KR20120040941A - Elastic non-woven fabric having a fitting property and a soft touch and manufacturing method thereof - Google Patents

Abstract

PURPOSE: A filament elastic non-woven fabric with fitness and soft texture and a method for fabricating the same are provided. CONSTITUTION: A filament elastic non-woven fabric with soft texture: comprises a sheath part with A ingredient polymer containing high density polyethylene(HDPE) with 25-35 g/10 minutes of melt index and 0.9515-0.9565g/cm^3 of density at 190°C; and a core part with B ingredient polymer containing propylene elastomer polymers.

Description

Elastic non-woven fabric having a fitting property and a soft touch and manufacturing method

The present invention relates to a long-fiber elastic spunbond nonwoven fabric having a fit and a soft touch and a method of manufacturing the same, and more particularly, to a composition comprising a thermoplastic polymer and a propylene-based elastomer polymer using a two-component composite spinning technique. spunbonding to provide a fit and soft touch at the same time, in disposable diapers, feminine hygiene products, personal care products such as bands and health care items such as bandages, gauze, sterile wraps, and many other products such as bedroom products and wipes. The present invention relates to a stretchable long fiber nonwoven fabric and a method for producing the same.

The manufacture of inexpensive fibers and webs, to name a few, has become a well-developed industry that enables many innovative products such as disposable diapers, children's swim pants, children's training pants and adult incontinence garments. As the product evolves and improves, the requirements of the fiber and web components also change and increase the demand for the material.

As described above, nonwoven fabrics are widely used in many other fields, but when used in products of each field, they need to be manufactured so as to have properties or structures suitable for the purpose of each product.

For example, a nonwoven fabric used for use in an absorbent article is required to be easily stretched to fit the movement of the wearer or the body being worn so that the wearer does not experience discomfort. Moreover, when used as a disposable diaper, the nonwoven fabric should have strength enough to prevent the sheet from breaking during stretching while maintaining elasticity, and at the same time, since these nonwoven fabrics are mainly used in contact with the skin, the touch feeling with the skin should be good. Required.

As such, the nonwoven fabric has been developed to have specific properties in accordance with the characteristics of the applied field, and in particular, various techniques for manufacturing fibers and webs for expressing the elastic properties required for hygiene products such as diapers have been proposed. For example, Korean Patent Laid-Open Publication No. 2009-0128481 discloses a method of providing elasticity by performing a gear stretching process on a latent stretchable nonwoven sheet fixed by self-fusion by softening or melting by mixing and stacking stretchable fibers and stretchable fibers. , By forming and stretching a crosslinked elastic film layer from the thermoplastic styrene block copolymer introduced in Korean Patent Application Publication No. 2007-7014056, and then providing elasticity to the nonwoven fabric by bonding to one or more nonwoven webs in a stretch-bonded laminate manner. A method is disclosed. However, in the case of the above technique, stretching is possible only in the uniaxial direction, and in the case of the laminate method, since the adhesive treatment must be performed to give adhesive properties with other materials, the processing process is complicated and the manufacturing cost increases. There is this.

Therefore, in the method of expressing elastic properties due to the above problems, interest in a method of expressing elastic properties by introducing an appropriate elastic raw material rather than on a facility has been expanded. As such a method, for example, Korean Patent Laid-Open Publication No. 2005-0088361 discloses a method for producing stretchable fibers by spunbonding a polymer containing a thermoplastic polyurethane elastomer. However, this method has a problem in that a polyurethane has a peculiar smell and a yellowing phenomenon occurs over time.

On the other hand, various methods for improving the contact feeling of the nonwoven fabric to the skin have also been studied. For example, Korean Patent Publication No. 2007-0085091 discloses an ethylene-octene-based elastomer and a thermoplastic polyethylene (PE) copolymer or poly Disclosed is a method for producing fibers and webs having a non-tacky feel using a bicomponent composite spinning technique using propylene (PP) as a raw material. However, in the case of the elastic raw material used in the above method, the high viscosity and melt elasticity at high temperature increase the pressure on the spinning nozzle during production, resulting in various problems such as decreased productivity during long-term continuous production, and also expensive in terms of raw material price. It has a disadvantage of poor commerciality. In addition, in the case of the ethylene-octene-based elastomer, in the disposable hygiene product application, the user's wearing feeling such as the deformation is large due to the increased load during urine or defecation of the user, that is, the low external load Or there is a disadvantage of poor fit.

Thus, polymer manufacturers can melt process in much the same way as traditional polyolefins, but have relatively elastic properties that approximate traditional rubber and textile elasticity and are relatively inexpensive which may be cost effective for disposable fiber and web applications such as those described above. A new class of olefin-based propylene elastomer polymers has been commercially available. For example, according to Korean Patent Laid-Open Publication No. 2010-0080625, a nonwoven fabric using a propylene-based elastomer polymer is disclosed. In the case of the patent, 30% by weight of erucamide and 70% by weight of propylene-based elastomer are disclosed. Attempts have been made to reduce the tacky feel of elastic raw materials using polymers. However, even in the above technique, since the content of the elastic raw material according to the high content of erucamide, which is a high slip agent, cannot be increased, excellent elasticity, which is an elastic property, cannot be expressed, and control of elastic modulus cannot be performed.

As noted above, the tolerance of the olefin polymers to many applications of nonwovens that are able to withstand deformation with conventional soft non-tacky elastic properties and constant external loads has been delayed for the following reasons. That is, the first reason is adhesiveness and uncomfortable touch which makes fiber and web undesirable for skin contact use, and secondly, when the content of elastic raw material is increased to increase the physical properties such as elastic recovery, high viscosity and melt Resilience continues to mean that self-adhesion contaminates the device and results in costly downtime, especially for applications in disposable diapers where the elastic nonwovens need to control deformation of certain external loads. .

Accordingly, the present inventors have completed the present invention by intensively researching a method for recognizing the above problems and their causes and solving the conventional problems based thereon.

Patent Document 1: Republic of Korea Patent Publication No. 2005-0088361 Patent Document 2: Republic of Korea Patent Publication No. 2007-0085091 Patent Document 3: Republic of Korea Patent Publication No. 2007-0087619 Patent Document 4: Republic of Korea Patent Publication No. 2006-0090838 Patent Document 5: Republic of Korea Patent Publication No. 2010-0080625

Therefore, the present invention has been devised in view of the above-described conventional technical problems, and more specifically, the increase in the elastic content for the increase of the elastic properties is usually caused by a large degree of deformation even by a low external load, such that the sagging occurs when worn. Its disadvantage is that the user's fit or fit is poor, and due to the high viscosity and melt elasticity of the elastic material, it continues to interfere with the high speed spinning of the continuous elastomeric fiber, and the adhesive property of the elastic raw material is in contact with the skin of the user. There was a bad problem, and the main object of the present invention is to solve the above technical problem to provide a long-fiber elastic nonwoven fabric having a fit and soft touch.

It is another object of the present invention to facilitate the long-fiber elastic nonwoven fabric having a fit and soft touch, which makes the long-fiber elastic nonwoven fabric having excellent characteristics as described above smoothly progressed, thereby improving workability. It is to provide a manufacturing method. In more detail, in the production of elastic nonwoven fabric having a soft touch, the elastic core of the fiber and thermoplastic olefins having a soft touch on the surface of the fiber were introduced, and an appropriate manufacturing equipment was introduced to solve the problem of the elastic raw material sticking to the manufacturing equipment. The purpose of the present invention is to provide a manufacturing method having excellent workability by performing two-component composite spinning by finding the optimum ratio of fit and stretch by changing the content ratio of elastic raw materials.

Still another object of the present invention is to provide a long-fiber elastic nonwoven fabric having a fit and a soft touch in which the elastic nonwoven fabric can be controlled for deformation of a certain external load for application to a disposable diaper.

The present invention may also be directed to accomplishing other objects that can be easily derived by those skilled in the art from the overall description of the present specification, other than the above-described and obvious objects.

The object of the present invention described above was to maintain a high spinning speed by utilizing the form of a two-component composite yarn together with the elastic propylene-based elastomer polymer and thermoplastic olefin, and also through this fit to the fibers and web, has excellent elastic recovery and soft touch Could provide fiber with

Long-fiber elastic nonwoven fabric having a fit and soft touch of the present invention for achieving the above object;

A component polymer constituting at least a portion of the fiber surface comprising high density polyethylene (HDPE) having a melt index of 25 to 35 g / 10 min at a temperature of 190 ° C. and a density of 0.9515 to 0.9565 g / cm 3 forms a sheath portion, and It is characterized in that the B-component polymer including the system elastomeric polymer is formed by a deep sheath type long filament forming the core portion.

According to another configuration of the present invention, the ratio of the sheath portion and the core portion is 30/70 to 0/100 of the sheath / core based on the total weight of the fiber, preferably 20/80 to 1/99, more preferably It is characterized in that it preferably has 10/90 to 5/95.

According to another configuration of the present invention, the B component polymer is characterized in that the propylene elastomer polymer having a melt index (MI) of 28 g / 10 minutes and a density of 0.860 to 0.870 g / cm 3 at 230 ℃.

According to another configuration of the invention, the elastic nonwoven fabric is characterized in that the elastic modulus in the MD direction is 1.0 to 1.8 kg / mm2 when measured using a 100% 1-cycle hysteresis test.

According to another configuration of the invention, the elastic nonwoven fabric is characterized by a permanent strain of 30% or less when measured using a 100% 1-cycle hysteresis test.

According to another configuration of the present invention, the elastic nonwoven fabric is characterized in that the basis weight is 10 to 200 g / ㎡.

According to another configuration of the present invention, the bicomponent material is characterized in that the fiber diameter of 15 to 35μm.

Method for producing a long-fiber elastic nonwoven fabric having a fit and soft touch of the present invention for achieving the above another object;

A method of making a long fiber elastic spunbond elastic nonwoven fabric, the method comprising:

a) melt component A comprising a high density polyethylene (HDPE) homopolymer having a melt index of 25 to 35 g / 10 min and a density of 0.9515 to 0.9565 g / cm 3 at 190 ° C. with 0% to 30% by weight of the total fibers; Forming;

b) forming a melt component B comprising a propylene-based elastomeric polymer that is 70% to 100% by weight of the total fibers;

c) coextruding the molten component A and the molten component B as a melt along the length of the fiber to form a plurality of fibers;

d) quenching the fibers to an appropriate temperature;

e) stretching the fibers;

f) collecting the fibers on a specially shaped surface belt;

g) separating the web on the belt at a suitable air speed of 15-25 m / s;

h) imparting form stability to the web by embossing bonds by patterned rolls; And

i) winding the web at a constant winding speed.

According to another configuration of the present invention, the step c) includes a distribution plate between the spin beam and the spinning nozzle so that the molten component A surrounds the molten component B in the longitudinal direction of the fiber, thereby providing the propylene-based elastomeric polymer in the core portion. By inducing and spinning high density polyethylene (HDPE) toward each nozzle hole in the sheath portion, it is characterized in that the preparation of a deep sheath type long fiber.

According to another configuration of the present invention, the step h) is a bonding calender, one side is typically emboss roll (Emboss roll) having a bonding area of 10 to 20%, the other side is a smooth swimming roll (Swimming) roll), wherein the thermal temperature is preferably 80 to 120 ° C, more preferably 90 to 110 ° C.

According to another configuration of the invention, the quenching temperature of step d) is 10 to 20 ℃, preferably 12 to 18 ℃, more preferably 14 To 16 ° C.

According to another configuration of the present invention, the winding condition of step i) is the winding speed of the winder 80 to 99%, preferably 85 to 97%, most preferably compared to the rotational speed of the emboss roll (emboss roll) It is characterized by lowering at a rate of 87 to 95%.

Absorbent articles such as disposable diapers and sanitary napkins, personal care products, cleaning products such as wipers, medical articles such as gauze and bandages for masks, etc. It is characterized in that it is made of a nonwoven fabric containing.

The long-fiber elastic nonwoven fabric having a fit and a soft touch of the present invention configured as described above is improved to have a fit and a soft touch by a simple manufacturing process, so that it can be used in many industries and can be widely applied. For example, the fabrics of the fit, excellent elasticity and soft touch at the same time can be used in the manufacture of hygiene products, for example diapers or personal care products such as diaper tabs, side panels, leg cuffs, top sheets, It can be used in back sheets, tapes, feminine hygiene products, swimwear, infant pull-up pants, incontinence garment components, and bands, and in particular as dynamic or stretchable components of these products, including but not limited to elastic fastening bands. In another embodiment, the fibers and nonwovens may be fabricated in other protective clothing or covers, such as For gowns or aprons, surgical drapes, sterilization Labrador, wipes, bedding, or the like, and a cover for a disposable medical it can be prepared. Moreover, the field of application of these materials can also be found in protective covers, household furniture such as padding, carpet anti-slip padding, wall coverings, floor coverings, window shades, streams and any other field in which traditional fabrics have conventionally been used. will be.

1 is a schematic diagram of a two-component spinning system capable of forming a spunbond nonwoven fabric for use in the manufacture of a long fiber elastic nonwoven fabric having a fit and soft hand in accordance with the present invention;
2 is a schematic diagram of an air jetting apparatus used in accordance with the present invention to facilitate separation of the laminated nonwoven fabric and the belt.

Before describing the present invention in more detail by preferred embodiments, the test procedures and terms used in the present invention are first summarized as follows:

[Test Procedure]

Permanent elongation (%) and elastic modulus (kg / mm 2) measurement test:

According to the ASTM D882 method, samples were dropped between pneumatically activated line-contact grips. Pressure was adjusted to prevent slippage (typically 50-100 psi). The crosshead speed was set to 300 mm / min. The crosshead was stretched to 100% strain and returned to 0% strain at the same crosshead speed. Elastic recovery force was defined according to the following equation (1). In all cases, the samples were measured not to be fresh or old.

[Equation 1]

Permanent Elongation (%) = (ΔL / L _i ) X 100

ΔL = L _f -L _i , L _f = length after fiber stretching, L _i = length before fiber stretching.

In addition, the elastic modulus is carried out under the same test conditions as the permanent elongation measurement, the elastic modulus can be obtained from the Law (Law) of the following hook.

Where σ = external stress and ε = strain length.

touch:

The touch of the spunbonded nonwovens was evaluated by 30 testers. This evaluation was performed based on the following criteria.

A: When more than 27 out of 30 testers said that the said nonwoven fabric was non-sticky, the touch was good.

B: 26 to 21 out of 30 testers said the nonwoven fabric was non-sticky and had good touch.

C: 20 to 15 out of 30 testers said that the nonwoven fabric was not sticky and had a good touch.

D: 14 to 9 out of 30 testers said the nonwoven fabric was non-sticky and had good touch.

E: When 8 to 0 of 30 testers said the nonwoven fabric was non-sticky, the touch was good.

Scanning electron microscope:

Fiber and nonwoven samples for the scanning electron microscope were mounted on an aluminum sample stage with a tape filled with carbon black and a copper tape. The loaded sample was then placed on a SPI-Module Sputter Coater, available from Structure Probe Incorporated (West Chester, Mass.), Equipped with an argon gas supply and vacuum pump. (Model No. 11430) was used to coat 100-200 μs of platinum. The coated samples were then examined on an S4100 scanning electron microscope supplied by Hitachi America, Ltd (Schaumburg, Ill.) And equipped with an enteric effect gun. Samples were examined using a secondary electronic imaging mode using an accelerating voltage of 3-5 kV and images were collected using a digital image capturing system.

As used herein, the term "elastic" or "elastic" means that when applying a biasing force, it is stretchable, that is, stretchable to at least 60%, and at least 50% of the stretched state upon release of the stretching force By any material that will be recovered again. Many stretchable materials can be stretched far beyond 60% (i.e., far more than 160% of the relaxed length), for example above 100%, many of which are substantially at the time of releasing their initial relaxation length, e.g. It will recover to 105% of their initial mitigation length.

The term "elastic or elastic web" refers to a web sample that will have a set of "permanent elongation" or "elastic resilience" of 30% or less as measured by the 1-cycle test described above in the test procedure up to 100% strain. .

In addition, the term "elastic modulus" used in the present invention indicates the ratio of the stress to the deformation of the object to the deformation within the limit, it is a numerical value representing the degree of elasticity of any material.

The term "nonwoven or nonwoven" as used herein refers to a web of fibers or filaments that are formed by means other than knit or woven and that contain a bond between some or all of the fiber or filament, such a bond being for example It may be formed by thermal, adhesive or mechanical means such as entanglement. Conventional nonwovens are formed by spunbond, meltblown, carding, wetlaying and airlaying processes.

The term “spunbond” as used herein is typically formed into strands quenched and stretched by high velocity air by melt extrusion of a polymer extrudate and collected on forming surfaces, often by patterned application of heat and pressure. By non-woven or non-woven fabric of filament reinforced bonded filament.

The terms "composite" and "multicomponent", as used herein, are used interchangeably and result in two or more separate sections occupied by separate polymeric components along the entire length of the fiber or filament. Refers to fibers or filaments formed by combining multiple extrudates to each fiber or filament. The cross sections of the fibers can take many different arrangements such as side-by-side, pie, sheath-core, eccentric sheath core and islands-in-the-sea. Of particular interest to the present invention is a sheath-core arrangement.

Based on the test procedures and terms used in the present invention described above, preferred embodiments of the present invention will be described in more detail with reference to the accompanying drawings.

According to a preferred embodiment of the present invention, component A of the present invention may use, for example, polyethylene homopolymer (MM810 grade) of SK Corporation, but is not limited thereto. For polyethylene homopolymers the density is preferably from about 0.9450 g / cm 3 to 0.9650 g / cm 3, more preferably from about 0.9505 to 0.9575 g / cm 3.

According to another preferred embodiment of the present invention, the propylene-based elastomer polymer of component B of the present invention is an isotactic poly, as a VISTAMAXX elastomer commercially available from Exxon-Mobil, although not limited thereto. Propylene-based elastomeric polymers in which propylene is copolymerized with ethylene in the base can be used. The density range may preferably be selected within 0.855 to 0.910 g / cm 3, with about 0.860 to 0.870 g / cm 3 being preferred for some applications.

Next, the manufacturing process of the stretchable nonwoven fabric according to the present invention will be described in detail.

1 is a schematic diagram of a two-component spinning system capable of forming a spunbond nonwoven fabric used in the manufacture of a long fiber elastic nonwoven fabric having a fit and soft touch according to the present invention, and FIG. 2 is a laminated nonwoven fabric used in accordance with the present invention. And a schematic view of an air jetting device that facilitates separation of the belt.

As shown in FIG. 1, which shows an exemplary manufacturing process of a nonwoven web according to the present invention, a stretchable nonwoven according to the present invention begins with melting a long fiber spunbond nonwoven in a bicomponent polymer in the illustrated process line. do. At this time, the bicomponent polymer is prepared by kneading the molten polymer in each of the extruders 1 and 2 respectively. The polymer A component is supplied from the first hopper (1-1) to the extruder, and optionally the polymer B component is supplied from the second hopper (HOPPER) 2-1 to the extruder. The molten component polymer is transferred from the individual extruders 1 and 2 to the spin beam 3 via respective polymer conduits. The form of the spinneret for spinning the bicomponent filaments is known to those skilled in the art and therefore is not described in detail in the present invention. The process line (A) is then solidified by cooling air which is injected through the honeycomb cooling chamber 5 in which the filaments radiated adjacent to the curtain of filaments extending from the spinneret 4 are also solidified. According to one embodiment of the present invention, when producing a multicomponent filament composed of the A polymer of the sheath portion and the B component polymer of the core portion, the cooling chamber portion temperature needs to be kept low. The reason is that when the temperature is higher than a certain level, the filament sticks in the cooling chamber so as to prevent continuous sheet production, and the drawing is not sufficiently performed, thereby greatly deteriorating the physical properties. Therefore, the temperature of the chamber portion is 10 to 20 ° C, preferably 12 to 18 ° C and most preferably 14 to 16 ° C.

The filament discharged from the spinning nozzle 4 is stretched by the pressure of the air blown from the upper part and the air sucked from the lower part of the conveyor belt 9 in the case of the cooling air of the cooling chamber 5, and has a good separation property. It is laminated | stacked by constant weight on (9), and a web is formed. In the present invention, the composite spunbond long fiber nonwoven fabric has a basis weight of 10 to 200 g / m 2, and particularly preferably a fiber diameter of 15 to 35 μm.

Referring to Figure 2, the non-woven fabric according to the present invention is a rectangular air blowing device (B-3) having a plurality of holes in the position of the reference numeral 10 between the conveyor belt and the calender roll before thermal bonding at the bottom of the belt A predetermined air pressure is injected upward to separate the laminated nonwoven fabric B-2 and the conveyor belt B-1. The air injection speed of the air injector needs to be maintained at 5 to 30 m / s. If the air blowing speed is less than 5m / s, the belt and the non-woven sheet phase separation is not made smoothly, if the air injection speed exceeds 30m / s it is not preferable because the air pressure is too strong to leave the sheet.

These laminated nonwovens are thermally bonded to impart mechanical properties and morphological stability. In other words, heat and pressure are applied through the thermal calender rolls to make them thermally adhered and sheeted. At this time, the configuration of the calender roll does not limit the adhesion area, but one side is usually composed of an emboss roll 11 surface having an adhesion area of 10 kPa to 20%, and the other side is composed of a roll 12 having a smooth surface. When the temperature of the roll is above a certain level, the sheet is thermally fused to the heating roll to prevent the production of the sheet, and when the temperature is too low, the physical properties of the sheet are deteriorated. Therefore, according to a preferred embodiment of the present invention, the thermal temperature of the roll is preferably 80 ° C to 120 ° C, more preferably 90 ° C to 110 ° C. In addition, since excessive roll pressure causes the soft sheet to be fused to the roll, it is necessary to manage it below a certain level.

After being thermally bonded as described above, it is wound using a winder 14 for blowing the nonwoven fabric 13. In this case, the stretchability of the nonwoven fabric is increased by the characteristics of the B polymer of the core part, so that the winding speed of the winder 14 is faster than the speed of the embossing roll 11 that thermally bonds the nonwoven fabric. This happens so that the windings are made uneven, which is undesirable. Therefore, the winding speed of the winder 14 should be lowered at a ratio of preferably 80 to 99%, more preferably 85 to 97%, and most preferably 87 to 95% relative to the emboss roll rotation speed. do.

The raw material used in the present invention is an propylene elastomer polymer having an melt index (MI) of 28 g / 10 min and a density of 0.860 to 0.870 at 230 ° C., especially at Exxonmobil.

At this time, the composition ratio of the high density polyethylene which is the sheath portion of the long fiber nonwoven filament and the propylene-based elastomer polymer which is the core portion is 30/70 to 0/100, preferably 20/80 to 0/100, based on the total weight of the fiber. 1/99, more preferably 10/90 to 5/95. If the proportion of the high density polyethylene of the sheath part and the propylene-based elastomer polymer of the core part increases to a certain level, the ratio of the elastomer content of the B component of the core part increases to a certain level, but the fit and elastic recovery force are improved. There is a disadvantage that the production is not made because the adhesion to the porous continuous belt and the heat calendar roll is not produced is not preferable.

In addition, since the elasticity of the nonwoven fabric is increased by the B component polymer property of the core portion, as described above, a winding condition different from the general method of the winding portion is required.

The following examples illustrate the invention in more detail, and the scope of the invention is not limited thereto.

Example 1

Using Reicofil-3.1, Bicomponent system from Reifenhauser, Germany, extruder condition is 150mm outer wall circumference, L / D 30, nozzle condition is 0.6mm, L / D 4, two-component spinning line with 5000 holes per unit meter It was. The conveyor belt used was Suprastat 4000 from COFPA with air permeability units 8910 m 3 / m 2 / Hr (100 Pa) to facilitate separation of the fiber sheet and the belt.

The raw materials used are commercially available from Ax (SK, Grade: MM810) of high density polyethylene (HDPE) having a melt index of 28 g / 10 min at 190 ° C. and a density of 0.954 g / cm 3 at the sheath part and from Exxonmobil at the core part. A propylene elastomer polymer (Vistamaxx, Grade: VM2125) was used as the central component, and the melt index of the elastic body was 28 g / 10 min at 230 ° C., and the density was 0.868 g / cm 3.

The ratio of the two-component spinning line was a weight ratio of the sheath part / core part to 20/80 of the total fibers. The air release rate of the rectangular air injector used for sheet separation was maintained at about 20 m / s. The temperature of the embossing roll was 100 degreeC, and the thermal bonding at the pressure of 50N / mm produced the nonwoven fabric of 30 gsm of the basis weight, and wound up the nonwoven fabric by the rpm of the embossing roll rotation speed X 0.90.

Permanent elongation and elastic modulus were measured at 100% elongation of the nonwoven fabric sheet formed of bicomponent fibers, and the results of the nonwoven fabrics were also evaluated and the results are shown in Table 1 below.

Example 2

Compared with Example 1, only the sheath part / core part raw material ratio was 10/90 of the total fibers, and a nonwoven fabric was manufactured in the same manner as in Example 1.

Example 3

Compared with Example 1, only the sheath part / core part raw material ratio was 5/95 of the total fibers, and a nonwoven fabric was manufactured in the same manner as in Example 1.

Comparative Example 1

Only the air discharge rate of the air injector for separating the sheet was set to maintain less than 5m / s, except that the nonwoven fabric was produced in the same manner as in Example 1.

Comparative Example 2

Compared to Example 1, the sheath part raw material has a polypropylene (PP) A component (manufactured by Honam pertrolchemical, Grade: SFR171-H) having a melt index of 34 g / 10 min at 230 ° C and a density of 0.900 g / cm 3. Other than that produced the nonwoven fabric by the same method as Example 1.

Comparative Example 3

A nonwoven fabric was produced in the same manner as in Example 1 except that the fiber spun from the nozzle was cooled by setting the fiber cooling part quenching temperature to 25 ° C. to produce a nonwoven fabric having a basis weight of 30 gsm.

Comparative Example 4

The nonwoven fabric embossing roll was 130 DEG C and a nonwoven fabric was prepared in the same manner as in Example 1 except that a nonwoven fabric having a basis weight of 30 gsm was heat-bonded at a pressure of 50 N / mm.

Comparative Example 5

The nonwoven fabric embossing roll was 100 DEG C and a nonwoven fabric was prepared in the same manner as in Example 1 except that a nonwoven fabric having a basis weight of 30 gsm was heat-bonded at a pressure of 100 N / mm.

Comparative Example 6

A nonwoven fabric was produced in the same manner as in Example 1 except that the nonwoven fabric was wound at an rpm of the emboss roll rotation speed X 1.0.

[Table 1]

Permanent Elongation (%), Elastic Modulus, and Tactile Change

As can be seen in Table 1, as the ratio of the sheath part to the core part is increased from 20/80 to 5/95, the ratio of the elastic raw material to the core part increases, the elastic properties increase and the permanent elongation and the elastic modulus decrease. Can be.

However, in Comparative Example 1, when the air injection speed of the air injector for easy separation of the sheet was maintained at less than 5 m / s, the sheet stuck to the belt and sheet production was impossible.

In addition, in Example 1 and Comparative Example 2, when the raw material of the sheath part is different, the results of the tester's analysis of how the texture of the fibers and the nonwoven fabric are felt, the case where PP is used when PE is used on the surface of the filament Compared with that, it was evaluated that a much softer texture was felt.

In comparison, when the fiber cooling part quenching temperature is set at a high level (25 ° C.), the spun filament is not sufficiently cooled and is trimmed or contaminated by the filament spun in the chamber, making continuous production of the sheet impossible. It was.

In addition, as shown in the case of Comparative Examples 4 and 5, in the Comparative Example in which the calender temperature and the pressure conditions were different, the work was not fused to the calender roll. In addition, in Comparative Example 6, when the winding conditions were not changed, the width of the sheet was greatly reduced, resulting in uneven externalization, and thus continuous production was not possible.

1, 2 --- extruder
3 --- spin bin
4 --- spinning nozzle
5 --- cooling chamber
13 --- Nonwoven
14 --- winder

Claims (15)

A component polymer constituting at least a portion of the fiber surface comprising high density polyethylene (HDPE) having a melt index of 25 to 35 g / 10 min at a temperature of 190 ° C. and a density of 0.9515 to 0.9565 g / cm 3 forms a sheath portion, and A long-fiber elastic nonwoven fabric having a fit and a soft touch, wherein the B-component polymer including the system elastomer polymer is formed by a core sheath composite long fiber forming a core part.
2. The long fiber elastic nonwoven fabric of claim 1, wherein the sheath / core has 20/80 to 1/99 based on the total weight of the fiber.
According to claim 1, wherein the component B polymer is a propylene elastomer polymer having a melt index (MI) of 28g / 10 minutes and a density of 0.860 to 0.870g / cm 3 at 230 ℃ long fiber having a soft and soft touch Elastic nonwoven fabric.
4. The elastic nonwoven of claim 1, wherein the elastic nonwoven fabric has an elastic modulus of 1.0 to 1.8 kg / mm2 in the MD direction as measured using a 100% 1-cycle hysteresis test. Long fiber elastic nonwoven fabric with fitting and soft feel.
4. The field of claim 1 wherein the elastic nonwoven fabric has a permanent strain of 30% or less, as measured using a 100% 1-cycle hysteresis test. Fiber elastic nonwoven fabric.
The long-fiber elastic nonwoven fabric according to any one of claims 1 to 3, wherein the elastic nonwoven fabric has a basis weight of 10 to 200 g / m 2.
The long fiber elastic nonwoven fabric having a fit and a soft touch according to claim 1, wherein the bicomponent material has a fiber diameter of 15 to 35 µm.
A method of making a long fiber elastic spunbond elastic nonwoven fabric, the method comprising:
a) melt component A comprising a high density polyethylene (HDPE) homopolymer having a melt index of 25 to 35 g / 10 min and a density of 0.9515 to 0.9565 g / cm 3 at 190 ° C. with 0% to 30% by weight of the total fibers; Forming;
b) forming a melt component B comprising a propylene-based elastomeric polymer that is 70% to 100% by weight of the total fibers;
c) coextruding the molten component A and the molten component B as a melt along the length of the fiber to form a plurality of fibers;
d) quenching the fibers to an appropriate temperature;
e) stretching the fibers;
f) collecting the fibers on a specially shaped surface belt;
g) separating the web on the belt at a suitable air speed of 15-25 m / s;
h) imparting form stability to the web by embossing bonds by patterned rolls; And
i) a method of producing a long-fiber elastic nonwoven fabric having a fit and a soft touch, comprising the step of winding the web at a constant winding speed.
9. The method of claim 8, wherein step c) comprises placing a distribution plate between the spin beam and the spinning nozzle so that the molten component A encloses the molten component B in the longitudinal direction of the fiber, thereby sheathing the propylene-based elastomeric polymer in the core portion. A method of manufacturing a long-fiber elastic nonwoven fabric having a fit and a soft touch, characterized by producing a deep sheath-type long filament by guiding and spinning high density polyethylene (HDPE) toward each nozzle hole.
9. The method of claim 8, wherein the step h) comprises an embossing roll having a bonding area of 10 to 20% on one side and a swimming roll having a smooth surface on the other side. It is configured, wherein the thermal temperature is 80 to 120 ℃ characterized in that the long fiber elastic nonwoven fabric having a soft fit and soft touch.
9. The method of claim 8, wherein the quenching temperature of step d) is 10 to 20 ° C.
[9] The fit and soft feel of claim 8, wherein the winding condition of step i) is performed by lowering the winding speed of the winder at a rate of 80 to 99% compared to the rotation speed of the emboss roll. Method for producing a long fiber elastic nonwoven fabric having a.
The spunbond nonwoven fabric having excellent elastic restoring force according to any one of claims 1 to 7, wherein the nonwoven fabric is melt extruded and becomes an extensible nonwoven fabric under air pressure.
A stretchable laminate comprising the nonwoven or nonwoven of claim 1.
The nonwoven fabric of Claim 13 or 14 used for absorbent articles, such as a disposable diaper and a sanitary napkin, cleaning products of a wiper, and gauze and a bandage of a mask.

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