KR20100084416A - Environment friendly agent for controlling rice planthopper - Google Patents
Environment friendly agent for controlling rice planthopper Download PDFInfo
- Publication number
- KR20100084416A KR20100084416A KR1020090003902A KR20090003902A KR20100084416A KR 20100084416 A KR20100084416 A KR 20100084416A KR 1020090003902 A KR1020090003902 A KR 1020090003902A KR 20090003902 A KR20090003902 A KR 20090003902A KR 20100084416 A KR20100084416 A KR 20100084416A
- Authority
- KR
- South Korea
- Prior art keywords
- oil
- weight
- azadilactin
- control agent
- rice
- Prior art date
Links
Images
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/26—Meliaceae [Chinaberry or Mahogany family], e.g. mahogany, langsat or neem
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
- A01N63/10—Animals; Substances produced thereby or obtained therefrom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/12—Asteraceae or Compositae [Aster or Sunflower family], e.g. daisy, pyrethrum, artichoke, lettuce, sunflower, wormwood or tarragon
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/20—Fabaceae or Leguminosae [Pea or Legume family], e.g. pea, lentil, soybean, clover, acacia, honey locust, derris or millettia
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/30—Polygonaceae [Buckwheat family], e.g. red-knees or rhubarb
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/38—Solanaceae [Potato family], e.g. nightshade, tomato, tobacco or chilli pepper
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/40—Liliopsida [monocotyledons]
- A01N65/42—Aloeaceae [Aloe family] or Liliaceae [Lily family], e.g. aloe, veratrum, onion, garlic or chives
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/40—Liliopsida [monocotyledons]
- A01N65/48—Zingiberaceae [Ginger family], e.g. ginger or galangal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Natural Medicines & Medicinal Plants (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Microbiology (AREA)
- Biotechnology (AREA)
- Pest Control & Pesticides (AREA)
- Mycology (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Virology (AREA)
- Dispersion Chemistry (AREA)
- Botany (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
본 발명은 친환경 벼멸구 방제제에 관한 것으로, 더욱 구체적으로는 님 오일(Neem Oil) 또는 아자디락틴을 주제로 한 벼멸구 방제용 조성물에 관한 것이다. 님 오일은 열대, 아열대 지방 (인도나, 미안마, 필리핀 등 동남아지방 지방)에 자생하는 멀구슬나무(Neem tree) 열매에서 추출한 식물성 유지로서, 본 발명은 특히 님 오일에 함유된 살충 효과가 있는 아자디락틴(Azadirachtin)을 농작물의 해충, 특히 벼멸구의 방제에 이용하는 것에 관한 것이다.The present invention relates to an environmentally friendly rice plant control agent, and more particularly, to a composition for plant control of a rice plant on the subject of neem oil (Neem Oil) or azadilactin. Nim oil is a vegetable oil extracted from the fruit of the Neem tree native to the tropical and subtropical regions (India, Myanmar, Philippines, Southeast Asia, etc.), the present invention is particularly effective in the insecticidal aza contained in nim oil Azadirachtin is used for controlling pests of crops, especially rice planthoppers.
지금까지 님 오일이 농업용으로 사용된 예로는 온실가루이, 총채벌레 방제용 유제가 있을 뿐이다. 인도, 일본, 미국 등지에서는 오래 전부터 여러 가지 용도로 사용되었고 우리나라에서도 약 10년 전부터 연구를 시작하여 최근에 일부 사용 되고 있다. So far, the only examples where Nim oil has been used for agriculture are greenhouse dusts and moth control oils. It has been used for various purposes in India, Japan, and the United States for a long time, and in Korea, it has been used for about 10 years and has been used recently.
님 오일에 유화제를 첨가하여 유제를 만들어 농작물에 살포하여 해충을 방제하거나, 광물성 분말과 혼합하여 입제로 만들어 논에 뿌려 해충을 방제하는 방법도 있다.There is also a method of controlling pests by adding emulsifiers to neem oil and spraying them on crops to control pests, or by mixing them with mineral powder to make granules and spraying them on rice paddies.
우리나라에는 벼멸구가 태풍을 타고 날아오므로 비래해충, 돌발 해충 이라하며 번식력이 강하여 피해가 큰 해충이다. In Korea, a rice pest comes from a typhoon, so it is called a pest, an abrupt pest, and has a strong propagation ability.
서식처는 벼 포기 밑 부분 습기가 많은 잎 집에서 서식하며 벼 즙액을 빨아먹기 때문에 결실이 되지 않고 쓸어져 크게 감수한다.Habitat lives in a humid leaf house at the bottom of rice abandonment, and since it sucks rice juice, it is wiped out without being fruited.
벼멸구는 볏대 아랫부분에서 흡즙하며 서식하는 습성이 있어 자연스럽게 아자디락틴이 몸에 접촉하게 되어 완전 방제가 가능하다. Rice bulbs are absorbed in the lower part of the crest and inhabit the habit, so that azadilactin comes into contact with the body and can be completely controlled.
이러한 벼멸구의 전통적인 방제제는 대부분 농약 성분이 함유되어 있으므로, 근래 각광받고 있는 친환경 유기농업에는 사용할 수 없다는 문제점이 있다. Since traditional pesticides of most of these pesticides contain pesticides, there is a problem that can not be used in the eco-friendly organic farming that is in the spotlight.
이에, 본 발명의 첫번째 목적은, 벼멸구를 효과적으로 방제할 수 있는 친환경 방제제를 제공하는데 있다.Thus, the first object of the present invention is to provide an environmentally friendly control agent that can effectively control the rice plant.
이에 따라, 본 발명의 한가지 목적은 님 오일 또는 아자디락틴을 주제로 한 친환경 벼멸구 방제제를 제공하는데 있다.Accordingly, one object of the present invention is to provide an environmentally friendly rice plant control agent based on neem oil or azadilactin.
구체적으로, 본 발명의 목적은 님 오일 또는 아자디락틴을 주제로 한 벼멸구 방제제로서, 벼멸구의 서식 특성에 착안하여 방제 효과를 최적화시킨 특정 유형의 방제제를 제공하는데 있다.Specifically, it is an object of the present invention to provide a specific type of control agent that optimizes the control effect by focusing on the habitat characteristics of the rice planter as a neem oil or azadilactin-based.
이를 위하여, 본 발명에서는, 크게 두가지 형태의 방제제, 즉 수면전개제 제형과 입제 제형의 님 오일 또는 아자디락틴을 주제로 한 방제제를 제공한다.To this end, the present invention provides a control agent mainly based on two types of control agents, namely, a sleep spreader formulation and a granule oil of nim oil or azadilactin.
즉, 본 발명은 님 오일이 첨가된 식물성 기름이 벼논의 물위에서 기름방울로 뭉치지 않고 골고루 퍼질 수 있도록 하는 방법을 제공하는 것이다.That is, the present invention is to provide a method for spreading the vegetable oil added to the nim oil evenly without clumping into oil droplets on the water of rice paddy.
본 발명의 또 다른 목적은 님 오일의 주성분인 아자디락틴이 물 표면에 얇은 피막을 형성하도록 함으로써 벼멸구와 벼 물바구미를 친환경적으로 방제하기 위한 방법을 제공하는 것이다.It is still another object of the present invention to provide a method for environmentally friendly control of rice pestle and rice weevil by allowing azadilactin, the main component of neem oil, to form a thin film on the surface of water.
본 발명의 또 다른 목적은 현재 여러 농도로 시판되는 님 오일 또는 불순물을 정제한 아자디락틴 분말을 이용한 제형의 다양화로 입제 또는 수면전개제 제형으로 친환경 벼멸구 방제제를 제공하는 데 있다.Still another object of the present invention is to provide an eco-friendly rice pest control agent in granules or in a sleep development formulation by diversifying the formulation using purified azadilactin powder which is currently marketed in various concentrations of Nim oil or impurities.
본 발명의 또 다른 목적은 저렴한 생선 통조림 부산물 또는 어박 제조 부산물과 같은 값 싼 동물성 기름인 생선기름(어유)을 원료로 하여 친환경 벼멸구 방제제를 저렴한 가격에 제공하는 데 있다.Still another object of the present invention is to provide an eco-friendly rice pest control agent using fish oil (fish oil), which is a cheap animal oil such as cheap canned fish by-product or fish food by-product, as a raw material.
본 발명은 또한, 활용가능한 저가 담체 또는 돌로마이트 등의 증량제를 이용함으로써 저렴한 원가로 입제형 벼멸구 방제제를 제공함으로써, 농업인의 농산물 생산비를 절감시키는데 그 목적이 있다.The present invention also aims to reduce the agricultural production cost of farmers by providing granular rice-hopper control agents at low cost by using an available low-cost carrier or extender such as dolomite.
본 발명의 또 다른 목적은 친환경농업이 광범위한 농작물에 적용되어 소비자가 우리 농산물을 안심하고 먹을 수 있도록 하는데 목적이 있다.Still another object of the present invention is to enable eco-friendly agriculture to be applied to a wide range of crops so that consumers can safely eat our agricultural products.
본 발명의 벼멸구 방제제는 살충 주성분으로서, 급성 독성이나 어독성이 없을 뿐 아니라, 작물에 잔류될 염려가 없는 님 오일 또는 아자디락틴 분말을 사용하는 친환경 방제제로서, 벼멸구의 서식 형태에 주목하여, 벼멸구를 효과적으로 방제 할 수 있도록 제형화 되었으므로, 벼를 비롯한 농작물의 친환경 재배에 크게 도움이 될 수 있다.The pesticide control agent of the present invention as an insecticide main ingredient, there is no acute toxicity or fish toxicity, as well as environmentally friendly control agent using nim oil or azadilactin powder which does not remain in crops, In addition, it is formulated to effectively control rice planthoppers, which can greatly help environmentally cultivation of crops including rice.
본 발명자는 전술한 과제를 해결하기 위하여 수많은 시험과 연구를 거듭한 결과, 님 오일 또는 아자디락틴이 식물성 유지로부터 얻어지는 천연물로서 우렁이, 거머리, 물방게 등 수생 동물에 대한 독성이 없는 등, 급성 독성이 약하고 어독성도 약하며, 농작물에 잔류가 되지 않아 친환경 해충방제제로 사용할 수 있다는 것에 착안하여, 본 발명을 완성하기에 이르렀다.As a result of numerous tests and studies in order to solve the above-mentioned problems, the inventors have found that neem oil or azadilactin is a natural product obtained from vegetable oils and is not toxic to aquatic animals such as worms, leeches and water droplets. The present invention has been completed in view of its weakness and weak fish toxicity, which can be used as an environmentally friendly pest control agent because it does not remain in crops.
구체적으로, 님 오일 또는 아자디락틴 분말을 활성 성분으로서 사용하고, 액상 동물성 기름과 식물성 기름을 단독 또는 혼용하며, 광물성 입자를 담체로 하여 분산제 등 보조제가 첨가된 입제; 또는, 활성 성분으로서 님 오일 또는 아자디락틴 분말을, 식물성 기름이나 액상 동물성 기름이 단독 또는 2종 이상 혼합된 기름에 균질하게 혼합된 수면 전개제 제형의 벼멸구 방제제가 제공된다. Specifically, granules using neem oil or azadilactin powder as an active ingredient, alone or in combination with liquid animal oil and vegetable oil, and supplementing agents such as dispersants with mineral particles as a carrier; Alternatively, neem oil or azadilactin powder as an active ingredient may be homogeneously added to vegetable oil or liquid animal oil alone or in a mixture of two or more thereof. Provided are rice control agents in mixed sleep developer formulations.
본 발명의 벼멸구 방제제는 상기한 바와 같이 크게 입제 제형과 수면 전개제 제형으로 분류할 수 있으며, 이를 이하에 구체적으로 설명한다.The rice plant control agent of the present invention can be largely classified into a granule formulation and a sleeping developer formulation as described above, which will be described in detail below.
입제형 벼멸구 방제제Granulated Creeper Control
본 발명에 따른 입제형 친환경 벼멸구 방제제는 님 오일 또는 아자디락틴을 함유하는 액상 동물성 기름과 식물성 기름이 혼합된 기름을 기제로 하고, 광물성 입자를 담체로 하여 분산제 등 보조제가 첨가된 입제로서, 더욱 구체적으로는 조립 식, 피복식 또는 흡착식 입제로 세분될 수 있다. 이를 좀 더 구체적으로 살펴보면,The granular eco-friendly rice plant control agent according to the present invention is a granule containing a liquid animal oil containing vegetable oil or azadilactin and an oil mixed with vegetable oil, and an auxiliary agent such as a dispersing agent added with mineral particles as a carrier. More specifically, it can be subdivided into granular, coated or adsorptive granules. Looking more specifically at this,
입제(Granule)에는 세가지 형태가 있는데There are three types of granules
1) 조립식입제(造粒式粒劑)는 주성분을 함유한 원제와 증량제, 보조제, 바인다 등을 사용하여 조립하고 건조하여 입도규격에 맞추어 선별하여 포장하는 공정에 의해 만들어진다.1) Prefabricated granules are made by the process of assembling, drying, sorting and packing according to the particle size standard using raw materials, extenders, auxiliaries, and binders containing the main ingredients.
2) 피복식입제(被覆式粒劑)는 광물질 담체(擔體: Carrier)에 접착물질인 바인더를 입히고 원제와 증량제를 피복(Coating)하거나, 원제를 용매에 녹여 분무함으로써 피복 및 건조시키는 방법으로 만들어진다.2) Coating type coating agent is a method of coating and drying by applying binder which is adhesive material to mineral carrier and coating original agent and extender, or dissolving original agent in solvent and spraying it. Is made.
3) 흡착식입제(吸着式粒劑)는 제올라이트, 벤토나이트,카올린 등 흡착력이 있는 광물질에 원제를 용매에 녹여 분무 등의 방법으로 원제를 흡착 시키고 건조하여 포장하는 공정에 의해 생산되며, 논, 밭등 포장(圃場)의 형태나 토양수분의 많고 적음에 따라 선택 사용할 수 있다.3) Adsorption type adsorbent is produced by dissolving the raw material in solvent with adsorbing mineral such as zeolite, bentonite, kaolin, etc. It can be used depending on the type of (i) or the high or low amount of soil moisture.
본 발명에 따른 입제형 벼멸구 방제제는:Granulated rice plant control according to the invention:
- 고등어, 꽁치 통조림에서 얻어지는 어유 또는 비료용 어분 제조공정에서 생산되는 어유를 비롯한 상온에서 액상 동물성 기름과 미강유, 카놀라유, 포도씨유, 팜유, 대두유, 피마자유, 땅콩기름, 들기름, 참기름, 유채유, 해바라기씨유, 홍화씨유, 면실유, 동백기름, 호박씨기름, 고추씨기름, 달맞이꽃기름, 호로과(수박, 박, 참외)씨기름, 옥수수유, 올리브유 중에서 선택되는 식물성 기름을 단독 또는 혼합하여 1 내지 20 중량%;-Liquid animal oil, rice bran oil, canola oil, grapeseed oil, palm oil, soybean oil, castor oil, peanut oil, perilla oil, sesame oil, rapeseed oil, sunflower at room temperature, including fish oil obtained from canned mackerel, saury or fish oil for fertilizer 1 to 20% by weight of vegetable oil selected from seed oil, safflower seed oil, cottonseed oil, camellia oil, pumpkin seed oil, red pepper seed oil, evening primrose oil, fenugreek (watermelon, gourd, melon) seed oil, corn oil and olive oil ;
- 카올린, 벤토나이트, 규조토, 탈크, 제올라이트, 화이트카본, 소성백토, 펄라이트, 소성황토, 버미큘라이트, 돌로마이트, 장석, 모래, 및 이들의 혼합물 중에서 선택된 담체 50 내지 90 중량%;50 to 90% by weight of a carrier selected from kaolin, bentonite, diatomaceous earth, talc, zeolite, white carbon, calcined clay, pearlite, calcined ocher, vermiculite, dolomite, feldspar, sand, and mixtures thereof;
- 님 오일과 아자디락틴 분말 중에서 선택된 적어도 1종의 활성성분 0.001 내지 20 중량%;0.001 to 20% by weight of at least one active ingredient selected from nim oil and azadilactin powder;
- 나프탈렌 설포네이트, 칼슘 리그노 설페이트(CLS), 소듐 리그노 설페이트(SLS), 포름알데히드, 폴리옥시에틸렌 노닐 페놀, 도데실벤젠설폰산, 솔벤트 나프타, Stoddard 용매, 디이소도데실 프탈레이트, 폴리비닐알코올(PVA) 및 프로필렌 글리콜 중에서 선택된 1종 이상의 분산제 0.1 내지 10 중량%Naphthalene sulfonate, calcium lignosulfate (CLS), sodium lignosulfate (SLS), formaldehyde, polyoxyethylene nonyl phenol, dodecylbenzenesulfonic acid, solvent naphtha, Stoddard solvent, diisododecyl phthalate, polyvinyl 0.1 to 10% by weight of one or more dispersants selected from alcohols (PVA) and propylene glycol
를 포함하여 이루어진다.It is made, including.
상온에서 액상인 동물성 기름의 원료의 예로는 고등어, 꽁치 등 통조림과 사료 또는 비료용 어분 제조공정에 사용되는 생선 기름, 즉 어유를 들 수 있다. Examples of raw materials of animal oil liquid at room temperature include fish oil, that is, fish oil used in canning such as mackerel, saury, and fish meal for feed or fertilizer.
흡착식 입제는 특히 제조 공정이 단순하고 원료가 저가여서 제조원가도 저렴하다는 장점이 있다.Adsorption type granules are particularly advantageous in that the manufacturing process is simple and the raw materials are inexpensive.
식물성기름 또는 액상 동물성 기름에 혼합된 아자디락틴은 물에는 용해되지 않고 분산제에 의해 물속에서 쉽게 분산되어 기름과 함께 물 표면으로 떠오르고 모세관 현상에 의하여 벼포기의 기부에 빨려 올라간다.Azadilactin mixed with vegetable oil or liquid animal oil is not dissolved in water, but is easily dispersed in water by a dispersant, floats with the oil to the surface of the water, and is sucked up to the base of rice dumpling by capillary action.
벼의 해충 중 큰 피해를 주는 벼멸구가 수분이 많은 기부에서 서식하며 즙액을 빨아 먹으므로 본 발명의 입제형 방제제는 벼멸구 방제에 특효가 있다.Among the pests of rice, the rice planter inhabits on the juicy base and sucks the juice, so the granule control agent of the present invention is effective in controlling the rice planter.
입제에 사용되는 담체로는 카올린, 밴토나이트, 규조토, 탈크, 제올라이트, 화이트카본, 소성백토, 펄라이트, 버미큘라이트, 소성황토, 돌로마이트, 장석, 모 래 등을 들 수 있고 제형에 따라 입상 또는 분상을 단독 또는 2종이상 혼용할 수 있다. Carriers used in granulation include kaolin, vantonite, diatomaceous earth, talc, zeolite, white carbon, calcined clay, pearlite, vermiculite, calcined ocher, dolomite, feldspar, sand, etc. Or two or more types can be mixed.
각제형의 담체의 입도(분말도)는 조립식 입제 피복식 입제와 흡착식 입제, 모두 대체적으로 4 내지 250 메쉬의 것을 사용하였다. 조립식 입제의 경우 입자가 고와야 하므로 250 메쉬 정도까지 미세한 분말을 사용하고, 흡착식 입제는 4 메쉬 정도로 입도가 굵어도 무방하다. 그러나 본 발명에 사용되는 담체의 입도가 반드시 상기 범위로 한정되는 것은 아니다.The particle size (powder degree) of each carrier of granular type | mold granules | coating type | mold granules and adsorptive granules, and generally used the thing of 4-250 mesh. In the case of the granulated granules, since the particles must be coarse, a fine powder is used up to about 250 mesh, and the adsorptive granules may have a grain size of about 4 mesh. However, the particle size of the carrier used in the present invention is not necessarily limited to the above range.
피복식입제에 사용되는 담체는 모래와 같은 흡착력이 거의 없는것은 접착력이 있는 바인더를 가해주고 원제를 피복시키거나 원제를 용해하여 흡착시킨 분말을 피복 시킬 수 도 있다.Carriers used in coating binders may be coated with a binder that has little adsorptive power such as sand, and may be coated with a raw material or a powder adsorbed by dissolving the raw material.
여기에 사용되는 바인더로는 접촉효과가 있는 폴리비닐 알코올(PVA:Polyvinyl alcohol), 당밀 (CMS: Condensed Molasses Soluble), 리그닌, 당류를 들 수 있고, 흡착식 입제에 사용되는 담체중 제올라이트처럼 흡착력이 강한 것은 분산제와 비료등 첨가물을 먼저 흡착시키고 식물성기름과 님 오일 또는 아자디락틴 용액을 흡착시킬 수 도 있다. Examples of the binder used include polyvinyl alcohol (PVA), molasses (CMS: Condensed Molasses Soluble), lignin, and sugars, which have a high adsorption power, such as zeolite. It may also adsorb additives such as dispersants and fertilizers first and then adsorb vegetable oil and nim oil or azadilactin solution.
본 발명의 흡착식입제와 피복식입제에 첨가되는 기름의 양은 입제 총량에 대하여 1 내지 20 중량%로 바람직하게는 5 내지 20 중량% 이다.The amount of oil added to the adsorbent binder and the coating agent of the present invention is 1 to 20% by weight, preferably 5 to 20% by weight, based on the total amount of the particles.
기름의 량이 1% 미만이면 방제 효과가 없고 20%를 초과하면 흡착 또는 피복을 시킬 수가 없다.If the amount of oil is less than 1%, there is no control effect. If the amount of oil is more than 20%, it cannot be adsorbed or coated.
기름의 종류는 미강유, 카놀라유, 포도씨유, 팜유, 대두유, 피마자유, 땅콩 기름, 들기름, 참기름, 유채유, 해바라기씨유, 홍화씨유, 면실유, 동백기름, 호박씨기름, 고추씨기름, 달맞이꽃기름, 호로과(수박, 박, 참외)씨기름, 옥수수유, 올리브유 중에서 선택되는 식물성 기름이나, 고등어, 꽁치 통조림에서 얻어지는 어유 또는 비료용 어분 제조공정에서 생산되는 어유를 단독으로 또는 2종 이상 혼합하여 사용할 수 있다. Types of oil are rice bran oil, canola oil, grape seed oil, palm oil, soybean oil, castor oil, peanut oil, perilla oil, sesame oil, rapeseed oil, sunflower seed oil, safflower seed oil, cottonseed oil, camellia oil, pumpkin seed oil, red pepper seed oil, evening primrose oil, Vegetable oil selected from watermelon, watermelon, melon) seed oil, corn oil, olive oil, fish oil obtained from canned mackerel, saury, or fish oil produced in a fish meal for fertilizer can be used alone or in combination of two or more kinds.
본 발명에 따른 벼멸구 방제제의 활성 성분인 님 오일 또는 아자디락틴은 시중에서 시판하는 님 오일 또는 고순도 아자디락틴 원제, 예컨대 아자디락틴 26% 분말일 수 있으며, 아자디락틴 함량 기준으로 입제 총량에 대하여 0.0004 내지 4 중량%, 바람직하게는 0.004 내지 0.4중량%의 양으로 함유되는 것이 좋다.Neem oil or azadilactin, the active ingredient of the rice plant control agent according to the present invention may be a commercially available nime oil or a high purity azadilactin raw material, such as azadilactin 26% powder, based on azadilactin content It is preferably contained in an amount of 0.0004 to 4% by weight, preferably 0.004 to 0.4% by weight.
아자디락틴 원제의 순도는 대략 0.01 내지 90 중량%로서 바람직하게는 0.3 내지 60 중량%의 것을 사용한다. 본 발명에서는 아자디락틴 함량 3%의 님 오일과, 아자디락틴 함량 26%의 아자디락틴 분말을 주로 사용하였다.The purity of the azadilactin base is approximately 0.01 to 90% by weight, preferably 0.3 to 60% by weight. In the present invention, a nimal oil having azadilactin content of 3% and azadilactin powder having azadilactin content of 26% were mainly used.
담체의 양은 50 내지 90 중량%로 바람직하게는 60 내지 90중량% 이다.The amount of carrier is 50 to 90% by weight, preferably 60 to 90% by weight.
입제의 기름성분 분산제로는 유화가 되지 않고 물 표면에 떠올라 분산되는 물질을 사용하며, 음이온성 고분자형 분산제, 중성고분자형 분산제를 들 수 있다. 예를 들면 나프탈렌 설포네이트, 칼슘 리그노 설페이트 (CLS), 소듐 리그노 설페이트 (SLS), 포름알데하이드, 폴리옥시에틸렌 노닐 페놀, 도데실 벤젠 설폰산, 솔벤트 나프타, Stoddard 용매, 디이소도데실 프탈레이트, 폴리비닐알코올(PVA) 등을 들 수 있다.As the oil-based dispersant of the granules, a substance which floats and disperses on the surface of water without emulsification is used, and anionic polymer type dispersants and neutral polymer type dispersants are mentioned. For example naphthalene sulfonate, calcium lignosulfate (CLS), sodium lignosulfate (SLS), formaldehyde, polyoxyethylene nonyl phenol, dodecyl benzene sulfonic acid, solvent naphtha, Stoddard solvent, diisododecyl phthalate, Polyvinyl alcohol (PVA) etc. are mentioned.
활성성분으로서 고순도 아자디락틴 분말을 사용할 경우, 디메틸포름아미 드(DMF), 디메틸설폭사이드(DMS), 메탄올, 에탄올, 이소프로필알코올, 에틸렌 글리콜, 헥산, 페트롤륨 에테르, 아세톤, N-메틸-2-피롤리돈 중에서 선택된 단독 또는 2종 이상의 용매 0.1 내지 20 중량%에 아자디락틴 분말을 용해시켜 사용할 수 있다. When using high purity azadilactin powder as active ingredient, dimethylformamide (DMF), dimethylsulfoxide (DMS), methanol, ethanol, isopropyl alcohol, ethylene glycol, hexane, petroleum ether, acetone, N-methyl- It can be used by dissolving azadilactin powder in 0.1-20% by weight of a single or two or more solvents selected from 2-pyrrolidone.
수면전개제 제형의 벼멸구 방제제Insecticides in Sleep Development Formulations
본 발명에서 수면전개제 제형이라 함은, 물에 희석할 경우, 물에 용해되거나 현탁이 되는 유제나 액제 제형과는 달리, 물에 뿌릴 경우 물에 용해되거나 현탁됨이 없이 물 위에 뜨게 되는 제형을 가리키며, 활성성분이 기름층에만 있으므로 소량으로도 우수한 살충 효과를 나타낸다.Sleep development formulations in the present invention, when diluted in water, unlike emulsions or liquid formulations that are dissolved or suspended in water, when sprayed in water is a formulation that floats on water without being dissolved or suspended in water. It shows excellent insecticidal effect even in small amount because the active ingredient is only in the oil layer.
또한, 수면전개제는 액체이므로 병 뚜껑만 열어 수면에 뿌리면 활성성분인 님 오일이나 아자디락틴이 수면에 골고루 퍼지므로 별도로 살포기를 사용할 필요가 없으므로 사용도 매우 간편하다는 장점이 있다.In addition, since the sleep development agent is a liquid, only the bottle cap is sprayed on the water surface, and thus active ingredient Nim oil or azadilactin is spread evenly on the water surface, so there is no need to use a separate sprayer.
보통 기름 성분은 수면에서 표면장력 때문에 둥글게 뭉쳐져 있게 되므로, 벼 잎집에 쉽게 빨려 올라가지 못하므로 충분한 약효를 발휘할 수 없다. 따라서, 본 발명의 수면전개제 제형은 오일의 표면 장력을 파괴할 수 있도록 계면활성제를 사용한다. Normally, oil components are rounded together due to surface tension at the surface of the water, so they are not easily sucked up by the rice leaves, so they cannot exert sufficient effects. Accordingly, the sleep spreader formulations of the present invention use surfactants to break the surface tension of the oil.
구체적으로, 본 발명에 따른 수면전개제 제형의 벼멸구 방제제는:Specifically, the rice plant control agent of the sleep development formulation according to the present invention:
- 고등어, 꽁치 통조림에서 얻어지는 어유 또는 비료용 어분 제조공정에서 생산되는 어유를 비롯한 상온에서 액상 동물성 기름과 미강유, 카놀라유, 포도씨유, 팜유, 대두유, 피마자유, 땅콩기름, 들기름, 참기름, 유채유, 해바라기씨유, 홍화씨유, 면실유, 동백기름, 호박씨기름, 고추씨기름, 달맞이꽃기름, 호로과(수박, 박, 참외)씨기름, 옥수수유, 올리브유 중에서 선택되는 식물성 기름을 단독 또는 혼합하여 50 내지 90 중량%;-Liquid animal oil, rice bran oil, canola oil, grapeseed oil, palm oil, soybean oil, castor oil, peanut oil, perilla oil, sesame oil, rapeseed oil, sunflower at room temperature, including fish oil obtained from canned mackerel, saury or fish oil for fertilizer 50 to 90% by weight of vegetable oil selected from seed oil, safflower seed oil, cottonseed oil, camellia oil, pumpkin seed oil, red pepper seed oil, evening primrose oil, fenugreek (watermelon, gourd and melon) seed oil, corn oil and olive oil ;
- 아크릴산 폴리머 나트륨염, 소듐 비스(2-에틸헥실)설포숙시네이트, 폴리비닐 알코올, 잔탄 검, 칼슘 리그노설페이트, 소르비탄 올리에이트, 폴리에틸렌 소르비탄 올리에이트, 프로필렌 글리콜, 옥솔란, CAS NO 166736-08-9 (oxirane 2-methyl polymer with oxirane, mono(2-propylheptyl)ether) 중에서 선택된 수면전개용 계면활성제 0.1 내지 30 중량%;Acrylic acid polymer sodium salt, sodium bis (2-ethylhexyl) sulfosuccinate, polyvinyl alcohol, xanthan gum, calcium lignosulfate, sorbitan oleate, polyethylene sorbitan oleate, propylene glycol, oxolane, CAS NO 166736-08-9 (oxirane 2-methyl polymer with oxirane, mono (2-propylheptyl) ether) from 0.1 to 30% by weight of a surfactant for sleep development;
- 활성성분으로서 님 오일과 아자디락틴 분말 중에서 선택된 적어도 1종의 활성성분 0.001 내지 20 중량%0.001 to 20% by weight of at least one active ingredient selected from nim oil and azadilactin powder as active ingredients
를 포함하여 이루어진다.It is made, including.
상기 설명한 입제에서와 마찬가지로, 수면전개제에 사용되는 상온에서 액상인 동물성 기름의 원료의 예로는 고등어, 꽁치 등 통조림과 사료 또는 비료용 어분 제조공정에 사용되는 생선 기름, 즉 어유를 들 수 있다. As in the granulation described above, examples of the raw material of the animal oil liquid at room temperature used in the sleep development agent include fish oil, that is, fish oil used in canning such as mackerel, saury, and fish meal for feed or fertilizer.
본 발명의 상기 성분 중 수면전개제용 계면활성제는 오일의 표면 장력을 파괴하기 위하여 사용되며, 음이온성 또는 비이온성 계면활성제를 사용한다. 구체적으로는 아크릴산 폴리머 나트륨염, 소듐 비스(2-에틸헥실)설포숙시네이트, 폴리비닐 알코올, 잔탄 검, 칼슘 리그노설페이트, 소르비탄 올리에이트, 폴리에틸렌 소르비탄 올리에이트 중에서 선택된 수면전개용 계면활성제를 사용한다. 계면활성제의 양이 0.1 중량% 미만이면 수면 전개 효과가 없고, 30%를 초과하면 수면 전개 효과 가 더 높아지지도 않고 경제적인 측면에서 바람직하지 않다.Among the above components of the present invention, the surfactant for sleep development is used to break the surface tension of oil, and an anionic or nonionic surfactant is used. Specifically, surfactant for sleep development selected from acrylic acid polymer sodium salt, sodium bis (2-ethylhexyl) sulfosuccinate, polyvinyl alcohol, xanthan gum, calcium lignosulfate, sorbitan oleate and polyethylene sorbitan oleate Use If the amount of the surfactant is less than 0.1% by weight, there is no sleep development effect, and if it exceeds 30%, the sleep development effect is not higher and it is not preferable in terms of economy.
계면활성제를 첨가하면 물 표면에 얇은 기름 피막이 형성되어 모세관 현상에 의해 벼 포기의 잎집으로 물과 기름이 빨려 올라가게 된다.When surfactant is added, a thin oil film is formed on the surface of the water, which causes water and oil to be sucked up to the leaf sheaths of rice abandoned by capillary action.
본 발명의 수면 전개제 제형 방제제에 첨가되는 기름의 양은 수면 전개제 제형 총량에 대하여 50 내지 90 중량%로 바람직하게는 60 내지 90 중량% 이다. 상기 범위를 초과할 경우 방제 효과가 없거나, 비효율적이다.The amount of oil added to the sleeping developer formulation control agent of the present invention is 50 to 90% by weight, preferably 60 to 90% by weight, relative to the total amount of the sleeping developer formulation. If it exceeds the above range, there is no control effect or it is inefficient.
기름의 종류는 미강유, 카놀라유, 포도씨유, 팜유, 대두유, 피마자유, 땅콩기름, 들기름, 참기름, 유채유, 해바라기씨유, 홍화씨유, 면실유, 동백기름, 호박씨기름, 고추씨기름, 달맞이꽃기름, 호로과(수박, 박, 참외)씨기름, 옥수수유, 올리브유 중에서 선택되는 식물성 기름이나, 고등어, 꽁치 통조림에서 얻어지는 어유 또는 비료용 어분 제조공정에서 생산되는 어유를 단독으로 또는 2종 이상 혼합하여 사용할 수 있다. Types of oil are rice bran oil, canola oil, grape seed oil, palm oil, soybean oil, castor oil, peanut oil, perilla oil, sesame oil, rapeseed oil, sunflower seed oil, safflower seed oil, cottonseed oil, camellia oil, pumpkin seed oil, red pepper seed oil, evening primrose oil, fenugreek ( Vegetable oil selected from watermelon, watermelon, melon) seed oil, corn oil, olive oil, fish oil obtained from canned mackerel, saury, or fish oil produced in a fish meal for fertilizer can be used alone or in combination of two or more kinds.
본 발명에 따른 벼멸구 방제제의 활성 성분인 님 오일 또는 아자디락틴은 시중에서 시판하는 님 오일 또는 고순도 아자디락틴 원제, 예컨대 아자디락틴 26% 분말일 수 있으며, 아자디락틴 함량 기준으로 입제 총량에 대하여 0.0004 내지 4 중량%, 바람직하게는 0.004 내지 0.4중량%의 양으로 함유되는 것이 좋다. Neem oil or azadilactin, the active ingredient of the rice plant control agent according to the present invention may be a commercially available nime oil or a high purity azadilactin raw material, such as azadilactin 26% powder, based on azadilactin content It is preferably contained in an amount of 0.0004 to 4% by weight, preferably 0.004 to 0.4% by weight.
아자디락틴 원제의 순도는 대략 0.01 내지 90 중량%로서 바람직하게는 0.3 내지 60 중량%의 것을 사용한다. 본 발명에서는 아자디락틴 함량 3%의 님 오일과, 아자디락틴 함량 26%의 아자디락틴 분말을 주로 사용하였다.The purity of the azadilactin base is approximately 0.01 to 90% by weight, preferably 0.3 to 60% by weight. In the present invention, a nimal oil having azadilactin content of 3% and azadilactin powder having azadilactin content of 26% were mainly used.
즉, 님 오일이나 아자디락틴 분말은 아자디락틴 기준 40 ppm 정도의 미량으 로도 방제 효과가 있는데, 님 오일 유제나 아자디락틴 액제와 같이 물에 녹거나 현탁이 되는 제형의 경우, 논물 전체가 40 ppm이 되기 위해서는 주성분인 님 오일이나 아자디락틴의 양이 많이 필요하게 된다. That is, neem oil or azadilactin powder is effective in controlling a small amount of about 40 ppm based on azadilactin.In the case of a formulation that is dissolved or suspended in water such as neem oil emulsion or azadilactin liquid, To reach 40 ppm, a large amount of nim oil or azadilactin, which is the main ingredient, is required.
그러나, 본 발명의 수면전개제 제형 또는 상기한 입제 제형은 수면에 떠 있는 기름에만 님 오일 또는 아자디락틴 성분이 섞여 있으므로 아자디락틴 극미량으로도 약효를 나타낼 수 있다. 즉, 유제나 액제 제형의 경우의 주성분량에 비해 500분의 1내지 1,000분의 1의 양만으로도 방제 효과를 나타낼 수 있으므로 경제적이고도 친환경적이다.However, the sleeping agent formulation or the above-described granule formulation of the present invention may be effective even in a very small amount of azadilactin since nim oil or azadilactin component is mixed only with oil floating on the surface. That is, it is economical and environmentally friendly as it can exhibit a control effect only in an amount of 1/500 to 1 / 1,000 compared to the main component amount in the case of emulsion or liquid formulation.
또한, 활성성분으로서 고순도 아자디락틴 분말을 사용할 경우, 디메틸포름아미드(DMF), 디메틸설폭사이드(DMS), 메탄올, 에탄올, 이소프로필알코올, 에틸렌 글리콜, 헥산, 페트롤륨 에테르, 아세톤, N-메틸-2-피롤리돈 중에서 선택된 단독 또는 2종 이상의 용매 0.1 내지 20 중량%에 아자디락틴 분말을 용해시켜 사용할 수 있다. In addition, when high purity azadilactin powder is used as the active ingredient, dimethylformamide (DMF), dimethyl sulfoxide (DMS), methanol, ethanol, isopropyl alcohol, ethylene glycol, hexane, petroleum ether, acetone, N-methyl It can be used by dissolving azadilactin powder in 0.1 to 20% by weight of a single or two or more solvents selected from -2-pyrrolidone.
한편, 벼멸구 방제 효과 뿐만 아니라, 기타의 살충 효과를 증진시키고, 적용대상 작물과 병해충의 방제범위를 넓히며, 아울러 제초효과를 거두는 등의 상승효과를 유도하기 위하여, 본 발명의 입제 또는 수면전개제 제형의 벼멸구 방제제에는 다음의 항균제나 제초제, 기타 살충제 성분을 추가로 포함시킬 수 있다. 이들 성분의 함량과 용법은 당업자에게 잘 알려져 있다.On the other hand, in order to enhance the pesticidal effect, as well as other pesticidal effects, to broaden the range of control of crops and pests to be applied, and to induce synergistic effects such as herbicidal effect, granulation or sleep development formulation of the present invention. The rice pesticide control of may further contain the following antibacterial, herbicides, and other pesticides. The content and usage of these components are well known to those skilled in the art.
소리쟁이, 대황추출물:크리소파놀, 파리에틴, 네포딘 - 흰가루병 방제 Blackberry, Rhubarb extract: Crisopanol, parietin, nepodine-powdery mildew control
울금 추출물: 커커민(CM:curcumin), 디메톡시커커민(DCM:dimethoxycurcumin) - 벼도열병, 고추역병, 도마도 역병 방제; Turmeric extract: curcumin (CM: curcumin), dimethoxycurcumin (DCM)-rice fever, red pepper blight, tomato blight control;
담배 추출물: 니코틴 - 니코틴 방제, Tobacco Extract: Nicotine-Nicotine Control,
유채 추출물: 펠라곤산(pelagonic acid) - 제초제; Rapeseed extract: Pelagonic acid-herbicide;
고삼 추출물: 마트린 (matrin) - 살충제;Ginseng extract: matrin-insecticide;
사바딜라(Sabadilla) 추출물: 베라트린(varatrine), 세바딘(cevadine); Sabadilla extracts: varatrine, cevadine;
라이아니아 추출물: 라이아니아Liania Extract: Liania
제충국 추출물: 피레트린(pyrethrine)을 포함하는 제충국 추출물; Pyrethrum extract: Pyrethrum extract, including pyrethrine;
데리스 추출물: 데리스 - 살충제; Deris Extract: Deris-Insecticide;
쿠아시아 추출물: 쿠아시아 - 벼멸구, 진딧물 등 방제; Ku-Asia Extract: Ku-Asia-Control of rice plant, aphids, etc .;
미생물 제제: 바실러스 서브틸리스 (Bacillus subtilis), 바실러스 써린지엔시스 (Bacillus thrungiensis), 바실러스 피르무스 (Bacillus firmus); 및Microbial agents: Bacillus subtilis (Bacillus subtilis), Bacillus written Lindsay N-Sys (Bacillus thrungiensis), Bacillus pireu Moose (Bacillus firmus); And
스트렙토마이신, 카스가마이신, 브라스티시딘-s, 폴리옥신류Streptomycin, kasugamycin, brastigidin-s, polyoxins
이하에 실시예를 들어 본 발명을 더욱 상세히 설명하나, 본 발명의 범위와 정신은 첨부된 특허청구범위를 벗어나지 않는 한, 얼마든지 변형이 가능하며, 하기 실시예로 본 발명의 범위가 한정되는 것은 아니다.Hereinafter, the present invention will be described in more detail with reference to Examples, but the scope and spirit of the present invention can be modified as many as possible without departing from the appended claims, and the scope of the present invention is limited to the following Examples. no.
실시예Example
입제 제형Granule formulation
<제조예 1><Manufacture example 1>
다음 표 1의 제조 처방과 같이 입상 규조토(24~40메쉬)를 담체로 하여 포도씨기름, 아자디락틴 디메틸 포름아미드(DMF)용액, 분산제로서 칼슘 리그노 설페이 트(CLS)를 골고루 혼합하고, 혼합용액을 분무하여 골고루 흡착시키고 건조하여 아자디락틴 입제 3kg을 제조하였다.As shown in Table 1, granular diatomaceous earth (24-40 mesh) is used as a carrier, and grape seed oil, azadilactin dimethyl formamide (DMF) solution and calcium lignosulphate (CLS) are uniformly mixed as a dispersant. Spray the mixed solution to adsorb evenly and dry to prepare 3kg of azadilactin granules.
* ( )내 숫자는 건조시 증발량 * The number in () is the amount of evaporation when drying
<제조예2><Production Example 2>
다음 표 2의 조성을 이용하여 제조예 1과 동일한 방법으로 벼멸구 방제용으로 아자디락틴 입제 3kg을 제조하였다.Next, using the composition of Table 2, 3kg of azadilactin granules were prepared in the same manner as in Preparation Example 1 for the control of rice bran.
< 제조예 3 > <Manufacture example 3>
다음 표 3의 조성을 이용하여 모래에 PVA를 물에 용해한 액을 골고루 피복하고 돌로마이트 분말과 CLS를 혼합하여 접착시키고 아자디락틴 분말을 DMF에 용해하여 유채유와 혼합하고 분무(Spray)하여 흡착시키고 건조하여 아자디락틴 피복입제 3kg을 생산하였다.Next, evenly coat the solution of PVA dissolved in water in the sand using the composition shown in Table 3, adhering by mixing Dolomite powder and CLS, adhering azadilactin powder to DMF, mixing with rapeseed oil, spraying, adsorbing, and drying. 3 kg of azadilactin coated granules were produced.
상기 제조예 3에서 모래 대신 입상장석을 사용해도 무방하다. 또한 조립식 입제에 돌로마이트 분말을 사용하면 크게 원가가 절감되는 효과가 있다.In manufacture example 3, granular feldspar may be used instead of sand. In addition, the use of dolomite powder in the granulated granulation has a significant cost reduction effect.
<제조예 4>≪ Preparation Example 4 &
다음 표 4의 조성 원료를 이용하여 분상의 원료들만 따로 혼합하고 분상원료에 님 오일이 혼합된 동물성기름인 어유와 바인더를 분무하여 원판형 회전 조립기로 조립(구형 입제)시킨 다음 건조하여 님 오일 입제 10kg을 생산하였다.Next, ingredients of powdery ingredients are mixed separately using the raw materials of Table 4, sprayed fish oil and binder, which are animal oils mixed with Nimes oil, are assembled into a disc-shaped rotary granulator (spherical granules), and then dried to form Nimes oil. 10 kg was produced.
님 오일(아자디락틴3%)
돌로마이트분말(200메쉬)
카올린분말
CLS
리그닌Fish oil
Nim oil (3% of azadilactin)
Dolomite Powder (200 Mesh)
Kaolin powder
CLS
Lignin
0.15
67.85
10
4
5(15)13
0.15
67.85
10
4
5 (15)
15
6,785
1,000
400
500(1,500)1,300
15
6,785
1,000
400
500 (1,500)
인도산
(주)백광소재
한백인터겜(주)
유성화연테크(주)
(주)백광소재 Hanjin Industry
Indian
Baekwang Material Co., Ltd.
Hanbaek Intergem Co., Ltd.
Yousung Hwayeon Tech Co., Ltd.
Baekwang Material Co., Ltd.
<제조예 5>Production Example 5
다음 표 5의 조성원료를 이용하여 “제조예 4”와 같이 제조하여 님 오일 입제 10kg을 생산하였다.Next, using the composition of the ingredient in Table 5 was prepared as "Preparation Example 4" to produce 10kg granules of Nim oil.
카놀라유
님 오일(아자디락틴3%)
돌로마이트분말(200메쉬)
카올린분말
CLS
리그닌Fish oil
Canola oil
Nim oil (3% of azadilactin)
Dolomite Powder (200 Mesh)
Kaolin powder
CLS
Lignin
7
0.15
67.85
10
4
5(15)6
7
0.15
67.85
10
4
5 (15)
700
15
6,785
1,000
400
500(1,500)600
700
15
6,785
1,000
400
500 (1,500)
(주)사조해표
인도산
(주)백광소재
한백인터겜(주)
유성화연테크(주)
(주)백광소재 Hanjin Industry
Sajo Seacoast Co., Ltd.
Indian
Baekwang Material Co., Ltd.
Hanbaek Intergem Co., Ltd.
Yousung Hwayeon Tech Co., Ltd.
Baekwang Material Co., Ltd.
<제조예 6><Manufacture example 6>
다음 표 6의 조성원료를 이용하여 님 오일과 쿠아시아 추출물(메탄올로 추출)을 혼합하고 리그닌을 가하여 균질하게 혼합하고, 돌로마이트, 카오린 과 CLS를 혼합한 분말을 회전 원판조립기에 고르게 펴고 앞의 미리 준비한 액을 분무하여 조립하고 건조시킴으로써 벼멸구 방제용 님 오일, 쿠아시아 혼합입제 1kg을 생산하였다.Next, mix Nim oil and Ku-Asia extract (extracted with methanol) using the ingredients in Table 6, add lignin and mix it homogeneously, evenly spread the powder mixed with dolomite, kaolin and CLS in a rotating disc assembler The prepared solution was sprayed, granulated, and dried to produce 1 kg of neem oil and Ku-Asia granules for rice planting control.
님 오일(아자디락틴3%)
쿠아시아 추출물
콩기름
돌로마이트분말(200메쉬)
카올린분말
리그닌
Nim oil (3% of azadilactin)
Kuasian extract
Soybean oil
Dolomite Powder (200 Mesh)
Kaolin powder
Lignin
0.15
5
13
64.85
7
6(15)
0.15
5
13
64.85
7
6 (15)
1.5
50
13
648.5
70
60(150)
1.5
50
13
648.5
70
60 (150)
인도산
자마이카산
(주)사조해표
(주)백광소재
한백인터겜(주)
(주)백광소재
Indian
Jamaica
Sajo Seacoast Co., Ltd.
Baekwang Material Co., Ltd.
Hanbaek Intergem Co., Ltd.
Baekwang Material Co., Ltd.
<시험예 1><Test Example 1>
제조예 1 및 제조예 2의 흡착식 입제와, 제조예 3의 피복식 입제, 및 제조예 4의 조립식 입제 등 총 4종의 제품을 용출시험을 하였다. Adsorption type granules of Production Example 1 and Production Example 2, coated granulation of Production Example 3, and granulated granulation of Production Example 4 A total of four products were tested for dissolution.
시험은 500 ml 비커에 물 300 ml를 담고 시제품 1.5 g씩을 가하여 5분간 용출시킨 결과를 육안검사 하였다. In the test, 300 ml of water was added to a 500 ml beaker, and 1.5 g of a test sample was added to the resultant to elute for 5 minutes.
도 1에 상기 4가지 입제의 용출시험 결과를 도시한 사진을 나타내었다. 도 1로부터 알 수 있는 바와 같이, 제조예 1, 제조예 2, 제조예 3 및 제조예 4 모두 잘 용출된 것으로 나타났다. 제조예 2의 경우 제올라이트의 흡착력이 다른 담체에 비하여 크기 때문에 나머지 세가지 제조예에 비해 용출력은 상대적으로 떨어지는 것으로 나타났다.Figure 1 shows a photograph showing the dissolution test results of the four granules. As can be seen from Figure 1, Preparation Example 1, Preparation Example 2, Preparation Example 3 and Preparation Example 4 all appeared to be well eluted. In Preparation Example 2, since the adsorption force of the zeolite is larger than that of the other carriers, the dissolving power was relatively lower than that of the other three preparation examples.
<시험예 2> <Test Example 2>
온실내 논 3.3m2에 벼 80주씩을 심고 망을 쳐서 곤충의 출입을 차단한 후 벼멸구 성충 200 마리 씩을 방사하여 “실시예 2,4,5.6”의 시료를 17g씩 수면에 살포하고 다음 식에 따라 10일후 생충율(방제가)을 조사한 결과 각각 85%, 87%, 86% 및 81%로 방제된 것으로 나타났다. 방제가는 다음 식에 따라 구하였다On interior non 3.3m ssikeul rice plant 80 weeks in two spray hit the net and then block the entry of insects by emission of a sample of 200 adult ssikeul BPH "Example 2,4,5.6" on the surface of the water and 17g by the following formula: As a result, after 10 days, the insecticides were controlled to 85%, 87%, 86% and 81%. The control value was obtained according to the following equation.
수면전개제 제형Sleep Development Agent Formulations
<제조예 7> <Manufacture example 7>
님 오일(아자디락틴3%)
수면전개제(CLS)Cooking Oil (Corn Oil)
Nim oil (3% of azadilactin)
Sleep development system (CLS)
0.15
1089.85
0.15
10
1.5
100898.5
1.5
100
인도산
(주)유성화연테크Sajo Seacoast Co., Ltd.
Indian
Yousung Hwayeon Tech Co., Ltd.
상기 표 7의 조성에 따라, 옥수수기름과 님 오일을 정확히 계량하고 수면전개제용 계면활성제로서 CSL (칼슘 리그노설페이트)를 첨가하여 아자디락틴 (45 ppm) 수면전개제 1 kg을 제조하였다.According to the composition of Table 7, 1 kg of azadilactin (45 ppm) was developed by accurately measuring corn oil and nim oil and adding CSL (calcium lignosulfate) as a surfactant for sleep development.
<제조예 8> <Manufacture example 8>
식용유(포도씨기름)
아자디락틴(26%)분말
DMF
계면활성제(아크릴산 폴리머 나트륨염)
Cooking Oil (Grape Seed Oil)
Azadilactin (26%) Powder
DMF
Surfactant (Acrylic Acid Polymer Sodium Salt)
87.983
0.017
2
10
87.983
0.017
2
10
879.83
0.17
20
100
879.83
0.17
20
100
(주)사조해표
인도산
화공약품
(주)코실
Sajo Seacoast Co., Ltd.
Indian
Chemical
Kosil
상기 표 8의 조성에 따라, 식물성기름(포도씨기름)과 DMF (디메틸 포름아미드)에 용해시킨 아자디락틴을 혼합하고 수면전개제용 계면활성제로서 아크릴산 폴리머 나트륨염을 첨가하여 아자디락틴 수면 전개제 1kg을 생산하였다.According to the composition of Table 8, 1 kg of azadilactin sleep developing agent by mixing azadilactin dissolved in vegetable oil (grape seed oil) and DMF (dimethyl formamide) and adding acrylic acid polymer sodium salt as a surfactant for sleep development. Produced.
<제조예 9><Manufacture example 9>
님 오일(아자디락틴3(%계면활성제(소르비탄 올리에이트)Canola oil
Nimes oil (azadilactin 3 (% surfactant (sorbitan oleate)
0.15
1089.85
0.15
10
1.5
100898.5
1.5
100
인도산
(주)유성화연테크Sajo Seacoast Co., Ltd.
Indian
Yousung Hwayeon Tech Co., Ltd.
상기 표 9의 조성에 따라 식물성 기름인 카놀라유와 님 오일을 혼합하고 수면전개제용 계면활성제로서 소르비탄 올리에이트를 첨가한 다음 균질하게 혼합시켜 아자디락틴 수면전개제 1 kg을 생산하였다.According to the composition of Table 9, vegetable oil canola oil and Nim oil were mixed, sorbitan oleate was added as a surfactant for sleep development, and then homogeneously mixed to produce 1 kg of azadilactin sleep development.
<제조예 10>Production Example 10
어유(고등어기름)
님 오일(아자디락틴3%)
계면활성제(소듐 비스(2-에틸헥실)설포숙시네이트 + 소르비탄 올리에이트)
Fish oil (mackerel oil)
Nim oil (3% of azadilactin)
Surfactant (sodium bis (2-ethylhexyl) sulfosuccinate + sorbitan oleate)
89.85
0.15
10(5+5)
89.85
0.15
10 (5 + 5)
898.5
1.5
100
898.5
1.5
100
한진산업(주)
인도산
(주)코실
Hanjin Industry
Indian
Kosil
상기 표 10의 조성에 따라 액상 어유 기름인 고등어 기름과 님 오일을 혼합하고, 수면전개제용 계면활성제로서 소듐 비스(2-에틸헥실)설포숙시네이트와 소르비탄 올리에이트를 첨가하여 아자디락틴 수면전개제 1 kg을 제조하였다.According to the composition of Table 10, the liquid fish oil oil mackerel oil and Nim oil are mixed, and azadilactin sleep by adding sodium bis (2-ethylhexyl) sulfosuccinate and sorbitan oleate as a surfactant for sleep development 1 kg of developer was prepared.
<제조예 11>Production Example 11
어유(꽁치)기름
식용유(팜유)
님 오일(아자디락틴3%)
계면활성제(PVA95)
Fish oil
Cooking Oil (Palm Oil)
Nim oil (3% of azadilactin)
Surfactant (PVA95)
45
44.85
0.15
10
45
44.85
0.15
10
450
448.5
1.5
100
450
448.5
1.5
100
한진산업(주)
(주)사조해표
인도산
(주)코실
Hanjin Industry
Sajo Seacoast Co., Ltd.
Indian
Kosil
상기 표 11의 조성에 따라, 액상 동물성 기름인 꽁치 기름과 식물성 기름으로서 팜유를 혼합한 기름과 님 오일을 잘 혼합하고 계면활성제용 수면전개제용 계면활성제로서 PVA95 (폴리비닐알코올 95)를 첨가하여 아자디락틴 수면전개제 1 kg을 제조하였다.According to the composition of Table 11, aza by mixing liquid oil and salam oil with palm oil as vegetable oil mixed well with Nim oil and adding PVA95 (polyvinyl alcohol 95) as a surfactant for a sleep development surfactant for surfactant 1 kg of dilactin sleep developing agent was prepared.
<제조예 12>Production Example 12
님 오일(아자디락틴3%)
울금추출물(Curcumin)
계면활성제 (폴리옥시에틸 소르비탄 올리에이트)
콩기름
Nim oil (3% of azadilactin)
Curcumin
Surfactant (polyoxyethyl sorbitan oleate)
Soybean oil
0.15
2
10
87.85
0.15
2
10
87.85
1.5
20
100
878.5
1.5
20
100
878.5
인도산
자체생산(메탄올로추출)
(주)유성화연테크
(주)사조해표
Indian
In-house production (extracted with methanol)
Yousung Hwayeon Tech Co., Ltd.
Sajo Seacoast Co., Ltd.
상기 표 12의 조성에 따라, 콩기름에 님 오일과 울금 추출물을 혼합하고 수면전개제용 계면활성제로서 폴리옥시에틸 소르비탄 올리에이트를 첨가하여 님 오일과 울금 추출물을 활성성분으로서 함유하는 수면전개제 1 kg을 제조하였다.According to the composition of Table 12, 1 kg of sleep development agent containing Nim oil and turmeric extract in soybean oil and adding polyoxyethyl sorbitan oleate as a surfactant for sleep development, containing Nim oil and turmeric extract as active ingredients Was prepared.
<시험예 3><Test Example 3>
온실 내 벼논 3.3m2에 벼 80주를 심고 망을 설치하여 곤충의 출입을 차단한 후 벼멸구 성충 240 마리를 방사하여 “제조예 10”의 수면전개제 3.3g을 수면에 전개시키고 10일후 생충율을 조사한 결과 90% 방제가 되었다.Installing networks to plant the rice 80 weeks in the greenhouse in rice paddies 3.3m 2 and then block the entry of insects to radiate BPH adult 240 deploy the first deployment sleep 3.3g of "Preparation Example 10" on the surface of the water and 10 days after production chungyul Investigations showed that 90% control was achieved.
<시험예 4><Test Example 4>
시험예 3과 같은 방법으로 시험한 결과 제조예 7 및 제조예 9의 경우 75% 방제되었고, 제조예 8은 56% 방제되었으며, 제조예 11은 65%, 제조예 12는 72%가 방제되어, 제조예 4의 수면전개제보다 효과가 떨어진 것으로 나타났다. 방제가는 상기 시험예 2에 나타낸 식에 의하여 구하였다.As a result of the test in the same manner as in Test Example 3, 75% of Preparation Example 7 and 9 were controlled, 56% of Preparation Example 8 was controlled, 65% of Preparation Example 11, and 72% of Preparation Example 12 was controlled. It showed that the effect was inferior to the sleep growth agent of manufacture example 4. The control value was calculated | required by the formula shown in the said Test Example 2.
<시험예 5><Test Example 5>
제조예 7, 8, 9, 10 및 11에서 얻은 수면전개제를 수면에 전개시킨 결과를 도 4에 나타내었다. 제조예 7과 제조예 9는 기름이 뭉쳐저 있고 전개 상태가 그다지 좋지 않았으며 제조예 8은 현탁이 되었다. 제조예 10은 수면 전개가 양호하였고 제조예 11은 기름 방울이 뭉쳐져 있었다. 시험 결과 제조예 10에서 얻어진 제제가 아자디락틴 수면 전개제로서 가장 적합한 것으로 판단된다. (도 4)4 shows the results of developing the sleep development agents obtained in Preparation Examples 7, 8, 9, 10, and 11 on the surface of the water. In Preparation Example 7 and Preparation Example 9, oil was agglomerated and the development state was not so good, and Preparation Example 8 was suspended. Preparation Example 10 had a good surface development, and Preparation Example 11 had oil droplets agglomerated. As a result of the test, the formulation obtained in Production Example 10 is judged to be the most suitable as an azadilactin sleep developing agent. (Figure 4)
본 발명에 따라, 님 오일(아자디락틴)을 활성 성분으로 하여 식물성기름 또는 액상 동물성기름인 어유를 단독 또는 2종이상 혼합하여 벼멸구 방제제를 조립식입제, 흡착식입제, 피복식 입제 제형으로 만들거나, 수면전개제 형태로 제조함으로써, 저렴하고, 친환경적인 벼멸구 방제제를 보급시킬 수 있다.According to the present invention, using the neem oil (azadilactin) as an active ingredient, fish oil, which is vegetable oil or liquid animal oil, alone or in combination of two or more, to prepare a rice bran control agent into a granulated granule, an adsorption granule, a coated granule formulation, or By manufacturing in the form of a sleep spreader, it is possible to spread a cheap and environmentally friendly rice plant control.
따라서 8~9월에 걸처 벼에 치명적 피해를 주는 벼멸구류와 뿌리혹선충을 농약이 아닌 친환경 방제제로 완벽하게 방제하므로 친환경 유기농 쌀과 밭작물을 생산할 수 있게 되었다. Therefore, it is possible to produce eco-friendly organic rice and field crops by completely controlling rice planthoppers and root-knot nematodes, which cause fatal damage to rice, from August to September with eco-friendly control agents, not pesticides.
특히, 수면전개제의 경우 액체이므로, 병뚜껑만 열어 수면에 뿌리면 님 오일이 수면에 골고루 퍼져 살포기가 필요없어 간편하다. In particular, in the case of a sleep spreading agent, it is easy to open the bottle cap and spray it on the water so that the neem oil is spread evenly on the water surface and does not need a sprayer.
뿐만 아니라, 님 오일은 우렁이, 거머리, 물방게 등 수생동물에 독성이 없고 농작물에 잔류가 되지 않아 친환경 쌀을 생산하고자 하는 농가에 꼭 필요한 친환경 살충제를 생산하는 것이 가능하다.In addition, since Nim oil is not toxic to aquatic animals such as snails, leeches and water droplets and does not remain in crops, it is possible to produce eco-friendly pesticides necessary for farmers who want to produce eco-friendly rice.
도 1은 담체로서 입상 규조토를 사용한 제조예 1, 담체로서 제올라이트를 사용한 제조예 2, 담체로서 모래를 제조예 3 및 담체로서 입상 돌로마이트 분말을 사용한 제조예 4의 입제 제형의 용출 시험 결과를 비교하여 나타낸 사진이다. 1 is a comparison of the dissolution test results of the granule formulation of Preparation Example 1 using granular diatomaceous earth as a carrier, Preparation Example 2 using zeolite as a carrier, Preparation Example 3 using sand as a carrier and Preparation Example 4 using granular dolomite powder as a carrier. The picture shown.
도 2는 도 1의 제조예 1과 제조예 2의 용출시험 결과를 확대하여 나타낸 사진이다.Figure 2 is an enlarged photograph showing the dissolution test results of Preparation Example 1 and Preparation Example 2 of FIG.
도 3은 도 1의 제조예 3과 제조예 4의 용출시험 결과를 확대하여 나타낸 사진이다.3 is an enlarged photograph showing dissolution test results of Preparation Example 3 and Preparation Example 4 of FIG. 1.
도 4는 제조예 7 내지 제조예 11의 수면전개제 제형의 수면 전개 상태의 시험 결과를 나타낸 사진이다.Figure 4 is a photograph showing the test results of the sleep development state of the sleep growth agent formulation of Preparation Examples 7-11.
Claims (10)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020090003902A KR20100084416A (en) | 2009-01-16 | 2009-01-16 | Environment friendly agent for controlling rice planthopper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020090003902A KR20100084416A (en) | 2009-01-16 | 2009-01-16 | Environment friendly agent for controlling rice planthopper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20100084416A true KR20100084416A (en) | 2010-07-26 |
Family
ID=42643827
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020090003902A KR20100084416A (en) | 2009-01-16 | 2009-01-16 | Environment friendly agent for controlling rice planthopper |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR20100084416A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101412111B1 (en) * | 2012-06-11 | 2014-06-26 | 경남과학기술대학교 산학협력단 | Pesticidal composition comprising neem extract and sophora flavescens aiton extract as effective components and pesticidal method using thereof |
| CN108402100A (en) * | 2018-02-02 | 2018-08-17 | 湖南杂交水稻研究中心 | A kind of organic paddy rice planthopper vegetable insecticide and its application method |
| KR102048071B1 (en) * | 2018-06-12 | 2019-11-22 | (주)현농 | foam control agent for prevention of rice damages by diseases and insects |
-
2009
- 2009-01-16 KR KR1020090003902A patent/KR20100084416A/en not_active Application Discontinuation
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101412111B1 (en) * | 2012-06-11 | 2014-06-26 | 경남과학기술대학교 산학협력단 | Pesticidal composition comprising neem extract and sophora flavescens aiton extract as effective components and pesticidal method using thereof |
| CN108402100A (en) * | 2018-02-02 | 2018-08-17 | 湖南杂交水稻研究中心 | A kind of organic paddy rice planthopper vegetable insecticide and its application method |
| KR102048071B1 (en) * | 2018-06-12 | 2019-11-22 | (주)현농 | foam control agent for prevention of rice damages by diseases and insects |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2546209C (en) | Pest control composition and method | |
| US20080249186A1 (en) | Fungicidal Composition | |
| KR20100084416A (en) | Environment friendly agent for controlling rice planthopper | |
| CN1221173C (en) | Pesticidal composition | |
| KR920005587B1 (en) | Pesticidal composition | |
| TW200826841A (en) | An agro-horticultural pesticidal composition | |
| KR20070036019A (en) | Improved granular formulation of neem seed extract and its process thereof | |
| RU2027364C1 (en) | Solid bensultap-based pesticidal composition | |
| KR101632246B1 (en) | Pesticides using the Insect flower powder or sludge and manufacture method thereof | |
| AU2007273441A1 (en) | Parasitic plant control agent and use thereof | |
| CN107646864A (en) | A kind of Pesticidal combination | |
| CN103749521B (en) | A kind of Pesticidal combination | |
| KR20140084596A (en) | Pesticides using the Insect flower powder or sludge | |
| CN103478150B (en) | Pesticide insecticidal composition containing spirotetramat and pyridaphenthion | |
| KR100813317B1 (en) | An agent for controlling water weevil | |
| CN101669505A (en) | Tefluthrin composition | |
| JP2010001263A (en) | Vermin damage-preventing agent for vegetable and flowering plant | |
| CN102308796B (en) | Diazinon emulsifiable granules and preparation method thereof | |
| KR101214412B1 (en) | Sustained-release agricultural formulation and controlling method of disease and pest for paddy rice using the same | |
| CN104542605A (en) | Spreadable granule containing nereistoxin pesticides and cyantraniliprole | |
| CN101263824A (en) | Insecticidal composition | |
| CN104472533A (en) | Multifunctional pesticide composition and application thereof | |
| CN104522034A (en) | Compound granule for direct broadcasting and application | |
| CN109673652A (en) | A kind of insecticide composition preventing and treating nematode and mite pest | |
| JP2007099623A (en) | Animal repellent granule |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A201 | Request for examination | ||
| E902 | Notification of reason for refusal | ||
| E601 | Decision to refuse application |