KR20090126683A - Anti-wrinkle composition of hydroscopic for fabric - Google Patents

Abstract

PURPOSE: An anti-wrinkle composition for hydroscopic of fabric is provided to improve quality of the fabric, and to offer good dyeability, flexibility, smoothness while preventing generation static electricity of the fabric. CONSTITUTION: An anti-wrinkle composition for hydroscopic of fabric includes liquid paraffin, spindle oil, alkylbenzene oil, diester oil, castor oil, their mixture mixed with two or more selected from a group, high alcohol of 5 ~ 40 parts by weight, sulfate oil of 5 ~ 30 parts by weight, Emulphor STS of 5 ~ 20 parts by weight, a non-ionic surfactant of 10 ~ 50 parts by weight, and an antistatic agent of 10 parts by weight. The anti-wrinkle composition further includes perfume of 0.1 ~ 0.5 parts by weight.

Description

Hygroscopic anti-wrinkle composition for fabrics {Anti-Wrinkle Composition of Hydroscopic for Fabric}

The present invention relates to anti-wrinkle compositions, and more particularly, to hygroscopic anti-wrinkle compositions for textiles comprising vegetable or higher alcohols, sulfated oils, emulsion perties and nonionic surfactants.

Generally, anti-wrinkle agents are used to dye fabrics to prevent contamination of fabrics and to provide a soft feel to natural fibers. Such anti-wrinkle agents are made of polyethylene, fiber, and micro Mainly used for dyeing fibers.

In particular, loft anti-wrinkle and hygroscopic anti-wrinkle agent in dyeing processing of fibers and / or fabrics, anti-wrinkle agent mainly used for dyeing various kinds of fibers, acrylic blends, cotton, T / C, polyester fiber knitted fabrics, and dyeing of rapids Most of them are imported from Japan.

Such anti-wrinkle agent is changed by the type of fabric and the concentration, temperature, pH, additives, etc. of the fabric, the electrical negatively charged fibers are about 1,000 times more than when using an anionic surfactant than a cationic surfactant It has hygroscopicity.

This is due to electrical neutralization. In general, nonionic interfacial hygroscopic antiwrinkle agents emulsify polyester resins to impart a special feel, thereby providing strong hygroscopic contamination prevention and special texture to fibers, polyester and spandex fabrics, thereby providing excellent elasticity and flexibility. Will be used.

Here, the hygroscopic anti-wrinkle agent is most commonly used in the textile industry because the moisture is rapidly penetrated into the surface of the fiber and / or fabric, such as easy to penetrate the inside, but according to the purpose of use requires additional physical properties in addition to wetting and penetration Done.

However, conventionally used anti-wrinkle agent, when dyed directly as a dye, such as fiber and / or fabric, the wet fastness is poor, the washing resistance is reduced, and the dye is easily detached from the fiber and / or fabric by secretion such as sweat There is a problem.

In order to overcome these problems, expensive dry salt dyes and reactive dyes having good wet strength can be used. However, expensive dyes cannot be used for relatively low-cost products such as curtains and prints. The method of enhancing the washing fastness is used.

Therefore, it is required to develop a hygroscopic anti-wrinkle agent capable of enhancing the quality of fibers and / or fabrics as a low-molecular hygroscopic surfactant in view of the demand desire of the textile industry.

Furthermore, the anti-wrinkle agent additionally provides anti-static, flexibility, smoothness and lubricity to flexibly smooth the fiber and / or fabric surface to enable high speed dyeing and to minimize frictional contact with the machine. Is required.

The present invention has a problem to be solved by providing a hygroscopic anti-wrinkle composition that can improve the quality of fibers and / or fabrics as a hygroscopic surfactant during dyeing processing of fibers and / or fabrics and excellent dyeing workability.

In order to overcome the above-mentioned problems, the anti-wrinkle composition, in particular the hygroscopic anti-wrinkle composition, according to the present invention is a liquid paraffin, spindle oil, alkylbenzene oil, diester oil, castor oil or a mixture or two or more selected from these 5 to 40 parts by weight of alcohol; 5 to 30 parts by weight of sulfated oil; 5 to 20 parts by weight of Emulphor STS; There is a problem solving means including 10 to 50 parts by weight of a nonionic surfactant.

The anti-wrinkle composition according to the present invention is an inexpensive hygroscopic surfactant used for dyeing processing to prevent wrinkles occurring in fibers and / or fabrics, thereby improving the quality of the fibers and / or fabrics, as well as antistatic, flexibility and smoothness. And lubricity and the like.

In one aspect, the present invention is a liquid paraffin, spindle oil, alkylbenzene oil, diester oil, castor oil or a mixture of two or more selected from these or higher alcohol 5 to 40 parts by weight; 5 to 30 parts by weight of sulfated oil; 5 to 20 parts by weight of Emulphor STS; It provides a anti-wrinkle composition comprising 10 to 50 parts by weight of a nonionic surfactant.

In another aspect, the present invention may further include 0.5 to 10 parts by weight of the antistatic agent based on the total weight of the antiwrinkle composition.

In another aspect, the present invention may further comprise 0.01 to 0.5 parts by weight of fragrance relative to the total anti-wrinkle composition.

The anti-wrinkle composition according to the present invention is used for processing of fibers and / or fabrics, particularly for dyeing or post-treatment processes, or for washing of fibers and / or fabrics to generate wrinkles in the fibers and / or fabrics. To prevent.

Here, the anti-wrinkle composition may additionally have an antistatic, flexibility, smoothness, lubricity, or at least one function thereof in the fibers and / or fabrics.

The antiwrinkle composition according to the present invention, in particular the moisture absorbing antiwrinkle composition, is coated on fibers and / or fabrics to soften the fibers and / or fabrics to prevent static electricity or to remove fiber contaminants, such as liquid paraffin, spindle oil, Alkylbenzene oil, diester oil, castor oil or a mixture of at least two or more selected from them may be used, and the amount thereof is preferably 5 to 40 parts by weight based on the total weight of the anti-wrinkle composition.

Here, instead of the liquid paraffin, spindle oil, alkylbenzene oil, diester oil, castor oil or a mixture of at least two or more selected from them, constituting the anti-wrinkle composition, higher alcohol, in particular 70 to 90% higher alcohol, Can also be used.

At this time, the higher alcohol is an aliphatic alcohol having 6 or more carbon atoms commonly used in the art.

The sulfated oil according to the present invention is used for preventing staining of fibers and / or fabrics and for uniform dyeing, but is not particularly limited as long as it is a sulfated oil commonly used in the art for this purpose. It is preferable to use a neutralized product with alkali after washing and removing unreacted sulfuric acid by sulfuric acid fatty oils such as castor oil, olive oil, cottonseed oil or soybean oil, and the amount thereof is 5 to 5 based on the total weight of the antiwrinkle composition. It is recommended to use 30 parts by weight.

Emulphor STS according to the present invention is not particularly limited as long as it is an emulsion ester commonly used in the art as one of the anionic surfactants, and the amount thereof is 5 to 20 weight based on the total weight of the antiwrinkle composition. It is good to use wealth.

The nonionic surfactant according to the present invention is a kind of surfactant having an ionized atomic group as a hydrophilic group, and has a -OH group to dissolve a hydrophobic group in water or an ester, an acid amide, or an ether bond in a molecule, although relatively less hydrophilic. As such, conventional nonionic surfactants in the art having such a configuration, for example fatty acid omoglycerin esters, fatty acid polyglycol esters, fatty acid sorbitan esters, fatty acid sucrose esters, fatty acid alkanolamides or polyethylene glycol condensed nonionic interfaces It is preferable to use an activator or the like, and more preferably, a higher alcohol polyethylene glycol ether type isooctylphenol ethylene oxide is used as the polyethylene glycol condensation type nonionic surfactant, and the amount thereof is 10 to 10 based on the total weight of the antiwrinkle composition. 50 Amount preferably used parts.

Meanwhile, the above-described anti-wrinkle composition according to the present invention basically includes anti-wrinkle, anti-static, flexibility, smoothness, lubricity, or one or more of these functions by the composition contained therein, but provides a better anti-static function. To provide may further comprise 0.5 to 10 parts by weight of the antistatic agent relative to the total weight of the anti-wrinkle composition.

Here, the antistatic agent is not particularly limited as long as it is an antistatic agent commonly used in the art, preferably a cationic compound consisting of a primary amine salt, a tertiary amine, a quaternary ammonium compound, a pyridine derivative or a mixture thereof; Consisting of sulfate ester oils, sulfate ester salts of olefins, fatty alcohol sulfate ester salts, alkyl sulfate ester salts, fatty acid ethyl sulfates, alkylnaphthalene sulfates, alkylbenzene sulfates, phosphate ester salts, phosphate ester salts or mixtures thereof Anionic compounds; Nonionics consisting of partial fatty acid esters of polyhydric alcohols, ethylene oxide adducts of fatty alcohols, ethylene oxide adducts of fatty acids, polyfatty amino, ethylene oxide adducts of alkylphenols, ethylene oxide adducts of alkylnaphtanol or mixtures thereof System compounds; It is preferable to use a zwitterionic compound composed of a carboxylic acid derivative, an imidazoline derivative or a mixture thereof, or a mixture of two or more thereof.

In addition, the anti-wrinkle composition according to the present invention may further include a fragrance that provides a fragrance to the fiber and / or fabric according to the user's preference, representative materials that can be used for this purpose include lemon oil, orange oil, Rose Oil, Cinnamon Reef Oil, Guayacol, Lavender Oil, Peppermint Oil, Linaryl Aceteto, Bonyl Aceteto, Benzyl Acetate, Citronellol, Tapineol, Phenyl Ethyl Alcohol, Cytorone And acetonitrile, geranyl pometo, β-phenyl ethanol, or a mixture thereof, and the amount thereof is preferably 0.01 to 0.5 parts by weight based on the total weight of the antiwrinkle composition.

As described above, those skilled in the art to which the present invention pertains will understand that the present invention may be implemented in other specific forms without changing the technical spirit or essential features. Therefore, it should be understood that the embodiments described above are all illustrative and not restrictive. The scope of the present invention should be construed as being included in the scope of the present invention all changes or modifications derived from the meaning and scope of the claims to be described later rather than the detailed description and equivalent concepts thereof.

Claims (5)

5 to 40 parts by weight of liquid paraffin, spindle oil, alkylbenzene oil, diester oil, castor oil or a mixture of two or more selected from these or higher alcohols; 5 to 30 parts by weight of sulfated oil; 5 to 20 parts by weight of an emulsion ester; Anti-wrinkle composition comprising 10 to 50 parts by weight of nonionic surfactant. The method of claim 1, Anti-wrinkle composition, characterized in that it further comprises 0.5 to 10 parts by weight of the antistatic agent relative to the total weight of the anti-wrinkle composition. The method of claim 2, A cationic compound in which the antistatic agent consists of a primary amine salt, a tertiary amine, a quaternary ammonium compound, a pyridine derivative or a mixture thereof; Consisting of sulfate ester oils, sulfate ester salts of olefins, fatty alcohol sulfate ester salts, alkyl sulfate ester salts, fatty acid ethyl sulfates, alkylnaphthalene sulfates, alkylbenzene sulfates, phosphate ester salts, phosphate ester salts or mixtures thereof Anionic compounds; Nonionics consisting of partial fatty acid esters of polyhydric alcohols, ethylene oxide adducts of fatty alcohols, ethylene oxide adducts of fatty acids, polyfatty amino, ethylene oxide adducts of alkylphenols, ethylene oxide adducts of alkylnaphtanol or mixtures thereof System compounds; An anti-wrinkle composition comprising a zwitterionic compound consisting of a carboxylic acid derivative, an imidazoline derivative or a mixture thereof, or a mixture of two or more thereof. The method according to claim 1 or 2, Wrinkle agent composition characterized in that it further comprises 0.01 to 0.5 parts by weight of fragrance against the total weight of the anti-wrinkle composition. The method of claim 4, wherein The fragrances include lemon oil, orange oil, rose oil, cinnamon leaf oil, guayacol, lavender oil, peppermint oil, linaryl acetate, bonyl aceto, benzyl acetate, citronellol, tapineol, phenyl ethyl alcohol, Anti-wrinkle composition, characterized in that the cytoneryl acetoto, geranyl pometo, β-phenyl ethanol or a mixture thereof.