KR20130132352A - Water sterilization device with variable plasma device - Google Patents
Water sterilization device with variable plasma device Download PDFInfo
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- KR20130132352A KR20130132352A KR1020130128894A KR20130128894A KR20130132352A KR 20130132352 A KR20130132352 A KR 20130132352A KR 1020130128894 A KR1020130128894 A KR 1020130128894A KR 20130128894 A KR20130128894 A KR 20130128894A KR 20130132352 A KR20130132352 A KR 20130132352A
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- water
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- variable
- storage tank
- variable plasma
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/4608—Treatment of water, waste water, or sewage by electrochemical methods using electrical discharges
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/467—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
- C02F1/4672—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/46—Apparatus for electrochemical processes
- C02F2201/461—Electrolysis apparatus
- C02F2201/46105—Details relating to the electrolytic devices
- C02F2201/4612—Controlling or monitoring
- C02F2201/46125—Electrical variables
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Abstract
Description
The present invention relates to an agricultural and fishery water sterilization apparatus including a variable plasma apparatus, and more particularly, to a plasma generating apparatus in the related art, the manufacturing cost is reduced by simplifying the apparatus, and the amount of plasma is changed by changing the frequency. The present invention relates to an agricultural and fishery water sterilization apparatus including a variable plasma device that adjusts and sterilizes harmful bacteria present in seawater and fresh water to increase the productivity of agriculture and fishery, and also to be used as necessary agricultural and fishery water.
In farms, medicines and sterilizers are used to keep fish healthy. Recently, many sterilization apparatuses for preventing environmental pollution have been developed. As a device for sterilizing bacteria in the water as described above in the prior art Patent Publication No. 10-2010-0003341, the water introduced from the outside or the storage water circulated in the device cotton, microfiber fiber, charcoal fiber, Water flows for primary treatment while meandering through a layer or storage case of at least one selected from silver nanofibers, ocher fibers, charcoal, sand, gravel, jade, elvan, zeolite, germanium, chitosan, and reed wood A storage water pretreatment filtration device having a partition wall and at least one selected from among ultraviolet sterilization lamps, ozone generators, and ultrasonic generators installed on the side or bottom by receiving the storage water passing through the storage water pretreatment filtration device through the partition wall are installed. Detoxification device for oxidizing and decomposing heavy metals and residual pesticides in water and sterilizing germs, and through the filter and detoxification device. To the, characterized in that consisting of the discharge pipe and the shut-off valve member to enable the external exhaust, circulation motor for circulating supply the number stored in the pre-filtering device again with water, filtered and Admiral device is disclosed.
In addition, Patent Publication No. 10-0932377 (December 16, 2009) discloses a water treatment technique using plasma as a background art of the invention, generally water treatment technology is largely physical It can be divided into chemical treatment, biological treatment and multi-stage treatment. However, a lot of researches are currently being carried out to see a better water treatment effect beyond these technologies, and a lot of research is being conducted around a so-called advanced water treatment technology. In view of the above-described types of advanced water treatment technology, there are 1) an electrochemical method, 2) water treatment technology using electromagnetism, 3) water treatment technology using ultraviolet light, and 4) water treatment technology using plasma. It belongs to the water treatment technology using, as well as harmful substances in the water as well as harmful gases and odor treatment in the air is possible.
On the other hand, the conventional water treatment technology is agglomeration treatment, ozone oxidation treatment using ozone, activated carbon adsorption to adsorb soluble organic compounds and compounds, biological treatment by microorganisms, fenton oxidation process and the like are widely used. Among them, ozone is the most commonly used, and efforts are being made to apply ozone to environmental improvement and disease prevention in workplaces such as industrial wastewater and landfill leachate. This is because ozone has a strong oxidizing power, which in theory has the potential to completely decompose organic matter into CO 2 and H 2 O and produces no by-products, but the chemical properties and decomposition mechanism of ozone are gradually revealed. It is known that the reaction between ozone and some organic matters is selective or the reaction rate is slow.
In order to overcome the shortcomings of the ozone treatment and the limitations of the conventional oxidation treatment process, advanced oxidation treatment, which is a treatment that can purify contaminated water by promoting the generation of OH radicals having much stronger oxidizing power than general oxidizing agents in water ( The Advanced Oxidation Process (AOP) is considered to be very effective for water treatment.
Advanced oxidation process goes beyond the limitation of the conventional treatment method that directly decomposes organic substances from oxidant injected directly such as ozone, hydrogen peroxide, ultraviolet ray, etc., and combines several unit processes to combine artificially oxidizing OH radicals in water. It is an advanced oxidation treatment that produces and expects water treatment effects. OH Radical is an intermediate produced during the decomposition of ozone, and has a higher redox potential difference (2.80 [V]) than ozone itself. It easily targets unsaturated hydrocarbons and aromatic compounds, and in the case of halogenated compounds, replaces halogen elements. It may also be involved in degradation via pathways. After all, the ultimate goal of AOP is to maximize the concentration of these OH Radicals.
In addition, the types of AOP that can be applied to water treatment in a complex process include O 3 / highpH, O 3 / H 2 O 2 (Peroxone), O 3 / UV, H 2 O 2 / UV, and the like. Underwater high voltage plasma discharge is being actively researched.
In addition, among the advanced water treatment technologies, water treatment technology using plasma is mainly used for removing harmful gases in the air environment field in the past as a low temperature plasma process, but unlike the conventional water treatment technology, it does not require chemical input, and the treatment process is simple, and the second pollution Recently, a new concept of water treatment technology has emerged as an advantage that does not occur, and discharges forming low temperature plasma include pulse streamer discharge, silent discharge, partial discharge, creepage discharge and corona discharge. Electric discharges for water pollutant treatment have been actively conducted in the United States, Japan, the Netherlands, the Czech Republic, Russia and Canada since the late 1980s. The generation of high voltage pulse discharges in water or on the surface initiates a variety of physicochemical processes that generate UV, shock waves, and chemically active species such as H, O, OH, and H 2 O 2 . In the gas discharge, it is known that when oxygen is present in the background gas, high concentrations of ozone and active radicals are generated and easily dissolved in water to participate in the process of removing pollutants.
In particular, when air is used as the inlet gas of the plasma generator, the main reaction equation expected in the plasma generator is as follows, and radicals such as O 3 , O, OH, H, N, and HO 2 are generated and these unstable products are secondary. By reacting with pollutants or oxygen to form peroxide or a new type of radical, a chain oxidative decomposition reaction proceeds. This oxidation reaction is a water purification, such as hardly decomposable substances, harmful gases and odors in the atmosphere, and sterilization of color and wastewater. Can be widely applied to.
N 2 + e → N + N + e Equation 1
N 2 + e → N 2 - Equation 2
O 2 + e → 2O + e Equation 3
O 2 + e → O 2 - Equation 4
H 2 O + e → H + OH + e Equation 5
O + e → O - equation 6
O 2 + H → HO 2
H 2 O + O → 2OH Equation 8
O + O 2 → O 2 Equation 9
N 2 + O 2 → N 2 + 2
At present, the plasma discharge technique for water treatment has been studied so much, and it is already proved by many academic experiments that it is very good effect when the plasma is added to the water has been recognized.
However, to date, almost all technologies are very difficult to generate plasma due to the conductivity of water when plasma is generated in water, and short-circuit prevention technology must be applied. Electrodes on the surface of the surface for water surface discharge or electrodes coated with a coating film.
These devices are difficult to install due to their large size and heavy weight, and have disadvantages due to high power consumption, high price, and difficulty in operation and maintenance.
In addition, recently, techniques for generating discharge in water using various dielectrics have been studied, but problems such as short circuit or sudden decrease in discharge efficiency due to failure to maintain stable discharge in water are still occurring.
Accordingly, Patent Publication No. 10-0932377 relates to a water purification method using a high density underwater plasma torch as a solution thereof. As described in the Abstract, a plasma reactor is introduced into water to prevent deterioration of the reactor. In the water purification method using a high density underwater plasma torch to effectively transmit plasma energy by forming a strong electric field in the water surface and water, the method has an inner diameter of 1.0 ~ 20mm, an outer diameter of 5 ~ 20mm and a thickness of 0.5 ~ 5mm A transparent quartz tube having a length longer than the diameter of phosphorus standard, a conductive discharge electrode having a diameter inserted into the transparent quartz tube to secure an inner diameter and a discharge gap of the quartz tube, and an outer surface of the transparent quartz tube Meshes that form a high-density plasma region by contacting with and concentrating the maximum potential hardness at the conductive discharge electrode Underwater including a conductive counter electrode, an electrode tip assembled on top of the transparent quartz tube to fix the conductive discharge electrode to the inner central axis of the transparent quartz tube to maintain the gap distance, and a radial torch head having a gas inlet and a high voltage cable inlet. The first step of building a plasma reactor (torch) and the second step of increasing the fluidity of the plasma to be used by adjusting the position and distance of the conductive discharge electrode and the mesh type conductive counter electrode inserted into the transparent quartz tube and the gas A third step of maintaining plasma stably in the water by blocking the path of water with air or gas pressure injected through a regulator connected to the inlet port, and connecting the conductive discharge electrode and the mesh type conductive counter electrode to terminals of a commercial electronic neon transformer. Power supply 7 [kV] ~ 15 [kV], 21.0 [kHz] ~ 23 [kHz] A fourth step of generating a plasma and a fifth step of immediately injecting water into the water when the air or gas injected in the third step is activated in the high-density plasma region; and at the lower end of the transparent quartz tube, the high-density plasma region 6th to purify the contaminated water quality by increasing the contact time and surface area of water through the microporous bubble device that generates micron-sized bubbles to increase the diffusion effect and the catalytic oxidation reaction of activated radicals and gases from It provides a water purification method using a high density underwater plasma torch, comprising the step.
However, the sterilization method by the UV sterilization lamp, ozone generator, and ultrasonic generator does not exhibit sufficient and stable sterilization effect as desired in aquaculture farms, and the conventional sterilization methods using plasma are also activated in the plasma region. Radicals, gases, and the like do not have good diffusion, and the catalytic oxidation reaction does not increase as desired, so that it is difficult to easily and reliably remove environmental pollutants.
The present invention has been made to solve the above problems, to provide a agricultural, fishery water sterilization apparatus comprising a variable plasma device that can adjust the amount of plasma generated according to the amount to be sterilized using a variable plasma generator. have.
Another object of the present invention, using a venturi tube, agricultural, fishery water sterilization apparatus comprising a variable plasma device made by applying a structure for the production of oxidizing strong ozone and OH radicals in the absence of the conventional air supply In providing.
In order to solve the above problems, agricultural, fishery water sterilization apparatus comprising a variable plasma device according to the present invention comprises a power supply for supplying the power required for the device; A water pump receiving electric power from the power supply device and introducing water; A variable plasma generation device capable of controlling and controlling the intensity of the plasma generated by controlling the frequency of power supplied from the power supply device by generating and sterilizing the water flowing through the water pump; A first connection pipe having one side communicating with the water pump and the other side communicating with the variable plasma generating device; Sterilizing water storage tank for storing the water sterilized by the variable plasma generating device discharged; A second connection tube having one side communicating with the variable plasma generating device and the other side communicating with the sterilizing water storage tank; A contaminant and bubble discharge device disposed above the sterilizing water storage tank to discharge bubbles and ozone; And a sterilization water outlet disposed under the sterilization water storage tank and discharging the sterilization water after sterilization is completed in the sterilization water storage tank.
At this time, the variable plasma generating device,
A quartz tube having a length longer than the diameter; An air inlet formed on one side of the quartz tube; A conductive first electrode inserted into the quartz tube; A conductive second electrode formed outside the quartz tube to generate plasma; And a power frequency control device connected to one side of the power supply device to supply power but control the intensity of plasma generated between the first conductive electrode and the second conductive electrode by controlling the frequency of the supplied electric power. It is characterized by.
In addition, one side is in communication with the lower portion of the quartz tube and the other side is in communication with the side of the second connecting tube is laid, while forcibly supplying air to the variable plasma generating device and at the same time ozone and OH radicals to the second connecting tube It characterized in that it further comprises a venturi tube for supplying.
In this case, the contaminant and the bubble discharge device is in communication with one side, the activated carbon filter layer filled with activated carbon therein is characterized in that it further comprises.
The present invention has the advantage that the plasma generation amount can be adjusted according to the flow rate to be sterilized using the variable plasma generator.
In addition, the present invention has the advantage of simplifying the structure using a venturi tube.
1 is a conceptual diagram of a farming, fishery water sterilization apparatus including a variable plasma device according to an embodiment of the present invention.
2 is a graph measuring the amount of plasma generated according to frequency.
3 is an experimental result of the sterilized water using plasma.
4 is a graph showing the change in RNO concentration according to the air input amount.
Hereinafter, specific embodiments of the present invention will be described in detail with reference to the accompanying drawings.
1 is a conceptual diagram of a agricultural, fishery water sterilization apparatus including a variable plasma apparatus according to an embodiment of the present invention, Figure 2 is a graph measuring the amount of plasma generated according to the frequency, Figure 3 is an experiment for the sterilized water using plasma As a result, Figure 4 is a graph of the change in RNO concentration according to the air input amount.
1 to 4, the agricultural, fishery water sterilization apparatus including a variable plasma device according to the present invention includes a power supply device for supplying the power required for the device; A
At this time, the variable
A
Plasma can be used to remove BOD, COD, H 2 S and improve transparency. In addition, the removal and suppression of harmful bacteria such as Vibrio bacteria and fish diseases are made, and can remove the fishy smell of fish tanks, toilets, breeding sites raising livestock.
Let's look at the agricultural, fishery water sterilization process including the variable plasma device.
Water to be sterilized is introduced into the
Here, the difference from the
A graph regarding the amount of plasma generated according to frequency can be seen through FIG. 2. By using this, the user can control the plasma generation amount by adjusting the frequency according to the amount of water to be sterilized.
The unsterilized water introduced by using the
Thus, the ozone and OH radicals are generated by plasma while passing through the
Conventionally, in order to suck air into the
However, the present invention is configured in one step by simplifying the above two steps. In order to do so, the most important component will be the venturi tube (300).
The
Therefore, the amount of ozone and OH radicals moved through the
Figure 4 shows the RNO concentration according to the air amount, it can be seen that the lower the RNO concentration increases the amount of OH radicals generated. 4, it can be seen that the greater the amount of air coming in per unit time, the greater the amount of OH radicals generated.
Secondary sterilization is performed through ozone and OH radicals supplied to the first sterilizing water through the
Since these OH radicals are natural substances, they do not harm the human body and help to improve the environment. The use of other chemicals to sterilize and disintegrate may harm the human body, but OH radicals do not harm the human body. Chemicals may cause secondary environmental pollution, but OH radicals have strong sterilization, deodorization and decomposition effects. It is an eco-friendly material that does not have to worry about secondary pollution.
Secondary sterilization is performed using such OH radicals and ozone, which is well known in the art.
Secondary sterilization water made up to the second sterilization is sprayed to a wide sterilization water storage tank (400). In order to mix the OH radicals and ozone remaining in the second sterilization process with the sterilization water and to discharge the bubbles and remaining pollutants generated at the same time. Above the secondary sterilizing water in the sterilizing
Therefore, a contaminant and
Sterilized water sterilized through the above process is used for groundwater sterilization, rainwater greening sterilization, nutrient cultivation sterilizer, seed disinfection sterilization, low pesticide substitute, plant cultivation, etc. It can be used in various fields such as sterilization, sashimi, or aquarium of seaweed, fresh water sterilizer.
In the above described with reference to the accompanying drawings in order to help understand the technical idea of the present invention, this is merely illustrative of the preferred embodiments of the present invention is not limited thereto, and the scope of the technical idea of the present invention It will be apparent to those skilled in the art that various modifications, substitutions, and the like may be made without departing from the scope of the present invention.
100-power supply
110-Power Frequency Regulator
120-Water Pump
130-first connector
140-2nd connector
200-plasma generator
210-conductive 1 pole
220-conductive 2-pole
230-quartz tube
240-air inlet
300-Venturi Tube
400-sterile water reservoir
500-Pollutant and Foam Discharge Device
510-Activated Carbon Filter Layer
600-Sterilization Water Discharge Tube
Claims (4)
A water pump receiving electric power from the power supply device and introducing water;
A variable plasma generation device capable of controlling and controlling the intensity of the plasma generated by controlling the frequency of power supplied from the power supply device by generating and sterilizing the water flowing through the water pump;
A first connection pipe having one side communicating with the water pump and the other side communicating with the variable plasma generating device;
Sterilizing water storage tank for storing the water sterilized by the variable plasma generating device discharged;
A second connection tube having one side communicating with the variable plasma generating device and the other side communicating with the sterilizing water storage tank;
A contaminant and bubble discharge device disposed above the sterilizing water storage tank to discharge bubbles and ozone; And
Agricultural and fishery water sterilization apparatus including a variable plasma device is installed in the lower portion of the sterilizing water storage tank including a sterilizing water outlet for discharging the sterilized water is complete sterilization in the sterilizing water storage tank.
The variable plasma generating device,
A quartz tube having a length longer than the diameter;
An air inlet formed on one side of the quartz tube;
A conductive first electrode inserted into the quartz tube;
A conductive second electrode formed outside the quartz tube to generate plasma; And
A power frequency control device connected to one side of the power supply device and supplying power but controlling the intensity of plasma generated between the conductive first pole and the conductive second pole by controlling a frequency of the supplied power; Water sterilization apparatus comprising a variable plasma generating device, characterized in that.
One side is in communication with the lower portion of the quartz tube and the other side is in communication with the side of the second connecting tube is installed, while forcibly supplying and supplying air into the variable plasma generating device at the same time supplying ozone and OH radicals to the second connecting tube. Water sterilization apparatus comprising a variable plasma generating device characterized in that it further comprises a venturi tube.
A water sterilization apparatus including a variable plasma generator, which is connected to one side of the pollutant and the bubble discharge device, and further includes an activated carbon filter layer filled with activated carbon therein.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20150100031A (en) * | 2014-02-24 | 2015-09-02 | 주식회사 플라즈마코리아 | Water treatment apparatus using plasma |
CN117285210A (en) * | 2023-11-27 | 2023-12-26 | 黎明职业大学 | Printing and dyeing wastewater treatment device and method based on multi-frequency plasma technology |
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2013
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20150100031A (en) * | 2014-02-24 | 2015-09-02 | 주식회사 플라즈마코리아 | Water treatment apparatus using plasma |
CN117285210A (en) * | 2023-11-27 | 2023-12-26 | 黎明职业大学 | Printing and dyeing wastewater treatment device and method based on multi-frequency plasma technology |
CN117285210B (en) * | 2023-11-27 | 2024-04-05 | 黎明职业大学 | Printing and dyeing wastewater treatment device and method based on multi-frequency plasma technology |
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