KR20120134888A - Slurry type inorganic natural fertilizer - Google Patents
Slurry type inorganic natural fertilizer Download PDFInfo
- Publication number
- KR20120134888A KR20120134888A KR1020110054094A KR20110054094A KR20120134888A KR 20120134888 A KR20120134888 A KR 20120134888A KR 1020110054094 A KR1020110054094 A KR 1020110054094A KR 20110054094 A KR20110054094 A KR 20110054094A KR 20120134888 A KR20120134888 A KR 20120134888A
- Authority
- KR
- South Korea
- Prior art keywords
- weight
- fertilizer
- mixture
- slurry
- powder
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D3/00—Calcareous fertilisers
- C05D3/02—Calcareous fertilisers from limestone, calcium carbonate, calcium hydrate, slaked lime, calcium oxide, waste calcium products
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D5/00—Fertilisers containing magnesium
Abstract
The present invention relates to an inorganic natural fertilizer in the form of slurry, which can be expected at the same time a short-term effect in crop cultivation by liquid fertilizer in the slurry-type inorganic natural fertilizer and the long-term effect of improving the soil itself by solid fertilizer. It is made by suspending the solid fertilizer, wherein the liquid fertilizer is 5 to 15% by weight biotite, 1 to 10% by weight olivine, 1 to 10% by weight meteorite, 1 to 10% by weight of earstone, 5 to 15% by weight of sapphire, 1 to 10% by weight of red clay, and reduced calcined powder of the first mixture comprising mordenite as a remainder, and reduced calcined powder and shells of vermiculite in weight ratio vermiculite: shell It is obtained by adding 1-10% of organic acid to the raw material mixture obtained by mixing in the ratio of min: 1st mixture = 1: 1: 2-4, and fermenting with the seed of lactic acid bacteria. It consists of a supernatant of the fermentation product, and the solid fertilizer is characterized in that it consists of solids in the form of sludge remaining after separating the supernatant from the fermentation product.
Description
The present invention relates to an inorganic natural fertilizer in the form of a slurry, in particular, a slurry form that can be expected at the same time a long-term effect of short-term effects in crop cultivation by liquid fertilizer in the form of slurry-type inorganic fertilizer and improvement of the soil itself by solid fertilizer. It relates to mineral natural fertilizer of.
In the agricultural environment of the 21st century, the world is becoming one market, and competition is getting fiercer. In particular, the Free Trade Agreement (FTA) negotiations with the US, which will establish a global trade order, began in early May 2006. While the US-Korea FTA, which is broader in scope than the WTO and the Doha Development Agenda, is interested in how the Korean-American FTA will change the lives of our agricultural economy and rural industry, there is a growing focus on uncompetitive production in the long run. In the situation that its existence itself is threatened by the increase of overall imports, it is in the reality that it needs to find a way to support eco-friendly agriculture promotion policy as an alternative to future agriculture.
The use of pesticides and chemical fertilizers has been rapidly expanding in order to increase food and increase productivity per unit area due to the rapid development of industrial society and population growth. It causes acidification of the soil and thus the soil is gradually becoming desolate, and in order to eliminate the pests that occur during the growth of plants, the increase of resistance due to the overuse of pesticides and the simplification of soil pathogens and harmful nematodes by the simplification of soil microorganisms Today's reality is a recurring vicious cycle that requires the use of large amounts of pesticides.
In recent years, as the problems of crop pollution and environmental pollution become serious, the recognition of the importance of the development of organic farming technology using high quality organic fertilizer or compost rather than the use of chemical fertilizer or pesticide has been spreading. As a result, organic fertilizers obtained by treating livestock manure or food waste have been developed and used, and efforts to improve the compost fermentation method using microorganisms have been continued.
However, despite the above efforts, the use of organic fertilizers and composts by fermentation production cause another problem, and these natural organic fertilizers are mainly sawdust, herbal medicine meal, fish meal or livestock meal and natural mixtures thereof. Most of the organic materials are used to produce these natural organic fertilizers, which require a long time and excessive equipment by fermentation of microorganisms, making them difficult to use in actual production, as well as water pollution caused by waste and wastewater. There is also a problem that causes, and if you use the fertilizer containing an excessive amount of these organic matters for a long time, the growth of the crop is concerned.
In addition, in order to make a fermented compost mixed with sawdust or chaff to treat livestock manure or food waste, and to use in crops, tannin or lignin may remain in the state when sawdust or chaff is not sufficiently fermented, which may damage crops. In the process of decay, animal waste and food waste can cause damage to crop roots due to organic acids generated, and salt, heavy metals, etc. in the manure or food waste remain in the soil, further contaminating soil and deteriorating soil depth. .
In addition, the biggest problem of the above organic fertilizers or compost or chemical fertilizers have a fundamental problem to function as a perfect plant growth aid because it contains little trace elements necessary for plant growth.
Fertilizers refer to substances that cause chemical changes in the soil to nourish or assist the cultivation of plants, as well as substances that affect the plant. These fertilizers are based on fertilizer, manure, manure and formula. Granular fertilizer, powdered fertilizer, filamentous fertilizer, solid fertilizer, liquid fertilizer, organic fertilizer, inorganic fertilizer, mineral fertilizer depending on raw materials, sweet fertilizer, compound fertilizer, BB fertilizer, nitrogen fertilizer, phosphate fertilizer, bran fertilizer, trace urea fertilizer According to the effect, fast-acting fertilizer, slow-fertilizer, slow-fertilizer, water fertilizer, horticultural fertilizer, fruiting fertilizer, fertilizer, mineral nitrogen fertilizer, inorganic phosphate fertilizer, inorganic scallops, compound fertilizer, organic fertilizer, Lime fertilizer, siliceous fertilizer, high soil fertilizer, trace urea fertilizer, manure fertilizer, manure fertilizer, compost according to by-products, ripening, ash, manure residue, side soil, ami Acid fermentation is classified as Busan fertilizers, dry manure, dry animal waste, rice husk and sawdust compost, soil and soil microbial agent activator fertilizer.
A liquid fertilizer consisting of a double liquid is a liquid fertilizer, which is obtained by diluting powder or granular fertilizers. It is mainly belonging to the fourth type of compound fertilizer. However, it uses chemical fertilizers for liquid fertilizers that are easily soluble in water.
In general, liquid fertilizer is manure that is excreted in the liquid state by mixing manure excreted and livestock left in the process of raising livestock and litter.In comparison with compost, liquid fertilizer is used as a fast fertilizer and organic fertilizer. It has the advantage of lasting effect.
However, these liquid fertilizers fertilize the harmful substances generated during the livestock manure and rearing process without filtration, and as a result, harmful components are absorbed into the plant as it is fertilized to help the cultivation of the plant, and then fed into the body when cultivated. Absorbed as it was, there was a risk of various diseases.
As a method of using the livestock manure was previously used to collect the manure and store it in a tank, and then activated by adding a spawning agent to produce a liquid fertilizer by a biological method, but such a conventional manufacturing method is at random It is impossible to produce standardized liquid fertilizers by treating the collected manure with chemical prescription additives and uniform amounts of prescription additives without taking into account the state of heavy metals, toxicity, pH, etc. When the chemical fertilizer is returned to the soil, there are limitations and problems in its use, such as polluting the soil and adversely affecting the growth of plants.
In particular, when chemical components are included in the fertilizer, problems such as worsening soil contamination and depletion of mineral components in the soil occur, the fertilizer additives must be natural, require the composition of biological components, have no odor, are sterilized, stored and used. It is required to be convenient.
It is an object of the present invention to provide an inorganic natural fertilizer in the form of a slurry configured to supply various trace elements which are absolutely necessary for the growth and deletion of crops.
As described above, the inorganic natural fertilizer in the form of slurry according to the present invention for achieving the object of the present invention is made by suspending solid fertilizer in a liquid fertilizer, wherein the liquid fertilizer is 5 to 15% by weight of biotite, 1 To 10% by weight of olivine, 1 to 10% by weight of meteorite, 1 to 10% by weight of noble stone, 5 to 15% by weight of sapphire, 1 to 10% by weight of red ocher, and mordenite To the raw material mixture obtained by mixing the reducing calcined product of the powder of the first mixture, the reducing calcined product of the powder of vermiculite and the shell meal in the ratio of vermiculite: shell powder: first mixture = 1: 1: 2 to 4. It is composed of a supernatant of the fermentation product obtained by adding an organic acid at a concentration of 1 to 10% and fermenting with a seed of lactic acid bacteria, and the solid fertilizer is a sludge remaining after separating the supernatant from the fermentation product. It characterized by a support constituted by any type of solid component.
The organic acid may be selected from the group consisting of ascorbic acid (vitamin C), amino acids, succinic acid, malic acid, aspartic acid or a mixture of two or more thereof.
The mixing ratio of the raw material mixture and the organic acid may be 1: 0.5 to 1.5 weight ratio.
The inorganic natural fertilizer in the form of a slurry may further include a zeolite.
The zeolite may preferably be one having a Cation Exchange Capacity (CEC) of 10 or more.
In addition, the method for producing an inorganic natural fertilizer in the form of a slurry according to the present invention, (1) 5 to 15% by weight biotite, 1 to 10% by weight olivine, 1 to 10% by weight meteorite, 1 to 10% by weight The first mixing step of obtaining a first mixture of a noble stone, 5 to 15% by weight of sapphire, 1 to 10% by weight of red clay, and mordenite as a balance; (2) a first grinding step of pulverizing the first mixture to 900 to 1100 mesh to powder; (3) a first reduction firing step of reducing-firing the powder of the first mixture at a temperature of 300 to 400 ° C. under an oxygen-free or rare oxygen atmosphere; (4) a second reduction firing step of reducing the calcined powder of vermiculite into 10 to 80 mesh at a temperature of 900 to 1100 ° C. under an oxygen-free or rare oxygen atmosphere; (5) shells obtained by pulverizing the first mixture powder obtained in the first reduction firing step and the vermiculite powder and shell shell obtained in the second reduction firing step in a weight ratio vermiculite: shell meal: first mixture 1: 1: 2nd mixing step of obtaining a raw material mixture by mixing in a ratio of 2 to 4; And (6) a fermentation step of adding the organic acid at a concentration of 1 to 10% to the raw material mixture and fermenting with the seed of lactic acid bacteria to obtain a fermentation product.
According to the present invention, the effect of providing an inorganic natural fertilizer in the form of slurry that can be expected at the same time a short-term effect in the crop cultivation by the liquid fertilizer in the slurry-type inorganic natural fertilizer and the long-term effect of improving the soil itself by solid fertilizer. have.
Inorganic natural fertilizer in the form of slurry according to the present invention is made by suspending solid fertilizer in a liquid fertilizer, wherein the liquid fertilizer is 5 to 15% by weight biotite, 1 to 10% by weight olivine, 1 to 10% by weight Meteorite of 1 to 10% by weight of noble stone, 5 to 15% by weight of jadeite, 1 to 10% by weight of red clay, and reduced calcined powder of the first mixture comprising mordenite as a balance To the raw material mixture obtained by mixing the reduced calcined product and the shell powder of the powder in the ratio of vermiculite: shell powder: first mixture = 1: 1: 2 to 4, an organic acid having a concentration of 1 to 10% is added thereto. It is composed of the supernatant of the fermentation product obtained by fermentation with the spawn of the lactic acid bacteria, and the solid fertilizer is characterized by consisting of the sludge solids remaining after separating the supernatant from the fermentation product.
The biotite constituting the first mixture is a mineral belonging to a monoclinic system having a crystal structure such as mica, and its color is black, brownish black, and greenish black. It is produced from igneous rocks and metamorphic rocks, and is rarely produced from sedimentary rocks. The chemical composition is K (Mg, Fe) 3 AlSi 3 O 10 (OH) 2 . Lamellar or impression, often hexagonal or rhombohedral. The cleavage is perfect at the bottom and the flake is elastic, which is smaller than the gold mica. Split surface has pearlescent gloss, sometimes metallic gloss. Hardness 2.5-3.0, specific gravity 2.7-3.1. In pegmatite, huge biotite crystals can be obtained. Biotite ore has long been called a mysterious pebble, and when heat is applied, it is about 3 times higher in far-infrared emissivity than ocher and elvan, and its germanium content is 36 ppm. It is described as Master.
The olivine constituting the first mixture is a main coarse mineral belonging to a tetragonal system, and its chemical composition is (Mg, Fe) 2 SiO 4, and the hardness is 6.5 to 7, Specific gravity is 3.2 to 3.4, color is olive, tan or gray-red, also called chrysolite or olivine. There are columnar decisions, but some are not clear. Transparent or translucent, streak color is white. It shows a crack in the shape of a clam shell. It is one of the minerals that are easy to change and often turns into serpentine along its periphery or cracks. It is usually produced as a semiclinic rock of volcanic rocks such as andesite and basalt. It is also produced as a nodule of granular aggregates in volcanic rocks, and is often contained in plutonic rocks such as olive rocks. Fine ones are used as jade. The transparent green olivine is widely known as a jewel called peridot. The soil composed of olivines has a high drainage rate and high water content, which can be a great help in growing crops. It is also known that the anion emission is high.
The meteorite constituting the first mixture is generally composed of SiO 2 (78.6%), Fe 2 O 3 (0.73%), TiO 2 (0.03%), Al 2 O 3 (10.5%), CaO ( 2.40%), MgO (0.31%), K 2 O (2.49%), Na 2 O (2.01%), Ge (4.9%) and others (2.5%) (Korea Institute of Construction Materials) No. 917 Ho, June 11, 1999). In addition, the far infrared emissivity and radiation energy of the meteorite is 0.92 ㎛, 3.70 x 102 (W / ㎡ ㎛, 40 ℃) respectively (Korea Institute of Construction Materials issued No. FIR-520 (C778), May 12, 1999). For reference, infrared rays are light belonging to a wavelength of 0.76 to 1000 µm emitted from sunlight, and the far infrared rays are wavelengths of between 5.6 and 1000 µm, among which vibration of molecules of organic compounds constituting an object is performed. It performs a function that promotes metabolism. In particular, the wavelength band between 5.6 and 15 μm is a wavelength that is beneficial to human life, and coincides with the absorption wavelength band of organic compounds in the living body. Thus, molecules constituting the living body resonate and resonate, thereby improving blood circulation. to provide.
The precious stone that constitutes the first mixture is present in a mine formed by a high temperature random water action due to a tectonic change of about 65 million years ago, and is known as a mysterious material condensing energy of nature. Guinea stone generates a large amount of negative ions about 10 times of tourmaline, has a high far-infrared emissivity of 96%, shows a high surfactant activity (101% increase), and is known as a beneficial natural material for the human body without containing radioactive elements. . There are two types of guinea pigs, red and white, the composition of which is shown in Table 1 (unit weight%).
The sapphire constituting the first mixture is a mineral belonging to a rhombohedral family of hexagonal systems. Hardness 9, specific gravity 4.02, blue transparent corundum. There are light blue, purple blue, green blue, etc., but the dark blue beats best. It is the birthstone for September and is used as a gift for the 35th anniversary of marriage. Today there are some good ones that can be artificially synthesized. The chemical composition is Al 2 O 3 , solid 9 followed by diamond, and specific gravity 4.02, which is exceptionally heavy for nonmetallic minerals. It is a blue transparent corundum (corundum). Blue is the best, it is light blue, purple blue, green blue, gray blue, etc. There are also a mixture of shades, stripes, and other colors. In particular, there are six strands of citadels called star sapphire. Been used as a gem since ancient times, the larger than ruby is produced, the output is large, the value is behind ruby. The clear, transparent blue was used as a first-class jewel, and was used early as a jewel of the king as a necklace and a ring of high priests. Emeralds are spring, ruby is summer, diamonds are winter, and sapphire symbolizes autumn. It is the birthstone for September and is used as a gift for the 35th anniversary of marriage. This is a sapphire wedding. In addition, in the old days, it was said to remove poisons for medical purposes, to strengthen the heart, and to repair the eyes by looking at the blue ones. Today, it is synthesized artificially, and the quality is indistinguishable from natural stone. It is large in size, without any color unevenness, and there are no flaws or mammals, but most of the bubbles are synthetic products. Mountain ranges include Sri Lanka, Thailand, Myanmar and Cambodia.
The red loess constituting the first mixture is a type of loess, and has a composition as shown in Table 2 below.
As shown in the above table, the content of the components and their deviations, which are not expressed as an exact percentage, vary depending on the source of the loess, but have roughly the following characteristics. It can be understood that it is known enough to be purchased and used. Also called loess. It is widely distributed in the Huanghe River basin, the mainland of China, and also in the Mississippi River basin of the United States and central Europe. The loess of mainland China was transported and deposited by the westerly winds from the deserts in the northwest, and the others were carried in the wind after the glacier retreat. It is yellowish brown and not weathered well, and it is calcified by making angular vertical wall, mainly containing quartz, and containing fluorite and hornblende. Together with glacial sedimentation clay, it becomes the base material for fertile soil such as chernosome under the step climate. It is a general term for soil composed of silica and soil containing hydrous iron oxide and anhydrous iron oxide. It can be easily obtained from all over Korea. Especially, the red soil in Jeollanam-do province contains a lot of iron oxide, so the red energy is strong, and the yellow soil in Gyeongsang-do province is yellowish. Ocher is a honeycomb structure with a large surface, and a large number of spaces have a multi-layer structure. Since ancient times, loess has been used as a living, lifeless soil with tremendous weakness. About a hundred million microorganisms live in one tablespoon of ocher, causing various enzymes to circulate. In addition, the loess contains various enzymes such as diphenol (heavy metal degrading enzyme), oxidase (oxidase), saccharase (sugar degrading enzyme) and protease (protein degrading enzyme). In addition, each of them plays a role in the removal of toxins, degradability, adsorption, fertilizer elements, and purification. In addition, cultivation of microorganisms in ocher makes various antibiotics, so it can be seen that the strong anticancer and antibacterial activity of ocher. Our ancestors have taken advantage of the ability to automatically control the temperature and humidity of the loess. From the old days, ocher has been considered important in oriental medicine, and its drug value, like other herbal medicines, has been recognized as an empirical experience by experience and has been used as a single medicine. There are many examples of minerals and clays used as drugs in Lee Si-jin's Herb Herb, and Heo-jun's Gi-Bo-gam. Yellow soil emits a lot of far-infrared rays as heat is applied. Radiated Gi (氣) can feel the freshness by relieving the fatigue and stress accumulated in every corner of our body and decomposes foreign substances. There are various minerals such as germanium, elvan, macsumite, jade and loess as far infrared emitters, but it has been found that loess has the highest penetration. Far infrared rays of ocher penetrate deep into the skin, which is the most beneficial wavelength among infrared rays, so when heated and heated to ocher, the body heats up in the process of cell activity, increasing body temperature, capillaries expand, and blood circulation As it is activated, significant effects on self-recovery can be expected by promoting metabolism and increasing tissue regeneration. Ocher has a large amount of calcium carbonate (CaCO 3 ), which has a viscosity that is not easily broken by calcium carbonate, and turns water into clay when water is added. The chemical composition of ocher and its effects on the human body are as follows.
Silicon dioxide (SiO 2 ); 50-60%, removal of wastes in the pores.
Aluminum oxide (Al 2 O 3 ); 20-30%, water affinity and skin flexibility increase effect.
Ferric oxide (Fe 2 O 3 ); 5-10%, acts on collagen binding.
Others (MgO, CaO, K 2 O, CuO, ZnO, TiO 2 ); 5 to 10%.
MgO: Works on collagen binding and helps waste / excretion.
CaO: Detoxification.
Ocher is composed of various clay minerals such as quartz, feldspar, mica, and calcite. The unique properties of these minerals double the efficacy of the loess. There are many different types of clay minerals, which are somewhat different in nature, but generally have ion exchange properties. When a clay mineral, ie, loess, is added to a solution in which a cation component is dissolved, substitution occurs between a cation existing in the crystal structure of the clay mineral and a cation dissolved in water. For example, even when heavy metals or radioactive substances are dissolved in water, when minerals such as smectite or zeolite are put into water, the heavy metals and radionuclides are adsorbed to the clay minerals and become heavy metal free water. Clay minerals also react with organic matter, so when you apply ocher to your face, the clay minerals absorb organic matter, such as oil from your skin, to create a clay-organic complex.
Distribution and Function of Minerals (Minerals) in Ocher The mineral distribution function is as follows.
Calcium (Ca); Mostly present in inorganic salts of bones and teeth. Essential for muscle fiber contraction, blood coagulation, increased cell membrane permeability
Phosphorus (P); Mostly present in inorganic salts of bones and teeth. Ingredients involved in almost all metabolic reactions. Present in phosphate in body fluids
Potassium (K); Widely distributed, tends to concentrate on internal cells. Helps regulate intracellular pH Necessary for metabolism promotion, nerve shock conduction and muscle fiber contraction
Sulfur (S); Widely distributed. An essential part of several amino acids, diamines, insulin and biotin
Sodium (Na); Widely distributed, present in large proportion in extracellular fluid and bind to mineral salts of bone. Helps maintain osmotic pressure of cell fluids and balances moisture balance. Necessary for nerve shock conductivity and muscle fiber contraction
Chlorine (Cl); It is closely related to sodium. Helps to maintain the osmotic pressure of the extracellular fluid and adjust the pH, balance the electrolyte, essential for the production of hydrochloric acid, and help transport carbon dioxide by red blood cells
Magnesium (Mg); Rich in bone Required for metabolic reactions in mitochondria and related to ATP production. ATP plays an important role in the conversion to ADP Clay minerals generally contain water, but they also release and absorb water molecules in clay minerals due to changes in humidity.
There was no gynecological disease, such as uterine cancer, in the old women who set fire and fired the fire in the oak-burned firewood. It is known because. This loess is called Furyongan, and the ancestors' ancestors show off the wisdom of preventing diseases in their daily lives. Doenjang, soy sauce, and red pepper paste, which are our traditional foods, are fermented properly and are flavored because of Onggi breathing. At this time, the detoxification of the ocher removes the bad toxicities of the food and does not seal the fresh air so it gives the best taste. It is worth noting that the ancestors of kimjang kimchi are buried in the clay soil and buried in the soil. Also, in the old sayings, there is a saying that it is crust rather than jangmat. Loess far-infrared can also be found in traditional yaktanggi. Traditional herbal baths are said to be more effective because they have a drug extracting effect of about 80 times that of ordinary medicines as well as their decoctions.
The mordenite constituting the first mixture has a formula of (Ca, Na 2 , K 2 ) Al 2 Si 10 O 24 (hexahydrate), a tetragonal system, a density of 2.12 to 2.15, and a hardness of 4 to 5 It is mineral having. Properties are prismatic crystals, fine, acicular to fine fibers, color and gloss are colorless, white, yellow, painted, glass gloss to bright gloss. The main mountain ranges are Canada, Italy, Scotland, Iceland, Yugoslavia, Russia, Japan and New Zealand. Mordenite is a kind of zeolite, and among 19 kinds of natural zeolites, it is the most commonly produced mineral with clinoptilolite.
The mordenite is a hydrous aluminosilicate which contains a small amount of Na, K, Ca, Mg, Sr and Ba as a cation in chemical composition, and in terms of its crystal structure, (Si, Al) O 4 tetrahedron Although all of the oxygens are shared by another tetrahedron, they are three-dimensionally linked to the reticulated silicate minerals (Tectosilicate), but the same mineral minerals, quartz and feldspar, have a dense structure. Has a sloppy structure with a cavity of 2.3 to 7.5 mm 3. In order to compensate the charge defects arising by being substituted in structure Si 4 + Part of this mordenite has a Al 3 + cations are there is to be often involved in the structure, unlike the jangseokryu mordenite forms a structural cavity of in a mineral here Due to the presence of cations, large amounts of water molecules are always introduced into the cavity, depending on the nature of these cations that can be easily replaced by other cations in the surroundings and are also electrostatically strongly charged in the cavity. As a result, a large amount of negative ions are generated. Negative ions generated from mordenite increase the calcium and potassium in the blood, converting the acidic blood into alkalinity, purifying the blood, facilitating nourishment and discharging waste products, and regenerating diseased cells. Increasing antibodies to the virus not only increases resistance to viral infections, but also regulates the autonomic nervous system to energize the blood and nervous system, while generating endorphins and encapparins to restore fatigue, increase stamina and relieve pain. It is known to play a role of, for example.
The mixing ratios of the components constituting the first mixture, that is, biotite, olivine, meteorite, guineastone, sapphire, red loam and mordenite are not selected based on any particular theory, and the inventors' long experience And mixing ratios based on empirical evidence determined to be deemed to be the optimum ratio by the trial and error method (trial and error method), wherein the above ranges, namely 5 to 15 wt% biotite, 1 to 10 By weight percent olivine, 1 to 10% by weight meteorite, 1 to 10% by weight gemstone, 5 to 15% by weight jadeite, 1 to 10% by weight of red loess and the remaining amount of mordenite out of the mixing ratio In view of the short and long term perspectives of the growth and improvement of the soil, it is considered undesirable.
The powder of the first mixture is used by reducing firing, where reducing firing means heating and firing in an atmosphere where oxygen or rare oxygen, that is, oxygen is not sufficiently supplied. An oxygen-free atmosphere or a rare oxygen atmosphere may be achieved, for example, by substituting nitrogen for air in a furnace where firing is performed, but the present invention is not limited thereto. It will be understood by those skilled in the art that such may be accomplished by substitution with non-oxidizing or non-reactive gases.
The raw material mixture is prepared by mixing the reduced calcined product of the first mixture, the reduced calcined product of the vermiculite and the shell meal in a weight ratio of vermiculite: shell meal: first mixture = 1: 1: 2 to 4. The mixing ratio of vermiculite: shell meal: first mixture is also a mixing ratio based on the empirical basis determined by the inventors' long-term experience and the continuous approximation method to be considered as the optimum ratio, which is outside the above ranges. And in view of the short and long term aspects of soil improvement are considered undesirable.
Vermiculite is a mineral belonging to a monoclinic system having a crystal structure such as mica and is also called vermiculite. The color is grayish white or brown with pearlescent luster. Easily decomposes in acids, has a high cation exchange capacity and expands on heating. The chemical composition is C, Mg, Fe3 +, Al 3 (Al, Si) 4 O 10 (OH) 2 (tetrahydrate), which is a clay mineral with hydroxides of aluminum, magnesium and iron. Hardness 1-2 and specific gravity 2.76. Cleavage is complete on the [001] plane. Off-white or brown, pearlescent; Produced in the serpentine zone. It is porous and has good absorption ability, and is widely used as a heat-resistant material and a soundproofing material. The name derives from the Latin verb vermiculare, which is similar to earthworm when heated.
The liquid fertilizer in the slurry-type inorganic natural fertilizer according to the present invention consists of a supernatant of the fermentation product obtained by adding an organic acid at a concentration of 1 to 10% to the raw material mixture obtained as described above and fermenting with a seed of lactic acid bacteria. .
The organic acid may be selected from the group consisting of ascorbic acid (vitamin C), amino acids, succinic acid, malic acid, aspartic acid or a mixture of two or more thereof, but the present invention is not limited thereto. The organic acid increases the organic matter content of the liquid fertilizer, and functions to help the lactic acid fermentation by inhibiting the growth of various bacteria when lactic acid fermentation. The mixing ratio of the raw material mixture and the organic acid may be 1: 0.5 to 1.5 weight ratio. If the mixing ratio of the raw material mixture and the organic acid is out of the above range, there may be a problem that the lactic acid fermentation is not made sufficiently.
The lactic acid fermentation is inoculated with the seed of lactic acid to the mixture obtained by adding an organic acid of 1 to 10% concentration to the raw material mixture, and left to stir for 1 to 2 days at normal fermentation conditions, that is, about 37 ℃ temperature It is to be understood that fermentation may proceed by propagation of lactic acid.
After the lactic acid fermentation as described above, the liquid fertilizer according to the present invention can be obtained by separating only the supernatant which is a liquid part from the fermentation product obtained by filtration or the like.
Solid fertilizer of the inorganic mineral fertilizer in the form of a slurry according to the present invention is characterized in that it consists of solids in the form of sludge remaining after separating the supernatant from the fermentation product.
In addition, the inorganic natural fertilizer in the form of a slurry according to the present invention is characterized in that the solid fertilizer is dispersed in the liquid fertilizer and processed into a slurry form.
Therefore, according to the present invention, both the liquid and solid components produced from the input raw materials can be utilized to fertilize into inorganic mineral fertilizers in the form of slurry, minimizing waste of resources, and in addition to the liquid fertilizers when cultivating crops. It can provide the effect that can expect both long-term effect of short-term effect and long-term soil reform of soil improver by cultivation of crops.
The inorganic natural fertilizer of the slurry form according to the present invention may further include a zeolite. Zeolite is a generic term for minerals that are aluminum silicate hydrates of alkali and alkaline earth metals and are colorless or translucent white. It is also called zeolite and has many kinds, but has a high water content, common properties of crystals, and acid. The hardness is 6, the specific gravity is 2.2, and the color is colorless transparent or white translucent. It is named because it boils and expands when it is heated by duct. Most varieties are dissolved in hydrochloric acid, often glued, but few are not dissolved in hydrochloric acid. The main varieties include the stone, fisheye, caberite, soda-stone, hallandite, steel bite, lomonite, and insite. It is produced in the cavities of the basic igneous rocks such as basalt and tuff, and in the hot pole, and sometimes exists as a secondary mineral in granite and gneiss. It may also be produced in gold or other veins. In the crystal structure, the bonds of the atoms are loose, and even when the moisture filling the spaces is released at a high temperature, the skeleton remains the same, so that other fine particles can be adsorbed. This property is used as an adsorbent and used as a molecular sieve to separate particulates of different sizes. The zeolite may preferably be one having a Cation Exchange Capacity (CEC) of 10 or more. The cation substitution capacity is a concept used when measuring the potential fertility of the soil. The fine particles that can be treated as colloidal particles are called soil colloids. These are fine particles, which have a large surface area and are negatively charged in soil water, which can be easily used by plants such as nitrogen, potassium, magnesium and calcium. It adsorbs nutrients such as superphosphate and makes them available to plants. The ability to adsorb cations by the action of soil colloids is called catioa exchange capacity (CEC) or base displacement capacity. This represents the total amount of substitutional ions possessed by a certain amount of soil in equivalents, which is equal to the number of sites where hydrogen ions can be replaced by cations, i.e., the number of negative charges, per milligram of soil. If the cation substitution capacity is large, it means that there are many cations, but if the hydrogen ion occupies most of the substitution sites, even if the cation substitution capacity is large, it is used to measure the potential fertility. Therefore, in the present invention, by using a zeolite having a cation substitution capacity of 10 or more, it is possible to help crops to absorb and use nutrients.
Method for producing a liquid fertilizer made from natural inorganic resources according to the present invention, (1) 5 to 15% by weight biotite, 1 to 10% by weight olivine, 1 to 10% by weight meteorite, 1 to 10 weight A first mixing step of mixing the mordenite as a residual amount of gemstone, 5 to 15% by weight sapphire, 1 to 10% by weight of red clay, and the remaining amount to obtain a first mixture; (2) a first grinding step of pulverizing the first mixture to 900 to 1100 mesh to powder; (3) a first reduction firing step of reducing-firing the powder of the first mixture at a temperature of 300 to 400 ° C. under an oxygen-free or rare oxygen atmosphere; (4) a second reduction firing step of reducing the calcined powder of vermiculite into 10 to 80 mesh at a temperature of 900 to 1100 ° C. under an oxygen-free or rare oxygen atmosphere; (5) shells obtained by pulverizing the first mixture powder obtained in the first reduction firing step and the vermiculite powder and shell shell obtained in the second reduction firing step in a weight ratio vermiculite: shell meal: first mixture 1: 1: 2nd mixing step of obtaining a raw material mixture by mixing in a ratio of 2 to 4; And (6) a fermentation step of adding the organic acid at a concentration of 1 to 10% to the raw material mixture and fermenting with the seed of lactic acid bacteria to obtain a fermentation product.
The first mixing step of (1) is 5 to 15% by weight of biotite, 1 to 10% by weight of olivine, 1 to 10% by weight of meteorite, 1 to 10% by weight of precious stone, 5 to 15% by weight of It consists of mixing jadeite, 1 to 10% by weight of red clay and the remainder of mordenite as a balance to obtain a first mixture.
The pulverizing step of (2) consists of pulverizing the first mixture to 900 to 1100 mesh.
The first reduction firing step of (3) consists of reducing and firing the powder of the first mixture at a temperature of 300 to 400 ° C. under an oxygen-free or rare oxygen atmosphere.
The second reduction firing step of (4) consists of reducing and firing the powder of vermiculite pulverized vermiculite into 10 to 80 mesh at a temperature of 900 to 1100 ° C. under an oxygen-free or rare oxygen atmosphere.
In the second mixing step of (5), the first mixture powder obtained in the first reduction firing step and the shell powder obtained by grinding the vermiculite powder and the clam shell obtained in the second reduction firing step are vermiculite in a weight ratio. : Shell meal: first mixture = 1: 1: 1 to 2 to 4 by mixing to obtain a raw material mixture.
And the fermentation step of (6) consists of adding the organic acid of the concentration of 1 to 10% to the raw material mixture, fermented to the seed of lactic acid bacteria to obtain a fermentation product.
In the method for preparing a liquid fertilizer according to the present invention as described above, the same or similar descriptions as disclosed in the liquid fertilizer according to the present invention are omitted to avoid repetition.
The organic acid used in the fermentation step may be selected from the group consisting of ascorbic acid (vitamin C), amino acids, succinic acid, malic acid, aspartic acid or a mixture of two or more thereof.
The mixing ratio of the raw material mixture and the organic acid in the fermentation step may be 1: 0.5 to 1.5 weight ratio.
Hereinafter, specific embodiments of the present invention will be described in detail with reference to the accompanying drawings.
Hereinafter, preferred embodiments and comparative examples of the present invention will be described.
The following examples are intended to illustrate the invention and should not be understood as limiting the scope of the invention.
Example 1 to 8
Biotite, olivine, meteorite, jewels, jadeite, reddish earth and mordenite are mixed, but differently mixed as shown in Table 1 below to obtain a first mixture, and the average particle size is about 10 nm by a mill mill (ball mill mill). After grinding to 1000 mesh, the air in the furnace was dried and reduced-fired at about 350 ° C. in a dilute oxygen atmosphere substituted with nitrogen to obtain a first mixture powder, and separately, vermiculite was ground to have an average particle diameter of about 50 mesh. Then, dried and reduced-calcining at about 1000 ° C. in a dilute oxygen atmosphere to obtain vermiculite powder, and the first mixture powder, and shells obtained by pulverizing the vermiculite powder and shells in a weight ratio vermiculite: shell powder: The first mixture was mixed at a ratio of 1: 1: 3 and stirred at room temperature in an agitator for 1 hour to obtain a raw material mixture. To the obtained raw material mixture, succinic acid at a concentration of 5% was added, inoculated with a seed of lactic acid bacteria, and fermented at about 37 ° C. for 2 days. The fermentation products obtained by the fermentation are mixed with liquid fertilizer components and solid fertilizer components to obtain the inorganic mineral fertilizer in the form of slurry according to the present invention in which the solid fertilizer components are dispersed in the liquid fertilizer components and present in the form of slurry. .
Separating the liquid supernatant corresponding to the liquid fertilizer of the inorganic mineral fertilizer in the slurry form to obtain a liquid fertilizer component (Example 1), and the obtained liquid fertilizer component commercialized Inductively Coupled Plasma Optical Emission Elemental analysis was performed using Spectroscopy (ICP-OES), and the results are shown in Table 3 (unit ppm).
Liquid fertilizer
Subsequent experiments were carried out using inorganic natural fertilizers in the form of slurries according to the invention.
Experimental Example One
The inorganic natural fertilizer in the slurry form of Example 1 according to the present invention was used as a cultivation target of the crop, and lettuce was selected as a crop. Lettuce was tested after planting lettuce seedlings grown about 5cm from domestic seedlings. Lettuce can be harvested from 15 days after seedlings (planting seedlings), and then fertilized twice a week before the first harvest after seedlings. Cultivation was carried out by spreading evenly over 15 days after sowing. In addition, as a comparative example, normal lettuce (trade name lettuce (Comparative Example 1) and trade name precooled lettuce (Comparative Example 2)) sold in commercial marts were purchased and contrasted.
Samples were taken from each lettuce and subjected to elemental analysis using a commercially available inductive spectroscopy (ICP-OES), and the results are shown in Table 4 (unit ppm) and Table 5 (Comparative Example: Percentage of Example). Indicated.
division
As shown in Table 4, it was confirmed that the Example (Example 1) fertilized natural fertilizer according to the present invention showed an increase in the mineral content significantly higher than the commercially available products.
The present invention can be used in the industrial field of agriculture, forestry for growing crops, and can also be used in the industry for improving the soil of cropland for growing crops.
Claims (6)
Inorganic natural fertilizer in slurry form, characterized in that the organic acid is selected from the group consisting of ascorbic acid (vitamin C), amino acids, succinic acid, malic acid, aspartic acid or a mixture of two or more thereof.
Inorganic natural fertilizer in the form of a slurry, characterized in that the mixing ratio of the raw material mixture and the organic acid is 1: 0.5 to 1.5 weight ratio.
Inorganic natural fertilizer in the form of a slurry, characterized in that the inorganic mineral fertilizer in the form of a slurry further comprises a zeolite.
Inorganic natural fertilizer in the form of a slurry, characterized in that the zeolite has a Cation Exchange Capacity (CEC) of 10 or more.
(1) 5 to 15% by weight biotite, 1 to 10% by weight olivine, 1 to 10% by weight meteorite, 1 to 10% by weight precious stone, 5 to 15% by weight jadeite, 1 to 10% by weight A first mixing step of obtaining a first mixture by mixing mordenite as a red clay and a residual amount of;
(2) a first grinding step of pulverizing the first mixture to 900 to 1100 mesh to powder;
(3) a first reduction firing step of reducing-firing the powder of the first mixture at a temperature of 300 to 400 ° C. under an oxygen-free or rare oxygen atmosphere;
(4) a second reduction firing step of reducing the calcined powder of vermiculite into 10 to 80 mesh at a temperature of 900 to 1100 ° C. under an oxygen-free or rare oxygen atmosphere;
(5) shells obtained by pulverizing the first mixture powder obtained in the first reduction firing step and the vermiculite powder and shell shell obtained in the second reduction firing step in a weight ratio vermiculite: shell meal: first mixture 1: 1: 2nd mixing step of obtaining a raw material mixture by mixing in a ratio of 2 to 4; And
(6) a fermentation step of adding a 1-10% organic acid to the raw material mixture and fermenting with a seed of lactic acid bacteria to obtain a fermentation product;
Method for producing an inorganic natural fertilizer in the form of a slurry, characterized in that comprises a.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020110054094A KR20120134888A (en) | 2011-06-03 | 2011-06-03 | Slurry type inorganic natural fertilizer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020110054094A KR20120134888A (en) | 2011-06-03 | 2011-06-03 | Slurry type inorganic natural fertilizer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20120134888A true KR20120134888A (en) | 2012-12-12 |
Family
ID=47903018
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020110054094A KR20120134888A (en) | 2011-06-03 | 2011-06-03 | Slurry type inorganic natural fertilizer |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR20120134888A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104557291A (en) * | 2014-12-26 | 2015-04-29 | 中国热带农业科学院分析测试中心 | Production technology of slurry type compound fertilizer |
| CN104788227A (en) * | 2015-04-23 | 2015-07-22 | 国家海洋局第一海洋研究所 | Marine organism fermentation fertilizer and preparation method thereof |
-
2011
- 2011-06-03 KR KR1020110054094A patent/KR20120134888A/en not_active Application Discontinuation
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104557291A (en) * | 2014-12-26 | 2015-04-29 | 中国热带农业科学院分析测试中心 | Production technology of slurry type compound fertilizer |
| CN104788227A (en) * | 2015-04-23 | 2015-07-22 | 国家海洋局第一海洋研究所 | Marine organism fermentation fertilizer and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR102307748B1 (en) | Fertilizer Composition Containing silicate for Hydroponic cutivation of Panax Ginseng | |
| KR100996498B1 (en) | A promoter for growing plants, and a growing method of a plat by using the same | |
| CN104119169B (en) | The production method of medical stone mine tailing compression Nutrition Soil | |
| KR102228276B1 (en) | Organic carbon fertilizer composition using bio-char, and preparation method of the same | |
| KR100643047B1 (en) | Method of Producting of The Biovital-water using material Radiating Far Infared and Mineral | |
| CN104119156B (en) | The production method of diatomite compression Nutrition Soil | |
| CN104119188B (en) | The production method of loess compression Nutrition Soil | |
| CN104140334B (en) | The production method of vermiculite compression Nutrition Soil | |
| CN108718994A (en) | A kind of uniform plant culture soil of dustlessization nutrition | |
| CN104140336B (en) | The production method of phosphorus potassium composite tailing compression Nutrition Soil | |
| CN104119183B (en) | The production method of sylvite ore mine tailing compression Nutrition Soil | |
| WO2015053574A1 (en) | Soil-conditioning or growth-promoting composition for cultivating ginseng | |
| KR100755779B1 (en) | Soil conditioner and its usage using natural minerals | |
| CN104109037B (en) | The production method of basalt mine tailing compression Nutrition Soil | |
| CN104119191B (en) | The production method of wilkinite mine tailing compression Nutrition Soil | |
| CN104109035B (en) | The production method of diatomite mine tailing compression Nutrition Soil | |
| KR20120134888A (en) | Slurry type inorganic natural fertilizer | |
| CN104719233A (en) | Nano-catalysis aquaponics method | |
| CN104109040B (en) | The production method of mica mine tailing compression nutrition soil | |
| KR101922388B1 (en) | Nutritional supplements composition for plant containing mineral powder aqueous solution | |
| CN104119192B (en) | The production method of Rock Phosphate (72Min BPL) mine tailing compression Nutrition Soil | |
| KR102056285B1 (en) | Manufacturing method co cocopeat with tannin-reducing process, and plant treatment agent comprising the cocopeat manufactured by the same | |
| CN104109039B (en) | The production method of sepiolite compression nutrition soil | |
| CN104140335B (en) | The production method of perlite compression Nutrition Soil | |
| CN104119170B (en) | The production method of chlorite mine tailing compression Nutrition Soil |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| N231 | Notification of change of applicant | ||
| WITN | Withdrawal due to no request for examination |