KR20100119460A - Commodore function improves and the salt farm floor materials which is manufactured with manufacturing method and the foreign country law of the salt farm floor materials where the solid powder form uv interception system is included - Google Patents

Abstract

PURPOSE: A method for manufacturing a salt floor material which includes a UV interception material of solid power shape and improves a commodore function, and the salt floor material which is manufactured by the same are provided to enhance commodore function by using a far infrared ray and an anion emission function. CONSTITUTION: A method for manufacturing a salt floor material which includes a UV interception material of solid power shape and improves a commodore function remove or reduce the harmful components by absorbing the harmful components and continuously supplies the far infrared ray or anion. The method comprises the steps of: mixing charcoal powders with at least one material selected from polypropylene, polyethylene, polyvinylchloride, polystyrene and polyolefin; and fabricating a pellet-shaped chip by heating the mixture.

Description

Commodore function improves and the salt farm floor materials which is manufactured with manufacturing method and the foreign country law of the salt farm floor materials where the solid powder form UV interception system is included.}

1 and 2 is a manufacturing method of the salt flooring material and the manufacturing method of the salt flooring material prepared by this method to improve the detoxification function and contains a solid powder UV blocking agent.

General flooring materials currently used in salt farms or salt floorings with detoxification functions registered as utility models as of 20-0427958 on September 27, 2006 do not have UV blocking function, causing problems that cannot be used for a long time. Difficulties arise and the production cost of sun salt rises.

Continuous scraping using a rubber bar composed of heavy wood that can absorb salts for the purpose of gathering general salt-based flooring material colored with black color with good solar absorption rate can be mixed with sun-dried flooring material containing PVC and colorant. There is,

Utility Model Registered functional salt flooring material is continuously scratched using rubber ladle made of heavy wood that can absorb salts for the purpose of gathering, and fine silver nanoparticles attached to the functional salt flooring material are separated and mixed in the water of crystallized land and mixed in natural salt. In the process of deciding the natural salt and then discarding the used brine, the silver nanomixed in the brine is thrown into the sea, tidal flats or rivers, causing chemical reactions to kill bacteria or microorganisms that are beneficial to the ecosystem.

When the coal is finely pulverized to a size of 20 μm or less and mixed with plastic, the pores of the char are so fine that it is buried in the plastic and utilizes the function of the char A problem that is difficult to occur occurs, and a problem that requires more manufacturing costs occurs.

By mixing nano-sized fine charcoal with plastic, the pellet type plastic chips are made by using an extruder-type compounding machine in which the inside is kept in a vacuum state. Adsorption power, far infrared rays, negative ions are less efficient.

The present invention is a functional flooring for use in salt water by adsorbing and removing harmful components in seawater and continuously supplying far infrared rays or anions, using charcoal to poison, adsorb, neutralize, reduce, decompose and sterilize harmful substances. It can be used to improve the adsorption efficiency of, and can use natural charcoal powder without using a colorant that can act as a carcinogen,

Harmful ingredients in seawater can be removed and reduced, beneficial ingredients can be increased, and suspended solids are removed and reduced, safer, bitter taste is removed and reduced. produce natural salts with increased ph,

It is possible to produce mild and soft sun salt with a controlled taste of sodium or magnesium in brine by controlling the salinity from the evaporation site of salt farm, and also adsorb charcoal with detoxification function while minimizing the change of physical properties of the resin used. It is an invention that can improve the efficacy, and can be used for long-term salted flooring by adding a solid powder UV blocker with a high ratio of pure UV blocker without using a liquid UV blocker with a low content of pure UV blocker.

In order to produce sea salt by concentrating seawater, the temperature of seawater must be raised to high temperature. In this process, existing flooring materials with colorants etc. are eluted with various harmful substances, and heavy metals, residual pesticides, and life contained in the seawater. Chemical reactions with sewage, arsenic and chlorine can produce another toxic substance, and various toxic substances can be absorbed as they are in the natural salt process.

The higher the temperature, the higher the elution as time passes, and the serious problem that harmful substances such as dioxins are released even during the disposal and incineration process.

Continuous scratching using rubber bar composed of heavy wood that can absorb salt for the purpose of gathering general salt flooring material colored with black color with good solar absorption rate results in scratching of flooring material and harmful substances Will be eluted in, PVC, salt-containing flooring containing colorants are shaved has a problem that can be mixed in the natural salt.

"Polyvinyl chloride (PVC) is a carcinogenic component that causes birth defects and genetic modification. In addition, chemicals are used as softeners to soften the wraps. Add drugs, but if you pack a lot of fatty meat, cheese, etc., chemicals will seep into food. " And

"When you put something hot in a plastic bowl, a lot of chemical flows out, but every plastic releases it into the air, even at room temperature. The evidence is that when you open a plastic container that has a lid closed, it smells." Keep it hot, at room temperature, or constantly release harmful chemicals.

A research team at the University of Cincinnati, U.S.A., measured the concentrations of bisphenol A in children's plastic bottles, saying, "When you fill a bottle with boiling water, it's released about 55 times faster and melts into it." And

"Plastic can release harmful substances when contacted with heat, strong acids or salts, and environmental hormones can leak out when flaws occur." (Ask on July 14, kbs 2tv)

MBC 9 o'clock news on March 3, 2006, said, "Under Heidelberg University, Germany, 4-8 types of bottled water are sold in Europe. Almost no exception is found in bottled water. It is an additive material produced in natural water, but about 4 PPT is melted in natural water, but it is 3 6 0 PPT immediately after being put in PET bottle, and it is doubled to 7 0 0 PPT after 3 months. "It is said that you drink with toxic substances until you believe it."

PET bottles, which were considered to be hygienic, are composed of low-cost PVC, which can cause carcinogen bisphenol A, are in direct contact with strong salts, and the temperature continues to rise. It continues to occur, and the harmfulness of conventional salted flooring materials added with coloring agents and diHPylhexylphthalate (DEHP), which can act as carcinogens, is almost like a fire, and the salty sea salt can be concentrated in several steps. Hazardous components eluted from the vinyl flooring material, which is added to the crystallization paper, which is the final stage of the production process, and various harmful components in seawater may cause chemical reactions to produce more harmful components.

According to KBS 9 o'clock news on March 29, 2006, the KFDA tested 37 vitamin C-containing beverages sold in Korea last February, and found that benzene was detected in 36 products except one. In a survey of 10 vitamin-containing drinks, women's environmental solidarity, a civic group, found benzene in some beverages. As a result, five products detected benzene of up to 6 PB and up to 17 PB. And

Benzene is a representative carcinogen defined by the World Health Organization and the Center for International Cancer Research. Benzene-detected products were found to be a mixture of vitamin C and sodium benzoate, which is a preservative. It was not. It is inevitable that benzene is produced by chemical reaction between harmful components of vitamin C and sodium benzoate as a preservative.

Benzene, the raw material for many compounds, is used to make ethylbenzene, phenol, maleic anhydride (a raw material for plastics), aniline (a raw material for dyes), dodecylbenzene (a raw material for detergents) and chlorobenzene (a raw material for insecticides). Benzene reacts with sulfuric acid or nitric acid to form single, double and triple substituents, and with chlorine or bromine to perform substitution or addition reactions.

As a result of requesting the test from the Korea Testing and Research Institute as shown in the following [Tests and Experimental Examples] after scooping the water in the seawater tank producing sea salt, other chemicals such as phenol, chlorine, which generates toxic substances designated by the Ministry of Environment. Given the fact that harmful components have been detected, there are many possibilities for this.

At the Sun Salt Symposium, Dr. Han-Tae Seo and producers of salt salt have already pointed out and worried about the detection of environmental hormones in flooring materials used as salt flooring.

The press release on heavy metal contamination of sun salts was based on the JoongAng Ilbo dated October 11, 2000. The contents are as follows.

Detection of Lead in Domestic Processed Salt-October 11, 2000

Hazardous substances such as lead and cadmium mercury were found in processed salts sold in Korea. According to a report by the Consumer Protection Agency submitted to a member of Lee Wan-gu, a member of the National Assembly's Finance Ministry, on July 11, the Sobowon test survey in the second half of last year.

In eight of the 11 processed salts, 0.10-0.39 ppm of lead was detected, and 0.02-0.28 ppm and 0.07-0.14 ppm of lead were detected in four of the nine (secondary) salts and seven of the ten salts, respectively. Was detected

"We found cadmium (0.01-0.22ppm) in four species of lead, and mercury (0.04 ppm) in one species," Lee said. As a result of a sample survey (2 kinds) of exercise headquarters, 'potassium ferrocyanide' of cyanide, which should not be detected, was detected in 7.2ppm and 5.3ppm, respectively. As a result, it was a result of immunity to salt producers. ”In particular, since January 2002, quality inspections of salts, except by-product salts, were exempted. Threatened '

-JoongAng Ilbo October 11, 2000-

In addition, the press release on the harmful components of vinyl flooring of living room flooring, which is much more expensive than salt flooring, was referred to KBS covering file 4321, which was aired on February 2, 2006. The contents are as follows.

Glue releases deadly carcinogens to humans

Carcinogens BTX (benzene, toluene, xylene) are the most commonly found in adhesives for building materials in new houses.

The carcinogen BTX is called sick house syndrome, and it occurs about 3 to 10 years in a new house.

BTX (benzene, toluene, xylene) is often used as a solvent for adhesives. In the case of an apartment of 30 pyeong, about 100 kg of adhesive (BTX) should be poured when constructing the floor. Benzel is a representative carcinogen that is defined by the International Cancer Research Center (IARC) and the World Health Organization (WHO) as a definite carcinogen. Inhaling the bond with the nose destroys brain cells and causes them to be hallucinated. In severe cases, the destruction of NA causes leukemia and various cancer diseases.

Carcinogen Dioxins occur mainly in chemically treated kitchen furniture (sinks) and vinyl flooring. Most dioxin is attached to make the floor smooth. Therefore, heating the slate releases dioxin. Carcinogen Dioxin causes female infertility, bronchial asthma, various atopies, various cancer diseases, and adult diseases. Dioxins originate mainly from chemically processed kitchens (think units) and vinyl flooring. BTX (benzene, toluene, xylene) and dioxin are heavier than oxygen, so they are deadly when you lie down and sleep.

Eco-friendly adhesive, harmful ingredients

Adhesive required to floor the apartment is 4 kilograms per square foot. In the case of a 30-pyeong apartment, "A lot of 100 kg of adhesive must be poured out." Many of the adhesives with eco-labels have been detected as harmful to the human body, such as benzene and toluene. Some contractors also turned out to be oil-based adhesives, unlike ads

(KBS Report File 4321 2006.1.22.)

Tap, please feel free to use.

The Waterworks Headquarters launched an active public relations campaign to relieve the common sense and distrust of tap water held by some citizens. In the meantime, the complaints from restaurants in each region, saying, “The smell of tap water can't be eaten” continues to carry out such activities.

Arisu (tap water) is clean and safe water that has been inspected for 55 items of 'water quality standards' set by the Ministry of Environment and 90 items to meet WHO (World Health Organization) standards.

The reason why the food smells disgusting when cooked in a restaurant is because of the rubber lakes commonly used in restaurants. This is because the chlorine component dissolved in Arisu (tap water) and the plasticizer added when preparing the rubber hose react to dissolve substances such as phenol that are harmful to the human body in Arisu (tap water).

The disinfecting ingredients dissolved in Arisu (tap water) are used to protect the health of citizens from pathogenic microorganisms. They smell slightly chemical but are harmless to the human body and boil over time or disappear on their own. On the other hand, phenol and other substances that are dissolved in the rubber hose is not only harmful to the human body but also decomposes over time and is mixed with food or Arisu (tap water) to cause disgusting smell.

The Waterworks Division strongly recommends the use of rubber hoses or stainless steel corrugated tubes that have been inspected by the Food and Drug Administration to prevent this.

Gangnam Waterworks Customer Support Division Eun Young Park 3497-0866 ｜ 2006/05/04

According to the Food and Beverage News on March 30, 2009

According to the results of the safety testing of 2 types of salt plate products and 5 types of sun salt products from August 2012 through December 2012, the consumption of DEHP contained 8.2 to 10.7%. It was about 0.28 to 0.57 mg / kg.

At the time, the Consumer Source concluded that measures such as TDI (Daily Intake Allowance) standards are not enough to harm the human body, but they require measures such as strengthening the production facility standards as there is a possibility of contamination due to flooring.

The DEHP threshold for sun salt is not defined. In this regard, the Consumer Source pointed out that measures such as the establishment of standards for securing the safety of domestic sun salt are necessary. ”

According to a survey released by the KFDA in September last year, the amount of phthalate, DEHP, is known to be the main culprit of environmental hormones in PVC sap bags in actual storage of 0.012 ~ 0.035ppm. This is 11 times higher than the 3.19ppb content of DEHP containing drinking spring water, which was revealed by the National Institute of Environmental Research.

In July 2003, the Tsu City Council (Citizens' Movement Council to Resolve Garbage Problems) collected five PVC ringer bags and two NON-PVC ringer bags produced by three domestic companies and commissioned a test from the Korea Chemical Testing Institute. Only 180,000 ppm of DEHP (di-ethylhexylphthalate) was detected in PVC ringer bags.

These results indicate that DEHP, a well-known environmental hormone, is very harmful to the human body, is contained in a large amount of PVC sap bags, and there is a high possibility of DEHP flowing directly into the patient's blood vessels during the sap through Ringer's solution.

While the harmfulness and potential for additive leaching of PVC sap bags used for the treatment of patients are constantly being pointed out, the KFDA recently carried out DEHP when conducting medical procedures with high potential risks of DEHP exposure. It was also recommended to consider measures to minimize the use of PVC products.

However, a survey of the use of PVC sap bags at major hospitals in Korea by the Seoul Environmental Coalition's Bug Eater Apple Team showed that PVC sap bags are still used in major hospitals in Korea.

PVC sap bag and DEHP (phthalate)

The controversial PVC sap bag is very soft to the touch. This is because DEHP (phthalate) is added to PVC (polyvinyl chloride), which is generally known as plastic, to increase the ductility of materials.

Unlike glass bottles, they are widely used in medical devices such as sap bags and blood bags because they are less flexible and flexible. However, this soft PVC often uses heavy metal materials such as plasticizer DEHP, oxidative stabilizer, lead and cadmium to improve processability, and also has serious problems of releasing harmful substances such as dioxins during incineration. It is becoming.

Because DEHP is fat-soluble, there is research showing that it dissolves more in dialysis tubes containing blood than in saline. The higher the temperature, the higher the elution with time.

Harmful of lumpy PVC

Since its introduction in 1971, PVC sap bags containing DEHP have been constantly researched and debated.

In December 2002, Harvard University researchers found that DEHP is harmful to humans, including hampering male sperm count and motility.

Also, in 2001, the Swedish National Chemical Laboratory said that DEHP is "relevant to humans for its effects on testes, fertility and growth observed in other animal species." I said. The International Wildlife Protection Agency (WWF) has already defined it as a highly reproductive toxic secretory disturbance (environmental hormone).

However, charcoal never causes chemical reactions. Instead, it can absorb and neutralize harmful components such as chlorine, chlorine oxide, nitrogen oxide, and heavy metals that cause chemical reactions. Even though the charcoal powder comes out of the salted flooring material and is mixed into the natural salt and absorbed by the human body, there is no harm to the human body.

Charcoal is recognized in Korea as Medicinal Charcoal, Medicinal Charcoal in the US, Pharmacological Charcoal in the US Pharmacopoeia, and Medicinal Charcoal in Japanese Pharmacopoeia, the US. The FDA is also safe enough to recognize charcoal as a health food.

In order to solve the above problems, when producing natural salts by laying salts such as banban, jade, and germanium, which are far-infrared rays, to produce salt salts, it is not easy to adjust the height and height in the case of salt salt with a flat bottom. There is a shortage of shortages, and the gemstones must be cut again. In the case of very thin-walled vinyl flooring materials, and other gemstones, the thick-walled thickness causes problems that can be used only in the summer when the sunlight is very intense.

In addition, after the natural salt was completed, the person climbed on the gemstone and the stone was broken during the collection work, and the broken fragments were mixed in the natural salt, and the water rose between the gap between the gemstone and the gemstone to make the color of the natural salt even worse. There was also a problem making.

The production of sun salt by salting expensive charcoal tiles with charcoal powder compressed at high temperatures requires a lot of charcoal purchasing costs and a long time compression molding process at high temperatures. Although it takes tiles and sells more than 1,000 won per piece, it is desperately necessary for the health of the people, but the producers of small sea salts who pursue profits were not able to accept them in reality. The problem is that it takes longer than the natural salt production time of light but very thin thick vinyl flooring.

Similarly to the present invention, if the patent and utility model is filed as a utility model registered as a utility model registered 20-0427958 dated September 27, 2006, but the size of the charcoal constituting the flooring material mixed with plastics by grinding Because the pores of charcoal are so fine that they are buried in plastic, making it difficult to utilize the function of charcoal. However, the present application does not make the pores of char in nano state, but maintains the mesh state with a larger pore size than nano pores. The difference is that the larger size means better adsorption of harmful components.

When the char is finely pulverized to a nano size of 20 μm or less, the char particles become so fine that the adsorption rate is lower than that of the mesh (MESH) state, and the manufacturing cost is more expensive. Is made of pellet-type plastic chips using an extruder-type compounding machine in which the inside is kept in a vacuum state and extrudes the flooring material using the extruder-type compounding machine. The problem of far lower than the mesh (MESH) state occurred, but the adsorption rate can be increased by using a method of pulverizing the char in the mesh (MESH) state.

The present invention eliminates and reduces harmful substances by using a solid powder UV blocker having a high ratio of pure UV blockers without using a liquid UV blocker having a low content of charcoal and a pure UV blocker on plastics having relatively simple injection molding and low manufacturing cost. In addition, the beneficial ingredients are further increased, maintaining the salt production time as conventional flooring and providing a long-lasting salt flooring.

Harmful substances in sea water can be removed and reduced, beneficial ingredients can be increased, and suspended solids are removed and reduced, safer, bitter taste is removed and reduced, and turbidity is clean, healthy and beneficial to humans. It is possible to produce sun salt or functional sun salt with increased ph, ph and the like.

The only way to give black color of salt flooring material with natural materials without using coloring agent that can act as carcinogen is to use charcoal powder.

Charcoal is a hydrophilic material with a low apparent specific gravity and a porous structure inside, but synthetic resin (plastic) is a hydrophobic material having a high specific gravity and a high viscosity in a molten state, so the compatibility of charcoal and synthetic resin (plastic) is not very good.

Therefore, by simply mixing the two materials such as charcoal and synthetic resin (plastic), the charcoal powder cannot be uniformly dispersed in the synthetic resin (plastic). In other words, when the flooring is molded using synthetic resin (plastic), which is not uniformly dispersed in charcoal powder, the flowability of the molten resin is reduced during the molding, and the charcoal powder is concentrated in a specific area, which may cause deterioration and poor quality of the flooring. do

In addition, the char is released from the pores of the char due to the temperature rise in the process of forming a large number of pores formed inside and mixed with the synthetic resin (plastic), when the size of the charcoal powder particles more than a certain amount of air is released. It may cause defects such as pores and pinholes during molding.

Therefore, in manufacturing a charcoal-containing synthetic resin (plastic) flooring, using a fine charcoal powder having a particle size of less than a certain size, and using an extruder-type compounding machine in which the synthetic resin (plastic) and charcoal powder are kept in a vacuum state To make pellets (plastic) chips of pellet type and to form the flooring material using this chip as raw material or masterbatch to remove pores, pinholes and coal agglomeration which may occur during molding process. It is possible to manufacture a high quality synthetic resin (plastic) flooring having a function of.

Charcoal-added synthetic resin (plastic), a raw material for the production of functional flooring, dissolves or elutes harmful substances in 65.5 degrees salt water, sugar water, oil, xylene solubles, heptane extractables, and nucleic acid extracts. It is very safe to be certified as FDA's proper material through FDA testing.

On the contrary, charcoal powder adsorbs harmful ingredients generated in the contents of plastics and plasticizers, traps them in broad micropores, neutralizes them, and neutralizes them, while it does not absorb beneficial ingredients such as calcium and potassium. .

"The energy that causes the reaction can be obtained not only by heat but also by light. Ultraviolet rays with wavelengths below 3400 를 have enough energy to decompose molecules. Plastics are decomposed by about 3000 to 3400 의 of sunlight. It causes discoloration and crumbs. "

"The first thing that causes plastics to age is due to the sun's ultraviolet rays, which are absorbed by the ozone layer and the atmosphere until they reach the surface."

At present, the salt floors laid on the crystallization sites of saltfields are laid on the crystallization grounds until late autumn, winter and early spring, when they cannot make natural salt crystals. UV protection is urgent,

Currently, general floor materials used in salt or utility models registered functional salt floors do not have a UV blocking function, so there is a problem that can not be used for a long time, economical difficulties to replace the salt floors from time to time.

Continue scraping with a rubber bar composed of heavy wood that can absorb salts for the purpose of gathering general salt-based flooring which is colored with black color with good solar absorption rate, and the salt-based flooring containing PVC is shaved and mixed in natural salt. Can,

Utility Model Registered functional salt flooring material is continuously scratched using rubber ladle made of heavy wood that can absorb salts for the purpose of gathering, and fine silver nanoparticles attached to the functional salt flooring material are separated and mixed in the water of crystallized land and mixed in natural salt. In the process of deciding the natural salt and then discarding the used water, silver nano mixed in the water can be thrown into the sea, tidal flats or rivers, causing chemical reactions to kill bacteria and microorganisms that are beneficial to the ecosystem.

The harmful components can be absorbed and neutralized, but the beneficial components are not adsorbed, the minerals are increased, and the charcoal powder that does not react with chemicals without leaving secondary pollutants can be mixed with plastic to produce salt floors.

Charcoal is recognized in Korea as Medicinal Charcoal, Medicinal Charcoal in the US, Pharmacological Charcoal in the US Pharmacopoeia, and Medicinal Charcoal in Japanese Pharmacopoeia, the US. The FDA is also safe enough to recognize charcoal as a health food.

Adsorbs and neutralizes harmful ingredients, but does not absorb beneficial ingredients, increases minerals, and uses charcoal powder that does not leave secondary pollutants, but liquid UV with less charcoal powder and pure UV blocker. Solid powder type UV blocker with a high ratio of pure UV blocking material without using a blocking agent, and a pellet having a UV ray blocking property by mixing a predetermined weight with plastic and heating and kneading in an extruder-type compounding machine in which the inside is kept in a vacuum state It relates to a method of extrusion molding chips. By extruding such pellet-type chips in an extruder, it is possible to produce a functional salt flooring material having excellent physical and chemical properties as well as UV blocking properties.

The solid powder UV blocking agent used in the present invention is a substance obtained by dispersing benzotriazole in solid paraffin wax and adding other processing aids. In addition to benzotriazole, benzoxazinone may also be used. In addition, the amount of UV blocking agent used is 0.1 to 0.4% by weight with respect to the total resin is appropriate, if less than 0.1% by weight can not exhibit the UV blocking effect, 0.4% by weight or more is not preferable in terms of cost compared to the effect. In addition, the content of the pure UV blocker is suitable for 60 to 90% by weight compared to the UV blocker, when 60% by weight or less can not expect the desired UV blocking effect, when 90% by weight or more has a disadvantage in the dispersion effect in paraffin wax.

In the case of using a liquid UV blocker with a low content of pure UV blocker First, the net UV blocker content is composed of 60% or less, so that the input content must be higher than that of the ball batch to obtain the desired UV blocking performance. Second, since the plasticizing effect is severe and its content is higher than 10%, the product value is lost by causing physical property degradation by pyrolysis and hydrolysis in the injection molding process. Third, handling and transportation storage is not easy. Will cause problems.

Hereinafter, with reference to the accompanying drawings to improve the detoxification function of the present invention and a salt-based flooring material containing a solid powder UV blocking agent and a salt-based flooring prepared by this method as follows.

Figure 1 and Figure 2 is a manufacturing method of improving the detoxification function and a salt-floor flooring material containing a solid powder UV blocker and a manufacturing process chart of the salt flooring prepared by this method.

As shown in the figure

Adsorbs and removes harmful ingredients in sea water, continuously supplies far infrared rays or anions, and charcoal powder that poisons, adsorbs, neutralizes, reduces, decomposes and sterilizes harmful substances in 1 ~ 400 mesh (MESH) particle size. 60 to 40% by weight and at least one selected from polypropylene, polyethylene, polyvinyl chloride, polystyrene, polyolefin, polyester, melamine, polycarbonate, acrylonitrile styrene and acrylonitrile butadiene styrene, which are plastic raw materials. It is mixed by 99.5% by weight and heated and kneaded in an extruder-type compounding machine in which the inside is kept in a vacuum state to produce chips in pellet form, and the chips are produced by extrusion molding using the raw materials or masterbatch. .

In this way, it is possible to produce salt-based flooring material having detoxification function while minimizing the change of physical properties of the resin, and to improve the adsorption function by using charcoal powder which has improved the adsorption efficiency of charcoal, and can act as a carcinogen. You can use natural charcoal powder without using colorant.

Adsorbs and removes harmful components in seawater, continuously supplies far infrared rays or anions, and charcoal powders that poison, adsorb, neutralize, reduce, decompose and disinfect harmful substances into 1 ~ 400 mesh (MESH) particle size. 0.5 to 40% by weight and solid powder UV blocker up to 0.1 to 20% by weight of polypropylene, polyethylene, polyvinylchloride, polystyrene, polyolefin, polyester, melamine, polycarbonate, acrylonitrile styrene, acryl It is mixed with 40 to 99.4% by weight of at least one selected nitrile butadiene styrene and heated and kneaded in an extruder-type compounding machine in which the inside is kept in a vacuum state to form chips in pellet form, and the chips are prepared as raw materials or masterbatches. It produced by the method of extrusion molding as it is characterized by the above-mentioned.

In this way, it is possible to produce salt-based flooring material having detoxification function while minimizing the change of physical properties of the resin, and to improve the adsorption function by using charcoal powder which has improved the adsorption efficiency of charcoal, and can act as a carcinogen. You can use natural charcoal powder without using colorant,

By using a solid-type UV blocker with a high ratio of pure UV blockers without using a liquid UV blocker having a low content of pure UV blockers, the ratio of pure UV blockers can be characterized by a higher ratio of pure UV blockers, and is easier to handle and transport than a liquid. It is easy to store and can produce salt flooring with high UV protection.

Pure UV blocking agent of the UV blocker is benzotriazole or benzozazinone, the content is characterized in that 60 to 90% by weight relative to the total UV blocker.

Here, the charcoal powder can be used without any oak, bamboo, palm trees known to those skilled in the art,

The plastic raw material is not limited to the above materials, and all known to those skilled in the art can be used.

The UV blocker is preferably maintained at 0.1 to 0.4% by weight relative to the total resin, the pure UV blocker of the UV blockers used is benzotriazole or benzozazinone, the content of which is 60 to 90% by weight of the total UV blocker More preferred.

The UV blocking agent can be used as long as it is known to those skilled in the art, it is preferable to use a UV blocker or titanium dioxide in the form of a solid powder (ball tvpe).

The method of including the UV blocker in a salt-free plate may include the UV blocker during manufacture of the plate or coat the finished sheet with a UV blocker, but any method known to those skilled in the art is not limited to the above method. It is possible.

Chlorine or chlorine oxides, suspended solids that cause heavy metals, residual pesticides, antibiotics, preservatives, colorants, growth accelerators, sewage, E. coli, dioxin, etc. The taste of charcoal is changed by the charcoal adsorption function that adsorbs harmful components such as carcinogen trihalomethane, and the continuous detoxification, adsorption, neutralization, reduction, sterilization and decomposition of charcoal and the release of far infrared rays and anions. Can give,

The beneficial ingredients such as calcium, potassium, ph, etc., which are beneficial to the human body, are not only adsorbed, but the beneficial ingredients can be further increased due to the release of various minerals contained in charcoal, and have an anti-toxic effect and excellent UV blocking effect.

The bitter taste is removed and reduced, so that the taste is mild and soft, and the suspended solids are removed and reduced, and the turbidity can be produced with natural salts with increased calcium, potassium, ph, etc. Solar salt can be produced in evaporation of salt fields.

[Tests and Experimental Examples] According to the 2nd and 3rd test results of the Korea Testing Institute, charcoal is soaked to reduce and eliminate various harmful components in the water, while the beneficial components are not reduced. When comparing the second test result with 60 minutes of charcoal and the third test result with 4 days of charcoal, the third test result with 4 days of charcoal, the amount of minerals released in the charcoal is much higher, and the taste is more mild. The change was smooth.

Charcoal-added synthetic resins (Plastic) have been tested by FDA's tests that no harmful substances are dissolved or eluted in 65.5 degrees of salt water, sugar water, oil, xylene solubles, heptane extracts, and nucleic acid extracts. It is very safe to be certified as FDA proper material,

On the contrary, charcoal powder adsorbs harmful ingredients generated in the contents of plastics and plasticizers, traps them in broad micropores, neutralizes them, and neutralizes them, while it does not absorb beneficial ingredients such as calcium and potassium. .

In particular, sun-dried salt produced in summer tended to be the most favored by housewives because it had little bitter taste, but it can remove and reduce the bitter taste as charcoal controls sodium and magnesium regardless of season at any time.

The reason why we should eat sun salt rather than processed white refined salt

"White refined salt concentrates salty salt of salty salt, which is the main component of salt, up to 99.8%, and other components are almost completely removed in the process of purification. It's going to stick together things like calcium and magnesium, and it is discharged out of the body.So our body lacks calcium, magnesium and other ingredients, causing various diseases, lacking calcium, and not being absorbed by the body "Sodium alone is the worst poison that kills our body."

"Ingestion of natural salt means that gastric hydrochloric acid, which is the main ingredient of gastric juice, is active by combining various ingredients contained in it, so that gastrointestinal function is weakened due to the toxicity of sodium alone. Weakness in function makes it difficult to digest what we eat. "

"Also, red blood cells are made by iron, and iron is digested by gastric hydrochloric acid to make red blood cells. But gastric hydrochloric acid, which is weakened by the toxicity of sodium in white tablets, can't digest iron. Red blood cells supply 60 trillion cells of nutrients and oxygen and drive waste out of the body, so anemia can kill a person. "

Charcoal absorbs and neutralizes harmful components such as heavy metals and residual pesticides, while not only adsorbing beneficial ingredients such as calcium and potassium, but also increases the beneficial components by releasing various minerals in charcoal. There is an advantage.

For the charcoal data, reference is made to related literature and test data. The contents are as follows.

"Charcoal powder is a small cube of tiny particles, and when viewed under a microscope, the role of pores, many microscopic pores, is indigestible and adsorbs protein debris and fat grains that decay in the gut and remain in vegetables and fruits. Adsorption of pesticides and heavy metals that can be used Removes pigments or food additives that improve the color of food, and cleans the intestines by adsorbing artificial seasonings, etc. As a result, blood and body fluids in blood vessels are clean, For example, one unit of powdered charcoal can absorb up to 80 units of ammonia gas, which is quickly absorbed and discharged by the charcoal before the intestinal toxic gas is absorbed into the blood. Home Remedies P.143

The main characteristics of charcoal powder is that it quickly absorbs toxic and impurities in the body within one minute after eating, and charcoal absorbs various foreign substances such as pesticides and carcinogens despite the action of digestive fluid in the body. It has been reported (Cooney, David O. Actovated Charcoal. New York: 1980 p. 33).

Charcoal powder has not been shown to cause any harm to our bodies even when taken, but it has been reported to absorb benzopyrene, a carcinogen (AMA Archives of Industrial Health 18: 511-520, Dec. 1958)

Charcoal powder is bad for our bodies and absorbs harmful toxic ingredients, but it does not absorb any nutrients that are beneficial to our bodies. The rats were divided into two groups, one for charcoal and food, and the other for six months with the same food. No significant differences in weight or body were found, and charcoal did not absorb nutrients. de la Society de Chime Biologique 27; 513-518, Oct.-Dec. 1945)

About the Effects and Benefits of Charcoal In his book, Activated Charcoal by Dr. David Coony, charcoal (an activated charcoal) has analgesic, antipyretic, nicotine removal of pollutant tobacco, automobile exhaust (benzapyrin), and pesticide (parazzion) removal. It is said to be effective in treating gastritis, gastric ulcers, hepatitis and prevention of hepatitis.

"The adsorption of charcoal without harmful ingredients is explained by its superior adsorption rather than by special drugs, and the charcoal has a very large number of pores formed in the manufacturing process and has a large surface area. The pores vary in size, which provides a place for the adsorption and bonding of the various substances in the liquid state, which makes the charcoal adsorbable and the surface area of the charcoal is unbelievably large. If you break it very finely, the total surface area of all particles is about 400 to 1800 square meters, which is hard to imagine, and this large area provides a place to combine with all kinds of materials.

These small pores of charcoal vary in size and shape.The chemical properties of the inner surface formed when the char is activated is the principle of attracting any molecules that can fill the micropores in a liquid state. As it adsorbs the material having the same molecular weight as each hole, the more holes of various sizes can have various adsorption properties. "

"These micropores absorb odors, trap harmful bacteria, eliminate odors by suppressing decayed bacteria, adsorb decayed proteins, fat residues and decay gases in the intestines, On the other hand, there are no side effects when using charcoal, because the same molecular weight material is adsorbed in the pores of charcoal, and when it is put back into pure water, the two substances that are combined are separated from each other. "There are fewer side effects, because they do not combine with other substances into third substances, but rather remain bound and then separate when the situation changes."

"The charcoal sucks almost everything. The absorption of the charcoal comes from the surface of the fine particles. The surface area of the fine particles in 1 gram of char is calculated to be 400-1800 square meters! The surface area is such an unimaginable area that the very finely activated activated particles are so small that there are about 50 million particles in one pound of charcoal powder! I can explain some of the strong absorption. "

"A quick look at the absorption power of charcoal powder: 1/4 teaspoon of charcoal powder can absorb 1800mg of mercury chloride, 950mg of nitrate strikinin, 800mg of morphine, 700mg of nicotine, 400mg of phenol, 300mg of alcohol, 35mg of potassium cyanide Has absorbency. "

"Another component of the effect of charcoal is minerals, which have long been absorbed from the ground by the trees, so they do not burn out and remain in the charcoal. The minerals in the charcoal are primarily potassium and calcium, the main components of the charcoal. Phosphorus carbon collects and accumulates and maintains electrical energy, giving away its own electrons to others to prevent oxidation, so the objects near the char will not be damaged, and it will not be sour when the char is put in kimchi. "

Far-infrared rays emitted from charcoal make the molecular structure of water fine, improve the penetration of water into the body, increase the amount of dissolved oxygen, melt minerals in charcoal to make mineral water broth, make the best taste, and change it softly and softly. Charcoal has the effect of neutralizing acidified substances and foods, so it inhibits deterioration by alkalizing action of charcoal, makes broth into alkaline water beneficial to human body, promotes blood circulation, neutralizes toxins in body and skin, and recovers fatigue And various skin diseases can be improved, and body fluids and blood in the body can also be kept fresh.

The beneficial ingredients are not used to maintain freshness for a long time with an anion release effect, and they are used for filters of gas masks and water purifiers that block harmful gases that suffocate and kill people at once due to the excellent adsorption of harmful components. It is excellent in its ability to remove and reduce odors, release of charcoal semi-permanent anions and far-infrared rays, and detoxification, adsorption, neutralization, reduction, sterilization and decomposition to remove and reduce the various harmful ingredients. have.

"Charcoal is porous and has excellent adsorption. It has a long history of medicinal and therapeutic effects because of its adsorption. Our ancestors have long had diarrhea, indigestion, dysentery and enteritis under the pot. I have been taking soot and various wood charcoal powders as medicine, and this has led to conventional folk remedies, and is also used as a herbal remedy. "

"There are many experimental and clinical results that charcoal has medically analgesic, antipyretic, detoxification, pollutant and pesticide removal effects."

"In Korea, medicinal products are recognized as medicinal charcoal, medicinal charcoal in the US, medicinal charcoal in the US pharmacopoeia, and medicinal charcoal in the Japanese pharmaceutical visit. And FDA recognizes charcoal as a health food. "

"In one study, a mixture of aspirin and charcoal powder was taken up to about 99.6% of aspirin in the gastrointestinal tract."

"As a natural material, no deodorizing effect is as good as char."

"Charcoal has the effect of neutralizing acidified substances or foods and neutralizing them."

The beneficial ingredients are not adsorbed, but rather, the beneficial ingredients such as calcium, potassium, and PH are further increased, and the anion releasing effect maintains freshness for a long time, and the deodorizing effect is also excellent to remove and reduce odor. Charcoal does not act on chemical reactions and does not absorb nutrients in the body that are beneficial to the human body, and concentrates on carcinogens and bacteria.

All this is possible: "Charcoal has countless microscopic holes, which are the channels through which the tree carries nutrients and water absorbed from the roots, and these channels are open without any obstruction." 1 g of charcoal is 400 to 1800 m 2, and these micropores absorb odors, trap harmful bacteria, or eliminate odors by inhibiting decayed bacteria. Is promoted.

Professor Lee Kyung-soon (51. female) of Samyok University, who received his Ph.D. in charcoal research, explains the efficacy of charcoal, saying, "There is no drug that exceeds charcoal as an antidote."

Test and Experiment Example

[1st test result]

In order to investigate the various toxic components in seawater in the seawater tank producing sea salt and to examine the detoxification effects at each stage, request the test to the Korea Chemical Testing Institute three times using ozone and charcoal. Test results were obtained and the removal and reduction of toxic components was confirmed.

Primary targets: PH, mercury, phenol, lead, cadmium, hexavalent chromium, suspended solids, sodium, chlorine, turbidity

[Table 1] First Test Results Aug. 07, 2002 Korea Chemical Testing Institute Unit: mg / L, NTU

The test method was divided into seawater and (A) 30 minutes of ozone detoxified seawater (B), and as a result of the experiment, even if only 30 minutes of ozone detoxification of harmful substances in the seawater, the Ministry of Environment Phenol, which is the subject of intensive control, has been completely removed from certain water harmful substances, and it is cleaner due to the reduction of suspended substances, turbidity and chlorine, and PH is the only function used in the first detoxification process in a short time of 30 minutes. It was found that it was not increased, and furthermore, it was able to remove and reduce the toxic substances but not increase the beneficial components and, in part, the difference in the test method, but showed a reverse reaction of increasing lead component.

As a countermeasure, a second test was conducted to add the detoxification process and time to the above test method to confirm that the removal of toxic components in the sea water and the increase of beneficial components and the temporary increase in toxic components were not maintained.

Secondary targets: calcium, potassium, magnesium, PH, lead, arsenic, phenol, PCB

[Second Test Result] Korea Chemical Testing Institute, Aug. 29, 2002 Unit: mg / L

In the second test, seawater (A) and ozone treatment period were increased from 30 minutes to 60 minutes, and (B) two hours after ozone treatment, the water was distilled into charcoal for 60 minutes, and then treated with ozone. Numerical results showed that (B) the soaking of charcoal increased the (C) beneficial ingredient more than one case, and calcium, potassium, and magnesium all increased the beneficial ingredient in the second test result than the first test result. If the detoxification time is extended, it is possible to reduce and remove suspended solids, chlorine, and turbidity in the first test, and heavy metals can be adsorbed regardless of the type to remove and reduce toxic substances. It was confirmed by the above test result that the component became increased seawater.

Deodorization effect on the existing charcoal and heavy metal adsorption test results of the Korea Institute of Construction Materials Test Deodorization effect 51 ~ 57% after 30 minutes, 67 ~ 70% after 60 minutes, 70 ~ 74% after 90 minutes After 120 minutes, 70-77% of the metals were removed, and in the case of heavy metal adsorption, after 24 hours, lead was 78-82%, zinc was 23-47%, iron was 34-42%, and copper 92%. Even if it was found that the effect of adsorption of heavy metals on charcoal should be considered to be proportional to time regardless of the type.

It is believed that the change of new charcoal can increase the adsorption effect of heavy metals and shorten the detoxification time. By dipping charcoal during the detoxification process, it was found that beneficial ingredients continued to increase and harmful ingredients decreased.

This will also increase and decrease even more if the detoxification time is extended, and it will increase even more than the potassium in seawater, and considering that the charcoal life is semi-permanent, it also contains other beneficial ingredients such as calcium, magnesium and PH. It will continue to increase in proportion to the number of replacements, and on the contrary, it is thought that the toxic components will decrease regardless of the type, and thus, the third test was performed with the addition of more time to the same test method.

Tertiary object: calcium, potassium, magnesium, PH, suspended solids, turbidity, chlorine

[Third Test Result] E: 4 days 2002.09.09 Korea Research Institute for Chemical Testing Unit: mg / L, NTU (turbidity)

In the third test, the sea water was detoxified with ozone for 60 minutes, and after 2 hours, the charcoal was soaked.

Soak the charcoal in salt water for 4 days and compare it with the salt water (A) and salt water (E) soaked in charcoal for 4 days in Korea Chemical Testing and Research Institute as shown in the 2nd and 3rd test data below. As a result, the beneficial ingredient calcium increased 28%, potassium increased 31%, magnesium increased 26%, and PH, which was little increased even during ozone treatment, increased 21%. The test showed that 77% of suspended solids, 81% of turbidity, and 77% of chlorine, the source of dioxins, were reduced. Elimination, on the other hand, the beneficial components, etc. were confirmed to be excellent in further increasing the function.

The results of the 3rd test and the 3 test results so far are as above.In conclusion, it is more efficient to soak the char than ozone treatment, and the char is proportional to the soak time and the number of replacements. The numbers clearly showed that beneficial ingredients continued to increase and harmful components continued to decrease.

Considering the nature of the torsion, the charcoal can be soaked for a date longer than the test date of 4 days, and if the number of charcoal replacements is increased, the charcoal will increase and be removed even more than the test results.

By dipping charcoal as shown in the test data, various harmful ingredients in water are reduced and removed regardless of the kind, while the beneficial ingredients are not reduced, and the minerals in the char are melted to increase the beneficial ingredients. Various heavy metals block in advance the binding of harmful compounds such as chlorine compounds, benzene nuclei, benzene chloride, dioxins, PCBs, dibenzofuran, etc., which are catalysts of dioxins, which are generated during oxidation and bonding processes. Chlorine, which is the source of the chlorine, is removed in advance to neutralize dioxin.

"Dioxins are compounds that have a lot of chlorine, two benzene nuclei, and two oxygen. There are 75 types of chlorine, depending on the position of chlorine bonds. When two oxygens combine with benzene chloride, it becomes dioxin, and when two benzene chlorides combine, it becomes PCB, and when oxygen combines with it, it becomes dibenzofuran, commonly referred to as dioxins and dioxins. , "

"The production of dioxin requires three elements: organic materials, chlorine-containing materials, and environments where they can react with one another. Among them, organic materials are everywhere, and the reaction environment is common," The production of dioxins is inevitable because of the enormous amounts of primary and tertiary data from the test results, but the precaution is to remove (neutralize) and reduce the initial source of chlorine.

In conclusion, dioxins do not form harmful chlorine compounds without chlorine or one of the harmful compounds. Benzene nuclei cannot be formed even if they are oxidized or bonded, and they cannot bind without chlorine. It is known that the production of dioxins is possible by the presence of chlorine, just as it is not possible to produce dioxins.

About 50% of the charcoal produced in our country is used for filtration of tap water. Currently, domestic water purifiers use charcoal, which is called activated carbon, and incinerators and factories use charcoal or platinum catalysts. It has been used in gas masks, water purification plants, tobacco filters, deodorants in refrigerators, textiles, air purification and beverages. This is because the charcoal is versatile because of the adsorption power of charcoal alone, and because the fine pores in the charcoal burning process extract the bad substances without absorbing any nutrients that are beneficial to the human body.

The sample manufactured by our patented method was tested by ANRESCO according to the standards set by the Korea Food and Drug Administration. As a result, the salt water, sugar water, oil, xylene solubles, heptane extractables and nucleic acid (Hexane Extractables) of 65.5 degrees It was confirmed that no harmful substances were eluted at all.

Comparative incineration test of functional salt flooring containing charcoal and general salt flooring

Purpose: What is the difference between the functional salt flooring material containing charcoal powder and the general salt flooring material?

Experimental method: The charcoal powder containing functional salt flooring and general salt flooring used in the salt field were burned and observed.

What I found out: The flooring material for general salt smokes a lot of black smoke, and when I burn the waste vinyl, I have a bad toxic smell.

What we found out: The functional salt flooring material containing charcoal powder was markedly smoke-free and odorless.

CONCLUSIONS: The use of charcoal-based functional salt flooring for salt can produce cleaner and hygienic salts than the salt produced in conventional salt-based flooring.

Claims (3)

Adsorbs and removes harmful ingredients in sea water, continuously supplies far infrared rays or anions, and charcoal powder that poisons, adsorbs, neutralizes, reduces, decomposes and sterilizes harmful substances in 1 ~ 400 mesh (MESH) particle size. 60 to 40% by weight and at least one selected from polypropylene, polyethylene, polyvinyl chloride, polystyrene, polyolefin, polyester, melamine, polycarbonate, acrylonitrile styrene and acrylonitrile butadiene styrene, which are plastic raw materials. It is produced by a method of mixing by mixing in 99.5% by weight and heat-kneading in an extruder-type compounding machine in which the inside is maintained in a vacuum state to form pellet chips, which are extruded using the raw material or masterbatch. Improvement of Detoxification Function and Preparation of Salted Flooring with Solid Powder UV Blocker And the salts prepared in this way only Flooring Adsorbs and removes harmful ingredients in sea water, continuously supplies far infrared rays or anions, and charcoal powder that poisons, adsorbs, neutralizes, reduces, decomposes and sterilizes harmful substances in 1 ~ 400 mesh (MESH) particle size. 0.5-40% by weight and solid powder UV blocker up to 0.1-20% by weight of polypropylene, polyethylene, polyvinylchloride, polystyrene, polyolefin, polyester, melamine, polycarbonate, acrylonitrile styrene, acrylonitrile It is mixed into 40 to 99.4% by weight of one or more selected plastics of butadiene styrene and heated and kneaded in an extruder-type compounding machine in which the inside is kept in a vacuum to make pellet chips, and the chips are used as raw materials or master batches. To improve the detoxification function, characterized in that produced by the extrusion molding method and solid powder Manufacturing method of salted flooring material containing shape UV blocker and salted flooring material manufactured by this method The method according to claim 2, Among the UV blockers, pure UV blockers are benzotriazole or benzozazinone, the content of which is 60 to 90% by weight relative to the total UV blocker, which enhances the detoxification function and the solid powder of the salt-containing flooring material containing the UV blocker. Manufacturing method and flooring material for salt manufactured by this method

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