KR20140005990A - Hair cleansing agent composition and skin cleansing agent composition - Google Patents

Abstract

(A) anionic surfactant, (B) amphoteric surfactant, (C) silicone, (D) nonionic surfactant which has unsaturated or branched alkyl group, and (A) anionic surfactant And a mass ratio ((A) component / (B) component) with said (B) amphoteric surfactant is 1.5 or more and 3.5 or less, and also has the said (C) silicone and said (D) unsaturated or branched alkyl group It is a hair cleaning composition or skin cleaning composition whose mass ratio ((D) component / (C) component) with a warm surfactant is 0.1 or more.

Description

Hair cleaner composition and skin cleaner composition {HAIR CLEANSING AGENT COMPOSITION AND SKIN CLEANSING AGENT COMPOSITION}

The present invention relates to a hair cleanser composition and a skin cleanser composition.

The cleaning composition comprising an anionic surfactant, an amphoteric surfactant, and silicones is excellent in foaming and does not have a stiff feeling at the time of rinsing to the hair and skin, and is smooth and smooth at the time of finishing. It is known that it is excellent and exerts a favorable conditioning effect after washing (for example, refer patent documents 1-5). In particular, the effect that the finish is smooth and the smooth feeling is large is due to silicones.

Therefore, it is a present state that the provision of the cleaning composition which contains silicones stably is desired.

Patent Document 1: Japanese Patent Application Laid-Open No. 2004-262805 Patent Document 2: Japanese Patent Application Laid-Open No. 2004-292387 Patent Document 3: International Publication No. 2004/045568 Patent Document 4: Japanese Patent Application Laid-Open No. 2011-520822 Patent Document 5: Japanese Laid-Open Patent Publication No. 2009-518330

MEANS TO SOLVE THE PROBLEM The present inventors, when manufacturing the hair cleaning composition or skin cleaning composition containing silicones in large quantities at the time of production, when mixing in order to mix uniformly each composition, foam mixes and as shown in FIG. At the same time, a new problem has been found that silicones in the hair cleaner composition or the skin cleaner composition float on the surface of the liquid, resulting in a hair cleaner composition or a skin cleaner composition in which silicones are uniformly blended.

The reason for this is that since bubbles are hydrophobic, silicones, which are hydrophobic compounds, are attracted to the bubbles, and the silicones float and float on the liquid surface. do.

It is an object of the present invention to solve the above-mentioned conventional problems and to achieve the following objects. That is, the present invention, when stirring at the time of manufacture, can prevent the generation of bubbles, can suppress the separation of silicones, uniform composition, hair excellent in the smooth feeling of hair and skin at the time of finishing It is an object to provide a cleaning composition and a skin cleaning composition.

MEANS TO SOLVE THE PROBLEM In order to solve the said subject, as a result of earnestly examining, the present inventors acquired the following knowledge. Namely, a detergent containing (A) anionic surfactant, (B) amphoteric surfactant, (C) silicones, and (D) a nonionic surfactant having an unsaturated or branched alkyl group. As a composition, the mass ratio ((A) component / (B) component) of the said (A) anionic surfactant and the said (B) amphoteric surfactant is 1.5 or more and 3.5 or less, and also the said (C) silicones, The hair cleaner composition or the skin cleaner composition whose mass ratio ((D) component / (C) component) with the nonionic surfactant which has the said (D) unsaturated or branched alkyl group is 0.1 or more, is a foam | bubble when stirring at the time of manufacture, The present invention can be prevented, the separation of silicones can be suppressed, the composition is uniform, and it is excellent in the smooth feeling of hair and skin at the time of finishing, and the present invention has been completed.

This invention is based on the said knowledge by the present inventors, As means for solving the said subject, (A) anionic surfactant, (B) amphoteric surfactant, (C) silicones, ( D) A hair cleanser composition or skin cleanser composition containing a nonionic surfactant having an unsaturated or branched alkyl group, wherein the mass ratio of the (A) anionic surfactant to the (B) amphoteric surfactant ((A) component / (B) component) is 1.5 or more and 3.5 or less, Furthermore, the mass ratio ((D) component / (C) component) of the said (C) silicone and the nonionic surfactant which has the said (D) unsaturated or branched alkyl group. Is 0.1 or more, the hair cleanser composition or the skin cleanser composition.

ADVANTAGE OF THE INVENTION According to this invention, the said problem in the past can be solved, the said objective can be achieved, when stirring at the time of manufacture, foaming can be prevented, the separation of silicones can be suppressed, and it is uniform It is possible to provide a hair cleaner composition and a skin cleaner composition having one composition and excellent in the soft feeling of hair and skin at the time of finishing.

BRIEF DESCRIPTION OF THE DRAWINGS The figure which shows an example of the aspect which the silicon | silicone floated on the liquid surface at the time of manufacture.

(Hair cleanser composition, skin cleanser composition)

The hair cleaner composition of this invention contains at least the (A) anionic surfactant, (B) amphoteric surfactant, (C) silicone, and (D) nonionic surfactant which has an unsaturated or branched alkyl group, If necessary, it also contains other components.

Moreover, the skin cleanser composition of this invention contains at least a nonionic surfactant which has (A) anionic surfactant, (B) amphoteric surfactant, (C) silicone, and (D) unsaturated or branched alkyl group. And other components as necessary.

Hereinafter, the skin cleanser composition will be described together with the description of the hair cleanser composition. In addition, in this specification, together with the said hair cleaning composition and the said skin cleaning composition, it may only call "a cleaning composition."

<(A) Anionic Surfactant>

As a kind of said anionic surfactant (Hereinafter, it may be called "(A) component.), If it is used for cleaning composition, there will be no restriction | limiting in particular, According to the objective, it can select suitably, For example, Sulfonate, alkyl sulfate, acylated amino acid salt, polyoxyethylene (we may abbreviate as "POE" hereafter) alkyl ether sulfate, alkylbenzene sulfonate, N-acyl-N-methyltaurine salt, alpha-olefin sulfonate , Higher fatty acid ester sulfonate, alkyl ether acetate, POE alkyl ether acetate, fatty acid soap (potassium laurate, potassium myristinate, etc.), alkyl phosphate ester salt, N-lauroyl glutamate, N-palmi Toyl glutamate, N-lauroyl-N-ethylglycine salt, N-lauroyl sarcosine salt, N-myristoyl-β-alanine salt, and the like. These may be used individually by 1 type and may use 2 or more types together.

Among these, as for the said (A) component, fatty acid soap, alkyl sulfonate, and POE alkyl ether sulfate are preferable, and the average addition mole number of ethylene oxide (it may abbreviate as "EO" hereafter) is 1-5 more preferable. In particular, POE alkyl ether sulfate having an average added mole number of EO of 1 to 3 is particularly preferable.

There is no restriction | limiting in particular as carbon number of the alkyl group in the said (A) component, Although it can select suitably according to the objective, 6-24 are preferable and 10-16 are more preferable.

Moreover, there is no restriction | limiting in particular as a kind of salt in the said (A) component, According to the objective, it can select suitably, For example, sodium, potassium, magnesium, calcium, ammonium, etc. are mentioned.

Among these, sodium POE lauryl ether sulfate is preferable for the said (A) component from the point of the stability of silicones, and the smooth feeling.

There is no restriction | limiting in particular as content of the said (A) component, Although it can select suitably according to the objective, 3 mass%-30 mass% are preferable, and 5 mass%-20 mass% are more preferable at the point of washing power. When content of the said (A) component is less than 3 mass%, cleaning power may become low, and when it exceeds 30 mass%, the smoothness at the time of rinsing may not be acquired.

<(B) Amphoteric Surfactant>

As a kind of the said amphoteric surfactant (Hereinafter, it may be called "(B) component.), If it is used for cleaning composition, there will be no restriction | limiting in particular, According to the objective, it can select suitably, For example, alkyldimethyl Alkylbetaine-type activators such as amino acetate betaine, Amidebetaine-type activators such as alkylamide propylbetaine, Sulfobetaine-type activators, Hydroxysulfobetaine-type activators, Amide sulfobetaine-type activators, Phosphobetaine-type activators, and imida A zolinium betaine type | mold active agent, an amino propionic acid type | mold active agent, an amino acid type active agent, etc. are mentioned. These may be used individually by 1 type and may use 2 or more types together.

Among these, the alkyldimethylamino acetate betaine, such as alkylamide propyl betaine, such as lauric acid amide propyl betaine and palm oil fatty acid amide propyl betaine, and lauryl dimethyl amino acetate betaine, is preferable.

There is no restriction | limiting in particular as content of the said (B) component, Although it can select suitably according to the objective, 1 mass%-20 mass% are preferable, and 3 mass%-15 mass% are more preferable at the point of washing power. When content of the said (B) component is less than 1 mass%, there exists a thing with low washing power, the soft feeling of hair and skin at the time of finishing is not obtained, and when it exceeds 20 mass%, the smoothness at the time of rinsing There are things you can't get.

<(A) component / (B) component>

As mass ratio of the said (A) component and the said (B) component, if it is 1.5-3.5, there will be no restriction | limiting in particular and it can select suitably according to the objective. When the mass ratio of the component (A) / (B) is less than 1.5 or more than 3.5, the stability of the silicones may not be obtained.

<(C) Silicones>

The silicones (also referred to as "silicone compounds") can give a soft feeling to the hair and skin at the time of finishing.

In the present invention, silicones (hereinafter, may be referred to as "(C) component") are at least any one of dimethylpolysiloxane, cyclic silicone, and amino-modified silicone, and in terms of smoothness, , Dimethylpolysiloxanes and amino modified silicones are preferred. These may be used individually by 1 type and may use 2 or more types together.

There is no restriction | limiting in particular as said dimethyl polysiloxane, According to the objective, it can select suitably, For example, a trimethyl silyl group terminal dimethyl polysiloxane, a silanol group terminal dimethyl polysiloxane, etc. are mentioned.

There is no restriction | limiting in particular as a state of the said (C) component, Oil may be sufficient, and an emulsion may be sufficient.

There is no restriction | limiting in particular as kinematic viscosity of the dimethyl polysiloxane of the said (C) component, Although it can select suitably according to the objective, the kinematic viscosity in 25 degreeC from the point of the soft feeling of the hair and skin at the time of finishing, , 1 million mm 2 / s or more is preferable, and 4 million mm 2 / s or more is more preferable. Although it does not specifically limit as an upper limit of kinematic viscosity, 30 million mm <2> / s or less is preferable, 4 million mm <2> / s-30 million mm <2> / s are more preferable, and 4 million mm <2> / s-10 million mm <2> / s of dimethyl polysiloxane It is especially preferable to emulsify the dimethylpolysiloxane of 20 mm 2 / s to 1,000 mm 2 / s as a solvent.

Although there is no restriction | limiting in particular also as said amino modified silicone, Although it can select suitably according to the objective, What was emulsified using the dimethyl polysiloxane of 20mm <2> / s-1,000mm <2> / s as a solvent is preferable.

There is no restriction | limiting in particular as an emulsifier and an emulsification method at the time of emulsifying the said (C) component, According to the objective, it can select suitably.

As a measuring method of the said kinematic viscosity, it can measure by the method shown below, for example.

A toluene solution of silicon at a concentration of 1 g / 100 ml is prepared, and the specific viscosity ηsp (25 ° C.) is obtained by the following equation (1). Next, the intrinsic viscosity [η] is obtained by substituting the relation of Huggins represented by the following equation (2). The Huggins integer uses the one described in Nakamuda, Nikkei, 77 588 [1956]. Next, [η] is substituted into the formula of A. Kolorlov represented by the following formula (3) to obtain a molecular weight. Finally, the kinematic viscosity η of the silicones can be obtained by substituting M in the formula of A. J. Barry represented by the following formula (4).

ηsp = (η / η ₀ ) -1... Equation (1)

? sp = [?] + K '[?] ² . Equation (2)

^{[η] = 0.215 × 10 -4} M 0 .65 ... Equation (3)

logη = 1.00 + 0.0123M ^{0 .5} ... Equation (4)

In said formula (1), (eta) ₀ shows the viscosity of toluene, (eta) shows the viscosity of a solution.

The said (eta) ₀ and said (eta) are measured based on the cosmetic raw material standard general test method viscosity measuring method 1st method.

As a specific example of the said (C) component, a dimethyl polysiloxane (leofur DMS-60, a product made by Ibbosha Oil Industry Co., Ltd.), amojimethicone (SM 8904 Cosmetic Emulsion, made by Toray Dow Corning Co., Ltd.), an amino modified silicone (X) -52-2362, Shin-Etsu Chemical Co., Ltd.) etc. are mentioned, Among these, a dimethyl polysiloxane is more preferable at the point of the smooth feeling.

There is no restriction | limiting in particular as content of the said (C) component, Although it can select suitably according to the objective, 0.01 mass%-5 mass% are preferable, and 0.1 mass mass from the point of the smooth feeling of hair and skin at the time of finishing %-3 mass% are more preferable. When content of the said (C) component is less than 0.01 mass%, the soft feeling of the hair and skin at the time of finishing may not be acquired, and when it exceeds 5 mass%, stickiness may arise or the said The stability of (C) component may not be obtained.

<(D) Nonionic Surfactant Having Unsaturated or Branched Alkyl Group>

There is no restriction | limiting in particular as a kind of nonionic surfactant (Hereinafter, it may be called "(D) component.") Which has the said unsaturated or branched alkyl group, Although it can select suitably according to the objective, C12-C22 At least one ester of mono-, di-, and tri-forms consisting of fatty acids having an unsaturated or branched alkyl group, and at least one of glycerin, polyoxyalkylene glycerin, polyoxyethylene, sorbitan, and propylene glycol; and Preference is given to ethers.

The above-mentioned (D) component is a mono-, di-, and tri-body of these, containing at least one of a fatty acid having an unsaturated or branched alkyl group having 12 to 22 carbon atoms and glycerin and polyoxyalkylene glycerin. At least one ester is particularly preferred.

There is no restriction | limiting in particular as IOB (Inorganic Organic Balance) of the said (D) component, Although it can select suitably according to the objective, From the point of stability of silicones, it is preferable that it is 1 or less, and 0.25-0.7 are more preferable. When IOB exceeds 1, the stability of silicones may not be obtained.

The IOB means an oil-inorganic-organic balance of oil, that is, an index indicating the degree of polarity of the oil, and indicates the ratio of the oil to the inorganic organic matter. It is a value and is represented by following formula (5).

IOB = inorganic value of the oil / organic value of the oil... Formula (5)

Specifically, the "organic value" is set to 20 for one carbon atom in the oil molecule, the "inorganic value" is set to 100 for one copper hydroxyl group, and other substituents based on this It is a value calculated based on the inorganic value of the genital organs (Fujitazer "Organic Analysis" Kaniya Bookstore (1930), "Prediction and Organic Concept Map of Organic Compounds (Area 11-10 of Chemistry)" (1957). Pages 719-725, Fujita and Akatsuka, "Organic Organic Qualitative Analysis (Pure Water)," Punggan Bookstore (1970), page 487, by Koda, Organic Concepts-Basics and Applications, Sankyo Publishing (1984), 227. Page, by Yuchichi `` Emulsion Prescription Design by Organic Conceptual Diagram '' See Japanese Emulsion Co., Ltd. (1985), page 98, RH Ewell, JM Harrison, L. Berg: Ind Eng Chem 36, 871 (1944).

Specific examples of the component (D) include glyceryl isostearate (IOB: 0.63), glyceryl diisostearate (IOB: 0.29), glyceryl oleate (IOB: 0.62), and hexaglyceryl isostearic acid (IOB: 1.19). Glyceryl triisostearate (IOB: 0.16), dioleate glycol (IOB: 0.16), propylene glycol diisostearate (IOB: 0.16), propylene glycol dioleate (IOB: 0.16), triisostearic acid polyethylene glycol (PEG) -3 glyceryl (IOB: 0.2), trioleic acid PEG-3 glyceryl (IOB: 0.2), tristearic acid PEG-4 glyceryl (IOB: 0.24), diisostearic acid PEG-2 (IOB: 0.25), dioleic acid PEG-2 (IOB: 0.25), triisostearic acid polyglyceryl-2 (IOB: 0.26), triisostearic acid PEG-5 glyceryl (IOB: 0.3), trioleate acid PEGG-5 glyceryl (IOB: 0.3), Triisostearic acid PEG-4 sorbitan (IOB: 0.33), diisostearic acid PEG-3 (IOB: 0.33), dioleate acid PEGG-3 (IOB: 0.33), diiso Tearic acid PEG-4 (IOB: 0.4), dioleic acid PEG-4 (IOB: 0.4), diisostearic acid polyglyceryl-2 (IOB: 0.41), trioleic acid PEG-10 glyceryl (IOB: 0.5), Triisostearic acid PEG-10 glyceryl (IOB: 0.51), dioleic acid PEG-6 (IOB: 0.52), diisostearic acid polyglyceryl-3 (IOB: 0.52), diisostearic acid PEG-6 (IOB: 0.53) , POE (3) oleyl ether (IOB: 0.57), isostearic acid PEG-3glyceryl (IOB: 0.6), dioleic acid PEG-8 (IOB: 0.62), diisostearic acid PEG-8 (IOB: 0.63), Isostearic acid PEG-3 (IOB: 0.66), diisostearic acid PEG-10 glyceryl (IOB: 0.69), POE (5) oleyl ether (IOB: 0.75), POE (5) isostearyl ether (IOB: 0.76) ), Triisostearic acid polyglyceryl-10 (IOB: 0.76), diisostearic acid polyglyceryl-6 (IOB: 0.77), isostearic acid PEG-5glyceryl (IOB: 0.77), trioleic acid PEG-20 glyceryl (IOB: 0.78), triisostearic acid PEG-20 trimethyrol propane (IOB: 0. 78), dioleic acid PEG-12 (IOB: 0.79), triisostearic acid PEG-20 glyceryl (IOB: 0.79), stearic acid polyglyceryl-2 (IOB: 0.79), diisostearic acid PEG-12 (IOB: 0.8 ), Oleic acid polyglyceryl-2 (IOB: 0.8), POE (5) isocetyl ether (IOB: 0.82), POE (6) oleyl ether (IOB: 0.83), isostearic acid PEG-6glyceryl (IOB: 0.84), oleic acid PEG-6 (IOB: 0.9), isostearic acid PEG-6 (IOB: 0.91), sorbate oleate (IOB: 0.93), POE (8) oleyl ether (IOB: 0.95), isostearic acid PEG- 8 Glyceryl (IOB: 0.95), isostearic acid sorbitan (IOB: 0.95), trioleic acid PEG-30 Glyceryl (IOB: 0.97), triisostearic acid PEG-30 glyceryl (IOB: 0.98), diisostearic acid poly Glyceryl-10 (IOB: 1), diisostearic acid PEG-20 glyceryl (IOB: 1), etc. are mentioned.

Among these, triisostearic acid PEG-3 glyceryl, diisostearic acid PEG-2, diisostearic acid glyceryl, triisostearic acid PEG-5 glyceryl, diisostearic acid PEG-3, diisostearic acid PEG-4, and triiso PG-10 glyceryl stearic acid, glyceryl oleate, glyceryl isostearic acid, glyceryl isostearic acid are preferred, triisostearate PEG-3 glyceryl, diisostearic acid PEGG-2, diisostearic acid glyceryl, triisostearic acid PEG Particularly preferred are -5 glyceryl, diisostearic acid PEG-3, diisostearic acid PEG-4, glyceryl oleate, glycerol isostearic acid, and glyceryl isostearic acid.

As a specific example of the commercial item of the said (D) component, EMALEX GWIS-100EX (glycerol isostearic acid), NIKKOL MGIS (glycerol isostearic acid), EMALEX GWIS-200 (glyceryl diisostearate), NIKKOL MGO (glycerol oleate) ), EMALEX EG-di-O (dioleate glycol), EMALEX PG-di-IS (propylene glycol diisostearate), EMALEX PG-di-O (propylene glycol dioleate), EMALEX GWIS-303 (triisostearic acid PEG -3 glyceryl), EMALEX GWO-303 (trioleic acid PEG-3glyceryl), EMALEX GWS-304 (tristearic acid PEG-4glyceryl), EMALEX DEG-di-IS (diisostearic acid PEG-2), EMALEX DEG-di-O (dioleic acid PEG-2), EMALEX TISG-2 (triisostearic acid polyglyceryl-2), EMALEX GWIS-305EX (triisostearic acid PEG-5glyceryl), EMALEX GWO-305 (trioleic acid PEG-5glyceryl), EMALEX EG-2854-IS (triisostearic acid PEG-4 sorbitan), EMALEX TEG-di-IS (diisostearic acid PEG-3), EMALEX TEG-di-O (dioleoic acid PEG- 3 ), EMALEX 200di-ISEX (diisostearic acid PEG-4), EMALEX 200di-O (dioleoic acid PEG-4), EMALEX DISG-2EX (diisostearic acid polyglyceryl-2), EMALEX GWO-310 (trioleic acid PEG) -10 glyceryl), EMALEX GWIS-310EX (triisostearic acid PEG-10 glyceryl), EMALEX 300di-O (dioleoic acid PEGG-6), EMALEX DISG-3EX (diisostearic acid polyglyceryl-3), EMALEX 300di -ISEX (diisostearic acid PEG-6), EMALEX 503 (POE (3) oleyl ether), EMALEX GWIS-103EX (isostearic acid PEG-3glyceryl), EMALEX 400di-O (dioleoic acid PEGG-8), EMALEX 400di-ISEX (diisostearic acid PEG-8), EMALEX PEIS-3EX (isostearic acid PEG-3), EMALEX GWIS-210EX (diisostearic acid PEG-10glyceryl), EMALEX 505H (POE (5) oleyl ether) EMALEX 1805 (POE (5) isostearyl ether), EMALEX TISG-10 (triisostearic acid polyglyceryl-10), EMALEX DISG-6 (diisostearic acid polyglyceryl-6), EMALEX GWIS-105EX (iso) Stearic acid PEG-5 glyceryl), EMALEX GW O-320 (PEG-20 glyceryl trioleate), EMALEX TPIS-320 (PEG-20 trimetholpropane triisostearate), EMALEX 600di-O (PEG-12 dioleate), EMALEX GWIS-320EX (triisostearic acid PEG-20 glyceryl), EMALEX 600di-ISEX (diisostearic acid PEGG-12), EMALEX MOG-2 (polyglyceryl oleate oleate), EMALEX 1605 (POE (5) isocetyl ether), EMALEX 506 (POE ( 6) oleyl ether), EMALEX GWIS-106 (PEG-6 glyceryl isostearic acid), EMALEX OE-6 (PEG-6 oleate), EMALEX PEIS-6EX (PEG-6 isostearic acid), EMALEX SPO-100 (oleic acid) Sorbitan), EMALEX 508 (POE (8) oleyl ether), EMALEX GWIS-108 (isostearic acid PEGG-8glyceryl), EMALEX SPIS-100 (isostearic acid sorbitan), EMALEX GWO-330 (trioleate PEG- 30 glyceryl), EMALEX GWIS-330EX (triisostearic acid PEG-30 glyceryl), EMALEX DISG-10EX (diisostearic acid polyglyceryl-10), EMALEX GWIS-220EX (diisostearic acid PEGG-20 glyceryl) ( Above, Japanese emulsion Expression company there may be mentioned agents), pine Neto MI-610 (isostearic acid hexadecyl glyceryl) (Matsumoto Fine Chemical Co., Ltd.), TISG (tree isostearic acid glyceryl) (higher alcohol Industry Co., Ltd.) and the like.

There is no restriction | limiting in particular as content of the said (D) component, Although it can select suitably according to the objective, 0.01 mass%-10 mass% are preferable, In terms of stabilization of the said (C) component, 0.1 mass%-10 mass mass % Is more preferable, and 0.1 mass%-8 mass% are especially preferable at the point of the soft feeling of the hair and skin at the time of finishing. When content of the said (D) component is less than 0.01 mass%, the said (C) component may not be stabilized, and when it exceeds 10 mass%, the cleaning power and the smoothness at the time of rinsing may not be obtained, or finish You may not be able to get a smooth feeling of poetry hair or skin.

<(D) component / (C) component>

Although mass ratio ((D) component / (C) component) of the said (C) component and said (D) component is 0.1 or more, 0.1-20 are preferable, 0.1-15 are more preferable, and said (C) component In view of the stability, 0.3 to 6 are particularly preferable. When the said mass ratio ((D) component / (C) component) is less than 0.1, the stability of the said (C) component may not be acquired, and when it exceeds 20, the hair and skin feel soft at the time of finishing There are things you can't get.

<Other ingredients>

There is no restriction | limiting in particular as said other components, According to the objective, it can select suitably in the range which does not impair the effect of this invention, For example, other than nonionic surfactant other than the said (D) component, and (B) component Cationic polymers such as amphoteric surfactants, semipolar surfactants, cationic surfactants, anionic polymers, nonionic polymers, amphoteric polymers, cationic celluloses, antioxidants such as polyols, organic salts, BHT or α-tocopherol , Antiseptic agents such as triclosan and isopropylmethylphenol, viscosity modifiers such as fatty acid monoethanolamide, fatty acid diethanolamide, ultraviolet absorbers, antioxidants, protein derivatives, animal and vegetable extracts, anti-dandruff agents such as pyrotonolamine and zinc pyrithione , Anti-inflammatory agents such as dipotassium glycyrrhinate, benzoic acid and salts thereof, preservatives such as parabens and carton CG, citric acid and triethanolamine There may be mentioned tablets, ethylene glycol pearl agents, emulsions, hydro-trough, lower alcohols, such as dissipated esters, vitamins, volatile oil, hydrophobic solvents, dilution solvents, pigments, etc. (scented).

As content of the said other components, it can select suitably according to the objective in the range which does not impair the effect of this invention.

There is no restriction | limiting in particular as said coating agent, According to the objective, it can select suitably, For example, the coating agent A, the coating material B, the coating material C, and the coating material D of Table 5-Table 10 of Unexamined-Japanese-Patent No. 2006-63044. Etc. can be mentioned. These may be used individually by 1 type and may use 2 or more types together.

There is no restriction | limiting in particular as content of the said coating agent, Although it can select suitably according to the objective, 0.005 mass%-40 mass% are preferable with respect to the said whole cleaning composition, and 0.01 mass%-10 mass% are more preferable.

<pH>

There is no restriction | limiting in particular as pH of the said hair cleaning composition, Although it can select suitably according to the objective, 3-7 are preferable and 4-6 are more preferable. If the said pH is less than 3, there may be strong irritation to skin, and if it exceeds 7, the antiseptic force may fall and microorganisms may multiply.

Moreover, there is no restriction | limiting in particular as pH of the said skin cleanser composition, Although it can select suitably according to the objective, 5-11 are preferable and 5.5-11 are more preferable.

The said pH can be measured based on the cosmetic raw material standard general test method pH measurement method, for example.

<Viscosity>

There is no restriction | limiting in particular as viscosity in 25 degreeC of the said cleaning composition, According to a use, a use form, etc., it can select suitably.

For example, when using the said cleaning composition as a hair cleaning composition, 1,000 mPa * s-6,000 mPa * s are preferable. When the said viscosity is less than 1,000 mPa * s, since it flows out of a hand at the time of use, it may be difficult to use, and when it exceeds 6,000 mPa * s, the discharge property from a container may worsen.

When using the said cleaning composition as a skin cleaning composition, 1,000 Pa.s-3,000 mPa * s are preferable, and 1,000 Pa.s-2,000 mPa * s are more preferable. When the said viscosity is less than 1,000 mPa * s, it may be difficult to use because it flows out of a hand at the time of use, and when it exceeds 3,000 mPa * s, spreading worsens when it is applied to skin, and foaming performance is inferior It may become.

Moreover, when apply | coating the said cleaning composition to a dispenser container or a pump container, 100 mPa * s-300 mPa * s are preferable and 200 mPa * s-300 mPa * s are more preferable at the discharge | release property of the container.

When applying the said cleaning composition to a foamer container, 1 mPa * s-30 mPa * s are preferable from a discharge | release property of the container, and 1 mPa * s-10 mPa * s are more preferable.

The viscosity at said 25 degreeC can be measured based on the cosmetic raw material reference general test method viscosity measuring method 2nd method, for example.

<Container>

The cleaning composition may be contained in a container and used.

There is no restriction | limiting in particular as said container, According to the objective, it can select suitably, For example, besides tubes, such as an aluminum laminate tube, an EVAL tube, an aluminum tube, and a glass vapor-deposited plastic tube, by mechanical or differential pressure, Dispenser containers, squeeze containers, pump containers, laminate film containers, dropper containers, stick containers, bottle containers, foamer containers, and the like.

The laminate film of the aluminum laminate tube usually has a multilayer of two or more layers, the material of which is polyethylene, polyethylene terephthalate, polyester, biaxially stretched polypropylene, unstretched polypropylene, polyacrylonitrile, ethylene vinyl acetate airborne It consists of synthetic resins, such as coalescing, paper, aluminum vapor deposition plastics, etc. In consideration of strength, flexibility, weather resistance and the like, generally two to five layers are used.

There is no restriction | limiting in particular as a material of the said container, According to the objective, it can select suitably, For example, polyethylene, a polypropylene, polyethylene terephthalate, polystyrene, polyvinyl chloride, ethylene-vinyl alcohol resin, an acrylonitrile styrene resin , ABS resin, polyamide, glass, and the like. These may be used in a single layer or may be used in combination of two or more layers.

<Applications>

There is no restriction | limiting in particular as a use of the said hair cleaning composition, According to the objective, it can select suitably, For example, the shampoo, the rinse in shampoo which a shampoo effect and a rinse effect are obtained simultaneously, etc. are mentioned.

Moreover, there is no restriction | limiting in particular as a use of the said skin cleanser composition, According to the objective, it can select suitably, For example, a body soap, a hand soap, etc. are mentioned.

Example

Although an Example of this invention is given to the following and this invention is concretely demonstrated to it, this invention is not limited to these Examples at all. In addition, in the following Example and a comparative example, unless otherwise indicated, "%" shows the mass%, a ratio shows the mass ratio, and the quantity of each component in a table | surface shows the quantity converted in pure part.

(Examples 1 to 33, Comparative Examples 6 to 8)

(A) component, (B) component, (C) component, (D) component, and other components of the composition and compounding quantity shown to the following Table 1-5 are mixed uniformly, Examples 1-33, and The hair cleaning composition (shampoo) of Comparative Examples 6-8 was prepared. In addition, in following Tables 1-5, (C) component shows content as a silicon powder.

About each hair cleaning composition (shampoo) of Examples 1-33 and Comparative Examples 6-8, the evaluation of the stability of silicones ((C) component) and the soft feeling of hair are evaluated by the method shown below. It was done. The results are shown in combination with Tables 1 to 5.

<Evaluation of the stability of silicones>

500 ml of each cleaning composition of Examples and Comparative Examples were put into a tabletop emulsifying machine (trade name: AGI HOMO MIXER 2M-03, manufactured by Puramikus Co., Ltd.), and stirred for 120 seconds at 120 revolutions. The outer appearance of the liquid after filling into the bottle and storing it at 40 degreeC for room temperature (about 25 degreeC) for 1 month was visually observed. From the memory of the transparent glass bottle, evaluation was made according to the following criteria. In addition, about each washing | cleaning composition, the same evaluation is performed 3 times, respectively, and the result of three times of average points is shown to following Tables 1-5.

[Evaluation standard]

5 points: No separation of silicones

4 points | pieces: Although there exists separation of silicones, the separation degree is less than 3 volume%

3 points | pieces: The separation degree of silicones is 3 volume% or more and less than 5 volume%

2 points | pieces: The separation degree of silicones is 5 volume% or more and less than 20 volume%

1 point | piece: The separation degree of silicones is 20 volume% or more

In the evaluation criteria, the degree of separation was calculated by the following formula (I).

Separation degree = volume of separated volume / volume of whole detergent composition * 100... In formula (I)

<Evaluation of the soft feeling of hair>

Ten professional panelists of hair cleaner composition of woman of semi-long hair from short are haircut using approximately 6 g of each hair cleaner composition (shampoo) of Example and Comparative Example for ten days, respectively, The soft feeling of the hair at the time of finishing after drying hair after hair-drying was evaluated based on the following rating. The total score of ten ratings was computed, and the smooth feeling of hair was evaluated based on the following evaluation criteria. The results are shown in Tables 1 to 5 below.

[grade]

+2 points: very good

+1 point: slightly better

-1 point: slightly bad

-2 points: very bad

[Evaluation standard]

7 points: 15 points or more

6 points: Total points 14 to 10 points

5 points: Total points 9 to 5 points

4 points: Total points 4 to 0 points

3 points: Total points from -1 to -4 points

2 points: Total points from -5 to -9

1 point: Total point less than -10

(Comparative Example 1)

In Example 1, instead of depending on the composition and compounding amount shown in Table 1, according to the composition and compounding amount shown in Table 5, except having not added (A) component, it is a comparative example by the method similar to Example 1 The hair cleaning composition of 1 was prepared, and the evaluation of the stability of silicones ((C) component) and the soft feeling of hair were evaluated by the method similar to Example 1. The results are shown in Table 5 together.

(Comparative Example 2)

In Example 1, instead of depending on the composition and compounding amount shown in Table 1, according to the composition and compounding amount shown in Table 5, except having not added (B) component, it was the comparative example by the method similar to Example 1 The hair cleaning composition of 2 was prepared, and the evaluation of the stability of silicones ((C) component) and the soft feeling of hair were evaluated by the method similar to Example 1. The results are shown in Table 5 together.

(Comparative Example 3)

In Example 1, instead of depending on the composition and compounding amount shown in Table 1, according to the composition and compounding amount shown in Table 5, except having not added (C) component, it is a comparative example by the method similar to Example 1 The hair cleaning composition of 3 was prepared, and the soft feeling of hair was evaluated by the method similar to Example 1. The results are shown in Table 5 together.

(Comparative Example 4)

In Example 1, instead of depending on the composition and compounding amount shown in Table 1, according to the composition and compounding amount shown in Table 5, except having not added (D) component, it is a comparative example by the method similar to Example 1 The hair cleaning composition of 4 was prepared, and the evaluation of the stability of silicones ((C) component) and the soft feeling of hair were evaluated by the method similar to Example 1. The results are shown in Table 5 together.

(Comparative Example 5)

In Example 1, according to the composition and compounding quantity shown in Table 5 instead of following the composition and compounding quantity shown in Table 1, except having added the comparative component of (D) component instead of (D) component. , The hair cleaning composition of Comparative Example 5 was prepared in the same manner as in Example 1, and the stability of the silicones ((C) component) and the soft feeling of hair were evaluated in the same manner as in Example 1. . The results are shown in Table 5 together.

[Table 1]

[Table 2]

[Table 3]

[Table 4]

[Table 5]

(Examples 34-40, Comparative Examples 13-15)

(A) component, (B) component, (C) component, (D) component, and other components of the composition and compounding quantity shown to following Table 6 and 7 are mixed uniformly, Examples 34-40, and The skin cleanser composition (body soap) of Comparative Examples 13-15 was prepared. In addition, in following Tables 6 and 7, (C) component represents content as a silicone powder.

About each skin cleanser composition (body soap) of Examples 34-40 and Comparative Examples 13-15, the stability of silicones ((C) component) was evaluated by the method similar to the said Examples 1-33. Moreover, the soft feeling of the skin was evaluated by the method shown below. The results are shown in combination with Tables 6 and 7.

<Evaluation of skin soft feeling>

Ten expert panelists of skin cleanser composition use about 6 g of skin cleanser composition of Example and Comparative Example for 10 days, respectively, and feel the smooth feeling of skin at the time of finish after drying skin after day 10 And based on the following ratings. The total score of ten ratings was computed, and the smooth feeling was evaluated based on the following evaluation criteria. The results are shown in Table 6 below.

[grade]

+2 points: very good

+1 point: slightly better

-1 point: slightly bad

-2 points: very bad

[Evaluation standard]

7 points: 15 points or more

6 points: Total points 14 to 10 points

5 points: Total points 9 to 5 points

4 points: Total points 4 to 0 points

3 points: Total points from -1 to -4 points

2 points: Total points from -5 to -9

1 point: Total point less than -10

(Comparative Example 9)

In Example 24, instead of depending on the composition and compounding quantity shown in Table 6, according to the composition and compounding quantity shown in Table 7, except for not adding (A) component, it is a comparative example by the method similar to Example 24. The skin cleaning composition of 9 was prepared, and the evaluation of the stability of silicones ((C) component) and the soft feeling of the skin were evaluated by the method similar to Example 24. The results are shown in Table 7 together.

(Comparative Example 10)

In Example 24, instead of depending on the composition and compounding amount shown in Table 6, according to the composition and compounding amount shown in Table 7, except for not adding (B) component, it is a comparative example by the method similar to Example 24. The skin cleaning composition of 10 was prepared, and the evaluation of the stability of silicones ((C) component) and the soft feeling of the skin were evaluated by the method similar to Example 24. The results are shown in Table 7 together.

(Comparative Example 11)

In Example 24, instead of depending on the composition and compounding amount shown in Table 6, according to the composition and compounding amount shown in Table 7, except for not adding (C) component, it is a comparative example by the method similar to Example 24. The skin cleanser composition of 11 was prepared, and the evaluation of the stability of silicones ((C) component) and the soft feeling of the skin were evaluated by the method similar to Example 24. The results are shown in Table 7 together.

(Comparative Example 12)

In Example 24, instead of depending on the composition and compounding amount shown in Table 6, according to the composition and compounding amount shown in Table 7, except for not adding (D) component, it is a comparative example by the method similar to Example 24. The skin cleanser composition of 12 was prepared, and the evaluation of the stability of silicones ((C) component) and the soft feeling of the skin were evaluated by the method similar to Example 24. The results are shown in Table 7 together.

TABLE 6

[Table 7]

(Example 41: Hand soap)

Each component was mixed uniformly with the composition and compounding quantity shown below, and the skin cleanser composition (hand soap) of Example 41 was prepared. In addition, in the following compounding quantity, (C) component represents content as a silicone powder.

About the skin cleanser composition (hand soap) of Example 41, the stability of silicones ((C) component) was evaluated by the method similar to the said Examples 1-33. In addition, in the evaluation of the soft feeling of the skin of Examples 34 to 40, except that the amount of use of about 6 g is changed to about 1 g of the amount of use, the skin feels smooth in the same manner as in Examples 34 to 40. Was evaluated.

[Composition and Blending Amount]

Potassium laurate ((A) component) 10.0%

Palm oil fatty acid amide propyl betaine ((B) component) 5.0%

Dimethylpolysiloxane ((C) component) 2.0%

Glyceryl Diisostearate 2.0%

(IOB: 0.29) ((D) component)

Cationized Cellulose 0.3%

Glycerin 10.0%

Sorbitol 5.0%

Potassium hydroxide (pH10.2) proper amount

0.5% of A

Purified water Remainder

100% in total

(A) component / (B) component (mass ratio): 2.0

(D) component / (C) component (mass ratio): 1.0

[evaluation]

Silicon stability (room temperature): 5 points

Silicon stability (40 ℃): 5 points

Skin softness: 7 points

(Example 42: Foam hand soap)

Each component was mixed uniformly by the composition and compounding quantity shown below, and the skin cleanser composition (bubble hand soap) of Example 42 was prepared. Subsequently, 100 ml was filled in a 250 ml pump former container (manufactured by Yoshino Kogyo Co., Ltd., two 200 meshes). In the following compounding quantity, (C) component represents content as a silicone powder.

About the skin cleanser composition (foam hand soap) of Example 42, the stability of silicones ((C) component) was evaluated by the method similar to Examples 1-33, and the same method as the said Example 41 (a use amount: About 1g), the soft feeling of the skin was evaluated.

[Composition and Blending Amount]

Potassium laurate ((A) component) 7.0%

Myritic potassium potassium ((A) component) 3.0%

Laurin acid amide propyl betaine ((B) component) 3.0%

Dimethylpolysiloxane ((C) component) 2.0%

Diisostearic acid PEG-2 2.0%

 (IOB: 0.25) ((D) component)

Propylene Glycol 10.0%

Sorbitol 5.0%

Potassium hydroxide (pH10.2) proper amount

Isopropylmethylphenol 0.1%

0.5% of A

Purified water Remainder

100% in total

(A) component / (B) component (mass ratio): 3.3

(D) component / (C) component (mass ratio): 1.0

[evaluation]

Silicon stability (room temperature): 5 points

Silicon stability (40 ℃): 5 points

Skin softness: 7 points

Raw materials used in Examples 1 to 42 and Comparative Examples 1 to 8 are shown in Table 7 below.

[Table 7]

Industrial availability

When the hair cleaning composition of the present invention is stirred at the time of manufacture, it is possible to prevent the generation of bubbles, to suppress the separation of silicones, to have a uniform composition, and to be excellent in the smooth feeling of hair at the time of finishing. Therefore, it can be used suitably for shampoo, rinse, rinse-in shampoo and the like.

In addition, the skin cleanser composition of the present invention, when stirring at the time of manufacture, can prevent the generation of bubbles, can suppress the separation of silicones, and is a uniform composition, in the soft feeling of the skin at the time of finishing Since it is excellent, it can be used suitably for body soap, hand soap and the like.

As an aspect of this invention, it is as follows.

<1> The hair cleaning composition containing (A) anionic surfactant, (B) amphoteric surfactant, (C) silicone, and (D) nonionic surfactant which has an unsaturated or branched alkyl group, The said ( A) The mass ratio ((A) component / (B) component) of anionic surfactant and said (B) amphoteric surfactant is 1.5 or more and 3.5 or less, and (C) silicone and said (D) The mass ratio ((D) component / (C) component) with a nonionic surfactant which has an unsaturated or branched alkyl group is 0.1 or more, The hair cleaning composition characterized by the above-mentioned.

<2> Mono- and di-body which (D) nonionic surfactant which has unsaturated or branched alkyl group consists of a fatty acid which has a C12-C22 unsaturated or branched alkyl group, and at least any one of glycerol and polyoxyalkylene glycerine And the hair cleaning composition according to the above <1>, which is at least one ester of a trimer.

<3> (D) IOB of the nonionic surfactant which has an unsaturated or branched alkyl group is the hair cleaning composition in any one of said <1> to <2> which is 1 or less.

<4> A skin cleanser composition containing (A) anionic surfactant, (B) amphoteric surfactant, (C) silicones, and (D) a nonionic surfactant having an unsaturated or branched alkyl group. A) The mass ratio ((A) component / (B) component) of anionic surfactant and said (B) amphoteric surfactant is 1.5 or more and 3.5 or less, and (C) silicone and said (D) The mass ratio ((D) component / (C) component) with a nonionic surfactant which has an unsaturated or branched alkyl group is 0.1 or more, The skin cleansing composition characterized by the above-mentioned.

<5> (D) Mono- and di-body which non-ionic surfactant which has unsaturated or branched alkyl group consists of fatty acid which has a C12-C22 unsaturated or branched alkyl group, and at least any one of glycerol and polyoxyalkylene glycerine. And a skin cleanser composition according to the above <4>, which is at least one ester of a trimer.

<6> (D) IOB of the nonionic surfactant which has an unsaturated or branched alkyl group is the skin cleaning composition in any one of said <4> to <5> which is 1 or less.

Claims (6)

As a hair cleaning composition containing (A) anionic surfactant, (B) amphoteric surfactant, (C) silicone, and (D) nonionic surfactant which has an unsaturated or branched alkyl group,
The mass ratio ((A) component / (B) component) of the said (A) anionic surfactant and said (B) amphoteric surfactant is 1.5 or more and 3.5 or less, and (C) silicone and said ( D) The mass ratio ((D) component / (C) component) with a nonionic surfactant which has an unsaturated or branched alkyl group is 0.1 or more, The hair cleaning composition characterized by the above-mentioned. The method of claim 1,
(D) Mono-, di-, and tree, wherein the nonionic surfactant having an unsaturated or branched alkyl group consists of at least one of a fatty acid having 12 to 22 carbon atoms or an unsaturated or branched alkyl group, and glycerin and polyoxyalkyleneglycerin. Hair cleaning composition, characterized in that at least one ester of the sieve. 3. The method according to claim 1 or 2,
(D) IOB of nonionic surfactant which has an unsaturated or branched alkyl group is 1 or less, The hair cleaning composition characterized by the above-mentioned. As a skin cleanser composition containing (A) anionic surfactant, (B) amphoteric surfactant, (C) silicone, and (D) nonionic surfactant which has an unsaturated or branched alkyl group,
The mass ratio ((A) component / (B) component) of the said (A) anionic surfactant and said (B) amphoteric surfactant is 1.5 or more and 3.5 or less, and (C) silicone and said ( D) The mass ratio ((D) component / (C) component) with a nonionic surfactant which has an unsaturated or branched alkyl group is 0.1 or more, The skin cleansing composition characterized by the above-mentioned. 5. The method of claim 4,
(D) Mono-, di-, and tree, wherein the nonionic surfactant having an unsaturated or branched alkyl group consists of at least one of a fatty acid having 12 to 22 carbon atoms or an unsaturated or branched alkyl group, and glycerin and polyoxyalkyleneglycerin. Skin cleanser composition, characterized in that at least one ester of the sieve. The method according to claim 4 or 5,
(D) The skin cleanser composition whose IOB of a nonionic surfactant which has an unsaturated or branched alkyl group is 1 or less.

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