CN105780453B - One kind is based on antiflaming finishing agent, its preparation method and its application of montmorillonite/DNA hydrosols - Google Patents

One kind is based on antiflaming finishing agent, its preparation method and its application of montmorillonite/DNA hydrosols Download PDF

Info

Publication number
CN105780453B
CN105780453B CN201610176164.9A CN201610176164A CN105780453B CN 105780453 B CN105780453 B CN 105780453B CN 201610176164 A CN201610176164 A CN 201610176164A CN 105780453 B CN105780453 B CN 105780453B
Authority
CN
China
Prior art keywords
montmorillonite
dna
parts
weight
finishing agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201610176164.9A
Other languages
Chinese (zh)
Other versions
CN105780453A (en
Inventor
马辉
张焕侠
曹建达
吴雯
皮婷婷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiaxing University
Original Assignee
Jiaxing University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiaxing University filed Critical Jiaxing University
Priority to CN201610176164.9A priority Critical patent/CN105780453B/en
Publication of CN105780453A publication Critical patent/CN105780453A/en
Application granted granted Critical
Publication of CN105780453B publication Critical patent/CN105780453B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35Heterocyclic compounds
    • D06M13/355Heterocyclic compounds having six-membered heterocyclic rings
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32Polyesters

Abstract

The invention discloses a kind of antiflaming finishing agent for being based on montmorillonite/DNA hydrosols, in terms of parts by weight, the content of each component is as follows in the antiflaming finishing agent:The montmorillonite of 1 parts by weight, the DNA of 0.1~10 parts by weight, the coupling agent of 0.1~10 parts by weight.The preparation method of above-mentioned antiflaming finishing agent includes:Montmorillonite handles to obtain the montmorillonoid sample of stripping point by dioxygen water process, centrifugation and sodium carbonate liquor;Montmorillonite after stripping point is dispersed in ethanol water, is added coupling agent, is obtained modified montmorillonite;Modified montmorillonite is mixed to prepare the compound hydrosol with DNA.The above-mentioned compound hydrosol being prepared is applied to as antiflaming finishing agent in the final finishing of polyester-cotton fabric, and montmorillonite platelet in the compound hydrosol makes the polyester-cotton fabric after arrangement have certain flame retarding function in polyester fiber surface-assembled.The antiflaming finishing agent can reduce the fire retardant additive amount of flame-retardant system, ensure the mechanical property of material while flame retardant effect is ensured.

Description

One kind based on the antiflaming finishing agents of montmorillonite/DNA hydrosols, its preparation method and its Using
Technical field
The present invention relates to function textile field, more specifically to a kind of fire-retardant based on montmorillonite/DNA hydrosols Finishing agent, its preparation method and its application.
Background technology
Polyester cotton is because its polyester-cotton blend component physicochemical property is complementary, not only with intensity is high, wearability is good, color fastness High, the advantages that acidproof heat-proof is good, but also with excellent hygroscopicity, gas permeability and the soft wearability such as comfortable, It is widely used in apparel industry and furnishing fields.But " wick effect " when polyester-cotton fabric is due to burning is flammable high, once Fire, it is difficult to extinguish, easily trigger fire, leave no small security risk in daily life, thus application is restricted. According to cotton fiber and burning and the fire retardant mechanism of terylene, reach fire-retardant mesh generally by fire-retardant post processing is carried out to fabric 's.
External polyester cotton fire retardant can be attributed to following two major class:Phosphorus-nitrogen containing based flame retardant series, in phosphorus-nitrogen containing Halogen is added in fire retardant(Bromine)Fire retardant series and containing antimony and bromine-containing compound fire retardant series.Phosphorus-nitrogen containing flame retardant is commonly used Have N- methylol compounds(Such as DMDHEU), tetra methylol chlorination squama(THPC), trihydroxy methyl melamine(TMM), three Methyl phosphorodithioate(TMP), THPN(The preshrunk thing of tetra methylol squama salt THPS and ammonia)Deng.50/ is arranged by THPN, urea and TMM 50 polyester cottons, when applied amount is up to 20~30%, can obtain very high anti-flammability, but the feel of fabric at this time is slightly hard, it is more difficult to Adapt to the requirement of each side.This is to use more polyester cotton fire retardant at present to halogenated flame retardant, including bromine system With chlorine system, common is bromine antimony composite flame-retardant agent.Common bromide has decabromodiphenyl oxide, hexabromocyclododecane etc., antimonide Predominantly antimony oxide, antimony pentoxide.The derivative of bromine-containing compound acts synergistically with antimony oxide, is roasted using padding Technique is dried to arrange to obtain LOI >=27%, char length<150cm, after flame time≤5s, the fabric of smoldering time≤5s, have compared with Good flame retardant effect.But the shortcomings that these fire retardants be burning when smoke amount it is big, produce it is poisonous, be harmful to, have arrange by force it is corrosive Halide.
For a long time, the polyester-cotton fabric flame-proof finishing process technology and its flame retardant performance developed are difficult to meet some use The requirement on way.There are the problem of mainly arrange after fabric feeling or mechanical strength it is not fully up to expectations, secondly production ecology Also need to improve in terms of.The present patent application is the requirement based on environmental protection and sustainable development, and halogen-free flame-retardant system has non- Normal vast potential for future development, naturally occurring book clay-montmorillonite belong to inorganic nano fire retardant, the distributed pole in the earth's crust Extensively, there is excellent mechanical property, gas barrier and fire retarding effect, a new generation's fire retardant used for textiles can be used as completely.
The content of the invention
In view of the deficiencies of the prior art, the present invention proposes a kind of antiflaming finishing agent for being based on montmorillonite/DNA hydrosols, Its preparation method and its application in polyester-cotton fabric final finishing, the fire retardant which can reduce flame-retardant system add Dosage, ensures the mechanical property of material while flame retardant effect is ensured.
The technical proposal for solving the technical problem of the invention is:One kind is fire-retardant whole based on montmorillonite/DNA hydrosols Agent is managed, the antiflaming finishing agent mainly includes following components:Montmorillonite, DNA, coupling agent;It is described fire-retardant whole in terms of parts by weight The content for managing each component in agent is as follows:The montmorillonite of 1 parts by weight, the coupling of the DNA of 0.1~10 parts by weight, 0.1~10 parts by weight Agent.
Further, the montmorillonite be commercialization montmorillonite through stripping point, modified obtain nano imvite;It is described to change The average wafer thickness of nano imvite after property is less than 25nm.Modified nano imvite lamellar spacing becomes smaller, whole Fabric face can be more entirely coated on after reason, improves distributing homogeneity of the montmorillonite platelet in fabric face, more favorably The lifting of power is combined between montmorillonite coating film and fiber, in flame contact polyester-cotton fabric, have to it is certain it is fire-retardant every Thermal effect.
Further, the coupling agent is at least one of silane coupling agent or titanate coupling agent.The work of coupling agent With being the interface interaction that improves between inorganic matter and organic matter, so that the performance of composite material is greatly improved, such as physical property, electricity Performance, hot property, optical property etc..
Preferably, the silane coupling agent is KH550, KH560, and the titanate coupling agent is HY311.
DNA, also known as DNA, are a kind of molecules, duplex structure, by deoxyribonucleotide(Component is:Deoxidation Ribose, phosphoric acid and four kinds of nitrogenous bases)Composition.DNA is double-spiral structure, is contained in the water mating type DNA, DNA that are referred to as Type B Substantial amounts of amino, carboxyl isopolarity group, form substantial amounts of hydrogen bond in the cohesive process of modified montmorillonoid and fabric.DNA points Substantial amounts of phosphorus, nitrogen play the role of cooperative flame retardant when being attacked be subject to heat in son, and in phosphorus-nitrogen compound system, phosphorus is made For acid source, it can be decomposited in the case of high-temperature heating and promote heat-insulated layer of charcoal to be formed in polymer surfaces;Nitrogen is then used as source of the gas, in heat Non-combustible gas is discharged in decomposable process, above-mentioned layer of charcoal can be made expanded foamed, and ultimately form foamed char.Foamed char can have Effect isolation mass exchange and heat exchange, so as to reach good flame retardant effect.
One kind based on montmorillonite/DNA hydrosols antiflaming finishing agent preparation method, the preparation method mainly include with Lower step:
1)The montmorillonite of 1 parts by weight is added in 30% hydrogen peroxide of 10~100 parts by weight, reacted at -10~30 DEG C Centrifuged 5~60 minutes under the conditions of 24~100 h, 3000~9000 r/min, the sediment isolated is dispersed in 5~30% again Sodium carbonate liquor in, stir 2~20h, be ultrasonically treated under 5~50KHz 0.5~10 it is small when, in 3000~9000 r/min bars Centrifuged under part, obtain the montmorillonoid sample of stripping point;
2)By 1)In the obtained montmorillonite of the strippings point of 1 parts by weight be dispersed in 75% ethanol water of 5~150 parts by weight In, stir evenly, be heated to 30~80 DEG C, add the coupling agent of 0.1~10 parts by weight, when stirring reaction 1~6 is small, obtain Modified montmorillonoid sample;
3)By 2)In the obtained modified montmorillonoid of 1 parts by weight mixed with the DNA of 0.1~10 parts by weight, stirred at 0~60 DEG C 0.5~6h is mixed, montmorillonite and the compound hydrosols of DNA, the as antiflaming finishing agent based on montmorillonite/DNA hydrosols is made.
The application of antiflaming finishing agent of the one kind based on montmorillonite/DNA hydrosols, the antiflaming finishing agent are mainly used in In the finishing process of polyester-cotton fabric.The application of the antiflaming finishing agent mainly includes the following steps that:In terms of parts by weight, by third 1 part of polyester-mixed cotton cloth that ketone cleaned is immersed under the conditions of some tension in 30~150 parts of montmorillonites and the compound hydrosols of DNA, and 20 Dried at~50 DEG C, promote montmorillonite platelet in the compound hydrosol to obtain having certain fire-retardant in polyester fiber surface-assembled The polyester-cotton fabric of function.
The beneficial effects of the invention are as follows:Compared with prior art, the present invention selects stripping point, modified montmorillonite and DNA A kind of obtained green, the complex sol of environmental protection, while add coupling agent and improve the compound of montmorillonite and DNA;Arrange polyester-cotton blend When on fabric, preferable flame retardant effect can be reached by smaller dosage, meet the needs of green finishing agent development, meanwhile, to material The mechanical performance influence of material is smaller, and the preferable intensity of fabric can also be kept at the same time by improving flame retardant effect.
Embodiment
With reference to embodiment, the invention will be further described.The dosage of each material is with parts by weight in following embodiments Number meter.
Embodiment 1
1 part of montmorillonite is scattered in 30 part 30% of hydrogen peroxide, stands 72 h at 4 DEG C, under the conditions of 5000 r/min from 20 min of the heart, the sediment isolated are dispersed in 10% sodium carbonate liquor again, 6 h of ultrasound under stirring 20 h, 20KHz, Centrifuged under the conditions of 6000 r/min, obtain the montmorillonoid sample of stripping point;The montmorillonite of 1 part of stripping point is dispersed in 50 parts of 75% second In alcohol solution, stir evenly, be heated to 70 DEG C, add 0.1 part of KH560 silane coupling agents, stirring 3 h of reaction, obtain Modified montmorillonoid sample;1 part of modified montmorillonoid is mixed with 2 parts of DNA, 2 h are stirred at 60 DEG C, montmorillonite and DNA is made The compound hydrosol.1 part of polyester-mixed cotton cloth that acetone was cleaned is immersed under the conditions of some tension in 50 parts of compound hydrosols, 30 DEG C Lower drying, promotes montmorillonite platelet in polyester fiber surface-assembled, obtains the polyester-cotton fabric of compound hydrosol processing.
Embodiment 2
1 part of montmorillonite is scattered in 40 part 30% of hydrogen peroxide, stands 72 h at 4 DEG C, under the conditions of 5000 r/min from 20 min of the heart, the sediment isolated are dispersed in 10% sodium carbonate liquor again, 6 h of ultrasound under stirring 20 h, 20KHz, Centrifuged under the conditions of 6000 r/min, obtain the montmorillonoid sample of stripping point;The montmorillonite of 1 part of stripping point is dispersed in 50 parts of 75% second In alcohol solution, stir evenly, be heated to 70 DEG C, add 0.2 part of HY311 coupling agents, stirring 3 h of reaction, are modified Montmorillonoid sample;1 part of modified montmorillonoid is mixed with 2 parts of DNA, 2 h are stirred at 60 DEG C, the compound of montmorillonite and DNA is made The hydrosol.1 part of polyester-mixed cotton cloth that acetone was cleaned is immersed under the conditions of some tension in 100 parts of compound hydrosols, at 40 DEG C Drying, promotes montmorillonite platelet in polyester fiber surface-assembled, obtains the polyester-cotton fabric of compound hydrosol processing.
Embodiment 3
Difference lies in 1 part of polyester-mixed cotton cloth for cleaning acetone is immersed in 100 under the conditions of some tension with embodiment 1 In the compound hydrosol of part, remaining step is same as Example 1.
Embodiment 4
1 part of montmorillonite is scattered in 50 part 30% of hydrogen peroxide, stands 72 h at 4 DEG C, under the conditions of 5000 r/min from 20 min of the heart, the sediment isolated are dispersed in 5% sodium carbonate liquor again, 6 h of ultrasound under stirring 20 h, 20KHz, Centrifuged under the conditions of 6000 r/min, obtain the montmorillonoid sample of stripping point;The montmorillonite of 1 part of stripping point is dispersed in 100 parts of 75% second In alcohol solution, stir evenly, be heated to 80 DEG C, add 0.2 part of KH560 silane coupling agents, stirring 3 h of reaction, obtain Modified montmorillonoid sample;1 part of modified montmorillonoid is mixed with 2 parts of DNA, 2 h are stirred at 60 DEG C, montmorillonite and DNA is made The compound hydrosol.1 part of polyester-mixed cotton cloth that acetone was cleaned is immersed under the conditions of some tension in 100 parts of compound hydrosols, and 40 Dried at DEG C, promote montmorillonite platelet in polyester fiber surface-assembled, obtain the polyester-cotton fabric of compound hydrosol processing.
Material property characterization is carried out by taking the polyester-cotton fabric of the gained of embodiment 4 as an example, it is as follows:
Prepare with postfinishing process condition it is same as Example 4 in the case of, experiment one is to investigate different montmorillonites to contain Carbonization area before and after the composite finishing agent of amount arranges after polyester-cotton fabric burning, experiment two are to investigate answering for different montmorillonite contents The break-draw strength of polyester-cotton fabric before and after finishing agent arranges is closed, specific contrast test data are shown in Table 1, table 2.
Char area of 1 polyester-cotton fabric of table by different content montmorillonite and DNA assembling after-combustions
The char area that can be seen that polyester-cotton blend former cloth from the data of table 1 is 58.44 cm2, and cloth specimen damage is more;0.1g is covered De- soil and the fabric char area of 0.2gDNA assemblings are 21.59 cm2, have preferable flame retardant effect compared with former cloth;Work as illiteracy When de- soil content progressively increases to 0.5g, 0.9g, char area is reduced to 14.21 cm2 and 6.57 cm2 respectively, illustrates warp Crossing the ability of the fabric resistance flame combustion arranged is progressively strengthening, i.e. montmorillonite in composite finishing agent within the specific limits Content more high fire-retardance effect it is better.
After the processing of table 2 with the break-draw of before processing polyester-cotton fabric strength
Numbering Montmorillonite content (g) DNA content (g) Average tensile strength (N) Strength change rate (%)
A / / 478.2±5.0 /
C 0.1 0.2 479.4±5.2 0.24%
D 0.5 0.2 501.9±4.9 4.94%
E 0.9 0.2 527.3±4.1 10.25%
From table 2 it can be seen that 0.1g montmorillonites are knitted with the polyester-cotton fabric that 0.2gDNA is assembled compared to untreated polyester-cotton blend Thing, strength do not change significantly;When montmorillonite content is gradually increased to 0.5g, 0.9g, the average strength of polyester-cotton fabric is slightly It is micro- to have been lifted.As it can be seen that the composition of finishing agent that the present invention explores and technique to fabric using when strength will not cause it is too big Influence.
Embodiment of above is merely to illustrate the present invention, and not limitation of the present invention, in relation to the common of technical field Technical staff, without departing from the spirit and scope of the present invention, can also make a variety of changes and modification, therefore all Equivalent technical solution falls within scope of the invention, and scope of patent protection of the invention should be defined by the claims.

Claims (3)

1. one kind is based on the antiflaming finishing agent of montmorillonite/DNA hydrosols, it is characterised in that:The antiflaming finishing agent mainly includes Following components:Montmorillonite, DNA, coupling agent;In terms of parts by weight, the content of each component is as follows in the antiflaming finishing agent:1 weight Measure the montmorillonite of part, the parts by weight of 0 .1~10 the parts by weight of DNA, 0 .1~10 coupling agent;The montmorillonite is commercialization Montmorillonite through stripping point, modified obtain nano imvite;The average wafer thickness of the modified nano imvite is less than 25nm;The coupling agent is at least one of silane coupling agent or titanate coupling agent;The silane coupling agent is KH550, KH560, the titanate coupling agent are HY311;The antiflaming finishing agent based on montmorillonite/DNA hydrosols Preparation method, mainly include the following steps that:
1)The montmorillonite of 1 parts by weight is added in 30% hydrogen peroxide of 10~100 parts by weight, at -10~30 DEG C react 24~ Centrifuged 5~60 minutes under the conditions of 100 h, 3000~9000 r/min, the sediment isolated is dispersed in 5~30% carbon again In acid sodium solution, when supersound process 0.5~10 is small under stirring 2~20h, 5~50KHz, under the conditions of 3000~9000 r/min Centrifugation, obtains the montmorillonoid sample of stripping point;
2)By 1)In obtain 1 parts by weight stripping point montmorillonite be dispersed in 75% ethanol water of 5~150 parts by weight, stir Mix uniformly, be heated to 30~80 DEG C, add the coupling agent of 0.1~10 parts by weight, when stirring reaction 1~6 is small, obtain modified illiteracy De- earth sample;
3)By 2)In the obtained modified montmorillonoid of 1 parts by weight mixed with the DNA of 0.1~10 parts by weight, stirred at 0~60 DEG C 0.5~6h, is made montmorillonite and the compound hydrosols of DNA, the as antiflaming finishing agent based on montmorillonite/DNA hydrosols.
A kind of 2. application of the antiflaming finishing agent based on montmorillonite/DNA hydrosols as claimed in claim 1, it is characterised in that: The antiflaming finishing agent is mainly used in the finishing process of polyester-cotton fabric.
3. the application of the antiflaming finishing agent based on montmorillonite/DNA hydrosols as claimed in claim 2, it is characterised in that described The application of antiflaming finishing agent mainly includes the following steps that:In terms of parts by weight, 1 part of polyester-mixed cotton cloth that acetone was cleaned necessarily is being opened 30~150 parts of montmorillonites are immersed under the conditions of power with the compound hydrosols of DNA, being dried at 20~50 DEG C, promoting the compound hydrosol In montmorillonite platelet in polyester fiber surface-assembled, obtain the polyester-cotton fabric with certain flame retarding function.
CN201610176164.9A 2016-03-26 2016-03-26 One kind is based on antiflaming finishing agent, its preparation method and its application of montmorillonite/DNA hydrosols Expired - Fee Related CN105780453B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610176164.9A CN105780453B (en) 2016-03-26 2016-03-26 One kind is based on antiflaming finishing agent, its preparation method and its application of montmorillonite/DNA hydrosols

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610176164.9A CN105780453B (en) 2016-03-26 2016-03-26 One kind is based on antiflaming finishing agent, its preparation method and its application of montmorillonite/DNA hydrosols

Publications (2)

Publication Number Publication Date
CN105780453A CN105780453A (en) 2016-07-20
CN105780453B true CN105780453B (en) 2018-04-17

Family

ID=56392073

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610176164.9A Expired - Fee Related CN105780453B (en) 2016-03-26 2016-03-26 One kind is based on antiflaming finishing agent, its preparation method and its application of montmorillonite/DNA hydrosols

Country Status (1)

Country Link
CN (1) CN105780453B (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106906644B (en) * 2017-04-12 2019-03-15 陕西科技大学 Cotton fabric is fire-retardant attapulgite modified and preparation method thereof with difunctional
CN107385913B (en) * 2017-09-08 2019-09-27 公安部四川消防研究所 A kind of preparation method of durable flame-proof fabric finishing liquor and durable flame-proof fabric
CN107916573A (en) * 2017-11-30 2018-04-17 英泰时尚服饰(苏州)有限公司 A kind of preparation method of flame-retardant and anti-static finishing agent

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101338083A (en) * 2007-07-03 2009-01-07 青岛华舜工贸有限公司 Technological process for modifying montmorillonite by conventional flame retardants
CN102963898B (en) * 2012-12-06 2014-10-29 贵州省复合改性聚合物材料工程技术研究中心 Preparation method of dual-functional group organically modified montmorillonite

Also Published As

Publication number Publication date
CN105780453A (en) 2016-07-20

Similar Documents

Publication Publication Date Title
CN105780453B (en) One kind is based on antiflaming finishing agent, its preparation method and its application of montmorillonite/DNA hydrosols
Salmeia et al. Recent advances for flame retardancy of textiles based on phosphorus chemistry
WO2015101312A1 (en) Flame retardant working solution and flame retardant finishing method for pure cotton fabrics and/or cotton-polyester blend fabrics
CN100545343C (en) The flame-proof treatment method of light and thin natural fiber material
CN104975497B (en) Flame retardant, preparation method and applications thereof
Alongi et al. Recent advances in the design of water based-flame retardant coatings for polyester and polyester-cotton blends
JP5715732B2 (en) Multipurpose functional cotton and method for producing the same
US6066198A (en) Process and product for rendering a substance flame resistant
Zhou et al. Synthesis of a novel flame retardant phosphorus/nitrogen/siloxane and its application on cotton fabrics
Forouharshad et al. Preparation of flame retardant wool using zirconium acetate optimized by CCD
JP2007182652A (en) Flame retarding processing agent for polyester fiber and processing method
Maryan et al. One pot denim washing and finishing using organo-montmorillonite: introducing nano mineral washing and finishing
CN101514526B (en) Modified polyacrylonitrile fiber (fabric) with flame retardant or noncombustible performance and a preparation method thereof
Bourbigot Flame retardancy of textiles: New approaches
Khandual Green flame retardants for textiles
CN103173888A (en) Halogen-free flame retardant polyester material and preparation method thereof
TW200827159A (en) Combustion-blocked, heat-insulated and wet-permeated coating cloth and method thereof
CN105648756B (en) A kind of preparation method and applications of cotton non-formaldehyde flame retardant
CN105088791B (en) Fabric with anti-flaming, anti-microbial and electric conducting functions and preparation method thereof
JP2007291563A (en) Incombustible fiber structure
CA1077203A (en) Flame resistant substrates
KR100929346B1 (en) Manufacturing method of flame retardant fabric for printing
Kaynak et al. Halogen free flame retardant finishing of wool and wool rich fabrics for aircraft seats
CN101016695A (en) Clean treatment method for light and thin natural fiber material
Alam A critical study of the effects of flame retardancy on different knit fabrics

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20180417

Termination date: 20200326