KR20090067260A - Anti bacteria paper foil and method of manufacturing paper foil - Google Patents

Anti bacteria paper foil and method of manufacturing paper foil Download PDF

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KR20090067260A
KR20090067260A KR1020070134826A KR20070134826A KR20090067260A KR 20090067260 A KR20090067260 A KR 20090067260A KR 1020070134826 A KR1020070134826 A KR 1020070134826A KR 20070134826 A KR20070134826 A KR 20070134826A KR 20090067260 A KR20090067260 A KR 20090067260A
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South Korea
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weight
parts
paper
aqueous solution
foil
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KR1020070134826A
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Korean (ko)
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한성재
강경진
박승준
이기주
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주식회사 그린클린테크놀로지
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Priority to KR1020070134826A priority Critical patent/KR20090067260A/en
Publication of KR20090067260A publication Critical patent/KR20090067260A/en

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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/71—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/16—Pure paper, i.e. paper lacking or having low content of contaminants
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H5/00—Special paper or cardboard not otherwise provided for
    • D21H5/22—Fungicidal, bactericidal, insecticidal, disinfecting, antiseptic, or corrosion-inhibiting paper antistatic, antioxygenic paper

Abstract

Non-toxic paper foil having antibacterial and biodegradation properties and a manufacturing method thereof are provided to take in food without toxic metal components or environment hormone. Non-toxic paper foil having antibacterial and biodegradation properties is made of natural pulp paper. The foil is produced by dipping and drying the natural pulp paper in an aqueous solution of chitosan, silver nano particles, acetic acid, an emulsifier, and methyl phenyl silicone oil(S102-S108). The aqueous solution includes the chitosan of 0.1 - 3 parts by weight, the nanosilver particle of 0.1 - 3 parts by weight, the acetic acid of 0.1 - 2 parts by weight, the emulsifier of 0.3 - 4 parts by weight, and the methyl phenyl silicone oil of 15 - 40 parts by weight.

Description

항균·생분해 기능을 갖는 무독성 종이호일 및 그 제조방법{ANTI BACTERIA PAPER FOIL AND METHOD OF MANUFACTURING PAPER FOIL}Non-toxic paper foil with antibacterial and biodegradable function and its manufacturing method {ANTI BACTERIA PAPER FOIL AND METHOD OF MANUFACTURING PAPER FOIL}

본 발명은 항균·생분해 기능을 갖는 무독성 종이호일 및 그 제조방법에 관한 것으로서, 보다 상세하게는 펄프원단에 키토산과 실리콘을 도포시켜 항균작용과 무독성 기능을 가지도록 하는 항균·생분해 기능을 갖는 무독성 종이호일 및 그 제조방법에 관한 것이다. The present invention relates to a non-toxic paper foil having an antibacterial and biodegradable function and a method for manufacturing the same, and more particularly, to a non-toxic paper having antibacterial and biodegradable function by applying chitosan and silicone to a pulp fabric to have an antibacterial and non-toxic function. It relates to a foil and a method for producing the same.

쿠킹호일은 음식의 조리나 보관을 위하여 사용되는데, 주로 알루미늄 박막으로 이루어져 있어서, 필요에 따라 적당한 크기로 잘라서 사용할 수 있다.Cooking foil is used for cooking or storage of food, mainly made of a thin aluminum film, can be cut into a suitable size if necessary.

흔히 식품의 보관, 포장 및 가열 조리시 사용되는 알루미늄 호일은 300 내지 400㎛의 알루미늄 박판을 롤러로 4, 5회 압연하여 12 내지 20㎛ 두께로 가공하여 사용한다.The aluminum foil, which is often used for food storage, packaging, and heating cooking, is rolled four or five times with a thin aluminum sheet having a thickness of 300 to 400 µm and processed to a thickness of 12 to 20 µm.

알루미늄 호일은 열전도율이 높고 강도가 커서 육류나 생선을 구울 때, 오븐에서 빵을 구울 때 많이 사용되고 있다.Aluminum foil has high thermal conductivity and high strength, so it is widely used to bake meat or fish, and to bake bread in an oven.

그런데 알루미늄 호일을 사용하여 음식물을 가열하면 음식물이 알루미늄 호일 표면에 흡착되거나 단시간에 탄소화되는 현상이 발생하였다. 또한, 기름이 심 하게 튀고 연기도 과다하게 발생되었으며, 열에서 변색되고 염수에 산화될 뿐만 아니라 대기중의 아황산가스 등에 의해서도 산화, 변색되는 문제점이 있었다.However, when the food is heated using the aluminum foil, the food is adsorbed on the surface of the aluminum foil or carbonization occurs in a short time. In addition, the oil was splashed badly and smoke was excessively generated, there was a problem of discoloration in heat and oxidation to brine, as well as oxidation and discoloration by sulfur dioxide gas in the atmosphere.

알루미늄 호일이 열에 의하여 산화 또는 변색되면서 발생하는 유해물질이 음식물에 흡수될 경우 여러가지 질병을 일으킬 수 있다.When aluminum foil is oxidized or discolored by heat, it can cause various diseases when harmful substances are absorbed in food.

이러한 문제들로 인하여 음식물의 보관, 포장시 항균 및 살균기능이 없어 일반가정, 각종 대중 음식점, 단체 급식업소, 학교 식당 등에서는 환경, 위생상 각별한 주의가 요구되었다.Due to these problems, there is no antibacterial and antiseptic function during food storage and packaging, so special care is required for environment and hygiene in general homes, various restaurants, group restaurants, and school restaurants.

또한 사용 후에도 알루미늄 호일이 자연 토양에서 산화되는 기간은 일반적으로 약 500년이 소요됨으로서 이로 인한 2차 생태환경의 오염 폐해는 심각한 수준이라 하겠다.In addition, it takes about 500 years for aluminum foil to be oxidized in natural soil even after use, so the secondary ecological pollution hazard is serious.

본 발명은 전술한 문제점을 해결하기 위한 것으로서, 천연 펄프원지에 내열, 내수, 내유작용을 하는 물질을 흡수시켜 불판이나 오븐에 사용할 수 있도록 하는 항균·생분해 기능을 갖는 무독성 종이호일 및 그 제조방법을 제공하는 것을 목적으로 한다.The present invention is to solve the above-mentioned problems, non-toxic paper foil having antibacterial and biodegradable function to absorb heat-resistant, water-resistant, oil-resistant substances in a natural pulp paper so that it can be used in a fire plate or oven, and a manufacturing method thereof. It aims to provide.

또한 본 발명은 천연 펄프원지에 실리콘 오일과 은나노 입자를 도포하여 항균작용과 함께 인체에 해로운 물질이 방출되는 것을 방지할 수 있는 항균·생분해 기능을 갖는 무독성 종이호일 및 그 제조방법을 제공하는 것을 목적으로 한다.Another object of the present invention is to provide a non-toxic paper foil having an antimicrobial and biodegradable function and a method for manufacturing the same, by applying silicone oil and silver nanoparticles to natural pulp paper to prevent the release of harmful substances with antibacterial action. It is done.

전술한 문제점을 해결하기 위하여 안출된 본 발명은 고기를 굽는 불판 위에 올려놓는 종이 재질의 호일로서, 천연 펄프원지를 키토산, 은나노 입자, 빙초산(CH3COOH), 유화제, 메틸페닐 실리콘 오일의 수용액에 함침 및 건조시켜 생산하는 것을 특징으로 한다.The present invention devised to solve the above problems is a paper-based foil placed on a grill plate for meat, impregnated with a natural pulp base in an aqueous solution of chitosan, silver nanoparticles, glacial acetic acid (CH 3 COOH), emulsifier, methylphenyl silicone oil And producing by drying.

상기 유화제는 라우릴 알코올(CH3(CH2)11OH)인 것을 특징으로 한다.The emulsifier is characterized in that lauryl alcohol (CH 3 (CH 2 ) 11 OH).

상기 수용액은 키토산 0.1 내지 3 중량부와; 은나노 입자 0.1 내지 3 중량부와; 빙초산 0.1 내지 2 중량부와; 유화제 0.3 내지 4 중량부와; 메틸페닐 실리콘 오일 15 내지 40 중량부;를 포함한다.The aqueous solution is 0.1 to 3 parts by weight of chitosan; 0.1 to 3 parts by weight of silver nanoparticles; 0.1 to 2 parts by weight of glacial acetic acid; 0.3 to 4 parts by weight of an emulsifier; 15 to 40 parts by weight of methylphenyl silicone oil; includes.

다른 실시예에 따른 본 발명은 고기를 굽는 불판 위에 올려놓는 종이 재질의 호일을 제조하는 방법으로서, 함침탱크에 키토산, 은나노 입자, 빙초산, 유화제, 메틸페닐 실리콘 오일과 물을 넣어서 수용액을 준비하는 단계와; 천연 펄프원지를 상기 수용액 속에 함침시킨 후 꺼내는 단계와; 수용액이 흡수된 펄프원지를 건조시키는 단계와; 상기 펄프원지를 압축롤러 사이에서 압축하는 단계와; 압축된 펄프원지를 권취하는 단계;를 포함한다.According to another embodiment of the present invention, there is provided a method of manufacturing a foil of paper material on a grill plate for meat, comprising: preparing an aqueous solution by adding chitosan, silver nanoparticles, glacial acetic acid, emulsifier, methylphenyl silicone oil and water in an impregnation tank; ; Taking out the natural pulp paper in the aqueous solution and then taking it out; Drying the pulp paper absorbed with the aqueous solution; Compressing the pulp paper between compression rollers; And winding the compressed pulp paper.

상기 유화제는 라우릴 알코올(CH3(CH2)11OH)인 것을 특징으로 한다.The emulsifier is characterized in that lauryl alcohol (CH 3 (CH 2 ) 11 OH).

상기 수용액은 키토산 0.1 내지 3 중량부와; 은나노 입자 0.1 내지 3 중량부와; 빙초산 0.1 내지 2 중량부와; 유화제 0.3 내지 4 중량부와; 메틸페닐 실리콘 오일 15 내지 40 중량부;를 포함한다.The aqueous solution is 0.1 to 3 parts by weight of chitosan; 0.1 to 3 parts by weight of silver nanoparticles; 0.1 to 2 parts by weight of glacial acetic acid; 0.3 to 4 parts by weight of an emulsifier; 15 to 40 parts by weight of methylphenyl silicone oil; includes.

본 발명에 따르면 자연상태에서 빠른 시간안에 생분해되는 종이호일을 사용하여 음식을 조리함으로써 환경오염을 줄일 수 있으며, 고온에서 인체에 유해한 금속성분이나 환경 호르몬이 방출되지 않아서 안심하고 음식물을 섭취할 수 있게 된다.According to the present invention, it is possible to reduce environmental pollution by cooking food using paper foil which is biodegradable in a natural state in a short time, and it is possible to ingest food with confidence because no harmful metals or environmental hormones are released at high temperature. do.

또한 본 발명에 따르면 은나노 입자에 의하여 살균 및 항균작용이 일어나므로, 음식물을 조리하거나 보관, 포장시 음식물 내부 또는 조리기구에 서식하는 세균이나 대장균을 없앨 수 있는 효과가 있다.In addition, according to the present invention, since silver nanoparticles cause sterilization and antimicrobial activity, there is an effect of eliminating bacteria or Escherichia coli in the food or cooking utensils when cooking, storing or packaging food.

또한 본 발명에 따르면 약 250℃ 정도의 온도에서도 종이호일이 타거나 눌러붙지 않아서 호일의 탄소화를 방지할 수 있는 효과가 있다.In addition, according to the present invention, the paper foil does not burn or press even at a temperature of about 250 ° C., thereby preventing the carbonization of the foil.

또한 기름 연기를 감소시키고, 기름이 튀는 현상을 1/10 정도로 줄일 수 있으며, 사용 후 폐기시 약 60일 정도면 일반 토양에서 자연분해되므로 환경오염을 줄일 수 있는 효과가 있다.In addition, it can reduce oil smoke, reduce oil splashing by about 1/10, and when used and disposed of after about 60 days, it is naturally decomposed in general soil, thereby reducing environmental pollution.

이하, 도면을 참조하여 본 발명의 실시예에 따른 항균·생분해 기능을 갖는 무독성 종이호일 및 그 제조방법을 설명한다.Hereinafter, a nontoxic paper foil having an antibacterial and biodegradable function and a method of manufacturing the same according to an embodiment of the present invention will be described with reference to the drawings.

도 1은 본 발명의 실시예에 다른 종이호일의 제조설비를 나타낸 도면이며, 도 2는 본 발명의 종이호일의 제조방법을 나타낸 순서도이다.1 is a view showing a paper foil manufacturing equipment according to an embodiment of the present invention, Figure 2 is a flow chart showing a manufacturing method of a paper foil of the present invention.

도 1과 2를 참조하여 본 발명의 종이호일의 제조방법을 설명하면, 먼저 천연 펄프원지(10)가 권취된 와인더롤러(102)로부터 펄프원지(10)를 인출하면서 함침탱크(104) 속에 넣는다.(S102)Referring to FIGS. 1 and 2, the method for manufacturing the paper foil of the present invention will be described. First, the pulp paper 10 is drawn out from the winder roller 102 in which the natural pulp paper 10 is wound, and then into the impregnation tank 104. (S102)

함침탱크(104) 내부에는 펄프원지(10)에 흡수될 수용액(106)이 저장되어 있다.An aqueous solution 106 to be absorbed in the pulp paper 10 is stored in the impregnation tank 104.

함침탱크(104) 내부에 저장된 수용액(106)은 종이가 내유성과 내열성, 내수성을 가질 수 있도록 하는 물질들의 혼합액이다.The aqueous solution 106 stored in the impregnation tank 104 is a mixture of substances that allow the paper to have oil resistance, heat resistance, and water resistance.

이를 위해 수용액(106)에는 키토산, 은나노 입자, 빙초산(CH3COOH), 유화제, 메틸페닐 실리콘 오일이 물과 함께 혼합되어 있다.To this end, chitosan, silver nanoparticles, glacial acetic acid (CH 3 COOH), an emulsifier, and methylphenyl silicone oil are mixed with water in the aqueous solution 106.

키토산은 게나 가재, 새우 껍데기에 들어 있는 키틴을 탈아세틸화하여 얻어낸 물질을 말하는데, 노폐해진 세포를 활성화하여 노화를 억제하고 면역력을 강화 해주며 질병을 예방해주는 효과가 있다. 또한 유해 콜레스테롤을 흡착, 배설하는 역할 즉 탈콜레스테롤 작용과, 암 세포의 증식을 억제하는 항암 작용을 한다. 그리고 혈압 상승의 원인이 되는 염화물 이온을 흡착, 장에서의 흡수를 억제한 뒤 체외로 배출시킴으로써 혈압 상승 억제 작용 및 장내의 유효 세균을 증식시키고 세포를 활성화하는 작용도 한다.Chitosan refers to a substance obtained by deacetylating the chitin contained in crabs, crayfish, and shrimp shells. It activates depleted cells to inhibit aging, strengthen immunity, and prevent disease. In addition, the role of adsorption and excretion of harmful cholesterol, that is, decholesterol action and anticancer action to inhibit the proliferation of cancer cells. In addition, by inhibiting the absorption of chloride ions, which cause the increase of blood pressure in the intestine, and then discharged to the outside of the body to suppress blood pressure rise, and also to increase the effective bacteria in the intestine and to activate the cells.

은나노 입자는 수 내지 수십 ㎚ 정도의 크기를 가지는 은입자로서, 항균 및 살균작용을 하는 것으로 알려져 있다.Silver nanoparticles are silver particles having a size of about several tens of nm, and are known to have antibacterial and bactericidal effects.

빙초산은 약산으로서, 여러가지 유기물질을 녹이는 유기용매로 사용된다.Glacial acetic acid is a weak acid and is used as an organic solvent to dissolve various organic substances.

유화제는 유기물질을 에멀션화시키는 용매로서, 본 발명에서는 라우릴 알코올(CH3(CH2)11OH)이 사용된다. 라우릴 알코올은 화장품이나 세제 등의 제조에 널리 사용되는 물질이므로 자세한 설명은 생략한다.Emulsifiers are solvents for emulsifying organic materials. In the present invention, lauryl alcohol (CH 3 (CH 2 ) 11 OH) is used. Lauryl alcohol is a material widely used in the manufacture of cosmetics and detergents, etc., and thus, a detailed description thereof will be omitted.

메틸페닐 실리콘 오일(Methyl Phenyl Silicon Oil)은 발수제로 사용된다. 실리콘은 내열성이 있어서 200℃ 이상의 온도에서도 장시간 견딜 수 있는 물질이어서 내고온성 절연재료로 전기기구에 널리 사용되고 있다. 또한 실리콘수지의 일종인 실리콘 오일은 발수성이 좋아서 종이호일 내부에 물이 스며드는 것을 방지하는 기능을 하기도 한다.Methyl Phenyl Silicon Oil is used as a water repellent. Silicon is a material that can withstand a long time even at temperatures of 200 ° C. or higher due to its heat resistance, and thus it is widely used in electric appliances as a high temperature resistant insulating material. In addition, silicone oil, which is a kind of silicone resin, has a good water repellency, and serves to prevent water from penetrating into the paper foil.

본 발명의 수용액(106)은 다음과 같은 성분비율을 갖는 것이 바람직하다.It is preferable that the aqueous solution 106 of this invention has the following component ratios.

* 키토산 0.1 내지 3 중량부  * 0.1 to 3 parts by weight of chitosan

* 은나노 입자 0.1 내지 3 중량부  * 0.1 to 3 parts by weight of silver nanoparticles

* 빙초산 0.1 내지 2 중량부  * 0.1 to 2 parts by weight of glacial acetic acid

* 유화제 0.3 내지 4 중량부  * 0.3 to 4 parts by weight of emulsifier

* 메틸페닐 실리콘 오일 15 내지 40 중량부  15 to 40 parts by weight of methylphenyl silicone oil

* 물 40 내지 80 중량부  40 to 80 parts by weight of water

이외에도 필요에 따라 내유내수제 등이 첨가될 수 있다.In addition, oil-resistant and the like may be added as necessary.

전술한 성분들을 물과 함께 혼합하여 수용액 상태로 만들어서 함침탱크(104)에 저장한 상태에서 펄프원지(10)를 수용액(106) 속에서 일정한 속도로 통과시킨다. 이를 위해 함침탱크(104) 내부에는 함침롤러(104a)가 구비되는데, 함침롤러(104a)의 밑면은 수용액(106) 속에 잠기도록 설치된다.The pulp paper 10 is passed through the aqueous solution 106 at a constant rate in a state in which the above-mentioned components are mixed with water to form an aqueous solution and stored in the impregnation tank 104. To this end, an impregnation roller 104a is provided inside the impregnation tank 104, and the bottom surface of the impregnation roller 104a is installed to be immersed in the aqueous solution 106.

펄프원지(10)는 함침탱크(104)를 통과하면서 수용액(106)이 펄프원지(10) 내부에 흡수되는데, 펄프원지(10)는 열과 물에 약한 종이지만, 내외부에 흡수된 수용액(106)으로 인하여 발수성, 내열성, 내유성을 가지게 되는 것이다.While the pulp paper 10 passes through the impregnation tank 104, the aqueous solution 106 is absorbed into the pulp paper 10. The pulp paper 10 is weak to heat and water, but the aqueous solution 106 absorbed inside and outside. Due to it will have water repellency, heat resistance, oil resistance.

함침탱크(104)를 통과하는 시간은 적절하게 조절할 수 있다.The time passing through the impregnation tank 104 can be appropriately adjusted.

수용액(106)을 통과한 펄프원지(10)는 한 쌍의 압축롤러(108) 사이를 통과하는데, 압축롤러(108)는 펄프원지(10)를 압축하면서 과도하게 흡수된 수용액(106)을 재수거한다.(S104)The pulp paper 10 passing through the aqueous solution 106 passes between a pair of compression rollers 108, which compresses the pulp paper 10 to re-excessively absorb the aqueous solution 106. Collect it. (S104)

재수거된 수용액(106)은 재수거탱크(110)에 담겼다가 파이프(110a)를 통해 함침탱크(104)로 다시 돌아온다.The re-collected aqueous solution 106 is immersed in the recollection tank 110 and returned back to the impregnation tank 104 through the pipe (110a).

수용액(106)이 흡수된 상태의 펄프원지(10)는 1차 히팅챔버(112)를 통과하면 서 1차 가열 및 건조된다.(S106) 그리고 다시 2차 히팅챔버(114)를 통과하면서 다시 한 번 가열 및 건조된다.(S108)The pulp paper 10 in which the aqueous solution 106 is absorbed is first heated and dried while passing through the primary heating chamber 112 (S106) and again while passing through the secondary heating chamber 114. It is heated and dried once. (S108)

히팅챔버(112, 114)에서는 가열된 롤러 사이를 통과하면서 건조되도록 할 수도 있고, 적외선이나 열풍을 쐬면서 건조가 이루어지도록 할 수도 있을 것이다.In the heating chamber (112, 114) may be allowed to dry while passing between the heated rollers, it may be made to dry while blowing in the infrared or hot air.

가열 및 건조를 두 번에 걸쳐서 하는 이유는 급속하게 가열할 경우, 종이원단에 변형이 생기거나 얼룩이 생길 수 있기 때문이다. 그러나 이와 같은 사항은 선택사항일 뿐, 필수적인 구성요소는 아니다. 따라서 필요에 따라서는 한 번의 가열 및 건조과정을 거쳐서 제품을 생산할 수도 있다.The reason why the heating and drying are performed twice is that the rapid heating may cause deformation or stain of the paper fabric. However, this is optional and not an essential component. Therefore, if necessary, the product can be produced through one heating and drying process.

건조가 완료된 펄프원지(10)는 한 쌍의 압축드라이롤러(116) 사이를 통과하면서 주름이 펴지고 평평한 형상을 가지게 되며, 리와인더롤러(118)에 권취되면서 제품 생산이 완료된다.(S110)Completed pulp paper 10 is passed through a pair of compression dry rollers 116 to have a flattened wrinkles and have a flat shape, and is wound around the rewinder roller 118 to complete the production of the product.

마지막으로 재단기(도면 미도시)에서 제품의 용도에 맞는 크기와 형상으로 재단되면서 최종 제품이 완성된다.(S112)Finally, the final product is completed by cutting to a size and shape suitable for the purpose of the product in a cutting machine (not shown). (S112)

이상 첨부된 도면을 참조하여 본 발명의 바람직한 실시예를 설명하였지만, 상술한 본 발명의 기술적 구성은 본 발명이 속하는 기술 분야의 당업자가 본 발명의 그 기술적 사상이나 필수적 특징을 변경하지 않고서 다른 구체적인 형태로 실시될 수 있다는 것을 이해할 수 있을 것이다. 그러므로 이상에서 기술한 실시예들은 모든 면에서 예시적인 것이며 한정적인 것이 아닌 것으로서 이해되어야 하고, 본 발명의 범위는 상기 상세한 설명보다는 후술하는 특허청구범위에 의하여 나타내어지며, 특허청구범위의 의미 및 범위 그리고 그 등가 개념으로부터 도출되는 모든 변경 또는 변형된 형태가 본 발명의 범위에 포함되는 것으로 해석되어야 한다.Although the preferred embodiments of the present invention have been described above with reference to the accompanying drawings, the above-described technical configuration of the present invention may be embodied by those skilled in the art to which the present invention pertains without changing its technical spirit or essential features of the present invention. It will be appreciated that the present invention may be practiced as. Therefore, the above-described embodiments are to be understood as illustrative and not restrictive in all respects, and the scope of the present invention is indicated by the appended claims rather than the detailed description, and the meaning and scope of the claims and All changes or modifications derived from the equivalent concept should be interpreted as being included in the scope of the present invention.

도 1은 본 발명의 실시예에 다른 종이호일의 제조설비를 나타낸 도면.1 is a view showing the manufacturing equipment of the paper foil according to the embodiment of the present invention.

도 2는 본 발명의 종이호일의 제조방법을 나타낸 순서도.2 is a flow chart showing a manufacturing method of the paper foil of the present invention.

Claims (6)

고기를 굽는 불판 위에 올려놓는 종이 재질의 호일로서,Paper foil for placing meat on a grill 천연 펄프원지를 키토산, 은나노 입자, 빙초산(CH3COOH), 유화제, 메틸페닐 실리콘 오일의 수용액에 함침 및 건조시켜 생산하는 것을 특징으로 하는 항균·생분해 기능을 갖는 무독성 종이호일.Non-toxic paper foil with antibacterial and biodegradable function, characterized in that the natural pulp is produced by impregnating and drying the aqueous solution of chitosan, silver nanoparticles, glacial acetic acid (CH 3 COOH), emulsifier, methylphenyl silicone oil. 제1항에 있어서,The method of claim 1, 상기 유화제는 라우릴 알코올(CH3(CH2)11OH)인 것을 특징으로 하는 항균·생분해 기능을 갖는 무독성 종이호일.The emulsifier is lauryl alcohol (CH 3 (CH 2 ) 11 OH) Non-toxic paper foil having an antimicrobial, biodegradable function, characterized in that. 제2항에 있어서,The method of claim 2, 상기 수용액은The aqueous solution is 키토산 0.1 내지 3 중량부와;0.1 to 3 parts by weight of chitosan; 은나노 입자 0.1 내지 3 중량부와;0.1 to 3 parts by weight of silver nanoparticles; 빙초산 0.1 내지 2 중량부와;0.1 to 2 parts by weight of glacial acetic acid; 유화제 0.3 내지 4 중량부와;0.3 to 4 parts by weight of an emulsifier; 메틸페닐 실리콘 오일 15 내지 40 중량부;를 포함하는 항균·생분해 기능을 갖는 무독성 종이호일.15-40 parts by weight of methylphenyl silicone oil; Non-toxic paper foil having an antibacterial and biodegradable function comprising. 고기를 굽는 불판 위에 올려놓는 종이 재질의 호일을 제조하는 방법으로서,As a method of making paper foil for placing meat on a grilling plate, 함침탱크에 키토산, 은나노 입자, 빙초산, 유화제, 메틸페닐 실리콘 오일과 물을 넣어서 수용액을 준비하는 단계와;Preparing an aqueous solution by adding chitosan, silver nanoparticles, glacial acetic acid, emulsifier, methylphenyl silicone oil and water to the impregnation tank; 천연 펄프원지를 상기 수용액 속에 함침시킨 후 꺼내는 단계와;Taking out the natural pulp paper in the aqueous solution and then taking it out; 수용액이 흡수된 펄프원지를 건조시키는 단계와;Drying the pulp paper absorbed with the aqueous solution; 상기 펄프원지를 압축롤러 사이에서 압축하는 단계와;Compressing the pulp paper between compression rollers; 압축된 펄프원지를 권취하는 단계;를 포함하는 항균·생분해 기능을 갖는 무독성 종이호일 제조방법.Winding the compressed pulp paper; Non-toxic paper foil manufacturing method having an antimicrobial, biodegradable function comprising a. 제4항에 있어서,The method of claim 4, wherein 상기 유화제는 라우릴 알코올(CH3(CH2)11OH)인 것을 특징으로 하는 항균·생분해 기능을 갖는 무독성 종이호일 제조방법.The emulsifier is lauryl alcohol (CH 3 (CH 2 ) 11 OH) characterized in that the non-toxic paper foil manufacturing method having an antimicrobial, biodegradable function. 제5항에 있어서,The method of claim 5, 상기 수용액은The aqueous solution is 키토산 0.1 내지 3 중량부와;0.1 to 3 parts by weight of chitosan; 은나노 입자 0.1 내지 3 중량부와;0.1 to 3 parts by weight of silver nanoparticles; 빙초산 0.1 내지 2 중량부와;0.1 to 2 parts by weight of glacial acetic acid; 유화제 0.3 내지 4 중량부와;0.3 to 4 parts by weight of an emulsifier; 메틸페닐 실리콘 오일 15 내지 40 중량부;를 포함하는 항균·생분해 기능을 갖는 무독성 종이호일 제조방법.15 to 40 parts by weight of methylphenyl silicone oil; non-toxic paper foil manufacturing method having an antibacterial and biodegradable function comprising.
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106436473A (en) * 2016-09-18 2017-02-22 淮海工学院 Preparation method and application of compound chitosan bacteriostatic food wrapping paper
KR20190001047A (en) * 2017-06-26 2019-01-04 (주)바이오소재 Bio-vinyl composition for antimicrobial roll bags, sanitary bags and sanitary gloves using biodegradable catalyst
JP2019023302A (en) * 2018-09-25 2019-02-14 独立行政法人国立高等専門学校機構 Antifouling composite coat with biofilm forming ability suppressed
KR20220028252A (en) 2020-08-28 2022-03-08 박형자 The mold device for shape cooking paper hoil
KR20220127511A (en) 2021-03-11 2022-09-20 위소이 Paper foil for cooking food and its manufacturing method
WO2022260205A1 (en) * 2020-08-10 2022-12-15 주식회사 비지에프에코바이오 Biodegradable sheet having antiviral properties, method for manufacturing same, and use thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106436473A (en) * 2016-09-18 2017-02-22 淮海工学院 Preparation method and application of compound chitosan bacteriostatic food wrapping paper
KR20190001047A (en) * 2017-06-26 2019-01-04 (주)바이오소재 Bio-vinyl composition for antimicrobial roll bags, sanitary bags and sanitary gloves using biodegradable catalyst
JP2019023302A (en) * 2018-09-25 2019-02-14 独立行政法人国立高等専門学校機構 Antifouling composite coat with biofilm forming ability suppressed
WO2022260205A1 (en) * 2020-08-10 2022-12-15 주식회사 비지에프에코바이오 Biodegradable sheet having antiviral properties, method for manufacturing same, and use thereof
KR20220028252A (en) 2020-08-28 2022-03-08 박형자 The mold device for shape cooking paper hoil
KR20220127511A (en) 2021-03-11 2022-09-20 위소이 Paper foil for cooking food and its manufacturing method

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