KR20140087689A - A detergent composite - Google Patents
A detergent composite Download PDFInfo
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- KR20140087689A KR20140087689A KR1020120158256A KR20120158256A KR20140087689A KR 20140087689 A KR20140087689 A KR 20140087689A KR 1020120158256 A KR1020120158256 A KR 1020120158256A KR 20120158256 A KR20120158256 A KR 20120158256A KR 20140087689 A KR20140087689 A KR 20140087689A
- Authority
- KR
- South Korea
- Prior art keywords
- building
- acid
- detergent composition
- walls
- weight
- Prior art date
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- 239000003599 detergent Substances 0.000 title claims abstract description 26
- 239000002131 composite material Substances 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 30
- 239000002253 acid Substances 0.000 claims description 24
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 14
- 239000004094 surface-active agent Substances 0.000 claims description 14
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 claims description 13
- 239000004327 boric acid Substances 0.000 claims description 13
- 239000012459 cleaning agent Substances 0.000 claims description 12
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 6
- 238000005406 washing Methods 0.000 abstract description 12
- 239000000463 material Substances 0.000 abstract description 8
- 239000010438 granite Substances 0.000 abstract description 7
- 239000000356 contaminant Substances 0.000 abstract description 6
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 6
- 239000004575 stone Substances 0.000 abstract description 6
- 239000004579 marble Substances 0.000 abstract description 5
- 239000011521 glass Substances 0.000 abstract description 4
- 229910052751 metal Inorganic materials 0.000 abstract description 4
- 239000002184 metal Substances 0.000 abstract description 4
- 230000009182 swimming Effects 0.000 abstract description 4
- 239000004615 ingredient Substances 0.000 abstract description 3
- 239000013078 crystal Substances 0.000 abstract description 2
- 238000006253 efflorescence Methods 0.000 abstract 1
- 206010037844 rash Diseases 0.000 abstract 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 36
- 238000004140 cleaning Methods 0.000 description 28
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- -1 2 to 3% ~ 5 wt% Chemical compound 0.000 description 3
- 238000002845 discoloration Methods 0.000 description 3
- 239000012629 purifying agent Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 235000013311 vegetables Nutrition 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 239000004071 soot Substances 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- 230000002087 whitening effect Effects 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000010685 fatty oil Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000008194 pharmaceutical composition Substances 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/042—Acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C11D2111/16—
-
- C11D2111/24—
Abstract
Description
본 발명은 세제 조성물에 관한 것으로, 더욱 구체적으로 설명하면, 계면활성제 7~10 중량%, 붕산 3~5 중량%, 부틸셀루솔브 7~10중량%, 불화암모늄 3~5중량%, 산 제제 2~3중량%, 구연산 3~5중량%, 가성소다 2~4중량%, 산 정화제 5~10중량%, 나머지는 물로 구성되어, 건축물이나 터널벽과 같은 벽체의 세척이 용이하게 되며 벽체에 부착된 묵은 오염물을 비롯하여 금속 성분에 의한 녹까지 깨끗하게 세척할 수 있고, 건물 고유의 광택도 되살려 줄 수 있으며, 이러한 세제 조성물은 화강석, 대리석 등의 모든 석재는 물론, 타일, 갈아 닦기 후의 녹물, 공해로 찌든 때로 변색된 빌딩 내ㆍ외벽, 호텔, 병원, 백화점, 수영장, 터널 등의 건물 내ㆍ외벽의 세척에 적합한 성분으로 이루어져 있을 뿐 아니라 찌든 때는 물론 건축물 외벽에 흰색 결정이 생기는 백화현상까지도 완벽하게 제거해 낼 수 있는 세제 조성물에 관한 것이다.
More particularly, the present invention relates to a detergent composition comprising 7 to 10 wt% of a surfactant, 3 to 5 wt% of boric acid, 7 to 10 wt% of butyl cellosolve, 3 to 5 wt% of ammonium fluoride, 3 to 5% by weight of citric acid, 2 to 4% by weight of caustic soda, 5 to 10% by weight of an acid cleaning agent and the balance of water to facilitate the cleaning of walls such as buildings and tunnel walls, It is possible to thoroughly clean up to the rust due to the metal component as well as the old contaminants, and to restore the inherent luster of the building. Such detergent compositions can be used not only for all stones such as granite and marble, but also for tiles, It is not only composed of ingredients that are suitable for cleaning inside and outside walls of buildings and outer walls, hotels, hospitals, department stores, swimming pools, tunnels, etc., which are discolored when they are stained. The present invention relates to a detergent composition capable of removing impurities.
일반적으로 건물의 외벽은 누수를 방지함과 동시에 주위의 미관에 어울리도록 하기 위한 방안으로 그 둘레에 화강석, 대리석 등의 석재와 자기질, 도기질, 석기질 등의 타일 및 알루미늄, 세라믹, 법랑, 하니컴 패널 그리고 목재, 드라이비트 등의 외장재가 부착되는 형태로 시공되거나 페인트가 도포되어 있다.Generally, the exterior wall of a building is designed to prevent leaks and to match the aesthetics of the surroundings. It is used to make tiles such as granite, marble, and porcelain, porcelain, stone and aluminum, ceramic, enamel, Panels, and exterior materials such as wood, dry bits, etc. are attached or painted.
또한, 건물 이외에 방음벽, 터널, 교량 등의 구조물 역시 외장재 등으로 시공되어 있으며, 이러한 외장재는 시공 후 일정한 시간이 경과하면 외부로부터 미세 먼지 및 산성비 등으로 인해 이물질이 그 표면에 앉게 됨에 따라 시공초기에 비해 그 색상이 낮아지고, 이물질 등이 흘러내린 상태로 마르게 됨에 따라 얼룩져 보여 주위 미관을 저해하는 문제점이 있었다.In addition to the buildings, structures such as soundproof walls, tunnels, bridges, etc. are also constructed with exterior materials. Such exterior materials, when a certain period of time has elapsed after the construction, foreign substances are seated on the surface due to fine dust and acid rain, The color thereof is lowered, and as the foreign matter and the like are dried down, they are smudged, which hinders the aesthetics of the surroundings.
이러한 건물 및 구조물은 통상 일정한 기간이 경과한 후에는 정기적으로 세척하여 표면이 변색 되는 것을 방지함으로써, 그 수명을 연장시킬 수 있게 되고, 이와 같이 건물의 수명을 연장시키기 위한 세척방법은 먼저 작업자가 건물의 옥상에 올라가 밧줄을 지상으로 내려뜨린 다음 밧줄을 타고 상부에서 하부로 이동하면서 그 외벽이나 표면에 적당량의 세척제를 뿌리고, 이어 솔, 걸레 등의 청수도구를 이용하여 표면을 문질러서 이물질을 제거한 후 물로 헹구어 내는 방법으로 세척을 하는 방식으로 수행하고 있다.Such buildings and structures are regularly washed after a certain period of time to prevent discoloration of the surface, thereby extending the life of the building. In order to extend the life of the building, The rope is lowered to the ground and then the rope is moved from the upper part to the lower part while spraying an appropriate amount of cleaning agent on the outer wall or surface thereof and then rubbing the surface with a clean tool such as a brush or a rag to remove the foreign matter, And washing is carried out by a method of rinsing.
이와 같은 세척방법은 작업자의 작업자세가 안정적이지 못함에 따라 항상 안전사고의 위험이 있었고, 그에 따라 세척율이 낮아지는 또 다른 문제점이 있었다.Such a cleaning method has a risk of safety accidents due to the inability of the worker to attain a stable working posture, thereby causing another problem that the cleaning rate is lowered.
한편, 밧줄을 내릴 수 없는 방음벽, 터널, 교량 등의 구조물의 경우, 먼저 고압세척기를 이용하여 세척수를 분사한 후 이물질 등을 걸레 등의 청소도구로 세척하여 이물질을 분리시키는 세척방법 및 회전하는 브러시를 장착한 차량을 이용하여 그 표면의 이물질을 제거하는 세척방법이 있으나, 고압세척기를 이용한 세척방법은 구조물의 표면에 끼어 있는 이물질이 매연이나 기름때일 경우에는 이물질 깨끗하게 제거되지 않음으로써, 청소 전후가 크게 변화되지 않는 듯한 느낌을 갖게 되고, 또한, 브러시를 이용하여 세척을 할 경우에는 브러시의 끝이 표면에 심하게 마찰을 일으키는 과정에서 스크래치가 발생하게 됨에 따라 세척 후 스크래치 표면에 이물질이 다시 끼일 경우, 다음번 세척작업에서 이물질이 깨끗하게 제거되지 못하는 또 다른 문제점이 있었다.On the other hand, in the case of structures such as soundproof walls, tunnels, bridges and the like where the rope can not be lowered, the washing water is first sprayed using a high pressure washer, and then the foreign matter is washed with a cleaning tool such as a mop to separate the foreign matter. There is a cleaning method for removing foreign matter on the surface by using a vehicle equipped with a high pressure washer. However, in the cleaning method using a high-pressure washer, foreign matter trapped on the surface of the structure is not removed cleanly when the foreign matter is soot or oil, When the brush is cleaned, scratches are generated in the process of causing the end of the brush to be severely rubbed on the surface. Therefore, when the foreign substance is reattached to the scratch surface after cleaning, Another problem is that the foreign matter can not be removed cleanly in the next washing operation There.
특히, 건축물은 각기 다른 오염원과 재질로 이루어져 있기 때문에 그에 적합한 세제를 선택하는 것은 건축 구조물 세척에서 가장 중요한 요소이고, 특히, 화강석이나 타일의 경우는 재질에 맞지 않은 약품을 사용하여 세척한 때에는 외벽 재질을 부식시키거나 변색, 탈색을 시키고, 건물 고유의 모습과 색상을 없애는 등의 2차 오염을 만들어 건물에 치명적인 결과를 가져 올 수 있으며, 작업장 주변의 환경도 파괴하는 문제점이 있었다.
Especially, since the building is made of different pollutants and materials, it is the most important factor in cleaning the building structure. Especially, in case of granite or tile, when washing with chemicals that do not fit the material, And it is possible to cause secondary pollution such as erosion, discoloration, and discoloration of the building, such as eliminating the appearance and color of the building, and there is a problem that the environment around the workplace is destroyed.
본 발명의 목적은, 이러한 문제점을 해결하기 위한 것으로, 건물의 벽체의 재질을 손상을 주지 않고 세척하는 것이 가능하며, 묵은 오염물을 비롯하여 금속 성분에 의한 녹까지 깨끗하게 세척할 수 있고, 건물 고유의 광택도 되살려 줄 수 있으며, 벽체의 재질이 화강석, 대리석 등의 모든 석재는 물론, 타일, 유리에 관계없이 녹물, 공해로 찌든 때로 변색된 빌딩 내ㆍ외벽, 호텔, 병원, 백화점, 수영장, 터널 과 같은 건축물의 내ㆍ외벽을 손상을 주지않고 세척에 적합한 성분으로 이루어져 있을 뿐 아니라 찌든 때는 물론 건축물 외벽에 흰색 결정이 생기는 백화현상까지도 완벽하게 제거해 낼 수 있는 세제 조성물을 제공하는 것이다.
An object of the present invention is to solve such a problem, and it is an object of the present invention to provide a method of cleaning a wall of a building without damaging the material thereof, And the walls are made of all kinds of stone such as granite and marble, as well as tiles and glass, as well as in the interior and exterior walls of buildings that have been discolored by pollution due to greenery, pollution, hotels, hospitals, department stores, swimming pools, tunnels The present invention is to provide a detergent composition which can not only damage inner and outer walls of a building but also completely remove whitening phenomenon in which white crystals are formed on the outer wall of the building as well as stains.
본 발명의 이러한 목적은, 계면활성제 7~10 중량%, 붕산 3~5 중량%, 부틸셀루솔브 7~10중량%, 불화암모늄 3~5중량%, 산 제제 2~3중량%, 구연산 3~5중량%, 가성소다 2~4중량%, 산 정화제 5~10중량%, 나머지는 물로 구성된 본 발명에 따른 세제 조성물에 의하여 달성된다.
This object of the present invention is also achieved by a process for the preparation of a pharmaceutical composition comprising 7 to 10 wt% of a surfactant, 3 to 5 wt% of boric acid, 7 to 10 wt% of butylcellulose, 3 to 5 wt% of ammonium fluoride, 2 to 3 wt% 5 to 5 wt.%, Caustic soda 2 to 4 wt.%, Acid cleaning agent 5 to 10 wt.%, And the balance water.
본 발명에 따른 세제 조성물은 세척하고자 하는 건축 구조물의 내ㆍ외벽에 세제를 고르게 도포하고, 물로 씻어주고, 다시 깨끗한 물로 린스세정하면 묵은 오염물을 비롯하여 금속 성분에 의한 녹까지 깨끗하게 세척할 수 있고, 건물 고유의 광택도 되살려 줄 수 있으며, 이러한 세제 조성물은 모든 건축 구조물, 예를 들어 화강석, 대리석 등의 모든 석재는 물론, 타일, 유리와 같은 벽체의 녹물, 공해로 찌든 때로 변색된 빌딩 내ㆍ외벽, 호텔, 병원, 백화점, 수영장, 터널 등의 건물 내ㆍ외벽의 손상을 주지 않으며 세척에 적합한 성분으로 이루어져 있을 뿐 아니라 찌든 때는 물론 건축물 외벽에 흰색 결정이 생기는 백화현상까지도 완벽하게 제거해 낼 수 있는 효과가 있다.
The detergent composition according to the present invention can clean the rust due to metal components as well as old contaminants by rinsing the rinsing with clean water evenly by applying the detergent evenly on the inner and outer walls of the building structure to be cleaned, This detergent composition can be applied to all architectural structures, for example, all stones such as granite and marble, as well as tiles, lattices of walls such as glass, interior and exterior walls of buildings that are discolored by pollution, It does not damage inside and outside walls of buildings, such as hotels, hospitals, department stores, swimming pools, tunnels, etc. It is not only made of components suitable for cleaning but also completely removes whitening phenomenon have.
본 발명에 따른 세제 조성물은, 계면활성제 7~10 중량%, 붕산 3~5 중량%, 부틸셀루솔브 7~10중량%, 불화암모늄 3~5중량%, 산 제제 2~3중량%, 구연산 3~5중량%, 가성소다 2~4중량%, 산 정화제 5~10중량%, 나머지는 물로 조성되었다. The detergent composition according to the present invention comprises 7 to 10% by weight of a surfactant, 3 to 5% by weight of boric acid, 7 to 10% by weight of butylcellulose, 3 to 5% by weight of ammonium fluoride, 2 to 3% ~ 5 wt%, caustic soda 2 ~ 4 wt%, acid cleaning agent 5 ~ 10 wt%, and the balance water.
상기 계면활성제는 우수한 분산, 유화 및 세정능력을 지니고 있어 물과 잘 혼합될 수 있고, 물을 연화할 수 있어 세척효과를 높이며, 페인트, 식물유, 지방유 등을 용해 제거할 수 있고, 스케일방지 및 세척기능을 갖고 있다. The surfactant has excellent dispersing, emulsifying and cleaning ability and can be mixed well with water, softening water, improving the cleaning effect, dissolving and removing paint, vegetable oil and fatty oil, Function.
상기 계면활성제는 폴리옥시에틸렌 알킬에테르계 비이온계면활성제, 폴리옥시프로필렌 알킬에테르계 비이온계면활성제, 음이온성 계면활성제로 선형알킬벤젠술폰산 또는 그의 나트륨염중에서 선택된 어느 하나의 화합물을 사용하는 것이 바람직하다. 상기 계면활성제는 7중량% 이하이면 세척효과가 잘 발휘되지 않고, 10중량% 이상이 사용되면 붕산과의 상승효과가 감소되어, 그 함량이 계면활성제 7~10 중량%로 제한되었다. The surfactant is preferably selected from among polyoxyethylene alkyl ether nonionic surfactants, polyoxypropylene alkyl ether nonionic surfactants, linear alkylbenzenesulfonic acids or sodium salts thereof as anionic surfactants Do. If the amount of the surfactant is 7 wt% or less, the cleaning effect is not sufficiently exhibited. If 10 wt% or more is used, the synergistic effect with boric acid is reduced, and the content is limited to 7 to 10 wt% of the surfactant.
붕산(H3BO3)은 우수한 분산 및 유화 그리고 세정능력이 있어 물과 잘 혼합될 수 있고 물을 연화시킬 수 있게 되어 세척효과를 높일 수 있으며, 특히 석재 표면에 오염된 이물질을 쉽게 제거할 수 있게 된다. 상기 붕산은 3중량% 이하이면 세척효과가 잘 발휘되지 않고 5중량% 이상이면 상기 계면활성제와의 혼합시에 상승된 세정효과를 발휘하는데 한계가 있어, 붕산의 함량이 3~5 중량% 로 제한되었다.Boric acid (H 3 BO 3 ) has excellent dispersing, emulsifying and cleaning ability and can be mixed well with water and can soften water to improve cleaning effect. Especially, . If the amount of the boric acid is less than 3 wt%, the cleaning effect is not sufficiently exhibited. If the amount of the boric acid is more than 5 wt%, there is a limit in exhibiting an increased cleaning effect upon mixing with the surfactant, and the content of boric acid is limited to 3 to 5 wt% .
이와 같이 본 발명에서는 유사한 성질을 갖는 계면활성제와 붕산이 혼합되어 세정력이 기하급수적으로 증대되어 세정능력이 월등하게 향상되게 되는 것이다.As described above, in the present invention, surfactant having similar properties and boric acid are mixed with each other, so that cleansing power is increased exponentially and the cleaning ability is greatly improved.
부틸세루솔브는 휘발성이 강하고 세척능력을 가지고 있어, 오염물을 흡착함과 동시에 함께 휘발함으로써, 세척작업에서 물로 헹궈내는 등의 뒷작업을 필요로 하지 않으므로 세척작업을 보다 간편하고 용이하게 한다. 상기 부틸셀루솔브는 7중량% 이하이면 세척능력이 저하되고 10중량% 이상이면 휘발이 빨리 진행되게 되어, 부틸셀루솔브는 그 함량이 7~10중량% 로 제한되었다.The butyl serosolve is volatile and has a cleaning ability, which makes it easier and easier to clean because it does not require a back-up operation such as adsorption of the contaminants and volatilization together and rinsing with water in the cleaning operation. When the content of butylcellosolve is 7% by weight or less, the washing ability is decreased. When the content is 10% by weight or more, the volatilization proceeds quickly, and the content of butylcellosolve is limited to 7 to 10% by weight.
불화암모늄(NH4HF2)은 유리를 부식시킬 정밀한 부식성을 가지므로 전체 조성물 중량에서 5중량%가 넘지 않아야 하며, 이러한 불화암모늄은 미량의 사용으로도 세정능력이 뛰어나서 건축물의 표면에 부착된 오염된 때를 용이하게 제거할 수가 있다. 상기 불화암모늄은 3중량% 미안일 경우에는 오염된 때의 분리가 잘 일어나지 않게 되고, 5중량% 이상일 경우에는 표면에 미세한 손상이 발생되게 되어 그 함량이 불화암모늄은 3~5중량% 로 제한되었다.Ammonium fluoride (NH 4 HF 2 ) should not exceed 5% by weight of the total composition because it has a precise corrosiveness to corrode the glass. Such ammonium fluoride is excellent in cleaning ability even in a small amount of use, Can be easily removed. If the ammonium fluoride content is less than 3% by weight, separation at the time of contamination is not likely to occur. If the ammonium fluoride content is more than 5% by weight, minute damage occurs to the surface, and the content of ammonium fluoride is limited to 3 to 5% .
산 제제로는 인산(phosphoric acid), 염산(hydrochloric acid)이 혼합된 것을 사용하는데, 첨가될 산 제제의 중량을 100중량％로 보고 인산 70중량％, 염산 30중량％를 섞어 산 제제를 만들어 사용하며, 이는 오래된 건축물의 금속부분에 생긴 녹을 효과적으로 제거하여 준다. 산 제제는 그 함량이 2중량% 미만일 경우에는 표면의 녹이 잘 벗겨지지 않으며 3중량% 이상일 경우에는 세척물의 표면의 손상이 발생될 우려가 있어, 산 제제의 함량이 2~3중량% 로 설정되었다.The acidic agent is a mixture of phosphoric acid and hydrochloric acid. The acidic agent to be added is 100% by weight and 70% by weight of phosphoric acid and 30% by weight of hydrochloric acid are mixed. This effectively removes rust from the metal parts of old buildings. When the content of the acid agent is less than 2% by weight, the surface rust is not easily peeled off. When the content of the acid agent is more than 3% by weight, the surface of the washing agent may be damaged, and the content of the acid agent is set to 2 to 3% by weight .
상기 구연산은 인체에 무해하며, 구연산에 포함된 전해질인 나트륨염은 칼륨을 해리도가 낮은 칼슘염으로 포착하기 때문에 용액의 응고의 저지에 사용되며, 구연산은 나트륨이 증발 후에도 잔류가 가능하게 되므로 세정작업이 필요하다. 상기 구연산은 3중량% 미만일 경우에는 상기 부틸셀루솔브의 휘발성에 의하여 영향력이 거의 없게 되며 5중량% 이상일 경우에는 너무 잔류성이 많게 되므로, 구연산의 함량이 3~5중량% 로 제한되었다.Since sodium citrate, which is an electrolyte contained in citric acid, captures potassium as a calcium salt having low dissociation degree, it is used to inhibit the solidification of the solution, and citric acid is able to remain after the sodium is evaporated, Is required. When the content of citric acid is less than 3% by weight, the content of citric acid is limited to 3 to 5% by weight because the volatile property of the butylcellosolve has little influence. When the content is more than 5% by weight, the content of citric acid is limited to 3 to 5% by weight.
상기 구연산은 사용 시 용액의 비산을 막아 2차 오염을 예방하고, 급속한 수분의 증발시간을 늦춤으로써 충분한 가사시간을 확보하고, 작업면이 수직인 작업면에 세제 조성물이 충분히 부착되어 효과를 발휘하도록 하는데 그 목적이 있으며, 본 발명의 실시예에서는 구연산이 사용되었으나, 이에 제한되는 것이 아니고, 염화나트륨, 가용성 녹말, 과당, 잔탄검 등과 같은 자연친화적인 원료중에서 선택된 어느 하나가 사용될 수도 있을 것이며, 이와 같이 구연산의 사용으로 세척 후 발생하는 배출수의 오염을 최소화하고 생분해성을 높이고자 노력하였다The citric acid prevents the secondary scattering of the solution by preventing the scattering of the solution during use, secures a sufficient pot life by delaying the rapid evaporation time of water, and ensures that the detergent composition is sufficiently adhered to the work surface having a vertical working surface Citric acid is used in the embodiment of the present invention. However, the present invention is not limited thereto, and any one selected from natural friendly materials such as sodium chloride, soluble starch, fructose, xanthan gum, etc. may be used. Citric acid was used to minimize contamination of effluent water after washing and to improve biodegradability
가성소다로는 수산화나트륨(sodium hydroxide)이 사용되는데, 단백질이나 셀룰로오스 등의 유기물을 분해하는 작용이 강하여 건축물 상에서 식물유, 왁스, 수지, 니트로셀루로스, 바니쉬 등의 일부 유기고분자 성분을 지닌 오물에 대한 세척능력이 뛰어나다. 가성소다의 함량이 2중량% 미만이면 세척효과가 저하되고 가성소다의 함량이 4중량% 이상이면 그 세척효과가 증대될 수가 없어서, 가성소다의 함량이 2~4중량% 로 제한되었다.Sodium hydroxide is used as caustic soda. It has a strong action to decompose organic matter such as protein and cellulose. Therefore, it is possible to remove organic compounds such as vegetable oil, wax, resin, nitrocellulose and varnish Excellent cleaning ability. If the content of caustic soda is less than 2% by weight, the cleaning effect is deteriorated. If the content of caustic soda is 4% by weight or more, the cleaning effect can not be increased, and the content of caustic soda is limited to 2 to 4% by weight.
또한, 마지막으로 첨가되는 조성물인 산 정화제는 식물성 산 정화제로서, 이러한 식물성 산 정화제는 알코올류인 글리콜이 첨가되고 그 첨가량은 전체 중량%의 약 5~10중량% 정도가 첨가되며, 이러한 산 정화제는 조성물의 농도를 묽은 상태로 희석함과 동시에 혼합으로 발생되는 독성을 제거하는 역할을 한다. 산 정화제의 함량이 5중량% 미만이면 희석의 효과가 없으며 독성의 제거도 잘 되지 않으며, 10중량% 이상이면 너무 묽게 되어, 산 정화제의 함량이 5~10중량% 로 제한되었다.The acid cleaning agent, which is the last addition composition, is a vegetable acid cleaning agent. The vegetable acid cleaning agent is added with glycol, which is an alcohol, in an amount of about 5 to 10% by weight based on the total weight of the vegetable acid cleaning agent. Is diluted in a dilute state and at the same time, the toxicity generated by mixing is removed. When the content of the acid purifying agent is less than 5 wt%, the dilution effect is not effective and the toxicity is not easily removed. When the acid purifying agent content is more than 10 wt%, the content of the acid purifying agent is limited to 5 to 10 wt%.
본 발명의 제1실시예에 따른 세제 조성물은, 계면활성제 7 중량%, 붕산 3 중량%, 부틸셀루솔브 7중량%, 불화암모늄 3중량%, 산 제제 2중량%, 구연산 3중량%, 가성소다 2중량%, 산 정화제 5중량%, 나머지는 물로 조성되었다. The detergent composition according to the first embodiment of the present invention comprises 7 wt% of a surfactant, 3 wt% of boric acid, 7 wt% of butyl cellosolve, 3 wt% of ammonium fluoride, 2 wt% of an acid preparation, 2% by weight, acid pickling agent 5% by weight, and the remainder water.
본 발명의 제2실시예에 따른 세제 조성물은, 계면활성제 9 중량%, 붕산 4 중량%, 부틸셀루솔브 9 중량%, 불화암모늄 4 중량%, 산 제제 3중량%, 구연산 4 중량%, 가성소다 3 중량%, 산 정화제 8 중량%, 나머지는 물로 조성되었다. The detergent composition according to the second embodiment of the present invention comprises 9 wt% of a surfactant, 4 wt% of boric acid, 9 wt% of butyl cellosolve, 4 wt% of ammonium fluoride, 3 wt% of an acid preparation, 3% by weight, acid cleaning agent 8% by weight, and the balance of water.
본 발명의 제3실시예에 따른 세제 조성물은, 계면활성제 10 중량%, 붕산 5 중량%, 부틸셀루솔브 10중량%, 불화암모늄 5중량%, 산 제제 3중량%, 구연산 5중량%, 가성소다 4중량%, 산 정화제 10중량%, 나머지는 물로 조성되었다. The detergent composition according to the third embodiment of the present invention comprises 10 wt% of a surfactant, 5 wt% of boric acid, 10 wt% of butyl cellosolve, 5 wt% of ammonium fluoride, 3 wt% of an acid preparation, 4 wt%, acid cleaning agent 10 wt%, and the balance water.
이와 같은 실시예들의 세제조성물의 조성비를 표에 따라 정리하면 아래와 같이 나타날 수가 있을 것이다. (각 조성함량의 단위는 중량%)The composition ratios of the detergent compositions of the above embodiments can be summarized according to the following table. (Unit of each composition content is% by weight)
이와 같은 세제 조성물은 순차로 혼합되교 교반되어 제조되므로서, 청소가 필요한 건축물의 외벽이나 터널의 벽면 특히 화강암과 같은 암석으로 된 벽체의 표면에 세제 조성물을 뿌리고 약 5분정도의 시간이 경과되어 세제 조성물의 성분이 발휘되어 오염된 때나 오염된 유기물 또는 오염되어 고착된 먼지 등에 부착되어 이러한 오염물이 유리되게 좋은 상태에서 물을 뿌려주면, 오염된 오염물이 용이하게 세척이 가능하게 되는 것이다.Since the detergent composition is prepared by mixing and stirring in order, the detergent composition is sprayed on the outer wall of a building or a wall surface of a tunnel such as granite, which is required to be cleaned. After about 5 minutes, The contaminated contaminants can be easily cleaned when water is sprayed when the components of the composition are exposed and contaminated, or when the contaminants are adhered to the contaminated organic matter or the contaminated dust and the like.
이와 같이 물을 뿌려 준 후에, 벽체의 표면에 부착되어 있는 구연산의 성분을 씻어 내기 위하여 하부에서 상부로 지그재그형태로 물을 분사시키면, 건물이나 터널의 벽면에 부착되어 있던 매연이나 묶은 때가 깨끗하게 청소가 가능하게 되는 것이다.After spraying water like this, if you inject water in a zigzag form from the bottom to the top in order to wash out the citric acid component attached to the surface of the wall, you can clean the soot and the binding time attached to the wall of the building or tunnel It becomes possible.
이와 같이 본 발명에 따른 세제 조성물은 세제 조성물을 세척시킬 벽체에 뿌려주고 일정 시간이 경과된 후에 물로 1차로 세척하고 1차세척이 끝난 후에 다시 2차로 구연산과 같은 벽체에 부착된 성분을 물로 세척시키면 간단하게 청소작업이 종료되면서 건물의 벽체의 손상이 없이 청소가 가능하게 되므로서 청소 인력이 절감되고 청소인력이 위험한 작업을 수행하지 않아도 되므로 위험부담이 줄어들게 되는 우수한 효과가 있다.
As described above, the detergent composition according to the present invention is prepared by spraying a detergent composition onto a wall to be washed, washing the detergent composition first with water after a lapse of a predetermined time, washing the components attached to the wall, such as citric acid, It is possible to clean the building without damaging the wall of the building by simply ending the cleaning work, so that the cleaning workforce is reduced and the cleaning worker does not need to perform dangerous work, thereby reducing the risk burden.
본 발명에 따른 세제 조성물은 일반적인 세제의 제조산업에서 동일한 제품을 반복적으로 제조하는 것이 가능하다고 할 것이므로 산업상 이용가능성이 있다고 할 것이다.INDUSTRIAL APPLICABILITY The detergent composition according to the present invention is industrially applicable since it would be possible to repeatedly manufacture the same product in the general detergent manufacturing industry.
Claims (1)
상기 세제 조성물은, 계면활성제 7~10 중량%, 붕산 3~5 중량%, 부틸셀루솔브 7~10중량%, 불화암모늄 3~5중량%, 산 제제 2~3중량%, 구연산 3~5중량%, 가성소다 2~4중량%, 산 정화제 5~10중량%, 나머지는 물로 조성된 것을 특징으로 하는 세제 조성물In detergent compositions,
The detergent composition comprises 7 to 10 wt% of a surfactant, 3 to 5 wt% of boric acid, 7 to 10 wt% of butylcellulose, 3 to 5 wt% of ammonium fluoride, 2 to 3 wt% of an acid preparation, 3 to 5 wt% %, Caustic soda of 2 to 4 wt%, acid cleaning agent of 5 to 10 wt%, and the balance of water
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102007612B1 (en) | 2018-12-03 | 2019-08-05 | 박홍욱 | Detergent-free clean coating composition, construction method of coating layer using the same |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| KR102007612B1 (en) | 2018-12-03 | 2019-08-05 | 박홍욱 | Detergent-free clean coating composition, construction method of coating layer using the same |
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