KR20100082131A - System leachate-preventive , odor , virus remove for reclamation of avian influenza bird - Google Patents
System leachate-preventive , odor , virus remove for reclamation of avian influenza bird Download PDFInfo
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- KR20100082131A KR20100082131A KR1020090001469A KR20090001469A KR20100082131A KR 20100082131 A KR20100082131 A KR 20100082131A KR 1020090001469 A KR1020090001469 A KR 1020090001469A KR 20090001469 A KR20090001469 A KR 20090001469A KR 20100082131 A KR20100082131 A KR 20100082131A
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- phytoncide
- oxygen catalyst
- poultry
- leachate
- oxygen
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- 241000700605 Viruses Species 0.000 title claims abstract description 32
- 206010064097 avian influenza Diseases 0.000 title claims description 16
- 208000002979 Influenza in Birds Diseases 0.000 title claims description 8
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- 239000003054 catalyst Substances 0.000 claims abstract description 50
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- 239000011347 resin Substances 0.000 claims abstract description 46
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 38
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- 238000000034 method Methods 0.000 claims abstract description 25
- 244000144977 poultry Species 0.000 claims abstract description 24
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims abstract description 23
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- 230000002265 prevention Effects 0.000 claims description 16
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- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 229920005749 polyurethane resin Polymers 0.000 claims description 3
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- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 206010022000 influenza Diseases 0.000 claims 1
- 238000004078 waterproofing Methods 0.000 claims 1
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- 235000013311 vegetables Nutrition 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 208000031295 Animal disease Diseases 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 206010015150 Erythema Diseases 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 208000007212 Foot-and-Mouth Disease Diseases 0.000 description 1
- 241000710198 Foot-and-mouth disease virus Species 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 206010030113 Oedema Diseases 0.000 description 1
- 235000005311 Pandanus odoratissimus Nutrition 0.000 description 1
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- 229920002472 Starch Polymers 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
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- 241000223229 Trichophyton rubrum Species 0.000 description 1
- 241000893966 Trichophyton verrucosum Species 0.000 description 1
- 229920006311 Urethane elastomer Polymers 0.000 description 1
- 231100000460 acute oral toxicity Toxicity 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000001093 anti-cancer Effects 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 description 1
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- 231100000321 erythema Toxicity 0.000 description 1
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- 231100000636 lethal dose Toxicity 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 238000011587 new zealand white rabbit Methods 0.000 description 1
- 231100000344 non-irritating Toxicity 0.000 description 1
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- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
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- 235000019698 starch Nutrition 0.000 description 1
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- 231100000041 toxicology testing Toxicity 0.000 description 1
- 241000712461 unidentified influenza virus Species 0.000 description 1
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/014—Deodorant compositions containing sorbent material, e.g. activated carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D35/00—Filtering devices having features not specifically covered by groups B01D24/00 - B01D33/00, or for applications not specifically covered by groups B01D24/00 - B01D33/00; Auxiliary devices for filtration; Filter housing constructions
- B01D35/02—Filters adapted for location in special places, e.g. pipe-lines, pumps, stop-cocks
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B1/00—Dumping solid waste
- B09B1/008—Subterranean disposal, e.g. in boreholes or subsurface fractures
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D17/00—Excavations; Bordering of excavations; Making embankments
- E02D17/18—Making embankments, e.g. dikes, dams
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/20—Waste processing or separation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Mining & Mineral Resources (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biomedical Technology (AREA)
- Structural Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Civil Engineering (AREA)
- Paleontology (AREA)
- Materials Engineering (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
Description
본 발명은 침출수방지 , 악취 및 바이러스제거공법을 이용하여 조류독감등에 걸린 것으로 의심되는 닭과 오리등을 살처분하여 파묻은 매몰지에서 썩은 침출수가 밖으로 새나와 2차 감염 및 환경오염을 일으키는것을 방지하는 침출수방지 , 악취 및 바이러스제거공법에 관한 것이다. The present invention prevents rotting leachate leaking out of buried land buried by burying chickens and ducks suspected of avian influenza by using leachate prevention, odor and virus removal techniques to prevent secondary infection and environmental pollution. To leachate, odor and virus removal methods.
보다 구체적으로는, 본 발명은 피톤치드산소촉매 우레탄수용성수지를 포함하는 수용성 조성물을 이용하여 보통 4~5ｍ 깊이의 구덩이를 파고, 구덩이의 바닥과 벽면에 분사함으로써 연약지반을 개량하여 우레탄고무시트상을 형성시켜 침출수의 누수를 방지하고, 피톤치드산소촉매 활성탄을 사용하여 악취 및 바이러스인자를 제거하는 침출수방지 , 악취 및 바이러스제거공법에 관한 것이다. More specifically, the present invention uses a water-soluble composition containing a phytoncide oxygen-catalyzed urethane water-soluble resin to dig a pit of 4 to 5 m deep, and to improve the soft ground by spraying the bottom and wall of the pit to form a urethane rubber sheet phase The present invention relates to a leachate prevention, odor and virus removal method of forming and preventing leakage of leachate, and removing odor and virus factors using phytoncide oxygen catalyst activated carbon.
조류독감이 의심되는 닭과 오리들을 살처분해 파묻은 매몰지에서 썩은 침출수가 밖으로 새나와 2차 감염 및 환경오염이 우려된다. 조류독감이 처음 발생한 이후 지금까지 농장 부근 여러곳에 구덩이를 파 수백만 마리의 닭과 오리를 묻었는데, 20여일 지나면서 일부 매몰지에서 침출수가 밖으로 새나오고 있다. 이러한 문제점을 해결하는 공법중의 하나로, 감염된 닭, 오리 등에 대해서는 보통 4~5ｍ 깊이의 구덩이를 파고, 구덩이의 바닥과 벽면에 비닐을 덮은 후, 폐사 또는 도살 처분한 동물 사체를 투입하고, 생석회를 뿌린 다음 흙을 덮어 매립한다. 조류독감뿐 아니라 근래 잇따르고 있는 구제역 또는 브루셀라 등의 가축 질병이 발생한 때도 방역당국에서는 병원균에 노출된 가축들을 대부분 매립에 의한 방식으로 처리하고 있다. 그렇다면 이러한 매립 방식은 과연 안전한 것일까? 세계보건기구(WHO)에 의하면 고병원성 조류인플루엔자 바이러스는 감염된 동물 사체와 배설물 속에 섞여 섭씨 4도의 낮은 온도에서 최소 35일 이상, 섭씨 37도의 고온에서 6일 동안 생존이 가능하다고 한다. 땅속에 매립된 닭, 오리 등 동물의 사체는 미생물 활동에 의한 생물학적인 분해 과정을 거치면서 점차 온도가 올라간다. 온도가 30도를 넘으면 메탄 발생균의 활동이 활발해지면서 지구 온난화의 주범인 메탄가스가 발생하게 된다. 물론 이때쯤이면 조류독감 바이러스는 대부분 사멸할 터이지만 정작 사람들은 극심한 악취와 유독 가스로 인한 고통에 또다시 시달려야 한다. Rotten leachate leaks out of burial sites where birds and suspicious birds are buried, causing secondary infections and environmental pollution. Since the outbreak of bird flu, millions of chickens and ducks have been buried in several places near farms. Over 20 days, leachate is leaking out of some burial grounds. One of the methods to solve this problem is to dig a pit of 4 ~ 5m depth for infected chickens, ducks, etc., cover the bottom and wall of the pit with vinyl, and then put dead or slaughtered animal carcasses, Sprinkle and cover the soil with landfill. In addition to avian influenza, when animal disease such as foot-and-mouth disease or brussels has occurred recently, the authorities have treated most livestock exposed to pathogens by landfill. Is this landfill safe? According to the World Health Organization (WHO), the highly pathogenic avian influenza virus mixes in infected animal carcasses and excreta and can survive for at least 35 days at low temperatures of 4 degrees Celsius and for 6 days at high temperatures of 37 degrees Celsius. The carcasses of animals such as chickens and ducks buried in the ground gradually increase in temperature as they undergo biological decomposition through microbial activity. When the temperature exceeds 30 degrees Celsius, the activity of methane-generating bacteria becomes active and methane gas, which is the main cause of global warming, is generated. Of course, by this time most of the bird flu virus will be killed, but people will have to suffer from the bad smell and toxic gas again.
본 발명자들은 이러한 문제점을 해결하기위해 다각적으로 연구한 결과, 용도에 따라, 수용성 수지와 본 발명자가 개발한 악취제거 , 항균 및 항암바이러스인자를 제거하는 물질(특허출원 10-208-0063714)을사용하여 개발함으로써 경제적이며 환경친화적인 침출수 방지 공법을 이용하여 조류독감등에 걸린 것으로 의심되는 닭과 오리들을 살처분해 파묻은 매몰지에서 썩은 침출수가 밖으로 새나와 2차 감염 및 환경오염을 일으키는것을 방지하는 침출수방지 , 악취 및 바이러스제거공법을 제공할 수 있다는 것을 발견하고 본 발명을 완성하였다.The inventors have conducted various studies to solve these problems, and according to the use, water-soluble resins and substances which remove odor removal, antibacterial and anti-cancer virus factors developed by the present inventors are used (Patent Application 10-208-0063714). By using the economic and environmentally friendly leachate prevention method to kill chickens and ducks suspected of having bird flu, and to prevent rotting leachate from leaking out of buried land buried out to prevent secondary infection and environmental pollution. The present invention has been accomplished by finding that it can provide a leachate prevention, odor and virus removal method.
따라서, 본 발명의 목적은 피톤치드산소촉매 우레탄수용성수지등을 함유한 수용성 조성물을 이용한 침출수 방지 공법 및 썩은 가금류에서 발생하는 악취 및 바이러스인자등을 제거하는 악취 및 바이러스제거공법을 제공하는 데 있다. 본 발명의 궁극적인 목적은 2차 감염 및 환경오염을 일으키는것을 방지하는 침출수방지 , 악취 및 바이러스제거 공법을 제공하는 데 있다. Accordingly, an object of the present invention is to provide a leachate prevention method using a water-soluble composition containing a phytoncide oxygen catalyst urethane water-soluble resin and the like, and a odor and virus removal method for removing odors and virus factors generated in rotten poultry. The ultimate object of the present invention is to provide a leachate prevention, odor and virus removal method to prevent the secondary infection and environmental pollution.
본 발명에 사용될 수 있는 수용성 수지의 예로는, 아크릴 아미드계 수지, 전분-아크릴로니트릴 그라프트 공중합체가 혼합된 이소시아네이트계 수지, 폴리우레탄계 수지, 아크릴 우레탄계 수지, 라텍스 우레탄계 수지가 있으며, 이중에서 이소시아네이트계 수지와 라텍스 우레탄계 수지가 바람직하게 사용된다. Examples of the water-soluble resin that can be used in the present invention include an acryl amide resin, an isocyanate resin mixed with a starch-acrylonitrile graft copolymer, a polyurethane resin, an acrylic urethane resin, and a latex urethane resin, among which isocyanate Type resin and latex urethane type resin are used preferably.
본 발명에는 우레탄수용성수지를 사용하였으며, 지반에 저항없이 침투하고 물을 흡수하여 팽창할 때 체적 팽창율이 크고, 인장강도 및 신율 등의 기계적 물성이 우수하다. 즉, 물에 완전히 용해되는 수용성 수지액에 피톤치드산소촉매등의 충진재와 다량의 물을 완전혼합하여 4~5ｍ 깊이의 구덩이를 파고, 구덩이의 바닥과 벽면등에 분사하면 수용성 수지에 존재하는 미반응 말단 관능기가 물과 반응하여 미세한 기공을 가진 고무와 같은 탄성체가 형성되는 데 침투성이 우수하고 토양에 대한 접착력이 뛰어나 매몰지에서 침출수가 밖으로 새나오지 않는 완전한 방수층을 이룬다.그리고 우레탄수용성수지에 피톤치드산소촉매가 포함되어 있어 악취 및 바이러스인자 제거의 기능도 있다. Urethane water-soluble resin is used in the present invention, the volume expansion ratio is large, and the mechanical properties such as tensile strength and elongation are excellent when infiltrating without soil resistance and absorb water to expand. In other words, the water-soluble resin solution completely dissolved in water is completely mixed with a filler such as phytoncide oxygen catalyst and a large amount of water to dig a 4-5 m deep pit, and sprayed into the bottom and wall of the pit to unreacted terminal present in the water soluble resin. The functional group reacts with water to form a rubber-like elastic body with fine pores, which has excellent permeability and excellent adhesion to the soil, forming a complete waterproof layer where leachate does not leak out from the buried land, and the phytoncide oxygen catalyst in the urethane water-soluble resin. It also has the function of removing odor and virus factor.
하기 반응도식은 미반응 말단 관능기가 NCO인 경우를 나타낸것이다(하지만, 이러한 예는 본 발명을 예시하기위해 나타낸 것이며, 미반응 말단 관능기가 NCO로만 제한되지는 않는다):The following scheme depicts the case where the unreacted terminal functional group is NCO (but this example is shown to illustrate the invention and the unreacted terminal functional group is not limited to NCO):
2-R-N=C=O + H20 → R-NH-COOH → R-NH-CONR` +CO22-R-N = C = O + H20 → R-NH-COOH → R-NH-CONR` + CO2
이렇게 형성된 탄성체는 물에 재용해되지 않으며 토양에 대한 침투성이 우수하고 토양에 대한 접착력이 뛰어나 침출수가 밖으로 새나오지 않는 완전한 방수층을 이룬다. The elastic body thus formed is not re-dissolved in water, and has excellent permeability to the soil and excellent adhesion to the soil, thus forming a complete waterproof layer which does not leak out of the leachate.
아울러, 이러한 우레탄수용성수지와 더불어 피톤치드산소촉매등으로 구성된 군에서 선택된 1종 이상의 충진재가 사용된다.In addition, one or more kinds of fillers selected from the group consisting of phytoncide oxygen catalysts together with the urethane water-soluble resin are used.
피톤치드산소촉매, 고분자 우레탄수지등의 식물성 중합체를 함유하고 있어, 악취와 바이러스로 인한 2차 오염물질을 제거시켜주는 역할을 한다. It contains vegetable polymers such as phytoncide oxygen catalyst and high-molecular urethane resin, which removes secondary pollutants caused by odors and viruses.
본 발명에 사용된 공법은 용도에 따라 적용 방법이 다양한데, 수용성 수지와 물을 혼합하여 흙에 골고루 도포되도록 분사한다.The method used in the present invention has a variety of application methods, depending on the application, the water-soluble resin and water is mixed to spray evenly applied to the soil.
여기에서 사용되는 분사기계는 고압 분무기, 고압 발포기, 피스톤식 유압펌프 1액형 또는 2액형 모두 가능하다.The injection machine used herein can be either a high pressure atomizer, a high pressure foamer, a piston type hydraulic pump, or one component.
피톤치드산소촉매 우레탄수용성수지등을 함유한 수용성 조성물을 이용한 침출수 방지 공법 및 썩은 가금류에서 발생하는 악취 및 바이러스인자등을 제거하는 악취 및 바이러스제거공법을 제공하는 데 있다. 본 발명의 궁극적인 목적은 2차 감염 및 환경오염을 일으키는것을 방지하는 침출수방지 , 악취 및 바이러스제거 공법을 제공하는 데 있다.A leachate prevention method using a water-soluble composition containing a phytoncide oxygen catalyst urethane water-soluble resin and the like and a odor and virus removal method for removing odors and virus factors generated in rotten poultry. The ultimate object of the present invention is to provide a leachate prevention, odor and virus removal method to prevent the secondary infection and environmental pollution.
본 발명에 따른 침출수 방지 공법을 이용하여 조류독감등에 걸린 것으로 의심되는 닭과 오리들을 살처분하여 파묻은 매몰지에서 썩은 침출수가 밖으로 새나와 2차 감염 및 환경오염을 일으키는것을 방지하는 침출수방지 , 악취 및 바이러스제거에 유용하다.Leachate prevention, odor to prevent rotting leachate from leaking out from buried land buried by burrowing chickens and ducks suspected of avian influenza using the leachate prevention method according to the present invention. And virus removal.
본 발명에 사용될 수 있는 수용성 수지의 예로는, 아크릴 아미드계 수지, 전분-아크릴로니트릴 그라프트 공중합체가 혼합된 이소시아네이트계 수지, 폴리우레탄계 수지, 아크릴 우레탄계 수지, 라텍스 우레탄계 수지가 있으며, 이중에서 이소시아 네이트계 수지와 라텍스 우레탄계 수지가 바람직하게 사용된다. Examples of the water-soluble resin that can be used in the present invention include acryl amide resins, isocyanate resins mixed with starch-acrylonitrile graft copolymers, polyurethane resins, acrylic urethane resins, latex urethane resins, Cyanate resin and latex urethane resin are used preferably.
본 발명에는 우레탄수용성수지를 사용하였으며, 지반에 저항없이 침투하고 물을 흡수하여 팽창할 때 체적 팽창율이 크고, 인장강도 및 신율 등의 기계적 물성이 우수하다. 즉, 물에 완전히 용해되는 수용성 수지액에 피톤치드산소촉매등의 충진재와 다량의 물을 완전혼합하여 4~5ｍ 깊이의 구덩이를 파고, 구덩이의 바닥과 벽면등에 분사하면 수용성 수지에 존재하는 미반응 말단 관능기가 물과 반응하여 미세한 기공을 가진 고무와 같은 탄성체가 형성되는 데 침투성이 우수하고 토양에 대한 접착력이 뛰어나 매몰지에서 침출수가 밖으로 새나오지 않는 완전한 방수층을 이룬다.그리고 우레탄수용성수지에 피톤치드산소촉매가 포함되어 있어 악취 및 바이러스인자 제거의 기능도 있다. Urethane water-soluble resin is used in the present invention, the volume expansion ratio is large, and the mechanical properties such as tensile strength and elongation are excellent when infiltrating without soil resistance and absorb water to expand. In other words, the water-soluble resin solution completely dissolved in water is completely mixed with a filler such as phytoncide oxygen catalyst and a large amount of water to dig a 4-5 m deep pit, and sprayed into the bottom and wall of the pit to unreacted terminal present in the water soluble resin. The functional group reacts with water to form a rubber-like elastic body with fine pores, which has excellent permeability and excellent adhesion to the soil, forming a complete waterproof layer where leachate does not leak out from the buried land, and the phytoncide oxygen catalyst in the urethane water-soluble resin. It also has the function of removing odor and virus factor.
하기 반응도식은 미반응 말단 관능기가 NCO인 경우를 나타낸것이다(하지만, 이러한 예는 본 발명을 예시하기위해 나타낸 것이며, 미반응 말단 관능기가 NCO로만 제한되지는 않는다):The following scheme depicts the case where the unreacted terminal functional group is NCO (but this example is shown to illustrate the invention and the unreacted terminal functional group is not limited to NCO):
2-R-N=C=O + H20 → R-NH-COOH → R-NH-CONR` +CO22-R-N = C = O + H20 → R-NH-COOH → R-NH-CONR` + CO2
이렇게 형성된 탄성체는 물에 재용해되지 않으며 토양에 대한 침투성이 우수하고 토양에 대한 접착력이 뛰어나 침출수가 밖으로 새나오지 않는 완전한 방수층을 이룬다. The elastic body thus formed is not re-dissolved in water, and has excellent permeability to the soil and excellent adhesion to the soil, thus forming a complete waterproof layer which does not leak out of the leachate.
아울러, 이러한 우레탄수용성수지와 더불어 피톤치드산소촉매등으로 구성된 군에서 선택된 1종 이상의 충진재가 사용된다.In addition, one or more kinds of fillers selected from the group consisting of phytoncide oxygen catalysts together with the urethane water-soluble resin are used.
피톤치드산소촉매, 고분자 우레탄수지등의 식물성 중합체를 함유하고 있어, 악취와 바이러스로 인한 2차 오염물질을 제거시켜주는 역할을 한다. It contains vegetable polymers such as phytoncide oxygen catalyst and high-molecular urethane resin, which removes secondary pollutants caused by odors and viruses.
본 발명에 사용된 공법은 용도에 따라 적용 방법이 다양한데, 수용성 수지와 물을 혼합하여 흙에 골고루 도포되도록 분사한다.The method used in the present invention has a variety of application methods, depending on the application, the water-soluble resin and water is mixed to spray evenly applied to the soil.
여기에서 사용되는 분사기계는 고압 분무기, 고압 발포기, 피스톤식 유압펌프 1액형 또는 2액형 모두 가능하다.The injection machine used herein can be either a high pressure atomizer, a high pressure foamer, a piston type hydraulic pump, or one component.
실시예 1Example 1
4~5ｍ 깊이의 구덩이를 파고, 구덩이의 바닥과 벽면등에 전분-아크릴로니트릴 그라프트 공중합체가 혼합된 이소시아네트계 수지(전분:아크릴로니트릴(한국, 덕성화학)수용성 수지 100 중량부에 피톤치드산소촉매가 100 내지 500 중량부 와 물 1000 내지 2000 중량부를 투입하여 혼합하면 피톤치드산소촉매우레탄수용성수지가 만들어진다. 이를 고압 분무기로 구덩이의 바닥과 벽면등에 균일하게 분사시키면 5 내지 30분 사이에 고강도의 탄성체가 균일하게 형성되어 연약지반을 강화시켜 침출수 방지를 위한 방지막을 형성한다. 그위에 비닐을 도포하고나서100 parts by weight of isocyanate resin (starch: acrylonitrile (Korea, Duksung Chemical)) in which a pit of 4 to 5 m depth was dug and a starch-acrylonitrile graft copolymer was mixed on the bottom and wall of the pit. When the phytoncide oxygen catalyst is mixed with 100 to 500 parts by weight of water and 1000 to 2000 parts by weight of water, the phytoncide oxygen catalyst is made of a water-soluble resin. The elastic body of the uniformly formed to strengthen the soft ground to form a prevention film for preventing leachate.
2m정도의 흙을 채운다. 생석회와 피톤치드산소촉매가 포함됨 활성탄을 10 : 1비율 로 도포하고 조류독감등에 걸린 것으로 의심되는 닭과 오리등의 가금류를 2m정도로 매립한다. 매립된 가금류사이에 생석회와 피톤치드산소촉매가 포함됨 활성탄을 10 : 1비율로 매립된 가금류위에 도포한다.Fill the soil about 2m long. Quicklime and phytoncide oxygen catalyst are included. Activated carbon is applied at a ratio of 10: 1 and poultry such as chickens and ducks suspected of avian influenza are buried about 2m long. Between buried poultry contains quicklime and phytoncide oxygen catalyst Activated charcoal is applied over buried poultry in a 10: 1 ratio.
흙을 1m정도로 매립하면서 피톤치드산소촉매활성탄이 들어 있는 벤트홀을 설치한다. 매립된 흙표면을 위에서 제조한 피톤치드산소촉매우레탄수용성수지을 고압 분무기로 도포한다.그위에 비닐를 재차 도포하고나서 흙을 1m정도 매립한다.A vent hole containing phytoncide oxygen catalyst activated carbon is installed while the soil is reclaimed to about 1m. Apply the phytoncide oxygen-catalyzed urethane water-soluble resin prepared above with a high pressure sprayer, and apply vinyl on it, and then bury the soil about 1m.
실시예 2Example 2
4~5ｍ 깊이의 구덩이를 파고, 구덩이의 바닥과 벽면등에 아크릴 우레탄계 수지 50 중량부와 라텍스 우레탄계 수지 50 중량부를 균일하게 혼합한 수용성 수지 100 중량부에 피톤치드산소촉매가 100 내지 500 중량부 와 물 1000 내지 2000 중량부를 투입하여 혼합하면 피톤치드산소촉매우레탄수용성수지가 만들어진다. 이를 고압 분무기로 구덩이의 바닥과 벽면등에 균일하게 분사시키면 5 내지 30분 사이에 고강도의 탄성체가 균일하게 형성되어 연약지반을 강화시켜 침출수 방지를 위한 방지막을 형성한다. 그위에 비닐을 도포하고나서Digging a pit of 4 to 5m depth, 100 to 500 parts by weight of phytoncide oxygen catalyst and 1000 parts of water to 100 parts by weight of water-soluble resin in which 50 parts by weight of acrylic urethane resin and 50 parts by weight of latex urethane resin are uniformly mixed on the bottom and wall of the pit. When mixed with 2000 parts by weight to form a phytoncide oxygen catalyst urethane water-soluble resin. When it is sprayed uniformly to the bottom and wall of the pit with a high-pressure sprayer, a high-strength elastic body is uniformly formed between 5 to 30 minutes to strengthen the soft ground to form a prevention film for preventing leachate. After applying vinyl on it
2m정도의 흙을 채운다. 생석회와 피톤치드산소촉매가 포함됨 활성탄을 10 : 1비율로 도포하고 조류독감등에 걸린 것으로 의심되는 닭과 오리등의 가금류를 2m정도로 매립한다. 매립된 가금류사이에 생석회와 피톤치드산소촉매가 포함됨 활성탄을 10 : 1비율로 매립된 가금류위에 도포한다.Fill the soil about 2m long. Quicklime and phytoncide oxygen catalyst are included. Activated carbon is applied at a ratio of 10: 1 and poultry such as chickens and ducks suspected of avian influenza are buried about 2m. Between buried poultry contains quicklime and phytoncide oxygen catalyst Activated charcoal is applied over buried poultry in a 10: 1 ratio.
흙을 1m정도로 매립하면서 피톤치드산소촉매활성탄이 들어 있는 벤트홀을 설치한다. 매립된 흙표면을 위에서 제조한 피톤치드산소촉매우레탄수용성수지을 고압 분무기로 도포한다.그위에 비닐를 재차 도포하고나서 흙을 1m정도 매립한다.A vent hole containing phytoncide oxygen catalyst activated carbon is installed while the soil is reclaimed to about 1m. Apply the phytoncide oxygen-catalyzed urethane water-soluble resin prepared above with a high pressure sprayer, and apply vinyl on it, and then bury the soil about 1m.
실시예 3Example 3
4~5ｍ 깊이의 구덩이를 파고, 구덩이의 바닥과 벽면등에 라텍스 우레탄계 수지 40 중량부와 폴리우레탄계 수지 60 중량부가 혼합된 수용성 수지 100 중량부에 피톤치드산소촉매가 100 내지 500 중량부 와 물 1000 내지 2000 중량부를 투입하여 혼합하면 피톤치드산소촉매우레탄수용성수지가 만들어진다. 이를 고압 분무기로 구덩이의 바닥과 벽면등에 균일하게 분사시키면 5 내지 30분 사이에 고강도의 탄성체가 균일하게 형성되어 연약지반을 강화시켜 침출수 방지를 위한 방지막을 형성한다. 그위에 비닐을 도포하고나서Digging a pit of 4 to 5 m depth, 100 to 500 parts by weight of a phytoncide oxygen catalyst and 100 to 500 parts by weight of water-based resin containing 40 parts by weight of latex urethane-based resin and 60 parts by weight of polyurethane-based resin on the bottom and wall of the pit. When the mixture is added in parts by weight, phytoncide oxygen catalyst urethane water-soluble resin is formed. When it is sprayed uniformly to the bottom and wall of the pit with a high-pressure sprayer, a high-strength elastic body is uniformly formed between 5 to 30 minutes to strengthen the soft ground to form a prevention film for preventing leachate. After applying vinyl on it
2m정도의 흙을 채운다. 생석회와 피톤치드산소촉매가 포함됨 활성탄을 10 : 1비율로 도포하고 조류독감등에 걸린 것으로 의심되는 닭과 오리등의 가금류를 2m정도로 매립한다. 매립된 가금류사이에 생석회와 피톤치드산소촉매가 포함됨 활성탄을 10 : 1비율로 매립된 가금류위에 도포한다.Fill the soil about 2m long. Quicklime and phytoncide oxygen catalyst are included. Activated carbon is applied at a ratio of 10: 1 and poultry such as chickens and ducks suspected of avian influenza are buried about 2m. Between buried poultry contains quicklime and phytoncide oxygen catalyst Activated charcoal is applied over buried poultry in a 10: 1 ratio.
흙을 1m정도로 매립하면서 피톤치드산소촉매활성탄이 들어 있는 벤트홀을 설치한다. 매립된 흙표면을 위에서 제조한 피톤치드산소촉매우레탄수용성수지을 고압 분 무기로 도포한다.그위에 비닐를 재차 도포하고나서 흙을 1m정도 매립한다.A vent hole containing phytoncide oxygen catalyst activated carbon is installed while the soil is reclaimed to about 1m. Apply the phytoncide oxygen-catalyzed urethane water-soluble resin prepared above with high pressure powder, and apply vinyl on it, and then bury the soil about 1m.
도1은 조류독감등 각종 질병감염 가금류 매몰지 구조도로써 4~5ｍ 깊이의 구덩이를 파고, 구덩이의 바닥과 벽면등에 공정별로 나열하면 A는 구덩이흙이고 B는 피톤치드산소촉매우레탄수용성수지이고,C는 비닐이며,A1은 1미터 높이의 흙이며 ,A2는 2미터높이의 흙이며,D는 생성회 및 피톤치드산소촉매활성탄의 혼합물질이며,E는 가금류이며,F는 벤트홀이며,G는 산소촉매활성탄이다.1 is a structural diagram of poultry buried in various diseases infected birds, such as bird flu, digging a pit of 4 ~ 5m deep, arranged in the bottom and wall of the pit by the process, A is a pit soil, B is a phytoncide oxygen catalyst urethane water-soluble resin, C is Vinyl, A1 is 1 meter high soil, A2 is 2 meters high, D is mixture of ash and phytoncide oxygen catalyst activated carbon, E is poultry, F is vent hole, G is oxygen catalyst Activated carbon.
도2는 조류독감등 각종 질병감염 가금류 매몰현장의 사진으로써 다음과 같은 상황을 알수 있다. 조류독감에 걸린 닭과 오리를 매몰처분하면서 규정을 지키지 않아 토양과 지하수를 오염시킬 우려가 크다. 농림부령이 정한 매몰처분 규정에 따르면 바닥과 벽면에 비닐을 덮고 흙을 덮은 후 생석회를 뿌리도록 하고 있다. 그런데 최근 살처분되는 닭과 오리가 늘어나고 인력난이 가중되면서 비닐을 깔거나 석회 뿌리기를 생략한 채 매몰하는 곳이 많다고 한다. 지자체에서는 상황이 급한데 언제 규정대로 하느냐고 볼 멘 소리다. 이렇게 될 경우 토양과 지하수 오염으로 이어질 것이 뻔하다.Figure 2 is a picture of the buried poultry site infected with various diseases such as bird flu can see the following situation. There is a high possibility of contaminating soil and groundwater by burying chickens and ducks with bird flu and not following the regulations. According to the burial regulations set by the Ministry of Agriculture, Forestry and Forestry, the limestone is sprayed after covering the floor and walls with plastic and soil. However, as more chickens and ducks are being killed recently and manpower shortages are increasing, many places are buried without laying vinyl or lime. The situation is urgent in the local government, but when you do it according to the regulations, it is a sound. This would obviously lead to soil and groundwater contamination.
도3은 피톤치드산소촉매 입자크기로써 5nano이다.3 shows 5 nanometers of phytoncide oxygen catalyst particle size.
도4는 피톤치드산소촉매 악취제거실험(암모니아제거)으로써 암모니아제거율이 89%이상이다.4 is a phytoncide oxygen catalyst odor removal experiment (ammonia removal), the ammonia removal rate is 89% or more.
도5는 피톤치드산소촉매 악취제거실험(포름알데히드제거)으로써 포름알데히드제거 율이 85%이상이다.5 is a phytoncide oxygen catalyst odor removal experiment (formaldehyde removal) is more than 85% formaldehyde removal rate.
도6은 피톤치드산소촉매 항균성 및 곰팡이성시험으로써 대장균,황색포도상구균,폐렴간균의 및 곰팡이의 저항성이 99.9%이다.FIG. 6 shows 99.9% of the resistance of E. coli, S. aureus, pneumococcus, and mold to the phytoncide oxygen catalyst antimicrobial and fungal test.
도7은 피톤치드산소촉매 경구독성 및 피부자극시험으로써 안전성 시험을 위해 국가 공인 GLP 기관인 [한국화학시험연구원]에서 안전성시험에 일반적으로 널리 사용되는 랫드(설치류)를 통한 경구 독성 시험 및 피부 자극 시험을 완료하였습니다 Figure 7 is an oral toxicity and skin irritation test for phytoncide oxygen catalysts for oral toxicity test and skin irritation test through the rat (rodent) generally used for safety test in the [Korea Testing and Research Institute], a national GLP institution for safety testing Completed
경구독성시험은 본 시험물질에 대한 랫드의 급성 경구 독성시험(GLP) 결과, The oral toxicity test was based on the results of the acute oral toxicity test (GLP) of rats for this test substance.
투여 용량인 20ml/kg(체중) 에서 사망동물이 관찰되지 않아 개략의 치사량 치는 암, 수 모두 20ml/kg(체중) 이상으로 판단된다.At the dose of 20ml / kg (body weight), no dead animals were observed, so the approximate lethal doses were judged to be 20ml / kg (body weight) or more.
피부자극시험은 New Zealand White계 토끼에 있어서 본 시험물질 적용 후 24, 72시간째에서 적용부위를 관찰한 결과, 어떠한 피부자극반응(홍반, 기피 및 부종)을 유도하지 않았으며, 일차 피부자극지수(P.I.I.)가 "0.00"으로 산출되어 비자극성 물질(none irritating substance) 로 평가되었다The skin irritation test did not induce any skin irritation reaction (erythema, repellence and edema) in New Zealand White rabbits after 24 hours and 72 hours after application of this test substance. (PII) was calculated to be "0.00" and evaluated as a non irritating substance
도8은 피톤치드산소촉매 백선균시험으로써 위의 Halo test결과 T. rubrum에 대하여 5.0mm의 저지대 환 및 전체적인 저지대군을 조성해, 대조편으로 사용되어진 70% 알코올 대비 높은 곰팡이 저항성을 나타내었다Fig. 8 shows the phytoncide oxygen catalyst ringworm bacteria test, which showed 5.0 mm of low-ring and overall low-group for T. rubrum, and showed higher mold resistance than 70% alcohol used as a control.
도9는 피톤치드산소촉매 AGS바이러스 제거실험으로써 몰농도와 시간 경과에 따른 Figure 9 is a phytoncide oxygen catalyst AGS virus removal experiment as a function of molarity and time
제거율을 나타내며,도10은 피톤치드산소촉매 T-24바이러스 제거실험으로써 몰농도와 시간 경과에 따른 제거율을 나타내며, 도11은 피톤치드산소촉매 KB바이러스 제거실험으로써 몰농도와 시간 경과에 따른 제거율을 나타내며,도12는 피톤치드산소 촉매 Saos바이러스 제거실험으로써 몰농도와 시간 경과에 따른 제거율을 나타내며,Figure 10 shows the molarity and removal rate over time as a phytoncide oxygen catalyst T-24 virus removal experiment, Figure 11 shows the molarity and removal rate over time as a phytoncide oxygen catalyst KB virus removal experiment, 12 shows the molarity and removal rate over time as a phytoncide oxygen-catalyzed Saos virus removal experiment.
도13은 피톤치드산소촉매 HaLa바이러스 제거실험으로써 몰농도와 시간 경과에 따른 제거율을 나타낸다.Figure 13 shows the molarity and removal rate over time as a phytoncide oxygen catalyst HaLa virus removal experiment.
도2Figure 2
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| KR101040211B1 (en) * | 2011-02-18 | 2011-06-16 | 갈원홍 | Treatment tank facility for killing livestock epidemic and method of killing using it |
| WO2012138061A1 (en) * | 2011-04-07 | 2012-10-11 | 아름다운 환경건설(주) | Processing system and method for stabilizing livestock reclaimed ground by on-site underground oxidation (combustion) |
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| KR101040211B1 (en) * | 2011-02-18 | 2011-06-16 | 갈원홍 | Treatment tank facility for killing livestock epidemic and method of killing using it |
| WO2012138061A1 (en) * | 2011-04-07 | 2012-10-11 | 아름다운 환경건설(주) | Processing system and method for stabilizing livestock reclaimed ground by on-site underground oxidation (combustion) |
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