquid is prepared, and fine bubbles are formed in the coating liquid. When the coating liquid is coated on the gloves, the flow of water is blocked and the air is circulated.

본 발명은 장갑코팅액 제조시 미세한 기포가 형성되도록 함으로서 코팅된 장갑의 코팅 면에 공기의 유통이 이루어져 착용자의 손바닥에 땀이 발생되지 않아 작업시 땀에 의한 불편함을 방지하는 동시에, 물, 기름이 묻더라도 미끄럼을 방지하는 효과를 갖는다. In the present invention, since minute bubbles are formed in the production of the glove coating liquid, air is circulated on the coated surface of the coated gloves, so that sweat is not generated on the palms of the wearer, It has an effect of preventing sliding even when buried.

도1은 본 발명의 장갑코팅액 제조 공정도를 나타낸 블록도이다.1 is a block diagram showing a manufacturing process of a glove coating liquid according to the present invention.

이한 본 발명의 실시 예를 상세히 설명하면 다음과 같다.Hereinafter, an embodiment of the present invention will be described in detail.

제1공정: 코팅액 혼합단계(S10)First step: coating liquid mixing step (S10)

본 발명에서 설명되는 코팅수지 원료는 시중에서 유통되는 원재료를 구입하여 사용한다. The coating resin raw material described in the present invention is obtained by purchasing raw materials distributed in the market.

NBR수지 50∼70중량%와,50 to 70% by weight of an NBR resin,

폴리 우레아(poly urea)수지 30∼50중량%,30 to 50% by weight of a polyurea resin,

상기 NBR수지와 폴리 우레아를 혼합한 수지혼합물 100 중량부에 대하여 물 100∼150중량부 및 기포제 0.5∼2.0중량부로 혼합한다.100 to 150 parts by weight of water and 0.5 to 2.0 parts by weight of a foaming agent are mixed with 100 parts by weight of a resin mixture obtained by mixing the NBR resin and polyurea.

이를 다시 설명하면 상기 NBR수지 50∼70중량%와, 폴리 우레아(poly urea)수지 30∼50중량%로 혼합한 수지혼합물 1에 대하여 물 1∼1.5배의 중량비율로 혼합한다. To be more specific, the resin mixture 1 mixed with 50 to 70% by weight of the NBR resin and 30 to 50% by weight of the polyurea resin is mixed at a weight ratio of 1 to 1.5 times of water.

또한 상기 수지혼합물 100 중량부에 대하여 기포제 0.5∼2.0중량부로 혼합한다.
Further, 0.5 to 2.0 parts by weight of a foaming agent is mixed with 100 parts by weight of the resin mixture.

제2공정: 코팅액 1차 교반단계(S20)Second step: Primary stirring step (S20)

상기 혼합된 코팅액을 교반기에 넣고 24시간 교반한다.The mixed coating liquid is put into a stirrer and stirred for 24 hours.

상기 코팅액을 교반하는 교반기는 통상 안료를 교반하는 교반기를 사용하여 교반하다.The stirrer for stirring the coating liquid is usually stirred using a stirrer for stirring the pigment.

상기 코팅액을 교반하는 교반 날개의 RPM은 통상의 방법으로 시행되며, 교반기의 교반 온도는 상온에서 실시된다.
The RPM of the agitating blades stirring the coating liquid is carried out by a conventional method, and the stirring temperature of the agitator is carried out at room temperature.

제3공정: 코팅액 숙성단계(S30)Step 3: Aging the coating liquid (S30)

상기 교반기에서 교반된 코팅액은 교반기를 멈춘 상태에서 24시간 동안 숙성시킨다.The agitated coating liquid in the agitator is aged for 24 hours while the agitator is stopped.

상기 숙성은 상온에서 실시된다.
The aging is carried out at room temperature.

제4공정: 코팅액 2차 교반단계(S40)Step 4: Secondary stirring step (S40)

상기 숙성된 코팅액을 교반기에서 교반하여 기포를 발생시키는 단계를 실시한다.The aged coating liquid is stirred in a stirrer to generate bubbles.

본 공정에서는 1차 교반이 실시된 상태에서 24시간 보관하면서 숙성시킨 상태이므로 혼합된 코팅액의 입자가 연화되어 안정화된 상태이므로 이를 단시 2차 교반하면 코팅액 내부에 미세한 기포가 형성된다.In this process, the particles of the mixed coating liquid are in a state of being stabilized because the particles of the mixed coating liquid are aged while being kept in the state of being subjected to the primary agitation for 24 hours, so that when the particles are agitated for a second time, minute bubbles are formed in the coating liquid.

본 공정에서는 코팅액을 별도의 포장용기에 포장하여 장갑 코팅액으로 판매될 수 있다.
In this step, the coating liquid may be packaged in a separate packaging container and sold as a glove coating liquid.

제5공정: 장갑에 코팅단계(S50) Fifth step: coating step on gloves (S50)

상기 기포를 발생시킨 코팅액을 이용하여 장갑코팅장치로 장갑을 코팅한다.The glove is coated with a coating liquid for forming the bubbles by means of a glove coating apparatus.

본 공정에서 장갑에 코팅하는 코팅기는 현재 사용되는 어느 것을 사용하더라도 무방하다.In this process, a coating machine for coating on gloves may be used in any of the currently used coaters.

즉, 필요에 따라서 장갑의 손바닥 면과 손가락 바닥면에만 코팅할 수 있도 있고, 장갑 손목부위만 빼고 나머지 전체를 코팅할 수도 있고, 또한 손바닥 면과 손가락 전체가 코팅될 수 있도록 코팅할 수 있다.That is, if necessary, it can be coated only on the palm side and the finger bottom side of the glove, or the whole of the glove can be coated except for the wrist part, or the palm side and the entire finger can be coated.

이와 같이 코팅된 본 발명은 코팅액의 조성물 중 주 조성물을 물을 사용함으로 환경친화적인 소재를 사용하는 특징을 가지며, 코팅액을 이용하여 장갑에 코팅작업시 유해물질의 발생이 극히 미세하여 눈이 따가운 현상과 악취가 발생하지 않으므로 호흡기질환을 반지하는 효과를 갖는다.The coated coating of the present invention is characterized by using an environmentally friendly material by using water as the main composition of the composition of the coating liquid. When the coating liquid is coated on the gloves, the occurrence of toxic substances is extremely fine, And odor does not occur, it has an effect of ringing respiratory diseases.

또한 본 발명은 기존의 코팅제가 NBR수지만을 사용함으로써 작업시 기름, 물등이 코팅 면에 묻으면 잡을 때 미끄러지는 현상L 발생하였으나. NBR수지 50∼70중량%와, 폴리 우레아(poly urea)수지 30∼50중량%, NBR수지와 폴리 우레아를 혼합한 수지혼합물 100 중량부에 대하여 물 100∼150중량부 및 기포제 0.5∼2.0중량부로 조성된 코팅액 조성물을 사용함으로 코팅된 장갑의 코팅 면에 미세한 기공이 형성되어 공기는 유통되고, 물은 차단되어 작업시 손바닥에 땀이 발생하는 것을 막아준다.Also, according to the present invention, since the conventional coating agent uses NBR resin, when the oil or water is applied to the coating surface during the operation, the coating slips when the coating is caught. (100 to 150 parts by weight of water and 0.5 to 2.0 parts by weight of a foaming agent) of 50 to 70% by weight of an NBR resin, 30 to 50% by weight of a polyurea resin, 100 parts by weight of a resin mixture comprising an NBR resin and a polyurea, By using the coating liquid composition, fine pores are formed on the coated surface of the coated glove, air is circulated and water is blocked, thereby preventing perspiration on the palm during working.

또한 본 발명은 코팅면에 미세한 기공을 가지므로 작업자가 장갑을 오랜 시간 착용하더라도 공기의 유통에 의해 손이 답답한 현상이 없이 착용감이 좋은 장점이 있다.
Further, since the present invention has fine pores on the coated surface, even when the operator wears the gloves for a long time, the hand does not become stiffer due to the circulation of the air and the wear comfort is good.

S10: 코팅액 혼합단계
S20: 코팅액 1차 교반단계
S30: 코팅액 숙성단계
S40: 코팅액 2차 교반단계
S50: 장갑에 코팅단계 S10: coating liquid mixing step
S20: Primary stirring step of coating liquid
S30: Step of aging the coating solution
S40: Secondary stirring step of coating liquid
S50: Coating step on gloves

Claims (3)

장갑 코팅액 제조방법에 있어서,
NBR수지 50∼70중량%와 폴리 우레아(poly urea)수지 30∼50중량%를 혼합한 수지혼합물 100 중량부에 대하여 물 100∼150중량부, 기포제 0.5∼2.0중량부를 혼합하는 코팅액 혼합 단계;
상기 혼합된 코팅액을 교반기에 넣고 24시간 교반하는 단계;
상기 교반된 코팅액을 교반을 멈춘 상태에서 24시간 동안 숙성시키는 단계;
상기 숙성된 코팅액을 교반기에서 교반하여 기포를 발생시키는 단계;
상기 기포를 발생시킨 코팅액을 이용하여 장갑코팅장치로 장갑을 코팅하는 단계로 이루어진 공기유통 기능을 갖는 장갑 코팅액 제조방법 및 코팅장갑.A method for manufacturing a glove coating liquid,
100 to 150 parts by weight of water and 0.5 to 2.0 parts by weight of a foaming agent are mixed with 100 parts by weight of a resin mixture comprising 50 to 70% by weight of an NBR resin and 30 to 50% by weight of a polyurea resin,
Stirring the mixed coating solution in a stirrer for 24 hours;
Aging the agitated coating solution for 24 hours while stopping stirring;
Stirring the aged coating liquid in an agitator to generate bubbles;
And coating the glove with a glove coating apparatus using the coating liquid generating the bubbles. 장갑 코팅액 조성물은,
NBR수지 50∼70중량%와 폴리 우레아(poly urea)수지 30∼50중량%를 혼합한 수지혼합물 100 중량부에 대하여 물 100∼150중량부, 기포제 0.5∼2.0중량부를 혼합한 공기유통 기능을 갖는 장갑 코팅액 조성물.The glove coating composition may be,
100 to 150 parts by weight of water and 0.5 to 2.0 parts by weight of a foaming agent are mixed with 100 parts by weight of a resin mixture comprising 50 to 70% by weight of an NBR resin and 30 to 50% by weight of a polyurea resin, Glove coating composition. 제1항의 제조방법에 의해 제조된 코팅 장갑.

A coated glove made by the method of claim 1.

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