KR20100029589A - Tour maline battery - Google Patents

Tour maline battery Download PDF

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Publication number
KR20100029589A
KR20100029589A KR1020080088424A KR20080088424A KR20100029589A KR 20100029589 A KR20100029589 A KR 20100029589A KR 1020080088424 A KR1020080088424 A KR 1020080088424A KR 20080088424 A KR20080088424 A KR 20080088424A KR 20100029589 A KR20100029589 A KR 20100029589A
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KR
South Korea
Prior art keywords
tourmaline
battery
powder
manganese dioxide
zeolite
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KR1020080088424A
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Korean (ko)
Inventor
강보선
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지성중공업 주식회사
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Priority to KR1020080088424A priority Critical patent/KR20100029589A/en
Publication of KR20100029589A publication Critical patent/KR20100029589A/en

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/04—Cells with aqueous electrolyte
    • H01M6/045—Cells with aqueous electrolyte characterised by aqueous electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/42—Alloys based on zinc
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/46—Alloys based on magnesium or aluminium
    • H01M4/466—Magnesium based
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0002—Aqueous electrolytes
    • H01M2300/0014—Alkaline electrolytes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Abstract

PURPOSE: A tourmaline battery is provided to ensure higher electric energy compared with primary batteries, long lifetime and high capacity by reducing zinc plate or magnesium alloy plate. CONSTITUTION: A tourmaline battery uses a zinc plate or magnesium alloy plate(1) as a negative electrode material, a carbon stick(7) as a positive electrode material, tourmaline powder(9) and zeolite powder(10) as electrolyte, and manganese dioxide powder(11) as a catalyst.

Description

토르말린 전지 { Tour maline battery }Tourmaline Battery {Tour maline battery}

본 발명은 액체전해질에 의한 이온의 이동에 의해 전기에너지가 발생되는 전지에 관한 것이다.The present invention relates to a battery in which electrical energy is generated by the movement of ions by liquid electrolyte.

본 발명은 전해질에 의한 이온의 이동에 의해 음극에서는 전자를 잃고 양극에서는 전자를 얻어 음극이 지닌 전력량만큼 전기에너지를 사용할 수 있는 1차전지에 관한 것이다.The present invention relates to a primary battery which can use electric energy as much as the amount of power possessed by a cathode by losing electrons at a cathode and electrons at a cathode by the movement of ions by an electrolyte.

[문헌 1] 신재생 에너지 개발 동향 ( 검색일 : 2008 . 07 . 23)[Document 1] Trend of Renewable Energy Development (Search Date: 2008. 07. 23)

[문헌 2] 토르말린 ( 검색일 : 2008 . 07 . 28 )Tourmaline (Search Date: 2008. 07. 28)

에너지를 사용할 수 있는 1차전지로서, 기존의 전해질들과 같이 수소 발생에 의한 전력량 감소가 되는 문제가 없도록 물을 사용하여 음극제가 지닌 전기에너지를 사용할 수 있도록 하는 것을 과제로 한다.As a primary battery that can use energy, it is a problem to use the electrical energy of the negative electrode using water so that there is no problem of reducing the amount of power caused by hydrogen generation as in the conventional electrolytes.

일반적인 수돗물이나 빗물 또는 증류수 음이온·양이온의 이온이동도가 낮아 전해질로서 전지에 사용하기에는 전력발생량이 낮아 사용하기 어렵다. 그러므로, 영구적으로 0.06mA의 미세 전류가 결정입자 마다 흐르는 극성망간을 혼합하여 음극제인 아연 또는 마그네슘 합금판과 양극제인 탄소봉 사이에 구성시켜 물을 부면 물을 알칼리 이온수로 변화시켜 이온전도도가 높도록 하여 전지에너지가 발생되도록 하는 것을 해결 수단으로 한다.In general, tap water, rain water, or distilled water anions and cations have a low ion mobility and are difficult to use due to low power generation for use in batteries as electrolytes. Therefore, permanently mix the polar manganese with 0.06mA of fine current flowing between the crystal grains, and make it between the zinc or magnesium alloy plate, which is a cathode, and the carbon rod, which is a cathode, and change the water into alkaline ionized water to increase the ion conductivity. The solution means that the battery energy is generated.

물을 주입하면 전기에너지를 사용할 수 있는 토르말린 전지는 극성결정체로서 대기중의 전자를 입자 양극에서 받아 음극으로 방출하여 0.06mA의 전류가 영구적으로 흐르는 토르말린 분말에서 발생된 전자에 의해 전자를 내주고 산화되는 음극제인 아연핀 또는 마그네슘 합금판의 산화된 부분이 환원되어 일반적인 같은 크기의 1차전지들 보다 전력량이 많으며, 장수명이고, 대용량인 것을 특징으로 하는 토르말린 전지.The tourmaline battery, which can use electric energy when water is injected, is a polar crystal and receives electrons in the air from the cathode of the particle and emits them to the cathode, which emits electrons and oxidizes the electrons generated from the tourmaline powder with a current of 0.06 mA permanently flowing. Tourmaline battery, characterized in that the oxidized portion of the zinc pin or magnesium alloy plate, which is a negative electrode agent, is reduced and thus has more power, longer life, and larger capacity than primary batteries of the same size.

본 발명인 토르말린 전지의 구성 및 작용을 첨부된 도면 제 1도를 참고로 하여 설명하면 다음과 같다.The structure and operation of the tourmaline battery of the present invention will be described with reference to FIG.

먼저, 음극제로 사용한 원통 또는 사각통 형태의 아연 또는 마그네슘 합금(1) 기판에는 한쪽끝에는 절연막(2)을 접착시키고, 물주입구(3)를 형성시키고, 양극제로 사용한 탄소봉(7)은 탄소고정대(6)에 꽂아 원통 또는 사각통 모양의 아연 또는 마그네슘 합금 기판(1)과 탄소봉(7)이 접하지 않도록 한 다음 니켈기판(5)의 양극단자(4)에 탄소봉(7)을 압착 고정시킨 다음 가스켓(8)으로 분리시켜 아연 또는 마그네슘 합금(1)기판과 양극기판인 니켈기판(5)을 연 경화 고착 시킨다.First, an insulating film 2 is adhered to one end of a cylindrical or square cylinder-type zinc or magnesium alloy (1) substrate used as a negative electrode, and a water inlet 3 is formed, and the carbon rod 7 used as a positive electrode has a carbon fixing base ( 6) to prevent the zinc or magnesium alloy substrate (1) and the carbon rod (7) of the cylindrical or square shape to contact with each other, and then press-fix the carbon rod (7) to the anode terminal (4) of the nickel substrate (5) It is separated by the gasket (8), and the zinc or magnesium alloy (1) substrate and the nickel substrate (5), which is a positive electrode substrate, is soft set and fixed.

내부공간에는 토르말린(9) : 제올라이트(10) : 이산화망간(11) 을 80∼90 : 5∼17 : 3∼5 wt％ 무게 비율로 혼합한 분말을 채워 넣은 후 돌출된 음극단자(12)가 형성된 기판 뚜껑(13)을 덮은 후 스포팅 용접하여 분리시킨다,The inner space was filled with a powder mixed with tourmaline (9): zeolite (10): manganese dioxide (11) at a weight ratio of 80 to 90: 5 to 17: 3 to 5 wt%, and then a protruding negative electrode terminal 12 was formed. The substrate lid 13 is covered and separated by spot welding.

위와 같이 완성된 토르말린 전지의 물주입구(3)를 통해 물(14)을 주입하면 회로(15)와 같이 전기에너지가 발생되는 거을 특징으로 하는 토르말린 전지.Tourmaline battery, characterized in that the electrical energy is generated, such as the circuit 15 when water 14 is injected through the water inlet (3) of the completed tourmaline battery as described above.

제 1도는 본 발명에 의한 토르말린 전지의 단면도.1 is a cross-sectional view of a tourmaline battery according to the present invention.

Claims (2)

음극제로는 아연 또는 마그네슘 합금기판(1)을 사용하고, 양극제로는 탄소봉(7)을 사용하고, 전해질로는 극성결정체인 토르말린 분말(9)과 이온교환제인 제올라이트 분말(10) 촉매제인 이산화망간 분말(11)을 사용하여 음·양극제 사이에 구성시킨 다음 사용시 물(14)을 주입하여 토르말린(9) +제올라이트(10) +이산화망간(11) 혼합분말과 접하게 하면 물(14)은 알칼리 이온수로 변하여 이온전도도가 높아져 음극제로는 마그네슘 사용시에는Zinc or magnesium alloy substrate (1) is used as an anode, carbon rod (7) is used as an anode, tourmaline powder (9), which is a polar crystal, and zeolite powder (10), which is an ion exchanger, and manganese dioxide powder, which is a catalyst. (11) is used to form a positive and negative electrode, and then water (14) is injected into contact with tourmaline (9) + zeolite (10) + manganese dioxide (11) mixed powder. The ion conductivity increases, Mg +2OH- → Mg(OH)2 + 2e- 와 같은 반응이 일어나고, 아연을 사용하면 Zn → Zn2++2e- 와 같은 반응이 일어나며 이산화 망간(11)의 촉매 작용에 의해 Mg + 2OH - → Mg (OH ) 2 + 2e - reaction taking place, such as, the use of zinc Zn → Zn 2+ + 2e - The reaction takes place, such as by the catalytic action of manganese dioxide (11) H2 +2MnO2 → Mn2O3 +H2O 와 같은 화학 반응에 의해 수소기체에 의한 전력 감소가 없으며 양극제로 사용한 탄소봉에서는There is no reduction of power by hydrogen gas due to chemical reaction like H 2 + 2MnO 2 → Mn 2 O 3 + H 2 O. O2 +2H2O + 4e- →4OH- 와 같은 반응에 의해 전기에너지가 발생되어 전기용품에 연결시켜 사용 가능한 것을 특징으로 하는 토르말린 전지. O 2 + 2H 2 O + 4e - → 4OH - the electrical energy generated by the reaction, such as the battery, characterized in that tourmaline is available to connect to the electric appliance. 제 1항에 있어서, 토르말린(9) +제올라이트(10) +이산화망간(11)의 혼합 비율은 80∼90 : 5∼17 : 3∼5 wt％ 무게비율로 혼합시킨 것을 특징으로 하는 토르말 린 전지.The tourmaline battery according to claim 1, wherein the mixing ratio of tourmaline (9) + zeolite (10) + manganese dioxide (11) is mixed at a weight ratio of 80 to 90: 5 to 17: 3 to 5 wt%. .
KR1020080088424A 2008-09-08 2008-09-08 Tour maline battery KR20100029589A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013082684A1 (en) * 2011-12-05 2013-06-13 Martins Valmeron Receiving, converting and emitting battery working according to the active magnetohydroresonant effect, method for preparing hydroresonant and biomagnetic compounds, method for preparing the battery, and general use of the same in the mineral, plant and animal kingdoms

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013082684A1 (en) * 2011-12-05 2013-06-13 Martins Valmeron Receiving, converting and emitting battery working according to the active magnetohydroresonant effect, method for preparing hydroresonant and biomagnetic compounds, method for preparing the battery, and general use of the same in the mineral, plant and animal kingdoms

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