KR20100132813A - An alkaline electrolytic liquid washing composition - Google Patents
An alkaline electrolytic liquid washing composition Download PDFInfo
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- KR20100132813A KR20100132813A KR1020090051592A KR20090051592A KR20100132813A KR 20100132813 A KR20100132813 A KR 20100132813A KR 1020090051592 A KR1020090051592 A KR 1020090051592A KR 20090051592 A KR20090051592 A KR 20090051592A KR 20100132813 A KR20100132813 A KR 20100132813A
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- water
- alkaline electrolytic
- alkaline
- electrolytic liquid
- bacteria
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- 239000007788 liquid Substances 0.000 title abstract description 14
- 239000000203 mixture Substances 0.000 title abstract description 7
- 238000005406 washing Methods 0.000 title description 6
- 239000003513 alkali Substances 0.000 claims abstract description 22
- 239000008399 tap water Substances 0.000 claims abstract description 18
- 235000020679 tap water Nutrition 0.000 claims abstract description 18
- 238000000034 method Methods 0.000 claims abstract description 14
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims abstract description 14
- 239000002778 food additive Substances 0.000 claims abstract description 10
- 235000013373 food additive Nutrition 0.000 claims abstract description 10
- 229910000027 potassium carbonate Inorganic materials 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 78
- 239000012459 cleaning agent Substances 0.000 claims description 15
- 238000005868 electrolysis reaction Methods 0.000 abstract description 7
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- 238000012360 testing method Methods 0.000 description 23
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- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 16
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
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- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
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- 238000013112 stability test Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
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- 201000004624 Dermatitis Diseases 0.000 description 1
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Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/12—Carbonates bicarbonates
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
Description
The present invention relates to a strong alkaline electrolytic water cleaner that provides cleaning and sterilization effect with strong alkali components, and more particularly, electrolyzed pure tap water as a raw material by electrolytic method to distill water and circulate alkaline electrolytic water to pH 13.2 or higher. The present invention relates to a strong alkaline electrolytic water cleaner that can be electrolyzed and washed, sterilized, rustproof, antibacterial and deodorized.
In general, the term "cleaning" removes dirt, removes deposits, degreases and sterilizes (also known as antibacterial, bactericidal or bactericidal), removes rust and prevents rust. One or two or more concepts are included, and the cleaning liquid exhibits a good cleaning effect against various dirts. For example, it is possible to exert an excellent cleaning effect against the dirt of oil adhered to various machines and working environments (in factories, etc.).
The conventional washing process using tap water has the disadvantage of no sterilizing effect and extremely low cleaning effect. The main component is an anionic surfactant such as LAS (linear alkylbenzene sulfonate) and AOS (alpha-olefin sulfonate). In the case of dishwashing detergents which are inexpensive, they are inexpensive, but many bubbles are generated, which is not suitable for washing fruits and vegetables, and the skin adsorption properties of anionic surfactants cause skin irritation or inflammation. If surfactant component in detergent, which is the main culprit of environmental hormone, penetrates or remains on the surface of fruits or vegetables, it also ingests the surfactant, which is a harmful ingredient, when it is ingested. Microorganisms present on the surface of food It is known that it is largely inadequate as a food detergent in that it does not exist. In particular, surfactants such as ABS (sodium alkylbenzene sulfonate) have poor biodegradability in rivers, which is undesirable in terms of environment, such as their use is strictly regulated in developed countries such as Germany, the United States, and the United Kingdom.
On the other hand, the chlorine-based compound, which is a main ingredient, is listed as a food additive even in the case of Lax-type disinfectant cleaners which are frequently used for disinfecting and cleaning of kitchen utensils such as cutting boards, dishcloths and tableware. The strong and unique smell of chlorine in food residues after washing has the disadvantage of altering the taste and aroma of the food.
Microorganisms also have a limited range of optimal pH, which is good for breeding, especially under mild to moderately acidic pH to pH 4.0-6.0, but under mildly alkaline environments ranging from pH 7.0 to 9.0. In recent years, the theory that sterilization with only pH is lost due to the discovery of bacteria that survive under strong acid or strong alkali environment.
Therefore, in general alkaline ionized water of pH 7-9, the desired bactericidal effect can not be obtained even for neutral to mildly acidic or weakly alkaline general bacteria, and the sodium chloride (NaCl) compound used as an electrolyte in the production of alkaline ionized water is used. Problems such as the generation of toxic sodium hydroxide (NaOH) in the human body have been raised, and it has been known to be inappropriate for use as a sterile detergent.
In addition, conventional detergents are composed of chemical components such as surfactants to maximize the bactericidal effect in alkaline ionized water. The reality is that there is a problem of pollution.
The present invention has been made in order to solve the above problems, the purpose is to electrolyze 100% pure tap water as a superelectrolytic method as a raw material to convert the pure tap water into distilled water (RO), a strong alkaline electrolytic water of pH 13.2 or more Purified super-electrolyzed water can be used as a cleaning agent or by adding a small amount of potassium carbonate, a food additive as an alkali accelerator, to prevent water pollution and environmental pollution. It is a colorless, odorless transparent liquid. To provide an environmentally friendly strong alkaline electrolytic water cleaner.
According to a first aspect of the present invention for achieving the above object, it provides a strong alkaline electrolytic water cleaning agent composed of ultra-electrolyzed water by electrolyzing the general tap water by distillation, circulating alkaline electrolytic water until the pH 13.2 or more.
At this time, according to an additional feature of the present invention, it is preferable that the super-electrolyzed water formed by circulating the alkaline electrolyzed water contains 0.5% by weight of potassium carbonate, which is a food additive, as an alkali promoter.
According to a second aspect of the present invention for achieving the above object, general tap water is electrolyzed to distill water, to obtain alkaline electrolytic water having a pH of 13.2 or higher, and to the obtained alkaline electrolytic water as a food additive, potassium carbonate as an alkali promoter, 0.5 Provided is a method for producing a strong alkaline electrolytic water cleaner by mixing the% weight.
Strong alkali electrolytic water cleaning agent according to the present invention, unlike the general electrolysis method, distilled water and composed of strong alkaline electrolytic water of pH 13.2 or more, exhibiting strong peeling effect, dirt, pesticides, chemicals, microorganisms on the surface of the cleaning target Various contaminants can be washed more perfectly, and it is very effective in removing bacteria that cause odor, preventing oxidation of organic matter, and deodorizing.
In addition, it is a clean water composed by electrolysis with pure tap water, which is harmless to human body because no surfactants, pigments, artificial flavors and harmful chemicals are added.It does not have an unpleasant smell after deodorization, and no residue remains on the floor. It is prevented and does not pollute the environment.
In addition, the detergent of the present invention is a 99% pure water product, which is an environmentally friendly substance containing almost no harmful ingredients to the human body and the environment, and is a colorless, odorless transparent liquid with the advantage that there is no concern of environmental pollution during disposal. There is no unpleasant feeling in use, and it also has a deodorant effect, so it can be effectively used for sterilization and deodorization of kitchen utensils such as cutting boards and dishcloths.
Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings.
1 is a block diagram of a device for producing a strong alkaline electrolytic water cleaner of the present invention, Figure 2 is a state diagram of a pre-test sample of E. coli gram negative bacteria for the sterilization test of the strong alkaline electrolytic water cleaner according to the present invention, Figure 3 shows a state diagram of the sample after the test for E. coli of Gram-negative bacteria according to Figure 2, Figure 4 is a pre-experimental sample of Staphylococcus aureus that is Gram-positive bacteria for sterilization experiment of strong alkaline electrolytic water cleaning agent according to the present invention Figure 5 is a state diagram, Figure 5 shows a state diagram of the sample after the test of Staphylococcus aureus, Gram-positive bacteria according to Figure 4, Figure 6 before the experiment for the sterilization capacity test of the strong alkaline electrolytic water cleaning agent as an embodiment according to the present invention. Fig. 7 is a state diagram of the sample, and Fig. 7 is a test report showing the stability test results of the Korea Alkali Water Electrolyte Cleaning Agent of the present invention.
Referring to the accompanying drawings for the production and procedure of the strong alkali electrolytic water cleaning agent according to the present invention having the configuration as described above,
The process for producing a strong alkaline electrolytic water cleaner of the present invention is the first step to obtain an alkaline electrolytic water of pH 13.2 or more by electrolyzing with 100% pure tap water as raw material to circulate the obtained alkaline electrolytic water The second step of making super-electrolyzed water, and the third step of adding 0.5% of potassium carbonate, a food additive, as an alkali accelerator.
In performing the process of separating and obtaining alkaline electrolytic water of pH 13.2 or higher from pure tap water,
The electrolysis of such a raw material aqueous solution can be carried out, for example, by adopting the same apparatus and conditions as the electrolysis performed in the production of conventionally known electrolyzed water, but to confirm the distilled water (RO) step, A configuration for checking the concentration can be additionally configured.
That is, an electrolytic cell having a configuration in which an anode chamber having an anode (anode) and a cathode chamber having a cathode (cathode) are blocked by an ion-permeable interlayer, and raw material aqueous solution supply means for supplying a raw material solution to the anode chamber and the cathode chamber, respectively And an electrolytic device having a power supply for applying a voltage between the anode and the cathode and a takeout means for taking out the liquid in the cathode chamber to the outside.
One structural example of the electrolytic apparatus which can use pure tap water raw material aqueous solution suitably for electrolysis is shown in FIG. The electrolytic apparatus 1 includes an
Tap water introduced through the supply means 20 in accordance with the operation of the flow
First, water containing an electrolyte is supplied through the
Water introduced through the
As a result, near the
The alkaline disinfecting detergent obtained by the above manufacturing process is checked by the pH measuring means 43 to determine whether the alkali is strong or more than pH 13.2.
At this time, when the pH concentration measured by the pH measuring means 43 is pH 13.2 or less, it is introduced into the
In addition, in the case of adding calcium carbonate, which is a food additive, as an alkali promoter, it is added to the calcium
After mixing the calcium carbonate, the obtained alkaline sterilizing detergent is discharged from the
In this case, the calcium carbonate mixed in the sterilizing detergent of the present invention should be used as an alkali catalyst and use an unrestricted purity product that is used as a food additive, and should be within 0.5% by weight of the total weight of the composition.
The pH of the alkaline electrolyzed water obtained through the above electrolysis step has a strong alkali of about 13.2 or more, and has strong ionic activity.
The sterilizing detergent composition obtained through the above process is a strong alkaline solution having a pH of 13.2 or higher containing activated OH-and a large amount of mineral ions such as calcium, potassium, sodium, magnesium, and iron. Forms intermolecular attraction with various pollutants (eg, dust, pesticides, microorganisms, etc.) that have cations on the surface of them, and exhibits an interfacial effect according to the peeling phenomenon caused by the repulsive action between pollutants surrounded by anions. In addition to providing a cleaning effect, it creates a strong alkaline environment, and shows strong bactericidal and bactericidal effects against a wide range of bacteria and fungi, including E. coli, Salmonella, Enteritis Vibrio, and 0-157. And it can be usefully used for cleaning and maintaining freshness of fruits and vegetables.
In addition, the present invention by adding an additional calcium carbonate component to the composition, promotes the alkaline component to remain on the surface of the object to be washed, showing the bactericidal and bactericidal effect against bacteria that are not removed or sterilized during washing, By preventing the internal penetration of the bacteria provides a proliferation inhibitory effect.
As is generally known, many microbial species, such as E. coli and Staphylococcus aureus, are detected in the human hand. Some of these may be pathogenic bacteria that cause oral infections in humans and cause food poisoning, while others may have no effect. The method for removing such bacteria is usually carried out by autoclaving. In other words, if the normal maintained at 121 ℃ for about 15 minutes all the bacteria will be killed.
In addition, as a method of ethylene oxide gas, mainly used for sterilizing heat-resistant plastic container, or sterilization method using ultraviolet rays is also used.
That is, ultraviolet rays are generally the strongest sterilizing power at wavelengths around 260 ~ 280nm, mainly used for sterilizing the surface, such as a clean room or a sterile workbench.
In addition, another method is to use a filter, that is, to remove not only bacteria but also large particles in the liquid. In other words, if the size of bacteria is 0.2 ~ 2.0μm and passes through a medium with a smaller hole than the size of the bacteria, everything larger than the hole will be caught and only those smaller than the hole will pass.
Chlorine, CaOCl 2 , H 2 O 2 , O 3 And chemicals such as phenol and cresol, which are phenol derivatives. Chlorine compounds are used a lot of them, and ozone is widely utilized through technology development.
Although there are various methods of removing bacteria as described above, in the present invention, the strong alkali electrolytic water cleaner is distilled water, and circulates the alkali electrolytic water until pH 13.2 or more to produce super electrolytic water, thereby conveniently removing bacteria. To provide.
According to the experimental method described below, the sterilization effect of the electrolyzed water cleaner obtained by introducing pure tap water into the electrolyzer according to the configuration of the cleaner manufacturing apparatus shown in FIG. Proceed with each result of the experiment is presented in the accompanying Figures 2 to 8.
Experiment method
In order to confirm the bactericidal effect of the strong alkaline electrolytic water cleaning agent according to the present invention, after shaking shaking culture of Staphylococcus aureus and Escherichia coli in a liquid heart (Brain Heart Infusion Broth), the cultured bacteria were diluted to 1 to 9 x 10 7 It was adjusted to cfu / ml and used for the test.
20 ml of the sample (detergent: strong alkaline water stock solution) was added to the sterilized cap tube, and adjusted to 200 µl of each cultured bacterium, and the rate of reduction of the initial bacterial count was confirmed by measuring the bacterial count 5 minutes after inoculation. .
However, at this time, the initial dilution of all experiments were carried out by neutralizing with D / E Neutralizing Broth (DIFCO), and when bacteria were grown in the test medium, the number of bacteria on the medium was multiplied by the dilution factor. When the bacteria do not grow in the medium, it is expressed as less than 10 (<10) by multiplying the dilution factor made in the neutralization step.
Test result
Experimental results according to the above experimental method
[Table 1] E. coli sterilization test
(Unit: CFU / mL)
(): Reduction (%) = (A-B) / A x 100
Where A: initial bacterial count
B: Number of bacteria after a certain time
As a result of testing the sterilization ability for the strong alkaline electrolyzed water detergent, E. coli sterilization test Gram-negative bacillus E. coli after 5 minutes of contact time as shown in [Table 1] for the sterilization before and after the experiment of FIGS. It was found to be more than 99.9% bactericidal power.
[Table 2] S.aureus sterilization test
()% Reduction
In addition, the results of the sample shown in Figures 4 to 5 attached to the gram-positive bacteria Staphylococcus aureus, which is the same as the above experimental method after 5 minutes, and has a 99.9% bactericidal power as shown in Table 2 above. Appeared.
That is, the samples of FIGS. 2 to 5 have excellent germicidal power of 99.9% with respect to Gram-negative bacteria and positive bacteria, and when used for the purpose of sterilization even for 5 minutes or more, it was confirmed that there is an excellent sterilizing effect.
In addition, the strong alkali electrolytic water cleaning agent according to the present invention as a alkaline electrolytic water of pH 13.2 or more, as a result of requesting the sterilization test to the Korea Testing and Research Institute, it is effective in sterilization by removing harmful bacteria such as O-157, Salmonella bacteria within 30 seconds It was confirmed that the sample for the test strain, the results are shown in Figure 6 attached.
In addition, as a result of the safety test of the cleaning agent to the Korea Chemical Testing Institute for the strong alkali electrolytic water cleaning agent of the present invention according to the safety standard Annex 07 of the test results, as shown in FIG. Confirmed.
In addition, the results of the sample and the test results for the bactericidal power of FIGS. 2 to 5 can also be confirmed in FIG. .
The invention being thus described, it will be obvious that the same way may be varied in many ways. Such modifications are intended to be within the spirit and scope of the invention as defined by the appended claims.
1 is a block diagram of an apparatus for producing a strong alkali electrolytic water cleaner of the present invention
Figure 2 is a pre-experimental sample of E. coli Gram-negative bacteria for the sterilization test of the strong alkaline electrolytic water cleaning agent according to the present invention.
3 is a sample after the experiment for E. coli of Gram-negative bacteria according to FIG.
Figure 4 is a pre-test sample of Gram-positive Staphylococcus aureus for sterilization experiment of strong alkaline electrolytic water cleaner according to the present invention
Figure 5 is a sample after the experiment of Staphylococcus aureus, Gram-positive bacteria according to Figure 4
Figure 6 before the experiment for the sterilization capacity test of the strong alkaline electrolytic water cleaning agent as an embodiment according to the present invention. A later sample
7 is a test report of the stability test of the Korea Institute of Chemical Testing of the strong alkaline electrolytic water cleaner of the present invention
8 is another test report of the Korea Chemical Testing Institute of the strong alkali electrolytic water cleaning agent of the present invention
<Description of the symbols for the main parts of the drawings>
1
12: diaphragm 14: anode chamber
16: cathode chamber 18: electrolytic water discharge pipe
20: raw material supply means 22: tap water supply source
24: flow rate control part 26: pump
28: positive and negative chamber entrance tube 30: power
32: anode 34: cathode
40: extraction means 41: lead pipe
42
44
46: calcium carbonate storage tank 47: mixing tank
48: exit
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020090051592A KR20100132813A (en) | 2009-06-10 | 2009-06-10 | An alkaline electrolytic liquid washing composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020090051592A KR20100132813A (en) | 2009-06-10 | 2009-06-10 | An alkaline electrolytic liquid washing composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20100132813A true KR20100132813A (en) | 2010-12-20 |
Family
ID=43508364
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020090051592A KR20100132813A (en) | 2009-06-10 | 2009-06-10 | An alkaline electrolytic liquid washing composition |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR20100132813A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101471126B1 (en) * | 2013-06-21 | 2014-12-11 | 한국식품연구원 | Electrolytic water producing apparatus for providing enhanced cleaning |
| KR20210153494A (en) | 2020-06-10 | 2021-12-17 | 이래에프엔씨(주) | Sterilization, deodorization and Cleansing effect excellent Therawater Alkali ionized water composition and manufacturing method |
-
2009
- 2009-06-10 KR KR1020090051592A patent/KR20100132813A/en not_active Application Discontinuation
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101471126B1 (en) * | 2013-06-21 | 2014-12-11 | 한국식품연구원 | Electrolytic water producing apparatus for providing enhanced cleaning |
| KR20210153494A (en) | 2020-06-10 | 2021-12-17 | 이래에프엔씨(주) | Sterilization, deodorization and Cleansing effect excellent Therawater Alkali ionized water composition and manufacturing method |
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