KR20110042519A - Perfume composition for expressing the fragrance of modern hanbang and the composition for external skin application containing the same - Google Patents

Abstract

PURPOSE: A perfume composition for reproducing herb fragrance and an external use skin formulation are provided to enjoy fresh feel. CONSTITUTION: A perfume composition for reproducing herb fragrance contains 45-65 weight% of D-limonene, 6.0-12 weight% of eucalyptol, 1.5-6.0 weight% of gamma-terpinene, 1.0-5.0 weight% of terpinol, 1.0-6.0 weight% of P-cymene, 2.3-2.7 weight% of camphor, 0.9-1.1 weight% of ethyl acetate and 1.0-1.4 weight% of furfural. The composition further contains 0.5-2.0 weight% of alpha-pinene, 0.2-1.0 weight% of beta-pinene, 0.2-0.9 weight% nerolidol, and 0.2-0.8 weight% of thymol.

Description

Perfume composition for expressing the fragrance of Modern Hanbang and the composition for external skin application containing the same}

The present invention relates to a fragrance composition reproducing a modern herbal fragrance and an external preparation for skin containing the same, and more particularly, to reproduce the fragrance analyzed by extracting the herbal fragrance through Simultous distillation extract (SDE) and citrus (Citrus) contains a lot of sweet D-limonene ingredients to give a light and refreshing feeling unlike the traditionally recognized herbal fragrance to reproduce the original scent and excellent taste and modern herbal scent and a fragrance composition It relates to an external preparation for skin containing.

Gamguk has a peculiar fragrance and a little bit sweet and cold. Cools eyes and head, stops tears and fevers down. The fever in the chest is effective for stuffy symptoms, pneumonia, bronchitis, headache, stiff shoulders and high blood pressure. It is used for skin problems such as liver function, hyperemia, menstrual irregularities and acne, and is also called Jinguk, Geumjeong, or Cut flowers.

Ui -in means seeds that have been removed from the seedlings of Coix lacryma-jobi L. var. Ma-yuen Stapf. It is a type of diarrhea or anorexia that is difficult to urinate as a species, each, or a discomfort. It can also be used for quadriplegia, pain, pain, muscle pain, fever, drainage or appendicitis. Pharmacological action has been reported to be anti-cancer, skeletal muscle contraction suppression, intestinal uterus suppression, soothing, analgesic and antipyretic effect. Appearance is ovate to broad ovate, both ends are somewhat concave, dorsal side is rounded and there is a vertical deep groove in the lower center. The dorsal side is almost white powder with brown membranous rinds and longitudinals attached to the lower groove and other surface areas.

Peel is a medicinal herb made from peony and peony roots of Paeonia suffruticosa Andrews. Removes blood, bruises, anti-inflammatory pain, boil treatment or early appendicitis. As pharmacological action, analgesic, sedation, antipyretic, anticonvulsion, anti-inflammatory, anti-thrombotic, anti-allergic, gastric secretion suppression, uterine mucosa and antibacterial action have been reported. Appearance is tubular shell, the outer side is dark brown or purple brown, and there is long horizontally small oval side root marks and vertical wrinkles. The inner side is pale greyish brown or dark purple in color, and the curved side is rough. Inner and curved surfaces sometimes have white crystals.

Dermis refers to Citrus unshiu Markovich or mature rinds of related plants. Pharmacological action has been reported that essential oil components have digestive stimulation, digestive stimulation, expectorant, anti-ulcer, anti-gastric secretion, strong heart, blood pressure increase, anti-allergy, bile secretion promotion, uterine smooth muscle suppression and antibacterial action. Appearance is irregular shell, outer surface is yellowish red or dark yellowish brown with many small concave marks caused by loss. The inside is white or light grayish brown, and the quality is light and fragile.

Essential oil (essential oil) has a calming, analgesic, antipyretic and anti-inflammatory action, inhibits the intestinal and uterine smooth muscle, and has a strong inhibitory effect on ringworm. Gobon is a long columnar, unevenly divided, with a part of the stem above the root.

Samsam is a medicinal herb made from Adenophora triphylla var. Japonica Hara or the roots of the same plant. Used for back. It is used for constipation symptoms such as dry mouth, dry throat and hard stool due to lack of false negatives. As pharmacological action, expectorant action, antibacterial action, hemolytic action and cardiac action have been reported. The shape is fusiform or long conical, curved and sometimes has branch roots. Root stems with transverse wrinkles on the upper side. The root is light and easy to bend, and the cut side is milky white with many gaps.

Phalanx is a dried herb of Lycium chinense Miller or other cognate plants (gnarled and Solanaceae). Neuralgia, headache, shoulder pain, muscle pain, back pain or if you have a weakness in the lower back and knees. Pharmacological action has been reported to lower blood pressure and lower blood sugar of the cardiovascular system. It is tubular or flake shaped, outer surface is yellow and grayish brown, inner surface is gray, and the shell is scaly and easily peeled off.

In general, various methods can be used to reproduce the scent of natural products. For example, the scent can be reproduced by extracting natural products by steam distillation, compression, solvent extraction, or supercritical extraction.

Steam distillation is the most basic essential oil extraction method widely used in the past. It is a method of extracting oil by breaking the cell wall of a plant using hot water or steam. Above a certain temperature, the cell wall of the plant is broken and the fragrance substance evaporates. When the evaporated fragrance substance is cooled again, a liquid oil can be obtained. Steam distillation has the advantage of obtaining oil in large quantities, but has the disadvantage of destroying some heat unstable components at high temperatures.

Expression is a method of directly squeezing the fruit of a plant, especially the peel of citrus such as lemon, orange, bergamot, lime and grapefruit, to obtain oil. A method of obtaining oil from a flower with low amount of essential oil. Not useful as

Solvent Extraction is a method of immersing a plant's flowers in a cool dark place for a certain period of time in a volatile organic solvent such as hexane and pertoleum ether to melt the fragrance. Although it is possible to efficiently extract oils such as plants or limbs having a very small amount of oil such as rose oil, the process is complicated and time-consuming and expensive.

Supercritical extraction is a method of extracting carbon dioxide in air into a liquid when it is left at a low temperature or high pressure, and becomes a solid when the temperature is lowered and the pressure is increased. In addition, the solvent can be completely removed, which is useful for extracting oil of high purity, but it is economically expensive.

In addition, herbal ingredients are often boiled with decoction, so in general, the smell of boiling decoction is recognized as a herbal medicine.

Accordingly, the present inventors obtained each herbal materials to reproduce the herbal odor, and analyzed using the SDE method effective for analyzing the herbal odorants, D-Limonene, Eucalyptol, γ- It was found that terpinene (γ-Terpinene), terpineol (Terpineol) and p-cymene (p-Cymene) are the main components of the herbal. In addition, the present inventors have found that by adjusting the content of the analyzed components in a specific ratio, while reproducing the inherent odor of herbal medicine, the palatability can be enhanced and the present invention has been completed.

Accordingly, it is an object of the present invention to provide a perfume composition having excellent palatability while reproducing the intrinsic odor of herbal medicine.

Another object of the present invention is to provide an external preparation for skin containing the perfume composition.

In order to achieve the above object, the present invention provides a fragrance composition that reproduces the herbal odor by containing D-limonene, eucalyptol, γ-terpinene, terpineol, p-cymene, camphor, ethyl acetate and perfural .

In addition, the present invention provides an external preparation for skin containing the perfume composition.

The fragrance composition according to the present invention contains D-limonene, eucalyptol, γ-terpinene, terpineol and p-cymen in specific ratios analyzed by SDE method, and further contains camphor, ethyl acetate and perfural. By containing, the palatability of the fragrance was also improved while reproducing the herbal fragrance.

Hereinafter, the present invention will be described in more detail.

In the present invention, by mixing a relatively light and refreshing scent of the raw materials of herbal medicines Gamuk (Chrysanthemum), Uiin (Yulmu), Mokpipi, dermis, Gobon, Samsam and Gigolpi to have a traditional image while giving the oriental image as it is The smell was reproduced.

Herbal flavor component in the present invention was analyzed by the SDE method. SDE method is also called "Likens & Nickerson appatus method". In one flask, water (450g) and sample (100g) are mixed together and warmed (100 ℃), and in the other flask, solvent such as ether is heated to 35 ℃ for 2 hours 30 After the minute reaction, the solvent is evaporated and the oil is analyzed by GC-MS. Therefore, the SDE method is suitable for reproducing the herbal odor when boiling herbal medicines. In the present invention, a combination fragrance was prepared based on the herbal fragrance components analyzed by the SDE method, and through the olfactory sensory test, the similarity between the reproduced fragrance and the actual herbal fragrance and the palatability of the fragrance were examined. Sensory tests were conducted by professional steering staff and the general public. Similarity with herbal odor and taste preference were evaluated by questionnaire survey.

The perfume composition according to the present invention contains D-limonene, eucalyptol, γ-terpinene, terpineol, p-cymene, camphor, ethyl acetate and perfural as main components, and α-terpineol ( α-Terpineol, aldehyde C-16, aldehyde, Linalool, α-pinene, β-pinene, celery loctone, thymol ) And nerolidol.

The fragrance composition according to the present invention is 45 to 65% by weight of D-limonene, 6.0 to 12% by weight of eucalyptol, 1.5 to 6.0% by weight of γ-terpinene, 1.0 to 5.0% by weight of terpineol, p- 1.0 to 6.0 wt% of cymen, 2.3 to 2.7 wt% of camphor, 0.9 to 1.1 wt% of ethyl acetate and 1.0 to 1.4 wt% of furfural. When the main component for reproducing the herbal odor is used out of the above range, it is not preferable because the odor similarity with the herbal odor is lowered, or the palatability of the odor is lowered.

In addition, the fragrance composition according to the present invention is 0.5 to 4.0% by weight of α-terpineol, 0.1 to 0.6% by weight of aldehyde C-16, 0.2 to 0.8% by weight of linalul, 0.5 to 2.0% by weight of α-pinene, and 0.2 to β-pinene 0.2 It may further contain -1.0 weight%, 0.2-0.8 weight% of celery lactone, 0.2-0.9 weight% of nerolidol, and 0.2-0.8 weight% of thymol. Such secondary components are preferably used within the above range, but may not be contained in an amount outside the above range as long as they do not affect the reproduction of the herbal odor.

The composition according to the present invention mixed in the above range can be blended into external skin substrates such as perfume or cosmetics, and the blending amount is 5 to 20 weight based on the total weight of perfume in the case of perfume, according to techniques conventional in the art. %, Cosmetics may be appropriately selected and blended to achieve the desired effect of 0.05 to 0.5% by weight relative to the total weight of the cosmetic.

Such external materials include, but are not limited to, ointments, lotions, soluble burns, suspensions, emulsions, creams, gels, sprays, papes, warning agents, patches or water pastes, and the like. It can be formulated in any base that has been formulated.

Hereinafter, the content of the present invention will be described in more detail through examples and test examples. These examples are provided only for understanding the contents of the present invention, and the scope of the present invention is not limited to these examples, and modifications, substitutions, and insertions commonly known in the art may be performed. This is also included in the scope of the present invention.

[Reference Example 1] Analysis of the odor of herbal medicine using the SDE method

100 g of Korean ginseng (Chrysanthemum), Uiin (Yulmu), Mokmokpi, dermis, Gobon, Samsam and Phalanx were mixed at a weight ratio of 40: 5: 3: 30: 2: 15: 5. It was mixed with 450 g of water and placed in a 1000 ml round bottom flask. Then, 100 g of ethyl ether was added to a 250 ml round bottom flask. Each round bottom flask was installed in the SDE apparatus and the water and sample parts were heated to 100 ° C. and the ether part to 40 ° C. After heating for 3 hours, the ether part was transferred to remove the ether, and the oil was analyzed by GC-MS.

GC-MS analysis conditions are as follows.

Analysis condition

. Analyzer: HP 5890 II GC. Detector: HP 5972 MSD

. Column: DB-1 (60 m × 0.25 mm × 0.25 μm). Carrier Gas: He

. Injection temperature: 250 ° C. Detector temperature: 280 ℃

. Oven temperature: 70-220 ° C. (3 ° C./min). Ionization Voltage: 70 eV

. Desorption time: 2 min.

As a result, the herbal fragrance components analyzed by the SDE method are shown in Table 1 (unit: wt%).

Fragrance ingredients content D-limonene 48.5 Eucalyptol 8.5 γ-terpinene 2.6 Terpineol 3.7 α-terpineol 1.7 p-cymen 4.0 Aldehyde C-16 0.5 Linarul 0.6 α-pinene 1.6 β-pinene 0.8 Celery lactone 0.6 Nerolidol 0.8 Thymol 0.8 Etc 25.3 Total content 100.0

As shown in the results of Table 1, D-limonene, eucalyptol, γ-terpinene, terpineol, α-terpineol and p-cymene are the main odorants, and these main ingredients Accounted for 69.00% by weight.

[Reference Example 2] Comparative sensory evaluation of the fragrance and herbal odor produced in the analysis result

Based on the analyzed results, a newly prepared combination flavor (Sample B) having the composition shown in Table 2 was prepared, and the aroma similarity between the herbal medicine and herbal medicines boiled with the herbal ingredients illustrated above was verified through sensory evaluation (unit: weight). %).

Fragrance ingredients content D-limonene 48.5 Eucalyptol 8.5 γ-terpinene 2.6 Terpineol 3.7 α-terpineol 1.7 p-cymen 4.0 Aldehyde C-16 0.5 Linarul 0.6 α-pinene 1.6 β-pinene 0.8 Celery lactone 0.6 Nerolidol 0.8 Thymol 0.8 Dipropylene Glycol (Solvent) 25.3 Total content 100.0

The sensory evaluation was performed on 20 general men and women aged 20 to 45 years.They were treated with the same amount of herbal medicine (Sample A) and the flavor of sample B of the combination perfume reproduced by the SDE method. By responding to the questionnaire of Table 3, the perfume similarity (question 1) and the palatability of the perfume (question 2) were investigated. The results are shown in Table 4.

survey
(1) Question 1: How similar are the flavors of Sample A and Sample B?
1) Not at all similar
2) Not very similar.
3) It is so.
4) Somewhat similar.
5) very similar.

(2) Question 2: How much do you like the smell of Sample B?
1) Not good at all
2) Not so good
3) It is so.
4) Slightly good
5) Very good

Evaluation Agent Question 1 (similarity) Question 2 (symbolic) One 4 2 2 2 2 3 4 2 4 3 3 5 3 3 6 2 2 7 3 3 8 One 2 9 3 2 10 4 2 11 3 2 12 3 4 13 2 3 14 2 3 15 2 2 16 3 2 17 2 3 18 3 3 19 3 3 20 4 3 Average 2.30 2.50

As shown in Table 4, Sample B of the combination fragrance was found to have a lot of difference with the herbal odor, and also showed a low palatability.

REFERENCE EXAMPLE 3 Comparison of odor analysis and herbal odor by professional evaluation team

As shown in the results of Reference Example 2, the perfume composition composed of the components analyzed by the SDE method did not have anti-odor similarity to decoction. Therefore, the professional evaluation team composed of the steering company performed sensory analysis on the flavor components of each herbal medicine. As a result, D-limonene, which produces citrus and sweet scents, which are the main constituents of herbal scents such as orange and grapefruit; Eucalyptol which has a fresh herb flavor with main ingredients such as eucalyptus, lavender and rosemary; Γ-terpinene, which gives off a herb Citrus scent; Dry woody scented terpineol; The five components, p-cymen, which produces gassy odors, were identified as the main constituents of herbal odor.

Example 1 Preparation of a New Combination Fragrance According to the Content Change of Seven Main Components

Based on the result of Reference Example 3, D-limonene, eucalyptol, γ-terpinene, terpineol, and p-cymene are included as main ingredients of the original herbal scent, and have a palatable odor while still showing the herbal scent. In order to prepare the new combination perfume of the following # 1 to # 4.

Combination fragrances # 1 to # 4 were prepared by changing the total content of the seven flavors to 60 to 90% by weight, as shown in Table 5, while maintaining the ratio of these five components (unit: wt%).

Fragrance ingredients #One #2 # 3 #4 (60%) (70%) (80%) (90%) D-limonene 44.7 52.1 59.5 66.9 Eucalyptol 7.1 8.3 9.5 10.7 γ-terpinene 3.0 3.5 4.0 4.5 Terpineol 2.2 2.6 3.0 3.4 p-cymen 3.0 3.5 4.0 4.5 α-terpineol 12.0 9.0 6.0 3.0 Aldehyde C-16 2.4 1.8 1.3 0.6 Linarul 2.8 2.1 1.5 0.7 α-pinene 8.0 6.0 4.0 2.0 β-pinene 4.0 3.0 2.0 1.0 Celery lactone 2.8 2.1 1.4 0.7 Nerolidol 4.0 3.0 1.9 1.0 Thymol 4.0 3.0 1.9 1.0 Total content 100 100 100 100

[Test Example 1] Sensory evaluation of the perfume prepared in Example 1

With respect to the four flavors prepared in the new combination in Example 1, the sensory evaluation for similarity and palatability with the herbal perfume was carried out in the same manner as in Reference Example 2. On the other hand, after conducting the comparative sensory evaluation of the two combination flavors, a 5-minute rest period was given so that there was no post-sensory paralysis. The results of sensory evaluation on flavor similarity and palatability between the new combination perfume and herbal perfume are shown in Table 6 below.

evaluation
agent Question 1 (similarity) Question 2 (symbolity) Combination flavor number Combination flavor number #One #2 # 3 #4 #One #2 # 3 #4 One 2.0 3.0 3.0 3.0 3.0 2.0 3.0 3.0 2 2.0 3.0 3.0 2.0 1.0 2.0 3.0 3.0 3 3.0 2.0 4.0 1.0 2.0 3.0 3.0 4.0 4 2.0 1.0 3.0 3.0 2.0 2.0 4.0 3.0 5 2.0 3.0 3.0 2.0 1.0 3.0 3.0 3.0 6 1.0 4.0 3.0 3.0 3.0 4.0 4.0 3.0 7 2.0 2.0 4.0 4.0 2.0 2.0 2.0 2.0 8 2.0 1.0 3.0 2.0 2.0 3.0 3.0 3.0 9 3.0 3.0 3.0 2.0 4.0 3.0 3.0 3.0 10 2.0 2.0 3.0 2.0 2.0 2.0 3.0 3.0 11 2.0 3.0 4.0 3.0 2.0 4.0 4.0 4.0 12 3.0 2.0 3.0 2.0 3.0 3.0 3.0 2.0 13 2.0 2.0 2.0 2.0 1.0 2.0 4.0 2.0 14 3.0 3.0 3.0 2.0 3.0 3.0 3.0 3.0 15 3.0 3.0 3.0 3.0 1.0 2.0 3.0 3.0 16 2.0 4.0 4.0 3.0 2.0 2.0 4.0 3.0 17 2.0 2.0 3.0 3.0 2.0 3.0 3.0 2.0 18 1.0 2.0 3.0 2.0 2.0 3.0 2.0 2.0 19 2.0 3.0 3.0 4.0 2.0 1.0 3.0 3.0 20 2.0 2.0 2.0 3.0 3.0 2.0 4.0 2.0 Average 2.2 2.5 3.3 2.6 2.5 2.6 3.2 2.8

As shown in the results of Table 6, Sample # 3, which has 80% of the total content of the five major components, was shown to have the best similarity and palatability among the four combination perfumes, but both similarity and palatability did not meet expectations. It did not appear.

Example 2 Production of flavor-enhancing fragrance by analysis of professional evaluation group

D-limonene, eucalyptol, γ-terpinene, terpineol, p A total of 80 percent by weight of cimen, where a group of experts composed of steerers to give one-sided similarity and palatability, analyzed the fragrance for warm Minty Campo, Light Fruity Ethyl acetate and Pungent Sweet perfural were added to prepare a new combination fragrance. In addition, the expert evaluation team composed of steering firms increased the content of camphor to 1.7%, 1.9%, 2.1%, 2.3 to increase the palatability of the fragrance and to specify the content range of each component so as not to impair the similarity with the herbal odor. By weight, 2.5% by weight, 2.7% by weight and 2.9% by weight; The content of ethyl acetate was 0.6%, 0.7%, 0.8%, 0.9%, 1.0%, 1.1% and 1.2% by weight; Combination perfumes were prepared by adding 0.4% by weight, 0.6% by weight, 0.8% by weight, 1.0% by weight, 1.2% by weight, 1.4% by weight and 1.6% by weight of furfural. The composition of these recombinant flavors is shown in Table 7 below (unit: wt%).

Fragrance ingredients Combination flavor number #end #I #All #la #hemp #bar #four D-limonene 59.5 59.5 59.5 59.5 59.5 59.5 59.5 Eucalyptol 9.5 9.5 9.5 9.5 9.5 9.5 9.5 γ-terpinene 4.0 4.0 4.0 4.0 4.0 4.0 4.0 Terpineol 3.0 3.0 3.0 3.0 3.0 3.0 3.0 p-cymen 4.0 4.0 4.0 4.0 4.0 4.0 4.0 Campo 1.7 1.9 2.1 2.3 2.5 2.7 2.9 Ethyl acetate 0.6 0.7 0.8 0.9 1.0 1.1 1.2 Perfural 0.4 0.6 0.8 1.0 1.2 1.4 1.6 α-terpineol 3.3 3.2 3.1 3.0 2.9 2.8 2.7 Aldehyde C-16 0.7 0.6 0.6 0.5 0.5 0.4 0.4 Linarul 0.9 0.8 0.8 0.7 0.7 0.6 0.6 α-pinene 2.2 2.1 2.0 1.9 1.8   1.7 1.6 β-pinene 1.1 1.1 1.0 1.0 0.9 0.9 0.8 Celery lactone 0.9 0.8 0.8 0.7 0.7 0.6 0.6 Nerolidol 1.1 1.1 1.0 1.0 0.9 0.9 0.8 Thymol 1.1 1.1 1.0 1.0 0.9 0.9 0.8 Total content 100.0 100.0 100.0 100.0 100.0 100.0 100.0

Test Example 2 Sensory Evaluation of Combination Perfumes Prepared in Example 2

For the combination fragrances prepared in Example 2, #A, #B, #D, #D, #MA, #Bar, # 4, the similarity of flavor with herbal perfume in the same manner as in Reference Example 2 and The sensory evaluation on the palatability of the smell was performed. After conducting the comparative sensory evaluation for each combination flavor, a 5 minute rest period was given to avoid the olfactory paralysis. The results for the similarity and palatability of the new combination fragrances and herbal perfumes are shown in Table 8 below.

Evaluation Agent Question 1 (similarity) Question 2 (symbolity) Combination flavor number Combination flavor number #end #I #All #la #hemp #bar #four #end #I #All #la #hemp #bar #four One 3.0 3.0 4.0 4.0 4.0 3.0 3.0 2.0 2.0 3.0 3.0 4.0 4.0 3.0 2 3.0 2.0 4.0 4.0 5.0 3.0 3.0 3.0 3.0 3.0 3.0 4.0 4.0 3.0 3 2.0 3.0 3.0 3.0 3.0 4.0 2.0 2.0 3.0 3.0 4.0 5.0 4.0 4.0 4 3.0 3.0 3.0 3.0 4.0 4.0 3.0 3.0 3.0 3.0 4.0 4.0 3.0 3.0 5 3.0 3.0 4.0 4.0 5.0 4.0 3.0 3.0 3.0 3.0 4.0 4.0 3.0 3.0 6 2.0 2.0 3.0 3.0 4.0 3.0 3.0 3.0 4.0 3.0 3.0 3.0 4.0 4.0 7 2.0 3.0 3.0 4.0 3.0 3.0 4.0 3.0 3.0 3.0 3.0 4.0 5.0 4.0 8 3.0 3.0 3.0 4.0 4.0 4.0 3.0 3.0 3.0 4.0 4.0 4.0 3.0 3.0 9 3.0 3.0 3.0 3.0 4.0 3.0 3.0 2.0 2.0 3.0 3.0 4.0 4.0 3.0 10 3.0 3.0 3.0 3.0 4.0 4.0 3.0 3.0 3.0 4.0 4.0 5.0 4.0 3.0 11 4.0 3.0 4.0 4.0 5.0 3.0 3.0 3.0 2.0 3.0 3.0 3.0 3.0 4.0 12 3.0 3.0 3.0 3.0 5.0 4.0 4.0 2.0 4.0 4.0 4.0 5.0 4.0 3.0 13 3.0 4.0 4.0 4.0 3.0 5.0 3.0 2.0 3.0 3.0 3.0 3.0 4.0 2.0 14 2.0 3.0 3.0 3.0 5.0 5.0 3.0 2.0 4.0 3.0 5.0 5.0 4.0 3.0 15 3.0 3.0 3.0 4.0 5.0 4.0 4.0 3.0 3.0 4.0 4.0 4.0 3.0 3.0 16 2.0 3.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0 3.0 3.0 4.0 4.0 3.0 17 2.0 3.0 3.0 3.0 4.0 5.0 3.0 4.0 4.0 3.0 5.0 4.0 3.0 4.0 18 3.0 4.0 3.0 4.0 4.0 4.0 3.0 3.0 3.0 4.0 4.0 4.0 3.0 3.0 19 2.0 2.0 3.0 3.0 3.0 4.0 3.0 3.0 3.0 4.0 4.0 4.0 3.0 2.0 20 3.0 2.0 4.0 4.0 4.0 3.0 2.0 3.0 3.0 3.0 3.0 4.0 3.0 3.0 Average 2.7 2.9 3.4 3.6 4.1 3.8 3.1 2.8 3.1 3.3 3.7 4.1 3.6 3.2

As shown in the results of Table 8, in the main components of herbal fragrance of D-limonene, eucalyptol, γ-terpinene, terpineol, p-cymene, Campo 2.3-2.7% by weight, ethyl acetate 0.9-1.1 When it contained by weight% and perfural 1.0-1.4 weight%, it was confirmed that the herbal fragrance can be reproduced and it shows the outstanding palatability (average 3.5 or more). On the other hand, if the content of camphor, ethyl acetate and perfural is out of the above range, the similarity to the herbal odor or rather poor taste.

[Production Example 1]

As described above, the fragrance composition having similarity with herbal fragrance was combined to prepare a perfume of Table 9 (unit: wt%).

Fragrance ingredients content Herbal Fragrance Reproduction Combination Fragrance (#LA, #MA, #Bar)
Alcohol
water
Pigment
Sunscreen 15
83
2
Suitable amount
Suitable amount

Claims (4)

The fragrance composition which reproduced the herbal aroma by containing D-limonene, eucalyptol, (gamma) -terpinene, terpineol, p-cymene, camphor, ethyl acetate, and perfural. The composition according to claim 1, wherein the composition comprises 45-65 wt% of D-limonene, 6.0-12 wt% of eucalyptol, 1.5-6.0 wt% of γ-terpinene, 1.0-5.0 wt% of terpineol, 1.0-1.0 p-cymene. Perfume composition, characterized in that it contains 6.0% by weight, Campo 2.3-2.7% by weight, ethyl acetate 0.9-1.1% by weight and perfural 1.0-1.4% by weight. According to claim 1, wherein the composition is 0.5 to 4.0% by weight of α- terpineol, 0.1 to 0.6% by weight of aldehyde C-16, 0.2 to 0.8% by weight linarul, 0.5 to 2.0% by weight α-pinene Perfume composition, characterized in that it further contains 0.2 to 1.0% by weight of β-pinene, 0.2 to 0.8% by weight of celery lactone, 0.2 to 0.9% by weight of nerolidol and 0.2 to 0.8% by weight of thymol. The external preparation composition for skin containing the fragrance composition as described in any one of Claims 1-3.