KR20130079804A - White light emitting device, display apparatus and illumination apparatus - Google Patents
White light emitting device, display apparatus and illumination apparatus Download PDFInfo
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- KR20130079804A KR20130079804A KR1020120000520A KR20120000520A KR20130079804A KR 20130079804 A KR20130079804 A KR 20130079804A KR 1020120000520 A KR1020120000520 A KR 1020120000520A KR 20120000520 A KR20120000520 A KR 20120000520A KR 20130079804 A KR20130079804 A KR 20130079804A
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/1336—Illuminating devices
- G02F1/133615—Edge-illuminating devices, i.e. illuminating from the side
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/50—Wavelength conversion elements
- H01L33/501—Wavelength conversion elements characterised by the materials, e.g. binder
- H01L33/502—Wavelength conversion materials
- H01L33/504—Elements with two or more wavelength conversion materials
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- Microelectronics & Electronic Packaging (AREA)
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- Chemical & Material Sciences (AREA)
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- Manufacturing & Machinery (AREA)
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- Optics & Photonics (AREA)
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Abstract
According to an aspect of the present invention, a blue light emitting diode emitting blue light having a peak wavelength of 430 to 460 nm, a first wavelength conversion material excited by the blue light to emit green light, and red light excited by the blue light White light obtained from the mixture of the light excited with the second wavelength conversion material, wherein the blue light is excited, the first peak wavelength in the wavelength band of 615 to 650 nm and the second peak wavelength in the wavelength band of 525 to 545 nm. And a lowest relative intensity between the first and second peak wavelengths is 0.08 or less of the relative intensity of the blue peak.
Description
BACKGROUND OF THE
In general, the phosphor material for wavelength conversion is used as a material for converting specific wavelength light of various light sources into the desired wavelength light. In particular, since light emitting diodes among various light sources can be advantageously applied as LCD backlights, automobile lights, and home lighting devices due to low power driving and excellent light efficiency, phosphor materials have recently been spotlighted as a core technology for manufacturing white light emitting devices.
In general, white light emitting devices are manufactured by applying one or more phosphors (eg, red, yellow or green) to short wavelength LED chips such as blue or ultraviolet light. The white light thus obtained needs to satisfy various color characteristics required in a display or an illumination device. These color characteristics may vary greatly depending on the type of phosphor and combinations thereof.
For example, better color reproducibility can be expected when using two or more phosphors (eg, a combination of red phosphors and one or more other phosphors) rather than a single phosphor (e.g. yellow phosphors). On the other hand, there is a problem that the visibility is lowered as well as the efficiency is lower than when using the yellow phosphor.
On the other hand, since white light emitting devices using LEDs are exposed to high temperature conditions, reliability problems such as temperature stability of phosphors used are important. This temperature stability problem can be a big problem at high power usage conditions. Therefore, the selection of the type of phosphor considering these conditions is required.
In the art, there is a demand for an excellent white light emitting device capable of satisfying color characteristics for natural white light with excellent color reproducibility, a display device and an illumination device using the same.
According to an aspect of the present invention, a blue light emitting diode emitting blue light having a peak wavelength of 430 to 460 nm, a first wavelength conversion material excited by the blue light to emit green light, and red light excited by the blue light A second wavelength converting material comprising a second wavelength converting material which emits light, wherein the white light obtained from the mixture of the excited light together with the blue light has a second peak wavelength in at least the wavelength range of 615-650 nm and the first peak wavelength in the wavelength band of 525-545 nm. And a lowest relative intensity between the first and second peak wavelengths is 0.08 or less of the relative intensity of the blue peak.
Preferably, the first wavelength converting material includes at least one of β-SiAlON phosphor, (Ba, Sr) SiO 4 : Eu phosphor, SrGa 2 S 4 : Eu phosphor, and semiconductor quantum dots, and the second wavelength converting material Silver includes at least one of a sulfide-based phosphor, a fluoride-based phosphor, and a semiconductor quantum dot.
The half value width of the green light may be 60 nm or less, and the half value width of the red light may be 110 nm or less.
The color reproducibility of the white light may be preferably 90% or more relative to the NTSC area, and more preferably 95% or more relative to the NTSC area.
Another aspect of the present invention includes an LED light source module and an image display panel for irradiating light from the LED light source module and displaying an image, wherein the LED light source module is mounted on a circuit board and the circuit board. It provides a display device comprising at least one white light emitting device described above.
Another aspect of the invention, the LED light source module, and disposed above the LED light source module, the diffusion unit for uniformly diffusing the light incident from the LED light source module; includes, the LED light source module, the circuit Provided is a lighting device comprising a substrate and at least one white light emitting device mounted on the circuit board.
By lowering the peak intensity of the color mixing region, color reproducibility is improved, and in the display device, the LCD transmittance can be further improved. In particular, by selecting a specific combination of the wavelength conversion material can be more effectively improved color reproducibility while exhibiting the desired spectral characteristics.
1 is a schematic view showing a white light emitting device according to an embodiment of the present invention.
2 shows an example of a spectrum of white light emitted from a white light emitting device according to an embodiment of the present invention.
3A shows a spectrum of white light emitted from a white light emitting device according to an embodiment of the present invention (Example 1).
3B shows a spectrum of white light emitted from a white light emitting device according to a comparative example (Comparative Example 1) outside the scope of the present invention.
4A and 4B show a spectrum of white light emitted from a white light emitting device according to another embodiment of the present invention (Examples 2A and 2B).
5A and 5B show a spectrum of white light emitted from a white light emitting device according to another embodiment of the present invention (Examples 3A and 3B).
6A and 6B show a spectrum of white light emitted from a white light emitting device according to another embodiment of the present invention (Examples 4A and 4B).
7A and 7B show a spectrum of white light emitted from a white light emitting device according to another embodiment (Examples 5A and 5B) of the present invention.
8 shows a spectrum of white light emitted from a white light emitting device according to a comparative example (Comparative Example 2) outside the scope of the present invention.
9A-9C are schematic diagrams each illustrating a white light emitting device according to various embodiments of the present invention.
Fig. 10 is a schematic diagram showing a white light emitting device according to a specific embodiment (including quantum dots) of the present invention.
11A and 11B illustrate various types of backlight units that may be employed in the display device according to the present invention.
12 is an exploded perspective view showing an LCD display device according to an embodiment of the present invention.
13A to 13C are cross-sectional views illustrating various types of backlight units that may be employed in the display device according to the present invention.
Hereinafter, various embodiments of the present invention will be described in more detail with reference to the accompanying drawings.
1 is a schematic view showing a white light emitting device according to an embodiment of the present invention.
The white
The
The
In the present embodiment, the blue light of the blue
As shown in FIG. 2, the lowest relative intensity RG between the first and second peak wavelengths G and R may be 0.08 or less of the relative intensity of the blue light peak B. FIG. In the present specification, the wavelength region between the first and second peak wavelengths G and R is also referred to as a “red and green mixed region” or a “color mixed region”.
As in the present embodiment, color reproducibility can be greatly improved by lowering the relative intensity RG corresponding to the mixed region of red and green to a level of 0.08 or less. Furthermore, in the display device, the LCD transmittance can be greatly improved, and as a result, the efficiency can be increased.
In general, since the mixed region of red and green overlaps each converted light by the first and second wavelength converting materials, the intensity in the region is set to 0.08 or less than the relative intensity B of blue light. It is not easy to do this, but it can be implemented by a combination of specific wavelength converting materials. In this respect, the condition of the wavelength conversion material employed in the present invention may be specified by the half width.
Preferably, the first wavelength conversion material includes at least one of β-SiAlON phosphor, (Ba, Sr) SiO 4 : Eu phosphor, SrGa 2 S 4 : Eu phosphor, and semiconductor quantum dots, and the second wavelength conversion The material may include at least one of a sulfide-based phosphor, a fluoride-based phosphor, and a semiconductor quantum dot. The half value width of the green light may be 60 nm or less, and the half value width of the red light may be 110 nm or less. The color reproducibility of the white light may be preferably 90% or more relative to the NTSC area, and more preferably 95% or more relative to the NTSC area.
Conditions for the white light emitting device according to various embodiments of the present invention, as well as operations and effects thereof, will be described with reference to the following embodiments.
< Example 1 >
First, in Example 1, a white light emitting device was manufactured using a blue light emitting diode having a peak wavelength of 455 nm, using CdSe / InP quantum dots as a green wavelength converting material and InP / ZnS quantum dots as a red wavelength converting material.
Light conversion characteristics (peak and half width) of each wavelength conversion material used in Example 1 are shown in Table 1.
< Comparative Example 1 >
In Comparative Example 1, a white light-emitting device was fabricated using a blue light emitting diode having a peak wavelength of 455 nm similar to that of Example 1, using CdSe / InP quantum dots as a green wavelength converting material and InP / ZnS quantum dots as a red wavelength converting material. Prepared.
Light conversion characteristics (peak and half width) of each wavelength conversion material used in Comparative Example 1 are shown in Table 1.
In addition to Example 1, the spectrum of white light of the white light emitting device manufactured according to Comparative Example 1 is shown in Figs. 3A and 3B, respectively.
In each spectrum, the lowest relative intensity between green and red is examined. As shown in FIG. 3A, the lowest relative intensity RG1 in the color mixing region of the white light emitting device according to
However, in contrast, in the case of Comparative Example 1, the lowest relative intensity RG (1) in the color mixing region is relatively out of the range of the present invention by 0.19 compared to the relative intensity of blue light, as shown in FIG. 3B. High.
Next, color reproducibility and transmittance of the LCD panel were measured, and the measured results are shown in Table 1 below. Here, color reproducibility is expressed as% of NTSC area.
Of NTSC
As shown in Table 1, the color reproducibility of Example 1, which was low in the color mixing region, was found to be considerably high at 105%, while in Comparative Example 1, it was only 82%.
In addition, when looking at the transmission loss ratio of the LC panel, in Comparative Example 1 was only 4.61%, but in Example 1 was 4.80%, 4.82% was significantly higher, showing a 4.5% improvement compared to Comparative Example 1 respectively. It was. Through the improvement of the LCD transmittance can be expected to improve the actual light efficiency.
Next, in order to examine a specific embodiment of the present invention, more embodiments were performed according to a combination of various wavelength converting materials.
< Example 2 A and 2B>
First, in Examples 2A and 2B, the β-sialon phosphor was used in the same manner as the green wavelength converting material together with the blue light emitting diode having the peak wavelength of 443 nm. Phosphor was used.
As such, a white light emitting device using different red phosphors (sulfide-based / fluoride-based phosphors) was manufactured.
The light conversion properties (peaks) of the wavelength conversion materials used in Examples 2A and 2B are shown in Table 2, respectively.
< Example 3 A and 3B>
In Examples 3A and 3B, blue light emitting diodes having a peak wavelength of 443 nm were used similarly to Examples 2A and 2B, but BaSiO 4 phosphors were similarly used as green wavelength converting materials. In addition, in Example 3A and 3B, a white light emitting device was manufactured using different phosphors of CaS and CaF as red wavelength converting materials, respectively.
The light conversion properties (peaks) of the wavelength conversion materials used in Examples 3A and 3B are shown in Table 2, respectively.
< Example 4 A and 4B>
In Examples 4A and 4B, blue light emitting diodes having a peak wavelength of 443 nm were used similarly to Examples 2A and 2B, but the same SrGa 2 S 2 phosphor was used as the green wavelength converting material. In addition, Example 4A and 4B manufactured white light emitting devices using different phosphors of CaS and CaF as red wavelength converting materials, respectively.
The photoconversion characteristics (peaks) of the wavelength converting materials used in Examples 4A and 4B, respectively, are shown in Table 2.
< Example 5 A and 5B>
In Examples 5A and 5B, blue light emitting diodes having a peak wavelength of 443 nm were used similarly to Examples 2A and 2B, but the same CdSe core quantum dots were used as green wavelength converting materials. In Example 5A and 5B, a white light emitting device was manufactured using different phosphors of CaS and CaF as red wavelength converting materials, respectively.
The photoconversion characteristics (peaks) of the wavelength converting materials used in Examples 5A and 5B, respectively, are shown in Table 2.
< Comparative Example 2 >
In Comparative Example 2, white light emission was performed using a β-sialon phosphor as a green wavelength converting material and a CaAlSiN 3 phosphor as a red wavelength converting material, together with a blue light emitting diode having a peak wavelength of 443 nm similar to those of Examples 2A and 2B. The device was prepared.
The light conversion characteristics (peaks) of each wavelength conversion material used in Comparative Example 2 are shown in Table 2.
In addition to Examples 2A, 2B and 5A, 5B, the spectra for white light of the white light emitting device manufactured according to Comparative Example 2 are shown in FIGS. 4A, 4B to 8, respectively.
In each spectrum, the lowest relative intensity between green and red is examined.
As shown in Figs. 4A and 4B, the lowest relative intensities RG2A and RG2B in the color mixing region of the white light emitting device according to Embodiments 2A and 2B are about 0.08 and 0.065 in comparison with the relative intensities of blue light. As shown in Figs. 5A and 5B, the lowest relative intensities RG3A and RG3B in the color mixing region of the white light emitting device according to Embodiments 3A and 3B are about 0.08 and 0.07 compared with the relative intensities of blue light.
6A and 6B, the lowest relative intensities RG4A and RG4B in the color mixing region of the white light emitting device of Example 4A and 4B are about 0.065 and 0.05 in comparison with the relative intensities of blue light. As shown in FIGS. 7A and 7B, the lowest relative intensities RG5A and RG5B in the color mixing region of the white light emitting device according to
However, in contrast, in Comparative Example 2, the lowest relative intensity RG (2) in the color mixing region was relatively high to deviate from the scope of the present invention by about 0.14 compared to the relative intensity of blue light.
The color reproducibility of each of Examples 2A, 2B to 5A, 5B and Comparative Example 2 was measured, and the measurement results of color reproducibility are shown in Table 3 above.
In Comparative Example 2, the color reproducibility was relatively low at 74%. However, in the case of Example, the color reproducibility was higher than 90%, more than 95%, and was particularly high when the semiconductor quantum dots were mixed.
In this way, color reproducibility can be greatly improved by lowering the relative intensity RG corresponding to the mixed region of red and green to a level of 0.08 or less. Furthermore, in the display device, the LCD transmittance can be greatly improved, and as a result, the efficiency can be increased.
The present invention can be implemented in various forms of light emitting devices, unlike the form shown in FIG. This embodiment is illustrated in Figures 9A-9C. Hereinafter, various examples and applications of the white light emitting device according to the present invention will be described with reference to FIGS. 9A to 9C.
The white
The white
The
In the embodiment shown in Fig. 9B, a form in which plural kinds of phosphors are mixed and dispersed in one resin packaging portion region is illustrated, but other structures can be variously modified. At least one phosphor may be provided in another layer structure to separate the same.
Similarly to the previous embodiment, the white
On the
As such, the first and second wavelength converting materials may be applied in various ways of the white light emitting device. In the case of semiconductor quantum dots, however, the characteristics thereof are greatly reduced in contact with the atmosphere, and therefore it is preferable to employ a separate sealed structure. Fig. 10 is a schematic diagram showing a white light emitting device according to a specific embodiment (including quantum dots) of the present invention.
The white light emitting device 50 shown in FIG. 10 includes a
The
This embodiment includes a sealing
11A and 11B illustrate various types of backlight units that may be employed in the display device according to the present invention.
Referring to FIG. 11A, an edge
The edge
In this embodiment, the LED
As shown in FIG. 11A, a reflecting
Referring to FIG. 11B, a
The direct
The
The LED
12 is an exploded perspective view showing a display device according to an embodiment of the present invention.
The
In the present exemplary embodiment, the
In addition, according to a demand for various optical properties, the
The LED
As such, the combination of the above-described wavelength converting material may be applied to various types of LED light source modules by applying the white light emitting device having various mounting structures. The light emitting device package or the light source module including the same may be applied to various types of display devices or lighting devices.
In addition to the embodiments described above, the wavelength conversion material may not be directly disposed in the package in which the LED is located, but may be disposed in other components of the backlight unit to convert light. This embodiment is illustrated in Figures 13A-13C.
First, as illustrated in FIG. 13A, the direct
The
Here, the LED
13B and 13C illustrate various types of edge type backlight units that may be employed in the display device of the present invention.
The edge
The edge
As such, the combination of the wavelength conversion material according to the present invention may not be directly applied to the LED light source, but may be implemented in a form applied to other devices such as a backlight unit.
The lighting apparatus according to the present invention includes a diffusion unit disposed above the LED light source module and uniformly diffusing the light incident from the LED light source module, wherein the LED light source module includes a circuit board and the circuit. At least one white light emitting device mounted on a substrate and described above is provided.
The present invention is not limited to the above-described embodiments and the accompanying drawings, but is intended to be limited only by the appended claims. It will be apparent to those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims. something to do.
Claims (9)
A first wavelength conversion material excited by the blue light to emit green light; And
A second wavelength conversion material excited by the blue light and emitting red light,
White light obtained from the mixture of the light excited with the blue light has at least a first peak wavelength in the wavelength band of 525-545 nm and a second peak wavelength in the wavelength band of 615-650 nm,
The lowest relative intensity between the first and second peak wavelength is less than 0.08 of the relative intensity of the blue peak.
The first wavelength converting material includes at least one of β-SiAlON phosphor, (Ba, Sr) SiO 4 : Eu phosphor, SrGa 2 S 4 : Eu phosphor, and a semiconductor quantum dot,
The second wavelength conversion material may include at least one of a sulfide phosphor, a fluoride phosphor, and a semiconductor quantum dot.
And a half width of the green light is 60 nm or less, and a half width of the red light is 110 nm or less.
The white light emitting device, characterized in that the color reproducibility of the white light is more than 90% of the NTSC area.
The white light emitting device, characterized in that the color reproducibility of the white light is more than 95% of the NTSC area.
It is irradiated with light of the LED light source module, and comprises an image display panel for displaying an image,
The LED light source module, the display device, characterized in that it comprises a circuit board and at least one white light emitting device according to any one of claims 1 to 5 mounted on the circuit board.
It is disposed on the LED light source module, the diffusion unit for uniformly diffusing the light incident from the LED light source module; includes;
The LED light source module, the illumination device, characterized in that it comprises a circuit board and at least one white light emitting device according to any one of claims 1 to 5 mounted on the circuit board.
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KR1020120000520A KR20130079804A (en) | 2012-01-03 | 2012-01-03 | White light emitting device, display apparatus and illumination apparatus |
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KR1020120000520A KR20130079804A (en) | 2012-01-03 | 2012-01-03 | White light emitting device, display apparatus and illumination apparatus |
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Cited By (8)
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KR20160000535A (en) * | 2014-06-24 | 2016-01-05 | (주)이코루미 | Natural light LED package and lighting device comprising the same |
KR20160082381A (en) * | 2014-12-26 | 2016-07-08 | 삼성전자주식회사 | Method of manufacturing fluoride phosphor, light emitting device, display apparatus and illumination apparatus |
KR20180047146A (en) * | 2016-10-31 | 2018-05-10 | 엘지디스플레이 주식회사 | Oxide phosphor, light emitting device and display device using the same |
US10020428B2 (en) | 2013-10-02 | 2018-07-10 | Glbtech Co., Ltd. | White light emitting device having high color rendering |
US10228584B2 (en) | 2014-12-29 | 2019-03-12 | Samsung Electronics Co., Ltd. | Light source, and back light unit and liquid crystal display including the light source |
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2012
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US10020428B2 (en) | 2013-10-02 | 2018-07-10 | Glbtech Co., Ltd. | White light emitting device having high color rendering |
KR20160000535A (en) * | 2014-06-24 | 2016-01-05 | (주)이코루미 | Natural light LED package and lighting device comprising the same |
JP2021193460A (en) * | 2014-10-30 | 2021-12-23 | 東洋紡株式会社 | Liquid crystal display device and polarizing plate |
KR20160082381A (en) * | 2014-12-26 | 2016-07-08 | 삼성전자주식회사 | Method of manufacturing fluoride phosphor, light emitting device, display apparatus and illumination apparatus |
US10228584B2 (en) | 2014-12-29 | 2019-03-12 | Samsung Electronics Co., Ltd. | Light source, and back light unit and liquid crystal display including the light source |
US11226447B2 (en) | 2014-12-29 | 2022-01-18 | Samsung Electronics Co., Ltd. | Light source, and back light unit and liquid crystal display including the light source |
KR20180047146A (en) * | 2016-10-31 | 2018-05-10 | 엘지디스플레이 주식회사 | Oxide phosphor, light emitting device and display device using the same |
US10831056B2 (en) | 2017-10-17 | 2020-11-10 | Samsung Display Co., Ltd. | Display device |
CN111788703A (en) * | 2018-02-26 | 2020-10-16 | 京瓷株式会社 | Light emitting device and lighting device |
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