KR20140060927A - Make-up cosmetic composition of oil-dispersed liquid type - Google Patents
Make-up cosmetic composition of oil-dispersed liquid type Download PDFInfo
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- KR20140060927A KR20140060927A KR1020120127890A KR20120127890A KR20140060927A KR 20140060927 A KR20140060927 A KR 20140060927A KR 1020120127890 A KR1020120127890 A KR 1020120127890A KR 20120127890 A KR20120127890 A KR 20120127890A KR 20140060927 A KR20140060927 A KR 20140060927A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/90—Block copolymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
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Abstract
More particularly, the present invention relates to a liquid make-up cosmetic composition for improving the dispersibility of a large amount of pigment and preventing coagulation by using ABn type silicone block copolymer and fumed silica as a dispersant, The present invention relates to a makeup cosmetic composition which provides a high spreadability and spreadability upon application to the skin, and which is rapidly adhered to the skin.
Description
More particularly, the present invention relates to a liquid make-up cosmetic composition for improving the dispersibility of a large amount of pigment and preventing coagulation by using ABn type silicone block copolymer and fumed silica as a dispersant, The present invention relates to a makeup cosmetic composition which provides a high spreadability and spreadability upon application to the skin, and which is rapidly adhered to the skin.
Generally, a dispersive makeup cosmetic is divided into oil dispersion and water dispersion. Generally, the oil dispersing type has the advantages of excellent durability and high covering power, but it has a disadvantage of feeling heavy and bundling. On the other hand, the water dispersion type has a disadvantage in that its usability is light and neat, but its sustainability and coverage are low.
The oil dispersion formulation is made of the composition of particles and liquid (oil) constituting the agglomerate, and the liquid is interspersed in various forms between the particles constituting the agglomerate, which affects the bonding and bonding force between particles.
In this case, depending on the form in which the liquid exists between the particles, it can be classified into a pendulum state, a funicular state, a capillary state, and a suspended state.
When the amount of the liquid used in the formulation is 0.1 to 5.0% by weight, a concave lens-like liquid-phase bond is formed between the particles. This state is the pendulum state (Fig. 1, Fig. 1), where the coupling of the aggregate is localized to the contact points of the particles, and the particle classification corresponds to this. The powder classification has flowability as a powder state, and is not molded, and it has the advantage of being able to exhibit a disadvantage in that powdery flakes are severely used and bright skin expression.
As the liquid content in these agglomerates increases (5 to 30 wt.%), The liquid forms a continuous phase, but air is dispersed in some spaces and begins to coalesce with the adjacent liquids. ). This applies to formulations such as compacts, twin cakes and powder factories, which have the property of being molded when a certain pressure is applied. The pendulum state and the funicular state are strictly powder dispersion techniques.
When the pores of the agglomerate are all filled with liquid (30 to 50% by weight), it becomes a capillary state (Fig. Capillary cake formulations have excellent coverage and durability, but they are heavy and have a thick makeup, which is a burden on the skin.
When the liquid content further increases (50 to 80% by weight) and the liquid completely surrounds the particles while isolating the particles (Fig. 1, d), the aggregate can not maintain the molded form, Lipstick, and dispersed liquid foundation.
Among them, the conventional floating state is advantageous in that the pigment is dispersed in the oil and stabilized with wax to form a formulation, thereby speeding up the composition adherence to the skin. However, there is a problem in that spreadability and spreadability are poor when the composition is initially applied.
Accordingly, the present inventors have made a study to provide a cosmetic composition capable of shortening the make-up speed because of its excellent spreadability and spreadability and fast adhesion speed. As a result, unlike the conventional wax-stabilized oil dispersion form, ABn type silicone block copolymer and dry It is possible to realize a liquid phase formulation in which the dispersibility of the pigment is improved by using silica as a dispersant, and the present invention has been completed.
Accordingly, it is an object of the present invention to provide a makeup cosmetic composition which can be easily applied to skin and is excellent in adhesion.
In order to achieve the above object, the present invention provides a makeup cosmetic composition using an ABn-type silicone block copolymer and dry silica as a dispersant.
The makeup cosmetic composition of the present invention can stabilize an oil-dispersed liquid form that flows like water by using ABn-type silicone block copolymer and dry silica, and thus, when applied to skin, it has low viscosity and spreadability due to low viscosity and frictional force The excellent and volatile components are volatilized during application, and the composition quickly adheres to the skin, thereby shortening the makeup time.
Figure 1 shows a form in which liquid is present between particles.
Fig. 2 shows the redispersibility after aggregation of Example 1 and Comparative Example 1. Fig.
Fig. 3 shows the stability of pigment dispersion of Example 1 and Comparative Example 2. Fig.
The cosmetic composition of the present invention is prepared by mixing ABn-type silicone block copolymer and fumed silica as a dispersant and an anti-aggregation agent, thereby stabilizing the oil-dispersed formulation of the liquid phase, thereby providing excellent spreadability and spreadability So as to provide a makeup cosmetic composition that is rapidly adhered thereto.
The ABn-type silicone block copolymer used in the present invention has a structure represented by the following formula (1), and specific examples thereof include bis-isobutylpyridine / piperidine-10/7 dimethicone copolymers of Dow Corning (Trade name: FZ-2233), bis-isobutyl phthalate / piperazine-24/7 dimethicone copolymer (trade name FZ-2222) or bis-isobutyl phage-13 dimethicone copolymer But is not limited thereto.
(Wherein a and b are 0 to 40, preferably 0 to 30, and a and b can not be 0 at the same time)
Specific examples of the dry silica used in the present invention include Aerosil series silica (trade name Aerosil 130, 200, 255, 300, etc.) of Evonik Degussa GmbH, silica silicate (trade name Aerosil R 805, R 812, R 816, etc.) or silica dimethicone silicate (trade names Aerosil R 202, R 974, etc.), but are not limited thereto.
The cosmetic composition according to the present invention is used in an amount of not less than 0.1% by weight, preferably not less than 1% by weight, more preferably not less than 5% by weight based on the total weight of the composition of ABn type silicone block copolymer. The cosmetic composition according to the present invention is used in an amount of 20% by weight or less, preferably 17% by weight or less, more preferably 13% by weight or more, based on the total weight of the composition of ABn type silicone block copolymer. The cosmetic composition according to the present invention is used in an amount of 0.1 to 20% by weight, preferably 1 to 17% by weight, more preferably 5 to 13% by weight, of the ABn type silicone block copolymer. When the content is less than 0.1% by weight, the pigment is not dispersed. When the content is more than 20% by weight, the feeling of use such as slippery and sticky is deteriorated.
The cosmetic composition according to the present invention is used in an amount of 0.1 wt% or more, preferably 1 wt% or more, and more preferably 5 wt% or more, based on the total weight of the composition. The cosmetic composition according to the present invention is used in an amount of 20% by weight or less, preferably 17% by weight or less, more preferably 13% by weight or more, based on the total weight of the composition. The cosmetic composition according to the present invention is used in an amount of 0.1 to 20% by weight, preferably 1 to 17% by weight, and more preferably 5 to 13% by weight, based on dry silica. When the content is less than 0.1% by weight, aggregation of the pigment can not be prevented. When the content is more than 20% by weight, the feeling of use such as slippery and sticky is deteriorated.
In addition, the composition according to the present invention may further contain a skin active ingredient or various oils known in the art, and the oil is preferably contained in an amount of 1 to 80% by weight based on the total weight of the composition. Examples of such oils include silicone oils such as dimethicone or cyclomethicone; Ester-based oils such as cetyl ethyl hexanoate or C12-15 alkyl benzoate; But are not limited to, hydrocarbon-based oils such as Hydrogenated Polydecene or Squalane, and mixtures thereof.
For the realization of fast adhesion, volatile components such as volatile oil may be contained. Examples of volatile components include volatile silicone oil such as cyclomethicone, trimethicone, and dimethicone having a low viscosity (1.5 cs or less) ; Volatile hydrocarbon oils such as isododecane and dodecane; And other volatile materials such as ethanol. The volatile component is preferably contained in an amount of 5 to 50% by weight based on the total weight of the composition.
In addition, the makeup cosmetic composition according to the present invention may further contain auxiliary components such as coloring matters, fragrance, preservative and thickener which are usually used in the make-up cosmetic preparation, In an amount of 20% by weight.
The cosmetic composition according to the present invention is not particularly limited as long as it is a makeup cosmetic composition in a liquid form, and can be formulated into, for example, an ultraviolet screening agent, a liquid foundation, a makeup base, or the like.
Hereinafter, the present invention will be described more specifically with reference to examples and test examples. It is to be understood that the scope of the present invention is not limited to these embodiments and test examples, and that variations, substitutions, and insertions conventionally known in the art And this is also included in the scope of the present invention.
[Reference Example] Preparation of Example 1 and Comparative Examples 1 to 7
Makeup cosmetics of Examples 1 to 5 and Comparative Examples 1 to 7 were prepared with the compositions shown in Tables 1 to 3 (unit: wt%). In Examples 1 to 7 of the present invention, ABn-type silicone block copolymer and dry silica were used in combination, and Comparative Examples 1 and 2 were used alone of ABn-type silicone block copolymer or dry silica. In Comparative Example 3, a branched silicon polymer Pigi-10 dimethicone was used instead of the ABn type silicone block copolymer. In Comparative Example 4-5, wet silica (SPHERICA MICRO BEADS P-1500, JGC CATALYSTS AND CHEMICALS LTD) and talc, a representative extender pigment, were used. In Comparative Examples 6 and 7, a common in-water type make-up cosmetic composition and an oil-dispersed make-up cosmetic composition stabilized with wax were prepared for comparison.
Iron oxide
- Aerosil 200
- Aerosil R 812
- Aerosil R 202
Iron oxide
- Aerosil 200
Iron oxide
- Aerosil 200
The dispersion stability and feeling of use of the makeup cosmetic compositions prepared in Examples 1 to 5 and Comparative Examples 1 to 7 were evaluated by the following methods.
[Test Example 1] Comparison of dispersion stability
To confirm the dispersion stability of the makeup cosmetic composition of the present invention, 30 g of each of Examples 1 to 5 and Comparative Examples 1 to 5 were taken and allowed to stand at room temperature for one week, and the degree of dispersibility was confirmed. And Figs. 2 to 3.
X: very poor (dye separation visible / not redispersible)
△: slightly poor (visible within 1 week of pigmentation / slight reddening of redispersions)
○: Good (no separation of pigment for more than one month / cleanly mixed in redispersing)
From the results of Table 4, it was confirmed that the makeup cosmetic compositions of Examples 1 to 5 containing the dispersing agent of the present invention had excellent dispersion stability as compared with Comparative Examples 1 to 5 using other dispersing agents. In addition, when Examples 1 to 5 are compared, it can be seen that the stability is good regardless of the type of the ABn-type silicone block copolymer and the dry silica.
This is because the ABn-type silicone block copolymer used in the present invention is located at a certain distance from the powder surface, and the silicon portion is bulky, as compared with the branched silicon polymer, It can stabilize one by one. Also, in the case of dry silica, it has a low specific gravity and a large specific surface area, so that the repulsive force between the particles is maximized, so that they are not agglomerated with each other and are helpful in redispersion of other pigments. Therefore, Comparative Example 1 using the ABn-type silicone block copolymer alone showed good pigment dispersibility but poor redispersibility. In Comparative Example 2 using dry silica alone, redispersion was observed, but pigment dispersibility was poor 2 and Fig. 3).
[Test Example 2] Comparison of spreadability, spreadability, adhesion speed
In order to confirm spreadability, spreadability and adhesion speed upon application of the makeup cosmetic composition of the present invention, the sensory evaluation of sensation in Examples 1 to 5 and Comparative Examples 6 to 7 was conducted on 20 professional panelists, 5 points scale) are shown in Table 4 below.
<Evaluation criteria> 5 points: Very good, 4 points: Good, 3 points: Average, 2 points: Not well, 1 point: Very unbalanced
<Criteria for evaluation of adhesion speed> 5 points: very fast, 4 points: fast, 3 points: normal. 2 points: Slow, 1 point: Very slow
As can be seen from Table 4, Comparative Example 6, which is a typical water-based makeup composition, showed favorable spreadability and spreadability, but Comparative Example 7, which is an oil-dispersed makeup composition having a slow adhesion rate and stabilized with wax, And it was not good.
On the other hand, Examples 1 to 5, which are the liquid oil-dispersible makeup compositions of the present invention, are different from the oil-in-water type makeup compositions which are stabilized with the wax-stabilized Comparative Example 6 and the oil-in-water type makeup compositions, The advantages of the makeup composition are as follows. As a result of complementing the disadvantages, the initial application has excellent spreadability and spreadability, and has a high adhesion speed and a short feeling of use which shortens the makeup speed.
Claims (7)
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2017003122A1 (en) * | 2015-06-30 | 2017-01-05 | (주)아모레퍼시픽 | Liquid oil dispersion cosmetic composition |
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KR100805218B1 (en) | 2000-09-11 | 2008-02-21 | 쇼와 덴코 가부시키가이샤 | Cosmetic composition |
KR20090074877A (en) * | 2008-01-03 | 2009-07-08 | (주)아모레퍼시픽 | Water in oil make-up cosmetic compositions containing silicone/silica powder |
US20120189676A1 (en) * | 2009-05-04 | 2012-07-26 | Milanka Susak | Cosmetic Compositions Comprising Cyanodiphenylacrylates |
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2012
- 2012-11-13 KR KR1020120127890A patent/KR102047875B1/en active IP Right Grant
Patent Citations (4)
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KR100805218B1 (en) | 2000-09-11 | 2008-02-21 | 쇼와 덴코 가부시키가이샤 | Cosmetic composition |
KR20050121260A (en) * | 2003-04-14 | 2005-12-26 | 더 프록터 앤드 갬블 캄파니 | Anhydrous, silicone modified fluorinated polymers for transfer-resistant cosmetic lip compositions |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017003122A1 (en) * | 2015-06-30 | 2017-01-05 | (주)아모레퍼시픽 | Liquid oil dispersion cosmetic composition |
KR20170003292A (en) * | 2015-06-30 | 2017-01-09 | (주)아모레퍼시픽 | Oil-dispersed liquid type cosmetic composition |
CN107708663A (en) * | 2015-06-30 | 2018-02-16 | 株式会社爱茉莉太平洋 | Fluid oil disperses cosmetic composition |
US10441526B2 (en) | 2015-06-30 | 2019-10-15 | Amorepacific Corporation | Liquid oil dispersion cosmetic composition |
TWI702964B (en) * | 2015-06-30 | 2020-09-01 | 南韓商愛茉莉太平洋股份有限公司 | Oil-dispersed liquid type cosmetic composition and its cosmetic product |
CN107708663B (en) * | 2015-06-30 | 2021-04-06 | 株式会社爱茉莉太平洋 | Liquid oil-dispersed cosmetic composition |
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