CN108976534A - A kind of safety and industrial gloves and its manufacture craft of the ultra-thin anti-skidding skin care of butyronitrile - Google Patents
A kind of safety and industrial gloves and its manufacture craft of the ultra-thin anti-skidding skin care of butyronitrile Download PDFInfo
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- CN108976534A CN108976534A CN201810748355.7A CN201810748355A CN108976534A CN 108976534 A CN108976534 A CN 108976534A CN 201810748355 A CN201810748355 A CN 201810748355A CN 108976534 A CN108976534 A CN 108976534A
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- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/142—Compounds containing oxygen but no halogen atom
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/0055—Plastic or rubber gloves
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C41/14—Dipping a core
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D2400/00—Functions or special features of garments
- A41D2400/80—Friction or grip reinforcement
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- C08J2313/00—Characterised by the use of rubbers containing carboxyl groups
- C08J2313/02—Latex
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Abstract
The invention discloses the safety and industrial gloves and its manufacture craft of a kind of ultra-thin anti-skidding skin care of butyronitrile, gloves are made of each substance of following mass parts: 100 parts of carboxylic acrylonitrile butadiene rubber latex, 0.1-1 parts of potassium hydroxide, 0.5-3 parts of zinc oxide, 0.5-1.5 parts of sulphur, 0.5-3 parts of promotor, 1-2 parts of anti-aging agent, 0.05-0.2 parts of dispersing agent, 1-3 parts of titanium dioxide, 1-3 parts of anti-wear agent, coupling agent 0.2-1 parts aqueous, 1-4 parts of wax emulsion, 10-30 parts of deionized water, 1-5 parts of thickener, 1-3 parts of foaming agent.The manufacture craft of gloves includes multiple steps, whole are as follows: cover die, preheating, leaching coagulator, impregnation, spray salt, drying, washing, drying vulcanization, demoulding, skin conditioner processing, secondary drying, finished product.The present invention is low to the consumption of raw material, and gloves are frivolous flexibly, grip is strong, wear-resisting property is excellent, using comfortable, and therefore, the application scenarios of product are very extensive, and this product is skin friendly, have protective effect to skin.
Description
Technical field
The present invention relates to a kind of gloves and its manufacture craft more particularly to a kind of labour protection hands of the ultra-thin anti-skidding skin care of butyronitrile
Set and its manufacture craft.
Background technique
Nitrile rubber safety and industrial gloves is with its excellent oil resistance, wear-resisting excellent, wearing comfort, and raw material sources are extensive, valence
The advantages such as lattice are moderate, increasing trend is presented in usage amount in recent years.As butyronitrile safety and industrial gloves is used because of above-mentioned advantage
Amount becomes increasing, and the safety and industrial gloves of various category knitting liner dip-coating butyronitrile coatings is developed applied to each neck
Domain.Wherein, glove surface coating did anti-skid frosted processing, more with extremely excellent grip, non-skid property by vast
The trend of rising is presented always in the favor of labourer, consumer, its usage amount.
Although existing butyronitrile frosted safety and industrial gloves have the advantages that it is many, due to being all made of traditional impregnation scheme
It is made, gloves product is harder, and the dexterity of user is insufficient after wearing, can not be applied to accurate operation
The defect in class field；And the chemicals such as methanol, calcium nitrate are inevitably applied in its production process, therefore remain
Object can generate certain injury to skin；The usage amount of parent latex (carboxylic acrylonitrile butadiene rubber latex) is also relatively large, due to carboxyl fourth
Nitrile latex is to be formed by raw material emulsion polymerizations such as the product butadiene of petrochemical industry, acrylonitrile, and belong to can not for these raw materials
Regenerated resources, therefore, the usage amount for how saving these industrial chemicals achieve the purpose that sustainable development, are labour protection hands instantly
Covering developer, there is still a need for the directions of effort.
Summary of the invention
In order to solve shortcoming present in above-mentioned technology, the present invention provides a kind of ultra-thin anti-skidding skin cares of butyronitrile
Safety and industrial gloves and its manufacture craft.
In order to solve the above technical problems, the technical solution adopted by the present invention is that: a kind of labor of the ultra-thin anti-skidding skin care of butyronitrile
Gloves are protected, are made of each substance of following mass parts:
Further, promotor is one of promotor ZDC, accelerant B Z, promotor TP.
Further, anti-aging agent is Hinered phenols antioxidant.
Further, dispersing agent be sodium metnylene bis-naphthalene sulfonate, calgon, sodium pyrophosphate, mostly in polynary
One of more aziridine block copolymers of alcohol-.
Titanium dioxide is preferably rutile type titanium white.
Further, anti-wear agent is one of nano silica, mica powder, nano aluminium oxide, carbon black, silicon carbide
Or two kinds of combination.
Further, aqueous coupling agent is silane coupling agent KH450, silane coupling agent KH566, silane coupling agent KH578
One of.
Further, wax emulsion be polythene wax emulsion, paraffin wax emulsions, palm wax emulsion, dimethicone wax emulsion,
One of hydroxy silicon oil wax emulsion.
Further, thickener is sodium carboxymethylcellulose, hydroxyethyl cellulose, casein, Sodium Polyacrylate, alkali soluble
The combination of one or both of swollen acrylic thickener.
Further, foaming agent is neopelex.
A kind of manufacture craft of the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile, overall flow are as follows:
A, by mass parts be respectively 0.1-1 parts of potassium hydroxide, 0.5-3 parts of zinc oxide, 0.5-1.5 parts of sulphur,
0.5-3 parts of promotor, 1-2 parts of anti-aging agent, 0.05-0.2 parts of dispersing agent, 1-3 parts of titanium dioxide, 1-3 parts wear-resisting
Agent, 0.2-1 parts of aqueous coupling agent, 10-30 parts of deionized water are added into ball mill, grind 72h, obtain vulcanizing agent point
Granular media；
B, agent dispersion and the addition of 100 parts of carboxylic acrylonitrile butadiene rubber latex, 1-3 parts of foaming agent will be vulcanized after ball milling
To the sulfur still with frequency control function, adjustment revolving speed is 30-180 revs/min, stirs 6-12 hours, obtains vulcanizate
Material；
C, vulcanized rubber is filtered with the strainer of 100-200 mesh, 1-4 parts of wax emulsion is then added, carried out mechanical
Foaming；Then 1-5 parts of thickener is added to be viscosified, butyronitrile slurry is made；
D, gloves impregnation forms:
A, knitted gloves is covered on mold, carries out 50-70 DEG C of preheating, then successively immerses coagulator, butyronitrile slurry
It is interior, it proposes；Coagulator is the calcium nitrate methanol soln of 0.5-5%；
B, upper one layer of anhydrous sodium sulfate particle is sprayed on the glove mould surface after impregnation, is then fed into baking oven dry
Processing；
C, the glove mould after drying is put into clear water, foam washing 40-60 minutes；
D, the glove mould after foam washing 80-120 DEG C of drying in oven is put into vulcanize 60-125 minutes；
E, it demoulds, makes gloves and mold separation；
F, the gloves separated are immersed in skin care agent solution and are handled 30 minutes；Skin conditioner be natural moisturizing factor,
The combination of one or both of polyalcohol, amino acid；The mass concentration of skin care agent solution is 0.5-10%；
G, skin conditioner treated gloves are dried, the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile is made.
The present invention is low to the consumption of raw material, and gloves are frivolous flexibly, grip is strong, wear-resisting property is excellent, use
Comfortably, therefore, the application scenarios of product are very extensive, and this product is skin friendly, have protective effect to skin.
Specific embodiment
The present invention will be further described in detail with reference to the specific embodiments.
A kind of safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile, is made of each substance of following mass parts:
Wherein, promotor is one of promotor ZDC, accelerant B Z, promotor TP.
Anti-aging agent is Hinered phenols antioxidant.
Dispersing agent be sodium metnylene bis-naphthalene sulfonate, calgon, sodium pyrophosphate, mostly in it is sub- with the more ethylene of polyalcohol-
One of amine block copolymer.
Titanium dioxide is preferably rutile type titanium white.
Anti-wear agent is the group of one or both of nano silica, mica powder, nano aluminium oxide, carbon black, silicon carbide
It closes.
Aqueous coupling agent is one of silane coupling agent KH450, silane coupling agent KH566, silane coupling agent KH578.
Wax emulsion is polythene wax emulsion, paraffin wax emulsions, palm wax emulsion, dimethicone wax emulsion, hydroxy silicon oil wax
One of lotion.
Thickener is sodium carboxymethylcellulose, hydroxyethyl cellulose, casein, Sodium Polyacrylate, alkali soluble is swollen, and acrylic acid increases
One or both of thick dose of combination.
Foaming agent is neopelex.
A kind of manufacture craft of the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile, overall flow are as follows:
A, by mass parts be respectively 0.1-1 parts of potassium hydroxide, 0.5-3 parts of zinc oxide, 0.5-1.5 parts of sulphur,
0.5-3 parts of promotor, 1-2 parts of anti-aging agent, 0.05-0.2 parts of dispersing agent, 1-3 parts of titanium dioxide, 1-3 parts wear-resisting
Agent, 0.2-1 parts of aqueous coupling agent, 10-30 parts of deionized water are added into ball mill, grind 72h, obtain vulcanizing agent point
Granular media；
B, agent dispersion and the addition of 100 parts of carboxylic acrylonitrile butadiene rubber latex, 1-3 parts of foaming agent will be vulcanized after ball milling
To the sulfur still with frequency control function, adjustment revolving speed is 30-180 revs/min, stirs 6-12 hours, obtains vulcanizate
Material；
C, vulcanized rubber is filtered with the strainer of 100-200 mesh, 1-4 parts of wax emulsion is then added, carried out mechanical
Foaming；Gas release is 10-40%, and 1-5 parts of thickener is then added and is viscosified, the viscosity of final butyronitrile slurry is 100-
3000mpa.s；
D, gloves impregnation forms:
A, knitted gloves is covered on mold, carries out 50-70 DEG C of preheating, then successively immerses coagulator, butyronitrile slurry
It is interior, it proposes；Coagulator is the calcium nitrate methanol soln of 0.5-5%；
B, the anhydrous sodium sulfate particle of upper one layer of 30-120 mesh is sprayed on the glove mould surface after impregnation, is then fed into
It is dried in 50-90 DEG C of baking oven, the surface of gloves is made to have the effect of frosted, antiskid function can be played；
C, the glove mould after drying is put into clear water, foam washing 40-60 minutes；
D, the glove mould after foam washing 80-120 DEG C of drying in oven is put into vulcanize 60-125 minutes；
E, it demoulds, makes gloves and mold separation；
F, the gloves separated are immersed in skin care agent solution and are handled 30 minutes；Skin conditioner be natural moisturizing factor,
The combination of one or both of polyalcohol, amino acid；The mass concentration of skin care agent solution is 0.5-10%；
G, skin conditioner treated gloves are dried, the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile is made.
It elaborates below by specific embodiment to technical solution of the present invention:
Embodiment one,
A kind of safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile, is made of each substance of following mass parts:
Wherein, promotor is promotor ZDC.Anti-aging agent is Hinered phenols antioxidant.Dispersing agent is methylene dinaphthalene sulfonic acid
Sodium.Titanium dioxide is rutile type titanium white.Anti-wear agent is nano silica.Aqueous coupling agent is silane coupling agent KH450.
Wax emulsion is polythene wax emulsion.Thickener is sodium carboxymethylcellulose.Foaming agent is neopelex.
The manufacture craft of safety and industrial gloves in the present embodiment are as follows:
It A, is respectively 0.1 part of potassium hydroxide, 3 parts of zinc oxide, 1.5 parts of sulphur, 0.5 part of promotion by mass parts
Agent, 2 parts of anti-aging agent, 0.2 part of dispersing agent, 1 part of titanium dioxide, 1 part of anti-wear agent, 0.2 part of aqueous coupling agent, 30 parts
Deionized water be added into ball mill, grind 72h, obtain vulcanization agent dispersion；
B, by after ball milling vulcanization agent dispersion and 100 parts of carboxylic acrylonitrile butadiene rubber latex, 1 part of foaming agent be added to
In sulfur still with frequency control function, adjustment revolving speed is 30 revs/min, stirs 12 hours, obtains vulcanized rubber；
C, vulcanized rubber is filtered with the strainer of 100 mesh, 4 parts of wax emulsion is then added, carries out mechanical foaming；
Then 1 part of thickener is added to be viscosified；
D, gloves impregnation forms:
A, knitted gloves is covered on mold, carries out 50 DEG C of preheatings, then successively immersed coagulator, in butyronitrile slurry, mention
Out；The calcium nitrate methanol soln that coagulator is 0.5%；
B, upper one layer of anhydrous sodium sulfate particle is sprayed on the glove mould surface after impregnation, is then fed into baking oven and carries out
It is dried；
C, the glove mould after drying is put into clear water, foam washing 40 minutes；
D, the glove mould after foam washing 80 DEG C of drying in oven are put into vulcanize 125 minutes；
E, it demoulds, makes gloves and mold separation；
F, the gloves separated are immersed in skin care agent solution and are handled 30 minutes；Skin conditioner is natural moisturizing factor；
The mass concentration of skin care agent solution is 0.5%；
G, skin conditioner treated gloves are dried, the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile is made.
Embodiment two,
A kind of safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile, is made of each substance of following mass parts:
Wherein, promotor is accelerant B Z.Anti-aging agent is Hinered phenols antioxidant.Dispersing agent is calgon.Titanium white
Powder is rutile type titanium white.Anti-wear agent is mica powder.Aqueous coupling agent is silane coupling agent KH566.Wax emulsion is paraffin cream
Liquid thickener is hydroxyethyl cellulose.Foaming agent is neopelex.
A kind of manufacture craft of the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile, overall flow are as follows:
A, by mass parts be respectively 1 part of potassium hydroxide, 0.5 part of zinc oxide, 0.5 part of sulphur, 3 parts of promotor,
1 part of anti-aging agent, 0.05 part of dispersing agent, 3 parts of titanium dioxide, 3 parts of anti-wear agent, 1 part of aqueous coupling agent, 10 parts go
Ionized water is added into ball mill, grinds 72h, obtains vulcanization agent dispersion；
B, by after ball milling vulcanization agent dispersion and 100 parts of carboxylic acrylonitrile butadiene rubber latex, 3 parts of foaming agent be added to
In sulfur still with frequency control function, adjustment revolving speed is 180 revs/min, stirs 6 hours, obtains vulcanized rubber；
C, vulcanized rubber is filtered with the strainer of 200 mesh, 1 part of wax emulsion is then added, carries out mechanical foaming；
Then 5 parts of thickener is added to be viscosified；
D, gloves impregnation forms:
A, knitted gloves is covered on mold, carries out 70 DEG C of preheatings, then successively immersed coagulator, in butyronitrile slurry, mention
Out；The calcium nitrate methanol soln that coagulator is 5%；
B, upper one layer of anhydrous sodium sulfate particle is sprayed on the glove mould surface after impregnation, is then fed into baking oven and carries out
It is dried；
C, the glove mould after drying is put into clear water, foam washing 60 minutes；
D, the glove mould after foam washing 120 DEG C of drying in oven are put into vulcanize 60 minutes；
E, it demoulds, makes gloves and mold separation；
F, the gloves separated are immersed in skin care agent solution and are handled 30 minutes；Skin conditioner is polyalcohol；Skin conditioner
The mass concentration of solution is 10%；
G, skin conditioner treated gloves are dried, the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile is made.
Embodiment three,
A kind of safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile, is made of each substance of following mass parts:
Wherein, promotor is promotor TP.Anti-aging agent is Hinered phenols antioxidant.Dispersing agent is sodium pyrophosphate.Titanium dioxide
For rutile type titanium white.Anti-wear agent is nano aluminium oxide.Aqueous coupling agent is silane coupling agent KH578.Wax emulsion is palm
Wax emulsion.Thickener is casein.Foaming agent is neopelex.
A kind of manufacture craft of the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile, overall flow are as follows:
A, by mass parts be respectively 0.5 part of potassium hydroxide, 2 parts of zinc oxide, 1 part of sulphur, 2 parts of promotor,
1.5 parts of anti-aging agent, 0.1 part of dispersing agent, 2 parts of titanium dioxide, 2 parts of anti-wear agent, 0.5 part of aqueous coupling agent, 20 parts
Deionized water is added into ball mill, grinds 72h, obtains vulcanization agent dispersion；
B, by after ball milling vulcanization agent dispersion and 100 parts of carboxylic acrylonitrile butadiene rubber latex, 2 parts of foaming agent be added to
In sulfur still with frequency control function, adjustment revolving speed is 100 revs/min, stirs 8 hours, obtains vulcanized rubber；
C, vulcanized rubber is filtered with the strainer of 150 mesh, 3 parts of wax emulsion is then added, carries out mechanical foaming；
Then 4 parts of thickener is added to be viscosified；
D, gloves impregnation forms:
A, knitted gloves is covered on mold, carries out 60 DEG C of preheatings, then successively immersed coagulator, in butyronitrile slurry, mention
Out；The calcium nitrate methanol soln that coagulator is 3%；
B, upper one layer of anhydrous sodium sulfate particle is sprayed on the glove mould surface after impregnation, is then fed into baking oven and carries out
It is dried；
C, the glove mould after drying is put into clear water, foam washing 50 minutes；
D, the glove mould after foam washing 100 DEG C of drying in oven are put into vulcanize 80 minutes；
E, it demoulds, makes gloves and mold separation；
F, the gloves separated are immersed in skin care agent solution and are handled 30 minutes；Skin conditioner is amino acid；Skin conditioner
The mass concentration of solution is 5%；
G, skin conditioner treated gloves are dried, the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile is made.
Example IV,
A kind of safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile, is made of each substance of following mass parts:
Wherein, promotor is promotor ZDC.Anti-aging agent is Hinered phenols antioxidant.Dispersing agent is how interior with polynary
The more aziridine block copolymers of alcohol-.Titanium dioxide is rutile type titanium white.Anti-wear agent is carbon black.Aqueous coupling agent is silane
Coupling agent KH450.Wax emulsion is dimethicone wax emulsion.Thickener is Sodium Polyacrylate.Foaming agent is detergent alkylate sulphur
Sour sodium.
A kind of manufacture craft of the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile, overall flow are as follows:
A, by mass parts be respectively 0.8 part of potassium hydroxide, 1 part of zinc oxide, 0.8 part of sulphur, 1 part of promotor,
1.2 parts of anti-aging agent, 0.15 part of dispersing agent, 2 parts of titanium dioxide, 1.5 parts of anti-wear agent, 0.8 part of aqueous coupling agent, 15
The deionized water of part is added into ball mill, grinds 72h, obtains vulcanization agent dispersion；
B, by the vulcanization agent dispersion and 100 parts of carboxylic acrylonitrile butadiene rubber latex, the addition of 1.5 parts of foaming agent after ball milling
To the sulfur still with frequency control function, adjustment revolving speed is 80 revs/min, stirs 10 hours, obtains vulcanized rubber；
C, vulcanized rubber is filtered with the strainer of 160 mesh, 2 parts of wax emulsion is then added, carries out mechanical foaming；
Then 3 parts of thickener is added to be viscosified；
D, gloves impregnation forms:
A, knitted gloves is covered on mold, carries out 60 DEG C of preheatings, then successively immersed coagulator, in butyronitrile slurry, mention
Out；The calcium nitrate methanol soln that coagulator is 2%；
B, upper one layer of anhydrous sodium sulfate particle is sprayed on the glove mould surface after impregnation, is then fed into baking oven and carries out
It is dried；
C, the glove mould after drying is put into clear water, foam washing 60 minutes；
D, the glove mould after foam washing 120 DEG C of drying in oven are put into vulcanize 60 minutes；
E, it demoulds, makes gloves and mold separation；
F, the gloves separated are immersed in skin care agent solution and are handled 30 minutes；Skin conditioner is natural moisturizing factor
With the combination of polyalcohol；The mass concentration of skin care agent solution is 8%；
G, skin conditioner treated gloves are dried, the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile is made.
Embodiment five,
A kind of safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile, is made of each substance of following mass parts:
Wherein, promotor is accelerant B Z.Anti-aging agent is Hinered phenols antioxidant.Dispersing agent is methylene dinaphthalene sulfonic acid
Sodium.Titanium dioxide is rutile type titanium white.Anti-wear agent is silicon carbide.Aqueous coupling agent is silane coupling agent KH566.Wax emulsion
For hydroxy silicon oil wax emulsion.Thickener is the swollen acrylic thickener of alkali soluble.Foaming agent is neopelex.
A kind of manufacture craft of the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile, overall flow are as follows:
It A, is respectively 0.2 part of potassium hydroxide, 1.5 parts of zinc oxide, 1.2 parts of sulphur, 1.5 parts of rush by mass parts
Into agent, 1.7 parts of anti-aging agent, 0.2 part of dispersing agent, 1.5 parts of titanium dioxide, 2.5 parts of anti-wear agent, 0.4 part of aqueous coupling
Agent, 15 parts of deionized water are added into ball mill, grind 72h, obtain vulcanization agent dispersion；
B, by after ball milling vulcanization agent dispersion and 100 parts of carboxylic acrylonitrile butadiene rubber latex, 2 parts of foaming agent be added to
In sulfur still with frequency control function, adjustment revolving speed is 100 revs/min, stirs 8 hours, obtains vulcanized rubber；
C, vulcanized rubber is filtered with the strainer of 200 mesh, 3 parts of wax emulsion is then added, carries out mechanical foaming；
Then 2 parts of thickener is added to be viscosified；
D, gloves impregnation forms:
A, knitted gloves is covered on mold, carries out 60 DEG C of preheatings, then successively immersed coagulator, in butyronitrile slurry, mention
Out；The calcium nitrate methanol soln that coagulator is 4%；
B, upper one layer of anhydrous sodium sulfate particle is sprayed on the glove mould surface after impregnation, is then fed into baking oven and carries out
It is dried；
C, the glove mould after drying is put into clear water, foam washing 60 minutes；
D, the glove mould after foam washing 90 DEG C of drying in oven are put into vulcanize 110 minutes；
E, it demoulds, makes gloves and mold separation；
F, the gloves separated are immersed in skin care agent solution and are handled 30 minutes；Skin conditioner is polyalcohol and amino
The combination of acid；The mass concentration of skin care agent solution is 2%；
G, skin conditioner treated gloves are dried, the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile is made.
Embodiment six,
A kind of safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile, is made of each substance of following mass parts:
Wherein, promotor is promotor TP.Anti-aging agent is Hinered phenols antioxidant.Dispersing agent is calgon.Titanium white
Powder is rutile type titanium white.Anti-wear agent is the combination of nano silica and mica powder.Aqueous coupling agent is silane coupling agent
KH578.Wax emulsion is polythene wax emulsion.
Thickener is the combination of sodium carboxymethylcellulose and casein.Foaming agent is neopelex.
A kind of manufacture craft of the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile, overall flow are as follows:
It A, is respectively 0.9 part of potassium hydroxide, 2 parts of zinc oxide, 1 part of sulphur, 1 part of promotor, 2 by mass parts
Part anti-aging agent, 0.1 part of dispersing agent, 1 part of titanium dioxide, 2 parts of anti-wear agent, 1 part of aqueous coupling agent, 20 parts go from
Sub- water is added into ball mill, grinds 72h, obtains vulcanization agent dispersion；
B, by the vulcanization agent dispersion and 100 parts of carboxylic acrylonitrile butadiene rubber latex, the addition of 2.5 parts of foaming agent after ball milling
To the sulfur still with frequency control function, adjustment revolving speed is 120 revs/min, stirs 9 hours, obtains vulcanized rubber；
C, vulcanized rubber is filtered with the strainer of 200 mesh, 4 parts of wax emulsion is then added, carries out mechanical foaming；
Then 3 parts of thickener is added to be viscosified；
D, gloves impregnation forms:
A, knitted gloves is covered on mold, carries out 70 DEG C of preheatings, then successively immersed coagulator, in butyronitrile slurry, mention
Out；The calcium nitrate methanol soln that coagulator is 1%；
B, upper one layer of anhydrous sodium sulfate particle is sprayed on the glove mould surface after impregnation, is then fed into baking oven and carries out
It is dried；
C, the glove mould after drying is put into clear water, foam washing 40 minutes；
D, the glove mould after foam washing 110 drying in oven are put into vulcanize 100 minutes；
E, it demoulds, makes gloves and mold separation；
F, the gloves separated are immersed in skin care agent solution and are handled 30 minutes；Skin conditioner is natural moisturizing factor
With the combination of amino acid；The mass concentration of skin care agent solution is 4%；
G, skin conditioner treated gloves are dried, the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile is made.
Embodiment seven,
A kind of safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile, is made of each substance of following mass parts:
Wherein, promotor is promotor ZDC.Anti-aging agent is Hinered phenols antioxidant.Dispersing agent is sodium pyrophosphate.Titanium white
Powder is rutile type titanium white.Anti-wear agent is the combination of mica powder and nano aluminium oxide.Aqueous coupling agent is silane coupling agent
KH450.Wax emulsion is paraffin wax emulsions.Thickener is the combination of hydroxyethyl cellulose and Sodium Polyacrylate.Foaming agent is dodecane
Base benzene sulfonic acid sodium salt.
A kind of manufacture craft of the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile, overall flow are as follows:
It A, is respectively 0.6 part of potassium hydroxide, 1 part of zinc oxide, 1 part of sulphur, 2 parts of promotor, 1 by mass parts
Part anti-aging agent, 0.1 part of dispersing agent, 3 parts of titanium dioxide, 2 parts of anti-wear agent, 1 part of aqueous coupling agent, 10 parts go from
Sub- water is added into ball mill, grinds 72h, obtains vulcanization agent dispersion；
B, by the vulcanization agent dispersion and 100 parts of carboxylic acrylonitrile butadiene rubber latex, the addition of 2.5 parts of foaming agent after ball milling
To the sulfur still with frequency control function, adjustment revolving speed is 150 revs/min, stirs 10 hours, obtains vulcanized rubber；
C, vulcanized rubber is filtered with the strainer of 100 mesh, 2 parts of wax emulsion is then added, carries out mechanical foaming；
Then 2 parts of thickener is added to be viscosified；
D, gloves impregnation forms:
A, knitted gloves is covered on mold, carries out 70 DEG C of preheatings, then successively immersed coagulator, in butyronitrile slurry, mention
Out；The calcium nitrate methanol soln that coagulator is 4%；
B, upper one layer of anhydrous sodium sulfate particle is sprayed on the glove mould surface after impregnation, is then fed into baking oven and carries out
It is dried；
C, the glove mould after drying is put into clear water, foam washing 40 minutes；
D, the glove mould after foam washing 120 DEG C of drying in oven are put into vulcanize 60 minutes；
E, it demoulds, makes gloves and mold separation；
F, the gloves separated are immersed in skin care agent solution and are handled 30 minutes；Skin conditioner is natural moisturizing factor
With the combination of amino acid；The mass concentration of skin care agent solution is 3%；
G, skin conditioner treated gloves are dried, the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile is made.
Embodiment eight,
A kind of safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile, is made of each substance of following mass parts:
Wherein, promotor is accelerant B Z.Anti-aging agent is Hinered phenols antioxidant.Dispersing agent is sodium pyrophosphate.Titanium dioxide
For rutile type titanium white.Anti-wear agent is the combination of nano aluminium oxide and carbon black.Aqueous coupling agent is silane coupling agent KH566.
Wax emulsion is palm wax emulsion.Thickener is the combination of Sodium Polyacrylate and the swollen acrylic thickener of alkali soluble.Foaming agent is 12
Sodium alkyl benzene sulfonate.
A kind of manufacture craft of the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile, overall flow are as follows:
It A, is respectively 0.3 part of potassium hydroxide, 1.5 parts of zinc oxide, 0.5 part of sulphur, 1.5 parts of rush by mass parts
Into agent, 1 part of anti-aging agent, 0.05 part of dispersing agent, 2 parts of titanium dioxide, 1 part of anti-wear agent, 0.3 part of aqueous coupling agent, 15
The deionized water of part is added into ball mill, grinds 72h, obtains vulcanization agent dispersion；
B, by after ball milling vulcanization agent dispersion and 100 parts of carboxylic acrylonitrile butadiene rubber latex, 1 part of foaming agent be added to
In sulfur still with frequency control function, adjustment revolving speed is 120 revs/min, stirs 10 hours, obtains vulcanized rubber；
C, vulcanized rubber is filtered with the strainer of 150 mesh, 3 parts of wax emulsion is then added, carries out mechanical foaming；
Then 2 parts of thickener is added to be viscosified；
D, gloves impregnation forms:
A, knitted gloves is covered on mold, carries out 50 DEG C of preheatings, then successively immersed coagulator, in butyronitrile slurry, mention
Out；The calcium nitrate methanol soln that coagulator is 3%；
B, upper one layer of anhydrous sodium sulfate particle is sprayed on the glove mould surface after impregnation, is then fed into baking oven and carries out
It is dried；
C, the glove mould after drying is put into clear water, foam washing 60 minutes；
D, the glove mould after foam washing 120 DEG C of drying in oven are put into vulcanize 60 minutes；
E, it demoulds, makes gloves and mold separation；
F, the gloves separated are immersed in skin care agent solution and are handled 30 minutes；Skin conditioner be natural moisturizing factor,
With the combination of amino acid；The mass concentration of skin care agent solution is 7%；
G, skin conditioner treated gloves are dried, the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile is made.
Embodiment nine,
A kind of safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile, is made of each substance of following mass parts:
Wherein, promotor is promotor TP.Anti-aging agent is Hinered phenols antioxidant.
Dispersing agent is how interior with the more aziridine block copolymers of polyalcohol-.Titanium dioxide is rutile type titanium white.
Anti-wear agent is carbon black.Aqueous coupling agent is silane coupling agent.Wax emulsion is dimethicone wax emulsion.Thickener is casein
With the combination of the swollen acrylic thickener of alkali soluble.Foaming agent is neopelex.
A kind of manufacture craft of the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile, overall flow are as follows:
It A, is respectively 0.4 part of potassium hydroxide, 1.6 parts of zinc oxide, 1.5 parts of sulphur, 1.5 parts of rush by mass parts
Into agent, 2 parts of anti-aging agent, 0.2 part of dispersing agent, 2 parts of titanium dioxide, 3 parts of anti-wear agent, 0.6 part of aqueous coupling agent, 30
The deionized water of part is added into ball mill, grinds 72h, obtains vulcanization agent dispersion；
B, by after ball milling vulcanization agent dispersion and 100 parts of carboxylic acrylonitrile butadiene rubber latex, 2 parts of foaming agent be added to
In sulfur still with frequency control function, adjustment revolving speed is 120 revs/min, stirs 8 hours, obtains vulcanized rubber；
C, vulcanized rubber is filtered with the strainer of 150 mesh, 1 part of wax emulsion is then added, carries out mechanical foaming；
Then 3 parts of thickener is added to be viscosified；
D, gloves impregnation forms:
A, knitted gloves is covered on mold, carries out 60 DEG C of preheatings, then successively immersed coagulator, in butyronitrile slurry, mention
Out；The calcium nitrate methanol soln that coagulator is 5%；
B, upper one layer of anhydrous sodium sulfate particle is sprayed on the glove mould surface after impregnation, is then fed into baking oven and carries out
It is dried；
C, the glove mould after drying is put into clear water, foam washing 40 minutes；
D, the glove mould after foam washing 90 DEG C of drying in oven are put into vulcanize 115 minutes；
E, it demoulds, makes gloves and mold separation；
F, the gloves separated are immersed in skin care agent solution and are handled 30 minutes；Skin conditioner is polyalcohol and amino
The combination of acid；The mass concentration of skin care agent solution is 4%；
G, skin conditioner treated gloves are dried, the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile is made.
Embodiment ten,
A kind of safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile, is made of each substance of following mass parts:
Wherein, promotor is promotor ZDC.Anti-aging agent is Hinered phenols antioxidant.Dispersing agent is methylene dinaphthalene sulfonic acid
Sodium.Titanium dioxide is rutile type titanium white.Anti-wear agent is the combination of nano aluminium oxide and silicon carbide.Aqueous coupling agent is silane
Coupling agent KH566.Wax emulsion is dimethicone wax emulsion.Thickener is that sodium carboxymethylcellulose and the swollen acrylic acid of alkali soluble increase
Thick dose of combination.Foaming agent is neopelex.
A kind of manufacture craft of the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile, overall flow are as follows:
It A, is respectively 0.7 part of potassium hydroxide, 1.8 parts of zinc oxide, 0.5 part of sulphur, 3 parts of promotion by mass parts
Agent, 1.5 parts of anti-aging agent, 0.15 part of dispersing agent, 2 parts of titanium dioxide, 1 part of anti-wear agent, 0.9 part of aqueous coupling agent, 15
The deionized water of part is added into ball mill, grinds 72h, obtains vulcanization agent dispersion；
B, by after ball milling vulcanization agent dispersion and 100 parts of carboxylic acrylonitrile butadiene rubber latex, 2 parts of foaming agent be added to
In sulfur still with frequency control function, adjustment revolving speed is 100 revs/min, stirs 10 hours, obtains vulcanized rubber；
C, vulcanized rubber is filtered with the strainer of 200 mesh, 2 parts of wax emulsion is then added, carries out mechanical foaming；
Then 4 parts of thickener is added to be viscosified；
D, gloves impregnation forms:
A, knitted gloves is covered on mold, carries out 50 DEG C of preheatings, then successively immersed coagulator, in butyronitrile slurry, mention
Out；The calcium nitrate methanol soln that coagulator is 3%；
B, upper one layer of anhydrous sodium sulfate particle is sprayed on the glove mould surface after impregnation, is then fed into baking oven and carries out
It is dried；
C, the glove mould after drying is put into clear water, foam washing 50 minutes；
D, the glove mould after foam washing 110 DEG C of drying in oven are put into vulcanize 80 minutes；
E, it demoulds, makes gloves and mold separation；
F, the gloves separated are immersed in skin care agent solution and are handled 30 minutes；Skin conditioner is natural moisturizing factor
With the combination of polyalcohol；The mass concentration of skin care agent solution is 4%；
G, skin conditioner treated gloves are dried, the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile is made.
Make further verifying below by using effect of the test to above embodiments:
The gloves liner of above embodiments is used into 13 needle nylon gloves liner impregnations, and uses commercially available common butyronitrile
Frosted gloves product is as experimental control.
The performances such as the wear-resisting of gloves, cutting, tearing, puncture are tested referring to European standard EN388；Flexibility test
Standard dresses the gloves of each embodiment using the same person respectively, then removes to grab the steel of the specification from 0.5mm to 10mm with it
Pearl, once to grab, the steel ball of minimum gauge can be grabbed successfully for standard is that the characterization of its flexibility (can grab
Specification is smaller, and flexibility is higher)；Consumption glue amount test method uses weight method to be tested, and (measured result is the attached glue of dry glue
Grammes per square metre indicates).Test result is as shown in table 1:
Table 1
Compared with the control, product of the invention is wear-resisting has all reached level Four, then the case where from attached glue grammes per square metre from the point of view of the present invention
Dry rubber content be only half of comparative example or so, illustrate product of the invention in the use for greatly reducing raw material latex
In the case where amount, wear resistance level has also achieved the comparable level of similar product.
From the point of view of the test result of flexibility, product of the invention disposably can easily pick up the tiny of 1mm, 2mm
Steel ball is put into specified container, and the product of comparative example is all difficult success when picking up the steel ball of 5mm, 6mm size, until
The steel ball of 7mm size could be picked up disposably, illustrate that its flexibility is nothing like product of the invention.
The present invention has the advantage that compared with traditional technology
(1) on the basis of maintaining or promoting original mechanical performance, the consumption glue amount of gloves can be made to reduce half, to have
It imitates energy saving and reduces production cost；
(2) touch sensitive glove lighter weight improves the flexibility of product significantly, to be suitable for fine generic operation；
(3) it by skin conditioner treatment process, can effectively completely cut off injury of the chemical component to skin in gloves, reduce people
Skin-protecting function is realized in the contact of body and chemical residual amount；
(4) it is the frictional force for improving gloves operation delicate items, anti-skidding processing is done to glove surface, it can be successfully
Realize the operation in grease environment, application range is wider；
(5) product inner surface uses cool feeling yarn knitting technology, and sense of touch ice is refreshing, wears more comfortable.
Above embodiment is not limitation of the present invention, and the present invention is also not limited to the example above, this technology neck
The variations, modifications, additions or substitutions that the technical staff in domain is made within the scope of technical solution of the present invention also belong to this
The protection scope of invention.
Claims (10)
1. a kind of safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile, it is characterised in that: the gloves by following mass parts each substance
It is made:
2. the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile according to claim 1, it is characterised in that: the promotor is to promote
Into one of agent ZDC, accelerant B Z, promotor TP.
3. the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile according to claim 1, it is characterised in that: the anti-aging agent be by
Hinder phenolic antioxidant.
4. the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile according to claim 1, it is characterised in that: the dispersing agent is Asia
Methyl sodium dinaphthalenesulfonate, calgon, sodium pyrophosphate, mostly interior one matched in the more aziridine block copolymers of polyalcohol-
Kind.
5. the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile according to claim 1, it is characterised in that: the anti-wear agent is to receive
The combination of one or both of rice silica, mica powder, nano aluminium oxide, carbon black, silicon carbide.
6. the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile according to claim 1, it is characterised in that: the aqueous coupling agent
For one of silane coupling agent KH450, silane coupling agent KH566, silane coupling agent KH578.
7. the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile according to claim 1, it is characterised in that: the wax emulsion is poly-
One of ethylene wax emulsion, paraffin wax emulsions, palm wax emulsion, dimethicone wax emulsion, hydroxy silicon oil wax emulsion.
8. the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile according to claim 1, it is characterised in that: the thickener is carboxylic
Sodium carboxymethylcellulose pyce, hydroxyethyl cellulose, casein, Sodium Polyacrylate, alkali soluble are swollen one or both of acrylic thickener
Combination.
9. the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile according to claim 1, it is characterised in that: the foaming agent is ten
Dialkyl benzene sulfonic acids sodium.
10. a kind of manufacture craft of the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile as described in claim 1, it is characterised in that:
The overall flow of the technique is as follows:
It A, is respectively 0.1-1 parts of potassium hydroxide, 0.5-3 parts of zinc oxide, 0.5-1.5 parts of sulphur, 0.5-3 parts by mass parts
Promotor, 1-2 parts of anti-aging agent, 0.05-0.2 parts of dispersing agent, 1-3 parts of titanium dioxide, 1-3 parts of anti-wear agent, 0.2-1 parts
Aqueous coupling agent, 10-30 parts of deionized water be added into ball mill, grind 72h, obtain vulcanization agent dispersion；
B, vulcanization agent dispersion and 100 parts of carboxylic acrylonitrile butadiene rubber latex, 1-3 parts of the foaming agent after ball milling are added to having
In the sulfur still of frequency control function, adjustment revolving speed is 30-180 revs/min, stirs 6-12 hours, obtains vulcanized rubber；
C, vulcanized rubber is filtered with the strainer of 100-200 mesh, 1-4 parts of wax emulsion is then added, carries out mechanical foaming；
Then 1-5 parts of thickener is added to be viscosified, butyronitrile slurry is made；
D, gloves impregnation forms:
A, knitted gloves is covered on mold, carries out 50-70 DEG C of preheating, then successively immersed coagulator, in butyronitrile slurry, mention
Out；The coagulator is the calcium nitrate methanol soln of 0.5-5%；
B, upper one layer of anhydrous sodium sulfate particle is sprayed on the glove mould surface after impregnation, is then fed into baking oven and is dried；
C, the glove mould after drying is put into clear water, foam washing 40-60 minutes；
D, the glove mould after foam washing 80-120 DEG C of drying in oven is put into vulcanize 60-125 minutes；
E, it demoulds, makes gloves and mold separation；
F, the gloves separated are immersed in skin care agent solution and are handled 30 minutes；The skin conditioner be natural moisturizing factor,
The combination of one or both of polyalcohol, amino acid；The mass concentration of the skin care agent solution is 0.5-10%；
G, skin conditioner treated gloves are dried, the safety and industrial gloves of the ultra-thin anti-skidding skin care of butyronitrile is made.
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| CN109796640A (en) * | 2019-01-25 | 2019-05-24 | 南通倍成劳护用品有限公司 | A kind of wear-resisting antiskid emgloves and preparation method thereof |
| CN110317380A (en) * | 2019-07-26 | 2019-10-11 | 蓝帆医疗股份有限公司 | A kind of butyronitrile gloves and preparation method thereof |
| CN110372893A (en) * | 2019-07-26 | 2019-10-25 | 蓝帆医疗股份有限公司 | A kind of butyronitrile gloves and preparation method thereof |
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| RU2745289C1 (en) * | 2020-07-14 | 2021-03-23 | Федеральное государственное унитарное предприятие "Ордена Ленина и ордена Трудового Красного Знамени научно-исследовательский институт синтетического каучука имени академика С.В. Лебедева" (ФГУП "НИИСК") | Method of modifying butadiene-nitrile rubber for increasing their frost-resistance |
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| CN113563648A (en) * | 2021-05-24 | 2021-10-29 | 汇鸿(南通)安全用品有限公司 | Nitrile rubber frosted glove capable of preventing slag falling and preparation method |
| CN113969000A (en) * | 2021-11-30 | 2022-01-25 | 青岛科技大学 | Sweat-absorbing material for inner layer of carboxyl butyronitrile latex examination glove and preparation method thereof |
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| CN115678136A (en) * | 2021-07-31 | 2023-02-03 | 青岛创信防护用品有限公司 | Carboxyl butyronitrile wrinkled glove and preparation method thereof |
| WO2023017738A1 (en) * | 2021-08-13 | 2023-02-16 | ビーエスティー スペシャリティー カンパニー リミテッド | Latex composition for dip molding, and method for producing dip-molded article |
| CN116874898A (en) * | 2023-07-11 | 2023-10-13 | 山东景元记劳保用品有限公司 | Butyronitrile texture superfine foaming glove and preparation method thereof |
| CN116970227A (en) * | 2023-08-01 | 2023-10-31 | 山东景元记劳保用品有限公司 | Nitrile-butadiene water-flushing superfine foaming glove and preparation process thereof |
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| CN109796640A (en) * | 2019-01-25 | 2019-05-24 | 南通倍成劳护用品有限公司 | A kind of wear-resisting antiskid emgloves and preparation method thereof |
| CN110317380A (en) * | 2019-07-26 | 2019-10-11 | 蓝帆医疗股份有限公司 | A kind of butyronitrile gloves and preparation method thereof |
| CN110372893A (en) * | 2019-07-26 | 2019-10-25 | 蓝帆医疗股份有限公司 | A kind of butyronitrile gloves and preparation method thereof |
| CN110372893B (en) * | 2019-07-26 | 2022-03-15 | 蓝帆医疗股份有限公司 | Butyronitrile gloves and preparation method thereof |
| CN110862592A (en) * | 2019-11-28 | 2020-03-06 | 北京石油化工学院 | Alumina/carboxylic butyronitrile composite material and preparation method thereof |
| CN110862592B (en) * | 2019-11-28 | 2022-05-20 | 北京石油化工学院 | Alumina/carboxylic butyronitrile composite material and preparation method thereof |
| CN111321603A (en) * | 2020-02-26 | 2020-06-23 | 浙江东亚手套有限公司 | Manufacturing method of antibacterial moisture-proof labor protection gloves |
| RU2745289C1 (en) * | 2020-07-14 | 2021-03-23 | Федеральное государственное унитарное предприятие "Ордена Ленина и ордена Трудового Красного Знамени научно-исследовательский институт синтетического каучука имени академика С.В. Лебедева" (ФГУП "НИИСК") | Method of modifying butadiene-nitrile rubber for increasing their frost-resistance |
| CN112375274A (en) * | 2020-11-11 | 2021-02-19 | 天长市恒生医疗器械有限公司 | Composite latex protective gloves |
| CN112457546A (en) * | 2020-11-27 | 2021-03-09 | 恒劢安全防护用品（南通）有限公司 | Polyimide-latex slurry and preparation method of multifunctional gloves thereof |
| CN112552569A (en) * | 2020-11-27 | 2021-03-26 | 恒劢安全防护用品（南通）有限公司 | Preparation method of modified latex and friction power generation functional gloves |
| CN113563648A (en) * | 2021-05-24 | 2021-10-29 | 汇鸿(南通)安全用品有限公司 | Nitrile rubber frosted glove capable of preventing slag falling and preparation method |
| CN115678136A (en) * | 2021-07-31 | 2023-02-03 | 青岛创信防护用品有限公司 | Carboxyl butyronitrile wrinkled glove and preparation method thereof |
| WO2023017738A1 (en) * | 2021-08-13 | 2023-02-16 | ビーエスティー スペシャリティー カンパニー リミテッド | Latex composition for dip molding, and method for producing dip-molded article |
| CN113995974A (en) * | 2021-10-29 | 2022-02-01 | 山西新华化工科技有限公司 | Protective clothing and jumpsuit with functions of gas defense and radiation protection and preparation method thereof |
| CN113969000A (en) * | 2021-11-30 | 2022-01-25 | 青岛科技大学 | Sweat-absorbing material for inner layer of carboxyl butyronitrile latex examination glove and preparation method thereof |
| CN113969000B (en) * | 2021-11-30 | 2023-10-13 | 青岛科技大学 | Inner layer sweat-absorbing material of carboxyl butyronitrile latex inspection glove and preparation method thereof |
| WO2024107042A1 (en) * | 2022-11-15 | 2024-05-23 | Synthomer Sdn Bhd | Silane compound and compositions containing same |
| CN116874898A (en) * | 2023-07-11 | 2023-10-13 | 山东景元记劳保用品有限公司 | Butyronitrile texture superfine foaming glove and preparation method thereof |
| CN116874898B (en) * | 2023-07-11 | 2024-06-21 | 山东景元记劳保用品有限公司 | Butyronitrile texture superfine foaming glove and preparation method thereof |
| CN116970227A (en) * | 2023-08-01 | 2023-10-31 | 山东景元记劳保用品有限公司 | Nitrile-butadiene water-flushing superfine foaming glove and preparation process thereof |
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