KR20110033822A - 암석 및 골재, 및 이의 제조 방법 및 용도 - Google Patents
암석 및 골재, 및 이의 제조 방법 및 용도 Download PDFInfo
- Publication number
- KR20110033822A KR20110033822A KR1020107027766A KR20107027766A KR20110033822A KR 20110033822 A KR20110033822 A KR 20110033822A KR 1020107027766 A KR1020107027766 A KR 1020107027766A KR 20107027766 A KR20107027766 A KR 20107027766A KR 20110033822 A KR20110033822 A KR 20110033822A
- Authority
- KR
- South Korea
- Prior art keywords
- aggregate
- carbonate
- aggregates
- water
- magnesium
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 195
- 239000011435 rock Substances 0.000 title abstract description 55
- 239000000203 mixture Substances 0.000 claims abstract description 214
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 198
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 196
- -1 cation carbonates Chemical class 0.000 claims abstract description 91
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 70
- 239000002440 industrial waste Substances 0.000 claims abstract description 59
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 53
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 30
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims abstract description 23
- 239000001095 magnesium carbonate Substances 0.000 claims abstract description 22
- 239000000463 material Substances 0.000 claims description 231
- 239000011777 magnesium Substances 0.000 claims description 146
- 239000011575 calcium Substances 0.000 claims description 129
- 150000001768 cations Chemical class 0.000 claims description 114
- 239000013049 sediment Substances 0.000 claims description 112
- 239000007789 gas Substances 0.000 claims description 107
- 229910052799 carbon Inorganic materials 0.000 claims description 106
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 105
- 238000004519 manufacturing process Methods 0.000 claims description 83
- 239000013535 sea water Substances 0.000 claims description 65
- 229910052749 magnesium Inorganic materials 0.000 claims description 60
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 57
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 56
- 239000004568 cement Substances 0.000 claims description 54
- 229910052791 calcium Inorganic materials 0.000 claims description 53
- 150000001875 compounds Chemical class 0.000 claims description 43
- 239000003546 flue gas Substances 0.000 claims description 40
- 239000002803 fossil fuel Substances 0.000 claims description 40
- 239000002244 precipitate Substances 0.000 claims description 37
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 36
- 239000003245 coal Substances 0.000 claims description 33
- 239000012267 brine Substances 0.000 claims description 30
- 230000008859 change Effects 0.000 claims description 30
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 30
- 238000001556 precipitation Methods 0.000 claims description 30
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims description 30
- 238000012545 processing Methods 0.000 claims description 24
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 19
- 229910052753 mercury Inorganic materials 0.000 claims description 19
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 18
- 230000009919 sequestration Effects 0.000 claims description 18
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 17
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 17
- 238000002485 combustion reaction Methods 0.000 claims description 16
- 238000002955 isolation Methods 0.000 claims description 12
- HHSPVTKDOHQBKF-UHFFFAOYSA-J calcium;magnesium;dicarbonate Chemical compound [Mg+2].[Ca+2].[O-]C([O-])=O.[O-]C([O-])=O HHSPVTKDOHQBKF-UHFFFAOYSA-J 0.000 claims description 11
- 238000002360 preparation method Methods 0.000 claims description 11
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims description 11
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 10
- 150000003839 salts Chemical class 0.000 claims description 8
- 125000002091 cationic group Chemical group 0.000 claims description 5
- 239000003345 natural gas Substances 0.000 claims description 5
- 238000004062 sedimentation Methods 0.000 abstract description 48
- 239000012615 aggregate Substances 0.000 description 775
- 239000002245 particle Substances 0.000 description 72
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical class O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 71
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 68
- 229910052500 inorganic mineral Inorganic materials 0.000 description 66
- 235000010755 mineral Nutrition 0.000 description 66
- 239000011707 mineral Substances 0.000 description 66
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 60
- 239000004567 concrete Substances 0.000 description 59
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- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 29
- 238000006243 chemical reaction Methods 0.000 description 28
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- 239000000377 silicon dioxide Substances 0.000 description 26
- 239000000126 substance Substances 0.000 description 26
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- 229910002091 carbon monoxide Inorganic materials 0.000 description 24
- 239000012298 atmosphere Substances 0.000 description 23
- 238000002411 thermogravimetry Methods 0.000 description 23
- 229910021532 Calcite Inorganic materials 0.000 description 22
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 21
- 239000012071 phase Substances 0.000 description 21
- 230000009257 reactivity Effects 0.000 description 21
- 239000007787 solid Substances 0.000 description 21
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 20
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- 238000002441 X-ray diffraction Methods 0.000 description 20
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- ZFXVRMSLJDYJCH-UHFFFAOYSA-N calcium magnesium Chemical compound [Mg].[Ca] ZFXVRMSLJDYJCH-UHFFFAOYSA-N 0.000 description 19
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- 230000015572 biosynthetic process Effects 0.000 description 16
- 238000005259 measurement Methods 0.000 description 16
- 238000001228 spectrum Methods 0.000 description 16
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- 229910004298 SiO 2 Inorganic materials 0.000 description 15
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- 239000002344 surface layer Substances 0.000 description 15
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 13
- 230000006870 function Effects 0.000 description 13
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- 239000011159 matrix material Substances 0.000 description 13
- 239000002253 acid Substances 0.000 description 12
- 229910001748 carbonate mineral Inorganic materials 0.000 description 12
- 239000000446 fuel Substances 0.000 description 12
- 239000004576 sand Substances 0.000 description 12
- 239000002893 slag Substances 0.000 description 12
- 230000000996 additive effect Effects 0.000 description 11
- 239000004566 building material Substances 0.000 description 11
- 238000005065 mining Methods 0.000 description 11
- 239000002994 raw material Substances 0.000 description 11
- 239000011734 sodium Substances 0.000 description 11
- 239000000758 substrate Substances 0.000 description 11
- 238000012360 testing method Methods 0.000 description 11
- 239000010456 wollastonite Substances 0.000 description 11
- 229910052882 wollastonite Inorganic materials 0.000 description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 10
- WYTGDNHDOZPMIW-RCBQFDQVSA-N alstonine Natural products C1=CC2=C3C=CC=CC3=NC2=C2N1C[C@H]1[C@H](C)OC=C(C(=O)OC)[C@H]1C2 WYTGDNHDOZPMIW-RCBQFDQVSA-N 0.000 description 10
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- 238000004090 dissolution Methods 0.000 description 9
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- 229910001385 heavy metal Inorganic materials 0.000 description 9
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 9
- 150000001342 alkaline earth metals Chemical class 0.000 description 8
- 239000012633 leachable Substances 0.000 description 8
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 8
- 239000000347 magnesium hydroxide Substances 0.000 description 8
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
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- 238000004876 x-ray fluorescence Methods 0.000 description 8
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 7
- 238000005299 abrasion Methods 0.000 description 7
- 239000006227 byproduct Substances 0.000 description 7
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Inorganic materials [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 7
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- 229910052739 hydrogen Inorganic materials 0.000 description 6
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 6
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Classifications
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- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
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- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02P40/00—Technologies relating to the processing of minerals
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Landscapes
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- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
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US12/163,205 US7744761B2 (en) | 2007-06-28 | 2008-06-27 | Desalination methods and systems that include carbonate compound precipitation |
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US12187208P | 2008-12-11 | 2008-12-11 | |
PCT/US2008/088242 WO2010074686A1 (fr) | 2008-12-23 | 2008-12-23 | Système et procédé d'hydroxyde électrochimique à faible énergie |
PCT/US2008/088246 WO2010074687A1 (fr) | 2008-12-23 | 2008-12-23 | Système et procédé de transfert de protons électrochimique à faible énergie |
WOPCT/US08/088242 | 2008-12-23 | ||
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US12/344,019 | 2008-12-24 | ||
US12/344,019 US7887694B2 (en) | 2007-12-28 | 2008-12-24 | Methods of sequestering CO2 |
US14835309P | 2009-01-29 | 2009-01-29 | |
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Cited By (1)
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KR101530363B1 (ko) * | 2013-09-06 | 2015-06-22 | 주식회사 포이엔 | 이산화탄소를 함유한 경량 골재 제조 방법 및 이에 의해 제조된 경량 골재 |
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- 2009-05-29 GB GB0911440A patent/GB2461622B/en active Active
- 2009-05-29 WO PCT/US2009/045722 patent/WO2009146436A1/fr active Application Filing
- 2009-05-29 KR KR1020107027766A patent/KR20110033822A/ko not_active Application Discontinuation
- 2009-05-29 MX MX2010012947A patent/MX2010012947A/es unknown
- 2009-05-29 EP EP09716193A patent/EP2240257A1/fr not_active Ceased
- 2009-05-29 JP JP2011511869A patent/JP2011521879A/ja not_active Withdrawn
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2010
- 2010-11-16 IL IL209365A patent/IL209365A0/en unknown
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KR101530363B1 (ko) * | 2013-09-06 | 2015-06-22 | 주식회사 포이엔 | 이산화탄소를 함유한 경량 골재 제조 방법 및 이에 의해 제조된 경량 골재 |
Also Published As
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JP2011521879A (ja) | 2011-07-28 |
EP2240257A4 (fr) | 2010-10-20 |
GB2461622A (en) | 2010-01-13 |
IL209365A0 (en) | 2011-01-31 |
WO2009146436A1 (fr) | 2009-12-03 |
EP2240257A1 (fr) | 2010-10-20 |
GB2461622B (en) | 2011-04-13 |
GB0911440D0 (en) | 2009-08-12 |
MX2010012947A (es) | 2011-04-27 |
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