KR20130082374A - Methods of fabricating semiconductor devices - Google Patents
Methods of fabricating semiconductor devices Download PDFInfo
- Publication number
- KR20130082374A KR20130082374A KR1020120003561A KR20120003561A KR20130082374A KR 20130082374 A KR20130082374 A KR 20130082374A KR 1020120003561 A KR1020120003561 A KR 1020120003561A KR 20120003561 A KR20120003561 A KR 20120003561A KR 20130082374 A KR20130082374 A KR 20130082374A
- Authority
- KR
- South Korea
- Prior art keywords
- hard mask
- gate electrode
- film
- pattern
- forming
- Prior art date
Links
- 239000004065 semiconductor Substances 0.000 title claims abstract description 52
- 238000000034 method Methods 0.000 title claims abstract description 47
- 229910052751 metal Inorganic materials 0.000 claims abstract description 60
- 239000002184 metal Substances 0.000 claims abstract description 60
- 238000002161 passivation Methods 0.000 claims abstract description 42
- 239000000758 substrate Substances 0.000 claims abstract description 18
- 238000000059 patterning Methods 0.000 claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 claims description 32
- 230000001681 protective effect Effects 0.000 claims description 9
- 239000010410 layer Substances 0.000 description 113
- 229910052581 Si3N4 Inorganic materials 0.000 description 12
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 12
- 238000005530 etching Methods 0.000 description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 238000004518 low pressure chemical vapour deposition Methods 0.000 description 7
- 150000004767 nitrides Chemical class 0.000 description 7
- 229910052814 silicon oxide Inorganic materials 0.000 description 7
- 238000005229 chemical vapour deposition Methods 0.000 description 6
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 238000000231 atomic layer deposition Methods 0.000 description 4
- 229910044991 metal oxide Inorganic materials 0.000 description 4
- 150000004706 metal oxides Chemical class 0.000 description 4
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 238000001312 dry etching Methods 0.000 description 3
- 239000011241 protective layer Substances 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 2
- 230000001808 coupling effect Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 229910000449 hafnium oxide Inorganic materials 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- -1 WSi Chemical compound 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000000206 photolithography Methods 0.000 description 1
- 229910021332 silicide Inorganic materials 0.000 description 1
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 229910001936 tantalum oxide Inorganic materials 0.000 description 1
- 230000005641 tunneling Effects 0.000 description 1
- 238000001039 wet etching Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/401—Multistep manufacturing processes
- H01L29/4011—Multistep manufacturing processes for data storage electrodes
- H01L29/40114—Multistep manufacturing processes for data storage electrodes the electrodes comprising a conductor-insulator-conductor-insulator-semiconductor structure
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/66007—Multistep manufacturing processes
- H01L29/66075—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
- H01L29/66227—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
- H01L29/66409—Unipolar field-effect transistors
- H01L29/66477—Unipolar field-effect transistors with an insulated gate, i.e. MISFET
- H01L29/66825—Unipolar field-effect transistors with an insulated gate, i.e. MISFET with a floating gate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/788—Field effect transistors with field effect produced by an insulated gate with floating gate
Abstract
A first insulating film, a first conductive film, a dielectric film, a second conductive film, a metal film, and a hard mask film are sequentially formed on the substrate, the hard mask film is patterned to form a hard mask pattern, and the hard mask pattern is patterned. The metal layer is patterned using a mask to form a metal gate electrode having exposed sides, a first passivation layer is formed on the exposed side of the metal gate electrode, and the second mask is formed using the hard mask pattern as a patterning mask. The conductive layer is patterned to form a second gate electrode having exposed sides, a second passivation layer is formed on the exposed side of the second gate electrode, and the dielectric layer and the substrate are formed using the hard mask pattern as a patterning mask. Patterning the first conductive film to form the dielectric pattern and the first gate electrode to form the gate structures. This method is described in the semiconductor device.
Description
The technical field of the present invention relates to a semiconductor device and a method of manufacturing the same.
Patterns of semiconductor devices are gradually becoming finer, and thus the uniformity of fine patterns is becoming more stringent.
The problem to be solved by the present invention is to provide a semiconductor device.
Another object of the present invention is to provide a semiconductor device having excellent uniformity of patterns.
Another object of the present invention is to provide a semiconductor device having a protective film on the side of the metal gate electrode.
Another object of the present invention is to provide a semiconductor device having an air gap.
Another object of the present invention is to provide a method for manufacturing a semiconductor device.
Another object of the present invention is to provide a method of forming a pattern of a semiconductor device having excellent uniformity.
Another object of the present invention is to provide a method of manufacturing a semiconductor device including patterns having a double protective film.
Another object of the present invention is to provide a method for preventing a conductive pattern of a semiconductor device from being damaged in an etching process.
Another object of the present invention is to provide a method for preventing by-products of a conductive pattern of a semiconductor device from being generated in an etching process.
The various problems to be solved by the present invention are not limited to the above-mentioned problems, and other problems not mentioned herein will be fully understood by those skilled in the art from the following description.
The semiconductor device manufacturing method according to the technical idea of the present invention for solving the above problems, sequentially forming a first insulating film, a first conductive film, a dielectric film, a second conductive film, a metal film and a hard mask film on a substrate Patterning the hard mask layer to form a hard mask pattern, and patterning the metal layer using the hard mask pattern as a patterning mask to form a metal gate electrode having exposed sides, and on the exposed side of the metal gate electrode A first passivation layer is formed, and the second conductive layer is patterned using the hard mask pattern as a patterning mask to form a second gate electrode having exposed side surfaces, and a second passivation layer on the exposed side surface of the second gate electrode. And the dielectric film and the first conductive film are patterned using the hard mask pattern as a patterning mask. And forming a dielectric pattern and a first gate electrode to form gate structures.
The forming of the hard mask layer may include forming a first hard mask layer on the metal layer, and forming a second hard mask layer on the first hard mask layer.
The first passivation layer is vertically aligned with an upper surface and a side surface of the second hard mask pattern, a side surface of the first hard mask pattern, a side surface of the metal gate electrode, a surface of the second conductive layer, and side surfaces of the metal gate electrode. Vertical surfaces can be conformally covered.
The second passivation layer conforms to a top surface and a side surface of the second hard mask pattern, a side surface of the first hard mask pattern, a side surface of the first passivation layer pattern, a side surface of the second gate electrode, and an exposed top surface of the dielectric layer. Can be covered.
Forming the metal gate electrode may include removing a portion of the surface of the second conductive layer to recess it.
Forming the metal gate electrode may include partially removing side surfaces of the metal film.
Forming the first passivation layer removes portions formed on the top and side surfaces of the second hard mask pattern, the side surfaces of the first hard mask pattern, the side surfaces of the metal gate electrode, and the surface of the second conductive layer. And remaining portions formed on the sides of the metal gate electrodes.
Forming the first gate electrode may include removing all of the second passivation layer.
The method of manufacturing a semiconductor device according to the inventive concept may further include forming a second insulating layer pattern covering the gate structures, wherein the second insulating layer pattern may include side surfaces of the gate structures and an upper surface of the exposed substrate. And second insulating layer patterns formed on side surfaces and upper surfaces of the hard mask patterns of the adjacent gate structures may be physically connected to each other.
An air gap may be defined between the gate structures by the second insulating layer pattern.
The semiconductor device according to the inventive concept may provide a semiconductor device having uniform characteristics by forming patterns having excellent uniformity.
The semiconductor device according to the inventive concept may prevent the deterioration of characteristics of semiconductor devices by forming double protective layer patterns to prevent generation of by-products during etching of the conductive layers.
According to an aspect of the inventive concept, a semiconductor device may have a protective layer pattern formed thereon to prevent electrical deterioration of a device due to an electrical short or a coupling effect through electrical separation between fine gate electrodes of several tens of nm or less, and thus, the product to which the device is applied. Can improve the performance.
According to the semiconductor device of the inventive concept, by forming double protective layer patterns, the reliability of the device may be improved to increase the production yield of the product to which the device is applied.
Method of manufacturing a semiconductor device according to the technical idea of the present invention provides methods that can improve the productivity without burdening the existing process technology.
In addition, various effects of the technical features of the present invention will be added to the detailed description.
1 is a conceptual longitudinal cross-sectional view of a semiconductor device according to the inventive concept.
2 to 15 are conceptual longitudinal cross-sectional views illustrating a method of manufacturing a semiconductor device according to the inventive concept.
Configuration and manufacturing method according to the technical spirit of the present invention and the objects to be achieved through them will be clearly understood through the embodiments and drawings described below.
The embodiments described below are provided to enable those skilled in the art to easily convey and to practice the spirit of the present invention. Therefore, the technical idea of the present invention may be modified in various forms without being limited to the embodiments described below.
Shapes and sizes of the regions shown in the drawings described below are merely illustrated to facilitate understanding of the present invention and may be exaggerated for convenience and used in the specification of the present invention, examples and drawings. Etc. are used to help understand the technical idea and do not limit the scope of the present invention.
1 is a longitudinal cross-sectional view conceptually illustrating a semiconductor device in accordance with some example embodiments of the inventive concepts;
Referring to FIG. 1, a
The
The first
The
The
The
The
The
The
2 to 15 are longitudinal cross-sectional views illustrating a method of manufacturing a semiconductor device in accordance with some example embodiments of the inventive concepts.
2, a method of manufacturing a semiconductor device according to an embodiment of the inventive concept may include preparing a
Referring to FIG. 3, a method of manufacturing a semiconductor device according to an embodiment of the inventive concept may include forming a first insulating
Referring to FIG. 4, a method of manufacturing a semiconductor device according to an embodiment of the inventive concept may include forming a first
Referring to FIG. 5, a method of manufacturing a semiconductor device according to an embodiment of the inventive concept may include forming a
Referring to FIG. 6, a method of manufacturing a semiconductor device according to an embodiment of the inventive concept may include forming a second
Referring to FIG. 7, a method of manufacturing a semiconductor device according to an embodiment of the inventive concept may include forming a
Referring to FIG. 8, a method of manufacturing a semiconductor device according to an embodiment of the inventive concept may include forming a
9, a method of manufacturing a semiconductor device according to an embodiment of the inventive concept may include forming a
Referring to FIG. 10, a method of manufacturing a semiconductor device according to an embodiment of the inventive concept may include forming a
Referring to FIG. 11, a method of manufacturing a semiconductor device according to an embodiment of the inventive concept may include partially removing side surfaces of the
Referring to FIG. 12, a method of manufacturing a semiconductor device according to an embodiment of the inventive concept may include conformally forming a
Referring to FIG. 13, a method of manufacturing a semiconductor device according to an embodiment of the inventive concept may include forming a
Referring to FIG. 14, a method of manufacturing a semiconductor device according to an embodiment of the inventive concept may include conformally forming a
Referring to FIG. 15, a method of manufacturing a semiconductor device according to an embodiment of the inventive concept may include forming a
Referring back to FIG. 1, the method of manufacturing a semiconductor device according to an embodiment of the inventive concept may include forming a second insulating
While the present invention has been described in connection with what is presently considered to be practical exemplary embodiments, it is to be understood that the invention is not limited to the disclosed embodiments, but, on the contrary, It will be understood. Therefore, it should be understood that the embodiments described above are exemplary in all respects and not restrictive.
10: semiconductor device 11: gate structures
d1: gate line width d2: gate separation distance
d3: metal gate line width 100: substrate
101: first insulating
102: first
103:
103b:
104: second
105:
106:
106b: second hard mask film 107: first protective film
107a: first protective film pattern 108: second protective film
109: second insulating film pattern 110: air gap
113:
113b:
116:
116b: second hard mask pattern
Claims (10)
Patterning the hard mask layer to form a hard mask pattern,
Patterning the metal layer using the hard mask pattern as a patterning mask to form a metal gate electrode with exposed side surfaces,
Forming a first passivation layer on the exposed side surface of the metal gate electrode,
Patterning the second conductive layer using the hard mask pattern as a patterning mask to form a second gate electrode with exposed side surfaces,
Forming a second passivation layer on the exposed side of the second gate electrode, and
And forming a gate structure by forming the dielectric pattern and the first gate electrode by patterning the dielectric layer and the first conductive layer using the hard mask pattern as a patterning mask.
Forming the hard mask film,
Forming a first hard mask film on the metal film, and
A method of manufacturing a semiconductor device comprising forming a second hard mask film on the first hard mask film.
The first protective film,
Conformal top surfaces and side surfaces of the second hard mask pattern, side surfaces of the first hard mask pattern, side surfaces of the metal gate electrode, surfaces of the second conductive layer, and vertical surfaces aligned vertically with side surfaces of the metal gate electrode. Method for manufacturing a semiconductor device to be covered.
The second protective film,
A semiconductor device conformally covering top and side surfaces of the second hard mask pattern, side surfaces of the first hard mask pattern, side surfaces of the first passivation layer pattern, side surfaces of the second gate electrode, and an exposed top surface of the dielectric layer. Manufacturing method.
Forming the metal gate electrode,
And removing a portion of the surface of the second conductive film to recess it.
Forming the metal gate electrode,
And partially removing the side surface of the metal film.
Forming the first protective film,
The portions formed on the top and side surfaces of the second hard mask pattern, the side surfaces of the first hard mask pattern, the side surfaces of the metal gate electrode, and the surface of the second conductive layer are removed and formed on the side surfaces of the metal gate electrode. A method of manufacturing a semiconductor device comprising leaving a portion.
Forming the first gate electrode,
A method of manufacturing a semiconductor device comprising removing all of the second protective film.
The method may further include forming a second insulating layer pattern covering the gate structures.
The second insulating film pattern,
Covering side surfaces of the gate structures and an upper surface of the exposed substrate, and
And a second insulating layer pattern formed on side surfaces and top surfaces of the hard mask patterns of the adjacent gate structures.
And an air gap is defined between the gate structures by the second insulating layer pattern.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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KR1020120003561A KR20130082374A (en) | 2012-01-11 | 2012-01-11 | Methods of fabricating semiconductor devices |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020120003561A KR20130082374A (en) | 2012-01-11 | 2012-01-11 | Methods of fabricating semiconductor devices |
Publications (1)
Publication Number | Publication Date |
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KR20130082374A true KR20130082374A (en) | 2013-07-19 |
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Family Applications (1)
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KR1020120003561A KR20130082374A (en) | 2012-01-11 | 2012-01-11 | Methods of fabricating semiconductor devices |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2022007521A1 (en) * | 2020-07-10 | 2022-01-13 | 长鑫存储技术有限公司 | Preparation method for semiconductor structure and semiconductor structure |
US11935925B2 (en) | 2020-07-10 | 2024-03-19 | Changxin Memory Technologies, Inc. | Method for manufacturing semiconductor structure and semiconductor structure |
-
2012
- 2012-01-11 KR KR1020120003561A patent/KR20130082374A/en not_active Application Discontinuation
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2022007521A1 (en) * | 2020-07-10 | 2022-01-13 | 长鑫存储技术有限公司 | Preparation method for semiconductor structure and semiconductor structure |
US11935925B2 (en) | 2020-07-10 | 2024-03-19 | Changxin Memory Technologies, Inc. | Method for manufacturing semiconductor structure and semiconductor structure |
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