KR20150130663A - To remove the oders from shoes while using this deodorizer composition and processing - Google Patents

Abstract

A deodorant composition for removing an odor of shoes includes 2.0-10.0 wt% of alum, 50.0-80.0 wt% of biotite, 2.0-10.0 wt% of zeolite, 3.0-10.0 wt% of tourmaline, 0.5-2.0 wt% of monazite, 3.0-10.0 wt% of kaolin, 1.0-5.0 wt% of bentonite, 0.1-3.0 wt% of methanol, 0.5-3.0 wt% of thyme, and 0.1-2.5 wt% of an essential oil. The deodorant composition is characterized by being manufactured by heating a powdered deodorant composition through a one hour heating process at 80°C and drying the composition at room temperature for three hours, wherein the powdered deodorant composition is completed by using a mixer in a dry process for about 60 minutes.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a deodorant composition for removing shoe odors,

 The present invention relates to a deodorant composition for removing shoe odor and a process for producing the same, characterized in that it comprises at least one functional natural mineral selected from biotite, monazite, tourmaline, kaolin, zeolite and bentonite having a particle size of 4.5 to 30 μm In particular, it has an antimicrobial effect by suppressing the proliferation of bacteria, as well as a function of removing shoe odor, and can be easily used immediately when sweat is felt in an unspecified place, and the effect is also exhibited within 1 hour. It carries life and radiates far infrared rays, promotes metabolism, absorbs and decomposes pollutants, releases anions and acts as an air, sterilizing and cell activating agent. It is also characterized by the addition of menthol, You can feel the essence oil, Fragrance is emitted and provides a manufacturing method using this composition and a deodorant powder formulation characterized by a long period of time continues.

The deodorizing composition completed by the invention is characterized by having a drying process at room temperature for 3 hours after the dry manufacturing process and the heating process for about 60 minutes.

The present invention relates to a deodorant composition for removing shoe odor and a process for producing the same. The medium of shoes is used only by people who are walking upright. It protects the feet and absorbs the shock that occurs when walking upright, and relieves fatigue. Due to long wearing outdoors, the shoes are sealed, the inside air is decayed, bad smell is generated by various viruses, bacteria and germs, the blood circulation disorder occurs easily, and fatigue easily occurs. When taking off shoes, It has been pointed out that the atmosphere is created and interpersonal relations are not smooth.

 The human body continues to diffuse the harvest although there is a difference in strength depending on the relative degree. In the human body, harvesting is caused by the disintegration of secretions from sweat glands and sebaceous glands. The sweat glands are the secretions of sweat, and there are two types of glands: eccrine glands and apocrine glands. Echinacea is distributed throughout the body, especially in the front part of the head, armpit, palms and soles. His secretion is weakly acidic and inhibits the growth of bacteria. The sweat produced in the echinacea gland is 0.3-1.5% of the solid component, and the main ingredient in it is sodium chloride. Other components include urea, lactic acid, sulfide, ammonia, uric acid, creatine, amino acid and the like. In addition, the foot, which is a part of the body, corresponds to the area where the center of gravity is leaning, and it corresponds to the area where it continuously touches, so sweat is easily generated and various kinds of germs are parasitized, resulting in a lot of foot odor and causing various foot diseases.

In the process of decomposing sweat and stratum corneum, a malodorous chemical called isovaleric acid is generated. When athlete's foot, fungus or skin disease grows bacteria, or when feet are not washed frequently or socks are not changed frequently Causes can occur, especially if you are sweating congenitally or have lots of keratinous feet on your feet. In the case of perspiration excreted outside the body, it is colorless and odorless in the early stage. However, lactic acid, urea and ammonia, which are one of the sweat components of perspiration, . Therefore, in the case of a foot that has more sweat than the other parts of the body as the activity is larger, air is not passed through when the shoe is worn, so that the swollen part of the toe and toe are particularly swollen. In severe cases, the swollen part is accompanied by itching Athlete's bacillus is easily breeded, which not only lowers the odor and fit of the footwear, but also poses a problem causing growth of eczema and anthrocnose pathogens.

It is the best condition for breeding germs in the shoes that get wet due to sweat and hot in hot weather. Compared to 9 cfu / cm ² in the toilet, it is known that many bacteria live in the shoe with 392 cfu / cm ² of bacteria. As the temperature inside the shoe is increased, the temperature is increased to the temperature at which the growth of the bacterium is promoted. As the growth of the bacterium is promoted, the concentration of the odor gas gradually increases and the smell and bacteria are seated on the foot skin. .

  Generally, the smell of perspiration from the feet is thought to be the cause of foot odor, but in summer, the cause of foot odor is that most of the smell that permeates the foot is intact. Most often when you smell your feet you wash your feet clean, use your feet to keep them from sweating, or use sprays to keep your feet dry. However, even if you keep your feet clean, If you wear it again, you can not be free from foot odor. In recent years, various attempts have been made to improve these problems. In particular, considering the effects on the human body, there is a tendency to develop products which are more safe to human body, that is, products which are not toxic, And powder products are being launched. Spray type products require time to spray on shoes and drying time. Spraying into socks or shoes has a remarkable effect of reducing foot odor. However, frequent application of 5 ~ 6 times a day in daily life is the most effective It is very weak and can not be said to be practical because of the frequent use of it. [Patent Application Number; 10-2002-0031209 Liquid Antibacterial Deodorant Composition] Powdered product can be applied within 1 hour when it is applied to shoes insole, and when powder is used a lot, there is a disadvantage that it can stick to sock, [Patent application number; AU-B-11363/92 Acceptance No. 651433 A DEODORANT COMPOSITION]

 In order to remove odor from footwear, it was applied to insole or functional sock. Looking at the patent application data on the manufacturing method of the insole having deodorizing, antibacterial, far infrared ray and negative ion generating function,

 Application number; 20-2001-0016215 Foot insole for foot odor deodorization

 Application number; 20-2002-0012620 Shoe insole with negative ion generating function

 Application number; 20-2003-0026904 antibacterial deodorizing shoe insole

 Application number; 10-2004-0028367 Functional shoe insole with excellent antimicrobial, deodorant, deodorization and far-infrared radiation ability

 Application number; 10-2004-0056235 Composition with deodorizing and health promoting effect and shoe insole using the composition

 Application number; 10-2005-0068594 Manufacturing method of shoe insole with deodorizing and antibacterial function

 Application number; 10-2005-0078702 sole

 Application number; Insole for antimicrobial and antimicrobial dressing and its manufacturing method

 Application number; 10-2011-0066608 Functional shoe insole provided to absorb sweat and odor from foot,

Looking at the patent application data applied to socks,

 Application number; 20-2001-0010226 Deodorizing socks

Application number; 20-2002-0026015 There are socks for removing foot odor which combines antibacterial and foot pressure function.

To minimize the smell of shoes, use functional insole alternately, or use thick cotton socks to induce sweating out of the toes, or try to disperse the amount of sweat by wearing toe socks to minimize the amount of sweat We are looking for a solution, and a lot of research is underway.

Accordingly, the inventor of the present invention confirmed that using an absorption function, which is an inherent characteristic of biotite, and using it as a deodorant product would have an excellent effect in removing shoe odor, thereby completing the present invention .

10-2003-0099104; Multi-use antibacterial deodorant to prevent odor and bacteria growth 10-2001-0030927; Foot odor removal and athlete's foot healing composition 10-2001-0012255; Socks for removing offensive odors using rare earth compounds and manufacturing method 10-2001-0007384; Moisture removal and odor removal shoes 20-2011-0008703; Shoes that can remove odors 20-2004-0022259; Foot odor elimination footwear socks bandage

(Literature 01) Korean Journal of Dermatology v.44 no.5, 2006 pp. 554-560 Park So Hyun and others 3   Identification and effective disinfection of bacteria causing unpleasant shoe odor (Literature 02) Shoe refrigerator that removes 100% of shoe odor

After wearing shoes, sweat begins to come out from the foot and is combined with isovaleric acid which is a component of sweat which is discharged to the skin surface and rare earth element which is a monazite component. Oxygen (O ₂ ) is produced through chemical reaction to release sweat And the odor is not generated in the inside of the shoe, so that the smell of shoe is reduced for a long time or continuously.

 Accordingly, it is an object of the present invention to overcome the above-described problems of the prior art, and it is an object of the present invention to provide an osteotomy apparatus, an osteotomy apparatus, To keep the inside of the shoe clean, to provide more mental comfort and to maintain a healthy life when wearing shoes.

In addition, it has excellent deodorization effect, radiates far infrared rays, strengthens metabolism, activates cells by releasing anions, stabilizes the nervous system by cleansing blood, and acts as an antimicrobial effect. And it is possible to feel cooler and refreshing feeling of tired feet and impregnate with Essential oil so that the fragrance is emitted for a long time, so that it is possible to enjoy comfortable and leisurely daily life.

Far infrared rays are infrared rays having a long wavelength in the range of 5.6 to 1,000 micrometers in the visible light of light. Among them, far infrared rays in the range of 6 to 14 micrometers are known to be beneficial to the human body. As the effect of far infrared rays on the human body, It is known to help maintain body temperature, strengthen metabolism, promote fatigue recovery, promote digestion, help relieve stress, improve energy rhythm by raising energy, and promote growth It is known that there is an effect of alleviating the pain and increasing the flexibility of the body in addition to the effect of the antibacterial, deodorizing and insecticidal effects, thereby eliminating the odor, suppressing the growth of fungi, and preventing the growth of fungi.

Anions are all things that have a negative charge value from extremely minute substances such as atoms and electrons in the atmosphere to suspended matters having a particle diameter. The anions mentioned above are the cations which are contaminated in the air And the anion is absorbed into the human body to activate the cells, purify the blood, stabilize the nervous system, and the like, thereby improving appetite, restoring fatigue, delaying the padding, changing the mood, Pain relief, and the like.

Configuration and action

 In order to achieve the above-mentioned object, the present invention provides a method for producing a natural mineral which comprises 50.0-80.0% by weight of biotite, 3.0-10.0% by weight of kaolin, 0.1-2.0% by weight of monazite, 3.0-10.0% by weight of Tourmaline, 3.0-10.0 2.0 to 10.0% by weight of zeolite, 1.0 to 5.0% by weight of bentonite, 1.0 to 5.0% by weight of thyme, 1.0 to 4.0% by weight of ZnO, 0.1 to 3.0% by weight of menthol and 0.5 to 2.5% by weight of essential oil.

 The shoe deodorant deodorant composition according to the present invention may further comprise at least one of Biotite 50.0 to 80.0 wt% Kaolin 3.0 to 10.0 wt% Monazite 0.5 to 2.0 wt% Tourmaline 3.0 to 10.0 wt% Alum 3.0 to 10.0 wt% Zeolite 2.0 wt% 10.0 wt% of bentonite, 1.0 to 5.0 wt% of bentonite, 0.5 to 3.0 wt% of thyme, 0.1 to 3.0 wt% of menthol, and 0.1 to 2.5 wt% of essential oil. Essential oil may be selected from the group consisting of Eucalyptus, German chamomile, cedarwood, cinnamon, bergamot, lemon, cypress, lemon grass, juniper berries, tea tree, peppermint, rosemary, sandalwood, ginger, lavender, And the amount of the composition to be added other than Biotite is 3.0 to 30.0% by weight.

In addition, the method of manufacturing a shoe deodorizing and deodorizing composition according to the present invention comprises the steps of mixing Essential oil with Biotite powder at room temperature and stirring in a first step, and adding Alum, Tourmaline, Monazite, Zeolite and Bentonite when the oil is completely mixed with Biotite powder Thyme powder and Menthol powder were separately taken and dried for 20 minutes. The mixture was stirred and mixed thoroughly using a Mixer machine. The kaolin was added to the mixture, and a homogeneous mixture And the uniform mixture was subjected to 5 steps of removing water for 1 hour by using a dryer at 80 ° C and 6 steps of naturally drying the powder deodorant composition at room temperature for 3 hours and filling And the final step is to finish.

 The components used in the deodorant composition of the present invention will be described in detail as follows.

Alum or alum can also be referred to as the formula _{MI MIII (SO 4) 2 12H} 2 O , or _{MI 2 (SO 4) MIII 2} (SO4) alum as a general term for double salt which may be represented by ₃₂ 4H ₂ O. MI represents a monovalent metal ion or ammonium ion, and MIII represents a trivalent metal ion. Among them, KAl (SO ₄ ) ₂ 12H ₂ O (potassium aluminum alum) with MI of K and Al of MIII has been known for a long time and was firstly called alum. It has anti-inflammatory, astringent, It is effective against malaria, hemorrhoids, acne, improvement (omnis), and fat breakdown. (CAS No. 7784-25-0)

The chemical composition of biotite is a mineral represented by K (Mg, Fe) ₃ AlSi ₃ O ₁₀ (OH) ₂ , which is in the form of a plate or scales. It is often hexagonal or rhombohedral, It has a rust black color and has a pearl luster, sometimes metallic luster, a hardness of 2.5 to 3.0 and a specific gravity of 2.7 to 3.1. It is produced from igneous rock metamorphic rocks, and a large biotite crystal can be obtained from pegmatite. In addition to the air purification function, ammonia gas which is harmful to the human body is adsorbed and decomposed by ladon gas and formaldehyde gas, which is generated in foods, weakens aerobic microorganisms and anaerobic microorganisms which cause various diseases, Which is effective for controlling the amount of anions and eliminating odors by discharging a large amount of anions, is used as the main substrate of the deodorant composition of the present invention and is preferably used in an amount of 50.0 to 80.0% by weight. (CAS No. 1302-27-8)

Tourmaline is a borosilicate with hexagonal columnar crystals and is a natural mineral belonging to the hexagonal system. Tourmaline is also called tourmaline because it has the characteristics of generating electricity itself. It has the only permanent electrical properties among the minerals present on the earth. The anions and weak currents generated by this ore (human body electric power / 0.06 mA) and far-infrared rays are epoch-making materials that are actively underway in various research institutes for health and environment. Tourmaline efficacy is very diverse, such as improving cleaning power, preventing re-adhesion of pollutants, alkalizing water, deodorizing, removing chlorine, moisturizing, preventing skin trouble, and antibacterial effect. (CAS No. 1317-93-7)

Monazite (RePO4, RE is a rare earth element) is a phosphate mineral in the form of a rare earth element and phosphoric acid combined. Major rare earth elements include cerium (Ce), lanthanum (La) and neodymium (Nd). Praseodymium (Pr), gadolinium (Gd), and samarium (Sm). Uranium (U) and thorium (Th) can also be obtained as by-products in the process of extracting monazite or treating monazite. Among the methods for extracting rare earth elements from monazite, economical methods include acid leaching which drips monazite into sulfuric acid or hydrochloric acid to extract rare earth, basic leaching to extract rare earth by immersion in sodium hydroxide, Or sintering at a high temperature together with sodium phosphate. [Patent application number; 10-2009-0114710 Rare Earth Extraction Method in Monazite]

Kaolin is a fine, normally white clay formed by the weathering of aluminum containing minerals (feldspar) and is mainly composed of kaolinite. Kaolinite will in general also containing one or more compounds of formula _{Al 4 Si 4 O 10 (OH} ) 8; Al ₂ O ₃ .2SiO ₂ .2H ₂ O; And / or Al ₂ Si ₂ O ₅ (OH) ₄ . Kaolin is one of many industrial minerals currently mined. The kaolin mine is found in Georgia (USA), Egypt, Brazil, England, Queensland (Australia), Korea, China, and Ukraine. Anti-caking agents are used to prevent agglomeration of solid particles to prevent agglomeration or binding cake, and examples thereof include magnesium myristate, magnesium silicate, magnesium aluminum silicate, microcrystalline cellulose, silica , Zinc laurate, zinc stearate, natural aluminum silicate, glyceride behenate, and zinc undecylenate. (CAS No. 1332-58-7)

Zeolite is a crystalline aluminosilicate, which is composed of a SiO ₂ tetrahedron and an AlO ₂ tetrahedron bonded in a three-dimensional network, and contains cations to neutralize the negative charge of AlO _2. These cations are easily exchanged with other cations in aqueous solution , It is used as a cation exchanger and has a porous structure such as a molecular sieve and is used not only as an adsorbent but also as a catalyst for many reactions. These zeolites are known as natural and artificial zeolites, and are classified into various types depending on the crystal structure. Since natural zeolite is expensive and contains a large amount of impurities, there is a lot of interest in artificial zeolite, which is cheaper than natural zeolite but has little difference in performance. Many manufacturing methods have been studied. (CAS No. 1318-02-1)

Bentonite is known as montmorillonite because its main constituent is montmorillonite. It is an aggregate of fine colloidal materials as a general property. It is absorbed and swollen when put into water, exhibits high viscosity, and has a higher cation exchange capacity than other clay minerals. It is very diverse. Bentonite is a minerals formed by eruption of volcanic ash and lava due to volcanic eruption at the beginning of the earth, and then rising up to the ground due to crustal fluctuations. In FDA (Food and Drug Administration) Bentonite is classified as GRAS (Generally Regarded As Safe), and it is known that Korea is heavily buried in the East Sea region. Bentonite has been reported to contain 66 essential minerals that are essential to the human body and has been reported to improve the health of the human body in various fields. It helps digest food, clears blood, It is effective in promoting metabolism and promoting vitality. It is especially excellent in skin care and skin treatment. It provides whitening effect, skin wastes removal, skin regeneration, spots, freckles, acne, dullness, keratin, fine wrinkles, atopy, It exhibits excellent effects on cosmetics. (CAS No. 1302-78-9)

Menthol is a colorless needle-like crystal with a unique sense of exhilaration and has a unique melting point. It is a white crystal which is cooled and purified by distilling the leaves of peppermint. It has a unique aroma, It is used as an anti-inflammatory or anti-inflammatory drug for asthma. According to traditional oriental medicine, it has a refreshing effect and a spasolysio effect. It protects a cold, it has a heat effect and a sea table. It is an itch when it is bitten by insects, pain such as arthritis or neuralgia, Gastrointestinal disorders, and the like. And vascular relaxation effect on the central nervous system. In addition to this, it is said that it is good to take a lot of nerves, and to take a noodle when the stress is severe. This effect of mint is known to be due to L-menthol, the main ingredient of mint. L-menthol is expressed as C ₁₅ H ₂₀ O and is a colorless needle-shaped crystal with a unique exhilarating flavor. It is almost insoluble in water and soluble in ethanol, ether and chloroform. Such menthol can be obtained by steam distillation of leaves or stems of naturally occurring peppermates or by chemical synthesis methods in which water is added to ketone groups or double bonds such as menthone · pregon · piperitone · thymol and isopregone . (CAS No. 89-78-1, 1490-04-6)

Thyme is a semi-evergreen shrub with honey grass. It is called thyme because its fragrance spreads far away. It contains 1 ~ 2% of essential oil and 10 ~ 30% of essential oil. It is in the leaves. The essential oil component is thymol, and there are carbachol, simol, pinene, terpinene, borneol, thinanol, and borneol acetal. Most of the phenolic substances are thymol. In the outpost, in addition to essential oils, there are triterpene acid, titus acid, trimus saponin, oleenoic acid, caffeic acid, chlorogenic acid, flavonoid, luteolin and its glycoside. Thymol is less toxic than other phenolic substances and has a weak stimulatory effect on the mucous membrane and acts to inhibit the strong antimicrobial action and bacteria against pathogenic bacteria and fungi. In the present invention, the time-lapse leaf was freeze-dried, and finely processed into powder form, and applied to the present invention.

 Aromatherapy with essential oils is based on the discovery that flowers, leaves, roots and stems of plants in ancient Egypt, China, and India have beneficial effects on the management of human mind and body. It can be said that it is the stem of the system. Essential oils play an important role in the life cycle and germination process of the plants themselves, and they have been shown to be hormones and vitamins of plants because they have the power against diseases. They have been used for religious ceremonies, wound healing and beauty. Eucalyptus, German chamomile, cedarwood, cinnamon, bergamot, lemon, cypress, lemon grass, juniper berry, tea tree, peppermint, rosemary, sandalwood, ginger , Lavender, thyme, etc. have been used for skin diseases due to excellent antimicrobial action and anti-inflammatory action in the western countries for a long time, and orange or pine oil can be added in the present invention.

 Eucalyptus is an evergreen evergreen tree with the highest amount of plum. It is an oil extracted from the most abundant tree leaves in Australia and has analgesic, antiviral and antimicrobial effects.

 German chamomile is an oil extracted from the petals of the Asteraceae, the origin of the Mediterranean coast, and has been used for over 2,000 years as a household remedy in Europe. It contains an azulene ingredient that has anti-bacterial and anti-inflammatory properties. It is effective for acne, eczema, diaper eczema, burns and skin inflammation.

 Cedarwood is an oil extracted from coniferous trees and used as an antiseptic or cosmetic in the ancient Egyptian period. Its fragrance has the function of fighting ants, moths and other harmful insects, and has antibacterial, insecticide and disinfecting functions. have.

 Cinnamon is an excellent antimicrobial oil extracted from tropical camphor tree leaves and branches and has antibacterial activity against most bacteria.

 Bergamot is an oil extracted from the skin of citrus fruits and has a disinfection effect and is effective for eczema, dry bruises, acne, skin and scalp bruises, chicken pox, shingles and insects.

 Lemon is an oil extracted from the shell of mandarin orange. It has antiseptic, antimicrobial and antioxidant properties and it is known that it is inactivated even at 0.2% dilution against Mycobacterium tuberculosis.

 Cypress is an oil extracted from the leaves of evergreen trees and has insecticidal and antibacterial effects.

 Lemongrass is an oil extracted from the leaves of the pomegranate and has antimicrobial, antioxidant and antifungal properties.

 Juniper Berry is an oil extracted from the evergreen conifers of the myrtle trees and has antibacterial and antiseptic properties, and is used in lotions after shaving.

 Tea tree is an oil extracted from small leaves and twigs of plums and is known to have an excellent action against all infectious diseases such as antibacterial, antibacterial and antiviral disinfection.

 Peppermint is an oil extracted from the leaves and flower-tipped parts of the herb leaves of chrysanthemum, and is effective against bronchial diseases and has anti-inflammatory, antibacterial, anti-inflammatory and antiviral effects.

 Rosemary is an oil extracted from the flowering part of a shrub with a flower grass and has antibacterial, antifungal, disinfecting and insecticidal action.

 Sandalwood is known as herbaceous and rosemary herb, and is an oil extracted after drying the core of wood. It has antimicrobial and disinfecting action.

 Lavender is an oil extracted from flower parts of shrubs and is the most popular and widely known for its antibacterial, sedative and anti-inflammatory effects.

 Time is an evergreen tree of Chakugaku. It is an oil extracted from leaves and flowers. It is effective in antimicrobial, antioxidant, anti-decay, antiseptic and anti-parasitic effects.

The deodorant composition of the present invention can be used as a deodorant composition containing at least one selected from the group consisting of eucalyptus, German chamomile, cedarwood, cinnamon, bergamot, lemon, cypress, lemongrass, juniper berry, tea tree, peppermint, rosemary, sandalwood, ginger, Lt; RTI ID = 0.0 > essential oils. ≪ / RTI >

FIG. 1 is a process diagram showing a process for producing a shoe deodorant composition according to the present invention, and a rare earth element applied to the deodorant composition of the present invention will be briefly described.

The rare earth element is a compound of La (57), Ce (58), Pt (59), Nd (59) and the like, collectively referred to as 17 elements including scandium and yttrium in the third group of the periodic table and lanthanide series (63), Gd (64), Td (65), Dy (66), Ho (67), Er (68), Tm (69), Yb (70), Lu (71), and Se (21), Y (39). Of the lanthanum-based elements, 14 elements below cerium, excluding lanthanum, are generically referred to as lanthanides. These rare earth elements are present only in a very small amount in the natural world, and the demand for the high-tech industries such as electric, electronic, catalyst, optical, special metals, superconductors and phosphors is rapidly increasing.

 On the other hand, rare-earth producing countries such as China regulate exports from a strategic point of view, and recently, the prices of rare earth elements have soared along with the rise of raw material prices, and the world is focusing on securing rare earth elements worldwide. Recently, many attempts have been made to extract rare earth elements from marine (sea sand), especially Monazite, in order to secure rare earth elements. [Korean patent application number; 10-2011-0144779, A method for extracting a rare earth element from monazite. 10-2009-0114710, Rare Earth Extraction Method in Monazite]

Therefore, as in the present invention, since organic matter contained in the sweat component is not decomposed due to release of oxygen by reacting with isovaleric acid generated and released from the rare earth element and perspiration, the odor disappears and odor is prevented, It is possible to prevent the proliferation and wear more comfortable and comfortable shoes.

By using the deodorant composition of the present invention as described above, it has an excellent deodorizing effect for removing the smell of shoes, and it emits far infrared rays as a tourmaline raw material and feels warmth and relieves fatigue. It is possible to provide a deodorant composition for removing the shoe odor which is always excellent in antimicrobial effect to inhibit and maintain the clean and healthy feet at all times. Also, it is highly recommended to use Korean soldiers, police officers, firefighters, guards, long-term safety workers, athletes, long-distance drivers, It is expected that the composition of natural minerals will be harmless to the human body and will be a good product for many people suffering from the smell of shoes. In addition, the deodorant composition for removing the shoe odor of the present invention, I am sure that it will be a great help to form a new market of shoe deodorizer by entering the world market.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a process diagram for producing a deodorant composition of the present invention. FIG.
Fig. 2 is a data of deodorization test results of the deodorant composition of the present invention.
FIG. 3A is data of far-infrared emissivity and radiant energy measurement results of the deodorant composition of the present invention.
FIG. 3B is data of far-infrared emissivity measurement results of the deodorant composition of the present invention.
FIG. 3C is data of far-infrared radiation energy measurement results of the deodorant composition of the present invention.
4 is a data of an anion test result of the deodorant composition of the present invention.
Fig. 5 is data of radiation test results of the deodorant composition of the present invention.
FIG. 6A is data of an antibacterial test result on the deodorant composition of the present invention. FIG.
6B is a photograph of an E. coli antibacterial test on the deodorant composition of the present invention.
6C is a photograph of a staphylococcus antibacterial test on the deodorant composition of the present invention.
7A is an electron microscope photograph of the deodorant composition of the present invention.
7B is an electron microscope photograph of the deodorant composition of the present invention.
7C is an electron microscope photograph of the deodorant composition of the present invention.
7D is a photomicrograph of a biotite particle electron microscope.
7E is a photograph of kaolin particle electron microscope measurement.
FIG. 8 shows data on the particle size analysis of the deodorant composition of the present invention.

[Example]

Detailed process description

 In the process of the embodiment of the present invention, the main raw material, biotite natural mineral, is mixed into the mixer and uniformly mixed for 20 minutes while the essential oil is added to the mixture. The remaining raw materials are further added to the mixture, All the raw materials are mixed and mixed homogeneously while maintaining the time.

 The raw materials are fed to the mixer, and the raw materials contained in the mixing tank are mixed with the raw materials contained in the mixing tank for a predetermined period of time, and the raw materials contained in the mixing tank are mixed by driving. The crushing blades are mixed uniformly do. The mixing time is preferably about 30 minutes to about 1 hour. When the mixing is completed, the outlet is opened to discharge the composition to the outside, and the mixture is heated. The heating process according to the embodiment of the present invention is performed by a heating device for heating the composition so as to separate impurities and moisture present in the raw materials. At this time, the heating apparatus temperature is usually maintained at 80 캜. The heating process time is approx. 1 hour, and the powder deodorant composition, which has been heated, can be filled (packaged) in a container after natural drying at room temperature for 3 hours.

                                   [Picture 1]

 The process for producing the shoe deodorant deodorant composition of the present invention will now be described.

 1. Step 1 to mix and mix essential oil with biotite at room temperature.

 2. Alumina, monazite, tourmaline, zeolite, and bentonite, respectively, put in the two-stage mixing at room temperature.

 3. Add 3 times powder and menthol powder and mix at room temperature.

 4. Step 4 to mix kaolin at room temperature.

 5. Five steps of drying the composition completed by the invention at 80 DEG C for 1 hour.

 6. 6 steps of naturally drying the composition dried by the invention at ambient temperature for 3 hours.

 7. It can be expressed as 7 steps of packing (packing) work.

The product thus manufactured and packaged is called 'Foot Magic Powder'.

While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the invention is not limited to the disclosed exemplary embodiments, but, on the contrary, And such variations are within the scope of protection of the present invention.

[Example 1]

A mixture of 70.0% by weight of natural natural mineral Biotite, 1.0% by weight of essential oil, 5.0% by weight alum, 1.0% by weight of monazite, 5.0% by weight of tourmaline, 6.0% by weight of zeolite, 5.0% by weight of bentonite, And 5.0 wt% of kaolin were mixed, heated, and dried to prepare a deodorant composition.

[Example 2]

A mixture of 80.0% by weight of biotite, 1.0% by weight of essential oil, 3.0% by weight of alum, 1.0% by weight of monazite, 4.0% by weight of tourmaline, 4.0% by weight of zeolite, 2.0% by weight of bentonite, 1.5% 3.0 wt% of kaolin was mixed, heated, and dried to prepare a deodorant composition.

[Example 3]

A mixture of 80.0% by weight of biotite, 1.0% by weight of essential oil, 3.0% by weight of alum, 1.0% by weight of monazite, 4.0% by weight of tourmaline, 4.0% by weight of zeolite, 2.0% by weight of bentonite, 1.5% 3.0 wt% of kaolin was mixed, heated, and dried to prepare a deodorant composition.

[Example 4]

A mixture of 80.3% by weight of biotite, 1.0% by weight of essential oil, 3.0% by weight of alum, 0.7% by weight of monazite, 4.0% by weight of tourmaline, 4.0% by weight of zeolite, 2.0% by weight of bentonite, 3.0 wt% of kaolin was mixed, heated, and dried to prepare a deodorant composition.

[Example 5]

A mixture of 78.0% by weight of natural natural mineral Biotite, 1.0% by weight of essential oil, 3.0% by weight of alum, 1.0% by weight of monazite, 4.0% by weight of tourmaline, 4.0% by weight of zeolite, 2.0% by weight of bentonite, 3.5 wt% of kaolin was mixed, heated and dried to prepare a deodorant composition.

[Example 6]

A mixture of 70.0% by weight of biotite, 1.0% by weight of essential oil, 5.0% by weight of alum, 1.0% by weight of monazite, 5.0% by weight of tourmaline, 5.0% by weight of zeolite, 3.0% by weight of bentonite, 1.5% And 8.0 wt% of kaolin were mixed, heated and dried to prepare a deodorant composition.

Deodorization test, far infrared ray emissivity test, anion emission test, radiation emission test, antibacterial test, sensory test, electron microscopic measurement, particle size analysis and the like were performed on the shoe deodorant and deodorant composition thus produced.

Test Example 1     Deodorization measurement test

In order to comparatively measure the deodorizing effect using the deodorant compositions of Examples 1 and 2, ammonia (NH ₃ ) gas, which is a malodorous substance, was conducted under the following conditions, and the deodorization rate according to the elapsed time was measured And the results of the deodorizing test are shown in Fig. In the compositions of Examples 1 and 2, a deodorant composition was prepared by preparing 70.0% by weight and 80.0% by weight of deodorant composition, respectively. However, in Examples 1 and 2, deodorization test was carried out after 30 minutes and 99.9% It was found that the content was 70.0 wt%, and the composition contained 60.0 wt% to 80.0 wt% with respect to the total weight.

 The test results are shown in [Table 1] and the related test reports are shown in Fig. 2, respectively. After 30 minutes, the deodorization rate was 99.9%.

         [Exam conditions]

       1. Test environment: Temperature (23 ± 5) ℃, Humidity (50 ± 10)% R.H.

       2. Test vessel and amount of sample: 10 L Tedra ra bag, 50 g sample

3. Test instrument: gas detector (GV-100S, Gas Tech, Japan)

Test Example 2     Far infrared emissivity measurement test

 The far infrared ray emissivity test was comparatively measured using the samples of Examples 1 and 2. The test facility was KFIA-FI-1005, and the test conditions were the measurement results for the black body using 37 ° C FT-IR Spectrometer. Test results of Example 2 are shown in Table 2, and test results are shown in FIG. 3-a.

 As a result of measuring the far infrared ray emissivity of the sample of Example 1, the far infrared ray emissivity was 91.9% and the sample of Example 2 was 92.3%, and the effect of the present invention can be easily achieved within the range of biotite ± 80.0 wt% there was.

Test Example 3.     Anion emission measurement test

 The anion emission test was comparatively measured using the sample of Example 3 and the sample of Example 4. The test was conducted under the conditions of room temperature 24 ° C, humidity 42%, number of anions in the air 106 / cc, and the measured values were measured with a KFIA-FI- And the number of IONs per unit volume was measured. The result of measurement of the anion emission amount of the sample of Example 3 was 1,402 ION / cc, and the result of measurement of the anion emission amount of the Example 4 was 1,000ION / cc. The monazite weight range was 1.0 wt% .

 The test results of Example 3 are shown in Table 3, and the anion test report is shown in FIG.

Test Example 4.     Radiation dose measurement test

Example 3 A radiation dose measurement test was conducted using a sample. The measuring instrument was tested by KFIA-FI-1108, the test sample was 10g, the test conditions were room temperature 23 ℃, and humidity 38%. The measured values were measured by radiation emitted from the measurement object Was measured and expressed as the dose of radiation per hour

  1 Sievert is 1,000 milli sibs (Sv) and 1 milli sievert is 1,000 micro sievers. tablet

When using artificial radiation other than natural radiation in the area, an annual over 1 milli-sievert (mSv)

And it is 0.89Sv as measured by 10g of sample.

It was. This sample is 0.18 siebt based on 2g per day and wears shoes for 8 hours

(365 days), the radiation dose is calculated as follows.

 0.18 x 8 x 365 = 525.6 micro sievert, so the government regulated 1,000 micro

Because it is below the Sievert number, it is safe for radiation emission.

. The radiation dose test results are shown in Table 4. The radiation dose test report is shown in FIG.

Test Example 5     Antimicrobial measurement test

Antimicrobial tests were carried out using the samples of Examples 4 and 5 in order to compare Thyme powders inhibiting microbial growth to 1.5 wt% and 3.0 wt%, respectively. The test organism was tested in KFIA-FI-1002, and Escherichia coli ATCC 25922 and Staphylococcus aureus ATCC 6538 were used. The test results are shown in Table 5, and the results of the antimicrobial test are shown in Fig. 6-a.

 [Table 5] Antimicrobial measurement test results After 24 hours at an initial concentration of 2,600,000 CFU / ml for Escherichia coli, the blank was found to be 3,300,000 CFU / liter. After 24 hours, the concentration was less than 1,000 CFU / ml. In the case of staphylococci, the initial concentration was 2,200,000 CFU / ml, and the blank was 3,600,000 CFU / ml after 24 hours. After 24 hours, the concentration was less than 1,000 CFU / ml. As a result of the test, 99.9% of Escherichia coli and Staphylococcus aureus were inhibited.

Test Example 6.     Sensory evaluation test

 EXAMPLES Example 1 A sensory evaluation test was conducted on a person suffering from a lot of sweat on foot using a shoe deodorizer as a sample. The subjects were male and female adults aged 20 to 55 years and male and female 53. The period of use was divided into the period before use and the day after use 1 day, 3 days, 7 days, 2 weeks, 4 weeks, 1 month, and the evaluation contents were very strong shoe odor, shoe odor , The same shoe odor, no shoe odor, and no shoe odor.

 In addition, sensory evaluation was carried out on 41 persons aged between 20 and 50 who were suffering from itching (athlete 's foot). The duration of use was divided into the period of use and the period of use before and after 1 day, 3 days, 7 days, 2 weeks, 4 weeks, and 1 month after use. The evaluation contents were aggravated itching, a little itching, itching The same, no itching, and no itching. The results of the sensory evaluation test are shown in Tables 6 and 7.

The results of the questionnaire were as follows: 1 person after 3 days, 23 people after 2 weeks, 12 people after 2 weeks, 5 people after 5 months. After using shoe deodorant, 44 , 91% were satisfied with the shoe deodorizer, and some of the respondents answered that they had a feeling of coolness and coolness because their feet had a warm effect and a smell.

As a result of the questionnaire evaluation, it was found that the test taker who had no itching, 1 person after 3 days use, 13 people after using 1 week, 5 people after 2 weeks, 6 people after 1 month, , 66% of them were satisfied with itching, and the sensory test showed that the Thyme powder component was excellent in the itching effect. It was also found that a person with a lot of sweat on his feet was accompanied by itching.

Test Example 7.     Electron microscope measurement test

EXAMPLES Example 1 A sample was measured with a scanning electron microscope, and the measurement results are shown in FIGS. 7 (a), 7 (b) and 7 (c). The measurement equipment was VERIOS 460L and the conditions were Resolution @ optimum WD- 0.6nm (at 30kV, STEM MODE) 0.6nm (at 15kV) 0.6nm (at 2kV), 0.7nm (at 1kV) Probe current: 0.8pA ~ 100 nA, respectively, and were measured at 1200, 6,500, and 15,000 magnifications using UC mode with 1 kV of 25 pA. Photo 2 shows the SEM equipment used for the measurement.

                           [Picture 2] SEM equipment

 Analysis of the measurement photographs (x 1,500) shows that the particles composed of the particle mixture are each composed of a single particle. When the mixing process continues for a long time, the mixture is irregularly formed. Even if the mixing of the components is satisfactory, non-mixing or segregation occurs unless care is taken. Segregation refers to irregular mixing of particles,

Figures 7-d and 7-e show SEM measurements to identify biotite and kaolin surface particles.

Test Example 8     Particle size analysis measurement test

Example 6 A Zetasizer nano ZS (Malvern Instruments) instrument was used to determine the particle size distribution of the sample. As can be seen from Fig. 8, the particle size of 700 to 800 nm was confirmed.

Claims (4)

2.0 to 10.0 wt% of Alum, 50.0 to 80 wt% of Biotite, 2.0 to 10.0 wt% of Zeolite, 3.0 to 10.0 wt% of Tourmaline, 0.5 to 2.0 wt% of Monazite, 3.0 to 10.0 wt% of Kaolin, 1.0 to 5.0 wt% of Bentonite, 0.1 to 5.0 wt.%, Thyme powder 0.5 to 3.0 wt.%, Essential oil 0.1 to 2.5 wt.%, And dried for about 60 minutes using a Mixer.
2.0 to 10.0 wt% of Alum, 50.0 to 80 wt% of Biotite, 2.0 to 10.0 wt% of Zeolite, 3.0 to 10.0 wt% of Tourmaline, 0.5 to 2.0 wt% of Monazite, 3.0 to 10.0 wt% of Kaolin, 1.0 to 5.0 wt% of Bentonite, 0.1 to 5.0% by weight of Thyme powder, 0.5 to 3.0% by weight of essential oil, 0.5 to 2.5% by weight of Essential oil, and dried for about 60 minutes using a Mixer to heat the deodorant composition of the powder form at 80 DEG C for 1 hour And drying the mixture at room temperature for 3 hours to remove the shoe odor.
The method according to claim 1, wherein the essential oil is selected from the group consisting of eucalyptus, German chamomile, cedarwood, cinnamon, bergamot, lemon, cypress, lemongrass, juniper berry, tea tree, peppermint, rosemary, sandalwood, ginger, lavender, Wherein the deodorant composition is at least one or more of the following:
The method of claim 1, wherein the anti-caking agents are selected from the group consisting of magnesium myristate, magnesium silicate, magnesium aluminum silicate, microcrystalline cellulose, silica, zinc laurate, zinc stearate, natural aluminum silicate, Wherein the deodorant composition is at least one member selected from the group consisting of zinc oxide, zinc oxide, zinc oxide, zinc undecylenate, and kaolin.

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