KR20130014950A - Manufacturing method of semiconductor light emitting device - Google Patents
Manufacturing method of semiconductor light emitting device Download PDFInfo
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- KR20130014950A KR20130014950A KR1020110076721A KR20110076721A KR20130014950A KR 20130014950 A KR20130014950 A KR 20130014950A KR 1020110076721 A KR1020110076721 A KR 1020110076721A KR 20110076721 A KR20110076721 A KR 20110076721A KR 20130014950 A KR20130014950 A KR 20130014950A
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- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/50—Wavelength conversion elements
- H01L33/501—Wavelength conversion elements characterised by the materials, e.g. binder
- H01L33/502—Wavelength conversion materials
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
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- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/02—Bonding areas; Manufacturing methods related thereto
- H01L2224/04—Structure, shape, material or disposition of the bonding areas prior to the connecting process
- H01L2224/05—Structure, shape, material or disposition of the bonding areas prior to the connecting process of an individual bonding area
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- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/42—Wire connectors; Manufacturing methods related thereto
- H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
- H01L2224/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
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- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
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- H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
- H01L2224/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
- H01L2224/484—Connecting portions
- H01L2224/48463—Connecting portions the connecting portion on the bonding area of the semiconductor or solid-state body being a ball bond
- H01L2224/48465—Connecting portions the connecting portion on the bonding area of the semiconductor or solid-state body being a ball bond the other connecting portion not on the bonding area being a wedge bond, i.e. ball-to-wedge, regular stitch
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
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Abstract
Description
The present invention relates to a method for manufacturing a semiconductor light emitting device, and more particularly, to a method for manufacturing a semiconductor light emitting device having a wavelength conversion layer.
In general, a semiconductor light emitting diode (Semiconductor light emitting diode) is a device used to transmit a signal converted from the electrical energy into the infrared, visible light or light by using the characteristics of the compound semiconductor, the current group III-V compound semiconductor Light emitting diodes using are widely commercialized.
Each chip constituting the light emitting device may be formed by growing a semiconductor layer on one wafer and then separating the wafer into chips by a cutting process. A process of forming a wavelength conversion layer including a wavelength conversion material such as phosphor particles and quantum dots is formed on the upper surface of each separated light emitting device.
In this case, in order to perform the process of forming the wavelength conversion layer on the upper surface of the individual devices, a process of aligning each chip is performed separately.
In addition, in order to improve the color coordinate yield, it is necessary to keep the thickness of the wavelength conversion layer constant. However, the wafer is bent due to the difference in thermal expansion coefficient with the epitaxial, and thus, the wafer has a predetermined curvature on the surface to which the wavelength conversion layer is applied, thus making it difficult to form a wavelength conversion layer having a uniform thickness. . Such nonuniform thickness of the wavelength conversion layer can cause a large variation in the color difference index indicating the difference in color.
This deviation in color difference index may be caused by the epitaxial itself. In other words, even in the epitaxial growth process, the difference in the growth conditions depending on the wafer region causes a difference in the composition or thickness of the active layer, so that the primary wavelength light of each light emitting device region may have a different spectrum according to the position of the wafer. . The color difference index problem may also occur due to the problem of epitaxial itself.
One of the objectives of the present invention is to provide a novel method of manufacturing a semiconductor light emitting device which can form a wavelength conversion layer with a uniform thickness so that the color difference index can be managed in a certain allowable range.
In order to realize the above technical problem, an aspect of the present invention,
Providing a wafer having a semiconductor stack for a plurality of light emitting devices, wherein a plurality of electrodes for the plurality of light emitting devices are positioned on the semiconductor stack; and a structure having a predetermined height on the plurality of electrodes Forming a layer, forming a wavelength conversion layer having at least two layers sequentially stacked on the semiconductor laminate, and polishing the wavelength conversion layer so that the wavelength conversion layer has a desired thickness; And at least two layers formed on the semiconductor laminate and having a wavelength converting material so as to serve as a main wavelength converting portion, and formed on the first layer and serving as a thickness adjusting portion. Provided is a method of manufacturing a light emitting device comprising a second layer having a transmittance with respect to a wavelength of light to be emitted from the first layer.
Preferably, the first layer may be formed to have a height lower than the top of the structure. In this case, in the polishing of the wavelength conversion layer, only a portion corresponding to the second layer may be removed.
In a specific embodiment, the forming of the wavelength conversion layer may be forming the wavelength conversion layer to cover the structure. In this case, the polishing of the wavelength conversion layer may form the wavelength conversion layer to expose the structure.
The polishing of the wavelength conversion layer may include polishing the wavelength conversion layer to have a planarized top surface with an upper surface of the structure.
The first layer may be a light transmissive resin layer containing the wavelength conversion material.
In this case, the second layer may be a light transmissive resin layer containing the wavelength conversion material at a content concentration lower than the wavelength conversion material content concentration of the first layer. The concentration of the wavelength conversion material in the second layer may be less than 30% of the concentration of the wavelength conversion material in the first layer.
Further, the second layer may be a light transmissive resin layer not containing the wavelength conversion material.
The light transmissive resin layer of the second layer may be made of the same material as the light transmissive resin layer of the first layer.
If necessary, the wavelength conversion layer may further include a light scattering powder. In this case, the light scattering powder may be contained in the second layer of the wavelength conversion layer.
In addition, the wavelength conversion layer may include at least one third layer containing an optical material different from the optical material contained in at least one of the first and second layers.
In a particular example, the forming of the wavelength converting layer may include applying a wavelength converting material for correction to at least a portion of the region on the first layer between forming the first layer and forming the second layer. It may include the step.
In this case, the wavelength converting material for correction may have a light emission color different from that of the wavelength converting material contained in the first layer.
Preferably, the wavelength conversion material for correction may be applied to have a height lower than the top of the structure.
In one embodiment, after polishing the wavelength conversion layer, the method may further include removing the structure to expose the electrode.
In this case, the structure may be formed of photoresist. Removing the structure may be a step of peeling the structure by applying a flux to the exposed structure.
In other embodiments, the structure can be a conductive bump. The remaining conductive bumps can be used as contacts in the final product.
Before forming the wavelength conversion layer, the method may further include half dicing a wafer on which the semiconductor stack is formed such that at least the semiconductor stack is separated into individual light emitting device units.
In this case, forming the wavelength converting layer includes forming the wavelength converting layer so that a wavelength converting material is filled in the half diced region, and cutting the wafer includes: And cutting the wafer so that the wavelength conversion layer is maintained in the side region of the light emitting device obtained by Xing.
The wafer is a conductive wafer, and the plurality of electrodes may be formed such that one electrode is positioned in each light emitting device region.
Forming the wavelength conversion layer may include screen printing, spin coating, dispensing, spray coating, tape attaching, electrophoresis, deposition process, It may be performed by at least one of sputtering and compression molding.
According to another aspect of the present invention, there is provided a light transmissive wafer having a semiconductor laminate for a plurality of light emitting devices, applying a light transmissive resin layer to a lower surface of the light transmissive wafer, and having the planarized surface. A method of manufacturing a light emitting device includes polishing a resin layer and forming a wavelength conversion layer containing a wavelength conversion material on the planarized surface.
The wafer is an insulating substrate, and the plurality of electrodes may be formed such that at least two electrodes are positioned in the light emitting device region.
In one aspect of the present invention, by forming the wavelength conversion layer into at least two layers having different wavelength conversion material containing conditions, it is possible to effectively reduce the deviation of the color difference index that may be caused by the thickness variation of the wavelength conversion layer. In particular, in the case where the wafer is thin, the difference in the thickness of the wavelength conversion layer is generated after the polishing process of the wavelength conversion layer. Therefore, the variation of the color variation according to the wafer area is effectively reduced by minimizing the thickness change of the main wavelength conversion part. You can.
In another aspect, the thickness of the wavelength conversion layer can be uniformly ensured by introducing a process for providing a flattening surface to reduce the influence of non-uniform surface conditions such as wafer bending.
1A to 1D are cross-sectional views of processes for describing a method of manufacturing a semiconductor light emitting device according to an embodiment of the present invention.
2A and 2B are sectional views of a subsequent process for explaining a method of manufacturing a semiconductor light emitting device according to one specific example of one embodiment of the present invention.
FIG. 3 is a cross-sectional view showing an example of a light emitting device equipped with the semiconductor light emitting device shown in FIG. 2B.
4 is a cross sectional view of a subsequent step for explaining a method of manufacturing a semiconductor light emitting device according to another specific example of one embodiment of the present invention;
FIG. 5 is a cross-sectional view illustrating an example of a light emitting device having the semiconductor light emitting device manufactured in FIG. 4.
6A to 6E are cross-sectional views of processes for explaining a method of manufacturing a semiconductor light emitting device according to another embodiment (half dicing application example) of the present invention.
7A and 7B are cross-sectional views of a subsequent process for explaining a method of manufacturing a semiconductor light emitting device according to one specific example of another embodiment of the present invention.
8 is a cross sectional view of a subsequent process for explaining a method of manufacturing a semiconductor light emitting device according to another specific example of another embodiment of the present invention;
9 and 10 are plan and side cross-sectional views showing an example of a semiconductor light emitting device that can be employed in the present invention.
Fig. 11 is a side cross-sectional view showing another example of a semiconductor light emitting element employable in the present invention.
12A to 12E are cross-sectional views of processes for describing an example of a method of manufacturing a semiconductor light emitting device as another aspect of the present invention.
13A-13D are process cross-sectional views illustrating the process of color correction that may be employed in certain embodiments of the present invention.
14 is a CIE color coordinate system illustrating the results of measuring whiteness for each LED chip at the wafer level.
Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings.
1A to 1D are cross-sectional views of processes for describing a method of manufacturing a semiconductor light emitting device according to an embodiment of the present invention.
As shown in FIG. 1A, a
The
In the present embodiment, the
Specifically, the semiconductor light emitting element employed in the present embodiment may be the light emitting structure shown in Figs.
In general, since the
Although the warping state shown in FIG. 1A is illustrated in the shape of the
As shown in FIG. 1B,
The
Preferably, the height of the
In addition, when the structure is to be removed as the
As shown in FIG. 1C, the
The
In a specific example, the
On the other hand, the
In this aspect, it may be preferable that the
Preferably, as in the present embodiment, the
In the case where both the first and second layers use the light transmissive resin layer, the light transmissive resin layer of the
The wavelength conversion material P employed in the present embodiment may be a phosphor or a quantum dot or a combination thereof. The wavelength conversion material may include yellow or yellowish orange together with yellow or red and green or red and green so that white light is obtained. The phosphor may be any one of a YAG-based, TAG-based, silicate-based, sulfide-based, or nitride-based nitride. As quantum dots, a nano crystal material exhibiting a quantum confinement effect, and includes Si-based nanocrystals, II-VI compound semiconductor nanocrystals, III-V compound semiconductor nanocrystals, and IV-VI compound semiconductors. It may be a nanocrystal. The resin layer may be at least one of epoxy, silicon, polystyrene, and acrylate.
If necessary, the
As shown in FIG. 1C, the thickness t1 of the
The
In this example, the
As shown in FIG. 1D, the
The
As such, even though the thickness variation of the
As described above, the structure employed in the present embodiment can be largely divided into the
2 and 3 illustrate a subsequent process of the type employed as the sacrificial pattern.
First, as shown in FIG. 2A, the
In the region O from which the sacrificial pattern is removed, an electrode may be exposed to provide a bonding region. The sacrificial pattern removing process may be performed by decomposing the
The sacrificial pattern removal process can be maintained almost intact without significantly damaging the polished
Subsequently, as shown in FIG. 2B, the
The process of separating the
Like the process according to the present embodiment, the
As described above, according to the present embodiment, even when the polishing process for exposing the
In addition, in this embodiment, since the surface of the deposited electrode is provided as it is without forming a separate conductive bump in the bonding region, as shown in FIG. 2, strong bonding strength can be ensured at the time of wire bonding. FIG. 2 is a cross-sectional view illustrating an example of a light emitting device having the semiconductor light emitting device manufactured in FIG. 1F.
Referring to FIG. 2, a semiconductor
In this embodiment, since the wire W is not connected to the
The
Unlike the previous example, the structure may be provided with a
As shown in Fig. 4, the resultant shown in Fig. 1D can be cut into each individual element unit. In the individually cut semiconductor light emitting device 10 ', the
In this structure, the exposed flat top surface of the
6A through 6E are cross-sectional views of processes for describing a method of manufacturing a semiconductor light emitting device according to one embodiment of the present invention.
As shown in FIG. 6A, the
As illustrated in FIG. 1A, since the
As shown in FIG. 6B, the
Through this process, the side surface of the
As shown in FIG. 6C, a
The
Preferably, the heights of the
As shown in FIG. 6D, the
The
In particular, in the present process, the
The
The
The
The
As shown in Fig. 6E, the
The
As described above, the structure employed in the present embodiment can be largely divided into the
7 and 8 illustrate the subsequent process of the type employed as the sacrificial pattern.
First, as shown in FIG. 7A, the
In the region O from which the sacrificial pattern is removed, an electrode may be exposed to provide a bonding region. The sacrificial pattern removing process may be performed by decomposing the
Subsequently, as shown in FIG. 7B, the
In the present cutting process, the
In the present embodiment, the
Further, in the present embodiment, the half dicing process is illustrated as being performed after the
As in the present embodiment, although the
As described above, according to the present embodiment, even if the polishing process for exposing the
Unlike the previous example, the structure may be provided with
As shown in Fig. 8, the resultant shown in Fig. 6E can be cut into each individual element unit. In the individually cut semiconductor light emitting device 10 ', the
9 and 10 are a plan view and a side cross-sectional view showing an example of a semiconductor light emitting element that can be employed in the present invention.
As shown in FIG. 9, the semiconductor
The
That is, the
On the other hand, the insulating
The
In addition, the
The second conductivity
Alternatively, unlike the light emitting device shown in FIG. 10, another
Referring to FIG. 11, in the
In the present embodiment, the
In the above embodiment, unlike the contact hole was connected to the conductive substrate, in the present embodiment, the
Accordingly, such a light emitting device can partially secure the light emitting area by forming a part of the first electrode on the light emitting surface and placing the remaining part under the active layer. Even when the current is applied, the current can be uniformly distributed, thereby alleviating the current concentration phenomenon in the high current operation.
As described above, the light emitting device shown in FIGS. 10 and 11 has first and second main surfaces facing each other, and the first and second conductive semiconductor layers providing the first and second main surfaces, respectively, and between them. A semiconductor laminate having an active layer formed thereon, a contact hole connected to a region of the first conductivity-type semiconductor layer from the second main surface through the active layer, and formed on a second main surface of the semiconductor laminate; It can be described as including a first electrode connected through the contact hole in one region of the conductive semiconductor layer, and a second electrode formed on the second main surface of the semiconductor laminate and connected to the second conductive semiconductor layer. have. Here, one of the first and second electrodes may have a structure that is drawn out in the lateral direction of the semiconductor laminate.
In another aspect of the present invention, it is possible to provide a wavelength conversion layer forming process of forming a flattened top surface by using a polishing process and forming a wavelength conversion portion having a uniform thickness using the flattened top surface. This embodiment can be described as an example applied in the manufacturing process of the flip chip light emitting device with reference to FIGS. 12A to 12G.
As shown in Fig. 12A, a
The
Therefore, the
As in the previous embodiment, since the
As shown in FIG. 12B, a light
The light
Then, as shown in Fig. 12C, the light
Finally, as illustrated in FIG. 12E, the semiconductor light emitting device having the desired flip chip structure may be provided by cutting the individual chip units. If necessary, the method may further include providing a wavelength conversion layer on the side of the device.
In various embodiments of the present disclosure, the method may include forming a separate at least one third layer in the wavelength conversion layer forming step.
If desired, additional third layers may be formed to assume various additional functions. For example, the third layer may be in charge of another emission color as a wavelength conversion part. As such, the third layer may include optical materials (wavelength converting materials, light scattering materials, light transmissive matrix materials, etc.) and other necessary optical materials contained in the first and second layers. On the other hand, the third layer may be used as a layer to protect the main wavelength conversion portion in the polishing process.
Similarly, certain embodiments of the invention include applying a wavelength converting material for correction to at least a portion of the region on the first layer between forming the first layer and forming the second layer. can do. This embodiment has been described with reference to FIGS. 13A-13D.
First, as shown in Fig. 13A, a
The
Next, as shown in FIG. 13B, a main
The main
Each chip located on each wafer is then directly measured by measuring the color characteristics of the white light emitted from the LED chip to which the wavelength conversion layer has already been applied, or based on information on the wavelength characteristics of the individual LED chips of the wafer manufactured under the same growth conditions. It can be determined whether they satisfy the desired target color characteristics (eg, color coordinates).
Referring to a specific example, as shown in FIG. 13C, as a result of color coordinate measurement for each individual chip, some chips c located in an area indicated by A, B, C, and D represent the target color coordinate area T. As shown in FIG. It can be understood that the off-color coordinate result is measured. The areas of A, B, C, and D that display chips outside the target color coordinate area are reflected in the color coordinate area indicated by the same letter together with the virtual wafer area WF in FIG.
The color coordinate difference according to the wafer region may be generated by the active layer having a different wavelength due to the difference in process conditions for each wafer region during the epitaxial growth process. Therefore, even when the wavelength conversion layer (
The formation process of the correction wavelength conversion portion is preferably performed before forming the thickness adjusting portion, which is the
First, as shown in FIG. 13C, a wavelength converting material for color correction may be selected and its amount may be determined according to whether the color correction obtained from the result of FIG. 14 is necessary or not. In addition, according to each region shown in FIG. 13C, a color correction process may be applied to chips of a certain region at once, but as shown in FIG. 13D, according to the color deviation of the individual chips C, more precise The
That is, when it is determined that color correction is necessary, the type and amount of phosphor required for the LED chip C to be color corrected are determined, and an additional
In addition, the chips located in the B, G, and D regions deviating from the target color coordinate region T may be appropriately combined with other phosphors. On the other hand, the amount of the selected phosphor may be appropriately selected based on the magnitude of the deviation, that is, the difference in the color coordinates.
After the color correction process is completed, the process of forming the light-transmissive resin layer corresponding to the above-described thickness adjusting unit may be performed, and the process of exposing the structure may be performed. This process may refer to the embodiment described above. Specifically, it will be apparent to those skilled in the art that the process of FIG. 2 or FIG. 4 together with FIGS. 1C-1D may advantageously employ the process for the subsequent process of this embodiment.
It is intended that the invention not be limited by the foregoing embodiments and the accompanying drawings, but rather by the claims appended hereto. It will be apparent to those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims. something to do.
Claims (27)
Forming a structure having a predetermined height on the plurality of electrodes;
Forming a wavelength conversion layer having at least two layers sequentially stacked on the semiconductor laminate; And
And polishing the wavelength conversion layer such that the wavelength conversion layer has a desired thickness.
The at least two layers are formed on the semiconductor laminate and have a first layer having a wavelength converting material so as to serve as a main wavelength converting portion, and are formed on the first layer and serve as a thickness adjusting portion to be emitted from the light emitting device. A light emitting device manufacturing method comprising a second layer having a transmittance with respect to the wavelength of light larger than the first layer.
The first layer is a light emitting device manufacturing method, characterized in that formed to have a lower height than the top of the structure.
In the polishing of the wavelength conversion layer, only a portion corresponding to the second layer is removed.
The forming of the wavelength conversion layer may include forming the wavelength conversion layer to cover the structure.
The polishing of the wavelength conversion layer is a step of forming the wavelength conversion layer to expose the structure.
The polishing the wavelength converting layer may include polishing the wavelength converting layer to have a planarized top surface with an upper surface of the structure.
The first layer is a light emitting device manufacturing method, characterized in that the light-transmitting resin layer containing the wavelength conversion material.
The second layer is a light emitting device manufacturing method, characterized in that the light-transmitting resin layer containing the wavelength conversion material at a lower concentration than the wavelength conversion material containing concentration of the first layer.
The wavelength conversion material-containing concentration of the second layer is a light emitting device manufacturing method, characterized in that less than 30% of the concentration of the wavelength conversion material of the first layer.
The second layer is a light emitting device manufacturing method, characterized in that the transparent resin layer containing no wavelength conversion material.
The light transmitting resin layer of the second layer is a light emitting device manufacturing method, characterized in that the light transmitting resin layer of the first layer is made of the same material.
The wavelength conversion layer is a light emitting device manufacturing method characterized in that it further comprises a light scattering powder.
The light scattering powder is a light emitting device manufacturing method, characterized in that contained in the second layer of the wavelength conversion layer.
The wavelength conversion layer may include at least one third layer containing an optical material different from the optical material contained in at least one of the first and second layers.
Forming the wavelength conversion layer,
And applying a wavelength converting material for correction to at least a portion of the region between the forming of the first layer and the forming of the second layer.
The wavelength conversion material for correction is a light emitting device manufacturing method characterized in that it has a different light emission color than the wavelength conversion material contained in the first layer.
The correction wavelength conversion material is a light emitting device manufacturing method, characterized in that applied to have a height lower than the top of the structure.
And after removing the wavelength converting layer, removing the structure so that the electrode is exposed.
The structure is a light emitting device manufacturing method, characterized in that formed with a photo resist.
Removing the structure is a method of manufacturing a light emitting device, characterized in that for removing the structure by applying a flux to the exposed structure.
The structure is a light emitting device manufacturing method characterized in that the conductive bump.
Before forming the wavelength conversion layer, further comprising half dicing a wafer on which the semiconductor stack is formed such that at least the semiconductor stack is separated into individual light emitting device units. .
The forming of the wavelength conversion layer may include forming the wavelength conversion layer such that a wavelength conversion material is filled in the half dicing region.
The cutting of the wafer may include cutting the wafer such that the wavelength conversion layer is maintained in a side region of the light emitting device obtained by the half dicing.
The wafer is a conductive wafer, the plurality of electrodes is a semiconductor light emitting device manufacturing method, characterized in that formed in each of the light emitting device area one electrode.
Forming the wavelength conversion layer may include screen printing, spin coating, dispensing, spray coating, tape attaching, electrophoresis, deposition process, A method of manufacturing a light emitting device, characterized in that performed by at least one of sputtering and compression molding.
Applying a light transmissive resin layer to a bottom surface of the light transmissive wafer;
Polishing the light transmissive resin layer to have a flattened surface; And
And forming a wavelength conversion layer containing a wavelength conversion material on the planarized surface.
The wafer is an insulating substrate, wherein the plurality of electrodes are formed so that at least two electrodes are located in the light emitting element region, respectively.
Priority Applications (1)
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KR1020110076721A KR20130014950A (en) | 2011-08-01 | 2011-08-01 | Manufacturing method of semiconductor light emitting device |
Applications Claiming Priority (1)
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KR1020110076721A KR20130014950A (en) | 2011-08-01 | 2011-08-01 | Manufacturing method of semiconductor light emitting device |
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KR (1) | KR20130014950A (en) |
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2011
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