KR20100079867A - High speed drying paint composition for marking road line and preparation process thereof - Google Patents

Abstract

PURPOSE: A high speed drying paint composition for marking a road line, and a manufacturing method thereof are provided to rapidly dry the composition when paving a road without containing environmentally harmful components. CONSTITUTION: A manufacturing method of a high speed drying paint composition for marking a road line comprises the following: producing a resin solution by dissolving a solid phase acrylic resin to an acrylic monomer; forming a mixture by additionally inserting the acrylic monomer to the resin solution; forming a base unit by mixing the mixture with a tertiary amine-based promoter; forming a hardener unit by mixing the mixture with a peroxide hardener; and mixing the base unit with the hardener unit.

Description

Fast-drying paint composition for road sign and manufacturing method thereof {HIGH SPEED DRYING PAINT COMPOSITION FOR MARKING ROAD LINE AND PREPARATION PROCESS THEREOF}

The present invention relates to a fast-drying paint composition for road marking and a method for manufacturing the same, and more particularly, to have a fast drying during coating and excellent adhesion and visibility with water, water resistance, abrasion resistance, weather resistance and alkali resistance, chemical resistance and durability It relates to a fast-drying coating composition for a label and a method for producing the same.

In general, lanes are marked on the road surface by using the paint for the driving direction or for the boundary between the lane and the lane, and the conventional road marking paints include heating type, room temperature type, water-soluble type, fusion type, etc. Each road marking paint has its own characteristics.

Heated road marking paints and fusion-type road marking paints apply heat to the surface of the road by heating and melting the paint, and the room temperature and water-soluble road marking paints are applied to the road surface and then diluted in the product (solvent, water). The paint is dried by volatilization. In addition, the room temperature dry paint has a lot of organic volatile components harmful to the environment because the solvent is used as a diluent.

Conventional fusion paints are exposed to high temperatures in the summer after melting the paints, and the viscosity decreases due to heat, which causes the air to fly away. When the beads sink into the paint or work at a temperature lower than the temperature, the paint hardens quickly, causing the beads not to be applied on the paint properly.As for fused paints, it is basically a thick sieve pigment or glass powder. Sedimentation occurs during operation. In other words, existing fusion and heating paints have the disadvantage of adjusting the construction temperature and working speed according to the working environment (especially air temperature), and peeling off the coating due to cracking and desorption due to plasticity and ductility (flexibility) Or cracking may occur.

In addition, the conventional coating material for paint coating on concrete roads and concrete roads, concrete roads are less adherent and durable due to their own properties and structural differences than asphalt roads, and the painting conditions are also difficult, requiring careful attention. There was a problem with. In general, it is possible to maintain excellent adhesion and durability even by removing dirt and debris by painting vehicles when painting asphalt road paints, but when coating concrete roads, weak coating layers that are difficult to process by general cleaning such as latencies and chemical salts Due to this, the adhesion and durability of the paint is inferior to that of asphalt.

In addition, the conventional two-component road marking paint mainly composed of epoxy resin, urethane resin, etc. has a problem that it is difficult to maintain and repair due to the slow drying time during painting, which is difficult to maintain and repair. (Elasticity) falls off, causing poor adhesion to the road surface and cracks.

Therefore, there is a need for a study on the development of road marking paints that are quick to dry during coating and have excellent adhesion and visibility with water, water resistance, abrasion resistance, weather resistance and alkali resistance, chemical resistance and durability.

According to the present invention, the coating composition for road marking, which does not contain components harmful to the environment such as thinner or gasoline, is dried quickly during coating, has excellent abrasion resistance, weather resistance and alkali resistance, chemical resistance and durability, and hardening and drying time. It is to provide a fast-drying coating composition for a paint label that can be adjusted and a method for producing the same.

The present invention provides a fast-drying coating composition for road marking comprising a resin solution in which a solid acrylic resin is dissolved in an acrylic monomer at 20 to 40 parts by weight based on the total weight of the total composition.

The present invention also comprises a) preparing a resin solution by dissolving a solid acrylic resin in an acrylic monomer, b) containing 20 to 40 parts by weight of the resin solution with respect to the total weight of the total composition, and the acrylic monomer in the resin solution To add a further to prepare a mixture, c) mixing the tertiary amine-based accelerator to the mixture prepared in step b) to prepare the main portion (A), d) the mixture prepared in step b) Producing a curing agent portion (B) by mixing a peroxide curing agent to, and e) providing a method for producing a fast-drying coating composition for road marking comprising mixing the main portion (A) and the curing agent portion (B). do.

Hereinafter, the present invention will be described in more detail.

The present invention effectively includes a solid acrylic resin having excellent adhesion and elasticity to concrete and asphalt base material with a highly reactive acrylic monomer in a specific content range, when painting without containing harmful ingredients such as thinner or gasoline, etc. It has been found that it is possible to provide a coating composition which is fast in drying and excellent in adhesion and visibility with water, excellent in water resistance, abrasion resistance, weather resistance and alkali resistance, chemical resistance and durability.

In particular, the fast-drying coating composition for road markings of the present invention is characterized in that it comprises a resin solution in which the solid acrylic resin is dissolved in an acrylic monomer at 20 to 40 parts by weight based on the total weight of the total composition.

Hereinafter will be described in more detail with respect to each composition component contained in the coating composition according to the present invention.

The coating composition of the present invention is a mixture of the acrylic resin, such as the solid acrylic resin, methyl methacrylate (MMA), hydroxypropyl methacrylate (HPMA) and the like, the hardness and flexibility (stretchability) of the coating film, pot life, drying time, etc. By appropriately controlling the crack and adhesion of asphalt and concrete material, workability, storage properties can be adjusted.

In particular, the paint composition is one or more types of solid acrylic resins based on the total weight of the paint composition, methyl methacrylate (MMA) and butyl methacrylate (BMA), butyl acrylate (BA), which is a monofunctional or higher functional monomer. 20 to 40 parts by weight of the resin solution dissolved in one or more kinds of acrylic monomers, and the like, preferably 25 to 35 parts by weight. Here, when the resin solution is less than 20 parts by weight, the hardness and adhesion of the coating film, flexibility (elasticity), etc. are lowered and the viscosity of the paint is increased, the workability is lowered, and when it exceeds 40 parts by weight, the viscosity of the paint is lowered and the appearance of the coating film and Workability and the like become poor.

On the other hand, the resin solution may contain a solid acrylic resin 20 to 40% by weight, preferably 25 to 35% by weight relative to the total weight of the resin solution, the acrylic monomer 60 to 80 relative to the total weight of the resin solution Wt%, preferably 65 to 75 wt%. When the solid acrylic resin is dissolved in less than 20% by weight, the hardness and flexibility (stretchability) of the coating film may be lowered, and the drying time and the pot life of the paint may be reduced.When the solid acrylic resin is dissolved in more than 40% by weight, the viscosity of the resin is increased and the solid acrylic It may be difficult to dissolve the resin.

In a preferred embodiment of the invention, the at least one type of solid acrylic resin may be dissolved in the acrylic monomer at 60 ° C. or higher in a reaction tank, and preferably, methyl methacrylate (MMA) and butyl methacrylate ( BMA) and butyl acrylate (BA) can be used. In particular, 30 wt% of at least one solid acrylic resin is preferably dissolved in 35 wt% of methyl methacrylate (MMA), 19 wt% of butylmethacrylate (BMA), and 16 wt% of butylacrylate (BA). Can be.

Meanwhile, the solid acrylic resin may have a glass transition temperature (Tg) of 40 to 60 ° C., preferably 42 to 58 ° C., and a weight average molecular weight of 80,000 to 160,000, preferably 85,000 to 158,000. Preferably, by using the above range, the hardness and durability, adhesion, flexibility (stretchability) of the coating film can be appropriate.

In the coating composition of the present invention, the acrylic monomer is methyl methacrylate, methacrylic acid, butyl methacrylate, hydroxypropyl methacrylate, ethylene glycol dimethacrylate, ethoxylated bisphenol-A diacrylate ester, Tetraethylene glycol dimethacrylate, diethylene glycol dimethacrylate, diethylene glycol diacrylate, hydroxylethyl diisoanurate triacrylate, alkyl ester acrylic acid, hydroxyalkyl ester acrylic acid, hydroxy alkyl ester methacrylic Acid, Butylene Glycol Dimethacrylate Tetraethylene Glycol Dimethacrylate, Polypropylene Glycol Dimethacrylate, Bisphenol-A Dimethacrylate, Ethoxylated Bisphenol-A Dimethacrylate, Pentaerydiol Dimethac Relate, butylene glycol tri methacrylate, polyethylene glycol tri methacrylate, bisphenol-A tri methacrylate, ethoxylated bisphenol-A tri methacrylate, pentaacryldiol trimethacrylate, alkyl methacrylate Rate, cycloalkyl methacrylate, ethyl methacrylate, isobutyl methacrylate, t-butyl methacrylate, n-octyl methacrylate, benzyl methacrylate, isooctyl methacrylate, 3-vinylcyclohexyl meta Acrylate, 3.3.5-trimethylcyclohexyl methacrylate, carbonyl methacrylate, isobornyl methacrylate, 1-methylcyclohexyl methacrylate, propanedioldi methylacrylate, butanedioldi methyl acrylate, hexanedioldi Methyl acrylate, oxane diol di methyl acrylate Yate, nonanediol dimethyl acrylate, decanediol dimethyl acrylate, triethyl propane tri methacrylate, trimethylol propane tri methacrylate, 2-hydroxyethyl methacrylate, 2-hydroxypropyl methacrylate , 4-hydroxybutyl acrylate, 2-hydroxyethyl acrylate, 2-hydroxypropyl acrylate, 4-hydroxybutyl methacrylate, kaduraacrylate, kaduramethacrylate, caprolactone acrylate, caprolactone Methacrylate, 2,3-dihydroxypropylacryl, 2,3-dihydroxypropylmethacrylate, polypropylene modified acrylate, polypropylene modified methacrylate, and ethylene glycol diglycidyl ether, normal butyl Methacrylate, normal hexyl methacrylate, 2-ethylhexyl methacrylate, cyclohexyl methacrylate, methyl acrylate Monofunctional or more than butyl acrylate, isobutyl acrylate, normal butyl acrylate, tertiary butyl acrylate, 2-ethylhexyl acrylate, normal octyl acrylate, isobornyl acrylate, cyclohexyl acrylate One or more acrylic monomers and equivalents may be included. Particularly, methyl methacrylate (MMA), hydroxypropyl methacrylate (HPMA), etc. are used in terms of mechanical properties such as pot life, drying time, abrasion resistance and adhesion to the body, tensile strength, adhesive strength, and bending strength. It is preferable to use.

In addition, the coating composition may further include an acrylic monomer in the solid acrylic resin solution, wherein the acrylic monomer is 0.5 to 20 parts by weight, preferably 2 to 18 parts by weight, more preferably, based on the total weight of the total composition. It may be 5 to 15 parts by weight. In view of viscosity control and workability, it is preferable to further add an acrylic monomer in the above range.

The coating composition of the present invention comprises a resin solution in which one or more solid acrylic resins are dissolved in an acrylic monomer, and one or more kinds of acrylic monomers such as methacrylate (MMA) and hydroxypropyl methacrylate (HPMA). When the curing agent is reacted, the coating film may become a solid state in a liquid state during drying due to the radical reaction. At this time, the curing reaction occurs in a short time due to the radical reaction, and when the complete curing can form a high coating film.

In particular, in another preferred embodiment, the coating composition, together with the solid acrylic resin solution, 5 to 10 parts by weight of methyl methacrylate (MMA), preferably as a non-functional acrylic monomer or vinyl monomer, relative to the total weight of the total composition. 5 to 7 parts by weight, and 0.5 to 5 parts by weight of hydroxypropyl methacrylate (HPMA), preferably 1 to 2 parts by weight, as a hydroxyl group-containing acrylic monomer or vinyl monomer.

At this time, if the methyl methacrylate (MMA) is less than 5 parts by weight of the paint to increase the workability and storage properties worsen the appearance of the coating during operation may be poor, when exceeding 10 parts by weight of the coating film is increased and the hardness of the paint The viscosity may be lowered, resulting in poor appearance of the coating during operation. In addition, when hydroxypropyl methacrylate (HPMA) is less than 0.5 parts by weight, the pot life and drying time become longer, resulting in poor drying of the coating film and faster curing when it exceeds 5 parts by weight.

The acrylic monomer may have a glass transition temperature (Tg) of 60 to 120 ° C., preferably 70 to 110 ° C., and a weight average molecular weight of 80 to 160, preferably 100 to 150. By using the above range, the hardness and durability of the coating film, adhesion, flexibility (elasticity) can be appropriate.

In one preferred embodiment of the invention, the coating composition of the present invention is 20 to 40 parts by weight of a resin solution in which a solid acrylic resin is dissolved in an acrylic monomer, 5 to 10 parts by weight of methyl methacrylate (MMA), and the total weight of the composition, and Hydroxypropyl methacrylate (HPMA) may comprise 0.5 to 5 parts by weight.

On the other hand, the coating composition of the present invention may be a two-component reactive road marking paint is a coating that is dried by the reaction of the main agent and the curing agent after applying the lane on the surface of the road. The two-component reactive paint is an environmentally friendly paint that does not use thinners or gasoline. Its construction and curing time and drying time can be controlled when compared to fusion paint and heating paint cover paint. Passage is possible.

In another preferred embodiment of the invention, the coating composition of the present invention is one or more types of solid acrylic resin and methyl methacrylate (MMA), hydroxy, which is a monofunctional or higher functional monomer having a high glass transition temperature (Tg) and high reactivity. Acrylic monomers and antifoaming agents, such as butyl methacrylate (BMA) and butyl acrylate (BA), propyl methacrylate (HPMA) and monofunctional or higher functional monomers having low reactivity and low glass transition temperature (Tg), and additives for surface control The main part (A) including an accelerator in the mixture containing the polymerization inhibitor solution, the paraffin wax solution, organic, inorganic pigment (colored pigment), extender pigment, dispersant, adhesion promoter, nano silica, antioxidant, and UV stabilizer. ) And the curing agent part (B) including the peroxide curing agent in the mixture, and the two paints are mixed to dry quickly and abrasion resistance, weather resistance and weather resistance Kari chemical resistance and durability are capable of providing excellent coating composition.

As described above, the coating composition of the present invention includes an antifoaming agent, a surface control agent, a polymerization inhibitor, a paraffin wax, a color pigment, a sieving pigment, a dispersant, an adhesion promoter, an inorganic filler, and an antioxidant to improve the workability of the paint and the physical properties of the coating film. It may further include one or more selected from the group consisting of a UV stabilizer, a tertiary amine-based accelerator, and a peroxide curing agent.

In particular, the polymerization inhibitor and paraffin wax can be used in the form of a solution. The antifoaming agent is 0.5 to 1 parts by weight, preferably 0.7 to 1 parts by weight, the paraffin wax is 0.5 to 2 parts by weight, preferably 1 to 1.5 parts by weight, and the polymerization inhibitor solution based on the total weight of the total coating composition. 2 to 3 parts by weight, preferably 2.2 to 3 parts by weight can be used.

In addition, the solid paraffin wax is a kind of air barrier material used to smooth the curing of the paint, and may be selected from at least one of the solid paraffin wax, such as 48 ℃, 52 ℃, 58 ℃ melting point as a petroleum compound.

The antifoaming agent is a silicone-based antifoaming agent, which removes bubbles in the coating during manufacture or operation of the coating to improve the appearance of the coating upon drying the coating, and at least one antifoaming agent may be selected.

In particular, the defoamer improves the appearance of the coating film during drying, by removing the bubbles in the paint during the manufacture of the paint, and if the antifoaming agent is not used, bubbles are generated in the coating film. It appears that the appearance of the coating film is poor. The polymerization inhibitor solution is a resin solution in which an accelerator, a curing agent and a solid acrylic resin are dissolved in acrylic monomers such as methyl methacrylate (MMA), butyl methacrylate (BMA), and butyl acrylate (BA), and methyl methacrylate. (MMA), hydroxypropyl methacrylate (HPMA), such as acrylic monomers when reacting with the reaction rate, pot life, drying time, storage properties, etc. are effective in controlling the paint and the external heat or reaction of the paint during storage Prevents gelation In addition, drying of the paint proceeds while the resin solution in the paint, the acrylic monomer, the curing agent, and the accelerator react with each other to form a radical reaction. If the oxygen in the air participates in the reaction, it may cause a poor drying and deterioration of physical properties. In particular, problems such as poor hardness of the coating film and adhesion, durability, and abrasion may appear. In order to suppress the reaction of oxygen, the paraffin wax solution forms a film on the surface of the coating film to suppress the reaction with oxygen, thereby making it possible to cure the coating film and obtain good physical properties.

On the other hand, the surface control agent smoothes the surface of the coating during operation to improve the appearance of the coating during drying, and improves problems such as insufficient wetting, poor wettability, cratering formation, color separation of the pigment, etc. during the coating is formed. It can play a role. Preferably, a silicone surface control agent, a non-silicone surface control agent and the like can be used.

The pigment may be an organic pigment, an inorganic pigment, a extender pigment. The organic and inorganic pigments may be selected from one or more of colored pigments as colored pigments. In particular, organic / inorganic pigments (colored pigments) are effective in realizing the color of the paint, it is effective in the coloring and imparting hiding power of the paint. In addition, the dispersant improves the dispersion of pigments and extender pigments in the paint to determine the visual effect and hiding power of the coating film and may play an important role in the manufacture of the paint, storage and coating.

Such pigmented pigments (organic and inorganic pigments) require particularly good durability. If the paint is poor in durability, especially light resistance, acid resistance, etc., the color of the paint may be discolored within a few days. Recently, due to air pollution, the air is contaminated with acidic substances, mixed with rainwater to become acidic and wet the coating film may cause discoloration of the weak acid resistance pigment. In consideration of this, it is possible to obtain a good physical property by selecting a pigment with good durability.

The extender pigment may be selected from at least one of a mixture of fillers and extender pigments such as calcium carbonate, talc, silica, mica, kaolin, etc. The extender pigment may control the physical properties such as fluidity and viscosity of the paint and the strength, durability, gloss of the coating film. It is effective for adjustment.

In addition, the dispersant may be selected from one or more of the dispersant for the organic inorganic pigment as a wet dispersant for the oil paint.

Nano-silica as the inorganic filler may be selected from one or more nano-silica and the like as used for imparting thickening and thixotropy, preventing sedimentation and redispersion of particles and improving flowability and storage stability of particles. The nano silica is used to impart thickening and thixotropy, to prevent sedimentation and re-dispersibility of particles, to improve flow properties, and to improve storage stability of particles, thereby having an effect on paint properties and storage properties.

The adhesion promoter is characterized in that at least one selected from adhesion promoters as an additive that serves to increase the adhesion with the base.

Adhesion promoters increase the adhesion between the base and the coating when the coating is dried. Phosphoric acid-acrylic and succinate esters, acrylated polyester oligomers, gamma-methacrylooxapropyltrimethoxysilane, tris-omega- Methoxyethoxy silane and the like can be used, and it is more preferable to use an acrylated polyester oligomer.

The antioxidant and ultraviolet stabilizer is an antioxidant and ultraviolet absorber and blocker, the antioxidant is characterized in that at least one selected from phenolic, thio (Thio), phosphorus, amine-based UV stabilizer is benzotriazo-based, benzophenone-based At least one selected from among triazine, organonickel and sunscreen agents and ultraviolet absorbers.

Antioxidants and UV stabilizers prevent the film from fading due to contact with ultraviolet rays and air after drying or during drying. The redox reaction proceeds when the polymer is exposed to UV and air. Oxidants and UV stabilizers are most effective in controlling fading and yellowing in the long term, and thus can obtain good physical properties in terms of weather resistance of UV and air coatings. Antioxidants are used antioxidants such as phenolic, thio (thio), phosphorus, amines and the like, characterized in that at least one selected from. In addition, UV stabilizers are divided into UV absorbers, sunscreens, etc., by function, and may be used by selecting one or more of benzotriazo-based, benzophenone-based, triazine-based, organonickel-based and sunscreens, and UV absorbers.

Such antifoaming agents, polymerization inhibitor solutions, paraffin wax solutions, surface control additives, organic, inorganic pigments (colored pigments), sieving pigments, dispersants, adhesion promoters, silica, antioxidants, ultraviolet absorbers and sunscreen agents, the total weight of the coating composition 0.5 to 1 part by weight of antifoaming agent, 2-3 parts by weight of polymerization inhibitor, 1 to 3 parts by weight of paraffin wax solution, 0.5 to 1 part by weight of additives for surface control, 0.5 to 1 part by weight of dispersant, 10 to 20 weight of pigmented pigment It is preferable to be contained within the range of 40-50 weight part of extender pigments, 0.1-0.5 weight part of adhesion promoters, 0.1-0.5 weight part of nano silicas, 0.1-0.5 weight part of antioxidants, and 0.1-0.5 weight part of ultraviolet stabilizers.

In particular, in another preferred embodiment of the invention, the coating composition of the present invention is 20 to 40 parts by weight, preferably 25 to 35 parts by weight, based on the total weight of the total coating composition, of a resin solution in which a solid acrylic resin is dissolved in an acrylic monomer. , Methyl methacrylate (MMA) 5 to 10 parts by weight, preferably 5 to 7 parts by weight, hydroxypropyl methacrylate (HPMA) 0.5 to 5 parts by weight, preferably 1 to 2 parts by weight, antifoam 0.5 to 1 part by weight, preferably 0.7 to 1 part by weight, 0.5 to 1 part by weight of surface conditioner, preferably 0.5 to 0.7 part by weight, 2 to 3 parts by weight of polymerization inhibitor, preferably 2 to 3 parts by weight, paraffin wax 1 to 3 parts by weight, preferably 1 to 1.5 parts by weight, 10 to 20 parts by weight of colored pigment, preferably 15 to 20 parts by weight, 40 to 60 parts by weight of extender pigment, preferably 50 to 60 parts by weight, dispersant Within 0.5 1 part by weight, preferably 0.7 to 1 part by weight, 0.1 to 0.5 parts by weight of adhesion promoter, preferably 0.2 to 0.4 part by weight, 0.1 to 0.5 part by weight of inorganic filler, preferably 0.2 to 0.4 part by weight, antioxidant 0.1 To 0.5 parts by weight, preferably 0.2 to 0.4 parts by weight, and 0.1 to 0.5 parts by weight of the UV stabilizer, and preferably 0.2 to 0.4 parts by weight.

As described above, the coating composition of the present invention includes a main portion (A) and a hardener portion (B) as a two-part reactive road marking paint, and the two coatings are dried by reaction of the respective main and hardeners. It can be a paint.

As the accelerator to be mixed in the main portion (A) in the coating composition, a tertiary amine accelerator is preferable, and para toluidine amine accelerator may be used more preferably. In particular, dimethyl-p-toluidine, diethanol-p-toluridine, diethoxy-p-toluidine, diethyl-p-toluidine, dipropoxy-p-toluidine or a mixture thereof which is a para toluidine amine accelerator You can select more than one species.

The accelerator may be used in an amount of 1 to 2 parts by weight, preferably 1 to 1.5 parts by weight, based on the total weight of the total composition. If the accelerator is used in an amount less than 1 part by weight, curing and drying speed and drying time may be prolonged, or drying of the coating film may not occur due to poor curing, and when the accelerator is used in excess of 2 parts by weight, the curing speed may be too fast, resulting in an appearance of the coating film. This is poor and the pot life is shortened, which affects the working time and the film drying time, and can also affect the strength, water resistance, durability and weather resistance of the film. That is, if the accelerator is not used in the range of 1 to 2 parts by weight, the coating film may not be formed or harden. Therefore, a better effect can be obtained when using 1 to 2 parts by weight of the tertiary amine accelerator based on the total weight of the total coating composition.

In addition, as the peroxide curing agent to be mixed in the curing agent portion (B) in the coating composition of the present invention, one or more types of peroxide-based peroxide curing agents, ester-based curing agents, and curing agents containing aliphatic azo groups may be used. Peroxide, ketone peroxide, acetylacetone peroxide, methylethylketone peroxide, cyclohexane peroxide, methylisobutylketone peroxide, benzoyl peroxide, lauryl peroxide, isobutyryl peroxide, acetyl peroxide, 2 Peroxide-based peroxide curing agents such as, 4-dichlorobenzoyl peroxide, succinic acid peroxide, dicanoyl peroxide, diisononanoyl peroxide, cumene hydroperoxide, perester curing agents, curing agents including aliphatic azo groups, and mixtures thereof. You can use one or more selected from the group consisting of, Among these, it is more preferable to use a benzoyl peroxide system.

The amount of the peroxide curing agent varies depending on the atmospheric temperature and the substrate (road surface) temperature, but may be used in an amount of 2 to 10 parts by weight, preferably 2 to 4 parts by weight, based on the total weight of the entire composition. At this time, if the curing agent is used in less than 2 parts by weight in the curing agent portion (B) in accordance with the atmospheric temperature and the holding temperature in general, the curing and drying speed and time is long, or the coating film is hardly dried in the summer. If it is used in excess of 10 parts by weight, the curing speed is so high that the appearance of the coating is poor and the pot life is shortened, which affects the working time and the drying time of the coating and also affects the storage time of the coating. Gelation may proceed. Therefore, it is preferable to use within the content range according to the atmospheric temperature and the holding temperature during the operation based on the total weight of the total coating composition.

In particular, since the amount of peroxide curing agent and accelerator is used varies depending on the air temperature and the holding temperature, the amount of peroxide curing agent and accelerator may be adjusted to adjust the pot life and drying time according to the amount of use, so that the amount of the peroxide curing agent and the accelerator may be reacted with the paint.

On the other hand, the present invention provides a method for producing such a fast-drying coating composition for road marking. The manufacturing method comprises the steps of a) dissolving a solid acrylic resin in an acrylic monomer to prepare a resin solution, b) further adding an acrylic monomer to the resin solution to prepare a mixture, c) prepared in step b) Mixing the tertiary amine accelerator into the mixture to prepare a main portion (A), d) mixing the peroxide curing agent into the mixture prepared in step b) to prepare the curing agent portion (B), and e) the Mixing the main portion (A) and the curing agent portion (B).

In the method of the present invention, the main portion (A) and the curing agent portion (B) in step e) may be mixed in a weight ratio of 0.8: 1 to 2: 1, preferably in a weight ratio of 0.9: 1 to 1.2: 1. It is preferable to maintain the blending ratio in terms of drying time, pot life, and physical properties.

In addition, the anti-foaming agent, surface control agent, polymerization inhibitor, paraffin wax, pigmented pigment, extender pigment, dispersant, adhesion promoter, inorganic filler, antioxidant, and UV stabilizer in the mixture prepared in step b) Mixing the above may be further included.

Referring to the method for producing a coating composition of the present invention is as follows.

First, in one preferred embodiment of the invention, the method for producing a two-component quick-drying curable reactive resin coating composition for road marking according to the present invention is 1) a resin in which at least one solid acrylic resin is dissolved in at least one acrylic monomer Preparing a solution; 2) preparing a polymerization inhibitor solution obtained by dissolving at least one polymerization inhibitor in an acrylic monomer; 3) preparing a paraffin wax solution in which at least one type of solid paraffin wax is dissolved; 4) preparing a mixture in which at least one kind or more functional acrylic monomers are added to the resin solution prepared in step 1); 5) mixing the antifoaming agent to the mixture prepared in step 4); 6) mixing the surface control additive to the mixture prepared in step 5), 7) adding the polymerization inhibitor solution, the paraffin wax solution to the mixture prepared in step 6); 8) mixing organic and inorganic pigments (colored pigments) to the mixture prepared in step 7); 9) mixing the extender pigment into the mixture prepared in step 8); 10) mixing the dispersant into the mixture prepared in step 9); 11) mixing the adhesion promoter into the mixture prepared in step 10); 12) mixing the nano silica to the mixture prepared in step 11); 13) mixing the antioxidant in the mixture prepared in step 12); 14) mixing the sunscreen and the ultraviolet absorber to the mixture prepared in step 13); 15) preparing a main part (A) by mixing an accelerator with the mixture prepared in step 14); 16) preparing a curing agent (B) by mixing the mixture prepared in step 14) with a peroxide curing agent; And 17) mixing the mixture prepared in step 15), that is, the main ingredient (A) and the mixture prepared in step 16), that is, the curing agent part (B) in a weight ratio of 1: 1. have.

In one preferred embodiment of the invention, first, the polymerization inhibitor is quinone ether, para-benzoquinone, methyl hydroquinone, methylethyl hydroquinone, ethyl hydroquinone, butyl catechol, di tertiary butyl para cresol or mixture before operation . And at least one selected from triphenyl stybin series and triphenyl antimony series. The polymerization inhibitor solution may be prepared by dissolving in methyl methacrylate (MMA) in a 40 ° C thermostat. The polymerization inhibitor is not evenly dissolved evenly in a step in which a resin solution, an acrylic monomer, a pigment, etc., in which a solid acrylic resin is dissolved in an acrylic monomer, is preferably dissolved in a constant temperature bath at 40 ° C. before operation. In addition, although it may be dissolved in other solvents and solvents, when a solvent other than methyl methacrylate (MMA), which is the main solvent of the coating composition, is used, it may affect the hardness and durability of the coating film, poor color drying and drying time. It is preferable to dissolve in methyl methacrylate (MMA) because physical properties may be degraded.

At this time, the polymerization inhibitor is dissolved in methyl methacrylate (MMA) to 10 to 20% by weight, when dissolved to less than 10% by weight to control the reaction rate in the reaction with the main portion (A) and the curing agent portion (B) Its role is lowered and may affect the reaction rate, pot life, drying time, shelf life, etc. during the reaction of the main part (A) and the hardener part (B)). Can promote gelation. In addition, when dissolved in more than 20% by weight is effective in controlling the reaction rate, pot life, drying time, storage properties, etc. during the reaction of the main portion (A) and the curing agent portion (B)), the paint is less dry and hard The slower the coating, the weaker the coating and the lower the durability and weather resistance.

In addition, in one preferred embodiment of the invention, in the same way as the polymerization inhibitor solution, at least one selected from petroleum compounds 48 ℃, 52 ℃, 58 ℃ (melting point) solid paraffin wax before operation, dissolved in toluene (methyl benzene) paraffin Wax solutions can be prepared. Paraffin wax is a petroleum-based compound, which is in a solid state and difficult to dissolve at room temperature (20-25 ° C.) and easily dissolved at a temperature above 40 ° C. depending on the melting point.

At this time, the paraffin wax is dissolved in toluene to 10 to 30% by weight, when dissolved in less than 10% by weight, the oxygen blocking effect is less, the oxygen in the air participates in the reaction during the reaction to reduce the poor drying and physical properties. Poor hardness of the coating and problems such as adhesion, durability and wear may occur. In addition, when dissolved in more than 30% by weight, it is not difficult to dissolve in toluene in a thermostat of 40 ℃ or more, but after dissolving, paraffin wax changes from a liquid state to a solid state at room temperature. Waking up. Poor drying and physical properties may be reduced when the coating film is dried. In addition, the solid paraffin wax is insoluble in solvents and solvents other than toluene (methyl benzene) at 40 ° C or higher. If methyl methacrylate (MMA) and other solvents, the main solvent of the coating composition, are used, complete dissolution does not occur, affecting the hardness and durability of the coating film, poor color drying and drying time. Since it is possible to dissolve in toluene (methylbenzene), it is preferable.

In a preferred embodiment of the invention, one or more types of solid acrylic resins are then dissolved in acrylic monomers such as one or more functional methyl methacrylate (MMA) and butyl methacrylate (BMA), butyl acrylate (BA). 20 to 40% by weight of the resin solution (preferably 25 to 35% by weight), 5 to 10% by weight of methyl methacrylate (MMA) and 0.5 to 5% by weight of hydroxypropyl methacrylate (HPMA) (preferably 1 ˜2% by weight) may be prepared.

In addition, methyl methacrylate (MMA) and hydroxypropyl methacrylate (HPMA) may be added and mixed with the above prepared resin solution while stirring. At this time, in addition to dissolving the solid acrylic resin, the reason for adding an acrylic monomer such as methacrylate (MMA) and hydroxypropyl methacrylate (HPMA), etc., in addition to the viscosity control and workability of the paint and the appearance and hardness of the coating film Because it can affect. When methyl methacrylate (MMA) is less than 5 parts by weight, the viscosity of the paint is increased, and workability and storage property are deteriorated, and the appearance of the coating is poor at the time of work. When it exceeds 10 parts by weight, the hardness of the coating is increased and the viscosity of the paint is decreased. Appearance of the coating film becomes poor. In addition, when hydroxypropyl methacrylate (HPMA) is less than 0.1 part by weight, the pot life and drying time become longer, resulting in poor drying of the coating film and faster curing when it exceeds 5 parts by weight.

In other words, by mixing the solid acrylic resin and the resin solution with methyl methacrylate (MMA), hydroxypropyl methacrylate (HPMA) to properly adjust the hardness and flexibility (stretchability), pot life, drying time, etc. of the coating film asphalt It can control the cracking, adhesion, workability and storage of concrete materials.

In addition, in a preferred embodiment of the invention, 0.5-1 part by weight of an antifoaming agent in a mixture of the solid acrylic resin solution, methyl methacrylate (MMA), hydroxypropyl methacrylate (HPMA) is added and mixed, 2 to 3 parts by weight of the polymerization inhibitor solution, 1 to 3 parts by weight of the paraffin wax solution, 0.5 to 1 part by weight of the leveling agent and 0.5 to 1 part by weight of the dispersant, and stirred and mixed at 500 to 1000 rpm for 10 to 20 minutes. Be sure to After the mixture is mixed, it is added within the range of 10 to 20 parts by weight of organic and inorganic pigments (colored pigments) and 40 to 50 parts by weight of extender pigments, and mixed by stirring at 1500 to 2000 rpm for 20 to 30 minutes. After the mixture is mixed, it is added within the range of 0.1 to 0.5 parts by weight of antioxidant, ultraviolet absorber, and 0.1 to 0.5 parts by weight of sunscreen, and mixed by stirring at 500 to 1000 rpm for 20 to 30 minutes.

In a preferred embodiment of the invention, the promoter is added to the coating composition prepared as described above in the range of 1 to 2 parts by weight based on the total weight of the total coating composition and mixed by stirring at 500 to 1000 rpm for 5 to 10 minutes. Part (A) is added to the coating composition prepared as described above to add a peroxide curing agent within the range of 2 to 10 parts by weight based on the total weight of the total coating composition and to stir for 5 to 10 minutes at 500 to 1000 rpm to mix the curing agent By making (B) and mixing the two paints in a 1: 1 weight ratio, it is possible to provide a coating composition which is quick to dry during coating and has excellent abrasion resistance, weather resistance and alkali resistance chemical resistance and durability.

In addition, when the peroxide curing agent is mixed in the main portion (A) in which the accelerator is mixed during coating, the pot life of the paint may be shortened rapidly, resulting in poor workability. On the contrary, even when the accelerator is mixed in the curing agent portion (B), the pot life of the paint may be shortened rapidly, resulting in poor workability and making it impossible to use.

On the other hand, the two-component fast-drying curable resin coating composition for road marking according to the present invention is used for marking roads with signs, letters, or lines on the road surface for the safety of traffic on asphalt, concrete road, etc. Or the like.

In the present invention, matters other than those described above can be added or subtracted as required, and therefore, the present invention is not particularly limited thereto.

The fast-drying coating composition for road markings of the present invention includes a solid acrylic resin having excellent adhesion and elasticity and an acrylic monomer having excellent reactivity to concrete and asphalt substrates in a specific content range to effectively mix with an acrylic monomer having excellent reactivity. And when drying, it is quick to dry and the adhesion and visibility with the body, water resistance, wear resistance, weather resistance and alkali resistance, chemical resistance, durability and the like can obtain an excellent effect.

Hereinafter, preferred examples are provided to help understanding of the present invention, but the following examples are merely to illustrate the present invention, and the scope of the present invention is not limited to the following examples.

Example 1

To a fast-drying paint composition for road marking with a composition as shown in Table 1 below.

First, the polymerization inhibitor solution was prepared by dissolving 1.25% by weight of the polymerization inhibitor in 98.75% by weight of methyl methacrylate in a separate container using a stibin-based polymerization inhibitor before operation. It was.

In addition, 15 wt% of toluene 85% by weight of paraffin wax was added to another separate container in a thermostat of 40 ° C. or higher using a solid paraffin wax (petroleum paraffin wax) having a petroleum compound melting point of 58 ° C. in advance as before the polymerization solution. Dissolve in wt% to prepare a paraffin wax solution.

Next, methyl methacryl was used as the acrylic monomer of the solid acrylic resin (Degussa), MMA (lodge Co.), BAM (lodge Co.) and BMA (lodge Co.) as the acrylic monomer. A resin solution was prepared by dissolving in 35% by weight of late (MMA), 19% by weight of butyl methacrylate (BMA), and 16% by weight of butyl acrylate (BA). The resin solution was used at 22.4% by weight based on the total composition, and 0.8% by weight of methyl methacrylate (MMA) and 4.6% by weight of hydroxypropyl methacrylate (HPMA) were further mixed as acrylic monomers during stirring. .

In addition, 0.5% by weight of the antifoaming agent, 3% by weight of the polymerization inhibitor solution, 1.5% by weight of the paraffin wax solution, 0.5% by weight of surface conditioner, 0.1% by weight of adhesion promoter, and 0.5% by weight of dispersant were added to the mixture of the solid acrylic resin solution. And stirred for 10 to 20 minutes at 500 ~ 1000 rpm to be uniformly mixed. Further, after the mixture is uniformly mixed, 15% by weight of organic / inorganic pigments (colored pigments), 50% by weight of extender pigments, and 0.2% by weight of nanosilica as an inorganic filler are further added, and 20 to 1500 to 2000 rpm. Stir for 30 minutes and mix. After the mixture was uniformly mixed, 0.1 wt% of antioxidant, 0.2 wt% of ultraviolet absorber, and 0.2 wt% of sunscreen were added and stirred at 500-1000 rpm for 20-30 minutes to ensure uniform mixing.

To the mixture of the solid acrylic resin solution prepared as above, 0.5% by weight of diethanol-p-toluidine and 0.5% by weight of dimethyl-p-toluidine were further added as a tertiary amine promoter based on the total weight of the total composition, Main part (A) was prepared by uniformly mixing by stirring for 5-10 minutes at 500 ~ 1000 rpm. In addition to the main portion (A), 5% by weight of a peroxide curing agent is further added to the mixture of the solid acrylic resin solution prepared as described above, based on the total weight of the entire composition, and 5 to 500 to 1000 rpm. Stirring for 10 minutes to uniformly mix to prepare a curing agent portion (B).

The main part (A) and the curing agent (B) thus prepared were mixed and stirred in a weight ratio of 1: 1 to prepare a quick drying coating composition for two-part road marking.

Examples 2-6 and Comparative Example 1

Except for changing the specific compound and content in the composition as shown in Table 1, was prepared in the same manner as in Example 1 two-component road marking fast-drying coating composition.

The compositions of Examples 1 to 6 and Comparative Example 1 are as shown in Table 1 below. The unit is weight percent.

division Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Comparative Example 1 Subject
(A) Resin solution ¹⁾ 22.4 22.4 224. 22.4 22.4 22.4 22.4 Acrylic monomer ^{2) 1} 0.8 1.8 2.8 2.5 3.8 4.5 5.0 Acrylic monomer ^{2) 2} 4.6 3.6 2.6 2.9 1.6 One 5.4 Antifoam ³⁾ 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Polymerization inhibitor solution ⁴⁾ 3 3 3 3 3 3 Paraffin wax solution ⁵⁾ 1.5 1.5 1.5 1.5 1.5 1.5 Dispersant ⁶⁾ 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Surface conditioner ⁷⁾ 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Pigmented pigments ⁸⁾ 15 15 15 15 15 15 15 Extender pigments ⁹⁾ 49.5 49.5 49.5 49.5 49.5 49.5 49.5 Inorganic filler ¹⁰⁾ 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Adhesion Promoter ^{11) 1} 0.1 0.1 0.1 0.1 0.1 0.1 Antioxidants ¹² 0.1 0.1 0.1 0.1 0.1 0.1 UV absorbers ^{13) 1} 0.2 0.2 0.2 0.2 0.2 0.2 Sunscreen ^{13) 2} 0.1 0.1 0.1 0.1 0.1 0.1 Tertiary Amine-Based Accelerator ^{14) 1} 0.5 0.5 0.5 0.5 Tertiary Amine-Based Accelerator ^{14) 2} 0.5 0.5 0.5 Tertiary Amine-Based Accelerator ^{14) 3} 0.5 0.5 0.5 0.5 Tertiary Amine-Based Accelerator ^{14) 4} 0.5 0.5 0.5 Sum 100 100 100 100 100 100 100 Curing agent part
(B) Resin solution ¹⁾ 22.4 22.4 224. 22.4 22.4 22.4 22.4 Monomer ^{2) 1} 0.8 1.8 2.8 2.5 3.8 4.5 5.0 Monomer ^{2) 2} 4.6 3.6 2.6 2.9 1.6 One 5.4 Antifoam ³⁾ 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Polymerization inhibitor solution ⁴⁾ 3 3 3 3 3 3 Paraffin wax solution ⁵⁾ 1.5 1.5 1.5 1.5 1.5 1.5 Dispersant ⁶⁾ 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Surface conditioner ⁷⁾ 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Pigmented pigments ⁸⁾ 15 15 15 15 15 15 15 Extender pigments ⁹⁾ 45.5 45.5 45.5 45.5 45.5 45.5 45.5 Inorganic filler ¹⁰⁾ 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Adhesion promoter ¹¹⁾ 0.1 0.1 0.1 0.1 0.1 0.1 Antioxidant ¹²⁾ 0.1 0.1 0.1 0.1 0.1 0.1 UV absorbers ^{13) 1} 0.2 0.2 0.2 0.2 0.2 0.2 Sunscreen ^{13) 2} 0.1 0.1 0.1 0.1 0.1 0.1 Peroxide Curing Agent ¹⁵⁾ 5 5 5 5 5 5 5 Sum 100 100 100 100 100 100 100 Sum 100 100 100 100 100 100 100 1): Mixed solution of solid acrylic resin (Degussa), MMA (lodge Co.), BAM (lodge Co.) and BMA (lodge Co.)
2) 1: methyl methacrylate (MMA, Roset Co.)
2) 2: 2hydroxy propyl methacrylate (Ooxun Industries)
3): Silicone additive (BYK)
4): Stebine-based (Unicorn Chemical)
5): Paraffin wax (Inochem, melting point 58 ℃)
6): Ester-based wetting and dispersing agent (BYK)
7): Silicone surface control agent (BYK)
8) Colored pigment, titanium oxide (millenium)
9) Sieving Pigment, Calcium Carbonate (Wujin Chemical)
10): Nano silica (SEWON Corporation)
11) Adhesion Promoter (Sungwon Materials)
12) Antioxidant Antioxidant
13) 1: sunscreen (Ciba specialty chemicals)
13) 2: UV absorber (Ciba specialty chemicals)
14) 1: Ethanol ptoluidine (Kun Il Co., Ltd.)
14) 2: dimethyl p toluidine (Dimethylptoluidine)
14) 3: diethoxy ptoluidine (Simechem International)
14) 4: diethylptoluidine (Donghwa Chemtech)
15): Benzoyl peroxide (Donghwa Chemtech)

Experimental Example 1

The physical properties of the two-component road marking quick-drying paint composition prepared according to Examples 1 to 6 and Comparative Example 1 were measured in the following manner.

Viscosity

It measured with the viscometer at 25 degreeC.

importance

The paint was poured into a defined specific gravity cup at a paint temperature of 25 ° C. and its weight was measured.

Housework time

As the work in the field was applied at intervals of 2 to 3 minutes with a brush or a roller at room temperature and open space to measure the time when the painting workability does not come out.

Drying time

Curing drying after application was measured at room temperature and in open space (time when no finger prints remained when twisted with thumb).

Hardness

The coating film was taken with a Shore D hardness tester, and the gauge was read to measure Shore D hardness.

Asphalt bleeding characteristics

It was evaluated after observing that the paint was applied to the asphalt and the asphalt melted in the paint so that black color appeared on the coating film.

Asphalt adhesion

After coating the asphalt with about 50 ~ 100 μm and drying it, scrape it with a letter X and cut the corners with a knife to observe the separation of asphalt and coating film.

Acid resistance

A coating film was formed on the slate plate with a thickness of 1 to 3 mm and immersed in 50% sulfuric acid solution to observe abnormalities such as peeling or discoloration.

Water resistance

The coating film was formed in a slate plate with a thickness of 1 to 3 mm, soaked in water to observe abnormalities such as peeling or discoloration.

Alkali resistance

A coating film was formed on the slate plate with a thickness of 1 to 3 mm and immersed in a 10% caustic soda solution to observe abnormalities such as peeling or discoloration.

Self leveling characteristics (Self leveling, Auto leveling characteristics, Self leveling)

When the paint was poured and scraped with a saw blade rake, it was observed and evaluated whether a saw blade was left and a smooth coating film was formed.

Workability

It was observed and evaluated whether roller marks or other visual abnormalities were found due to inadequate viscosity when painting with rollers, brushes and airless spray.

Sticky

After drying, the finger or palm was pressed with force to observe whether there was a slight feeling of sticking.

Concrete adhesion

After coating with concrete about 50 ~ 100 ㎛ and scratching with a knife after drying with a knife, the edges were cut out with a knife, and the concrete and the coating film were separated and evaluated.

The physical properties of the two-component road marking fast-drying paint compositions of Examples 1 to 6 and Comparative Example 1 measured in the same manner as described above are shown in Table 2 below.

 Experiment Item Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Comparative Example 1 Viscosity (Ku / 25 ℃) 89 88 89 87 89 89 80 importance 1.76 1.76 1.75 1.76 1.76 1.75 1.74 Pot life (min) 5 15 6 5 10 10 20 Drying time (min) 30 minutes 120 60 30 60 120 120 Shore D hardness 60 45 40 70 60 40 60 Asphalt bleeding castle Good Good Good Good Good Good Good Asphalt adhesion Good Good Good Good Good Good Good Acid resistance (deposition) Good Good Good Good Good Good After 3 days Water resistance (deposition) Good Good Good Good Good Good Good Alkali resistance (deposition) Good Good Good Good Good Good Bad Self leveling
(Lake work) Good Bad Good Good Good Good Good  Workability Good Good Good Good Good Good Good Sticky Good Good Good Good Good Good Bad Concrete adhesion Good Good Good Good Good Good Good

As shown in Table 2, Examples 1 to 6 according to the present invention, by adding additives such as a polymerization inhibitor solution and a paraffin wax solution, adhesion and visibility with the body, water resistance, wear resistance, weather resistance and alkali resistance, resistance It can be seen that excellent effects can be obtained in chemical properties and durability.

On the other hand, the coating composition of Comparative Example 1, in which no additives such as a polymerization inhibitor solution and a paraffin wax solution are added, is poor in acid resistance, alkali resistance, and adhesiveness, and may cause problems in terms of long-term physical properties.

Comparative Example 2

As a conventional road marking paint, a water-soluble road marking coating composition including an anti-foaming agent, an emulsifier, a dispersing agent, a PH regulator, a thickener and a white pigment, and an extender pigment in a water-soluble acrylic emulsion based on an aqueous acrylic emulsion (KSM 6080 2). Seeds, light paints) were prepared.

Comparative Example 3

As a commercially available road marking paint, it is an oil-based acrylic resin mainly composed of oil-based acrylate resin, including an antifoaming agent, a dispersant, a thickener and a white pigment, a sieving pigment, etc. Dimming paint) was prepared.

Experimental Example 2

About the coating composition prepared according to Example 4 and Comparative Examples 2 to 3, the respective physical properties were measured in the same manner as in Experimental Example 1, and the results are shown in Table 3 below.

Experiment Item Example 4 Comparative Example 2 Comparative Example 3 Pot life (min) 5 minutes Drying time (min) 30 minutes 24 hours 24 hours Complete Curing Time (h) 1 hours 7 days 7 days Shore D hardness 70 Asphalt bleeding sex Good Bad Bad Asphalt adhesion Good Good Good Acid Resistance (50% H ₂ SO ₄ ) Good 24 hours discoloration
Inflate 48 hours 24 hours discoloration
Inflate 48 hours Alkali Resistance (10% NaOH) Good Bad Bad Water resistance (H ₂ O) Good Bad Good Self levelling Good Workability Good Good Good State in container Good Good Good

As shown in Table 3, Example 4 according to the present invention has a fast drying time and excellent adhesion, chemical resistance, workability, etc. It can be seen that excellent effects can be obtained in alkali resistance, chemical resistance and durability.

On the other hand, the coating composition of Comparative Example 2 using a water-soluble acrylic emulsion is not good drying time and chemical properties, and may cause problems in terms of working time and physical properties. In addition, the coating composition of Comparative Example 3 using an oil-based acrylic resin is not good in drying time and chemical properties, it may cause problems in terms of working time and physical properties.

In particular, as shown in Tables 2 and 3, the coating composition of the present invention contains an acrylic monomer having excellent reactivity with a solid-state acrylic resin having excellent adhesion and elasticity to concrete and asphalt substrates, and added by adding a peroxide curing agent and an accelerator. Fast curing speed allows drying of paint in 30 minutes. In addition, it is possible to dry the paint within 30 minutes as described above has the advantage of minimizing the paint traffic control time and working time.

In addition to the excellent drying time, the coating composition of the present invention is excellent in adhesion, visibility, abrasion resistance, weather resistance and alkali resistance, chemical resistance and durability to extend the maintenance period than conventional paint can significantly reduce the maintenance cost have.

Furthermore, it can be seen that the coating composition can be cured at sub-zero temperatures by adding a curing agent and an accelerator according to the temperature, so that the workability is very excellent.

In particular, the paint composition of the present invention is a very environmentally friendly paint does not contain environmentally harmful components such as thinner or gasoline, and the construction and curing time and drying time is controlled when compared to fusion paints and coatings for heating type coatings It is possible that the vehicle can pass on the lane within 30 minutes.

Claims (16)

A fast-drying coating composition for road markings comprising a resin solution in which a solid acrylic resin is dissolved in an acrylic monomer at 20 to 40 parts by weight based on the total weight of the total composition. The method of claim 1, The solid acrylic resin has a glass transition temperature of 40 to 60 ℃, the weight average molecular weight of 80,000 to 160,000 road marking quick-drying coating composition. The method of claim 1, The resin solution comprises a solid acrylic resin of 20 to 40% by weight relative to the total weight of the resin solution, and an acrylic monomer containing 60 to 80% by weight relative to the total weight of the resin solution. The method of claim 1, A fast-drying coating composition for road markings comprising 0.5 to 20 parts by weight of acrylic monomers, based on the total weight of the total composition. The method of claim 1, The acrylic monomer is methyl methacrylate, methacrylic acid, butyl methacrylate, hydroxypropyl methacrylate, ethylene glycol dimethacrylate, ethoxylated bisphenol-A diacrylate ester, tetra ethylene glycol dimethacryl Diethylene glycol dimethacrylate, diethylene glycol diacrylate, hydroxylethyl diisoanurate triacrylate, alkyl ester acrylic acid, hydroxyalkyl ester acrylic acid, hydroxy alkyl ester methacrylic acid, butylene glycol di Methacrylate techlaethylene glycol dimethacrylate, polypropylene glycol dimethacrylate, bisphenol-A dimethacrylate, ethoxylated bisphenol-A dimethacrylate, pentaerydiol dimethacrylate, butyl Lenglycol Limethacrylate, polyethylene glycol trimethacrylate, bisphenol-A trimethacrylate, ethoxylated bisphenol-A trimethacrylate, pentaacryldiol trimethacrylate, alkyl methacrylate, cycloalkyl methacrylate Latex, ethyl methacrylate, isobutyl methacrylate, t-butyl methacrylate, n-octyl methacrylate, benzyl methacrylate, isooctyl methacrylate, 3-vinylcyclohexyl methacrylate, 3.3.5 Trimethylcyclohexyl methacrylate, carbonyl methacrylate, isobornyl methacrylate, 1-methylcyclohexyl methacrylate, propanediol dimethyl acrylate, butanediol dimethyl acrylate, hexanediol dimethyl acrylate, oxane diol Dimethylacrylate, nonanediol dimethyla Relate, decanediol dimethyl acrylate, triethyl propane tri methacrylate, trimethylol propane tri methacrylate, 2-hydroxyethyl methacrylate, 2-hydroxypropyl methacrylate, 4-hydroxybutyl acryl Latex, 2-hydroxy ethylacrylate, 2-hydroxypropylacrylate, 4-hydroxybutyl methacrylate, kaduraacrylate, kaduramethacrylate, caprolactone acrylate, caprolactone methacrylate, 2,3 -Dihydroxypropylacryl, 2,3-dihydroxypropylmethacrylate, polypropylene modified acrylate, polypropylene modified methacrylate, and ethylene glycol diglycidyl ether, normal butyl methacrylate, normal hexyl meta Acrylate, 2-ethylhexyl methacrylate, cyclohexyl methacrylate, methyl acrylate, propyl acrylate, For at least one road marking selected from the group consisting of sobutyl acrylate, normal butyl acrylate, tertiary butyl acrylate, 2-ethylhexyl acrylate, normal octyl acrylate, isobonyl acrylate, and cyclohexyl acrylate Quick-drying paint composition. The method of claim 1, A fast-drying paint composition for road marking comprising 5 to 10 parts by weight of methyl methacrylate (MMA) and 0.5 to 5 parts by weight of hydroxypropyl methacrylate (HPMA) based on the total weight of the total composition. The method of claim 1, About the total weight of the total composition 20 to 40 parts by weight of a resin solution obtained by dissolving a solid acrylic resin in an acrylic monomer, 5 to 10 parts by weight of methyl methacrylate (MMA), and 0.5 to 5 parts by weight of hydroxypropyl methacrylate (HPMA) Fast-drying paint composition for road marking comprising a. The method of claim 1, At least one selected from the group consisting of antifoaming agents, surface control agents, polymerization inhibitors, paraffin waxes, colored pigments, extender pigments, dispersants, adhesion promoters, inorganic fillers, antioxidants, UV stabilizers, tertiary amine accelerators, and peroxide curing agents Fast-drying paint composition for road signs further comprising. The method of claim 1, With respect to the total coating composition gross weight, 20 to 40 parts by weight of a resin solution obtained by dissolving a solid acrylic resin in an acrylic monomer, Methyl methacrylate (MMA) 5 to 10 parts by weight, 0.5 to 5 parts by weight of hydroxypropyl methacrylate (HPMA), Antifoam 0.5-1 part by weight, 0.5 to 1 part by weight of surface modifier, 2 to 3 parts by weight of polymerization inhibitor, Paraffin wax 0.5 to 2 parts by weight, 10 to 20 parts by weight of colored pigments, Extender pigment 40 to 50 parts by weight, 0.5 to 1 part by weight of a dispersant, 0.1 to 0.5 parts by weight of adhesion promoter, 0.1 to 0.5 parts by weight of an inorganic filler, 0.1 to 0.5 parts by weight of antioxidant, and UV stabilizer 0.1 to 0.5 parts by weight Fast-drying paint composition for road marking comprising a. The method of claim 8, Fast-drying coating composition for road markings comprising 1 to 2 parts by weight of the tertiary amine accelerator based on the total weight of the total composition. The method of claim 8, Fast-drying coating composition for road markings comprising 2 to 10 parts by weight of the peroxide curing agent based on the total weight of the total composition. The method of claim 8, The tertiary amine-based accelerator is a para- toluidine-based amine-based accelerator, the fast-drying paint composition for road marking. The method of claim 8, The peroxide curing agent is a fast-drying coating composition for road marking at least one selected from the group consisting of a peroxide-based peroxide, an ester-based curing agent, and a curing agent containing an aliphatic azo group. a) dissolving a solid acrylic resin in an acrylic monomer to prepare a resin solution, b) preparing the mixture by adding the resin solution in an amount of 20 to 40 parts by weight based on the total weight of the total composition, and further adding an acrylic monomer to the resin solution; c) mixing a tertiary amine accelerator into the mixture prepared in step b) to prepare a main part (A), d) mixing the peroxide curing agent to the mixture prepared in step b) to prepare a curing agent portion (B), and e) mixing the main portion (A) and the hardener portion (B) Method for producing a fast-drying paint composition for road marking comprising a. The method of claim 14, Method of producing a quick-drying coating composition for a paint label in the step (e) is mixing the main portion (A) and the curing agent (B) in a weight ratio of 0.8: 1 to 2: 1. The method of claim 14, At least one selected from the group consisting of an antifoaming agent, a surface conditioner, a polymerization inhibitor, a paraffin wax, a color pigment, an extender pigment, a dispersant, an adhesion promoter, an inorganic filler, an antioxidant, and an ultraviolet stabilizer in the mixture prepared in step b). Method for producing a fast-drying paint composition for road markings further comprising the step of mixing.