KR20100108648A - The fumigant to control honeybee pest and diseases - Google Patents

The fumigant to control honeybee pest and diseases Download PDF

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KR20100108648A
KR20100108648A KR1020090026762A KR20090026762A KR20100108648A KR 20100108648 A KR20100108648 A KR 20100108648A KR 1020090026762 A KR1020090026762 A KR 1020090026762A KR 20090026762 A KR20090026762 A KR 20090026762A KR 20100108648 A KR20100108648 A KR 20100108648A
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fumigation
acid
fumigant
agent
bee
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KR101156037B1 (en
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이명렬
최용수
이만영
김원태
이광길
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대한민국(농촌진흥청장)
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/02Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/18Vapour or smoke emitting compositions with delayed or sustained release
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/26Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/02Acyclic compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/06Oxygen or sulfur directly attached to a cycloaliphatic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08Oxygen or sulfur directly attached to an aromatic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • A01N65/38Solanaceae [Potato family], e.g. nightshade, tomato, tobacco or chilli pepper
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/40Liliopsida [monocotyledons]
    • A01N65/46Stemonaceae [Stemona family], e.g. croomia
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/40Liliopsida [monocotyledons]
    • A01N65/48Zingiberaceae [Ginger family], e.g. ginger or galangal

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Abstract

PURPOSE: A fumigant for preventing honey bee is provided to standardize organic acid and plant essential oil as a main ingredient and to enhance prevention efficiency. CONSTITUTION: A fumigant for preventing honey bee contains organic acid and fumigation catalyst. The organic acid is oxalic acid, acetic acid, lactic acid, succinic acid, tartaric acid, or malic acid. The fumigation catalyst is a beeswax existing at least one side of the fumigant. The fumigant further comprises fumigant relieving agent of crystal cellulose or hydroxy propylmethyl cellulose. The fumigant relieving agent is 20-50 weight parts based on 100 weight parts of total fumigant.

Description

꿀벌 병해충 방제용 훈증제{THE FUMIGANT TO CONTROL HONEYBEE PEST AND DISEASES}Fumigation agent for bee pest control {THE FUMIGANT TO CONTROL HONEYBEE PEST AND DISEASES}

본 발명은 꿀벌응애, 중국가시응애, 백묵병 등 꿀벌 병해충을 방제하기 위한 훈증제에 관한 것으로서, 더욱 상세하게는 증기를 통해 방제효과를 나타내는 유기산과 식물정유를 주성분으로 하고 훈증 촉매제로 밀랍을 피복한 훈증용 정제에 관한 것이다. The present invention relates to a fumigation agent for controlling bee pests such as bee mite, Chinese barley mite, chalk disease, and more specifically, it is mainly composed of organic acids and plant essential oils that have a control effect through steam and coated beeswax with a fumigation catalyst. It relates to a fumigation tablet.

꿀벌응애(바로아디스트럭터)는 세계적으로 분포가 확대되었으며 양봉산업에 심각한 피해를 주는 외부기생 해충으로 꿀벌의 유충, 번데기 및 성충에 기생하면서 체액을 빨아먹는다. 이로 인하여 꿀벌은 정상적인 발육을 하지 못하며 정상 활동을 할 수 없고, 발생이 심하면 봉군의 세력이 크게 약화되어 폐군에 이르게 된다. 세계적으로 유기합성 살비제에 대한 저항성 개체가 출현하고 있어 방제가 점차 어려워지고 있는 실정이며 우리나라뿐만 아니라 세계적으로도 생산 양봉에서 꿀벌에 가장 위협이 되고 있다. 꿀벌응애는 1960년대에 발생이 확인된 이후 국내 꿀벌에 만성적으로 기생하고 있는데, 1990년대 중반에 외국에서 유입된 중국가시응애와 더불어 국내 양봉산업에 가장 큰 피해를 주고 있다. Honeybee mites (baro-adstructors) are a globally distributed and parasitic pest that seriously damages the beekeeper industry and sucks body fluids while parasitic on bees' larvae, pupa and adults. Because of this, honeybees do not develop normally and cannot function normally, and if the outbreak is severe, the forces of the Bong-gun are greatly weakened and lead to the lung-gun. Resistant organisms are becoming increasingly difficult due to the emergence of resistant organisms to organic synthetic acaricides and are the most threat to bees in production beekeeping as well as in Korea. Bee mites have been chronically parasitic to domestic honey bees since they were confirmed in the 1960s. With the Chinese mites introduced from foreign countries in the mid 1990s, bee mites are the most damaging to domestic beekeepers.

꿀벌 봉군에서 만성적으로 나타나는 진균성 질병인 백묵병의 병원균(아스코레라아피스)은 포자 형태로 유충의 입으로 침입하고 중장에서 발아한 후, 균사가 증식함으로써 유충을 치사시키는데, 이 백묵병 포자는 10년~15년까지 병원성을 유지하여 완전 방제가 어려운 질병이다.The pathogen of asymptomatic bacteria (ascorera apis), a chronic fungal disease in the bee bong, invades the larvae's mouth in the form of spores, germinates in the intestine, and kills the larvae by proliferating mycelia. It is a disease that is completely difficult to control since it remains pathogenic for 15 to 15 years.

꿀벌 병해충 방제용 약제와 관련된 선행 유사 발명으로는 사료첨가용 꿀벌응애 방제약제 치미아졸의 합성 기술, 식물성 오일의 서방성 제형 즉 겔, 중합체 매트릭스를 통한 질병 억제방법이 개발되어 있다. 또한 전기가열식 꿀벌응애 구제기가 개발되어 시판 화공약품 원료인 옥살산 분말을 가열하여 기화하는 방제법이 제시되고 있는데 사용시 정확한 양을 처리하기가 어려울 뿐 아니라 취급과정에서 사용자가 분말과 강한 산성 냄새에 노출될 우려가 크다. 또한 벌통 외부에서 옥살산 분말을 탑재하면 훈증기에 분말이 짧은 순간 일시에 기화하여, 작업하는 사용자가 유출되는 가스에 노출됨으로써 정량 처리에 의한 안전하고 효율적인 방제효과를 기대하기 어렵다. Prior similar inventions related to bee pest control agents have been developed for the synthesis of feed bee mite control drug chimazole, sustained-release formulations of vegetable oils, ie gels, methods of disease suppression through polymer matrices. In addition, an electric heated bee mite extinguisher has been developed to control the vaporization of oxalic acid powder, a commercial chemical raw material, and to be vaporized.It is difficult to process the correct amount during use, and the user may be exposed to the powder and strong acidic odor during handling. Is large. In addition, when the oxalic acid powder is mounted outside the beehive, the powder is vaporized in a fume at a short time, and the working user is exposed to the outflowing gas, so it is difficult to expect a safe and effective control effect by the quantitative treatment.

본 발명은 꿀벌응애 등에 방제효과가 증명된 옥살산 등 유기산과 티몰 등 식물정유를 주성분으로 하고, 훈증속도 완화제와 훈증 촉매제를 첨가하여 사용이 간편하고 꿀벌 병해충의 방제 효율과 안전성을 증진하였다. 이전 관행적 훈증방법과는 달리 조성성분이 정량화되고 규격화된 훈증제로서의 특성을 갖는다.The present invention is mainly made of organic essential oils such as oxalic acid and plant essential oils such as thymol and the like, and added to the fumigation rate-reducing agent and the fumigation catalyst to improve the efficiency and safety of bee pest control. Unlike the previous conventional fumigation methods, the composition is characterized as a quantified and standardized fumigation agent.

꿀벌응애 등 꿀벌 병해충의 친환경적인 방제를 위하여 옥살산 등 유기산과 티몰 등 식물정유를 주성분으로 하고 훈증속도 완화제로 셀룰로오스 첨가 및 훈증촉매제로 밀랍을 피복하여 사용에 안전하고 편리하도록 제형화한 훈증용 정제 개발한 것이다. Development of fumigated tablets formulated to be safe and convenient for use by using organic acids such as oxalic acid and plant essential oils such as thymol as environmentally friendly ingredients for bee mite, and beeswax with cellulose and fumigation catalyst as a fumigation retardant. It is.

본 발명은 안전하고 효과적인 꿀벌 병해충 방제를 위해 유기산과 식물정유를 주성분으로 규격화된 친환경 훈증 정제를 개발함으로써 양봉가가 사용하기에 간편하고 안전하며, 방제 효율이 높은 꿀벌 병해충 방제 효과를 얻고자 하는 것이다.The present invention is to obtain a bee pest control effect, easy and safe for beekeepers to use, by developing eco-friendly fumigation tablets based on organic acids and plant essential oils for safe and effective bee pest control.

본 발명은 유기산 및 훈증 촉매제를 포함하는 꿀벌 병해충 방제용 훈증제를 제공한다.The present invention provides a fumigation agent for controlling bee pests comprising organic acid and fumigation catalyst.

또한, 본 발명은 유기산, 식물정유 및 훈증 촉매제를 포함하는 꿀벌 병해충 방제용 훈증제를 제공한다.The present invention also provides a fumigation agent for controlling bee pests, including organic acids, plant essential oils and fumigation catalysts.

상기 유기산은 옥살산, 초산, 젖산, 숙신산, 타르타르산 및 말릭산으로 이루어진 그룹에서 하나 이상 선택될 수 있다. 또는 상기 유기산은 무수 옥살산일 수 있다. The organic acid may be selected from the group consisting of oxalic acid, acetic acid, lactic acid, succinic acid, tartaric acid and malic acid. Alternatively, the organic acid may be anhydrous oxalic acid.

또한, 상기 식물 정유는 티몰, 멘톨, 시네올, 리나룰, 유제놀 및 제라니올로 이루어진 그룹에서 하나 이상 선택될 수 있다. In addition, the plant essential oil may be at least one selected from the group consisting of thymol, menthol, cineol, linalul, eugenol and geraniol.

상기 유기산과 상기 식물정유의 중량비는 1:1 내지 25:1일 수 있다. 또는 유 기산과 상기 식물정유의 중량비는 14:1일 수 있다.The weight ratio of the organic acid and the plant essential oil may be 1: 1 to 25: 1. Alternatively, the weight ratio of the organic acid and the plant essential oil may be 14: 1.

상기 훈증 촉매제는 밀랍으로서, 상기 밀랍은 상기 훈증제의 적어도 한 면을 피복한 형태로 존재할 수 있다. The fumigation catalyst is beeswax, and the beeswax may be present in a form covering at least one side of the fumigation agent.

상기 상기 훈증는 결정셀룰로오스 및 하이드록시프로필메틸셀룰로오스 중에서 적어도 하나 이상 선택된 훈증 완화제를 더 포함하며, 상기 훈증 완화제는 전체 훈증제 100중량부에 20~50중량부인 꿀벌 병해충 방제용 훈증제일 수 있다. The fumigation further comprises at least one fumigation relievers selected from crystalline cellulose and hydroxypropylmethylcellulose, the fumigation relief may be a fumigation agent for bee pest control to 20 to 50 parts by weight to 100 parts by weight of the total fumigation.

또한, 상기 훈증제는 괭이밥, 쇄기풀, 꽃향유, 생강과(Zingiberacea)의 아모뮴(ammomum)속, 생강과의 진지버(Zingiber)속 식물, 백부과(Stemonaceae)의 스테모나속 식물 및 담배로 이루어진 군에서 하나 이상 선택되는 것의 알코올 또는 물 증류 추출물을 더 포함할 수 있다. In addition, the fumigation agent is a hoe rice, dianthus, flowering perfume, ammomum of Zingiberacea, Zingiber genus plants of the family of ginger, Stemona genus plants of Tobacco (Stemonaceae) and tobacco It may further comprise an alcohol or water distillation extract of one or more selected from the group consisting of.

즉, 상기 과제를 해결하기 위해 제안된 본 발명의 실시예는 꿀벌응애류 등 꿀벌 병해충 방제를 위하여 옥살산, 구연산 등 유기산, 또는 유기산 및 티몰, 멘톨 등 식물정유를 주성분으로 하는 훈증제와 사용 목적에 따른 유기산과 식물정유의 적정 배합비율을 특징으로 한다. That is, the embodiment of the present invention proposed to solve the above problems is an organic acid according to the purpose and the fumigant mainly composed of plant essential oils such as oxalic acid, citric acid, or organic acids and thymol, menthol for the control of bee pests such as bee mite And a proper blending ratio of plant essential oils.

또한 훈증 촉진제로 밀랍을 피복함으로써 사용시 유해가스 발생과 피부접촉을 차단하고 초기 기화 속도를 늦추는 한편 벌통 내에서 액체 밀랍의 지속적 훈증촉진 역할을 특징으로 한다. In addition, the beeswax is coated with a fumigation accelerator to prevent harmful gas generation and skin contact, slow down the initial vaporization rate, and promote the continuous fumigation of liquid beeswax in the beehive.

본 발명은 유기산과 식물정유를 이용한 꿀벌 병해충 훈증 방제시 벌통 밖에 서 주성분이 일시 훈증되거나 사용자에게 직접 접촉되는 점을 방지함으로써 양봉가에게 보다 안전하고 효과적인 방제 방법을 제공할 수 있다. 또한 유기산과 식물정유의 꿀벌응애 등 병해충에 대한 방제 속도의 차이, 꿀벌에 대한 부작용 등을 고려하여 봉군 조건에 따라 다양한 배합 비율을 적용함으로써 방제효율 증진에 기여할 수 있다. 유기합성 농약 또는 항생제에 의존하는 관행 꿀벌 병해충 방제를 지양하고 친환경 방제 기술이 보급되어 양봉산업의 생산성과 벌꿀 등 양봉 생산물의 안전성을 증진하고 대외 경쟁력을 높이는 효과를 기대할 수 있다. The present invention can provide a safer and more effective control method to beekeepers by preventing the main ingredient is temporarily fumigation outside the beehive or directly contacted to the user when the bee pest fumigation using organic acids and plant essential oils. In addition, considering the difference in the rate of control against pests such as bee mite of organic acids and plant essential oils, and side effects to bees, various compounding ratios can be applied to increase the control efficiency according to the conditions. Conventional reliance on organic synthetic pesticides or antibiotics Avoiding the control of bee pests and the spread of environment-friendly control technologies can enhance the productivity of the bee farming industry and the safety of bee products, including honey, and enhance external competitiveness.

이하, 본 발명을 이하에서 상세히 설명한다.Hereinafter, the present invention will be described in detail below.

[실시예 1] Example 1

도 2는 본 발명의 한 실시예에 의한 꿀벌 병해충 방제용 훈증제의 제조 공정을 나타낸 것이다.Figure 2 shows the manufacturing process of the bee pest control fumigation agent according to an embodiment of the present invention.

먼저, 유기산을 압축 정제 성형한다. 상기 유기산은 옥살산, 포름산, 초산, 젖산, 숙신산, 타르타르산 및 말릭산으로 이루어진 그룹에서 하나 이상 선택할 수 있다. 바람직하게는, 상기 유기산은 옥살산이다. First, the organic acid is compression tableted. The organic acid may be at least one selected from the group consisting of oxalic acid, formic acid, acetic acid, lactic acid, succinic acid, tartaric acid and malic acid. Preferably, the organic acid is oxalic acid.

또한, 훈증제는 훈증 완화제를 더 포함할 수 있다. 즉, 유기산에 상기 훈증 완화제를 혼합한 후 압축 정제 성형할 수 있다.In addition, the fumigation agent may further include a fumigation relieving agent. That is, after mixing the fumigation relieving agent with an organic acid may be compression tablet molding.

상기 훈증 완화제는 방제속도와 방제효과, 꿀벌 안전성을 증진하기 위하여 제형화함에 있어 훈증속도 완화를 위해 추가하였다. The fumigation relieving agent was added to reduce the fumigation rate in the formulation in order to improve the control rate and control effect, bee safety.

상기 훈증 완화제는 결정셀룰로오스, 하이드록시프로필메틸셀룰로오스 또는 그 혼합물로서, 훈증제 전체 100중량부에 대하여 20~50중량부를 첨가할 수 있다. 상기 훈증 완화제가 20중량부 미만인 경우 본 발명의 훈증제가 빠르게 훈증되어 꿀벌이 소란을 일으킬 수 있으며, 50중량부 초과의 경우 훈증이 잘 일어나지 않는다.  The fumigation relieving agent is crystalline cellulose, hydroxypropylmethylcellulose or a mixture thereof, and may be added in an amount of 20 to 50 parts by weight based on 100 parts by weight of the whole fumigation agent. When the fumigation relieving agent is less than 20 parts by weight, the fumigation agent of the present invention can be quickly fumigation can cause a bee disturbance, in the case of more than 50 parts by weight fumigation does not occur well.

상기 압축 정제 성형된 훈증제의 적어도 한 면을 액상 밀랍으로 피복한 후 건조하여 본 발명의 훈증제를 제조할 수 있다. The fumigation agent of the present invention may be prepared by coating at least one side of the compression tablet molded fumigation agent with liquid beeswax and drying it.

상기 밀랍은 훈증 촉진제로서 사용시 유해가스 발생 및 사용자 피부접촉을 방지하고, 초기 가스 발생으로 억제하고 벌통 내에서 밀랍이 액화된 이후에는 지속적 훈증 촉진 역할도 한다. The beeswax prevents harmful gas generation and user's skin contact when used as a fumigation accelerator, inhibits the initial gas generation, and also acts as a continuous fumigation promotion after the wax is liquefied in the beehive.

[실시예 2] [Example 2]

도 3은 본 발명의 다른 실시예에 의한 꿀벌 병해충 방제용 훈증제의 제조 공정을 나타낸 것이다.Figure 3 shows the manufacturing process of the bee pest control fumigation agent according to another embodiment of the present invention.

유기산 및 식물정유를 혼합한 후에 압축 정제 성형한다. 또는 유기산 및 식물정유 혼합물에 실시예 1의 훈증 완화제를 혼합한 후 압축 정제 성형한다.The organic acid and the plant essential oil are mixed and then compressed and molded. Alternatively, the fumigation relieving agent of Example 1 is mixed with the organic acid and plant essential oil mixture, and then compressed and molded.

상기 식물정유는 티몰, 멘톨, 시네올, 리나룰, 유제놀 및 제라니올로 이루어진 그룹에서 하나 이상 선택할 수 있다. The plant essential oil may be at least one selected from the group consisting of thymol, menthol, cineol, linalul, eugenol and geraniol.

유기산과 식물정유의 중량비는 1:1 내지 25:1일 수 있다. 그 이외의 제조방법은 실시예 1과 동일하다.The weight ratio of organic acid and plant essential oil may be 1: 1 to 25: 1. The other manufacturing method is the same as that of Example 1.

[실험예 1]Experimental Example 1

분말 형태의 구연산, 옥살산 및 티몰 각각 1g을 각각 압축 정제 성형한 후 밀랍으로 피복하여 훈증제를 제조하였다. 벌통 내에서 각각의 훈증제를 1 내지 3분 동안 200~300℃로 가열하여 훈증한 결과를 도 5에 나타내었다.1 g of each of citric acid, oxalic acid and thymol in powder form was compression-molded and then coated with beeswax to prepare a fumigant. The fumigation results of heating each fumigant at 200 to 300 ° C. for 1 to 3 minutes in the hive are shown in FIG. 5.

도 5에서 보는 바와 같이, 밀랍 피복 정제 형태의 옥살산과 티몰의 개별 훈증에 의한 꿀벌응애 방제 효과를 꿀벌 봉군을 대상으로 시험한 결과로서 구연산 훈증 대조구(C)에서는 꿀벌응애의 초기 밀도가 처리 4일 후에 93%로 감소하고, 반면 옥살산(O)은 25%로, 티몰(T)은 19%로 현저하게 감소하였다. 또한 옥살산 훈증(O)은 처리 후 기간경과에 따라 점진적인 방제효과를 보이며, 반면 티몰 훈증(T)은 처리 1일 후에 초기 밀도의 75%가 감소하는 속효성 방제효과를 보였다. As shown in Figure 5, the bee mite control effect of the bee mite control effect by the individual fumigation of oxalic acid and thymol in the form of beeswax coated tablets as a result of testing the bee mite in the initial density of the bee mite 4 days Later it was reduced to 93%, while oxalic acid (O) was significantly reduced to 25% and thymol (T) to 19%. In addition, oxalic acid fumigation (O) showed a gradual control effect over the post-treatment period, whereas thymol fumigation (T) showed a fast-acting control effect that decreased 75% of the initial density after one day of treatment.

즉, 옥살산과 티몰의 훈증시 물리적 특성과 꿀벌응애 방제 효과 발현 양상은 다음과 같다.In other words, the physical characteristics of the oxalic acid and thymol fumigation and bee mite control effects are as follows.

가. 옥살산(유기산)은 밀랍 피복에 의한 고형의 정제 상태로 200∼300℃에서 훈증속도가 다소 느리고, 훈증시 꿀벌응애 방제효과는 지효성이며 반면 꿀벌에는 안정적이었다.end. Oxalic acid (organic acid) is a solid tablet by beeswax coating and has a slow fumigation rate at 200-300 ° C. The effects of bee mite control on fumigation are slow and stable to bees.

나. 티몰(식물정유)은 고형의 정제 상태로 섭씨 200∼300℃에서 훈증속도가 매우 빠르고, 훈증에 의한 꿀벌응애 방제효과는 티몰의 경우 특별히 속효성으로 나타났다. 처리 후 강한 향에 의해 꿀벌이 소란을 일으키고 10℃ 이하 저온에서는 일벌의 소요에 따른 다소의 피해가 나타났다. I. The thymol (plant essential oil) is a solid refined state in the fumigation rate is very fast at 200 ~ 300 ℃, the control effect of bee mite by fumigation was shown to be particularly fast in the case of thymol. After treatment, the honey bee disturbed by the strong fragrance, and at low temperature below 10 ℃, some damage was caused by worker bees.

[실시예 3]Example 3

서양종 꿀벌 봉군을 대상으로 무수옥살산 700㎎(A)과 티몰 25㎎, 50㎎, 100㎎을 각각 함유한 훈증제를 처리하고 8일간 사망한 꿀벌응애수와 브롬프로피레트 2배 농도처리에 의해 낙하한 잔여 꿀벌응애수 조사에 의한 처리전 총 꿀벌응애수 산출에 의한 방제효과 비교는 하기 표 1과 같다. Western bee bong group was treated with fumigant containing 700 mg (A) oxalic anhydride, 25 mg, 50 mg, and 100 mg, respectively, and dropped by double concentration treatment of bee mite and brompropiret who died for 8 days. Comparison of the control effect by the total bee mite calculation before treatment by the residual bee mite survey is shown in Table 1 below.

[표 1]TABLE 1

옥살산함량Oxalic acid content 티몰함량Thymol content 사망 꿀벌응애수Death bee 총 꿀벌응애수Total bee 방제율(%)Control rate (%) 700㎎700mg -- 2222 117117 18.818.8 700㎎700mg 25㎎25mg 2121 154154 13.613.6 700㎎700mg 50㎎50 mg 113113 142142 79.679.6 700㎎700mg 100㎎100mg 107107 227227 47.147.1

상기 표 1에서 보는 바와 같이, 옥살산 700㎎과 티몰 50㎎을 함유하는 훈증제에서 처리 후 8일간 처리구 중에서 방제율이 가장 높았으며, 옥살산 700㎎만 함유한 훈증제에 비해 4배 이상의 방제율을 보였다.As shown in Table 1, the fumigation agent containing oxalic acid 700 mg and thymol 50 mg was the highest control rate among the treatment groups for 8 days after treatment, and showed more than four times the control rate compared to the fumigation agent containing only oxalic acid 700 mg.

[실험예 2] Experimental Example 2

서양종 꿀벌 봉군을 대상으로 무수옥살산 700㎎과 티몰 50㎎을 함유한 훈증제 훈증처리구(A)와 옥살산 3%용액 분무(벌집당 1㎖) 처리구(B), 티몰분말 10g 방향 처리구(C), 포름산(8%)과 티몰(4%)를 함유한 0.8% 한천겔 100㎖ 방향 처리구(D), 무처리구(E)의 처리 전후 꿀벌응애 사망비율에 의한 방제효과 비교하였다. 그 결과를 하기 표 2에 나타내었다. Fumigation treatment group (A) containing 700 mg of oxalic anhydride and 50 mg of oxalic anhydride, spraying 3% solution of oxalic acid (1 ml per beehive), treatment group (B), thymol powder (10 g), formic acid (8%) and thymol (4%) of 0.8% agar gel containing 100ml aroma treatment (D) and no treatment (E) was compared with the control effect by the rate of death of honeybee mite before and after treatment. The results are shown in Table 2 below.

[표 2]TABLE 2

처리전 1일 평균 사망 꿀벌응애수(ㄱ)Average deaths per day before treatment 처리후 1일 평균 사망 꿀벌응애수(ㄴ)Average number of dead bee mites per day after treatment (b) 처리전후 꿀벌응애 사망 비율(ㄴ/ㄱ)Rate of death from honeybee mites before and after treatment (b / a) 옥살산+티몰 훈증(A)Oxalic acid + thymol fumigation (A) 1919 170170 8.98.9 옥살산 분무(B)Oxalic acid spray (B) 1414 2828 2.12.1 티몰 분말(C)Thymol powder (C) 1111 4242 3.83.8 포름산+티몰 겔(D)Formic acid + thymol gel (D) 2525 5252 2.12.1 무처리(E)No treatment (E) 9393 117117 1.31.3

상기 표 2에서 보는 바와 같이 옥살산과 티몰 혼합물의 훈증 처리구(A)가 자연 방향성 처리구(B, C, D) 보다 처리전 자연사망 꿀벌응애수에 비해 처리후 사망 꿀벌응애수가 현저하게 많았다.As shown in Table 2, the fumigation treatment (A) of the oxalic acid and thymol mixture was significantly higher than the natural directional treatment (B, C, D) than the natural death bee mite before treatment.

[실험예 3][Experimental Example 3]

서양종 꿀벌 봉군을 대상으로 꽃향유, 생강과의 아모뮴속과 진지버속 식물, 백부과의 스테모나속 식물의 식물 혼합추출물 분무 방향(A), 아모뮴속 식물 추출물 분무 방향(B), 관행 사용하는 플루바리네이트 스트립 1배 농도 방향(C), 개미산 용액 10㎖ 자연증발(D), 무처리구(E) 등의 처리전후 각 7일간 1일평균 꿀벌응애 사망비율에 의한 방제효과 비교는 도 4에 나타내었다. 이 실험예에 있어서 A, B는 각각 식물건체 총 200g에 대한 증류추출액 10㎖을 사용하였다. 점선은 3 반복 시험에 대한 표준편차이다. 처리구간 유의성은 인정되지 않았다.The spray direction (A), the spray direction (A) of the plant extracts of the plant extracts of the flower fragrance oil, the genus Amosium and the Gingerbread plant, the encyclopedia of the Stemona genus, and the method of the influenza used for the Western bee bong group Comparison of control effects by daily bee mite mortality rate for 7 days before and after treatment with varinate strip 1 times concentration direction (C), formic acid solution 10 ml spontaneous evaporation (D), and no treatment (E) is shown in FIG. . In this experimental example, A and B used 10 ml of the distillate extract for 200 g of the total dry matter, respectively. The dashed line is the standard deviation for three replicates. The significance of the treatment period was not recognized.

도 4에서 보는 바와 같이, 식물 혼합 추출액(A)의 경우 관행 화학약제 플루바리네이트(C)와 유기산 1종인 개미산(D)보다 꿀벌응애 방제효과가 높았고, 아모뮴 속 식물추출액은 중국가시응애에 대한 방제효과가 가장 높았다.As shown in Figure 4, the plant mixed extract (A) was higher than the conventional chemical agent flubarinate (C) and one organic acid, formic acid (D), the bee mite control effect was higher, the plant extract of the genus ammonium in Chinese barley mite The control effect was the highest.

도 1은 본 발명의 한 실시예에 의한 꿀벌 병해충 방제용 훈증제의 제조 공정을 나타낸 것이다.Figure 1 shows the manufacturing process of the fumigation agent for controlling bee pests according to an embodiment of the present invention.

도 2는 본 발명의 다른 실시예에 의한 꿀벌 병해충 방제용 훈증제의 제조 공정을 나타낸 것이다.Figure 2 shows the manufacturing process of the bee pest control fumigation agent according to another embodiment of the present invention.

도 3은 구연산, 옥살산, 티몰의 훈증 일자별 꿀벌응애 밀도변화를 나타낸 도표이다.Figure 3 is a chart showing the change in density of honey bee mite by the fumigation date of citric acid, oxalic acid, thymol.

도 4는 식물추출물, 개미산, 플루바리네이트 처리구벌 꿀벌응애 사망수 비교한 도표이다.4 is a chart comparing plant extracts, formic acid, fluvarinate-treated bulbous bee mite deaths.

Claims (15)

유기산 및 훈증 촉매제를 포함하는 꿀벌 병해충 방제용 훈증제.Fumigation agent for controlling bee pests including organic acid and fumigation catalyst. 제1항에 있어서,The method of claim 1, 상기 유기산은 옥살산, 초산, 젖산, 숙신산, 타르타르산 및 말릭산으로 이루어진 그룹에서 하나 이상 선택되는 꿀벌 병해충 방제용 훈증제.The organic acid is oxalic acid, acetic acid, lactic acid, succinic acid, tartaric acid and malic acid selected from the group consisting of one or more bee pest control fumigation. 제1항 또는 제2항에 있어서,The method according to claim 1 or 2, 상기 유기산은 무수 옥살산인 꿀벌 병해충 방제용 훈증제.The organic acid is a fumigant for controlling bee pests that is anhydrous oxalic acid. 제1항에 있어서,The method of claim 1, 상기 훈증 촉매제는 밀랍으로서, The fumigation catalyst is beeswax, 상기 밀랍은 상기 훈증제의 적어도 한 면을 피복한 형태로 존재하는 꿀벌 병해충 방제용 훈증제.The beeswax is a fumigant for controlling bee pests present in the form of covering at least one side of the fumigant. 제1항에 있어서,The method of claim 1, 상기 훈증제는 결정셀룰로오스 및 하이드록시프로필메틸셀룰로오스 중에서 적어도 하나 이상 선택된 훈증 완화제를 더 포함하며,The fumigation agent further includes a fumigation relieving agent selected from at least one selected from crystalline cellulose and hydroxypropylmethylcellulose, 상기 훈증 완화제는 전체 훈증제 100중량부에 20~50중량부인 꿀벌 병해충 방 제용 훈증제.The fumigation relieving agent is a fumigation agent for bee pest control that is 20 to 50 parts by weight in 100 parts by weight of the total fumigation. 제1항에 있어서,The method of claim 1, 상기 훈증제는 괭이밥, 쇄기풀, 꽃향유, 생강과(Zingiberacea)의 아모뮴(ammomum)속, 생강과의 진지버(Zingiber)속 식물, 백부과(Stemonaceae)의 스테모나속 식물 및 담배로 이루어진 군에서 하나 이상 선택되는 것의 알코올 또는 물 증류 추출물을 포함하는 꿀벌 병해충 방제용 훈증제.The fumigation agent is a group consisting of hoebab, dianthus, flowering perfume, ammomum of Zingiberacea, Zingiber genus of Gingeraceae, Stemona genus of the Wikipedia (Stemonaceae) and tobacco A fumigation agent for controlling bee pests, comprising distillation extract of alcohol or water of at least one selected from. 유기산, 식물정유 및 훈증 촉매제를 포함하는 꿀벌 병해충 방제용 훈증제.A fumigant for controlling bee pests, including organic acids, plant essential oils and fumigation catalysts. 제7항에 있어서,The method of claim 7, wherein 상기 유기산은 옥살산, 초산, 젖산, 숙신산, 타르타르산 및 말릭산으로 이루어진 그룹에서 하나 이상 선택되는 꿀벌 병해충 방제용 훈증제.The organic acid is oxalic acid, acetic acid, lactic acid, succinic acid, tartaric acid and malic acid selected from the group consisting of one or more bee pest control fumigation. 제7항 또는 제8항에 있어서,9. The method according to claim 7 or 8, 상기 유기산은 무수 옥살산인 꿀벌 병해충 방제용 훈증제.The organic acid is a fumigant for controlling bee pests that is anhydrous oxalic acid. 제7항에 있어서,The method of claim 7, wherein 상기 식물 정유는 티몰, 멘톨, 시네올, 리나룰, 유제놀 및 제라니올로 이루어진 그룹에서 하나 이상 선택되는 꿀벌 병해충 방제용 훈증제.The plant essential oil is a fumigation agent for controlling bee pests selected from the group consisting of thymol, menthol, cineol, linalul, eugenol and geraniol. 제7항에 있어서,The method of claim 7, wherein 상기 유기산과 상기 식물정유의 중량비는 1:1 내지 25:1인 꿀벌 병해충 방제용 훈증제.The weight ratio of the organic acid and the plant essential oil is a fumigant for controlling bee pests of 1: 1 to 25: 1. 제7항 또는 제11항에 있어서,The method according to claim 7 or 11, wherein 상기 유기산과 상기 식물정유의 중량비는 14:1인 꿀벌 병해충 방제용 훈증제.The weight ratio of the organic acid and the plant essential oil is a fumigant for controlling bee pests is 14: 1. 제7항에 있어서,The method of claim 7, wherein 상기 훈증 촉매제는 밀랍으로서, The fumigation catalyst is beeswax, 상기 밀랍은 상기 훈증제의 적어도 한 면을 피복한 형태로 존재하는 꿀벌 병해충 방제용 훈증제.The beeswax is a fumigant for controlling bee pests present in the form of covering at least one side of the fumigant. 제7항에 있어서,The method of claim 7, wherein 상기 훈증제는 결정셀룰로오스 및 하이드록시프로필메틸셀룰로오스 중에서 적어도 하나 이상 선택된 훈증 완화제를 더 포함하며,The fumigation agent further includes a fumigation relieving agent selected from at least one selected from crystalline cellulose and hydroxypropylmethylcellulose, 상기 훈증 완화제는 전체 훈증제 100중량부에 20~50중량부인 꿀벌 병해충 방제용 훈증제.The fumigation relieving agent is a fumigation agent for bee pest control that is 20 to 50 parts by weight to 100 parts by weight of the total fumigation. 제7항에 있어서,The method of claim 7, wherein 상기 훈증제는 괭이밥, 쇄기풀, 꽃향유, 생강과(Zingiberacea)의 아모뮴(ammomum)속, 생강과의 진지버(Zingiber)속 식물, 백부과(Stemonaceae)의 스테모나속 식물 및 담배로 이루어진 군에서 하나 이산 선택되는 것의 알코올 또는 물 증류 추출물을 포함하는 꿀벌 병해충 방제용 훈증제.The fumigation agent is a group consisting of hoe rice, dianthus, flowering perfume, ammomum of Zingiberacea, Zingiber genus of Gingeraceae, Stemona genus of the Encyclopedia (Stemonaceae) and tobacco A fumigation agent for controlling honey bee pests, comprising distillate extracts of alcohol or water of one selected from.
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CN102154370A (en) * 2010-12-13 2011-08-17 云南瑞升烟草技术(集团)有限公司 Method for preparing flavor for elsholtzia kachinensis prain tobacco through multi-strain composite fermentation
KR101384515B1 (en) * 2011-12-29 2014-04-11 대한민국 Compositions for controlling Varroa destructor by Metarizium anisopliae and Using the same
KR102096721B1 (en) * 2018-10-26 2020-04-02 경기도 Low―toxic and eco-friendly composition for controlling Dermanyssus gallinae having Oxalic Acid and method for manufacturing the same
KR20220077633A (en) * 2020-12-02 2022-06-09 박혁진 Easily diffusible formic acid containing mite repellent for bees

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KR20240025265A (en) 2022-08-18 2024-02-27 농업회사법인 비센 바이오 주식회사 A formic composition for removing honeybee mites gelled with polymer absorbent and container packaging sets including the same

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KR100479254B1 (en) * 1996-06-13 2006-09-20 바이터 (유럽) 리미티드 How to curb bee bee infection

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102154370A (en) * 2010-12-13 2011-08-17 云南瑞升烟草技术(集团)有限公司 Method for preparing flavor for elsholtzia kachinensis prain tobacco through multi-strain composite fermentation
CN102154370B (en) * 2010-12-13 2013-03-13 云南瑞升烟草技术(集团)有限公司 Method for preparing flavor for elsholtzia kachinensis prain tobacco through multi-strain composite fermentation
KR101384515B1 (en) * 2011-12-29 2014-04-11 대한민국 Compositions for controlling Varroa destructor by Metarizium anisopliae and Using the same
KR102096721B1 (en) * 2018-10-26 2020-04-02 경기도 Low―toxic and eco-friendly composition for controlling Dermanyssus gallinae having Oxalic Acid and method for manufacturing the same
KR20220077633A (en) * 2020-12-02 2022-06-09 박혁진 Easily diffusible formic acid containing mite repellent for bees

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