KR20110039663A

KR20110039663A - Method for detoxifying sulfur, and detoxicant sulfur produced thereby

Info

Publication number: KR20110039663A
Application number: KR1020090096612A
Authority: KR
Inventors: 안종호
Original assignee: 안종호
Priority date: 2009-10-12
Filing date: 2009-10-12
Publication date: 2011-04-20

Abstract

The present invention relates to a method for removing the toxicity of sulfur and non-toxic sulfur prepared therefrom, and more particularly, to non-toxic sulfur in which non-sulfur, radish powder, ginger, and licorice extracts are added to mineral sulfur and fermented and matured. It relates to a method for producing sulfur.

The non-toxic sulfur produced by the production method of the present invention can be used as a feed for livestock, since the toxic substances are sufficiently removed, the body absorbs well when ingested, and improves the meat quality of the livestock ingesting the non-toxic sulfur of the present invention. The manufacturing process is simple and mass production can be easily performed at low cost.

Description

Method for detoxifying sulfur, and detoxicant sulfur produced thereby

In the biological elements constituting the human body, 14 kinds of elements including hydrogen, oxygen, nitrogen, sulfur, etc. account for about 99% of human body elements, and sulfur occupies the eighth of human body elements.

Sulfur is an oxygen group element belonging to the sixth group of the periodic table. According to the agreement, there is a lot of heat and strong toxicity, but it helps drive the nourishment by driving away the cold air in the body, while controlling the capture and fraud of the heart. As a medicinal herb, it is known for its detoxification, as well as detoxification of heavy metals and pesticides, which are emerging as a cause of cancer and various incurable diseases. It is also known to be excellent.

In general, sulfur is classified into three types: vegetable sulfur, animal sulfur, and mineral sulfur. Vegetable sulfur, which is a dietary sulfur extracted from seaweed, is the most commonly used, but its purity is up to 34%. It is pointed out that the problem is lower than that of mineral sulfur.

Although animal sulfur can be obtained mainly from animals such as ungdam and musk, it is increasingly restricted to obtain the active ingredient of sulfur from animal sulfur in an environment where environmental regulations for animal protection and natural ecosystem are being tightened. .

On the other hand, the method of obtaining sulfur efficacy from mineral sulfur is partially performed by applying traditional legislative methods known in oriental medicine, but a series of methods of removing the poison of mineral sulfur having high thermal toxicity are very complicated. While a method of mass production is being attempted while showing a certain efficacy of sulfur, it has not been satisfactory.

In addition, when the non-toxic sulfur produced by the conventional sulfur legislation method is used as feed for livestock, the mortality rate of the livestock is 30% or more, which considerably limits the feed amount of the regulated sulfur, and most of the sulfur consumed is also 2 hours. Exposed within, there is a problem such as less residual effect of sulfur feed.

In addition, since the economic efficiency of livestock raising is very low due to the sluggish growth of the livestock and the high mortality rate when the non-toxic sulfur produced by various methods is added to the livestock feed, the development of a method for overcoming this is the first priority. do.

Therefore, in order to use the sulfur component in livestock feed, there is a need for a method of removing sulfur toxicity that can be used without limitation in animal feed by sufficiently removing sulfur toxicity while using mineral sulfur, which is easy to secure raw materials.

The problem to be solved by the present invention is to provide a sulfur poisoning method and a non-toxic sulfur prepared therefrom that can sufficiently remove the toxicity of sulfur to be able to use without limitation in animal feed.

In addition, it provides an economical sulfur removal method.

In order to achieve the above object, the present invention, the step of removing the foreign matter by selecting the mineral sulfur and pulverized into fine powder; Washing the roots of radishes from which the leaves have been removed to remove water, and then compressing the extract to extract radish, and drying the remaining radish at low temperature at 45˜55 ° C., followed by pulverization, to prepare radish powder; Adding water to each of ginger and licorice and decoction to prepare ginger juice and licorice juice; To the pulverized sulfur, the radish juice is mixed at a weight ratio of 1: 8 to 25, and added to the ginger juice solution 0.5-1.5% by weight, licorice juice solution 0.5-1.5% by weight and powderless powder 1.0-3.5% by weight. Preparing a mixture; Adding the mixture to a aging tank, and then stirring the mixture for 10 to 15 hours while maintaining the temperature inside the aging tank at 25 to 35 ° C; Stabilizing the stirred mixture at room temperature for 1 to 3 hours; Separating sulfur from the stagnant mixture and drying at a low temperature of 45 to 55 ° C. for 10 to 18 hours; And pulverizing the dried sulfur to a size of 300 to 400 mesh.

At this time, between the stirring step and the stagnation step is preferably added to the stirred mixture for 1-2 hours and then stirred for 5-7 hours at a temperature of 25 ~ 35 ℃ again.

In addition, the step of preparing the ginger juice and licorice juice solution, 5 to 8 times the weight of ginger or licorice and poured into a weak fire, it is preferable to leave 40 to 60% of the total weight before decoction .

In addition, the pulverized size of the dried sulfur is preferably 340 mesh.

The present invention also provides a non-toxic sulfur produced by the above method.

The non-toxic sulfur produced by the production method of the present invention can be used as a feed for livestock, since the toxic substances are sufficiently removed, the body absorbs well when ingested, and improves the meat quality of the livestock ingesting the non-toxic sulfur of the present invention. do.

In addition, the manufacturing process of the present invention is simple and mass production can be easily performed at low cost.

Hereinafter, the present invention will be described in detail.

Mineral sulfur is first sorted to remove foreign matter and then ground into fine powder.

Next, clean the roots of the radish with leaves and then drain.

Radish is a biennial or biennial herb of the dicotyledonous plant Poppy, which contains glucose, sucrose, fructose and various organic acids and amino acids, and decomposes starch and diasterase and carcinogens to promote digestion and absorption. It contains high amounts of enzymes and vitamin C, such as orgestatase and amylase, a starch degrading enzyme that detoxifies and protects the stomach wall.

In herbal medicine, such as herbal herb, radish juice is said to promote digestion and toxin poisoning, and it is said to help the five intestines and lighten the body, making the skin feel harder. Also, the radish juice removes the wall, stops coughing, controls the blood The warmth, anemia and drinking juice is said to control diarrhea.

The present invention is to remove the toxicity of sulfur by using the root of the radish having the above effects, extract the juice by compressing the roots of the radish from which the water is removed, the remaining radish (extract juice from the root of radish remaining The residue, which is the same as below), is dried at a low temperature at 45 to 55 ° C. and then pulverized into fine powder.

If the dried radish is less than 45 ° C mold and receding during storage, and if the drying exceeds 55 ° C it is preferred to dry in the above temperature range because the portion that shows the effect of blacking occurs when the drying is reduced.

Next, prepare a solution of ginger and licorice.

Ginger is a perennial herb with a monocotyledonous plant, Ginger-necked Ginger, which uses root stem. In oriental medicine, dried root stem is used as a medicine called health. It is written that it is used to remove the cold of the five viscera.

In addition, ginger contains diastase and protease, which help digestion of sashimi, and ginger's flavor component helps digestion in digestive organs, stimulating the secretion of digestive juices and promoting gastrointestinal movement. It is known to improve appetite.

In addition, ginger has bactericidal and antibacterial activity against bacteria causing food poisoning. Gingerol and shogaols are the main ingredients of ginger, and the fragrance ingredients are various essential oils. In combination with the ingredients, it shows bactericidal activity against bacteria such as typhoid bacteria and cholera bacteria.

Licorice uses the root as a perennial herb of the dicotyledonous plant Rosaceae, and in Dongbobogam, licorice governs the heat and fraud of the five Jangyuk, normalizes the physiology of eyes, nose, mouth, ears and faeces, and communicates all blood veins and muscles. It is written that it strengthens and strengthens bones and improves nutrition, and also detoxifies the toxicity of all medicines and harmonizes 72 stones and 1200 herbs.

In addition, licorice antagonizes various polar drugs or toxic drugs to treat drug poisoning caused by extreme medicine or poison, and the poison caused by bacteria also has a function of neutralization and detoxification.

In addition, licorice has an adjustment effect such as corticosteroids, so as to release the urgent symptoms and to relax the pain or nervous tension caused by muscle tension, and is known to have an anti-allergic effect.

In the present invention to detoxify the toxicity of sulfur by using the roots of ginger and licorice having the above-mentioned efficacy, ginger and licorice juice solution is prepared by the traditional herbal medicine decoction method each ginger and licorice.

To illustrate an example of the preparation of the lysate, pour the clean water of about 5 to 8 times the weight of ginger or licorice and put it on a low heat to prepare the lysate so that about 40 to 60% of the total weight remains before decoction.

When the ingredients are prepared, the pulverized mineral sulfur powder is mixed with the radish juice in a ratio of 1: 8 to 25 weight ratio, and 0.5 to 1.5% by weight of ginger juice solution, 0.5 to 1.5% by weight licorice juice solution and 1.0 to 3.5 powderless powder. Add the materials to the weight percent.

The powderless powder is mixed with raw radish juice to expand the volume of about 25 times to play a role of maximizing the activity of various enzymes present in the radish juice.

To describe this in more detail, the sugarless polysaccharides and various enzymes are present in the juice, and the residue after extracting the juice is about 35% of the original weight, and when dried at low temperature, the water evaporates and only the fiber and the active ingredient are dried. It is a high sugar content of enzyme.

Drying the radish as described above and mixed with raw radish juice acts as a catalyst for maximizing the activity of various enzymes in the low sugary environment of raw radish juice while the lumps of sugar-rich radish enzymes expand about 25 times. It can be said to be a catalyst having homogeneous components and potency, and is a natural catalyst using homogeneity rather than an artificial and chemical reaction inducing agent, which leads to natural reaction at room temperature.

The sulfur, radish juice, radish powder, ginger juice solution and licorice juice solution mixture was added to a aging tank equipped with a stirring facility, and then stirred for 10-15 hours while maintaining the temperature inside the aging tank at 25-35 ° C. .

While the mixture is agitated, enzymes of ginger and licorice and enzymes of sterilization, flavor, detoxification, and neutralization are used as catalysts, and enzymes in juice are actively reacted to remove harmful and toxic components of sulfur by evaporation by the fermentation technique. At the same time, the mixture is aged, and the organic polysaccharides and enzyme components of succulents are coated around the surface of the sulfur particles to obtain mineral organic non-toxic sulfur which is easily absorbed by the body when ingested.

The organic non-toxic sulfur obtained above can be used as it is removed most of the sulfur toxicity, if the need to remove sulfur more poisonous sulfur may be subjected to the stirring process once more.

That is, the aged non-toxic sulfur is suspended for 1 to 2 hours while the stirring is stopped, and then stirred for 2 to 5 hours at a temperature of 25 to 35 ° C. again for residual toxicity of sulfur not removed in the first stirring process. Vaporize to remove.

When the temperature of the aging tank at the time of stirring and stagnation falls below 25 ° C., the fermentation and maturation efficiency of the sulfur, radish juice, ginger juice solution, licorice juice solution and powderless powder mixture is lowered and the stirring time is long.

At this time, in order to maintain the temperature of the aging tank operating temperature 25 ℃ or more to install a heater directly inside the aging tank is not preferable in the physical properties of the mixture, it is preferable to maintain the aging tank temperature by the external indirect heat.

In addition, when the aging tank operation temperature exceeds 35 ℃, the reaction activity of the various enzymes present in the juice, etc. is inhibited may cause a problem in the mechanism of removing the harmful components of sulfur, the juice is a volatile substance, so the temperature is It is not preferable because it is difficult to maintain the proper mixing ratio because of the large amount of evaporated and evaporated when going up.

Thus, by extracting the radish juice from radish and drying and grinding the remaining radish and reused as an activator of various enzymes, it is possible to expect improved effects in terms of cost and productivity, as well as to maximize the technical effects such as increased enzyme activity.

In addition, the sterilizing component of ginger and licorice acts as a natural preservative during the fermentation and ripening of the mixture to prevent the mixture from deterioration.

Next, the fermented and matured mixture is transferred to a precipitation tank and stabilized for 1 to 3 hours at room temperature.

During stagnation, juice and sulfur are separated into the upper and lower portions of the settling tank, and sulfur, that is, non-toxic sulfur, collected at the lower portion is collected and dried at low temperature at 45 to 55 ° C. for 10 to 18 hours.

If the drying temperature is less than 45 ℃ drying time is prolonged and mold may occur, if the drying temperature exceeds 55 ℃ the properties of non-toxic sulfur is deteriorated and weakness is not preferred.

Next, the dried non-toxic sulfur is pulverized and preferably prepared into a powder having a particle size of 300 to 400 mesh, and more preferably manufactured into a particle size of 340 mesh, which is a range in which sulfur is best absorbed into the body.

When the above pulverization is completed, it is possible to obtain a mineral organic non-toxic sulfur in the powder state in which the harmful and toxic components according to the present invention are removed.

Hereinafter, the present invention will be described in more detail based on the following Examples and Comparative Examples.

However, the following examples are only for illustrating the present invention, and the present invention is not limited by the following examples, and may be changed to other embodiments equivalent to substitutions and equivalents without departing from the technical spirit of the present invention. Will be apparent to those of ordinary skill in the art.

Mineral sulfur was first selected to remove foreign matters and then ground into fine powder.

Next, the roots of the radish with the leaves removed were washed to remove water and then pressed to extract the radish, and the remaining radish was dried at 50 ° C. and then ground with fine radish powder.

Next, six times the weight of purified water was poured into each of the neatly trimmed ginger and licorice, and weighed on low heat until half of the total weight was left to prepare a ginger and licorice essence solution.

The radish juice was mixed with 17 times by weight based on the weight of the juice, and each of the above ingredients was added so that 1.0% by weight of the ginger juice solution, 1.0% by weight licorice solution and 2.0% by weight of powderless powder.

The sulfur, radish juice, radish powder, ginger juice solution and licorice juice solution mixture was added to a aging tank equipped with a stirring facility, and the mixture was first stirred for 13 hours while maintaining the temperature of the aging tank at 30 ° C.

After the first stirring, the stirring was stopped, the mixture was allowed to stand for 1 hour, and then stirred for 2 hours at a temperature of 30 ° C.

After the completion of the secondary stirring mixture was transferred to the settling tank and allowed to stand for 2 hours at room temperature, the non-toxic sulfur separated in the bottom of the settling tank was collected and dried at 50 ℃ for 12 hours at low temperature.

The dried non-toxic sulfur was pulverized with 340 mesh to obtain a non-toxic sulfur-free sulfur according to the present invention.

Comparative Example

Non-toxic sulfur was prepared in the same manner as in the above example, except that the mixture was prepared using only sulfur, juice, ginger juice, and licorice juice without adding powderless powder to the mixture.

Test Example 1 Analysis of Hazardous Metal Content

In order to measure the toxic metal content of the non-toxic sulfur prepared by the above Examples and Comparative Examples, the analysis was performed using an inductively coupled plasma mass spectrometer (ICP-MS).

The non-toxic sulfur of the Examples and Comparative Examples was pretreated using a nitric acid solution and then subjected to quantitative analysis by separating each component using ion chromatography, and the results are shown in Table 1 below.

Hazardous Metal Content Measurement Item Pb Hg As CD Cr Se unit ppm Example ND ^{Note 1)} N.D. N.D. N.D. N.D. N.D. Comparative example N.D. N.D. N.D. N.D. N.D. N.D. MDL ^{Note 2)} 5 2 3 One One 3

Note 1) N.D. = Not Detected, <MDL

Note 2) MDL = Method Detection Limit

As can be seen from the above results, lead (Pb), mercury (Hg), arsenic (As), cadmium (Cd), chromium (Cr), selenium (Se) and the like are almost all peaks in ion chromatography. It was detected to the extent that it did not occur.

In addition, qualitative and quantitative analysis was carried out based on the ICP-MS of the non-toxic sulfur of the example using live sulfur as a control, and the results are shown in Tables 2 and 3 below.

Qualitative Analysis Results division Detection element Example (non-toxic sulfur) Al, Ba, Ca, Co, Cr, Cu, Fe, K, Mg, Mn, Mo, Na,
Ni, Pb, Sb, Sn, Sr, Ti, Y, Zn, Zr, Control group (fresh sulfur) Al, Ba, Ca, Cr, Cu, K, Mg, Mn, Mo, Na, Ni, Pb,
Sn, Sr, Ti, Y, Zn, Zr,

Quantitative Results Detection element unit Example (non-toxic sulfur) Control group (fresh sulfur) Al ppm 338 315 Ba <2 << 2 Ca 678 534 Co << 2 << 2 Cr << 2 << 2 Cu 5 << 2 Fe 55 - K 1,534 83 Mg 35 21 Mn << 2 << 2 Mo 2 << 2 Na 128 102 Ni 2 3 Pb << 2 << 2 Sb << 2 << 2 Sn << 2 << 2 Sr << 2 << 2 Ti 4 4 Y << 2 << 2 Zn 2 2 Zr << 2 << 2

As shown in Table 2 and Table 3, it can be seen that iron (Fe) and potassium (K) contents of the non-toxic sulfur of the Example were increased compared to raw sulfur, which is added to the non-toxic sulfur in the iron and potassium components of the radish. It seems to have been.

Test Example 2 Analysis of Sulfur Purity and Carbon Content

Sulfur-free and carbon content of the above example was measured using an elemental analyzer (EA).

The analysis is a method of analyzing the mass while burning sulfur under a nitrogen atmosphere four times the results are shown in Table 4 below.

Sulfur Purity and Carbon Content Analysis division unit Sulfur (S) content Carbon content 1st analysis weight% 98.34 1.35 1st analysis 98.72 1.25 1st analysis 98.47 1.51 1st analysis 98.29 1.67 Mean analysis 98.455 1.445

As a result, sulfur contained an average of 98.455% by weight, and carbon was measured as 1.445% by weight.

<Test Example 3> Analysis of the effect on cholesterol content and meat quality

Cholesterol content was measured using a photodiode array (PDA) spectrophotometer (UV-Vis Spectrophotometer) to evaluate the effect of non-toxic sulfur prepared by the above Examples and Comparative Examples when used as feed for livestock. .

Blood samples of the pig group (treated group) fed with 0.15% by weight of non-toxic sulfur in the above-mentioned Examples and Comparative Examples, and the blood sample of the pig group (controlled) fed normal feed without addition of the non-toxic sulfur After taking each of the five by examining the cholesterol content the average value is shown in Table 5 below.

Results of Measurement of Cholesterol Content in Porcine Blood Cholesterol Types unit Example Comparative example Control HDL Mg / ㎗
165 153 108 LDL 105 121 163

In addition, the cholesterol content of egg yolk in the eggs was measured in the same manner as in Test Example 3 chickens.

Results of Measurement of Cholesterol Content in Egg Yolk sample unit Example Comparative example Control Egg yolk Mg / 100g 613 863 1538

As shown in the above results, the high-density lipoprotein (HDL) content of the beneficial cholesterol in pigs is higher than that of the comparative example and the control according to the present invention, and the low-density lipoprotein (Low Dendity) is harmful cholesterol. Lipoprotein (LDL) content is the lowest.

In addition, in the case of chicken, the cholesterol content of the Example was measured lower than that of the comparative example and the control.

This is an important factor among many factors that determine the grade of meat quality, and it is expected that the improvement of the fat of livestock and health status and metabolic activity will be activated.

As described above, by adding the non-toxic sulfur produced by the method of the present invention to the feed of the livestock, it is expected that the quality of the meat of the livestock can be improved, and the taste and nutrition will also be improved.

Claims

Selecting mineral sulfur to remove foreign matters and then pulverizing it into fine powder;

Washing the roots of radishes from which the leaves have been removed to remove water, and then compressing the extract to extract radish, and drying the remaining radish at low temperature at 45˜55 ° C., followed by pulverization, to prepare radish powder;

Adding water to each of ginger and licorice and decoction to prepare ginger juice and licorice juice;

To the pulverized sulfur, the radish juice is mixed at a weight ratio of 1: 8 to 25, and added to the ginger juice solution 0.5-1.5% by weight, licorice juice solution 0.5-1.5% by weight and powderless powder 1.0-3.5% by weight. Preparing a mixture;

Adding the mixture to a aging tank, and then stirring the mixture for 10 to 15 hours while maintaining the temperature inside the aging tank at 25 to 35 ° C;

Stabilizing the stirred mixture at room temperature for 1 to 3 hours;

Separating sulfur from the stagnant mixture and drying at a low temperature of 45 to 55 ° C. for 10 to 18 hours; And

Toxic removal method of the sulfur comprising the step of crushing the dried sulfur to 300 ~ 400 mesh size.

The method of claim 1,

Between the stirring step and the stagnation step, and then the mixture is stirred for 1 to 2 hours and then stirred for 5 to 7 hours at a temperature of 25 ~ 35 ℃ again the sulfur toxicity method characterized in that it is added.

The method of claim 1,

The step of preparing the ginger and licorice juice solution, 5 to 8 times the weight of ginger or licorice and poured on a low heat, sulfur, characterized in that the remaining 40 to 60% of the total weight before decoction How to get rid of toxicity.

The method of claim 1,

The pulverized size of the dried sulfur is 340 mesh, characterized in that the sulfur removal method.

Non-toxic sulfur prepared by the method of claims 1 to 4.