KR20090080360A - Producing method of fire-proof fabric for printing - Google Patents
Producing method of fire-proof fabric for printing Download PDFInfo
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- KR20090080360A KR20090080360A KR1020080006265A KR20080006265A KR20090080360A KR 20090080360 A KR20090080360 A KR 20090080360A KR 1020080006265 A KR1020080006265 A KR 1020080006265A KR 20080006265 A KR20080006265 A KR 20080006265A KR 20090080360 A KR20090080360 A KR 20090080360A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C7/00—Heating or cooling textile fabrics
- D06C7/02—Setting
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/347—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated ethers, acetals, hemiacetals, ketones or aldehydes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/01—Stain or soil resistance
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/14—Dyeability
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S57/00—Textiles: spinning, twisting, and twining
- Y10S57/904—Flame retardant
Abstract
Description
본 발명은 인쇄용 방염 원단의 제조방법에 관한 것으로서, 더욱 상세하게는 침지방식으로 방염성능 발현과 잉크 발색층 형성이 가능한 프린터용 방염 원단의 제조방법에 관한 것이다.The present invention relates to a method for manufacturing a flame retardant fabric for printing, and more particularly, to a method for manufacturing a flame retardant fabric for a printer capable of expressing flame retardant performance and forming an ink coloring layer by an immersion method.
종래의 인쇄용 원단은 주로 코팅방식으로 실리카를 포함한 유용성 코팅제를 나이프 코팅방법으로 코팅하여 인쇄 발색층을 형성하기 때문에, 제조공정이 복잡하고 실리카를 사용함으로써 내마모성, 내구성, 내알칼리성 등의 저하를 초래할 뿐만 아니라 영구적이지 못하여 실리카 탈락 등의 2차적 환경오염을 유발할 수 있다.Conventional printing fabrics mainly use coating methods to coat the oil-soluble coating agent including silica with a knife coating method to form a printing chromophoric layer. Therefore, the manufacturing process is complicated, and the use of silica leads to deterioration of wear resistance, durability and alkali resistance. However, it is not permanent and may cause secondary environmental pollution such as silica dropout.
또한 종래의 원단 침지방식에 의해 제조되는 원단은 실사, 현수막 등의 광고소재용 출력물이나 열승화날염기에 한정되어 사용되었으며, 방염소재로서 인테리어용 원단 등에의 사용은 어려운 실정이었다.In addition, the fabric manufactured by the conventional fabric immersion method was used to be limited to the printed material or heat-sublimation printing material for advertising materials such as live-action, banners, etc., it was difficult to use the interior fabric as a flame retardant material.
본 발명은 상기와 같은 종래 인쇄용 원단의 문제점을 해결하여, 방염 및 잉크 발색층을 원단 침지방식에 의해 형성할 수 있어 방염성을 요구하는 다양한 용도로 활용이 가능할 뿐만 아니라, 친환경적이고 경제적인 인쇄용 방염 원단의 제조방법을 제공하는 것을 목적으로 한다.The present invention solves the problems of the conventional printing fabric as described above, the flame retardant and ink coloring layer can be formed by the fabric immersion method can be utilized for a variety of applications requiring flame retardancy, environmentally friendly and economical printing flame retardant fabric An object of the present invention is to provide a manufacturing method.
상기 목적을 달성하기 위한 본 발명에 따른 인쇄용 방염 원단의 제조방법은,Method for producing a flame retardant fabric for printing according to the present invention for achieving the above object,
유기인산염계의 방염제 함량 10~40중량%의 침지액에 원단을 침지처리한 후, 스퀴징하고 130~200℃의 온도에서 건조 및 열처리하는 1차 침지공정과;A first immersion step of immersing the fabric in an immersion liquid having an organophosphate flame retardant content of 10 to 40% by weight, squeezing, drying and heat-treating at a temperature of 130 to 200 ° C .;
폴리에스테르수지 함량 5~25중량%와 실리콘 수지 함량 1~10중량%, 침투제 함량 0.1~1중량%의 침지액에 상기 1차 침지공정을 거친 원단을 침지하고 스퀴징한 후, 130~200℃의 온도에서 건조 및 열처리하는 2차 침지공정을 포함하여 구성된다.After immersing and squeezing the fabric after the first immersion step in the immersion liquid of polyester resin content 5-25% by weight, silicone resin content 1-10% by weight, penetrant content 0.1-1% by weight, 130 ~ 200 ℃ It comprises a secondary immersion step of drying and heat treatment at a temperature of.
상기 구성에 있어서, 상기 유기인산염계 방염제는, 트리아릴포스페이트와 알킬디아릴포스페이트 및 트리아릴 포스페이트를 각각 1:1:1의 비율로 용해하여 사용하는 것이 바람직하다.In the above configuration, the organophosphate flame retardant is preferably used by dissolving triaryl phosphate, alkyldiaryl phosphate and triaryl phosphate in a ratio of 1: 1: 1.
본 발명에 따른 인쇄용 방염 원단의 제조방법은 2단계에 걸친 침지공정을 통해 방염성을 갖춘 인쇄용 원단을 제조할 수 있기 때문에 종래 코팅방식에 의한 인쇄용 원단에 비해 촉감이 좋고 경제적일 뿐만 아니라, 친환경적이라는 이점이 있 다.The method of manufacturing a flame retardant fabric for printing according to the present invention is not only good for touch and economical, but also environmentally friendly as compared to a conventional fabric for printing, since the fabric for printing can be manufactured with flame retardancy through two immersion processes. There is.
또한, 이렇게 제조된 인쇄용 원단은 방염효과를 가지므로 종래의 광고소재용 실사출력물 제조용으로서 뿐만 아니라, 롤블라인드, 사진, 벽지 등의 인테리어용 원단 인쇄 등에 다양하게 활용이 가능하다는 이점이 있다. In addition, the printing fabric thus produced has a flame-retardant effect, and thus, it is not only used for manufacturing the actual printout of the advertisement material in the related art, but also has various advantages such as printing of interior fabrics such as roll blinds, photographs, and wallpaper.
이하, 본 발명을 좀 더 상세하게 설명한다.Hereinafter, the present invention will be described in more detail.
본 발명에 따른 인쇄용 방염 원단의 제조방법은 폴리에스테르나 면, 혼방과 같은 다양한 형태의 섬유 원단에 적용 가능하다.The method for manufacturing a flame retardant fabric for printing according to the present invention is applicable to various types of textile fabrics such as polyester, cotton, and blend.
1차 침지공정에서는, 유기인산염계의 방염제 함량 10~40중량%의 침지액에 원단을 침지처리한 후, 스퀴징하고 130~200℃의 온도에서 건조 및 열처리하는 과정을 거치게 되는데, 이때 상기 유기인산염계 방염제로서 트리아릴포스페이트와 알킬디아릴포스페이트 및 트리아릴 포스페이트를 각각 1:1:1의 비율로 혼합하여 사용한다.In the first immersion process, the fabric is immersed in an immersion liquid of 10 to 40% by weight of the organic phosphate flame retardant, squeezed and dried and heat treated at a temperature of 130 ~ 200 ℃, wherein the organic As the phosphate-based flame retardant, triaryl phosphate, alkyldiaryl phosphate and triaryl phosphate are used in a ratio of 1: 1: 1, respectively.
이들 유기 인산염계 방염제는 각각 하기 화학식 1~3으로 표시되는 구조를 가지며, 유기인산염계 방염제는 할로겐계나 안티몬계 방염제에 비해 유독성이 적어 환경에 나쁜 영향을 미치지 않는다.These organophosphate flame retardants have structures represented by the following Chemical Formulas 1 to 3, respectively, and the organophosphate flame retardants have less toxicity than the halogen or antimony flame retardants and thus do not adversely affect the environment.
이들 3가지 유기 인산염계 방염제는 도 1에 나타낸 그래프에서 보는 바와 같이, 방염성능에서 차이가 나며, 트리아릴포스페이트의 경우에는 방염성은 높으나 연기가 많이 나고, 반대로 알킬디아릴포스페이트나 트리알킬포스페이트의 경우에는 방염성능은 상대적으로 낮으나 연기발생이 적기 때문에 이들을 혼합하여 사용함으로써 서로 장단점을 보완하게 된다. As shown in the graph shown in Figure 1, these three organic phosphate-based flame retardant, the flame retardant performance is different, in the case of triaryl phosphate flame retardant but high smoke, and in the case of alkyldiaryl phosphate or trialkyl phosphate The flame retardant performance is relatively low, but smoke is less generated, so the use of a mixture thereof complements each other's advantages and disadvantages.
한편, 이들 유기 인산염계 방염제는 원단을 구성하는 섬유의 종류에 따라 사 용량을 조절하게 된다. 즉 예컨대 원단 자체가 난연성이 비교적 우수한 폴리에스테르섬유에는 방염제의 사용량을 20중량% 정도로 줄이고, 난연성이 나쁜 면섬유로 이루어진 원단에는 사용량을 40중량%까지로 높인다. 그리고 이들의 혼방소재인 경우에는 그 중간인 30중량% 정도로 사용하면 된다.On the other hand, these organic phosphate-based flame retardant is to adjust the amount used according to the type of fibers constituting the fabric. That is, for example, the amount of flame retardant is reduced to about 20% by weight for polyester fibers having relatively high flame retardancy, and the amount is increased to 40% by weight for fabrics made of cotton fibers having poor flame retardancy. And in the case of these blended materials may be used about 30% by weight in the middle.
2차 침지공정에서는, 폴리에스테르수지 5~25중량%와 실리콘 수지 1~10중량%, 침투제 0.1~1중량%를 함유한 침지액에 상기 1차 침지공정을 거친 원단을 침지하고 스퀴징한 후, 130~200℃의 온도에서 건조 및 열처리하여 잉크발색층을 형성하게 된다.In the second immersion step, after immersing and squeezing the fabric through the first immersion step in the immersion liquid containing 5 to 25% by weight polyester resin, 1 to 10% by weight silicone resin, 0.1 to 1% by weight penetrant Drying and heat treatment at a temperature of 130 ~ 200 ℃ to form an ink color layer.
상기 폴리에스테르수지는 침지방식에 의해 잉크발색층을 형성할 수 있도록 하는 친환경적인 소재로서 수성 및 유성잉크로 인쇄작업을 할 수 있게 해주는 경제적인 제품이다. 폴리에스테르수지는 바람직하게는 20~25중량%를 사용한다.The polyester resin is an economical product that enables printing operations with aqueous and oil-based ink as an environmentally friendly material for forming an ink color layer by dipping. The polyester resin is preferably used 20 to 25% by weight.
그리고, 상기 실리콘 수지는 원단의 강도 및 인쇄시 발색을 도와주며, 터치를 보완하여 주는 역할을 하는 것으로 약솔벤트잉크 및 강솔벤트 잉크의 잉크 발색층 형성에 모두 적합하다는 이점이 있다.In addition, the silicone resin helps color development and strength of printing, and serves to complement the touch, and has the advantage of being suitable for forming the ink coloring layer of weak solvent ink and strong solvent ink.
한편, 상기 1차 침지공정에 의해 방염제를 처리한 후에는 2차 침지공정에서 사용되는 수지의 원단에의 침투가 어려워지게 되므로, 2차 침지공정에서는 침투를 도와주는 약품으로 소량의 침투제를 혼합하여 사용하게 된다. 침투제는 0.3~1중량%의 범위에서 사용하게 된다.On the other hand, after the flame retardant is treated by the primary immersion process, it becomes difficult to penetrate the fabric of the resin used in the secondary immersion process, so in the secondary immersion process, a small amount of a penetrant is mixed with a chemical to help the penetration. Will be used. The penetrant is used in the range of 0.3 to 1% by weight.
본 발명의 방법에 의해 폴리에스테르소재, 폴리에스테르/면 혼방소재 및 면소재에 대해 인쇄용 방염 원단을 제조할 경우, 1차 침지공정과 2차 침지공정에서의 침지액은 예컨대 하기 표 1과 같은 조성으로 이루어질 수 있다.When manufacturing a flame retardant fabric for printing on a polyester material, a polyester / cotton blend material and a cotton material by the method of the present invention, the immersion liquids in the first and second immersion processes may have, for example, a composition as shown in Table 1 below. Can be done.
도 1은 본 발명에서 사용하는 방염제별 방염성능을 도시한 그래프. 1 is a graph showing the flame retardant performance of each flame retardant used in the present invention.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20190108681A (en) | 2018-03-15 | 2019-09-25 | 주식회사 이알인터내셔널 | Selective catalytic reduction system for in-use vehicles |
| KR102122849B1 (en) | 2019-02-08 | 2020-06-15 | 주식회사 에코닉스 | Selective catalytic reduction(SCR) device for vehicles |
| KR102337528B1 (en) | 2020-06-30 | 2021-12-10 | 주식회사 에코닉스 | Variable back pressure diesel catalyst (DOC) device with low pressure characteristics |
| KR20230030091A (en) | 2021-08-24 | 2023-03-06 | 주식회사 이알인터내셔널 | Emission Reduction System for Operating Vehicles |
| KR20230114820A (en) | 2022-01-25 | 2023-08-02 | 주식회사 이알인터내셔널 | Construction machinery monitoring system |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3783774B2 (en) | 2001-02-15 | 2006-06-07 | 平岡織染株式会社 | Flame retardant film material for printing |
| JP3923739B2 (en) | 2001-02-26 | 2007-06-06 | セーレン株式会社 | Inkjet recording fabric having flame retardancy and method for producing the same |
| KR100441299B1 (en) * | 2001-10-31 | 2004-07-23 | 주식회사 티엔지코리아 | fire retardant print sheet manufacture method and print sheet |
| KR100743156B1 (en) | 2006-03-23 | 2007-07-30 | (주)티피엠켐 | The real-picture transfer fabrics for output that usedin large-sized plotter and use methods |
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2008
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20190108681A (en) | 2018-03-15 | 2019-09-25 | 주식회사 이알인터내셔널 | Selective catalytic reduction system for in-use vehicles |
| KR102122849B1 (en) | 2019-02-08 | 2020-06-15 | 주식회사 에코닉스 | Selective catalytic reduction(SCR) device for vehicles |
| KR102337528B1 (en) | 2020-06-30 | 2021-12-10 | 주식회사 에코닉스 | Variable back pressure diesel catalyst (DOC) device with low pressure characteristics |
| KR20230030091A (en) | 2021-08-24 | 2023-03-06 | 주식회사 이알인터내셔널 | Emission Reduction System for Operating Vehicles |
| KR20230114820A (en) | 2022-01-25 | 2023-08-02 | 주식회사 이알인터내셔널 | Construction machinery monitoring system |
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