KR20110061807A - High strength, toughness and deformability steel plate for pipeline and manufacturing metod of the same - Google Patents

Abstract

PURPOSE: A steel plate for a high intensity, high tenacity and high transform ability line pipe and a manufacturing method thereof are provided to satisfy mechanical property for API-X100 class. CONSTITUTION: A steel plate for a high intensity, high tenacity and high transform ability line pipe comprises carbon(C) 0.03~0.08%, silicon(Si) 0.05~0.50%, manganese(Mn) 1.4~2.0%, aluminum(Al) 0.01~0.05%, titanium(Ti) 0.005~0.02%, niobium(Nb) 0.02~0.07%, nitrogen(N) 0.003~0.01%, calcium(Ca) 0.0005~0.004%, vanadium(V) less than 0.05%, nickel(Ni) less than 0.4% copper less than 0.5%(Cu) phosphorus(P) less than 0.02%, sulfur(S) less than 0.005%, inevitable remnant iron(Fe), and impurities. A micro-structure comprises martensite(MA) 3~10%, ferrite 5~20% and remnant bainite.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a steel plate for a high-strength, high-toughness and high-

More particularly, the present invention relates to a steel sheet for a line pipe which satisfies the strength, low temperature toughness and deformability required by the API-X100 grade, and a steel sheet for a line pipe which can be used in a cold- And a method for manufacturing the same.

In recent years, the development of oilfields in cold climates, such as Siberia and Alaska, has become more active, and the requirements for low temperature toughness of steel sheets for line pipes have been strengthened. Particularly, in order to secure sufficient stability of the pipe structure, a guarantee at a level of 0 ° C or -10 ° C has been required. However, in recent years, a line pipe steel pipe having a level of -20 ° C have.

Generally, in order to safely use a steel sheet for a line pipe at a low temperature, a drop weight tear test (DWTT) characteristic showing brittle fracture stop characteristics should be excellent. In the conventional environment, it was possible to use DWTT ductile waveguide ratio of more than 85% at -10 ℃ in the pipe state. However, in extreme cold environment, DWTT ductile waveguide ratio is required to be 85% or more at -20 ℃.

In addition, superior pipe deformation in the pipe axis direction is also required in terms of the stability of the pipeline against earthquakes and the risk of collapse of the pipeline due to the movement of the soil when the frozen soil thaws to the cold region. In order to have resistance to earthquake and soil movement, the buckling strain in the pipe condition is 1.5 in the case of the 100 ksi class steel with yield strength of 1.5 % Or more is required.

20 / Cu + 20 + Ni / 60 + Cu + 20 + Cu + 20 + Cu + 20 + Cu + Characterized by comprising a bainite structure containing 5 to 20% of martensite structure having a Cr / 32 + Mo / 7 value of 0.11 and an aspect ratio of 4.0. To a steel member.

Another technique is Japanese Patent Application Laid-Open No. 2004-131799, which is a bainite structure in which the structure of the base material portion contains ferrite having an average particle diameter of 5 탆 or less at an area ratio of 20% or more, Characterized in that lower bainite is contained in an area ratio of 5% or more in a structure formed in a coarse-grained austenite grain boundary of a heat-affected zone, and a high-strength steel pipe excellent in low-temperature toughness and HAZ toughness.

Another technique is Japanese Patent Application Laid-Open No. 2004-143499. This technique has a microstructure containing ferrite having an average crystal grain size of 10 탆 or less and an areal ratio of 70 to 90% and is measured by X-ray diffraction Strength steel pipes and slabs excellent in buckling characteristics having a local austenite content of 5 to 15% are reheated at a temperature higher than 1050 DEG C, and rolled at an accumulation reduction rate of 65% And cooling the steel sheet at a temperature not lower than the Ar3 temperature to 5 deg. C / s or more and controlling the cooling conditions.

The techniques disclosed in the above-mentioned Japanese Patent Laid-Open Publication No. 2000-22995 all show a uniform elongation of 6% or more for pipes having excellent plastic deformation characteristics. However, when the pipes are heat-treated at a maximum temperature of 250 占 폚 for corrosion- Since discontinuous yielding occurs, the plastic deformation capacity can not be reduced rapidly, so it is difficult to easily apply it to the extremes or earthquakes.

Therefore, in order to solve such a problem, a steel sheet for a line pipe exhibiting excellent plastic deformation resistance even when heat-treated with a corrosion-resistant coating has been studied. In Japanese Patent Laid-Open Publication No. 2002-220634, The present inventors have proposed a method of restricting strain aging by restricting the content and further adding Nb and Ti and combining these elements with C and N. However, since the rolling is performed at an extremely low temperature for the precipitation of carbonitrides during rolling, There is a problem in that the manufacturing cost is increased.

Japanese Patent Application Laid-Open No. 2007-302947 also proposes a method of manufacturing a steel sheet and a steel pipe having good HAZ toughness and having a deformability even after coating heat treatment. However, the amount of Cr added is in the range of 0.5 to 1.5% by weight, which is not preferable. The effect of physical properties on toughness is expressed only by the impact energy value, but the effect on DWTT showing ductile fracture characteristics is not shown. In addition, since the rolling finish temperature is as low as 700 to 850 DEG C, the productivity is somewhat deteriorated.

The present invention relates to an API-X100 grade line which improves strength, low-temperature toughness and deformability by controlling the microstructure by optimizing the composition of the steel sheet and cooling the hot-rolled steel sheet by cooling twice during cooling A steel sheet for a pipe, and a manufacturing method thereof.

In one embodiment, the present invention provides a method of manufacturing a semiconductor device, comprising, by weight%, 0.03 to 0.08% carbon, 0.05 to 0.50% silicon, 1.4 to 2.0% manganese (Mn) (N): 0.003 to 0.01%, calcium (Ca): 0.0005 to 0.004%, vanadium (V): not more than 0.05%, titanium (Ti): 0.005 to 0.02%, niobium (Nb): 0.02 to 0.07% Not more than 0.4% of nickel (Ni), not more than 0.5% of copper (Cu), not more than 0.02% of phosphorus (P), not more than 0.005% of sulfur (S) The structure provides a steel sheet for a line pipe comprising 3 to 10% of martensite (MA), 5 to 20% of ferrite and bainite bainite.

The steel sheet may further include at least one of chromium (Cr): 0.1 to 0.5% and molybdenum (Mo): 0.3% or less by weight.

The grain size of the amorphous martensite (MA) is preferably 3 m or less, and the grain size of the ferrite and bainite is preferably 8 m or less.

In another embodiment of the present invention, there is provided a method of manufacturing a semiconductor device, comprising: 0.03 to 0.08% carbon (C), 0.05 to 0.50% silicon (Si), 1.4 to 2.0% manganese (Mn) (N): 0.003 to 0.01%, calcium (Ca): 0.0005 to 0.004%, vanadium (V): not more than 0.05%, titanium (Ti): 0.005 to 0.02%, niobium (Nb): 0.02 to 0.07% , Fe (Fe) and other unavoidable impurities, the content of iron (Fe) being 0.4% or less, the content of copper (Cu) being 0.5% or less, the content of phosphorus (P) being 0.02% To 1100 to 1180 캜; Rolling the slab at a temperature of 1000 to 1100 DEG C at a reduction ratio of 10% or more per pass; A non-recrystallized reverse rolling step in which the rolling is performed at a cumulative rolling reduction of 70% or more at 800 to 950 ° C; A first cooling step of cooling the rolled steel sheet to a temperature equal to or higher than the Ar3 transformation point at a cooling rate of 5 to 10 DEG C / s to an Ar1 transformation point or more; And a second cooling step of cooling the cooled steel sheet at a rate of 10 to 30 占 폚 / s within a range of Ms (martensitic transformation start temperature) -50 占 폚 to Ms-200 占 폚. to provide.

The steel sheet may further include at least one of chromium (Cr): 0.1 to 0.5% and molybdenum (Mo): 0.3% or less by weight.

It is preferable that the manufacturing method is air-cooled between the recrystallization reverse rolling step and the non-recrystallization reverse rolling step without rolling.

According to the present invention, it is possible to provide a steel sheet for a line pipe excellent in strength, toughness and deformability, and the steel sheet for a line pipe can satisfactorily satisfy the mechanical properties required by the API-X100 grade.

The present invention provides a steel sheet for a line pipe excellent in strength, toughness and deformability having a microstructure including graphite martensite, ferrite and bainite by controlling the component system and the manufacturing method.

The present inventors have found that when ferrite is included, the concentration of free carbon is lowered by ferrite and the displacement of the dislocations can be improved to increase the deformability. In the case of containing martensite, the mobility increases locally around the martensite It is found that the strain can be increased and the grain size of the microstructure can be miniaturized to increase the toughness. In order to utilize this, the present invention has been completed by optimizing the component system and the manufacturing method.

Hereinafter, the component system of the steel sheet of the present invention will be described first.

Carbon (C): 0.03 to 0.08 wt%

Carbon is an element that can improve the strength of steel efficiently. When the content of carbon is less than 0.03% by weight, the effect of improving the strength is insignificant. Therefore, in order to satisfy the intended strength of the present invention, a large amount of expensive alloying elements must be added. On the other hand, when the content of carbon exceeds 0.08% by weight, weldability, moldability, toughness and deformability are impaired.

Silicon (Si): 0.05 to 0.5 wt%

Silicon is an element capable of deoxidizing molten steel and obtaining a solid solution strengthening effect. If the content of silicon is less than 0.05% by weight, deoxidation of the molten steel may not be sufficiently carried out and the toughness may be lowered, and sufficient strength can not be ensured. On the other hand, if it is more than 0.5% by weight, the martensite (MA) or the like may be generated on the heat affected portion of the welded portion, and the toughness of the welded portion may be inhibited.

Manganese (Mn): 1.4 to 2.0 wt%

Manganese is an element capable of enhancing the solid solution strengthening effect and toughness and promoting the formation of martensite on the surface. When the content of manganese is 1.4 wt% or more, the effect of increasing the entrapment property and the sufficient yield strength (yield strength required in 100 ksi steel) can be obtained. However, when the content exceeds 2.0% by weight, segregation occurs at the time of slab casting, and toughness and weldability of the final product may be impaired.

Aluminum (Al): 0.01 to 0.05 wt%

Aluminum is added as a deoxidizer together with silicon, which has the effect of strengthening the solid solution during the addition. In order to obtain such an effect, the content of aluminum is preferably 0.01 wt% or more. However, when it exceeds 0.05% by weight, impact toughness is deteriorated.

Titanium (Ti): 0.005-0.02 wt%

Titanium is an element capable of improving the toughness of the steel by forming a TiN precipitate and heating the slab or suppressing the growth of the austenite grains during hot rolling to miniaturize the grain size of the final product. When the content of titanium is less than 0.005% by weight, the formation of TiN precipitates is insufficient and the effect of inhibiting the growth of the austenite is small. On the other hand, if it exceeds 0.02% by weight, there is too much titanium, so that TiN is precipitated in the case of heating the slab, which adversely affects fineness of grain size.

Niobium (Nb): 0.02 to 0.07% by weight

Niobium is an element that fines crystal grains and promotes bainite formation, which is a high strength structure. When the content of niobium is less than 0.02% by weight, the effect is insignificant, so that the steel of the present invention preferably contains 0.02% by weight or more. However, if it exceeds 0.07% by weight, the generation of the low-temperature transformation phase is promoted and the toughness of the weld heat affected zone may be lowered.

Calcium (Ca): 0.0005 to 0.004 wt%

Calcium can stabilize the MnS inclusions and prevent cracking around the inclusions. However, when it is added at less than 0.0005% by weight, this effect is insignificant. Therefore, calcium is preferably contained in an amount of 0.0005% by weight or more, but if it exceeds 0.004% by weight, a large amount of CaO-based inclusions may be formed, thereby deteriorating toughness.

Nitrogen (N): 0.003 to 0.01 wt%

Nitrogen may lower the toughness of steel, so that the content thereof is generally controlled to a minimum. In the present invention, nitrogen reacts with titanium to form TiN precipitates, which can suppress the growth of grains during the slab reheating process. In order to exhibit such an effect, nitrogen is preferably contained in an amount of 0.003% by weight or more. However, when the content exceeds 0.01% by weight, nitrogen is contained too much to exist as nitrogen solide instead of TiN precipitate, which may result in a problem that the toughness can be largely lowered.

In addition, when the content ratio of titanium to nitrogen satisfies 2? Ti / N? 4, TiN precipitates can be appropriately formed.

Vanadium (V): not more than 0.05% by weight

Vanadium forms a V (C, N) precipitate with carbon and nitrogen and has a precipitation strengthening effect. It is an element useful for improving the strength and improving the incombustibility. However, when the content exceeds 0.05% by weight, weldability and toughness are deteriorated.

Nickel (Ni): not more than 0.4% by weight

Nickel improves toughness and improves brittle fracture stopping properties. However, when it is added in a large amount, it is uneconomical, so it is preferable to limit the upper limit of the content to 0.4 wt%.

Copper (Cu): not more than 0.5% by weight

If the content of copper exceeds 0.5% by weight, the toughness of the weld heat affected zone is lowered and the weldability in the field becomes poor.

The remainder of the present invention is iron (Fe). However, in the ordinary steel manufacturing process, impurities which are not intended from the raw material or the surrounding environment may be inevitably incorporated, so that it can not be excluded. These impurities are not specifically mentioned in this specification, as they are known to any person skilled in the art of steel making. However, since phosphorus and sulfur are generally referred to as impurities, a brief description thereof is as follows.

Phosphorus (P): not more than 0.02% by weight

Phosphorus is inevitably contained in the steel. When phosphorus is added, it is segregated in the center of the steel sheet to lower the toughness. Therefore, it is preferable to control the phosphorus content as low as possible. In theory, it is preferable to limit the phosphorus content to 0% . Therefore, it is important to manage the upper limit, and in the present invention, the upper limit of the content of phosphorus is preferably limited to 0.02 wt%.

Sulfur (S): 0.005 wt% or less

Sulfur is inevitably contained in the steel and forms a nonmetallic inclusion to lower the toughness and strength of the steel. Therefore, it is preferable to control the sulfur as low as possible. In theory, it is advantageous to limit the content of sulfur to 0% I can not help it. Therefore, it is important to manage the upper limit, and in the present invention, the upper limit of the sulfur content is preferably limited to 0.005 wt%.

In addition, the steel material of the present invention can further improve the effect of the present invention when at least one element of chromium (Cr) and molybdenum (Mo) is additionally added.

Cr (Cr): 0.1 to 0.5 wt%

Chromium is an effective element for improving the strength and is an element effective for forming martensite on the road during cold-accelerated cooling, and can replace an expensive molybdenum element. In addition, it improves the plastic deformation of the steel and affects the resistance to deformation of the steel in extreme conditions. In order to exhibit the above effect, it is preferable that chromium is contained at 0.1 wt% or more. However, if it is contained in an excessively large amount, the weldability may be deteriorated. Therefore, the upper limit of the content is preferably limited to 0.5% by weight.

Molybdenum (Mo): not more than 0.3% by weight

Molybdenum is an element effective for improving the strength of steel such as chromium, and is an effective element for forming bainite which is a low-temperature transformed structure. In addition, it is an element having a large influence on the improvement of the incombustibility, and contributes to the formation of the martensite on the road during the cold-cooling accelerated cooling, thereby improving the strength of the steel. However, if it is contained in an excessively large amount, the weldability may deteriorate, so that the upper limit of the content is preferably limited to 0.3 wt%.

The microstructure of the steel sheet according to the present invention satisfying the above-mentioned component system preferably contains 3 to 10% of martensite (MA), 5 to 20% of ferrite and 5 to 20% of bainite.

When 3 to 10% of martensite is included, locally movable dislocations are increased around the on-road martensite to improve the deformability of the steel sheet. If the amorphous martensite fraction is less than 3%, the strength may be lowered and the deformability may be lowered. On the other hand, if it exceeds 10%, an excessive amount of on-state martensite may be formed and the deformability may be lowered. The grain size of the onyx martensite (MA) is preferably 3 mu m or less. If the grain size of the amorphous martensite exceeds 3 mu m, the toughness may be lowered.

In addition, when 5 to 20% of ferrite is included, free carbon which diffuses to the center of the dislocation and inhibits the movement of the dislocation can be minimized. In addition, the grain size of ferrite and bainite is preferably 8 탆 or less. When the size of the crystal grains exceeds 8 mu m, the strength is lowered, the movable potential is insufficient, and the deformability may be lowered.

Hereinafter, a method of manufacturing the steel sheet of the present invention will be described.

The method for manufacturing a steel sheet according to the present invention is characterized in that the slabs satisfying the above-mentioned composition are reheated at 1100 to 1180 ° C and then subjected to a recrystallization reverse rolling step of rolling at an average reduction rate of 10% or more per pass at a temperature of 1000 to 1100 ° C, Lt; 0 > C and a cumulative rolling reduction of 70% or more at a temperature of < RTI ID = 0.0 > 300 C, < / RTI >

Slab reheating step: 1100 ~ 1180 ℃

In the present invention, titanium, niobium, and vanadium are selectively added, and solid carbon and solid molybdenum are selectively added to form a fine carbonitride precipitate, thereby forming bainite in the microstructure. Therefore, it is preferable that the slab is heated to 1100 DEG C or higher before the hot rolling to dissolve the carbonitride precipitates so that the elements are present in an atomic state. However, when it exceeds 1180 DEG C, there is a problem that TiN is dissolved and the crystal grains of austenite can coarser. Therefore, the reheating temperature of the slab is preferably limited to 1100 to 1180 ° C.

Recrystallization reverse rolling step: a temperature of 1000 to 1100 ° C, an average rolling reduction of 10% or more

In the present invention, since the content of niobium is 0.02 to 0.07% by weight, the austenite can be completely recrystallized during rolling in the case of performing the polycrystallization annealing in the above temperature range. When the rolling is performed in a temperature range of less than 1000 캜, partial recrystallization occurs and coarse austenite and fine austenite are mixed and formed. Therefore, the toughness may be largely lowered even when the rolling amount is large in the non-recrystallization reverse rolling step. The average rolling reduction per pass is preferably 10% or more, and when it is less than 10%, the austenite is partially recrystallized and the austenite grows non-uniformly, so that the grain size of the martensite becomes coarse after the final cooling, .

It is preferred that the slab is air-cooled between the subsequent recrystallization reverse rolling step and the subsequent uncrystallized reverse rolling step without rolling the slab. Rolling of the slab may result in partial recrystallization of the austenite resulting in coarse austenite and brittle fracture.

Non-recrystallized reverse rolling step: a temperature of 800 to 950 캜, a cumulative rolling reduction of 70% or more

The non-recrystallized reverse rolling is carried out in order to form a fine ferrite and bainite by inducing a grain boundary of the austenite stretched in the longitudinal direction and a strain structure in the grain. The lower the finishing temperature in the non-recrystallized reverse rolling, the more the austenite deformation increases and the toughness improves. However, when the finishing temperature is lower than 800 ° C, the deformed ferrite structure is formed and the toughness is lowered. Further, when rolling is performed at a temperature lower than 800 캜 to form a deformed ferrite, the dislocation is fixed to the solute carbon, so that strain aging may occur and the deformability may drop sharply. In addition, toughness of the non-recrystallized reverse rolling is increased as the cumulative rolling reduction is larger, and when the rolling reduction is less than 70%, sufficient brittle fracture stop resistance is not obtained.

Two stage cooling stage

It is preferable that the primary cooling step is started at the point immediately above the Ar3 transformation point and ends at the Ar1 transformation point or higher, and the cooling rate in the primary cooling step is preferably 5 to 10 占 폚 / s. When the cooling start temperature is less than Ar3, the ferrite may be generated during rolling or after cooling to reduce the physical properties. When the cooling end temperature is less than Ar1, the content of ferrite becomes too large and the strength may be lowered. When the cooling rate is less than 5 캜 / s, the grain size of the ferrite becomes coarse, and when the cooling rate exceeds 10 캜 / s, ferrite can not be formed. Therefore, the size of the crystal grains of the ferrite can be controlled to 8 탆 or less by performing the primary cooling step.

After the first cooling step, the second cooling step is preferably performed at a cooling rate of 10 to 30 ° C / s to terminate cooling at Ms-50 to Ms-200 ° C. Ms is the temperature at which the transformation of the martensite begins. In the present invention, the Ms temperature is defined as 561-747 * (% C) -33 * (% Mn) -17 * (% Ni) -17 * (% Cr) -21 * (% Mo). When the cooling rate is less than 10 ° C / s, the fraction of ferrite increases and the strength decreases. When the cooling rate exceeds 30 ° C / s, the low temperature martensite or low temperature bainite may be formed and the toughness may be lowered. In addition, when the cooling end temperature exceeds Ms-50 占 폚, the fraction of the martensite on the surface is lowered, the strength is lowered and the deformability is lowered. On the other hand, when the temperature is lower than Ms-200 DEG C, the martensite fraction becomes too high and toughness may be lowered. The secondary cooling step can be carried out to control the amorphous martensite fraction to 3 to 10%, and the grain size can be controlled to 3 탆 or less.

When the steel sheet produced by the above-mentioned manufacturing method is manufactured by a line pipe, the steel sheet has a circumferential yield strength of 690 MPa or more, a circumferential tensile strength of 760 MPa or more, a longitudinal yield strength of 660 MPa or more, a tensile strength in the longitudinal direction of 760 MPa or more, Impact toughness value (-20 ℃): 250J or more, DWTT (-20 ℃) Ductile waveguide ratio: 95~99%, weld heat affected zone toughness value (-20 ℃): 51J or more, uniform elongation: 6.0% It is possible to secure a deformation rate of 1.5% or more.

Hereinafter, the present invention will be described by way of examples.

(Example)

Slabs satisfying the composition shown in Table 1 were prepared, and then Inventive Examples and Comparative Examples each having a thickness of 20 mm were produced according to the production conditions shown in Table 2 below. Further, Submerged arc welding was performed in the longitudinal direction of the fabricated inventive and comparative examples to manufacture a 28-inch diameter steel tube, and then expanded to have a shrinkage amount of about 0.8% for securing the roundness. A tensile specimen of ASTM sub-size standard was taken in the circumferential direction and the longitudinal direction of the steel pipe, and then subjected to a tensile test after being subjected to heat treatment at 250 ° C. The yield strength and tensile strength were measured and are shown in Table 3 below. (20 deg. C), DWTT (-20 deg. C), HAZ toughness (-20 deg. C) and uniform elongation were measured and shown in Table 3 below. The results are shown in Table 3.

River classification C Si Mn P S Nb V Ni Cr Mo Al Ca Ti N Inventive Steel 1 0.05 0.2 1.9 0.010 0.001 0.02 0.04 0.1 0.1 0.2 0.03 0.0010 0.01 0.004 Invention river 2 0.04 0.1 1.8 0.007 0.001 0.055 0.04 0.35 0.3 0.1 0.02 0.0006 0.015 0.004 Invention steel 3 0.06 0.2 1.9 0.010 0.0011 0.03 0.03 0.2 0.3 0.2 0.02 0.0010 0.012 0.005 Inventive Steel 4 0.065 0.2 1.8 0.008 0.001 0.03 0.03 0.3 0.2 0.15 0.01 0.0005 0.014 0.005 Invention steel 5 0.07 0.1 1.9 0.012 0.0015 0.045 0.04 0.35 0.1 0 0.03 0.0011 0.013 0.005 Comparative River 1 0.1 0.25 1.5 0.011 0.0012 0.03 0.03 0.2 0.2 0.2 0.02 0.0007 0.01 0.005 Comparative River 2 0.06 0.3 1.8 0.011 0.001 0.03 0.02 0.1 0.4 0.1 0.02 0.0010 0.015 0.001 Comparative Steel 3 0.02 0.4 2 0.011 0.001 0.03 0.04 0.2 0.1 0.3 0.03 0.008 0.01 0.004 Invention steel 6 0.08 0.25 1.8 0.009 0.001 0.05 0.02 0.4 0.4 0 0.02 0.0010 0.015 0.005

In Comparative Steel 1, the content of carbon is higher than that of the present invention. In Comparative Steel 2, the content of nitrogen is lower than that of the present invention. In Comparative Steel 3, the content of carbon is controlled by the present invention Carbon content, and the content of titanium is higher than the content of titanium controlled by the present invention. On the contrary, invention steels 1 to 6 all satisfy the component system controlled by the present invention.

Specimen Number River classification Slab
heating
Temperature
(° C) Recrystallization station
Rolling
Reduction rate
(%) Non-recrystallized reverse rolling
Initiation temperature
(° C) Non-recrystallized reverse rolling
End
Temperature
(° C) Non-recrystallized reverse rolling
accumulate
Reduction rate
(%) Primary
Cooling
End
Temperature
(° C) Primary
Cooling
speed
(° C / s) Secondary
Cooling
End
Temperature
(° C) Secondary
Cooling
speed
(° C / s) Inventory 1 Inventive Steel 1 1140 11 900 815 70 673 5 317 20 Inventory 2 Invention river 2 1130 10 920 810 75 682 7 294 25 Inventory 3 Invention steel 3 1150 12 915 805 80 671 6 301 15 Honorable 4 Inventive Steel 4 1120 11 890 800 70 666 7 309 22 Inventory 5 Invention steel 5 1160 12 903 806 75 668 8 256 23 Inventory 6 Invention steel 3 1135 11 912 804 80 661 9 273 25 Honorable 7 Inventive Steel 4 1130 10 896 807 70 686 6 285 26 Comparative Example 1 Invention river 2 1140 5 920 803 75 672 7 279 18 Comparative Example 2 Invention steel 3 1150 12 920 850 50 661 8 311 25 Comparative Example 3 Invention river 2 1130 13 930 810 70 672 5 289 5 Comparative Example 4 Invention steel 3 1150 11 920 815 75 631 8 451 16 Comparative Example 5 Comparative River 1 1140 10 920 820 72 681 8 333 24 Comparative Example 6 Comparative River 2 1200 11 910 820 73 677 7 264 21 Comparative Example 7 Comparative Steel 3 1130 12 913 830 70 661 6 324 29 Comparative Example 8 Invention steel 6 1150 11 900 800 80 667 9 180 28 Comparative Example 9 Inventive Steel 4 1135 12 908 805 70 656 One 283 23

In Comparative Example 1, the recrystallization reverse average reduction rate was as low as 5%, and the road martensite was coarsened and the toughness was poor, whereby the impact toughness value and the DWTT value were measured to be low. In Comparative Example 2, the non-recrystallized cumulative rolling reduction was as low as 50%, and the toughness was lowered and the impact toughness value and the DWTT value were measured to be low. In Comparative Example 3, the secondary cooling rate was as low as 5 占 폚 / s, the ferrite fraction increased, the strength was lowered, the uniform elongation and the buckling strain were poor.

In Comparative Example 4, the secondary cooling termination temperature was as high as 451 ° C, and martensite was formed to a small extent on the road, resulting in poor uniform elongation and buckling strain. In Comparative Example 5, the content of carbon was as high as 1% by weight and the strength was improved, but the toughness was poor, and the impact toughness value, DWTT and weld heat affected portion toughness were measured to be low. In Comparative Example 6, the nitrogen content was as low as 0.001 wt%, the slab heating temperature was as high as 1200 DEG C, the TiN precipitates were formed to be small, the austenite grains were coarsened and the toughness was poor, Respectively.

In Comparative Example 7, the carbon content was as low as 0.02% by weight and the strength was lowered. In Comparative Example 8, the secondary cooling termination temperature was as low as 180 占 폚 and the strength and toughness were lowered. In Comparative Example 9, since the primary cooling rate was as low as 1 占 폚 / s, the amount of ferrite to be produced was increased, resulting in insufficient movable potential, and the buckling strain was poorly measured.

On the other hand, Inventive Example 1 to Inventive Example 7 demonstrate excellent strength, toughness and deformability of a steel pipe using steel sheets satisfying the conditions controlled by the present invention.

Claims (7)

(Si): 0.05 to 0.50%, manganese (Mn): 1.4 to 2.0%, aluminum (Al): 0.01 to 0.05%, titanium (Ti): 0.005 (N): 0.003-0.01%, calcium (Ca): 0.0005-0.004%, vanadium (V): 0.05%, nickel (Ni): 0.4% (Fe) and other unavoidable impurities, and the microstructure includes at least one of martensite (MA (M), martensite ) 3 to 10%, ferrite 5 to 20%, and the balance bainite. The steel sheet for a line pipe according to claim 1, wherein the steel sheet further comprises one or two of Cr, Cr and Mo in an amount of 0.1 to 0.5% by weight and molybdenum (Mo). The steel sheet for a line pipe according to claim 1 or 2, wherein the steel sheet has a grain size of martensite (MA) of 3 mu m or less. The steel sheet for a line pipe according to claim 1 or 2, wherein the steel sheet has a grain size of ferrite and bainite of 8 탆 or less. (Si): 0.05 to 0.50%, manganese (Mn): 1.4 to 2.0%, aluminum (Al): 0.01 to 0.05%, titanium (Ti): 0.005 (N): 0.003-0.01%, calcium (Ca): 0.0005-0.004%, vanadium (V): 0.05%, nickel (Ni): 0.4% The slab containing 0.5% or less of copper (Cu), 0.02% or less of phosphorus (P), 0.005% or less of sulfur (S), the balance iron (Fe) and other unavoidable impurities is heated to 1100 to 1180 캜 step; Rolling the slab at a temperature of 1000 to 1100 DEG C at a reduction ratio of 10% or more per pass; A non-recrystallization reverse rolling step of rolling the recrystallized back-rolled steel sheet at a temperature of 800 to 950 ° C to a cumulative rolling reduction of 70% or more; A first cooling step of cooling the unrecrystallized uniaxially rolled steel sheet to a temperature equal to or higher than the Ar3 transformation point at a cooling rate of 5 to 10 占 폚 / s to a temperature equal to or higher than the Ar1 transformation point; And And cooling the cooled steel sheet at a cooling rate of 10 to 30 占 폚 / s within a range of Ms-50 占 폚 to Ms-200 占 폚. 6. The steel sheet for a line pipe according to claim 5, wherein the steel sheet further comprises one or two of chromium (Cr): 0.1 to 0.5% and molybdenum (Mo): 0.3% Way. 6. The method of manufacturing a steel plate for a line pipe according to claim 5, wherein the manufacturing method is air-cooled between the recrystallization reverse rolling step and the non-recrystallization reverse rolling step without rolling.