KR20120111319A - Pheromonal compounds for induction and control of scrobipalpa salinella and uses thereof - Google Patents
Pheromonal compounds for induction and control of scrobipalpa salinella and uses thereof Download PDFInfo
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Abstract
Description
본 발명은 퉁퉁마디뿔나방 암컷이 분비하는 성페로몬 성분을 이용한 퉁퉁마디뿔나방 유인, 방제용 성페로몬 조성물 및 이의 용도에 관한 것이다.
The present invention relates to a horn horn moth attracting, sperm pheromone composition for control and its use using a sex pheromone component secreted by the horned moth female.
일반적으로 퉁퉁마디(學名: Salicornia herbacea, 英名: glasswort)는 우리나라 서남해안 갯벌에서 자라는 한해살이풀로 알려져 있으며, 바닷물과 가까운 갯벌이나 염전 주위에 무리지어 분포되어 있다. 퉁퉁마디는 맛이 몹시 짜며 지구상에서 유일하게 염분을 흡수하면서 자라는 식물로서 Na를 비롯하여 Ca, Mg, K, Fe 등 갖가지 미네랄이 풍부하게 함유되어 있고, 그 이용가치가 점차적으로 높아지고 있다. Salicornia in general herbacea (English: glasswort) is a perennial herb that grows on the tidal flats of the southwestern coast of Korea and is distributed in groups around tidal flats and salt fields close to seawater. Stalk is very salty and is the only plant on the planet that absorbs salt. It is rich in various minerals such as Na, Ca, Mg, K, and Fe, and its value is gradually increasing.
현재 퉁퉁마디뿔나방이 퉁퉁마디 재배지역에서 큰 피해를 주고 있다. 퉁퉁마디뿔나방(Scrobipalpa salinella)은 그 유충이 퉁퉁마디(함초)의 줄기에 거미줄을 치고 엽육을 갉아 먹으며, 피해가 심할 경우에는 퉁퉁마디를 전혀 수확할 수 없게 된다.The horned horn moth is now causing great damage in the cultivated area. Scrobipalpa salinella , whose larvae hit spider webs on the stems of the stalks, eats the leafy flesh , and, in the case of severe damage, the stalks cannot be harvested at all.
재배농가 및 산업체에서는 퉁퉁마디뿔나방에 의한 피해를 해결하기 위한 연구 및 노력을 기울이고 있으나, 친환경적으로 재배되는 퉁퉁마디의 특성 때문에 농약 등을 이용한 해충 방제가 힘들며, 현재까지 마땅한 방제 방법이 개발되어 있지 않은 실정이다.
Cultivated farmers and industries have been researching and making efforts to solve the damage caused by the horned moth, but it is difficult to control pests by using pesticides due to the characteristics of the cultivated eco-friendly cultivars, and no proper control methods have been developed so far. It is true.
이에, 본 발명자들은 퉁퉁마디뿔나방(Scrobipalpa salinella)에 의한 퉁퉁마디 피해를 막기 위해 친환경적인 방제 방법을 연구, 노력한 결과, 퉁퉁마디뿔나방(Scrobipalpa salinella)의 성페로몬을 이용한 방제 방법을 고안하여, 이를 위해 퉁퉁마디뿔나방 암컷의 성페로몬을 최초로 동정하여 수컷 성충의 유인에 가장 적합한 조성물을 탐색 후 이를 적용한 결과, 퉁퉁마디뿔나방(Scrobipalpa salinella)에 의한 퉁퉁마디 피해를 획기적으로 감소시킬 수 있음을 발견함으로써 본 발명을 완성하게 되었다.The present inventors have studied the eco Salicornia horns moth control methods to prevent damage caused by the Salicornia (Scrobipalpa salinella), the result sought, Salicornia horns moth (Scrobipalpa Salinella ) was designed to control the sex pheromone, and for this purpose, we first identified the sex pheromone of females, and then found the most suitable composition for attracting adult males, and applied it as a result. Scrobipalpa salinella The present invention has been completed by discovering that it is possible to drastically reduce the damage caused by bumps.
따라서 본 발명은 퉁퉁마디뿔나방의 성페로몬 유래 물질을 이용한 퉁퉁마디뿔나방의 유인 또는 방제용 조성물을 제공하는 것을 그 목적으로 한다.Accordingly, an object of the present invention is to provide a composition for attracting or controlling a ragged moth moth using a sex pheromone-derived material of rhododendron moth.
또한 본 발명은 상기 퉁퉁마디뿔나방 유인 또는 방제용 조성물을 포함하는 것을 특징으로 하는 페로몬트랩 또는 교미교란제를 제공하는 것을 또 다른 목적으로 한다.
It is another object of the present invention to provide a pheromone trap or mating disturbance agent comprising the composition for attracting or controlling the rhabdomite moth.
상기 과제를 해결하기 위해,In order to solve the above problems,
본 발명은 (Z)-3-도데세닐아세테이트, (E)-3-도데세닐아세테이트 및 (Z)-5-도데세닐아세테이트로 이루어진 군에서 선택된 1 종 이상의 화합물을 포함하는 것을 특징으로 하는 퉁퉁마디뿔나방 유인 또는 방제용 조성물을 제공한다.The present invention comprises at least one compound selected from the group consisting of (Z) -3-dodecenyl acetate, (E) -3-dodecenyl acetate and (Z) -5-dodecenyl acetate. Provided is a horn moth attraction or control composition.
또한 본 발명은 상기 퉁퉁마디뿔나방 유인 또는 방제용 조성물을 포함하는 페로몬트랩 또는 교미교란제를 제공한다.
In another aspect, the present invention provides a pheromone trap or copious disturbance agent comprising the composition for attracting or controlling the rhododendron moth.
본 발명에 따른 퉁퉁마디뿔나방 유인, 방제용 성페로몬 조성물은 퉁퉁마디뿔나방 수컷의 유인에 가장 적합한 페로몬 루어(미끼)로써, 퉁퉁마디뿔나방에 의한 퉁퉁마디의 피해를 조기에 예방할 수 있으며, 이를 대량유살 및 교미교란제로 제작하여 친환경적 방제 농자재로 활용할 수 있다는 장점이 있다. 또한 방제제의 국산화로 외화 절감이 가능하며, 친환경적으로 퉁퉁마디를 생산하는데 기여할 수 있다.
The horned horn moth attracting and controlling sex pheromone composition according to the present invention is the most suitable pheromone lure (bait) for attracting horned horned moth males, and can prevent the damage of the horned ear by the horned horn moth, It has the advantage that it can be used as an environmentally friendly agricultural material by producing it as a mass killing and mating disturbance agent. In addition, it is possible to reduce the foreign currency by localization of the preservatives, and contribute to the production of lumps in an eco-friendly way.
도 1은 퉁퉁마디뿔나방 암컷 성페로몬샘 추출물의 GC-MS 분석 결과이다.
도 2는 야외에서 Z3-12:OAc와 Z5-12:OAc 혼합조성 페로몬 성분(standard)과 단독처리 페로몬 성분이 퉁퉁마디뿔나방 수컷 유인력에 미치는 영향을 나타낸 그래프이다.
도 3은 야외에서 페로몬 조성별 퉁퉁마디뿔나방 수컷 유인효과를 나타낸 그래프이다(Tukey's test: P>0.05).
도 4는 페로몬 트랩에 유인된 퉁퉁마디뿔나방 수컷 성충을 나타낸 사진이다.Figure 1 shows the results of GC-MS analysis of the female sex pheromone extract of the horned horn moth female.
Figure 2 is a graph showing the effect of Z3-12: OAc and Z5-12: OAc mixed composition pheromone (standard) and single-treated pheromone on the male attraction of male hornworm moth.
3 is a graph showing the attracting effect of male horned moth male according to the composition of pheromone in the open air (Tukey's test: P> 0.05).
Figure 4 is a photograph showing the male adult male snapper moth attracted to the pheromone trap.
본 발명에서는 이제까지 밝혀지지 않았던 퉁퉁마디뿔나방의 성페로몬을 최초로 동정하였으며, 상기 동정한 물질의 분석 및 퉁퉁마디뿔나방 유인에 적합한 최적 조성비를 밝혀내어 퉁퉁마디뿔나방의 유인 및 방제에 극대화된 효과를 나타내는 조성물을 제공하는 것을 주요 특징으로 한다.In the present invention, the sex pheromone of the horned rhinoceros moth has not been identified for the first time, and the optimum composition ratio for the analysis and identification of the horned rhinoceros moth attracted to maximize the effect of attracting and controlling the horned rhinoceros moth It is a main feature to provide a composition which shows.
본 발명은 퉁퉁마디뿔나방으로부터 퉁퉁마디(함초)를 친환경적으로 방제하기 위한 성페로몬 조성물에 관한 것으로서, 보다 구체적으로 (Z)-3-도데세닐아세테이트(Z3-12:OAc), (E)-3-도데세닐아세테이트(E3-12:OAc) 및 (Z)-5-도데세닐아세테이트(Z5-12:OAc)로 이루어진 군에서 선택된 1 종 이상의 화합물을 포함하는 퉁퉁마디뿔나방 유인 또는 방제용 조성물 및 이를 이용한 교미교란제 또는 페로몬트랩에 관한 것이다.The present invention relates to a sex pheromone composition for environmentally friendly control of spurs (seaweed) from spurs, more specifically (Z) -3-dodecenyl acetate (Z3-12: OAc), (E)- 3-Dodecenyl Acetate (E3-12: OAc) and (Z) -5-Dodecenyl Acetate (Z5-12: OAc) composition comprising one or more compounds selected from the group consisting of horn horn moth attracting or controlling And it relates to a mating disturbance agent or pheromone trap using the same.
이하, 이들을 구체적으로 설명한다.Hereinafter, these are demonstrated concretely.
본 발명의 퉁퉁마디뿔나방 유인 또는 방제용 조성물은 (Z)-3-도데세닐아세테이트, (E)-3-도데세닐아세테이트 및 (Z)-5-도데세닐아세테이트로 이루어진 군에서 선택된 1 종 이상의 화합물을 포함한다.At least one member selected from the group consisting of (Z) -3-dodecenyl acetate, (E) -3-dodecenyl acetate and (Z) -5-dodecenyl acetate Compound.
보다 바람직하게는 (Z)-3-도데세닐아세테이트를 필수적으로 포함하며, (E)-3-도데세닐아세테이트 및 (Z)-5-도데세닐아세테이트 중 선택된 하나 이상의 화합물을 포함하는 형태로 사용하는 것이 퉁퉁마디뿔나방 유인 또는 방제에 보다 우수한 효과를 나타내므로 바람직하다. More preferably (Z) -3-dodecenyl acetate, and (E) -3-dodecenyl acetate and (Z) -5-dodecenyl acetate. It is preferable because it shows a better effect on attracting or controlling the ragged moth.
상기 조성물간의 사용비는 제한되지는 않으나, 바람직하게는 (Z)-3-도데세닐아세테이트 100 중량부에 대하여, (E)-3-도데세닐아세테이트 및 (Z)-5-도데세닐아세테이트 중 선택된 하나 이상의 화합물을 1 ~ 20 중량부로 포함하는 것이 바람직하며, 보다 바람직하게는 5 ~ 15 중량부로 포함하는 것이 퉁퉁마디뿔나방 유인에 가장 우수한 효과를 나타내므로 좋다.The use ratio between the compositions is not limited, but is preferably selected from (E) -3-dodecenyl acetate and (Z) -5-dodecenyl acetate with respect to 100 parts by weight of (Z) -3-dodecenyl acetate. It is preferable to include 1 to 20 parts by weight of one or more compounds, and more preferably, 5 to 15 parts by weight is preferable because it shows the best effect on attracting moth.
상기 (Z)-3-도데세닐아세테이트(Z3-12:OAc), (E)-3-도데세닐아세테이트(E3-12:OAc) 및 (Z)-5-도데세닐아세테이트(Z5-12:OAc) 화합물은 퉁퉁마디뿔나방 암컷 성페로몬샘으로부터 분리가 가능하며, 예를 들어, 암컷의 복부 끝에 위치한 성페로몬 샘(gland)을 유기용매에 넣어 추출하는 방법으로 분리할 수 있다.(Z) -3-dodecenyl acetate (Z3-12: OAc), (E) -3-dodecenyl acetate (E3-12: OAc) and (Z) -5-dodecenyl acetate (Z5-12: OAc The compound can be separated from the female sex pheromone gland, and, for example, it can be separated by extracting the sex pheromone gland located in the female abdomen in an organic solvent.
상기 화합물을 포함하는 본 발명의 퉁퉁마디뿔나방 유인 또는 방제용 조성물은 당업계에 공지된 방법을 사용하여 다양한 형태로 제조할 수 있으며, 예를 들어, (Z)-3-도데세닐아세테이트(Z3-12:OAc)와 (E)-3-도데세닐아세테이트(E3-12:OAc)를 유기용매 속에서 혼합하여 고무격막(rubber septa) 등 담체에 침적하여 유기용매는 휘발시키고 페로몬 성분만 담체에 스며들게 하여 제조할 수 있다.Compositions for attracting or controlling the rhabdomyomoth moth of the present invention comprising the compound may be prepared in various forms using methods known in the art, for example, (Z) -3-dodecenyl acetate (Z3). -12: OAc) and (E) -3-dodecenyl acetate (E3-12: OAc) are mixed in an organic solvent and deposited on a carrier such as a rubber septa to volatilize the organic solvent and only the pheromone component to the carrier. It can be made to soak.
본 발명에 따른 퉁퉁마디뿔나방 유인 또는 방제용 조성물은 다양한 제형으로 제조하여 퉁퉁마디뿔나방의 유인 또는 방제제로 사용할 수 있다. 본 발명의 상기 제형의 형태는 당업계에서 통상적으로 제조되는 어떠한 제형으로도 제조될 수 있으며, 예를 들어 용액, 에멀전, 현탁액, 유탁액, 페이스트, 겔제, 크림제, 오일, 분말, 왁스 및 스프레이제 등으로 제형화할 수 있으나 이에 한정되는 것은 아니다.According to the present invention, the horned moth attracting or controlling composition can be prepared in various formulations and used as an attractant or controlling agent of the horned moth. The form of the formulation of the present invention may be prepared in any formulation conventionally prepared in the art, for example, solutions, emulsions, suspensions, emulsions, pastes, gels, creams, oils, powders, waxes and sprays It may be formulated as a formulation, but is not limited thereto.
본 발명의 제형이 크림제인 경우에는 첨가제로서 에틸 알콜, 물 또는 프로필렌 글리콜과 같은 액상의 희석제, 라놀린 오일, 아세틸화 라놀린 알콜(Acetylated lanolin alcohol), 세틸 알콜, 스테아릴 알콜, 비스왁스, BHT, 알킬파라벤 등이 이용될 수 있다. 본 발명의 제형이 겔제 형태인 경우에는 첨가제로서 알킬렌 글리콜, 물, 카보머 940 등이 이용될 수 있다. 본 발명의 제형이 스프레이제인 경우에는 첨가제로서 물, 에틸 알콜 또는 프로필렌 글리콜과 같은 액상의 희석제 등이 이용될 수 있다.When the formulation of the present invention is a cream, as an additive, a liquid diluent such as ethyl alcohol, water or propylene glycol, lanolin oil, acetylated lanolin alcohol, cetyl alcohol, stearyl alcohol, biswax, BHT, alkyl Parabens and the like can be used. When the formulation of the present invention is in gel form, alkylene glycol, water, carbomer 940 and the like may be used as additives. When the formulation of the present invention is a spray, a liquid diluent such as water, ethyl alcohol or propylene glycol may be used as an additive.
본 발명에 따른 퉁퉁마디뿔나방 유인 또는 방제용 조성물은 해충 예찰 및 친환경적 방제제인 교미교란제로 활용이 가능하며, 예를 들어 본 발명에 따른 퉁퉁마디뿔나방 유인 또는 방제용 조성물을 포함하는 교미교란제 또는 페로몬트랩 형태로 제작하여 사용할 수 있다.The horn bitter moth attracting or controlling composition according to the present invention can be utilized as a pest antagonist that is pest pest observation and environmentally friendly control agent, for example, a copulation disturbance agent comprising the horn moth attracting or controlling composition according to the present invention. Alternatively, the pheromone trap may be manufactured and used.
보다 구체적으로 본 발명에 따른 퉁퉁마디뿔나방 유인 또는 방제용 조성물은 퉁퉁마디 주변에 설치하여 사용되며, 퉁퉁마디를 가해하는 퉁퉁마디뿔나방의 교미를 교란시키는 교미교란제로 사용될 수 있다. 예를 들면, 본 발명의 퉁퉁마디뿔나방 유인 또는 방제용 조성물을 크림 형태로 제조하여 퉁퉁마디의 원하는 부위에 부착시켜 사용할 수 있다. 그러나 본 발명 페로몬 조성물의 사용방법이 이에 한정되는 것은 아니며, 주변환경에 따라 사용방법이 달라질 수 있는데, 퉁퉁마디 주변에서 페로몬을 방출하여 해충의 교미교란을 유도할 수 있는 모든 사용방법이 적용 가능하다. 또한, 보다 바람직하게는 비처리 지역으로부터의 해충 수컷의 이동을 막기 위해 농작물 주변에 먹이트랩을 배치하여 상기 페로몬 조성물과 함께 사용할 수 있다. 또, 필요에 따라 사용 시 전착제를 혼합하여 사용할 수 있다. 본 발명의 페로몬 조성물을 사용하는 방제방법은 교미교란에 의해 해충이 방제될 수 있는 모든 농작물에 적용될 수 있으며, 특히 퉁퉁마디뿔나방이 가해하는 모든 염생식물에 적용될 수 있다.More specifically, the horn horn moth attracting or controlling composition according to the present invention is used by installing around the horn, and can be used as a mating disturbance agent to disturb the copulation of the horn horn moth. For example, the horn horn moth attracting or controlling composition of the present invention may be prepared in the form of a cream and attached to a desired portion of the horn. However, the method of using the pheromone composition of the present invention is not limited thereto, and the method of use may vary depending on the surrounding environment. . In addition, more preferably, a food trap may be disposed around the crop to prevent movement of the pest male from the untreated area and used with the pheromone composition. In addition, when used, it is possible to mix and use an electrodeposition agent. The control method using the pheromone composition of the present invention can be applied to all crops that can be controlled by pests disturbed by mating disturbance, in particular can be applied to all salt plants to which the rhizome moth is added.
본 발명에 따른 페로몬 트랩의 경우 예를 들어, (Z)-3-도데세닐아세테이트(Z3-12:OAc)와 (E)-3-도데세닐아세테이트(E3-12:OAc)의 혼합물을 침적한 고무격막을 끈끈이판이 삽입된 해충 유인용 트랩의 미끼(루어)로 사용하여 야외에 설치함으로써 퉁퉁마디뿔나방으로부터 효과적으로 퉁퉁마디를 보호할 수 있다.
In the case of the pheromone trap according to the invention, for example, a mixture of (Z) -3-dodecenyl acetate (Z3-12: OAc) and (E) -3-dodecenyl acetate (E3-12: OAc) was deposited. The rubber diaphragm can be used outdoors as a lure of a pest attraction trap with a sticky plate inserted to effectively protect it from the horn moth.
이하 본 발명의 내용을 실시예 및 시험예를 통하여 구체적으로 설명한다. 그러나, 이들은 본 발명을 보다 상세하게 설명하기 위한 것으로 본 발명의 권리범위가 이들에 의해 한정되는 것은 아니다.
Hereinafter, the present invention will be described in detail with reference to Examples and Test Examples. However, these are for the purpose of illustrating the present invention in more detail, and the scope of the present invention is not limited thereto.
실시예Example 1: One: 퉁퉁마디뿔나방Horned Horn Moth 암컷의 페로몬 성분의 추출 및 분석 Extraction and Analysis of Pheromone Components in Females
퉁퉁마디뿔나방 성충의 교미가 주로 이루어지는 야간에 아직 교미를 하지 않은 암컷 성충을 포획하여, 성페로몬 샘이 위치하고 있는 복부 끝마디를 가위로 잘라 유기용매(hexane)에 넣어 추출물을 얻었다. 상기 얻어진 추출물을 DB-23 칼럼이 장착된 GC-MS로 분석한 결과, 퉁퉁마디뿔나방 암컷이 분비하는 성페로몬 성분은 (Z)-3-도데세닐아세테이트(Z3-12:OAc), (E)-3-도데세닐아세테이트(E3-12:OAc) 및 (Z)-5-도데세닐아세테이트(Z5-12:OAc)로 동정되었으며, 그 중 (Z)-3-도데세닐아세테이트(Z3-12:OAc)가 주성분으로 나타났다.At night, when mating horned moths are mainly mated, females that have not yet been mated were captured, and the abdominal end where the pheromone gland was located was cut with scissors and put in an organic solvent (hexane) to obtain an extract. The obtained extract was analyzed by GC-MS equipped with a DB-23 column. As a result, the sex pheromone secreted by the female horned moth was (Z) -3-dodecenyl acetate (Z3-12: OAc), (E ) -3-dodecenyl acetate (E3-12: OAc) and (Z) -5-dodecenyl acetate (Z5-12: OAc), among which (Z) -3-dodecenyl acetate (Z3-12) : OAc) was the main component.
상기 결과를 하기 표 1 및 도 1에 나타내었다.The results are shown in Table 1 and FIG. 1.
상기 결과에서 확인할 수 있듯이, 퉁퉁마디뿔나방 암컷의 성페로몬은 3 가지 성분인 (Z)-3-도데세닐아세테이트(Z3-12:OAc), (E)-3-도데세닐아세테이트(E3-12:OAc) 및 (Z)-5-도데세닐아세테이트(Z5-12:OAc)로 이루어져 있었으며, 그 비율은 약 91 : 6 : 3임을 확인할 수 있다.
As can be seen from the above results, the sex pheromone of the female of the horned moth female is (Z) -3-dodecenyl acetate (Z3-12: OAc), (E) -3-dodecenyl acetate (E3-12) : OAc) and (Z) -5-dodecenyl acetate (Z5-12: OAc), and the ratio was about 91: 6: 3.
실시예Example 2: 야외에서 페로몬 단독사용과 혼합사용에 따른 2: outdoor pheromone alone and mixed use 퉁퉁마디뿔나방Horned Horn Moth 수컷 유인효과 검정 Male Attraction Effect Test
야외에서 (Z)-3-도데세닐아세테이트(Z3-12:OAc)와 (Z)-5-도데세닐아세테이트(Z5-12:OAc)의 혼합조성(standard) 페로몬 성분과 단독처리 페로몬 성분이 퉁퉁마디뿔나방 수컷 유인력에 미치는 영향을 알아보기 위하여, 퉁퉁마디가 재배되고 있는 야외 포장에서 하기 표 2에 기재된 페로몬 조성을 사용하여 퉁퉁마디뿔나방 수컷 유인효과를 실험하였다.The mixed composition of (Z) -3-dodecenyl acetate (Z3-12: OAc) and (Z) -5-dodecenyl acetate (Z5-12: OAc) and pheromone alone In order to investigate the influence on the male horn moth male attraction, the male horn moth male attracting effect was tested using the pheromone composition shown in Table 2 below.
야외에서 페로몬 조성별 퉁퉁마디뿔나방 수컷 유인효과에 대한 측정 결과를 하기 표 2 및 도 2에 나타내었다. 측정은 퉁퉁마디가 재배되고 있는 야외 포장에 페로몬 조성이 다른 루어를 설치하여 1주일 후에 유인된 수컷 수를 조사하여 실시하였다.Measurement results for the male horned moth male moth effect according to the composition of pheromone in the open air are shown in Table 2 and FIG. 2. The measurement was carried out by installing lures with different pheromone compositions in outdoor pavement where the stalks were grown, and examining the number of males attracted after one week.
(standard)Z3-12: OAc + Z5-12: OAc
(standard)
(단위)usage
(unit)
상기 결과에서 보듯이, (Z)-3-도데세닐아세테이트(Z3-12:OAc)와 (Z)-5-도데세닐아세테이트(Z5-12:OAc)의 혼합조성 페로몬 성분이 퉁퉁마디뿔나방 수컷에 높은 유인효과를 보였고, 단독처리 페로몬 성분은 유인효과가 거의 없음을 확인할 수 있었다.
As shown in the above results, the mixed pheromone component of (Z) -3-dodecenyl acetate (Z3-12: OAc) and (Z) -5-dodecenyl acetate (Z5-12: OAc) was found It showed a high attraction effect, and the single-treated pheromone component was found to have almost no attraction effect.
실시예Example 3: 야외에서 페로몬 조성비율별 3: Outdoor composition of pheromone 퉁퉁마디뿔나방Horned Horn Moth 수컷 유인효과 확인 Male Attract Effect
야외에서 페로몬 혼합 조성에 따른 퉁퉁마디뿔나방 수컷 유인 효과를 더욱 자세히 알아보기 위하여, 퉁퉁마디가 재배되고 있는 야외 포장에서, 하기 표 3에 기재된 페로몬 조성으로 퉁퉁마디뿔나방 수컷 유인효과를 확인하였다. 측정 결과를 하기 표 3에 나타내었다. 측정은 퉁퉁마디가 재배되고 있는 야외 포장에 페로몬 조성이 다른 루어를 설치하여 1주일 후에 유인된 수컷 수를 조사하여 실시하였다.In order to learn more about the male horned moth male attracting effect according to the pheromone mixed composition in the open air, the male horned male moth attracting effect was confirmed by the pheromone composition shown in Table 3 below in the outdoor packaging in which the horned cultivated. The measurement results are shown in Table 3 below. The measurement was carried out by installing lures with different pheromone compositions in outdoor pavement where the stalks were grown, and examining the number of males attracted after one week.
상기 결과를 통해서도 확인할 수 있듯이, 야외에서 주성분인 (Z)-3-도데세닐아세테이트(Z3-12:OAc)에 (E)-3-도데세닐아세테이트(E3-12:OAc) 또는 (Z)-5-도데세닐아세테이트(Z5-12:OAc)가 첨가되었을 때 퉁퉁마디뿔나방 수컷의 유인 효과가 가장 크게 향상되었음을 확인할 수 있었다. 또한 퉁퉁마디뿔나방 수컷의 유인에는 (Z)-3-도데세닐아세테이트(Z3-12:OAc) 90 중량부에 (E)-3-도데세닐아세테이트(E3-12:OAc) 또는 (Z)-5-도데세닐아세테이트(Z5-12:OAc) 10 중량부를 첨가한 혼합물이 적합함을 확인할 수 있었다.
As can be seen from the above results, (E) -3-dodecenyl acetate (E3-12: OAc) or (Z)-to (Z) -3-dodecenyl acetate (Z3-12: OAc) which is a main component in the open air. When 5-dodecenyl acetate (Z5-12: OAc) was added, it was confirmed that the attracting effect of the male Rhododendron male was greatly improved. In addition, to attracting male horned moth males, (Z) -3-dodecenyl acetate (Z3-12: OAc) in 90 parts by weight of (E) -3-dodecenyl acetate (E3-12: OAc) or (Z)- It was confirmed that the mixture to which 10 parts by weight of 5-dodecenyl acetate (Z5-12: OAc) was added was suitable.
제조예Manufacturing example 1: One: 퉁퉁마디뿔나방Horned Horn Moth 유인 또는 방제용 조성물을 이용한 페로몬 트랩의 제조 Preparation of Pheromone Trap Using Attract or Control Composition
퉁퉁마디뿔나방 수컷 유인물질인 본 발명의 조성물을 제조하기 위해, (Z)-3-도데세닐아세테이트(Z3-12:OAc) 및 (E)-3-도데세닐아세테이트(E3-12:OAc) 또는 (Z)-3-도데세닐아세테이트(Z3-12:OAc) 및 (Z)-5-도데세닐아세테이트(Z5-12:OAc)를 9:1의 비율로 혼합하였다. 상기 혼합물을 고무격막(흰색, 직경 8mm, Aldrich사)에 침적하여 페로몬 루어(미끼)를 제작하였다.
(Z) -3-dodecenyl acetate (Z3-12: OAc) and (E) -3-dodecenyl acetate (E3-12: OAc) Or (Z) -3-dodecenyl acetate (Z3-12: OAc) and (Z) -5-dodecenyl acetate (Z5-12: OAc) in a ratio of 9: 1. The mixture was immersed in a rubber diaphragm (white, 8 mm in diameter, Aldrich) to prepare a pheromone luer.
제조예Manufacturing example 2: 2: 퉁퉁마디뿔나방Horned Horn Moth 유인 또는 방제용 조성물을 이용한 교미교란제의 제조 Preparation of Mating Disorders Using Attractant or Control Composition
(Z)-3-도데세닐아세테이트(Z3-12:OAc)와 (E)-3-도데세닐아세테이트(E3-12:OAc) 또는 (Z)-3-도데세닐아세테이트(Z3-12:OAc)와 (Z)-5-도데세닐아세테이트(Z5-12:OAc)를 각각 9:1의 비율로 혼합하여 겔제(Gel)의 교미교란제를 제조하였다.
(Z) -3-dodecenyl acetate (Z3-12: OAc) and (E) -3-dodecenyl acetate (E3-12: OAc) or (Z) -3-dodecenyl acetate (Z3-12: OAc) And (Z) -5-dodecenyl acetate (Z5-12: OAc) were mixed in a ratio of 9: 1, respectively, to prepare a gel mating disturbance agent.
제조예Manufacturing example 3: 3: 겔제(Gel)의Gel 제조 Produce
(Z)-3-도데세닐아세테이트 90g과 (E)-3-도데세닐아세테이트 10g 또는 (Z)-3-도데세닐아세테이트 90g과 (Z)-5-도데세닐아세테이트 10g을 사용하였으며, 여기에 물 30g을 가하면서 프로필렌 글리콜(Propylene glycol) 30g과 혼합하여 주었다. 여기에 카보머 940(Carbomer 940) 2g을 가하여 완전히 용해시킨 후 정제수를 가하여 혼합해 주었다.
90 g of (Z) -3-dodecenyl acetate and 10 g of (E) -3-dodecenyl acetate or 90 g of (Z) -3-dodecenyl acetate and 10 g of (Z) -5-dodecenyl acetate were used. 30g was added and mixed with 30g of propylene glycol. 2 g of Carbomer 940 was added thereto to completely dissolve it, and then purified water was added thereto and mixed.
제조예Manufacturing example 4: 스프레이제( 4: spray SpraySpray )의 제조 Manufacturing
(Z)-3-도데세닐아세테이트 90g과 (E)-3-도데세닐아세테이트 10g 또는 (Z)-3-도데세닐아세테이트 90g과 (Z)-5-도데세닐아세테이트 10g을 사용하였으며, 여기에 프로필렌 글리콜(Propylene glycol) 30g과 에틸 알콜(Ethyl alcohol) 10g을 가하여 혼합하여 주고 정제수를 넣은 후 혼합해 주었다.
90 g of (Z) -3-dodecenyl acetate and 10 g of (E) -3-dodecenyl acetate or 90 g of (Z) -3-dodecenyl acetate and 10 g of (Z) -5-dodecenyl acetate were used here. 30 g glycol (Propylene glycol) and 10 g of ethyl alcohol (Ethyl alcohol) was added to the mixture and mixed with purified water.
제조예Manufacturing example 5: 크림제( 5: cream CreamCream )의 제조Manufacturing
(Z)-3-도데세닐아세테이트 90g과 (E)-3-도데세닐아세테이트 10g 또는 (Z)-3-도데세닐아세테이트 90g과 (Z)-5-도데세닐아세테이트 10g을 용기에 넣어 하기 [조성 A]를 제조하였다. 이를 하기 [조성 B]와 혼합하였다. 그 후 여기에 [조성 C]와 [조성 D]의 혼합물을 넣어 고속 혼합기로 섞어주었다.90 g of (Z) -3-dodecenyl acetate and 10 g of (E) -3-dodecenyl acetate or 90 g of (Z) -3-dodecenyl acetate and 10 g of (Z) -5-dodecenyl acetate were placed in a container. A] was prepared. This was mixed with the following [Composition B]. Thereafter, a mixture of [Composition C] and [Composition D] was added thereto and mixed with a high speed mixer.
[조성 A의 제조][Production of Composition A]
1. 본 발명의 조성물 ........................... 100g1. Composition of the present invention ..................... 100g
2. 프로필렌 글리콜(Propylene glycol) ............ 30g2.Propylene glycol ...... 30g
3. 라놀린 알콜(Lanolin alcohol) .................. 4g3. Lanolin alcohol ..... 4g
상기 1 내지 3의 물질들을 혼합하여 <조성 A>를 제조하였다.<Composition A> was prepared by mixing the materials of 1 to 3.
[조성 B의 제조][Production of Composition B]
1. 세틸 알콜(Cetyl alcohol) .................... 1.0g1.Cetyl alcohol ..................... 1.0g
2. Solulan C-24 ................................ 0.3g2.Solulan C-24 ......... 0.3g
3. 스테아르산(Stearic acid) .................... 3.0g3. Stearic acid ..................... 3.0g
4. 글리세릴 스테아레이트(Glyceryl stearate) .... 2.0g4. Glyceryl stearate .... 2.0g
상기 1 내지 4 물질들을 혼합한 후 80℃로 가온하여 용융시켰다. 이후 이를 식혀 30℃가 되도록 하여 <조성 B>를 제조하였다.The 1-4 materials were mixed and then melted by heating to 80 ° C. Then it was cooled to 30 ℃ to prepare <Composition B>.
[조성 C의 제조][Production of Composition C]
1. 메틸 글루세스-10(Methyl gluceth-10) ......... 5.0gMethyl gluceth-10 ......... 5.0g
2. 물(H2O) .................................... 20.0g2. Water (H 2 O) ..................... 20.0 g
상기 1 내지 2의 물질들을 혼합하여 <조성 C>를 제조하였다.<Composition C> was prepared by mixing the materials of 1-2.
[조성 D의 제조][Production of Composition D]
1. 메틸파라벤(Methylparaben) ................... 0.3gMethylparaben ......... 0.3g
2. 프로필파라벤(Propylparaben) ................ 0.25g2. Propylparaben ................ 0.25g
3. 물(H2O) ...................................... 10g3. Water (H 2 O) ...................... 10g
상기 1 내지 3 물질들을 혼합한 후 80℃로 가온하여 용융시켰다. 이후 이를 식혀 30℃가 되도록 하여 <조성 D>를 제조하였다.The 1-3 materials were mixed and then melted by heating to 80 ° C. Thereafter, it was cooled to 30 ° C to prepare <Composition D>.
Claims (7)
(Z) -3-dodecenyl acetate, (E) -3-dodecenyl acetate, and (Z) -5-dodecenyl acetate, at least one compound selected from the group consisting of Or a composition for control.
(Z)-3-도데세닐아세테이트; 및
(E)-3-도데세닐아세테이트 및 (Z)-5-도데세닐아세테이트 중 선택된 하나 이상의 화합물
을 포함하는 것을 특징으로 하는 퉁퉁마디뿔나방 유인 또는 방제용 조성물.
The method of claim 1,
(Z) -3-dodecenyl acetate; And
At least one compound selected from (E) -3-dodecenyl acetate and (Z) -5-dodecenyl acetate
Tongalung moth attracting or controlling composition comprising a.
The method according to claim 2, 1 to 20 parts by weight of at least one compound selected from (E) -3-dodecenyl acetate and (Z) -5-dodecenyl acetate relative to 100 parts by weight of (Z) -3-dodecenyl acetate. Composition for attracting or controlling the ragged horn moth, characterized in that it comprises.
The method according to claim 1, wherein the (Z) -3-dodecenyl acetate, (E) -3-dodecenyl acetate and (Z) -5-dodecenyl acetate are derived from sex pheromones of females Compositions for attracting or controlling the ragged horn moth.
The composition of claim 1, wherein the composition is formulated in the form of a solution, emulsion, suspension, emulsion, paste, gel, cream, lotion, oil, powder, wax or spray. Composition for attracting or controlling the rhabdomyomoth moth, characterized in that.
Pheromone trap, characterized in that it comprises a composition for attracting or controlling the ragged horn moth moth of any one selected from the group consisting of claims 1 to 4.
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KR20210127485A (en) * | 2020-04-14 | 2021-10-22 | 서울대학교산학협력단 | Composition for controlling Geometrid moth, method for preparing the same, and method for controlling Geometrid moth using the same |
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