KR20110044844A - Speedy Hair Coloring Composition For Protecting Skin Coloration - Google Patents

Abstract

PURPOSE: A speedy hair coloring composition for preventing staining on the skin is provided to reduce staining and quickly and ensure moisturizing and hair coating effects. CONSTITUTION: A speedy hair coloring composition for preventing staining on the skin contains 32.0-97.57 weight% of aqueous part containing metal complex and polyol; 0.1-3.0 weight% of takifier containing cellulose tackifier; 0.1-8.0 weight% of dye, 1.91-30.0 weight parts of oil phase containing high quality alcohol, wax of high melting point, ester oils, and natural oil; 0.1-6.0 weight% of silicon part containing silicon oil of cyclomethicone and dimethicone; 0.02-8.0 weight% of oxidation delay part containing citric acid, lactic acid, or maleic acid; and 0.2-13.0 weight% of oxidation promoting part containing urea.

Description

Speedy Hair Coloring Composition For Protecting Skin Coloration

The present invention relates to a quick dye composition for preventing skin dyes and a method for manufacturing the same, and more particularly, the quick dye composition for preventing skin dyes is 1 minute, which is a coating time of oxidation reaction of dye using citric acid, lactic acid or maleic acid for reaction rate control. Suppresses only about 2 minutes at to reduce the phenomenon of hair dye on the skin when applied, and elutes the protein that fills the hair using urea in neutral conditions under neutral conditions and injects hair dye into the empty spot quickly and surely. The hair dye and eluted protein relates to a fast hair dye composition for preventing skin pigmentation and a method for producing the same having excellent moisturizing effect by coating the surface of the hair.

Generally, hair dyes for dyeing hair are classified into temporary hair dyes, semi-permanent hair dyes, and permanent hair dyes according to the dyeing mechanism. Acidic hair dyes, which are temporary hair dyes and semi-permanent hair dyes, have a short duration and are drastically depleted. Therefore, most hair dyes in the market consist of permanent hair dyes using an oxidation polymerization reaction.

Permanent hair dyes are composed of one hair dye and two oxidants. The first hair dye includes a dye for coloring and an alkaline agent such as ammonia and monoethanolamine, which swell the hair and accelerate the decomposition of hydrogen peroxide to cause an oxidation reaction. It also contains a reducing agent to control the oxidation reaction of the dye, a chelating agent to block the antioxidant and metal ions. In addition, hair conditioners such as fatty alcohols, surfactants, cationic polymers, and fragrances are included. The oxidant, which is the second agent, contains an oxidant such as hydrogen peroxide to decompose the melanin of the hair to brighten the background color of the hair and to promote the oxidation reaction of the dye.

On the other hand, the oxidation type permanent hair dye has the advantage of excellent color persistence because the dye penetrates into the hair by the oxidation polymerization reaction. However, the alkaline protein and hydrogen peroxide used in permanent hair dyes damage hair proteins. In particular, when the alkali agent content is increased to express the color more brightly, the color becomes brighter but hair damage is also increased. In addition, if the ammonia content is increased, there is a problem that a lot of smell. In addition, there is a problem that the hair dye and hair irritation to the scalp by hair dye for 10 to 40 minutes is not fast when using the permanent hair dye.

In order to solve such a problem, a technique for promoting hair dye by combining 1 to 5% of arginine as a technique for fast hair dyeing (Korean Patent Registration No. 633,439) is disclosed. However, the technique of promoting the hair dye by combining the arginine 1 ~ 5% by using a mechanism to increase the pH of the hair to open the cuticle layer to penetrate the dye, in addition to arginine, MEA (monoethanolamine), TEA (Triethanolamine), KOH (Potassium hydroxide ), Using strong alkali such as NaOH (Sodium Hydroxide), has a limitation in inhibiting hair damage and odor removal.

Accordingly, the object of the present invention is to solve the problem of hair damage and stimulation to the scalp by a conventional slow hair dye using a fast hair dye within 1 to 5 minutes, and to prevent hair damage and odor caused by using strong alkali. The problem is solved by providing a neutral hair dye in weak alkalis without increasing pH using urea, and the problem of dyeing on the skin is applied by applying oxidation reaction of dye using citric acid, lactic acid or maleic acid for reaction rate control. Fast hair dye composition for preventing skin dyes by reducing only 2 minutes to minutes to reduce the phenomenon that the hair dye applied to the skin when applied to the skin to remove the hair dye at the time of application is complete And the purpose is to provide a method for producing the same.

In order to solve the above object, the present invention provides a quick hair dye composition for preventing skin inflammation,

(a) 32.0 to 97.57% by weight of an aqueous phase including a metal complex and a polyol;

(b) 0.1 to 3.0% by weight of a thickener comprising a cellulose thickener;

(c) 0.1 to 8.00% by weight of the dye portion;

(d) 1.91 to 30.0% by weight of the oil phase including higher alcohol, high melting wax, ester oil and natural oil;

(e) 0.1 to 6.0 wt% of a silicon portion including silicon oil of cyclomethicone and dimethicone;

(f) 0.02 to 8.0 weight percent of an oxidation retardation portion including any one of citric acid, lactic acid or maleic acid or a mixture of two or more thereof; And

(g) 0.2 to 13.0% by weight of the oxidation reaction promoting part comprising a urea; provides a rapid hair dye composition for preventing skin inflammation comprising a.

In addition, the present invention is a method for producing a fast hair dye composition for preventing skin inflammation,

In preparing a hair dye using an emulsifier, a method for producing a stable oil-in-water emulsion containing a stabilized dye and a mixture of citric acid and urea,

(a) 32.0 ~ 97.57% by weight of the aqueous phase is dissolved by heating to 50 ~ 90 ℃ and 0.1 to 3.0% by weight of the thickener consisting of a cellulose-based thickener was added to uniformly using a conventional emulsifier (Homo-mixer) Dispersing to form an aqueous phase in which the thickener is dispersed;

(b) adding 0.1 to 8.00% by weight of the dye to the aqueous phase in which the thickener is dispersed, and warming to 50 to 90 ° C. to dissolve with an emulsifier to form an aqueous phase in which the dye is dissolved;

 (c) warming and dissolving 1.91 to 30.0 wt% of the oil phase at 70 to 85 ° C. to form a uniform oil phase;

(d) adding the uniform oil phase to the aqueous phase in which the thickener is dispersed and emulsifying at a speed of 2,000 to 3,500 rpm with an emulsifier (Homo-mixer) to form a primary oil phase;

(e) A secondary oil image is prepared by incorporating 0.1 to 6.0% by weight of a silicon portion containing silicon oil of cyclomethicone and dimethicone into the primary oil phase at a speed of 2,000 to 3,500 rpm with an emulsifier (Homo-mixer). Forming a;

(f) cooling the secondary oil phase to 35 to 60 ° C. to form an emulsion cooling phase;

(g) adding 0.02 to 8.0% by weight of an oxidation-retardation part including water to 0.01 to 5.0% by weight of citric acid and the remainder of the emulsion cooling phase to form an oxidation-retarded phase by stirring;

(h) adding 0.2 to 13.0% by weight of an oxidation reaction accelerator including 0.1 to 10.0% by weight of urea and water to the oxidation reaction delay phase to form an active material input phase; And

(i) stabilizing the active material input phase by cooling to 20 ~ 40 ℃ to prepare a fast hair dye composition for preventing skin dyes provides a method for producing a fast hair dye composition for preventing skin dyes.

Rapid hair dye composition for preventing skin dyeing of the present invention and a method for producing the same, the dye is applied to the hair using a citric acid, lactic acid or maleic acid in order to obtain a good hair dye while the dyeing on the hair is less dyeing on the skin by controlling the reaction rate Only 1 to 2 minutes of time is suppressed to reduce the phenomenon that the dye applied to the skin when applied to the skin dyeing effect is excellent after the hair dye effect is remarkable. In addition, unlike conventional hair dyes that use the high pH to heat hair cuticles and dye the hair, the urea is used to elute the protein that fills the hair, and the hair dye is added to the vacant spots. Protein is coated on the surface of the hair to develop a hair dye with excellent moisturizing effect, and accordingly, it is possible to develop a hair dye that has significantly reduced irritation factors due to high pH. To provide.

1 is a view showing a reduction reaction as a reverse reaction to control the oxidation reaction rate of the skin dye prevention rapid hair dye composition according to the present invention.
Figure 2 is a view showing the chemical structural formula of the urea that is the main component to enhance the penetration effect of the hair dye preventive rapid hair dye composition for the hair according to the present invention.
Figure 3 is a photograph comparing the dyeing effect on the skin of a commercial hair dye and a rapid hair dye composition for preventing skin dye according to the present invention.
Figure 4 is a photograph showing the hair dye effect tested in human hair using the hair dye prepared in the compositions of Examples and Comparative Examples according to the present invention.

The present invention is a rapid hair dye composition for preventing skin inflammation,

(a) 32.0 to 97.57% by weight of an aqueous phase including a metal complex and a polyol;

(b) 0.1 to 3.0% by weight of a thickener comprising a cellulose thickener;

(c) 0.1 to 8.00% by weight of the dye portion;

(d) 1.91 to 30.0% by weight of the oil phase including higher alcohol, high melting wax, ester oil and natural oil;

(e) 0.1 to 6.0 wt% of a silicon portion containing silicon oil of cyclomethicone and dimethicone;

(f) 0.02 to 8.0 weight percent of an oxidation retardation portion including any one of citric acid, lactic acid or maleic acid or a mixture of two or more thereof; And

(g) 0.2 to 13.0% by weight of the oxidation reaction accelerator comprising the element;

The quick hair dye composition for preventing skin dyeing inhibits the oxidation reaction of the dye using citric acid, lactic acid or maleic acid for reaction rate control only for 1 to 2 minutes, which is a coating time, thereby reducing the phenomenon that the hair dye stained on the skin is applied to the skin. In weak alkaline, urea is used to elute the protein that fills the hair, and the hair dye is added to the vacant spots to quickly and reliably dye. The eluted protein coats the surface of the hair and has excellent moisturizing effect.

The present invention uses a fast hair dye within 1 to 5 minutes, so as not to cause hair damage and irritation to the scalp, and using a factor of hair damage and odor problems in the neutral alkali without weakening the pH in the neutral area By providing a temporary reduction reaction to reduce the oxidation rate involved in the oxidation reaction of phenylenediamine, and suppressing the initial reaction rate instantaneously without affecting the overall reaction. It is a quick hair dye composition for preventing skin dyes that does not dye on the skin during the time applied to the hair, and removes the dye on the skin at the time when the application to the hair is completed.

In addition, the present invention is a fast dyeing agent for preventing skin dyeing that is dyed in the skin at a fast time due to less dyeing on the skin, and a dyeing delay in a trade-off using a structural difference between the hair and the skin. By developing a new hair dye that satisfies both goals of improving the dyeing speed, it delays the dyeing on the skin and has an allergic reaction to the hair. By increasing the accessibility of the hair, it contributes to the expansion of the market, while the hair is designed for rapid hair dyeing, which enables hair dyeing in the wet zone, which is a short amount of time for brushing, thereby increasing the inducement effect of consumers who are concerned about hair dyeing. About development of hair dye of new composition to contribute to expansion The.

First of all, a method of reducing dyeing on the skin in the permanent hair dye which realizes dyeing by oxidation of phenylenediamines. The second is to terminate the dyeing speed in the hair as soon as possible. This requires a technical method to reduce the initial oxidation reaction as much as possible and to increase the oxidation reaction as much as possible after removing the hair dye applied to the skin.

In order to complete this invention, the reduction of the skin dye by the oxidation reaction of the first phenylenediamine is involved in the oxidation reaction of the phenylene diamine to reduce the oxidation rate. By suppressing the initial reaction rate instantaneously without affecting the overall reaction, it does not become dye on the skin during the time applied to the hair, and when the hair dye is removed from the skin when the application is completed on the hair, it is dyed on the skin. It is based on principles that do not work. Reduction reaction that inhibited only the initial time and inhibited the oxidation reaction by administering the minimum reduction reaction material necessary for suppressing the initial reaction within about 1 to 5 minutes, which is the time when the average person applies hair dye to the hair. As soon as the role of the substance is fulfilled, the original oxidation reaction explodes, and the hair can be dyed in the shortest time. The oxidation reaction of fiphenylenediamine is as follows.

Scheme 1

The presence or absence of Lewis acid has no change in hair color and fading, but the oxidation rate is affected. The reason is that Lewis acid attacks the unshared electron pair of NH _{2 and} becomes (+) NH ₃ to become an ion receiving electron. Therefore, the density of the benzene ring is lowered and the oxidation reaction is slowed down.

The hair dye of the present invention, which does not increase the hair pH by increasing the hair pH and speeds up the oxidation rate, focuses on the reduction reaction, which is a reverse reaction of oxidation, and uses citric acid, lactic acid, and maleic acid as Lewis acids to limit the oxidation reaction rate. By delaying the reaction, the reaction can be delayed only for the time required for application to prevent dyeing on the skin.

The second is to promote the hair dyeing rate. The oxidation reaction of the oxidized dye, which has been delayed by the reduction reaction, is triggered at the same time as the reduction reaction is terminated, so as to infiltrate into the hair in a short time to terminate the reaction. In the present invention, hair using monoalcohols such as monoethanolamine (MEA), triethanolamine (TEA), potassium hydroxide (KOH), sodium hydroxide (Sodium Hydroxide; NaOH), etc. It is possible to suppress hair damage caused by strong alkalis by enabling fast hair dyeing of 1 to 5 minutes in the neutral region without weakening the pH without increasing the pH by using urea without the strong alkaline substance. By giving moisturizing and conditioning at the same time when dyeing, you can produce soft hair without using a separate conditioner after use.

At this time, urea is a substance that helps to elute the protein that fills the hair tightly and consequently gives a conditioning effect on the surface of the hair, so that dye can quickly penetrate into the space escaped by the urea and the surface can be conditioned with moisturizing ingredients. Done. Urea is also produced in vivo by the ornithine cycle, in which arginine produces urea and ornithine in the presence of citrulline and arginine. When the right amount of urea is added, urea helps to maintain the chemical equilibrium of arginine to keep the pH essential for hair dyes below the limit. In addition to the direct penetration of the dye, it has the effect of inhibiting hair damage and preventing odors in hair dyeing.

Here, the fast hair dye composition for preventing skin dyeing has excellent effects on hair dyeing without hair dyeing. Skin and hair has a structural difference, as shown in the following picture, it is possible to obtain a quick hair dye composition for preventing the skin dyeing does not dye on the skin through a fixed time adjustment.

[Skin structure]

[Cuticle image]

[Hair structure]

The skin has a brick and mortar structure, making it difficult to penetrate hair dye in a relatively short time. On the other hand, the cuticle layer of hair has an open interlayer structure, so that hair dye penetrates relatively easily. In light of these structural differences, the present invention applies the reduction reaction shown in FIG. 1, which is an oxidation inhibitory reaction for a short time, which is difficult for dye to penetrate the skin, to the hair dyeing process, and the hair dye for the hair for a minimum time when the skin prevents dye penetration. Wiping the hair dye on the skin around the hair after applying it will solve hair dye deposition on the skin, which is a concern for the consumer, while developing a hair dye that can be dyed quickly.

At this time, while applying the quick hair dye composition for preventing hair dye on the hair, NH ₂ ions are extracted using NH ₃ ions using citric acid, lactic acid, and maleic acid so that the hair dye on the skin does not cause dyeing. By ionizing to lower the electron density of the benzene ring, it delays the hair dye effect for a short time, and the urea component helps to elute the protein that fills the hair, while obtaining a good hair dye effect even at low pH in the neutral zone. Can increase.

That is, the quick hair dye composition for preventing skin dyeing is to be rapidly dyed to hair while controlling the reaction rate, while the hair dye is less, and the quick hair dye composition for preventing skin dyeing is (a) an aqueous phase including a metal complex compound and a polyol. 97.57 weight percent; (b) 0.1 to 3.0% by weight of a thickener comprising a cellulose thickener; (c) 0.1 to 8.00% by weight of the dye portion; (d) 1.91 to 30.0% by weight of the oil phase including higher alcohol, high melting wax, ester oil and natural oil; (e) 0.1 to 6.0% by weight of a silicon portion containing silicon oil of cyclomethicone and dimethicone; (f) 0.02 to 8.0 weight percent of an oxidation retardation portion including any one of citric acid, lactic acid or maleic acid or a mixture of two or more thereof; And (g) 0.2 to 13.0% by weight of the urea portion comprising the element.

Here, the water phase part contains 0.005 to 0.5% by weight of the metal complex compound, 0.1 to 20.0% by weight of the polyol, 0.01 to 0.5% by weight of antioxidant, 0.1 to 10.0% by weight of a cationic surfactant having at least 18 carbon atoms, and the remaining amount of water. do.

At this time, the metal complex is EDTA-2Na, EDTA-3Na or EDTA-4Na.

The metal complex compound of the aqueous phase is used in 0.005 to 0.5% by weight for the purpose of stabilizing citric acid and dyes, these are commonly used in the art, EDTA-2Na (EDTA-2Na), EDDI-3Na (EDTA-3Na) , EDTA-4Na (EDTA-4Na) can be used. If the content is less than 0.005% by weight, the above-mentioned effects are insignificant, and if the content is more than 0.5% by weight, there is a problem of impairing the stability of the formulation due to excessive use.

In addition, the polyol of the water phase portion is used 0.1 to 20.0% by weight for the purpose of softening the feel of the hair dye of the present invention, and to prevent freezing of the water phase in the continuous phase at low temperature.

The cationic surfactant having at least 18 carbon atoms in the water phase part uses 0.1 to 10.0% by weight in order to stably emulsify a large number of benzene rings and strong ionic dyes and a large amount of higher alcohol used in the oil phase part, and 0.1% by weight. If less than used, it is difficult to obtain the above-mentioned emulsification stability, and when used in excess of 10.0% by weight, there is a problem of losing the value as a commodity due to the rapid increase in hardness and difficulty of use.

In addition, the cellulosic thickener may be any one or a mixture of two or more of hydroxypropyl cellulose, hydroxyethyl cellulose or hydroxypropylmethyl cellulose.

Cellulose thickeners of the thickeners are generally stable to ions and have a small viscosity increase over time compared to cationic polymers and carbomers, which are generally used for hair dyes, and thus greatly contribute to the formation, maintenance and maintenance of physical properties over time. 0.1 to 3.0% by weight is used for the purpose, these cellulosic thickeners are any one of hydroxy propyl cellulose, hydroxyethyl cellulose or hydroxypropyl methyl cellulose or a mixture of two or more thereof. When the content of the cellulose thickener is used in less than 0.1% by weight, its thickening effect is insignificant, and when it is used in excess of 3.0% by weight, there is a problem in its dispersibility, and the viscosity is too high due to excessive hydration (Hydration) so as not to be emulsified. There is no problem.

In addition, the dye portion as a dye precursor o-aminophenol, p-aminophenol, toluene-2,5-diamine hydrochloride, p-phenylenediamine hydrochloride, toluene-2,5-diamine, p-phenylenediamine, sulfuric acid p Methylaminophenol, sulfuric acid o-aminophenol, p-aminophenol sulfate, toluene-2,5-diamine or p-phenylenediamine sulfate, or mixtures of two or more thereof, and 2-methyl-5- Hydroxyethyl aminophenol, p-amino-o-cresol, m-aminophenol, hydrochloric acid 2,4-diaminophenoxyethanol, hydrochloric acid m-phenylenediamine, m-phenylenediamine, N-methyl-p -Phenylenediamine, p-amino-o-cresol sulfate, 4-ethoxy-m-phenylenediamine sulfate, m-phenylenediamine sulfate, α-naphthol, resorcinol or 2-methylsorborcinol Any one or a mixture of two or more thereof.

The precursor and the coupler of the dye of the dye portion is usually used in the hair dye, and the content and blending ratio can be adjusted according to the color and content.

The oil phase portion is 0.1 to 8.0% by weight of the higher alcohol, 0.1 to 3.0% by weight of the high melting point wax, 0.1 to 2.0% by weight of the self-emulsifying surfactant, 0.5 to 2.0% by weight of the hydrophilic surfactant, 0.1 to 7.0% by weight of the ester oil %, 1.0 to 7.0% by weight of the natural oil, the remaining amount comprises an oil-soluble antioxidant.

Here, the higher alcohol (higher alcohol) used in the oil phase is 0.1 to 8.0% by weight in order to emulsify the oil stably by improving the density of the particle interface mainly composed of emulsifiers with excellent regularity of chemical structure When using less than 0.1% by weight, it is difficult to obtain the effect of maintaining the above-mentioned stability, and when used in excess of 8.0% by weight, the feeling of use is too stiff and the problem of deterioration of stability due to excessive interfacial orientation occurs. Preference is given to using within the content range.

At this time, the higher alcohol is any one of cetanol, cetostearyl alcohol, stearyl alcohol, behenyl alcohol or batyl alcohol or a mixture of two or more thereof.

In addition, the high melting point wax may include any one or a mixture of two or more of microcrystalline wax, sericin wax, paraffin wax, or polyethylene.

High melting point wax is used 0.1 ~ 3.0% by weight to improve the stability of the hair dye product of the present invention, when less than 0.1% by weight it is difficult to improve the high temperature stability, when using 3.0% by weight emulsified and cooled There is a problem that the product hardens too hard during the curing.

In addition, the self-emulsifying surfactant is cetearylalcohol (Cetearylalcohol) / cetearylglucoside (Cetearylglucoside), cetearyl alcohol / cetheares-20 (Ceteareth-20), cetearyl alcohol / cetearece-23 or Glyceryl stearate / polyoxyethylene (100) stearate, or a mixture of two or more thereof.

The self-emulsifying surfactant formulated for stable emulsification of water phase components and oil components such as dyes has an oil-in-water emulsion in which a hydrophilic lipophilic balance (HLB) is stable at about 9.0 to 12.0. It is easily formed, using 0.1 to 2.0% by weight. If it is less than 0.1% by weight it does not form an oil-in-water emulsion, and when used in excess of 2.0% by weight rather hydrophilic lipophilic balance has a disadvantage that the stability is worse.

In addition, the hydrophilic surfactant is polyoxyethylene sorbitan stearate, polyoxyethylene sorbitan oleate, polyoxyethylene sorbitan laurate, ceteares-20, ceteares-23 or steares-21 (Steareth-21) Hydrophilic nonionic surfactants composed of any one or two or more of these compounds of polyoxyethylene and a fatty acid and a higher alcohol.

The hydrophilic surfactant is used in an oil-in-water emulsion.

The hydrophilic lipophilic balance (HLB) is used in a hydrophilic surfactant 0.5 ~ 2.0% by weight of 12.0 or more in order to compensate for the hydrogen bonding power of the relatively weak water because the pH of the quick dye composition for preventing skin dyes is kept weakly alkaline, 0.5 If it is less than the weight%, the effect of strengthening the hydrogen bonding force is insignificant to prevent the phenomenon of water desorption from the product. If it exceeds 2.0 wt%, the hydrogen bonding power is strengthened, but the hydrophilic lipophilic balance (HLB) of the oil-in-water emulsion is There is a problem that is too high to damage the stability.

In addition, the ester-based oil may be any one of alkylbenzoate, phenyltrimethicone or phenyldimethicone or a mixture of two or more thereof.

The ester-based oil is used 0.1 to 7.0% by weight, and maintains stability by increasing the compatibility with natural oils and higher fatty alcohols and silicone oils.

The natural oil has a soft and good feeling like basic cosmetics, and is known as a camellia oil, sesame oil, olive oil, macadamia nut, meadow palm seed oil, or apricot seed oil, which are known to have excellent hair protection effect to reduce hair damage due to hair dye. ~ 7.0% by weight is used.

In addition, the silicone oil dimethicone, dimethiconol, cyclomethicone can be used for the purpose of controlling the feeling.

The ester oil, the natural oil and the silicone oil can be used in the content when the developer develops a product from a low viscosity emulsion to a high viscosity cream.

In addition, the rapid hair dye composition for preventing skin dyeing has a delayed oxidation portion of 0.01 to 8.0% by weight of any one or a mixture of two or more of citric acid, lactic acid or maleic acid.

Among them, citric acid as a retardant of the oxidation reaction of the skin dye prevention quick hair dye composition is used 0.01 to 5.0% by weight based on the total weight of the quick hair dye composition, which is less than 0.01% by weight substantially delayed reaction If it does not play a role as 5.0% by weight or more, the reduction reaction dominates the oxidation reaction, the reaction rate of the hair dye is too late, the hair dye does not go well even if the time period of the target time of the present invention 1 ~ 5 minutes There is. The component that can be used as a retardant used at this time can also be used lactic acid, maleic acid and the like. Citric acid has been proven to be safe for a long time in various formulations in cosmetics, and the high temperature stability of the formulation is good.

In addition, the quick hair dye composition for preventing skin dyeing has an oxidation reaction accelerator 0.2 ~ 13.0% by weight including urea.

The element represented by the chemical structure of Figure 2 serves to elute out the protein filling the hair to promote the hair dye effect in the hair to speed up the dyeing. When the urea is used in an amount of 0.1 to 10.0% by weight, and less than 0.1% by weight, the effect of eluting the above-mentioned proteins is insignificant, and thus, a desirable hair dye-promoting effect cannot be obtained. And due to the oxidation of the mother surface by the protein component, there is a problem in that the dyeing effect is inferior because the dyeing in the inside of the hair is not made.

In addition, the method for producing a fast hair dye composition for preventing skin inflammation of the present invention,

In preparing a hair dye using an emulsifier, a method for producing a stable oil-in-water emulsion containing a stabilized dye and a mixture of citric acid and urea,

(a) 32.0 ~ 97.57% by weight of the aqueous phase is dissolved by heating to 50 ~ 90 ℃ and 0.1 to 3.0% by weight of the thickener consisting of a cellulose-based thickener was added to uniformly using a conventional emulsifier (Homo-mixer) Dispersing to form an aqueous phase in which the thickener is dispersed;

(b) adding 0.1 to 8.00% by weight of the dye to the aqueous phase in which the thickener is dispersed, and warming to 50 to 90 ° C. to dissolve with an emulsifier to form an aqueous phase in which the dye is dissolved;

 (c) warming and dissolving 1.91 to 30.0 wt% of the oil phase at 70 to 85 ° C. to form a uniform oil phase;

(d) adding the uniform oil phase to the aqueous phase in which the thickener is dispersed and emulsifying at a speed of 2,000 to 3,500 rpm with an emulsifier (Homo-mixer) to form a primary oil phase;

(e) A secondary oil image is prepared by incorporating 0.1 to 6.0% by weight of a silicon portion containing silicon oil of cyclomethicone and dimethicone into the primary oil phase at a speed of 2,000 to 3,500 rpm with an emulsifier (Homo-mixer). Forming a;

(f) cooling the secondary oil phase to 35 to 60 ° C. to form an emulsion cooling phase;

(g) adding 0.01-8.0% by weight of an oxidation-retardation unit including water to 0.01-5.0% by weight of citric acid and the remaining amount in the emulsion cooling phase to form an oxidation-retarded phase by stirring;

(h) adding 0.2 to 13.0% by weight of an oxidation reaction accelerator including 0.1 to 10.0% by weight of urea and water to the oxidation reaction delay phase to form an active material input phase; And

(i) cooling the active material input phase to 20 to 40 ° C. to stabilize to prepare a fast hair dye composition for preventing skin dyes.

Here, the input temperature of the urea and citric acid is an important process for making a stable hair dye product must be kept at 55 ~ 60 ℃ when added and mixed with stirring only for 5 to 40 minutes without stirring the emulsifier (Homo-mixer) . If the input and stirring temperature is less than 55 ° C deterioration of the stability of the formulation due to the desorption of high alcohols and waxes of high content, in the case of 60 ° C or more there is a problem that the decomposition of urea and citric acid does not occur to obtain the desired effect. The emulsifier (Homo-mixer) is a strong shear force when stirring when the urea and citric acid is added when inducing the collapse and precipitation of the higher alcohol and wax that is closely packed may cause the formulation collapse.

In addition, the water phase part contains water in the amount of 0.005 to 0.5% by weight of the metal complex, 0.1 to 20.0% by weight of polyol, 0.01 to 0.5% by weight of antioxidant, 0.1 to 10.0% by weight of the cationic surfactant having at least 18 carbon atoms.

Here, the description about the said water phase part uses the preceding description.

In addition, the metal complex compound is EDTA-2Na, EDTA-3Na or EDTA-4Na.

Here, the description about the said metal complex compound uses the previous description.

In addition, the cellulosic thickener may be any one or a mixture of two or more of hydroxypropyl cellulose, hydroxyethyl cellulose or hydroxypropylmethyl cellulose.

Here, the description about the cellulose-based thickener uses the above description.

In addition, the dye portion as a dye precursor o-aminophenol, p-aminophenol, toluene-2,5-diamine hydrochloride, p-phenylenediamine hydrochloride, toluene-2,5-diamine, p-phenylenediamine, sulfuric acid p Methylaminophenol, sulfuric acid o-aminophenol, p-aminophenol sulfate, toluene-2,5-diamine sulfate, p-phenylenediamine sulfate, or mixtures of two or more thereof, and 2-methyl-5- as a coupler. Hydroxyethyl aminophenol, p-amino-o-cresol, m-aminophenol, hydrochloric acid 2,4-diaminophenoxyethanol, hydrochloric acid m-phenylenediamine, m-phenylenediamine, N-methyl-p -Phenylenediamine, p-amino-o-cresol sulfate, 4-ethoxy-m-phenylenediamine sulfate, m-phenylenediamine sulfate, α-naphthol, resorcinol, or 2-methylsorbory Any one or a mixture of two or more of them.

Here, the base material of the said dye part uses the preceding base material.

In addition, the oil phase is 0.1 to 8.0% by weight of the higher alcohol, 0.1 to 3.0% by weight of the high melting point wax, 0.1 to 2.0% by weight of the self-emulsifying surfactant, 0.5 to 2.0% by weight of the hydrophilic surfactant, 0.1 to the ester oil 7.0% by weight, 1.0 to 7.0% by weight of the natural oil, the remaining amount comprises an oil-soluble antioxidant.

Here, the description about the oil phase part uses the above description.

In addition, the higher alcohol may be any one of cetanol, cetostearyl alcohol, stearyl alcohol, behenyl alcohol or batyl alcohol or a mixture of two or more thereof.

Here, the description of the higher alcohol uses the above description.

In addition, the high melting point wax may include any one or a mixture of two or more of microcrystalline wax, cerisin wax, paraffin wax, or polyethylene.

Here, the base material for the high melting point wax uses the previous base material.

In addition, the self-emulsifying surfactant is cetearylalcohol (Cetearylalcohol) / cetearylglucoside (Cetearylglucoside), cetearyl alcohol / cetheares-20 (Ceteareth-20), cetearyl alcohol / cetearece-23 or Glyceryl stearate / polyoxyethylene (100) stearate, or a mixture of two or more thereof.

Here, the description about the said self-emulsifying surfactant uses the previous description.

In addition, the hydrophilic surfactant is polyoxyethylene sorbitan stearate, polyoxyethylene sorbitan oleate, polyoxyethylene sorbitan laurate, ceteares-20, ceteares-23 or steares-21 (Steareth-21) Hydrophilic nonionic surfactants composed of any one or two or more of these compounds of polyoxyethylene and a fatty acid and a higher alcohol.

Here, the description about the said hydrophilic surfactant uses the previous description.

In addition, the ester-based oil may be any one of alkylbenzoate, phenyltrimethicone or phenyldimethicone or a mixture of two or more thereof.

Here, the description of the ester-based oil is used for the above description.

In addition, the description about the said oxidation-delay part containing citric acid and the oxidation reaction promotion part containing urea uses the preceding description.

As described above, the present invention controls the oxidation reaction time of the fast hair dye composition for preventing hair dye by reducing the hair dye applied to the skin in the process of applying the hair to citric acid, lactic acid or maleic acid, and then immediately after applying the hair dye to the hair. It is formulated with urea that prevents dyeing on the inner skin and enables hair dyeing in a short time by eluting protein inside the hair and infiltrating the hair dye in place. Temperature and stirring conditions when mixing citric acid, lactic acid or maleic acid and urea To limit the dyeing to the skin that consumers are most reluctant to purchase hair dye products and to prevent hair dye products that can obtain products for hair dyes that solve technically conflicting problems that solve the fast hair dyes, which is a recent consumer demand. A hair dye composition and a method for producing the same.

Hereinafter, the present invention will be described in detail by way of examples.

However, the following examples are merely to illustrate the invention, but the content of the present invention is not limited by the following examples.

Example  To the skin Dyeing  Less hair dyeing is faster Hair dye  Preparation of the composition

Oxidant Manufacturing example

Before the examples are detailed, the preparation examples of the oxidizing agent, which is a second agent containing hydrogen peroxide, used in admixture with the hair dye invented by the present invention are shown in Table 1 below. The oxidizers in Table 1 below are generally prepared with conventional compositions and methods of preparation prepared to stabilize hydrogen peroxide.

division Ingredient (% by weight) Award water 91.45 EDTA-2Na 0.1 Phosphoric Acid 0.05 Dibasic Sodium Phosphate 0.1 Incremental Eritso Big Acid 0.1 Sodium cetyl sulfate 0.2 The upper part Cetearyl alcohol 2.0 Ceteares-20 1.5 Dimethicone 1.5 Active substance part Hydrogen peroxide 3.0
1) EDTA-2Na: Junghan Pharm, Korea
2) Phosphoric Acid, Dibasic Sodium Phosphate, Eryso Big Acid: Samjeon Chemical, Korea
3) Sodium Cetyl Sulfate: Cogness Knows, Germany
4) Seteares-20: Cognis, Germany
5) Dimethicone: DC Silicone 200-100cs (Dowcorning, USA)
6) Hydrogen Peroxide: Samjeon Chemical, Korea

Example  1 to 4 and Comparative example  1 to 12

Less dye to the skin according to the present invention with a composition as shown in Table 2, the hair dye was prepared fast hair dye composition, the preparation method is as follows.

The temperature shown in Table 2 to the temperature control and stirring in the vacuum emulsion tank capable of stirring and warming the water phase to 40 ℃, and gradually added to the thickener to 10 minutes at a speed of 2,500rpm conventional emulsifier, 80 ℃ After heating, the dye portion was added and dissolved for 10 minutes, and then the oil phase was heated and dissolved in an oil phase dissolving tank capable of temperature control and stirring. The oil phase was gradually added to the water phase and emulsified with an emulsifier at 3,000 rpm to form an oil-in-water emulsion. Make The citric acid and urea in each of the water to the content shown in Table 2 and Table 3 are dissolved by stirring to prepare a citric acid portion, which is an oxidation reaction delaying portion, and an urea portion, which is an oxidation reaction promoting portion. The emulsified emulsion was prepared by cooling to 60 ° C., prepared by adding citric acid and urea, followed by stirring for 10 minutes to stabilize, and cooling it to 35 ° C. again to obtain a hair dye having a fast effect.

Using the obtained hair dye, the hair dye effect of each time zone was measured and compared using the oxidizing agent which is the second agent shown in Table 1 above.

division Ingredients (parts by weight) Example 1 Example 2 Example 3 Example 4 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Award water 61.78 50.18 49.78 37.38 55.18 47.18 52.33 46.08 EDTA-2Na 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 glycerin 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 Sodium sulfide 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Eritso Big Acid 0.2 0.2 0.2 0.2 _ _ 0.2 _ Stearalkonium chloride 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 Incremental Hydroxyethyl Cellulose 1.0
1.0
1.0
1.0
1.0
1.0
1.0 1.0 Dye part Paraphenylenediamine 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 m-aminophenol 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 m-phenylenediamine 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 Resorcinol 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 The upper part Cetyl alcohol 4.0 4.0 2.0 4.0 4.0 4.0 4.0 4.0 Microcrystalline Wax 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 Glyceryl
Stearate 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 Polyoxyethylene sorbitan stearate 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 Alkylbenzoate 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 Natural oil 5.0 2.5 2.5 2.0 2.0 2.0 2.0 2.0 Tocopherol Acetate 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Silicone part Dimethicone 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 Cyclomethicone 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 Citric acid Purified water 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 Citric acid 0.1 2.0 0.5 0.5 _ _ _ 0.5 Active substance part Purified water 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 Element 2.0 2.0 0.1 5.0 2.0 2.0 2.0 2.0
1) EDTA-2Na: Junghan Pharm, Korea
2) Glycerin: USA, P & G
3) Sodium sulfide, erythorbic acid: Samjeon Chemical, Korea
4) steralconium chloride: Clariant, Germany
5) Cetyl alcohol: Lorol C-16, Germany, Cognis
6) Microcrystalline Wax: Multi-wax 445, United States, Witco
7) Glyceryl Stearate: Kwang Il, Korea
8) Polyoxyethylene sorbitan stearate: TWEEN 60 (United States, ICI Corporation), RHEODOL TWS-120 (Japan, Kao Corporation), Crillet 3 (Germany, Croda Corporation)
10) Dimethicone: Silicone KF96-100cs (Japan, Shin-Etsu Co., Ltd.), DC Silicone 200-100cs (United States, Dow Corning Co., Ltd.)
11) Tocopherol acetate: Vitamin E-acetate, Germany, Roche
12) Citric acid: ZUNGBANZULAURE, Austria
13) Element: UREA, Korea, Deoksan Pharmaceutical Industry

division Ingredients (parts by weight) Comparative Example 5 Comparative Example 6 Comparative Example 7 Comparative Example 8 Comparative Example 9 Comparative example
10 Comparative example
11 Comparative example
12 Award water  61.78 50.18 49.78 37.38 55.18  47.18  52.33  46.08 EDTA-2Na 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 glycerin 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 Sodium sulfide 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Eritso Big Acid 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Stearyltrimonium chloride 1.0 5.0 _ _ 4.0 4.0 4.0 4.0 Cetyltrimonium chloride _ _ 1.0 5.0 _ _ _ _ Incremental Hydroxyethyl Cellulose 0.1
1.0
1.0
1.0
1.0
1.0 1.0 1.0 Dye part Paraphenylenediamine 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 m-aminophenol 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 m-phenylenediamine 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 Resorcinol 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 The upper part Cetyl alcohol 4.0 4.0 2.0 4.0 4.0 4.0 4.0 4.0 Microcrystalline Wax 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 Glyceryl
Stearate 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 Polyoxyethylene sorbitan stearate 1.5 1.5 1.5 1.5 1.5 0.05 10.0 1.5 Alkylbenzoate 4.0 4.0 4.0 4.0 _ 4.0 4.0 4.0 Natural oil 5.0 2.5 2.5 2.0 2.0 2.0 2.0 2.0 Tocopherol Acetate 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Silicone part Dimethicone 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 Cyclomethicone 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 Citric acid Purified water 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 Citric acid 0.01 2.0 0.5 0.5 0.5 0.5 0.5 0.5 Active substance part Purified water 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 Element 2.0 2.0 0.1 5.0 2.0 2.0 2.0 2.0 Stability
High temperature stability Good Bad Good Bad Bad Water Tally Bad Good Low temperature stability Good Bad Good Good Good Bad Good Good
1) EDTA-2Na: Junghan Pharm, Korea
2) Glycerin: USA, P & G
3) Sodium sulfide, erythorbic acid: Samjeon Chemical, Korea
4) steralconium chloride: Clariant, Germany
5) Cetyl alcohol: Lorol C-16, Germany, Cognis
6) Microcrystalline Wax: Multi-wax 445, United States, Witco
7) Glyceryl Stearate: Kwang Il, Korea
8) Polyoxyethylene sorbitan stearate: TWEEN 60 (United States, ICI Corporation), RHEODOL TWS-120 (Japan, Kao Corporation), Crillet 3 (Germany, Croda Corporation)
10) Dimethicone: Silicone KF96-100cs (Japan, Shin-Etsu Co., Ltd.), DC Silicone 200-100cs (United States, Dow Corning Co., Ltd.)
11) Tocopherol acetate: Vitamin E-acetate, Germany, Roche
12) Citric acid: ZUNGBANZULAURE, Austria
13) Element: UREA, Korea, Deoksan Pharmaceutical Industry

Experimental Example  1 of skin Color  And to the hair Dynamism  Measure

1-1 to the skin Color  Measure

Example 1 and Comparative Examples were mixed with a second oxidizing agent and 2g each, and then applied to the upper arm, washed with running water after 1 minute, and dyeing power was visually compared as shown in FIG.

1-2 of hair Dynamism  Measure

Example 1 was mixed with a second oxidizer and 2g, and then applied to a test Swatch (2.5g, 10cm) (bleached hair (human hair), 50% sagittal hair (human hair)) and left at 25 ° C. for 1 to 3 minutes, then lukewarm. Washed with water and dried to compare the hair dye to the hair as shown in FIG.

Experimental Example  2 Physical and Stability Characteristics

In Examples 1 to 4 and Comparative Examples 1 to 4 there is no significant difference in physical properties and stability, and in order to determine the formulation stability of the obtained hair dye compositions of Comparative Examples 5 to 12 at 50 ° C. for 1 month and at low temperatures. 5 ℃ 1 month was checked to display the results at the bottom of Table 3. In Comparative Example 5, the emulsion stability is good, but the viscosity is low, whereas Comparative Example 6 is a product having a high viscosity cream. On the other hand, in the case of Comparative Examples 7 and 8, even if the content is high, the stability over time is poor, which was found to be stable over time by reducing the activity of the particle interface to a certain amount of carbon number (18) or more. As in the case of Comparative Example 9 and Comparative Example 12, the alkyl benzoate determines the presence or absence of oil detachment at high temperatures depending on the inclusion. This increases the compatibility of silicone and general oils due to the benzene ring of alkyl benzoate, thereby preventing oil desorption at high temperatures. In Comparative Example 10, when the amount of the hydrophilic surfactant is small, the hydrophilicity at high temperature is insufficient, so that the desorption phenomenon of water is promoted. In the case of Comparative Example 11, in which the content is excessive, the hydrophilicity is excessive and the hardness decrease at low temperature is outstanding.

Experimental Example  3 hair dye experiment

Although dyeing using hair dyes obtained from the compositions of Examples 1 to 4 showed a relatively good anti-dye effect on skin or dyeing ability to hair, the first anti-dye effect on skin was found in Example 2> Example 3 = Example 4> In the order of Example 1, it can be seen that when the amount of citric acid is contained in a predetermined amount or less, the anti-dyeing effect is weak. However, since the most important thing is the purpose of preventing dyeing only for the time necessary as the second hair dye effect, it was found that the most suitable thing was actually Example 3 or Example 4. On the other hand, the dyeing power was found in the order of Example 4> Example 1> Example 2> Example 3 in that the urea was effective in improving the dyeing speed upon input. However, since the difference between the effects of 1 and 2 in the implementation is not large, it can be seen that the actual effect does not increase even if the content of the urea is excessively large.

The foregoing description is merely illustrative of the technical idea of the present invention, and various changes and modifications may be made by those skilled in the art without departing from the essential characteristics of the present invention. Therefore, the embodiments disclosed in the present invention are not intended to limit the technical idea of the present invention but to describe the present invention, and the scope of the technical idea of the present invention is not limited by these embodiments. The protection scope of the present invention should be interpreted by the following claims, and all technical ideas within the equivalent scope should be interpreted as being included in the scope of the present invention.

Claims (11)

(a) 32.0 to 97.57% by weight of an aqueous phase including a metal complex and a polyol;
(b) 0.1 to 3.0% by weight of a thickener comprising a cellulose thickener;
(c) 0.1 to 8.00% by weight of the dye portion;
(d) 1.91 to 30.0% by weight of the oil phase including higher alcohol, high melting wax, ester oil and natural oil;
(e) 0.1 to 6.0% by weight of a silicon portion containing silicon oil of cyclomethicone and dimethicone;
(f) 0.02 to 8.0 weight percent of an oxidation retardation portion including any one of citric acid, lactic acid or maleic acid or a mixture of two or more thereof; And
(g) 0.2 ~ 13.0% by weight of the oxidation reaction promoting part comprising a urea; Hair dye prevention rapid hair dye composition comprising a.
The method of claim 1, wherein the water phase portion is 0.005 to 0.5% by weight of the metal complex compound, 0.1 to 20.0% by weight of the polyol, 0.01 to 0.5% by weight of antioxidants, 0.1 to 10.0% by weight of the cationic surfactant having at least 18 carbon atoms, the remaining amount Rapid hair dye composition for preventing skin inflammation, characterized in that it comprises water.
The method of claim 1 or claim 2, wherein the metal complex compound is EDTA-2Na, EDTA-3Na or EDTA-4Na, characterized in that the rapid hair dye composition for preventing skin inflammation.
The method of claim 1, wherein the cellulose-based thickener is any one of hydroxypropyl cellulose, hydroxyethyl cellulose or hydroxypropylmethyl cellulose or a mixture of two or more thereof, characterized in that the rapid hair dye composition for preventing skin inflammation .
The method of claim 1, wherein the dye portion is a dye precursor o-aminophenol, p-aminophenol, toluene-2,5-diamine hydrochloride, p-phenylenediamine hydrochloride, toluene-2,5-diamine, p-phenylene Diamine, p-methylaminophenol sulfate, o-aminophenol sulfate, p-aminophenol sulfate, toluene-2,5-diamine sulfate, p-phenylenediamine sulfate or any mixture of two or more thereof, and 2- Methyl-5-hydroxyethyl aminophenol, p-amino-o-cresol, m-aminophenol, hydrochloric acid 2,4-diaminophenoxyethanol, m-phenylenediamine hydrochloride, m-phenylenediamine, N Methyl-p-phenylenediamine, p-amino-o-cresol sulfate, 4-ethoxy-m-phenylenediamine sulfate, m-phenylenediamine sulfate, α-naphthol, resorcinol, or 2- Fast hair dye composition for preventing skin inflammation, characterized in that any one or a mixture of two or more of methylesorcinol.
According to claim 1, wherein the oil phase is 0.1 to 8.0% by weight of the higher alcohol, 0.1 to 3.0% by weight of the high melting wax, 0.1 to 2.0% by weight of the self-emulsifying surfactant, 0.5 to 2.0% by weight of the hydrophilic surfactant, the ester 0.1 to 7.0% by weight of the oil, 1.0 to 7.0% by weight of the natural oil, a rapid hair dye composition for preventing skin inflammation, characterized in that it comprises an oil-soluble antioxidant as a residual amount.
The skin dye according to claim 1 or 6, wherein the higher alcohol is any one of cetanol, cetostearyl alcohol, stearyl alcohol, behenyl alcohol or batyl alcohol or a mixture of two or more thereof. Fast hair dye composition for prevention.
The method of claim 1 or 6, wherein the high melting point wax is any one of Microcrystalline wax, Serisin wax, Paraffin wax, or polyethylene or a mixture of two or more thereof. Rapid hair dye composition for preventing skin inflammation, characterized in that.
The method of claim 6, wherein the self-emulsifying surfactant is cetearylalcohol (Cetearylalcohol) / cetearylglucoside (Cetearylglucoside), cetearyl alcohol / ceteaeth-20 (Ceteareth-20), cetearyl alcohol / cete Ares-23 or glyceryl stearate / polyoxyethylene (100) stearate any one or a mixture of two or more thereof, the rapid hair dye composition for preventing skin inflammation.
The method according to claim 6, wherein the hydrophilic surfactant is polyoxyethylene sorbitan stearate, polyoxyethylene sorbitan oleate, polyoxyethylene sorbitan laurate, ceteares-20, ceteares-23 or steares-21 ( Steareth-21) any one or two or more of these polyoxyethylene and fatty acid and a high-alcohol (higher alcohol) hydrophilic non-ionic surfactant comprising a compound consisting of a high-alcohol (fast alcohol) preventing hair dye composition.
The method of claim 1 or claim 6, wherein the ester-based oil is any one of alkyl benzoate, phenyl trimethicone or phenyl dimethicone or a mixture of two or more thereof.

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