KR20120002054A - Reflection paints of heat and a road pavement method using it - Google Patents

Reflection paints of heat and a road pavement method using it Download PDF

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KR20120002054A
KR20120002054A KR1020100062741A KR20100062741A KR20120002054A KR 20120002054 A KR20120002054 A KR 20120002054A KR 1020100062741 A KR1020100062741 A KR 1020100062741A KR 20100062741 A KR20100062741 A KR 20100062741A KR 20120002054 A KR20120002054 A KR 20120002054A
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heat
weight
paint
coating layer
reflective paint
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홍창우
김인중
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충주대학교 산학협력단
(주)지케이
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004Reflecting paints; Signal paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/40Glass
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/22Expanded, porous or hollow particles
    • C08K7/24Expanded, porous or hollow particles inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/02Ingredients treated with inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C23/00Auxiliary devices or arrangements for constructing, repairing, reconditioning, or taking-up road or like surfaces
    • E01C23/14Auxiliary devices or arrangements for constructing, repairing, reconditioning, or taking-up road or like surfaces for heating or drying foundation, paving, or materials thereon, e.g. paint
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/005Additives being defined by their particle size in general

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
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  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
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Abstract

PURPOSE: A heat-reflective paint is provided to decrease the surface temperature of a road pavement material by 7-15°C, and to obtain more than 70% of reflectivity in all sunlight wavelength areas. CONSTITUTION: A heat-reflective paint comprises a mixture of 30-50wt% room temperature-drying type acryl emulsion resin, 10-25wt% glass beads, 10-30wt% hollow ceramic, 10-30wt% colored inorganic pigment, 10-30wt% water, 1-5wt% surfactant, 1-5wt% thickening agent, 1-35wt% dispersant and 1-3wt% sedimentation agent. The glass beads is vacuum deposition-coated by aluminum or metal which has the thickness of 1-40 micron, on a glass of which refractive index is at least 2.2 or higher. The density of the hollow ceramic is 0.5-0.7g/cc, grain size is 15-65, the volume hollow rate is 20-60%.

Description

열저감 반사도료 및 이를 이용한 도로 포장 공법{Reflection paints of heat and a road pavement method using it}Reflective paints of heat and a road pavement method using it}

본 발명은 도로 포장 혼합물에 관한 것으로서, 더욱 상세하게는 도로 포장면으로 유입되는 열을 반사 또는 소멸시켜 차열 효과를 갖도록 도로 포장면에 열저감 반사도료가 코팅되도록 하여서 된 열저감 반사도료 및 이를 이용한 도로 포장 공법에 관한 것이다.
The present invention relates to a road pavement mixture, and more particularly, a heat-retardant reflective paint made by coating a heat-resistant reflective paint on a road pavement surface to have a heat shielding effect by reflecting or dissipating heat flowing into the pavement surface. It is about road pavement method.

일반적으로, 도심지의 기온은 포장이나 건축물에 의한 지표면 피복의 인공화와, 냉방이나 자동차 등에 의한 인공배열의 증가로 인해 자연 상태의 태양에너지의 순환이 원활히 이루어지지 못함으로 인해, 국지적인 열섬(Heat lsland : 온도가 대기오염이나 인공열 등의 영향으로 주변지역보다 높게 나타나는 현상)현상이 빈번히 발생되어 심각한 사회문제로 대두되고 있다.In general, urban air temperature is a local heat island due to the inability to circulate natural solar energy due to the artificial surface cover by paving or buildings, and the increase in artificial arrangement by cooling or automobiles. lsland: The temperature is higher than the surrounding area due to air pollution or artificial heat.) is a frequent social problem.

근적외선은 태양광에 포함되는 780~2100nm 영역에 속하며, 적외선 및 가시광선과는 달리 열에너지에 따라 변화하기 쉬운 파장영역이다. 근적외선이 대상물질에 닿아 흡수되면 열에너지로 바뀌는데 아스팔트 및 콘크리트 포장이 그 열을 포함하고 있어 포장체 온도가 상승하게 되는 것이다. 일반도료(페인트)는 태양으로부터 받는 적외선을 모두 흡수해 발열하기 때문에 여름에는 도로 포장체 표면이 60~70℃까지 상승한다. Near-infrared ray belongs to 780 ~ 2100nm which is included in sunlight, and unlike infrared and visible light, it is a wavelength range that is easy to change according to thermal energy. When near-infrared rays are absorbed by the target material, they are converted into thermal energy. Asphalt and concrete pavements contain the heat, the pavement temperature rises. The general paint (paint) absorbs all the infrared rays from the sun and generates heat, so the road pavement surface rises to 60 ~ 70 ℃ in summer.

최근, 아스팔트 포장에 대한 포장면에서의 대책으로서, 다양한 연구가 시도되고 있다. 또한 도심부 환경을 개선하기 위해 차열성 포장이 제시되고 있으며, 상기 차열성 포장은 특히, 여름철 포장체의 방사열에 의한 열섬 현상을 개선함으로서 주행 및 보행의 쾌적함을 향상시킬 수 있을 뿐만 아니라 지구 온난화 방지를 위한 환경개선과 포장체의 도로소음저감 등의 긍정적 효과도 있을 것으로 기대되어 그 기술이 다양하게 제시되고 있다.In recent years, various studies have been attempted as a countermeasure on the pavement surface for asphalt pavement. In addition, heat shield packaging has been proposed to improve the urban environment, and the heat shield packaging can improve the comfort of driving and walking as well as to prevent global warming by improving the heat island phenomenon caused by the radiant heat of the summer package. It is expected to have positive effects such as environmental improvement and road noise reduction of pavement.

차열성 도료에 대한 국내외 관련 기술의 현황을 살펴보면,Looking at the current status of domestic and foreign related technologies for heat shield paints,

(1) 국외 기술 현황(1) Overseas Technology

차열성 도료에 대한 외국의 기술은 초기에는 건물의 차열에 중점을 두고 진행되었으나, 최근에는 일본을 중심으로 토목분야의 도로포장에 적용하기 위해 기술개발에 박차를 가하고 있다. 기존의 건축물에 적용시에는 하중을 받지 않는 비구조체에 적용하기 때문에 차열성능에 중점을 두었으나, 도로포장에 적용하기 위해서는 내마모성, 내구성 등 고려되어야 하는 사항이 많기 때문에 일본이 가장 먼저 최근에 시험포장을 통해 사용가능성을 평가하고 확대적용하기 위해 JIS 기술표준안을 수립하고 있는 실정이다.The foreign technology of heat shielding paint was initially focused on the heat shielding of buildings, but recently, it has been spurring technology development to apply to road paving in civil engineering centering around Japan. When applied to existing buildings, the emphasis was placed on thermal insulation performance because it is applied to non-structural structures that are not subjected to load.However, in order to apply to road pavement, there are many things to consider such as wear resistance and durability. In order to evaluate and expand the applicability of the system, JIS technical standards are being established.

기술의 특성 및 현황을 살펴보면 다음과 같다.The characteristics and status of the technology are as follows.

① 일본의 미쯔미 금속도료 화학의 ‘유니코프스 마일드(상품명)’는 아크릴 에멀전 수지계로 환경친화형의 1액형 수계 후막형 태양열 차단 도료이다. 특성으로는 백색을 기본색상으로 고반사율의 저열전도성 특수 실리카나 세라믹 등을 사용하여 태양복사에너지에 대한 반사율은 80%이상, 차단율 90% 이상의 성능을 갖는 것으로 나타났다.(1) “UNICOPS Mild” of Mitsumi Metallic Paint Chemicals in Japan is an acrylic emulsion resin-based, environmentally friendly, one-component water-based thick film type sunscreen. As a characteristic, white was used as the basic color, and high heat reflectivity, low thermal conductivity special silica or ceramic, etc., showed that the reflectance of the solar radiation energy was over 80% and the blocking rate was over 90%.

② 나가시마 특수도료에서 생산중인 제품인 ‘Thermo shield'는 열과 환경 보전에 관계하는 특수기능성 도료이다. 도막의 구조는 우주비행체의 외면단열층의 구조와 같은 형태로, 전공세라믹 버블이 정밀하게 배열되어 약 40%의 용적률을 차지한다. 도막은 비중이 1.11로 가볍고, 태양광을 약 80% 반사하며, 열전도도는 0.025(kcal/mh℃)의 성능을 갖는다. 그 결과 외면온도의 내부로의 열전달을 저지하여 실온을 여름철에도 낮게 유지할 수 있다고 알려져 있다.② 'Thermo shield', a product produced by Nagashima Specialty Paint, is a special functional paint related to heat and environmental conservation. The structure of the coating film is the same as that of the outer insulation layer of the space vehicle, and the ceramic ceramic bubbles are precisely arranged to occupy about 40% of the volume ratio. The coating film has a specific gravity of 1.11 and is light, reflects about 80% of sunlight, and has a thermal conductivity of 0.025 (kcal / mh ° C.). As a result, it is known that room temperature can be kept low even in summer by preventing heat transfer to the inside of the outside temperature.

③ 미크론테크사 단열도료 ‘미크코트’는 세라믹 비드를 주체로 하여 안료로서 개발된 제품으로서, 열선 방사선등의 차단성이 우수하여 미관, 단열, 보습성에 효과적이며, 단열도료를 도장함으로서 표면 온도가 6~10도 정도 온도차가 있어 에너지 절약효과는 20~30%가 있다고 알려져 있다. 하루중 상온이 30~34℃인 한여름은 경량철골 건축물의 지붕온도는 40~50℃까지 열이 발산된다. 실험에서는 6~10℃의 단열효과가 인정되었으며, 개구부가 있는 건물이라도 상당한 단열효과가 있다고 보고되고 있다. 건축 내외장, 지붕에 도장하는 것으로 마무리되며, 색상은 쥐색,갈색, 오프화이트(off-white) 및 다양한 색상을 판매하고 있다.③ Microntech's thermal insulation coating 'micro coat' was developed as a pigment mainly composed of ceramic beads. It has excellent barrier properties such as heat radiation, and is effective for aesthetics, insulation and moisture retention. It is known that the energy saving effect is 20 to 30% due to the temperature difference of about 6 to 10 degrees. In midsummer, when the room temperature is 30 ~ 34 ℃, the roof temperature of the light steel structure is 40 ~ 50 ℃. In the experiment, insulation effect of 6 ~ 10 ℃ was recognized, and it is reported that even buildings with openings have significant insulation effect. It is finished by painting the interior and exterior of the building and the roof. The colors are white, brown, off-white and various colors.

④ 토다공업은 중금속 프리로 높은 광반사율을 실현하는 차열도료용 흑색안료를 개발하였다. 차열도료용 신규 흑색 무기안료는 산화철 생성기술인 습식합성법을 활용하여 산화철과 Rare metal을 복합화한 복합 산화물을 사용하여 지금까지 주로 사용되고 있던 크롬계 등을 함유하지 않는 중금속 제로로 생산하였다. 그리고 회색(N6)에서 파장 780~2,100 나노미터 영역의 적외선을 50%이상 반사하여 온도상승을 억제하는 외에 내후성에 우수하며 카본블랙과 동등의 흑색특성을 갖는 것으로 제시되었다.④ Toda Industrial Co., Ltd. has developed a black pigment for heat-shielding paint that realizes high light reflectivity with free of heavy metals. New black inorganic pigments for heat-resistant coatings were produced with zero heavy metals, which do not contain chromium-based materials, which have been mainly used up to now, using a composite oxide of iron oxide and Rare metal using wet synthesis method, which is an iron oxide production technology. In addition, it is suggested that the gray (N6) reflects more than 50% of infrared rays in the wavelength range of 780 to 2,100 nanometers and suppresses the temperature rise, and is excellent in weatherability and has black characteristics equivalent to those of carbon black.

⑤ 일본의 NIPPO는 나가시마 특수도료와 공동으로 차열도료를 개발하였다. 개발된 차열도료는 여름철 맑은날 하루중에 60℃가 넘는 아스팔트 노면의 온도를 15℃이상 낮출 수 있다. 이번에 개발한 차열성 포장은 재료와 도막구조를 집중적으로 연구한 것으로 포장 표면의 색을 회색으로 처리해 태양광 반사율이 50%이상 유지할 수 있다. 일본 국토교통성, 도쿄도, 요코하마시등이 성능 시험과 시험시공을 실시해 개발된 포장의 온도절감 효과를 높게 평가하였다.
⑤ NIPPO of Japan developed heat shield coating jointly with Nagashima special coating. The developed thermal insulation paint can lower the temperature of asphalt road surface above 60 ℃ by more than 15 ℃ during sunny day in summer. The heat shield packaging developed this time is an intensive study of the material and coating structure, and it can maintain the solar reflectance of more than 50% by graying the color of the packaging surface. Japan's Ministry of Land, Infrastructure, Transport and Tourism, Tokyo Metropolitan Government, and Yokohama City conducted performance tests and test constructions to evaluate the effect of temperature reduction on the developed pavement.

(2) 국내 기술 현황 (2) Domestic technology

국내에는 중공안료를 수입해 단열도료나 결로방지용 도료로 단순히 페인트에 혼합하는 형태로 열차단 기능이 있는 도료가 사용되기 시작했다. 그러나 중공안료를 단순히 혼합한 도료는 도색 후 발생한 불균일성과 취약한 내구성 때문에 성능이 문제시되는 한계를 노출하였다.
In Korea, hollow pigments are imported and heat-blocking or condensation prevention paints are simply mixed with paint. However, paints simply mixed with hollow pigments exposed the limitations of performance due to the inhomogeneity and weak durability.

이에, 본 발명은 상기한 문제점을 개선하기 위해 창안된 것으로, 본 발명의 목적은, Accordingly, the present invention was made to improve the above problems, the object of the present invention,

첫째; 열저감 반사도료를 아스팔트 또는 콘크리트 도로 포장면에 도포시 도로 포장체의 표면온도를 7~15℃ 정도 저감시킬수 있도록 하며, 아울러 태양광 전 파장영역에서의 일사반사율은 70% 이상을 보이도록 하는데 있다. first; When applying the heat-reduced reflective paint on the asphalt or concrete pavement surface, the surface temperature of the road pavement can be reduced by about 7 ~ 15 ℃, and the solar reflectance in the full wavelength range of the solar light is 70% or more. .

둘째; 주 바인더로 사용하는 상온건조형 아크릴에멀젼수지는 유기용제(신나)를 사용하지 않도록 하여 휘발성 유기화합물 규제에 대응할 수 있는 환경 친화적 제품을 얻고자 하는데 있다.
second; The normal temperature-drying acrylic emulsion resin used as a main binder is to obtain an environmentally friendly product that can cope with the regulation of volatile organic compounds by avoiding the use of an organic solvent (thinner).

상기 목적을 달성하기 위하여 본 발명은, 상온건조형 아크릴에멀젼수지 30~50중량%, 그라스비드 10~25중량%, 중공세라믹 10~30중량%, 유색무기안료 10~30중량%, 물 10~30중량%, 계면활성제 1~5중량%, 증점제 1~5중량%, 분산제 1~3중량%, 침강제 1~3중량%를 혼합하여 얻어지는 것을 특징으로 한다.In order to achieve the above object, the present invention, the room temperature drying type acrylic emulsion resin 30-50% by weight, glass beads 10-25% by weight, hollow ceramic 10-30% by weight, colored inorganic pigment 10-30% by weight, water 10- It is obtained by mixing 30 weight%, surfactant 1-5 weight%, thickener 1-5 weight%, dispersing agent 1-3 weight%, and settling agent 1-3 weight%.

상기 글라스비드는, 굴절률이 적어도 2.2 이상인 그라스에 알루미늄 또는 금속이 1~40㎛ 두께를 가지며 진공증착으로 코팅된 것이 적용될 수 있다.The glass beads may be applied to a glass having a refractive index of at least 2.2 or more and aluminum or metal having a thickness of 1 to 40 μm and coated by vacuum deposition.

상기 중공세라믹은, 밀도 0.5-0.7(g/cc), 입도 15~65이고 체적대비 중공률이 20~60%인 것이 적용될 수 있다.The hollow ceramic, the density of 0.5-0.7 (g / cc), the particle size may be 15 to 65 and the hollow ratio of the volume 20 to 60% can be applied.

상기 상온건조형 아크릴에멀젼수지(Acrylate emulsion resin)는, 메칠메타아크릴과 메타아크릴산의 공중합체로 이루어진다.The room temperature drying type acrylic emulsion resin (Acrylate emulsion resin) is made of a copolymer of methyl methacryl and methacrylic acid.

상기한 열저감 반사도료를 콘크리트 또는 아스팔트 포장면에 적용시,When applying the above-mentioned heat-resistant reflective paint on the concrete or asphalt pavement surface,

도로 포장면에 유변성 알키드 수지와 경화제로 MDI를 사용한 바인더를 도포하여 0.1-0.5mm로 형성하는 1차 도포층 형성단계를 수행하고, 상기 1차 도포층 형성단계후 상면에 상도로 열저감반사도료를 규사와 혼입하여 0.1-3mm로 도포하는 2차 도포층 형성단계를 수행하면 된다. Perform a primary coating layer forming step of forming a 0.1-0.5mm by applying a binder using rheology alkyd resin and a curing agent to the road pavement surface, and after the primary coating layer forming step, the heat-reduced reflection to the top surface What is necessary is just to perform the secondary coating layer forming step which mixes a coating material with silica sand and apply | coats it at 0.1-3 mm.

또한, 열저감 반사도료를 투수 및 배수 가능한 콘크리트 또는 아스팔트 포장면에 적용시,In addition, when applying heat-resistant reflective paint to the concrete or asphalt pavement that can be permeated and drained,

보수성 폴리머 수지를 유변성 알키드 수지와 혼합하여 도포하는 1차 도포층 형성 단계를 수행하고, 상기 1차 도포 단계 후 상면에 상도로 열저감반사도료를 규사와 혼입하여 0.1-3mm로 도포하여 2차 도포하는 2차 도포층 형성단계를 수행하면 된다.
Perform the first coating layer forming step of applying a water-repellent polymer resin mixed with a rheology alkyd resin, and after the first coating step by mixing a heat-resistant low-reflective paint with silica sand on the upper surface to apply 0.1-3mm to the secondary What is necessary is just to perform the secondary coating layer forming step of apply | coating.

따라서, 본 발명은 열저감 반사도료를 적용함에 따라 아스팔트 콘크리트 도로 포장면에 도포시 도로 포장체 표면 온도를 7~15℃ 정도 저감시킬수 있는 효과가 있고 또한 태양광 전 파장영역에서의 일사반사율은 70% 이상을 보이는 효과가 있다.Therefore, the present invention has an effect of reducing the surface temperature of the road pavement by about 7 ~ 15 ℃ when applied to the asphalt concrete pavement surface by applying a heat-resistant reflective paint and the solar reflectance in the entire wavelength range of the solar light 70 It is effective to show more than%.

또한, 주 바인더로 사용하는 상온건조형 아크릴에멀젼수지는 유기용제(신나)를 사용하지 않음에 따라 휘발성 유기화합물 규제에 대응할 수 있는 환경 친화적 제품을 얻게 되는 효과가 있다.
In addition, the room temperature drying type acrylic emulsion resin used as the main binder has an effect of obtaining an environmentally friendly product that can cope with the regulation of volatile organic compounds by not using an organic solvent (thinner).

도 1은 본 발명에 따른 열저감 반사도료를 이용한 도로 포장의 단면도이다. 1 is a cross-sectional view of a road pavement using a heat-resistant reflective paint according to the present invention.

이하, 본 발명에 따른 바람직한 실시예를 첨부된 도면을 참조로 하여 상세히 설명하며 본 발명을 설명함에 있어 관련된 공지 기술 등은 본 발명의 요지를 흐리게 할 수 있다고 판단되는 경우 그 자세한 설명은 생략하기로 한다.Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings. In the following description of the present invention, a detailed description of known functions and configurations incorporated herein will be omitted when it may obscure the subject matter of the present invention. do.

본 발명은 열저감 반사도료에 관한 것이다.The present invention relates to a heat reducing reflective coating.

본 발명에 따른 열저감 반사도료는, 상온건조형 아크릴에멀젼수지 30~50중량%, 그라스비드 10~25중량%, 중공세라믹 10~30중량%, 유색무기안료 10~30중량%, 물 10~30중량%, 계면활성제 1~5중량%, 증점제 1~5중량%, 분산제 1~3중량%, 침강제 1~3중량%를 혼합하여 얻어진다.Heat-resistant reflective paints according to the invention, the room temperature drying type acrylic emulsion resin 30-50% by weight, glass beads 10-25% by weight, hollow ceramic 10-30% by weight, colored inorganic pigments 10-30% by weight, water 10- It is obtained by mixing 30 weight%, surfactant 1-5 weight%, thickener 1-5 weight%, dispersing agent 1-3 weight%, and settling agent 1-3 weight%.

상기 글라스비드는, 굴절률이 적어도 2.2 이상인 그라스에 알루미늄 또는 금속이 1~40㎛ 두께를 가지며 진공증착으로 코팅된 것이 적용된다.The glass bead is applied to a glass having a refractive index of at least 2.2 or more and aluminum or metal having a thickness of 1 to 40㎛ and coated by vacuum deposition.

상기 중공세라믹은, 밀도 0.5-0.7(g/cc), 입도 15~65이고 체적대비 중공률이 20~60%를 주성분으로 한다.The hollow ceramic has a density of 0.5-0.7 (g / cc), a particle size of 15 to 65, and a hollow ratio of 20 to 60% by volume.

상기 상온건조형 아크릴에멀젼수지는, 메칠메타아크릴과 메타아크릴산, 아크릴아마이드의 공중합체로 이루어진다.The said room temperature drying type acrylic emulsion resin consists of a copolymer of methyl methacryl, methacrylic acid, and acrylamide.

상기한 열저감 반사도료를 일반 도로 또는 투수 및 배수용 포장면에 적용하였다.The heat-reduced reflecting paints described above were applied to general roads or pavements for permeation and drainage.

도로 포장면에, 유변성 알키드 수지와 경화제로 MDI를 사용한 바인더를 도포하여 0.1-0.5mm로 형성하는 1차 도포층 형성단계를 수행하고, 연속해서 상기 1차 도포층 형성단계후 상면에 상도로 열저감반사도료를 규사와 혼입하여 0.1-3mm로 도포하는 2차 도포층 형성단계를 수행하였다.On the road pavement surface, applying a binder using a rheology alkyd resin and a curing agent to form a binder using MDI to form a 0.1-0.5mm, and subsequently to the top surface after the primary coating layer forming step A secondary coating layer forming step was performed in which the thermally-reduced antireflective coating was mixed with silica sand and applied at 0.1-3 mm.

그리고, 투수 및 배수가 가능한 아스팔트 또는 콘크리트 포장면에는, 상기 1차 도포층 형성 단계시 보수성 폴리머 수지를 더 혼합하였다.The water-permeable and drainable asphalt or concrete pavement surface was further mixed with the water-retaining polymer resin during the first coating layer forming step.

상기와 같이 포장면에 적용되는 열저감 반사도료는 제1 및 제2 실시예를 통해 실험예를 설명하며, 상기 열저감 반사도료의 구성은 다음과 같다.As described above, the heat-reduced reflective paint applied to the pavement surface will be described by the first and second embodiments, and the heat-reduced reflective paint will be described below.

<실험조건><Experimental conditions> 아크릴에멀젼수지Acrylic Emulsion Resin 그라스비드Grasvid 중공세라믹Hollow Ceramic 유색무기안료Colored inorganic pigment water 계면활성제Surfactants 증점제Thickener 분산제Dispersant 침강제Sedimentant 30-50중량%30-50% by weight 10-25중량%10-25% by weight 10-30중량%10-30% by weight 10-30중량%10-30% by weight 10-30중량%10-30% by weight 1-5중량%1-5% by weight 1-5중량%1-5% by weight 1-3중량%1-3% by weight 1-3중량%1-3% by weight

<제1실시예>First Embodiment

1. 실험1. Experiment

1.1 시험개요1.1 Exam Outline

실내 조사 시험은 차열 성능을 평가 하기 위한 실험으로 시험방법은 2008년 일본의 토목 기술센터에서 실시한 유체타입 차열성 포장의 노면온도 저감성능평가의 실내 조사시험법 표 1을 인용하여 실험을 실시하였으며, 조사 시험에 사용한 램프는 일본 차열성포장연구회에서 사용하는 키세논 램프와 빔 램프 중 자연광에 가까운 파장을 지닌 키세논 램프보다 일본 성능규정 공사에서의 규정치로서의 실적과 보수성 포장연구회에서도 사용되는 범용성이 높은 빔 램프를 선택 하였다. 본 실험에 사용된 빔 램프는 Philips사의 120W E27220-240V par38 30° 이다. 그리고 온도와 습도를 일정하게 유지하기 위해 항온항습실에서 실험을 실시하였으며, 시편의 표면온도는 접지식 온도계를 사용하여 전열대의 3점을 측정하여 평균온도를 측정하였다.
The indoor irradiation test is an experiment for evaluating the thermal insulation performance. The test method was carried out by citing Table 1 of the indoor irradiation test method of road surface temperature reduction performance evaluation of a fluid type thermal insulation pavement conducted by the Japanese Civil Engineering Center in 2008. The lamps used for the irradiation test are more versatile than those of the xenon lamps and beam lamps used by the Japan Thermal Protection Packaging Institute and the xenon lamps with wavelengths close to natural light. Beam lamp was selected. The beam lamp used in this experiment is Philips' 120W E27220-240V par38 30 °. In order to keep the temperature and humidity constant, the experiment was conducted in a constant temperature and humidity room. The surface temperature of the specimen was measured by measuring the three points of the heating table using a grounding thermometer and the average temperature was measured.

실내 조사시험법Indoor survey test method 항 목Item 차열성 포장Heat shield packaging 평가방법Assessment Methods 3시간 동안 조사(照射)하여 비교포장의 표면온도가 60℃가 되는 시험조건에서 차열성 포장 또는 보수성 포장의 표면온도를 구하여, 그 온도차를 노면온도 저감량으로 평가한다.After irradiation for 3 hours, the surface temperature of the heat-shielding pavement or water-retaining pavement is obtained under the test conditions at which the surface temperature of the comparative pavement reaches 60 ° C, and the temperature difference is evaluated as the road surface temperature reduction amount. 조사램프의 종류Type of irradiation lamp 산광형 빔 램프 BRF 110V 120W, 키세논 램프 XC-500EFDiffuse Beam Lamps BRF 110V 120W, Xenon Lamps XC-500EF 시험·양생온도Test and curing temperature 30±1℃30 ± 1 ℃ 시험·양생습도Test and Curing Humidity 50±5RH%50 ± 5RH% 조사높이 (조사량)Irradiation height 비교포장의 표면온도가 3시간이 지나면 60℃가 되는 높이(또는 조사량)Height (or irradiation amount) to 60 ℃ after 3 hours of surface temperature of comparative packaging 공시체
양생시간
Specimen
Curing time
5시간 이상5 hours or more
측정항목Metric 표면온도, 항온항습실의 온도 및 습도Surface temperature, temperature and humidity of constant temperature and humidity room 표면 온도 측정방법Surface temperature measurement method 열전대 공시체 표면Thermocouple specimen surface

1.2 공시체 및 단열재 제작1.2 Fabrication of specimens and insulation

본 조사실험에 사용된 아스팔트 시편은 일본 토목기술센터의 차열성 포장의 조사시험에 사용된 10×10×5㎝의 정사각형으로 제작 하였다.
Asphalt specimens used in this study were fabricated into 10 × 10 × 5cm squares, which were used for the thermal insulation paving test of the Japan Civil Engineering Center.

그림 1. 공시체 및 단열제 제작Figure 1. Construction of specimen and insulation

Figure pat00001
Figure pat00002

Figure pat00001
Figure pat00002

2. 실험 결과2. Experimental results

2.1 차열성능평가2.1 Thermal Performance Evaluation

① 아스팔트 콘크리트 포장① asphalt concrete pavement

아스팔트포장 기준 시편과 열저감반사도료를 도포한 아스팔트 시편을 일본의 토목 기술센터에서 실시한 유체타입 차열성 포장의 노면온도 저감성능평가의 실내 조사시험법에 의해 시험온도 30±1℃시험습도 50±5RH%의 항온 항습 조건에서 조사 실험을 실시 하였다.Asphalt pavement test specimen and asphalt specimen coated with heat-resistant antireflective paint were tested at room temperature 30 ± 1 ℃ by the indoor investigation test method for evaluation of road surface temperature reduction performance of fluid-type heat-shielding pavement conducted by the Japanese Civil Engineering Center. Irradiation experiments were carried out in a constant temperature and humidity conditions of 5RH%.

조사 3시간동안에 급격한 온도 변화를 나타냈지만 그이후 안정되는 경향을 나타냈고 아스팔트 기준 시편의 온도가 65℃까지 올라 갔을때, 열저감반사도료를 도포한 아스팔트시편에서 약 -20℃의 온도 저감 효과를 나타냈다.
After 3 hours of irradiation, there was a rapid temperature change, but it showed a tendency to stabilize thereafter. When the temperature of the asphalt-based specimens rose to 65 ℃, the temperature-reducing effect of about -20 ℃ was shown on the asphalt specimen coated with heat-resistant anti-reflective paint. .

Figure pat00003
Figure pat00003

측정시간Measuring time 아스팔트 포장Asphalt pavement 열저감반사도료Heat Resistant Reflective Paint 00:0000:00 28.128.1 27.927.9 01:0001:00 45.745.7 35.835.8 02:0002:00 56.956.9 41.241.2 03:0003:00 62.462.4 42.442.4 04:0004:00 64.864.8 42.642.6 05:0005:00 6565 43.443.4 06:0006:00 64.564.5 44.944.9 07:0007:00 66.266.2 44.844.8 08:0008:00 66.866.8 45.645.6 09:0009:00 67.567.5 45.445.4 10:0010:00 66.466.4 4545 11:0011:00 66.466.4 45.445.4 12:0012:00 65.665.6 46.446.4

② 시멘트 콘크리트 포장② cement concrete pavement

시멘트 콘크리트 기준 시편과 열저감반사도료를 도포한 콘크리트 시편을 일본의 토목 기술센터에서 실시한 유체타입 차열성 포장의 노면온도 저감성능평가의 실내 조사시험법에 의해 시험온도 30±1℃시험습도 50±5RH%의 항온 항습 조건에서 조사 실험을 실시하였다.Test temperature 30 ± 1 ℃ Test humidity 50 ± by cement-based concrete test specimen and concrete specimen coated with heat-resistant antireflective paint Irradiation experiments were conducted at a constant temperature and humidity of 5RH%.

조사 3시간동안에 급격한 온도 변화를 나타냈지만 그이후 안정되는 경향을 나타냈고 콘크리트 기준 시편의 온도가 65℃까지 올라 갔을때, 열반사 도료를 도포한 콘크리트시편에서 약 -15℃의 온도 저감 효과를 나타냈다.
After 3 hours of irradiation, there was a rapid temperature change, but it showed a tendency to stabilize thereafter. When the temperature of the concrete standard specimen rose to 65 ℃, the temperature reduction effect of -15 ℃ was shown on the concrete specimen coated with the heat-reflective paint.

Figure pat00004
Figure pat00004

측정시간Measuring time 콘크리트 포장Concrete pavement 열저감반사도료Heat Resistant Reflective Paint 00:0000:00 27.427.4 28.228.2 01:0001:00 41.641.6 36.836.8 02:0002:00 54.254.2 42.342.3 03:0003:00 59.159.1 45.445.4 04:0004:00 63.763.7 46.746.7 05:0005:00 64.964.9 47.247.2 06:0006:00 66.366.3 48.448.4 07:0007:00 66.466.4 50.650.6 08:0008:00 66.066.0 50.650.6 09:0009:00 65.965.9 50.250.2 10:0010:00 66.466.4 50.450.4 11:0011:00 65.965.9 50.750.7 12:0012:00 66.466.4 50.250.2

③ 명색안료 사용에 따른 차열성능평가③ Evaluation of thermal insulation performance by using bright pigment

열반사 차열도료를 적색과 녹색으로 조색 하였을 때 차열효과에 미치는 영향을 알아보기 위해 실시하였으며 이 실험에 사용된 차열도료는 적색 (L: 39.7, a: 33.4, b: 24.7) 녹색 (L: 40.3, a: -31.1, b: 21.2)로 색차계를 이용하여 색차를 측정하였다.This study was conducted to investigate the effect of heat reflecting heat shielding paint on the heat shielding effect of red and green color (L : 39.7, a : 33.4, b : 24.7) L * : 40.3, a * : -31.1, b * : 21.2), and measured the color difference using a color difference meter.

차열도료 적색과 녹색 모두 조사 3시간동안 급속한 온도 상승변화를 보였으나 3시간 이후에는 큰 온도상승 폭은 보이지 않았다. 아스팔트 시편과 비교 시 아스팔트 시편의 표면온도가 70℃로 상승시 적색차열도료의 경우 54.6℃, 녹색차열도료의 경우 55.5℃로 약 15℃의 온도 감소 효과를 나타냈다.
Both the red and green heat shields showed a rapid change in temperature over three hours of irradiation, but no significant increase in temperature was observed after three hours. Compared with the asphalt specimen, when the surface temperature of the asphalt specimen increased to 70 ℃, the temperature reduction effect of about 15 ℃ was shown at 54.6 ℃ for the red heat shield paint and 55.5 ℃ for the green heat shield paint.

Figure pat00005
Figure pat00005

측정시간Measuring time 아스팔트포장Asphalt paving 열저감반사도료
(적색)
Heat Resistant Reflective Paint
(Red)
열저감반사도료
(녹색)
Heat Resistant Reflective Paint
(green)
00:0000:00 20.220.2 19.419.4 19.719.7 01:0001:00 54.454.4 37.837.8 38.738.7 02:0002:00 64.264.2 46.946.9 49.549.5 03:0003:00 6666 49.649.6 50.750.7 04:0004:00 68.368.3 51.251.2 54.254.2 05:0005:00 67.367.3 52.252.2 54.454.4 06:0006:00 67.567.5 54.454.4 54.954.9 07:0007:00 67.167.1 5454 55.255.2 08:0008:00 67.467.4 54.654.6 5555 09:0009:00 70.270.2 54.854.8 55.755.7 10:0010:00 70.670.6 54.654.6 55.555.5

<제2실시예>Second Embodiment

1. 반사성능평가1. Reflection performance evaluation

반사율 성능 평가는 일본의 JIS K 5602:2008 규격을 인용하여 분광 반사율을 측정하여 일사반사율을 계산하였다. 분광반사율은 파장범위 300~2500nm에서 규정의 파장력에 대해 분광광도계를 사용하여 측정한 반사광속으로 구하여진 반사율을 말하며, 이로부터 구하여진 분광반사율에서 산출하는 일사분사율은 도막표면에 입사하는 전천일사에 대한 도막으로부터의 반사광속의 비율을 말한다.Reflectance performance evaluation was based on the JIS K 5602: 2008 standard of Japan to measure the spectral reflectance to calculate the solar reflectance. The spectral reflectance refers to the reflectance obtained by the reflected light flux measured using a spectrophotometer with respect to the prescribed wavelength power in the wavelength range 300 to 2500 nm. The ratio of the reflected light beam from the coating film to the

파장 wavelength 분광반사율(%)Spectral reflectance (%) 일사반사율(%)Increment reflectance (%) 전 파장 영역Full wavelength range 8484 8888 가시광 파
장 영역(320~780)
Visible light wave
Long Area (320-780)
8989 9191
적외선 파장 영역(780~2500)Infrared wavelength range (780 ~ 2500) 8080 8585

Figure pat00006
Figure pat00006

파장 λ(㎚)Wavelength λ (nm) 차폐계수 (W/㎡)Shielding coefficient (W / ㎡) 시험파장 λ(㎚)Test wavelength λ (nm) 보정파장 λ(㎚)Correction wavelength λ (nm) 분광반사율(%)Spectral reflectance (%) 일사반사율(%)Increment reflectance (%) 325325 0.10830.1083 325.26325.26 325325 95.2473101695.24731016 10.3152836910.31528369 330330 0.16260.1626 329.75329.75 330330 88.6529662088.65296620 14.4149723014.41497230 335335 0.19890.1989 335.67335.67 335335 91.0522422591.05224225 18.1102909818.11029098 340340 0.20900.2090 340.08340.08 340340 92.8441234492.84412344 19.4044218019.40442180 345345 0.22140.2214 344.46344.46 345345 94.4542554394.45425543 20.9121721520.91217215 350350 0.23370.2337 350.26350.26 350350 88.3392464388.33924643 20.6448818920.64488189 360360 0.50850.5085 360.32360.32 360360 81.6771518681.67715186 41.5328317241.53283172 370370 0.60100.6010 370.28370.28 370370 66.7076980266.70769802 40.0913265140.09132651 380380 0.69830.6983 380.16380.16 380380 54.1090354654.10903546 37.7843394637.78433946 390390 0.72590.7259 389.98389.98 390390 48.1051557448.10515574 34.9195325534.91953255 400400 0.87820.8782 399.76399.76 400400 55.6361757455.63617574 48.8596895348.85968953 410410 1.09981.0998 409.51409.51 410410 72.7402915972.74029159 79.9997726979.99977269 420420 1.18631.1863 420.63420.63 420420 89.0195373989.01953739 105.6038772105.6038772 430430 1.14261.1426 430.37430.37 430430 92.3531679792.35316797 105.5227297105.5227297 440440 1.20241.2024 440.11440.11 440440 93.1132858493.11328584 111.9594149111.9594149 450450 1.43241.4324 449.87449.87 450450 93.5284360993.52843609 133.9701319133.9701319 460460 1.58311.5831 459.65459.65 460460 93.3989846693.39898466 147.8599326147.8599326 470470 1.61101.6110 470.86470.86 470470 93.8611432593.86114325 151.2103018151.2103018 480480 1.62551.6255 480.70480.70 480480 94.1681864794.16818647 153.0703871153.0703871 490490 1.60441.6044 490.57490.57 490490 94.4811142494.48111424 151.5854997151.5854997 500500 1.56401.5640 500.48500.48 500500 94.4930122194.49301221 147.7870711147.7870711 510510 1.58801.5880 510.43510.43 510510 94.4814329094.48143290 150.0365155150.0365155 520520 1.55571.5557 520.42520.42 520520 94.7581068894.75810688 147.4151869147.4151869 530530 1.54851.5485 530.44530.44 530530 94.6726827294.67268272 146.6006492146.6006492 540540 1.58191.5819 540.49540.49 540540 94.6244276894.62442768 149.6863821149.6863821 550550 1.57641.5764 550.58550.58 550550 94.5674675094.56746750 149.0761558149.0761558 570570 3.10293.1029 570.86570.86 570570 94.3609765694.36097656 292.7926742292.7926742 590590 2.93472.9347 589.79589.79 590590 94.4658774594.46587745 277.2290105277.2290105 610610 2.91832.9183 610.28610.28 610610 94.4653478994.46534789 275.6782247275.6782247 630630 2.95742.9574 630.84630.84 630630 94.2785039294.27850392 278.8192475278.8192475 650650 2.89112.8911 650.00650.00 650650 94.4132493794.41324937 272.9581453272.9581453 670670 2.84882.8488 670.68670.68 670670 94.1888622394.18886223 268.3252307268.3252307 690690 2.55512.5551 689.92689.92 690690 94.0184240494.01842404 240.2264753240.2264753 710710 2.47852.4785 710.68710.68 710710 93.6523384993.65233849 232.1173210232.1173210 718718 0.94290.9429 718.11718.11 718718 93.4822371593.48223715 88.1444014188.14440141 724724 0.66570.6657 724.05724.05 724724 93.4614065793.46140657 62.2172583562.21725835 740740 1.78131.7813 740.40740.40 740740 93.2159111993.21591119 166.0455026166.0455026 753753 1.52281.5228 752.31752.31 753753 92.9286176692.92861766 141.5116990141.5116990 758758 0.60010.6001 756.78756.78 758758 92.8779105192.87791051 55.7360341055.73603410 763763 0.46060.4606 762.75762.75 763763 92.7676330992.76763309 42.7287718042.72877180 768768 0.42390.4239 767.22767.22 768768 92.6371020492.63710204 39.2688675539.26886755 780780 1.36871.3687 780.66780.66 780780 92.4029387592.40293875 126.4719023126.4719023 800800 2.24152.2415 800.12800.12 800800 92.2046258992.20462589 206.6766689206.6766689 816816 1.56471.5647 816.63816.63 816816 92.0874466592.08744665 144.0892278144.0892278 824824 0.63740.6374 824.15824.15 824824 92.0196043892.01960438 58.6532958358.65329583 832832 0.67220.6722 831.68831.68 832832 91.9001353191.90013531 61.7752709661.77527096 840840 0.70780.7078 840.74840.74 840840 91.7485424291.74854242 64.9396183264.93961832 860860 1.96401.9640 860.41860.41 860860 91.6246764791.62467647 179.9508646179.9508646 880880 1.93701.9370 880.17880.17 880880 91.3509670991.35096709 176.9468233176.9468233

파장 λ(㎚)Wavelength λ (nm) 차폐계수 (W/㎡)Shielding coefficient (W / ㎡) 시험파장 λ(㎚)Test wavelength λ (nm) 보정파장 λ(㎚)Correction wavelength λ (nm) 분광반사율(%)Spectral reflectance (%) 일사반사율(%)Increment reflectance (%) 905905 2.12952.1295 904.61904.61 905905 90.8816246790.88162467 193.5324197193.5324197 915915 0.71720.7172 915.35915.35 915915 90.4995193790.49951937 64.9062552964.90625529 925925 0.68770.6877 924.57924.57 925925 90.5079349490.50793494 62.2423068662.24230686 930930 0.27700.2770 930.72930.72 930930 90.4425535390.44255353 25.0525873325.05258733 937937 0.23470.2347 936.88936.88 937937 90.4036847590.40368475 21.2177448121.21774481 948948 0.31860.3186 947.68947.68 948948 90.3516725990.35167259 28.7860428928.78604289 965965 0.72360.7236 964.66964.66 965965 90.3225838190.32258381 65.3574216565.35742165 980980 0.89140.8914 980.11980.11 980980 90.4257137890.42571378 80.6054812680.60548126 994994 0.95260.9526 992.45992.45 994994 90.3272974290.32729742 86.0457835286.04578352 10401040 3.38523.3852 1044.111044.11 10401040 91.4437907691.44379076 309.5555205309.5555205 10701070 2.01792.0179 1075.731075.73 10701070 90.1918259490.19182594 181.9980856181.9980856 11001100 1.59571.5957 1106.401106.40 11001100 91.7315160291.73151602 146.3759801146.3759801 11201120 0.52830.5283 1116.411116.41 11201120 91.6657153591.66571535 48.4269974248.42699742 11301130 0.15090.1509 1126.331126.33 11301130 91.3857051591.38570515 13.7901029113.79010291 11371137 0.11390.1139 1136.151136.15 11371137 91.0119507091.01195070 10.3662611810.36626118 11611161 0.57280.5728 1165.021165.02 11611161 89.5127669489.51276694 51.2729129051.27291290 11801180 0.76890.7689 1183.791183.79 11801180 87.9671065887.96710658 67.6379082567.63790825 12001200 0.89510.8951 1202.211202.21 12001200 87.0915850987.09158509 77.9556778177.95567781 12351235 1.60281.6028 1238.011238.01 12351235 88.6368749688.63687496 142.0671832142.0671832 12901290 2.48942.4894 1289.291289.29 12901290 89.1985741589.19857415 222.0509305222.0509305 13201320 1.00791.0079 1322.001322.00 13201320 88.3998706688.39987066 89.0982296489.09822964 13501350 0.42960.4296 1353.651353.65 13501350 87.1173846987.11738469 37.4256284637.42562846 13951395 0.07770.0777 1391.841391.84 13951395 83.6739605183.67396051 6.5014667326.501466732 14431443 0.13790.1379 1443.101443.10 14431443 82.6480984782.64809847 11.3971727811.39717278 14771477 0.15470.1547 1478.371478.37 14771477 83.5865044783.58650447 12.9308322412.93083224 14971497 0.29130.2913 1499.091499.09 14971497 83.8745428883.87454288 24.4326543424.43265434 15201520 0.51810.5181 1519.531519.53 15201520 84.1081780884.10817808 43.5764470643.57644706 15391539 0.51660.5166 1539.721539.72 15391539 83.8692294983.86922949 43.3268439643.32684396 15581558 0.52850.5285 1559.701559.70 15581558 83.6896876283.68968762 44.2299999144.22999991 15921592 0.34890.3489 1592.651592.65 15921592 83.1482771583.14827715 29.0104339029.01043390 16101610 0.43410.4341 1612.271612.27 16101610 82.3144352582.31443525 35.7326963435.73269634 16301630 0.47940.4794 1631.831631.83 16301630 81.4089969581.40899695 39.0274731439.02747314 16461646 0.38840.3884 1644.851644.85 16461646 79.9069963779.90699637 31.0358773931.03587739 16781678 0.73800.7380 1677.451677.45 16781678 72.0222511372.02225113 53.1524213353.15242133 17401740 1.23101.2310 1743.401743.40 17401740 68.5222726268.52227262 84.3509176084.35091760 18001800 0.61450.6145 1797.691797.69 18001800 72.8611609672.86116096 44.7731834144.77318341 18601860 0.09940.0994 1861.421861.42 18601860 74.7974710474.79747104 7.4348686217.434868621 19201920 0.00970.0097 1922.481922.48 19201920 67.5593383867.55933838 0.6553255820.655325582 19601960 0.04540.0454 1958.081958.08 19601960 68.9557148368.95571483 3.1305894533.130589453 19851985 0.14220.1422 1981.471981.47 19851985 70.4892578670.48925786 10.0235724710.02357247 20052005 0.11940.1194 2004.592004.59 20052005 71.4447959671.44479596 8.5305086378.530508637 20352035 0.19190.1919 2038.772038.77 20352035 71.6128163171.61281631 13.7424994513.74249945 20652065 0.24300.2430 2061.212061.21 20652065 71.4198808471.41988084 17.3550310417.35503104 21002100 0.26500.2650 2105.292105.29 21002100 68.7423913968.74239139 18.2167337218.21673372 21482148 0.41650.4165 2148.292148.29 21482148 64.1017401964.10174019 26.6983747926.69837479 21982198 0.38930.3893 2200.512200.51 21982198 61.2752066761.27520667 23.8544379623.85443796 22702270 0.51680.5168 2270.772270.77 22702270 35.7445428435.74454284 18.4727797418.47277974 23602360 0.60260.6026 2356.242356.24 23602360 38.3407275338.34072753 23.1041224123.10412241 24992499 0.08850.0885 2494.642494.64 24992499 40.8689401040.86894010 3.6169011993.616901199

이상에서와 같이 콘크리트 또는 아스팔트 콘크리트 도로 포장면(100)에 1차 도포층(200) 도포후 2차 도포층(200) 도포시 도로 포장체 표면 온도를 7~15℃ 정도 저감시키게 되고 또한 태양광 전 파장영역에서의 일사반사율은 적어도 70% 이상을 보이는 결과를 알 수 있다.
As described above, when the first coating layer 200 is applied to the concrete or asphalt concrete pavement surface 100 and then the second coating layer 200 is applied, the surface temperature of the road pavement body is reduced by about 7 to 15 ° C. It can be seen that the solar reflectance in the entire wavelength range is at least 70%.

100: 포장면
200: 1차 도포층
300: 2차 도포층
100: packing cotton
200: primary coating layer
300: secondary coating layer

Claims (6)

상온건조형 아크릴에멀젼수지 30~50중량%, 그라스비드 10~25중량%, 중공세라믹 10~30중량%, 유색무기안료 10~30중량%, 물 10~30중량%, 계면활성제 1~5중량%, 증점제 1~5중량%, 분산제 1~3중량%, 침강제 1~3중량%를 혼합하여 얻어지는 것을 특징으로 하는 열저감 반사도료.
Room temperature drying acrylic emulsion resin 30-50 wt%, glass beads 10-25 wt%, hollow ceramic 10-30 wt%, colored inorganic pigment 10-30 wt%, water 10-30 wt%, surfactant 1-5 wt% A heat-retardant reflective coating, obtained by mixing%, thickener 1 to 5% by weight, dispersant 1 to 3% by weight, and settling agent 1 to 3% by weight.
청구항 1에 있어서,
상기 글라스비드는,
굴절률이 적어도 2.2 이상인 그라스에 알루미늄 또는 금속이 1~40㎛ 두께를 가지며 진공증착으로 코팅된 것을 특징으로 하는 열저감 반사도료.
The method according to claim 1,
The glass beads,
Heat-reduction reflecting paint, characterized in that the glass having a refractive index of at least 2.2 or more of aluminum or metal having a thickness of 1 ~ 40㎛ coated by vacuum deposition.
청구항 1에 있어서,
상기 중공세라믹은,
밀도 0.5-0.7(g/cc), 입도 15~65이고 체적대비 중공률이 20~60%인 것을 특징으로 하는 열저감 반사도료.
The method according to claim 1,
The hollow ceramic,
Heat-resistant reflective paint, characterized by a density of 0.5-0.7 (g / cc), a particle size of 15 to 65 and a hollow ratio of 20 to 60% by volume.
청구항 1에 있어서,
상온건조형 아크릴에멀젼수지(Acrylate emulsion resin)는,
메칠메타아크릴, 메타아크릴산, 아크릴아마이드의 공중합체로 이루어진 것임을 특징으로 하는 열저감 반사도료.
The method according to claim 1,
Room temperature drying type acrylic emulsion resin (Acrylate emulsion resin),
Heat-resistant reflective coating, characterized in that consisting of a copolymer of methyl methacryl, methacrylic acid, acrylamide.
도로 포장면에,
유변성 알키드 수지와 경화제로 MDI를 사용한 바인더를 혼합하여 0.1-0.5mm로 도포하는 1차 도포층 형성단계;
상기 1차 도포층 형성단계후 상면에 상도로 열저감반사도료를 규사와 혼입하여 0.1-3mm로 도포하는 2차 도포층 형성단계를 수행하여서 된 것을 특징으로 하는 열저감 반사도료를 이용한 도로 포장 공법.
On road pavement,
Forming a primary coating layer by mixing a rheology alkyd resin and a binder using MDI as a curing agent and coating the film with 0.1-0.5 mm;
The road pavement method using the heat-reduced reflective paint, characterized in that by performing a secondary coating layer forming step of incorporating the heat-resistant low-reflective paint with silica sand on the upper surface after the first coating layer forming step to apply 0.1-3mm .
상기 1차 도포층 형성 단계에서,
보수성 폴리머 수지를 더 혼합하여서 됨을 특징으로 하는 열저감 반사도료를 이용한 도로 포장 공법.
In the first coating layer forming step,
Road paving method using heat-resistant reflective paint, characterized by further mixing the water-retaining polymer resin.
KR1020100062741A 2010-06-30 2010-06-30 Reflection paints of heat and a road pavement method using it KR20120002054A (en)

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KR101297222B1 (en) * 2013-02-07 2013-08-16 송혜성 Anti-condensation paint composition comprising hollow ceramic beads
KR101519368B1 (en) * 2015-01-05 2015-05-18 권희문 Reflective Finishing Material with Concrete Reinforcing Function
CN105542636A (en) * 2015-12-26 2016-05-04 杭州福斯特光伏材料股份有限公司 Infrared high-reflection coating
KR101844768B1 (en) * 2017-12-12 2018-04-05 주식회사 한국도로기술 Pavement Style Waterproof Asphalt Composition for Construction and Construction Methods Using Thereof
CN113930114A (en) * 2020-08-06 2022-01-14 长沙民德消防工程涂料有限公司 Reflective heat-insulating coating and preparation method thereof
CN115798351A (en) * 2022-12-19 2023-03-14 淮安惠铭光学材料有限公司 Glass bead sealed capsule type vehicle body reflecting mark and processing technology thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101297222B1 (en) * 2013-02-07 2013-08-16 송혜성 Anti-condensation paint composition comprising hollow ceramic beads
KR101519368B1 (en) * 2015-01-05 2015-05-18 권희문 Reflective Finishing Material with Concrete Reinforcing Function
CN105542636A (en) * 2015-12-26 2016-05-04 杭州福斯特光伏材料股份有限公司 Infrared high-reflection coating
KR101844768B1 (en) * 2017-12-12 2018-04-05 주식회사 한국도로기술 Pavement Style Waterproof Asphalt Composition for Construction and Construction Methods Using Thereof
CN113930114A (en) * 2020-08-06 2022-01-14 长沙民德消防工程涂料有限公司 Reflective heat-insulating coating and preparation method thereof
CN115798351A (en) * 2022-12-19 2023-03-14 淮安惠铭光学材料有限公司 Glass bead sealed capsule type vehicle body reflecting mark and processing technology thereof
CN115798351B (en) * 2022-12-19 2023-12-01 淮安惠铭光学材料有限公司 Glass bead sealed capsule type vehicle body reflective marker and processing technology thereof

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