KR20120112278A - A composition of complex fertilizer for plant nutrition comprising atca as an effective component - Google Patents
A composition of complex fertilizer for plant nutrition comprising atca as an effective component Download PDFInfo
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- KR20120112278A KR20120112278A KR1020120040904A KR20120040904A KR20120112278A KR 20120112278 A KR20120112278 A KR 20120112278A KR 1020120040904 A KR1020120040904 A KR 1020120040904A KR 20120040904 A KR20120040904 A KR 20120040904A KR 20120112278 A KR20120112278 A KR 20120112278A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G1/00—Mixtures of fertilisers belonging individually to different subclasses of C05
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Abstract
Description
본 발명은 N-Acetyl thiazolidine carboxylic acid(이하 ATCA)를 이용한 식물영양제용 복합비료 조성물에 관한 내용으로 종래의 복합비료 또는 미량요소복합비료에 ATCA를 1~10중량% 첨가하는 것을 특징으로 한다.
The present invention relates to a composite fertilizer composition for phytonutrients using N-Acetyl thiazolidine carboxylic acid (hereinafter referred to as ATCA), characterized in that 1 to 10% by weight of ATCA added to a conventional fertilizer or a microurea complex fertilizer.
지금까지 식물생장조절제로서 유기화합물로 IAA, Gibberellin 등이 개발되어 다양하게 사용되어 왔다. 최근에는 6-히드록시-3(2H)-피리다지논(MH)이 신규한 식물생장조절제로 개발된 바 있고(특 제1981-0000898호), 또, 2-아릴아미노피리미디온유도체가 식물생장조절제로서 국내특허 공개번호 제1995-7000888호로 공지되어 있다. 또 다른 식물생식생장 증대에 효과적인 식물생장조절제로 국내특허공고번호 제1995-0002854호에 말론산 유도체가 공지된 바 있다. 이와 같은 식물생장조절제 특히 상기 공지된 유기화합물과 유사한 제초제 역할을 할 수 있는 화합물로는 벤조일사이클로헥세논이 국내특허공개번호 제1995-7004233호로 공지되었다.So far, IAA, Gibberellin, etc. have been developed and used as organic compounds as plant growth regulators. Recently, 6-hydroxy-3 (2H) -pyridazinone (MH) has been developed as a novel plant growth regulator (Specific No. 1981-0000898), and 2-arylaminopyrimidion derivatives As a growth regulator, it is known as Korean Patent Publication No. 1995-7000888. Malonic acid derivatives have been known in Korea Patent Publication No. 1995-0002854 as an effective plant growth regulator to increase the plant reproductive growth. Such a plant growth regulator, in particular, a compound that can act as a herbicide similar to the known organic compound is benzoylcyclohexenone is known in Korea Patent Publication No. 1995-7004233.
그러나 상기와 같은 유기화합물은 대체로 특정식물에 대한 선택적 제초제(Selective herbicide)로 작용하고 농작물의 영양생장과 생식생장을 동시에 수행할 수는 없는 것들이었다.However, such organic compounds generally acted as selective herbicides for specific plants and were unable to simultaneously carry out nutritional and reproductive growth of crops.
한편, 농작물의 영양생장과 생식생장은 동시에 증대시키므로서 증수효과를 유도할 수 있는 복합비료 조성물로는 복합희토류금속(RExOy)을 미량요소에 첨가하는 희토복합비료 조성물이 국내특허등록 제10-0401556호로 공지된 바 있고, 탄산칼슘(CaCO3)을 42%이상 혼합하는 복합비료 조성물은 국내특허등록 제10-0401419호에 개시되어 있으며 셀레늄염 예컨대, Na2SeO4 무기물을 0.001~35% 범위의 유효성분으로 하여 인체암 예방을 목적으로 하는 복합비료 조성물은 국내특허등록 제10-0543525호에 개시되어 있다. 그러나 상기 무기화합물은 식물체내에서 유기화가 이루어지기 어려워 그 실제적인 효과가 의문시되고 있는 단점이 있다.
On the other hand, as a complex fertilizer composition which can increase the nutrient growth and reproductive growth of crops at the same time and induce a water increase effect, a rare earth complex fertilizer composition which adds a complex rare earth metal (RExOy) to trace elements is registered in Korea Patent No. 10-0401556 Known as No., the composite fertilizer composition for mixing more than 42% of calcium carbonate (CaCO 3 ) is disclosed in Korean Patent Registration No. 10-0401419 and the selenium salt, such as Na 2 SeO 4 inorganic material in the range of 0.001 ~ 35% A composite fertilizer composition for the purpose of preventing human cancer as an active ingredient is disclosed in Korean Patent Registration No. 10-0543525. However, the inorganic compound has a disadvantage that the practical effect is questioned because it is difficult to be organicized in the plant.
본 발명은 상기와 같이 IAA 또는 지베렐린을 제외한 유기화합물들은 특정 생육단계에서 특정식물에 영양생장 또는 생식생장을 저해하여 선택적 제초제로서 사용될 수 밖에 없는 단점이 있거나, 무기화합물의 경우 농작물의 영양생장과 생식생장을 균형있게 조절하지 못할 뿐만 아니라 토양 또는 엽면 살포 후 용이하게 물에 의해 용탈되거나 식물이 흡수한다 하더라도 그 효과가 의심스럽다는 문제점들을 감안하여 안출하였다.The present invention has the disadvantage that organic compounds other than IAA or gibberellin as described above may be used as a selective herbicide by inhibiting nutrient growth or reproductive growth in a specific plant at a specific growth stage, or in the case of inorganic compounds, nutrient growth and reproduction of crops Not only did they not control the growth in a balanced manner, but they were devised in view of the problem that the effect is doubtful even if they are easily leached by water or absorbed by plants after the soil or foliar spraying.
본 발명은 유기화합물 중 식물성장조절제로서 N-Acetyl thiazolidine carboxylic acid(ATCA)를 유효성분으로 함유하는 복합비료 조성물을 제공하는데 그 목적이 있다.
It is an object of the present invention to provide a complex fertilizer composition containing N-Acetyl thiazolidine carboxylic acid (ATCA) as an active ingredient as a plant growth regulator among organic compounds.
본 발명의 상기 목적은 엘-시스테인(L-cystein) 유도체인 ATCA를 1~10중량% 함유하는 미량요소 복합비료 조성물을 제조하는 단계; 상기 미량요소 복합비료 조성물을 대조구와 구분하여 과채류의 수량, 생육, 품질에 미치는 영향을 조사하는 단계로 구성하고 그 결과를 평가함으로써 달성하였다.
The above object of the present invention is to prepare a microurea composite fertilizer composition containing 1 to 10% by weight of ATCA which is an L-cysteine derivative; The trace urea composite fertilizer composition was distinguished from the control, consisting of the step of investigating the effect on the yield, growth, quality of fruit and vegetables was achieved by evaluating the results.
본 발명은 식물생장조절제 ATCA 유기화합물의 첨가에 의하여 식물생육과 생물학적 특성을 개선하는 효과가 있으며 그 결과 과일의 증산 및 품질향상에 뛰어난 효과가 있다.
The present invention has the effect of improving the plant growth and biological properties by the addition of the plant growth regulator ATCA organic compound and as a result has an excellent effect on the transpiration and quality of the fruit.
실시예 1 Example 1 미량요소 복합비료 조성물Trace Urea Complex Fertilizer Composition
하기 표 1과 같이 몰리브덴소다, 붕산의 미량성분 2종과 ATCA를 1중량%이상 10중량%까지, 가장 바람직하게는 5중량%를 혼합하고 수용성 붕소 0.05중량%이상 바람직하게는 0.017중량%, 수용성 몰리브덴 0.001중량% 이상 바람직하게는 0.02중량%를 보충성분으로 하는 미량요소복합비료를 제조하였다. 한편, 식물의 생리활성 증가로 인한 열매의 물러지는 현상을 방지하는 목적으로 초산 및 질산 마그네슘과 초산 칼슘을 따로 보충하였다.
As shown in Table 1, two trace components of molybdenum soda and boric acid and ATCA are mixed in an amount of 1% by weight to 10% by weight, most preferably 5% by weight, and 0.05% by weight of water-soluble boron, preferably 0.017% by weight, water-soluble. A trace element composite fertilizer having a molybdenum content of 0.001% by weight or more and preferably 0.02% by weight as a supplement was prepared. On the other hand, supplemented with magnesium acetate and magnesium nitrate and calcium acetate separately for the purpose of preventing the fall of the fruit caused by the increase of physiological activity of the plant.
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실시예 2Example 2 복합비료 조성물Compound Fertilizer Composition
하기 표 2와 같이 질소, 인산, 가리와 미량요소를 혼합한 복합비료에 ATCA를 1중량% 이상, 가장 바람직하게는 5중량%를 첨가하고 질소 6중량%, 인 2중량%, 칼륨 5중량%, 붕소 0.05중량%, 몰리브덴 0.001중량%, 고토 0.05중량%, 구리 0.02중량%, 아연 0.03중량% 이상을 보충 성분으로 하는 복합비료를 제조하였다.As shown in Table 2, 1% by weight or more, most preferably 5% by weight of ATCA, and 6% by weight of nitrogen, 2% by weight of phosphorus, and 5% by weight of potassium in a fertilizer mixed with nitrogen, phosphoric acid, and garlic and trace elements. , A compound fertilizer containing 0.05% by weight of boron, 0.001% by weight of molybdenum, 0.05% by weight of clay, 0.02% by weight of copper, and 0.03% by weight of zinc as a supplement.
실험예 1 Experimental Example 1 미량요소 복합비료 시용 시험Trace element compound fertilizer application test
실시예 1의 미량요소복합비료와 실시예1에서 ATCA를 제외한 미량요소복합비료를 제조하여 아래와 같이 토마토의 생육시험을 실시하였다.The trace urea complex fertilizer of Example 1 and the trace urea complex fertilizer except for ATCA in Example 1 was prepared and subjected to the growth test of tomatoes as follows.
비닐하우스에서 처리구당 시험면적 15m2(1.5m×10m)로 하여 임의배치법 3반복으로 정식후 10일 간격으로 3회 토양살포하였고, 처리 방법은 표3과 같다.The soil area was sprayed three times at 10-day intervals after the formulation by three repetitions of the randomization method with a test area of 15m 2 (1.5m × 10m) per treatment zone in the plastic house.
재배실험 결과는 표4 같이 ATCA가 혼합된 미량요소복합비료가 혼합되지 않은 처리구에 비해 주당과수는 약 7%, 주당과중은 약 12%, 총수량은 13%의 증대 효과가 있었다.
The results of the cultivation experiments showed that the fruit per week was about 7%, the fruit weight per week was about 12%, and the total yield was 13%, compared to the treatment group without mixed ATCA mixed fertilizer.
실험예 2 Experimental Example 2 복합비료 시용 시험Compound Fertilizer Application Test
상기 실험예 1과 같은 방법으로 실시예1과 실시예2에서 ATCA를 제외한 복합비료를 제조하여 토마토의 생육과 품질에 미치는 영향을 조사하였고, 그 결과는 표 5, 6과 같다.
In the same manner as in Experimental Example 1 was prepared in Example 1 and Example 2 composite fertilizer except ATCA to investigate the effect on the growth and quality of tomatoes, the results are shown in Tables 5 and 6.
실험결과 ATCA가 혼합된 복합비료가 혼합되지 않은 처리구에 비해 품질면에서 엽장, 엽폭, 경경, 엽록소 수치에 있어 3~12%의 증대 효과가 있었고, 품질면에서는 과장 12%, 과폭 12%, 주당과수는 약 7%, 평균과중 12%, 당도 3% 이상의 증대 효과가 확인되었다. Experimental results showed that 3 ~ 12% increase in leaf, leaf width, diameter, and chlorophyll levels in quality compared to non-mixed fertilizer containing ATCA, and in terms of quality, 12%, 12%, and 12% per week. Fruits were found to increase about 7%, average fruit 12%, and sugar content 3% or more.
본 발명에서 ATCA의 혼합비가 10중량% 이상일 때에는 토양 수중에서 상기 화합물이 클러스터(Cluster)를 형성하여 흡수율이 저하될 뿐 아니라, 따라서 시용효과도 떨어진다.In the present invention, when the mixing ratio of ATCA is 10% by weight or more, the compound forms a cluster in the soil water and thus the absorption rate is lowered.
본 발명의 상기 실험예에서 획득할 수 있는 효과는 다른 성분은 동일하고 토양살포하는 대신 본 발명의 식물생장조절제 ATCA 20~200ppm만을 별도로 정식후 40일부터 10일 간격으로 3~5회 엽면 살포하여도 동일한 효과를 달성할 수 있었다.The effect that can be obtained in the above experimental example of the present invention is the same as the other components and instead of spraying the soil, the plant growth regulator ATCA of the present invention by spraying three to five leaf planes at intervals of 40 to 10 days after the formulation separately. The same effect could be achieved.
본 발명에서는 토마토를 공시재료로 사용하였으나, 기타 오이, 가지, 호박, 고추 등의 과채류에도 동일한 규모의 효과가 있음이 확인되었다.In the present invention, the tomato was used as a test material, but it was confirmed that the same scale effect was found in other vegetables, such as cucumbers, eggplants, pumpkins, peppers, and the like.
본 발명에서 상기 ATCA 엽면 시미시 농도가 200ppm이 초과되는 경우, 수중에서 화합물의 분자 클러스터 형성에 의해 점도가 높아져 흡수율이 저하되고 따라서 효과도 저하된다.
In the present invention, when the ATCA foliar seashish concentration exceeds 200 ppm, the viscosity increases due to the formation of molecular clusters of the compound in water, so that the absorption rate is lowered and thus the effect is also lowered.
이상에서 확인할 수 있는 바와 같이 본 발명 식물생장조절제용 유기화합물 ATCA가 첨가되어 이를 유효성분으로 하는 미량요소 복합비료 또는 복합비료 조성물은 토마토 등 원예작물의 영양 및 생식생장에 균등한 생육촉진효과가 있으므로 비료산업 및 작물재배산업상 매우 유용한 발명인 것이다.As can be seen above, the microelement complex fertilizer or composite fertilizer composition of the present invention, which is an organic compound ATCA is added to the plant growth regulator as an active ingredient, has an even growth promoting effect on the nutrition and reproductive growth of horticultural crops such as tomatoes. It is a very useful invention in the fertilizer industry and crop cultivation industry.
Claims (1)
N-Acetyl thiazolidine carboxylic acid (ATCA) is one of tomato, cucumber, eggplant, pumpkin and red pepper, characterized in that the leaves are sprayed with 20 ~ 200ppm concentration from 3 to 5 times at intervals of 40 to 10 days after the establishment of fruit vegetables. How to grow crops.
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Cited By (5)
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| CN104885755A (en) * | 2015-06-01 | 2015-09-09 | 广西大学 | Planting method allowing hairy gourd quality improvement |
| CN110881468A (en) * | 2019-12-12 | 2020-03-17 | 郑州郑氏化工产品有限公司 | Crop growth regulator composition and application thereof |
| KR20200030285A (en) * | 2018-09-12 | 2020-03-20 | 동아대학교 산학협력단 | Chelate selenium plant nutrition for selenium production |
| CN111763115A (en) * | 2020-07-08 | 2020-10-13 | 郑州郑氏化工产品有限公司 | Fertilizer synergist and preparation method and application thereof |
| KR20210101727A (en) * | 2020-02-11 | 2021-08-19 | (주)아미노피아 | Selenium-containing strawberry cultivation method and processed foods comprising strawberries grown through its |
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2012
- 2012-04-19 KR KR1020120040904A patent/KR20120112278A/en not_active Application Discontinuation
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104885755A (en) * | 2015-06-01 | 2015-09-09 | 广西大学 | Planting method allowing hairy gourd quality improvement |
| KR20200030285A (en) * | 2018-09-12 | 2020-03-20 | 동아대학교 산학협력단 | Chelate selenium plant nutrition for selenium production |
| CN110881468A (en) * | 2019-12-12 | 2020-03-17 | 郑州郑氏化工产品有限公司 | Crop growth regulator composition and application thereof |
| CN110881468B (en) * | 2019-12-12 | 2021-07-30 | 郑州郑氏化工产品有限公司 | Crop growth regulator composition and application thereof |
| KR20210101727A (en) * | 2020-02-11 | 2021-08-19 | (주)아미노피아 | Selenium-containing strawberry cultivation method and processed foods comprising strawberries grown through its |
| CN111763115A (en) * | 2020-07-08 | 2020-10-13 | 郑州郑氏化工产品有限公司 | Fertilizer synergist and preparation method and application thereof |
| CN111763115B (en) * | 2020-07-08 | 2022-06-10 | 郑州郑氏化工产品有限公司 | Fertilizer synergist and preparation method and application thereof |
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