KR20130001571A - Composition for improving frizzy hair - Google Patents

Composition for improving frizzy hair Download PDF

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KR20130001571A
KR20130001571A KR1020110062419A KR20110062419A KR20130001571A KR 20130001571 A KR20130001571 A KR 20130001571A KR 1020110062419 A KR1020110062419 A KR 1020110062419A KR 20110062419 A KR20110062419 A KR 20110062419A KR 20130001571 A KR20130001571 A KR 20130001571A
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composition
hair
polyquaternium
cationic polymer
present
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KR101808744B1 (en
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박민선
강병하
이존환
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(주)아모레퍼시픽
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64Proteins; Peptides; Derivatives or degradation products thereof
    • A61K8/645Proteins of vegetable origin; Derivatives or degradation products thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/98Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin
    • A61K8/987Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin of species other than mammals or birds
    • A61K8/988Honey; Royal jelly, Propolis
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/04Preparations for permanent waving or straightening the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54Polymers characterized by specific structures/properties
    • A61K2800/542Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5426Polymers characterized by specific structures/properties characterized by the charge cationic

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
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  • Zoology (AREA)
  • Cosmetics (AREA)

Abstract

PURPOSE: A composition containing hydrolyzed wheat proteins, cationic polymers, and a honey extract is provided to relax curliness of frizzy hair. CONSTITUTION: A composition for relaxing frizzy hair contains 0.01-10 wt% of hydrolyzed what proteins, 0.01-2 wt% of cationic polymers as active ingredients. The composition further contains 0.01-5 wt% of a honey extract. The cationic polymers are polyquaternium-4, polyquaternium-7, polyquaternium-10, or cationic guar.

Description

곱슬모발 완화용 조성물{Composition for improving frizzy hair}Composition for improving curly hair {Composition for improving frizzy hair}

본 발명은 곱슬모발 완화용 조성물에 관한 것으로, 가수분해 밀 단백질(Hydroyzed wheat protein), 양이온 폴리머 및 꿀 추출물을 유효성분으로 함유함으로써 모발 내외부 수분 환경의 항상성 유지를 통해 곱슬거림 현상을 완화시키는 곱슬모발 완화용 조성물에 관한 것이다.The present invention relates to a composition for relieving curly hair, and includes a hydrolyzed wheat protein, a cationic polymer, and a honey extract as an active ingredient, thereby relieving frizz through maintaining homeostasis of the external and external moisture environment. It relates to a composition for relaxation.

곱슬모발(Frizz), 즉 부시시함은 내외부 환경변화에 의해서 모발에서 발생되는 현상으로서 자칫 외모의 부정적인 영향을 주기도 한다. 특히 곱슬모발자에게 이런 현상이 더 쉽게 자주 발생하는데 습도가 많은 환경에서는 단백질 조성의 상이함으로 인해 곱슬모발 내외측의 팽윤 정도가 달라져 모발의 부시시함이 더 커진다. 그리하여 곱슬모발자들은 모발 열기구를 통한 스타일링으로 부시시함을 잠재우며 잦은 열기구 사용은 모발의 손상을 가속화시키기도 한다. Frizz, or frisch, is a phenomenon that occurs in hair due to internal and external environmental changes, which may have a negative effect on appearance. Especially for curly hairs, this phenomenon occurs more easily and often in humid environments, due to the difference in protein composition, the degree of swelling of the inside and outside of the curly hair is changed, resulting in greater hair softness. Thus, curly hairs keep the hair hot with styling through the hot air balloon, and frequent use of hot air balloon accelerates hair damage.

시판되는 대부분의 컨디셔닝 샴푸의 컨디셔닝력은 폴리머-계면활성제 콤플렉스에 의한 코아세르베이트의 흡착에 달려있다. 양이온 폴리머와 음이온 계면활성제로 이루어진 코아세르베이션은 샴푸를 헹구어낼 때 모발 표면에 침전되어 헹굼 시 부드러움과 컨디셔닝의 기능을 나타낸다.The conditioning power of most conditioning shampoos on the market depends on the adsorption of coacervates by the polymer-surfactant complex. Coacervation, consisting of a cationic polymer and an anionic surfactant, precipitates on the surface of the hair when the shampoo is rinsed, indicating the softness and conditioning of the rinse.

계면활성제의 음이온 작용기와 고분자의 양이온 그룹간의 쿨롱 흡착에 의해 특정 비율의 농도에서 중성화 콤플렉스(charge-neutral complex)를 형성한다. 하지만 음이온 계면활성제의 함량이 과다하면 고분자의 양전하는 상쇄되어 수용성 콤플렉스를 만든다. 특정 양이온 고분자만이 샴푸에 사용하였을 때 계면활성제의 CMC 이하로 희석되었을 때 침전한다. 이러한 현상은 샴푸 농축액으로 모발을 세정한 후의 헹굼과정에서 일어난다. 컨디셔닝 특성은 포밍(foaming)과 린싱(rinsing) 등의 희석(dilution) 조건의 낮은 계면활성제 농도에서, 계면활성제 solution과 양이온 폴리머 콤플렉스(polymer complex)가 액체상 분리현상(coacervation)을 일으키며 코아세르베이트(coacervates)나 침전(precipitates)이 겔(gel)과 같은 물성으로 모발에 흡착되어 에몰리언트한 사용감을 느낄 수 있도록 해준다. 이러한 상변화 현상을 "Lockhead Effect"라고도 하는데 양이온 폴리머의 특성, 계면활성제의 종류 및 특성, 전해질(electrolyte)에 의해 조절할 수 있다. 코아세르베이트는 젖은 상태에서의 빗질(wet combing)을 좋게 하고 다루기 쉽게(manageability) 해준다. 코아세르베이트 콤플렉스는 전적으로 고분자와 계면활성제의 분자적 특성에 영향을 받는다. 그리고 보조 계면활성제(cosurfactants)나 염(salt)과 같은 성분의 존재에도 크게 영향을 받는다. 연구자(formulator)에게 이러한 시스템의 최적화가 큰 과제로 남아 있다. 왜냐하면 천문학적인 숫자의 가능한 구성이 존재하고, 이들이 모두 각각은 다른 사용감(performance)을 나타내기 때문이다.Coulomb adsorption between the anionic functional group of the surfactant and the cationic group of the polymer forms a charge-neutral complex at a certain ratio. However, when the content of the anionic surfactant is excessive, the positive charge of the polymer is canceled to form a water-soluble complex. Only certain cationic polymers precipitate when diluted to below the CMC of the surfactant when used in shampoos. This phenomenon occurs during rinsing after washing the hair with shampoo concentrate. Conditioning properties include coacervates in which the surfactant solution and the cationic polymer complex cause coacervation at low surfactant concentrations under dilution conditions such as foaming and rinsing. Precipitates are adsorbed on the hair with gel-like properties, giving them an emollient feel. This phase change phenomenon is also called "Lockhead Effect" and can be controlled by the properties of the cationic polymer, the type and properties of the surfactant, and the electrolyte. Coacervate improves wet combing and manageability in wet conditions. Coacervate complexes are entirely affected by the molecular properties of the polymer and surfactant. It is also greatly influenced by the presence of components such as cosurfactants and salts. Optimizing such a system remains a challenge for formulators. Because there are possible configurations of astronomical numbers, each of them represents a different performance.

이에 본 발명자들은 곱슬모발의 정도를 완화시키기 위한 조성물에 대한 연구를 거듭하던 중, 가수분해 밀 단백질, 양이온 폴리머 및 꿀 추출물의 조합을 통해 모발 내외부 수분 환경의 항상성을 유지시킴으로써 곱슬거림 완화 효과를 얻을 수 있음을 발견하고 본 발명을 완성하게 되었다.Therefore, while the inventors have been studying the composition for alleviating the degree of curly hair, the combination of hydrolyzed wheat protein, cationic polymer and honey extract to obtain the effect of relieving frizz by maintaining the homeostasis of the moisture environment inside and outside the hair It has been found that the present invention has been completed.

따라서, 본 발명의 목적은 모발 내외부 수분 환경의 항상성을 유지시킬 수 있는 곱슬머리 완화용 조성물을 제공하는 것이다.Accordingly, it is an object of the present invention to provide a composition for relieving curly hair that can maintain homeostasis of the moisture environment inside and outside the hair.

상기한 목적을 달성하기 위하여, 본 발명에서는 가수분해 밀 단백질, 양이온 폴리머 및 꿀 추출물을 유효성분으로 함유하는 곱슬머리 완화용 조성물을 제공한다.In order to achieve the above object, the present invention provides a composition for relieving curly hair containing hydrolyzed wheat protein, cationic polymer and honey extract as an active ingredient.

본 발명에 의한 조성물은 가수분해 밀 단백질(Hydroyzed wheat protein), 양이온 폴리머 및 꿀 추출물을 유효성분으로 함유함으로써 곱슬 모발 내외부 균형을 유지하고 저/고습도조건에서 모발 수분 항상성 환경에서 수분 항상성 유지를 통해 곱슬거림 현상을 완화시킬 수 있다.The composition according to the present invention contains hydrolyzed wheat protein, cationic polymer and honey extract as active ingredients to maintain the balance between inside and outside curly hair and to maintain moisture homeostasis in the hair moisture homeostasis environment at low / high humidity conditions. It can alleviate flicker.

도 1은 계면활성제의 농도에 따른 폴리머-계면활성제 복합체의 코아세르베이션 과정을 보여주는 모식도이다.
도 2는 습도를 달리한 조건에서 곱슬거림 정도를 측정한 사진이다.
1 is a schematic diagram showing the coacervation process of the polymer-surfactant complex according to the concentration of the surfactant.
Figure 2 is a photograph measuring the degree of curl under different humidity conditions.

이하, 본 발명을 보다 상세히 설명한다.Hereinafter, the present invention will be described in more detail.

본 발명은 가수분해 밀 단백질 및 양이온 폴리머를 유효성분으로 함유하는 곱슬머리 완화용 조성물에 관한 것으로서, 보다 상세하게는 본 발명은 가수분해 밀 단백질 및 양이온 폴리머에 꿀 추출물을 유효성분으로 더 함유하는 곱슬머리 완화용 조성물에 관한 것이다.The present invention relates to a composition for relieving curly hair containing a hydrolyzed wheat protein and a cationic polymer as an active ingredient. More specifically, the present invention relates to a curly hair protein containing a honey extract as an active ingredient. The present invention relates to a hair relaxing composition.

본 발명에서 사용하는 가수분해 밀 단백질은 평균분자량 250~500 Da의 단백질로 비교적 작은 분자량으로 인해 모발 침투가 용이하여 큐티클 뿐만 아니라 코텍스 안까지 들어갈 수 있다. 이러한 용이한 침투성은 모발의 세기를 증가시켜줄 뿐만 아니라 손상을 방지하는 역할을 수행하기도 한다. 또한 고습도 하에서 모발에 처리하면 모발의 수분흡수를 더디게 하여 눅눅함으로 인한 헤어 스타일링의 어려움이나 모발 처짐을 방지해준다. 반대로 낮은 습도 환경에서는 모발의 수분방출을 더디게 하여 푸석하고 건조한 모발의 수분밸런스를 도와준다. 밀 단백질은 약 35% 이상의 글루탐산(Glutamic acid)을 함유하고 있어 아미노산 종류 중의 하나인 프롤린(proline)의 합성에 도움을 준다. Hydrolysed wheat protein used in the present invention is a protein having an average molecular weight of 250 ~ 500 Da due to the relatively small molecular weight is easy to penetrate the hair can enter the cortex as well as the cuticle. This easy penetration not only increases the strength of the hair but also serves to prevent damage. In addition, if the hair is treated under high humidity, the moisture absorption of the hair is slowed, thereby preventing the difficulty of hair styling or sagging due to dampness. On the contrary, in low humidity environment, the moisture release of the hair is slowed down, which helps balance the dry and dry hair. Wheat protein contains more than about 35% glutamic acid, which aids in the synthesis of proline, one of the amino acid classes.

본 발명에 의한 곱슬머리 완화용 조성물은 상기 가수분해 밀 단백질을 조성물 총 중량에 대하여 0.01~10 중량%로 함유할 수 있다. 가수분해 밀 단백질의 함량이 0.01 중량% 미만인 경우에는 모발 처짐 방지나 수분 밸런스 등의 효과를 얻을 수 없고, 10 중량%를 초과하는 경우에는 제형 안정성 및 사용감이 떨어질 수 있다.Curly hair relieving composition according to the present invention may contain the hydrolyzed wheat protein 0.01 to 10% by weight based on the total weight of the composition. When the content of hydrolyzed wheat protein is less than 0.01% by weight, effects such as hair sagging prevention and moisture balance may not be obtained, and when it exceeds 10% by weight, formulation stability and usability may be deteriorated.

또한 본 발명에 의한 조성물은 양이온 폴리머(Cationic Polymers)로서 하기 표 1에 기재된 폴리쿼터니움-4(Polyquaternium-4), 폴리쿼터니움-7, 폴리쿼터니움-10 및 양이온 구아(Guar hydroxypropyltrimonium chloride)폴리머 등을 단독 또는 2 종 이상 혼합하여 사용할 수 있으나, 이에만 한정되는 것은 아니다.In addition, the composition according to the present invention is a cationic polymer (Polyquaternium-4), polyquaternium-7, polyquaternium-10 and guar hydroxypropyltrimonium chloride polymer as shown in Table 1 below Etc. may be used alone or in combination of two or more, but is not limited thereto.

INCI 명칭INCI name 화학명Chemical name 구조rescue 폴리쿼터니움-10Polyquaternium-10 Cellulose 2-(2-hydroxy-3-(trimethylammonio)propoxy) ethyl etherCellulose 2- (2-hydroxy-3- (trimethylammonio) propoxy) ethyl ether

Figure pat00001
Figure pat00001
폴리쿼터니움 -4Polyquaternium -4 Hydroxyethyl cellulose dimethyl diallylammonium chlorideHydroxyethyl cellulose dimethyl diallylammonium chloride
Figure pat00002
Figure pat00002
폴리쿼터니움-7Polyquaternium-7 Dimethyldiallyl Ammonium Chloride·Acrylamide Copolymer
Dimethyldiallyl Ammonium ChlorideAcrylamide Copolymer

양이온성 구아Cationic Guar Guar hydroxypropyltrimonium chlorideGuar hydroxypropyltrimonium chloride
Figure pat00003
Figure pat00003

본 발명에 의한 곱슬머리 완화용 조성물은 상기 양이온 폴리머는 합성에 의한 것이며 구아 양이온 폴리머는 구아검에서 유래하여 합성된 천연유래 양이온 폴리머이다. 조성물 총 중량에 대하여 0.01~2 중량%로 함유할 수 있다. 양이온 폴리머의 함량이 0.01 중량% 미만인 경우에는 모발 처짐 방지나 수분 밸런스 등의 효과를 얻을 수 없고, 2 중량%를 초과하는 경우에는 제형 안정성이 떨어질 수 있다.Curly hair relaxation composition according to the present invention is the cationic polymer is a synthetic and guar cationic polymer is a naturally derived cationic polymer derived from guar gum. It may be contained in 0.01 to 2% by weight based on the total weight of the composition. When the content of the cationic polymer is less than 0.01% by weight, effects such as hair sagging prevention and moisture balance cannot be obtained, and when it exceeds 2% by weight, the formulation stability may be deteriorated.

꿀은 꿀벌이 여러 식물의 꽃으로부터 수집한 화밀과 화분을 그들의 식량으로 전환하여 저장한 것으로, 2개의 단당류, 즉 글루코오스(glucose)와 프룩토오스(fructose), 탄수화물, 무기질, 식물성 색소, 효소 및 화분 등을 함유하고 있다. 꿀의 성분 중 80% 이상은 글루코오스(glucose), 프룩토오스(fructose) 등의 단당류이다. 이 성분은 흡습성이 매우 뛰어나 피부에서 수분막을 형성하여 지속적인 보습효과를 가진다. 본 발명에서 사용하는 꿀 추출물은 이러한 성분이 다량 포함되어 있어 강력한 보습효과를 가진다. 꿀 추출물은 공지의 방법으로 제조된 것으로서, 벌꿀 원료를 가열하고 왁스 등 불순물을 제거하고 일반적인 용매로서 추출하여 제조되었다. Honey is stored by converting the nectar and pollen collected from the flowers of several plants into their food. Two monosaccharides, glucose and fructose, carbohydrates, minerals, vegetable pigments, enzymes, Pollen and the like. More than 80% of honey's components are monosaccharides such as glucose and fructose. This ingredient has excellent hygroscopicity and forms a moisture film on the skin, which has a continuous moisturizing effect. Honey extract used in the present invention contains a large amount of these components has a strong moisturizing effect. Honey extract is prepared by a known method, it was prepared by heating the honey raw material, removing impurities such as wax and extracted as a general solvent.

본 발명에 의한 곱슬머리 완화용 조성물은 상기 꿀 추출물을 프랑스 남부지방에 서생하는 꽃의 꿀로서 조성물 총 중량에 대하여 0.01~5 중량%로 함유할 수 있다. 꿀 추출물의 함량이 0.01 중량% 미만인 경우에는 원하는 모발 보습 효과를 얻을 수 없고, 5 중량%를 초과하는 경우에는 제형 안정성 및 사용감 등이 떨어질 수 있다.Curly hair relaxation composition according to the present invention may contain the honey extract of 0.01 to 5% by weight relative to the total weight of the composition as the honey of the flowers in the south of France. If the content of the honey extract is less than 0.01% by weight can not achieve the desired hair moisturizing effect, when the content of more than 5% by weight may lower the formulation stability and usability.

또한 본 발명에 의한 곱슬모발 완화용 조성물은 통상적인 모발 제형을 가질 수 있으며, 예를 들면 샴푸, 린스, 헤어토닉, 포마드, 헤어트리트먼트, 헤어 로션 또는 모발 영양 화장 젤 등으로 제형화될 수 있다. 이들 각 제형의 모발 조성물은 상기한 각종 제형에 따라 또는 최종 목적에 적합하게 통상의 모발 조성물에 배합되는 각종 성분들을 함유할 수 있으며, 이들 성분의 종류와 양은 당업자에 의해 용이하게 선정될 수 있다.
In addition, the composition for relieving curly hair according to the present invention may have a conventional hair formulation, and may be formulated, for example, as a shampoo, rinse, hair tonic, pomade, hair treatment, hair lotion, or hair nourishing cosmetic gel. . The hair composition of each of these formulations may contain various components formulated into conventional hair compositions according to the various formulations described above or as appropriate for the end purpose, and the types and amounts of these components can be easily selected by those skilled in the art.

이하, 본 발명의 내용을 실시예 및 시험예를 통하여 보다 구체적으로 설명한다. 이들 실시예는 본 발명의 내용을 이해하기 위해 제시되는 것일 뿐 본 발명의 권리범위가 이들 실시예 및 시험예로 한정되는 것은 아니고, 당업계에서 통상적으로 주지된 변형, 치환 및 삽입 등을 수행할 수 있으며, 이에 대한 것도 본 발명의 범위에 포함된다.
Hereinafter, the present invention will be described more specifically with reference to examples and test examples. These examples are provided only for understanding the contents of the present invention, but the scope of the present invention is not limited to these examples and test examples, and modifications, substitutions, and insertions commonly known in the art may be performed. It may be included in the scope of the present invention.

[실시예 1~9 및 비교예 1][Examples 1-9 and Comparative Example 1]

하기 표 2에 기재된 조성에 따라 각 구성성분으로 혼합하여 실시예 1~9 및 비교예 1을 제조하였다(단위: 중량%).To prepare according to the composition shown in Table 2 to each component to prepare Examples 1 to 9 and Comparative Example 1 (unit: weight%).

<곱슬모발 완화용 조성물><Composition for Curly Hair Relief> 성분ingredient 비교예1Comparative Example 1 실시예1Example 1 실시예2Example 2 실시예3Example 3 실시예4Example 4 실시예5Example 5 실시예6Example 6 실시예7Example 7 실시예8Example 8 실시예9Example 9 식물성오일+ 가수분해 밀 단백질Vegetable Oil + Hydrolyzed Wheat Protein 0.10.1 0.10.1 0.10.1 0.10.1 0.10.1 0.10.1 0.10.1 0.10.1 0.10.1 0.10.1 폴리쿼터니움-4Polyquaternium-4 -- -- 0.20.2 -- -- 0.20.2 -- -- 0.20.2 0.20.2 폴리쿼터니움-7Polyquaternium-7 -- -- -- 0.20.2 -- -- 0.20.2 -- 0.20.2 0.20.2 폴리쿼터니움-10Polyquaternium-10 -- -- -- -- 0.20.2 -- -- 0.20.2 0.20.2 0.20.2 Guarhydroxypropyl trimoniumchlorideGuarhydroxypropyl trimoniumchloride -- 0.20.2 -- -- -- 0.20.2 0.20.2 0.20.2 0.20.2 0.20.2 꿀 추출물Honey extract -- -- -- -- -- -- -- -- -- 0.10.1

본 발명에 의한 가수분해 밀 단백질, 양이온 폴리머 및 꿀 추출물을 유효성분으로 함유하는 곱슬모발 완화용 조성물은 하기의 제형예와 같이 제조될 수 있으나, 이에 한정되는 것은 아니다.
Curly hair relieving composition containing a hydrolyzed wheat protein, cationic polymer and honey extract according to the present invention as an active ingredient may be prepared as in the following formulation example, but is not limited thereto.

[제형예 1] 샴푸Formulation Example 1 Shampoo

하기 표 3에 기재된 조성에 따라 통상적인 방법으로 샴푸를 제조할 수 있다.The shampoo can be prepared according to the composition shown in Table 3 in a conventional manner.

원료명Raw material name 함량(G) Content (G) 기능function 정제수 Purified water To 100To 100 용제solvent 소듐라우레스설페이트Sodium laureth sulfate 2020 계면활성제Surfactants 벤조페논-5Benzophenone-5 0.020.02 자외선차단제Sunscreen 판테놀Panthenol 0.010.01 보습제Moisturizer 디소듐이디티에이Disodium iodide 0.050.05 이온봉쇄제Ion Blocker 메칠파라벤 Methylparaben 0.10.1 보존제Preservative 코카마이드엠이에이 Cocamide miai 1One 계면활성제Surfactants 소듐클로라이드 Sodium chloride 0.80.8 유화안정제Emulsifying Stabilizer 소듐라우레스설페이트Sodium laureth sulfate 1010 계면활성제Surfactants 암모늄라우릴설페이트Ammonium Lauryl Sulfate 1515 계면활성제Surfactants 정제수 Purified water 30.0599830.05998 용제solvent 코카미도프로필베타인 Cocamidopropyl betaine 55 계면활성제Surfactants 하이드롤라이즈드밀단백질 Hydrolyzed Wheat Protein 0.010.01 추출물extract 청색1호 Blue No. 1 0.000020.00002 색소Pigment 메칠클로로이소치아졸리논/메칠이소치아졸리논혼합액Methylchloroisothiazolinone / methylisothiazolinone mixture 0.030.03 보존제Preservative 시트릭애씨드(구연산), (KP: 시트르산수화물)Citric Acid (citric acid), (KP: Citric Acid Hydrate) 0.020.02 pH 조절제pH regulator 단품향료Single article flavor 0.80.8 착향제Flavoring agent

[시험예 1-곱슬머리 완화 효과평가] [Test Example 1-Curly Hair Relaxation Effect Evaluation]

상기 실시예 1~9 및 비교예 1의 조성물의 곱슬머리 완화 효과를 알아보기 위하여, 하기 과정을 거쳐 곱슬거림 정도를 측정하였으며, 그 결과를 하기 표 4에 나타내었다.In order to determine the curling hair relaxation effect of the compositions of Examples 1 to 9 and Comparative Example 1, the degree of curling was measured through the following process, and the results are shown in Table 4 below.

먼저, 하기와 같은 방법으로 비교예 1이 함유된 일반 샴푸(자사 컨디셔닝력 없는 샴푸인 아모스 뷰티샴푸)로 처리한 모발트레스(tress)(가로1.8cm, 세로 20.5cm 고정)와 실시예 1~9의 조성물을 함유한 샴푸로 처리한 모발트레스 9개를 준비하였다. First, hair stress treated with a general shampoo (Amos Beauty Shampoo, which is a shampoo without its own conditioning power) containing Comparative Example 1 in the same manner as described below, and Examples 1 to 9 Nine hairdressers treated with the shampoo containing the composition of the formulation were prepared.

1)실시예 1~9를 함유한 샴푸 및 비교예 1을 처리한 일반 샴푸를 각각 모발 트레스에 30분 동안 처리(1주일 누적 사용과 동등효과) 1) Shampoos containing Examples 1 to 9 and general shampoos treated with Comparative Example 1 were each treated with hair tresses for 30 minutes (equivalent to one week cumulative use)

2)상기 10개의 모발 트레스를 35℃ 부근의 흐르는 수돗물로 헹군 후 3분간 드라이기 사용 건조2) Rinse the 10 hair tresses with running tap water near 35 ° C and use a dryer for 3 minutes

3)항온 항습기(Low temp Constant Temp Humidity Apparatus, JISICO社)를 25℃, 90%(고습도조건)로 셋팅 3) Low temperature constant humidity (Low temp Constant Temp Humidity Apparatus, JISICO Co., Ltd.) is set at 25 ℃, 90% (high humidity conditions)

4)거치대에 상기 샴푸가 처리된 모발 트레스들을 세로로 걸어놓고 항온 항습기에 24시간 동안 방치
4) Hang the hair tresses treated with the shampoo vertically on a stand and stand in a thermo-hygrostat for 24 hours.

그 다음으로, 상기의 처리를 하기 전과 후의 비교예 1을 함유한 샴푸를 사용한 모발 트레스 및 실시예 1~9를 함유한 샴푸를 사용한 모발 트레스의 곱슬거림(가로길이와 세로길이의 변화)을 비교 관찰하였다.
Next, the curling of the hair tress using the shampoo containing Comparative Example 1 and the hair tress using the shampoo containing Examples 1 to 9 before and after the above treatment were compared (change in length and length). Observed.

평가항목Evaluation item 비교예1Comparative Example 1 실시예 1Example 1 실시예2Example 2 실시예3Example 3 실시예4Example 4 실시예5Example 5 실시예6Example 6 실시예7Example 7 실시예8Example 8 실시예9Example 9 가로길이(cm)Width (cm) 3.6cm3.6 cm 3.1 cm3.1 cm 3.3 cm3.3 cm 3.2 cm3.2 cm 3.1 cm3.1 cm 2.8 cm2.8 cm 2.6 cm2.6 cm 2.5 cm2.5 cm 2.4 cm2.4 cm 2.1 cm2.1 cm 세로길이(cm)Vertical length (cm) 16.0 cm16.0 cm 16.6 cm16.6 cm 16.5 cm16.5 cm 16.8 cm16.8 cm 17.0 cm17.0 cm 17.5 cm17.5 cm 17.4 cm17.4 cm 17.7 cm17.7 cm 17.8 cm17.8 cm 18 cm18 cm

곱슬거림의 완화 정도를 샴푸 처리전과 후 모발트레스의 가로길이와 세로길이의 변화 정도로 간주하였다. 상기 표는 그 가로와 세로길이의 변화를 측정한 결과이다. The degree of relieving frizz was considered as the degree of change in the transverse and longitudinal lengths of the hair stress before and after shampooing. The above table shows the results of measuring changes in the width and length.

상기의 표에 나타난 바와 같이, 실시예 9를 함유한 샴푸를 처리한 경우가 비교예 1이 함유된 샴푸로 처리한 경우에 비해 가로길이와 세로길이의 변화가 적은 것으로 나타났다. 따라서, 본원발명의 실시예 9가 고습도(30℃, 습도 90%) 조건에서 정성적, 정량적으로 곱슬거림을 완화시키는 효과가 있음을 확인할 수 있었다. As shown in the above table, the case of treating the shampoo containing Example 9 was found to be less change in the width and length than in the case of treatment with the shampoo containing Comparative Example 1. Therefore, it was confirmed that Example 9 of the present invention has an effect of alleviating frizz qualitatively and quantitatively under high humidity (30 ° C., humidity of 90%).

Claims (6)

가수분해 밀 단백질 및 양이온 폴리머를 유효성분으로 함유하는 곱슬머리 완화용 조성물.Curly hair relieving composition containing a hydrolyzed wheat protein and a cationic polymer as an active ingredient. 제 1항에 있어서, 상기 조성물은 꿀 추출물을 더 함유하는 것을 특징으로 하는 곱슬머리 완화용 조성물.According to claim 1, wherein the composition is a composition for relieving curly hair, characterized in that it further contains a honey extract. 제 1항에 있어서, 상기 가수분해 밀 단백질은 조성물 총 중량에 대하여 0.01~10 중량%로 함유되는 것을 특징으로 하는 곱슬머리 완화용 조성물.The method of claim 1, wherein the hydrolyzed wheat protein is characterized in that the composition for reducing the curls, characterized in that contained in 0.01 to 10% by weight based on the total weight of the composition. 제 1항에 있어서, 상기 양이온 폴리머는 폴리쿼터니움-4(Polyquaternium-4), 폴리쿼터니움-7, 폴리쿼터니움-10 및 양이온성 구아(Cationic Guar)로 이루어진 군에서 선택된 1종 이상임을 특징으로 하는 곱슬머리 완화용 조성물.The method of claim 1, wherein the cationic polymer is at least one selected from the group consisting of Polyquaternium-4, Polyquaternium-7, Polyquaternium-10, and Cationic Guar. Curly hair relief composition. 제 1항에 있어서, 상기 양이온 폴리머는 조성물 총 중량에 대하여 0.01~2 중량%로 함유되는 것을 특징으로 하는 곱슬머리 완화용 조성물.The method of claim 1, wherein the cationic polymer is characterized in that the curling hair relaxation composition, characterized in that contained in 0.01 to 2% by weight based on the total weight of the composition. 제 2항에 있어서, 상기 꿀 추출물은 조성물 총 중량에 대하여 0.01~5 중량%로 함유되는 것을 특징으로 하는 곱슬머리 완화용 조성물.According to claim 2, wherein the honey extract is curly hair relief composition, characterized in that contained in 0.01 to 5% by weight based on the total weight of the composition.
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