KR20090020206A - The pro-environment production technique of construction material for which silica natural mineral matter was used - Google Patents

The pro-environment production technique of construction material for which silica natural mineral matter was used Download PDF

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KR20090020206A
KR20090020206A KR1020070084761A KR20070084761A KR20090020206A KR 20090020206 A KR20090020206 A KR 20090020206A KR 1020070084761 A KR1020070084761 A KR 1020070084761A KR 20070084761 A KR20070084761 A KR 20070084761A KR 20090020206 A KR20090020206 A KR 20090020206A
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natural
mineral
siliceous
natural mineral
nature mineral
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KR1020070084761A
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KR100887662B1 (en
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김응교
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디에스케이엔지니어링(주)
김응교
디에스케이종합건축사사무소(주)
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00Producing shaped prefabricated articles from the material
    • B28B1/50Producing shaped prefabricated articles from the material specially adapted for producing articles of expanded material, e.g. cellular concrete
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02Treatment
    • C04B20/026Comminuting, e.g. by grinding or breaking; Defibrillating fibres other than asbestos
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/06Oxides, Hydroxides
    • C04B22/062Oxides, Hydroxides of the alkali or alkaline-earth metals
    • C04B22/064Oxides, Hydroxides of the alkali or alkaline-earth metals of the alkaline-earth metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/22Natural resins, e.g. rosin
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/10Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by using foaming agents or by using mechanical means, e.g. adding preformed foam

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Civil Engineering (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

A building material producing method using siliceous nature mineral is provided to be developed into greening construction material by using nature mineral, to radiate far-infrared ion, to improve infrastructure of human body, to purify air(antibiotic) and to have detoxication. A building material producing method using siliceous nature mineral comprises steps of: pulverizing nature mineral and lime over 300 mesh; mixing nature mineral 50~80 weight% and lime 20~50 weight%; adding vegetability foaming agent and animal foaming agent; mixing latex or seaweeds which is environment natural material in order to maintain cohesive property and prevent crack; distending, foaming and drying the nature mineral; and manufacturing environment construction material. The nature mineral uses selectively one of silicates consisting of elvan, biotite, pegmatite, granite, quartz, enterolith.

Description

규산질 천연광물질을 이용한 친환경 건축자재 제조방법{The pro-environment production technique of construction material for which silica natural mineral matter was used}The pro-environment production technique of construction material for which silica natural mineral matter was used}

본 발명은 규산질 천연광물질을 이용한 친환경 건축자재 제조방법에 관한 것으로, 특히 천연광물질(맥반석, 흑운모, 거장석, 화강암, 석영, 장석 등 규산염광물) 등을 이용하여 건축자재의 사용용도에 따라 바닥재, 천정재, 벽 패널 등을 제조하는 규산질 천연광물질을 이용한 친환경 건축자재 제조방법에 관한 것이다.The present invention relates to a method for manufacturing environmentally friendly building materials using siliceous natural minerals, in particular floor materials according to the use of the building materials using natural minerals (silicate minerals such as elvan, biotite, feldspar, granite, quartz, feldspar) The present invention relates to a method for manufacturing environmentally friendly building materials using siliceous natural minerals for manufacturing ceiling materials and wall panels.

일반적으로 천연 광물질은 자연 친환경적인 자재로서 특히 미네랄을 함유하고 있는 게르마늄, 나트륨, 세레늄 등은 다공성 및 흡착성이 강하고 다량의 무기염류를 함유하고 있다. In general, natural minerals are natural environmentally friendly materials, especially germanium, sodium, and selenium, which contain minerals, are highly porous and adsorbable, and contain a large amount of inorganic salts.

이러한 무기염류는 중금속과 이온을 상호 교환하는 작용을 하기 때문에 유해금속의 제거제로 사용되어 왔다. These inorganic salts have been used as a remover of harmful metals because they act to exchange heavy metals and ions.

특히 이러한 천연광물질은 원적외선 방사, 인체의 체질개선, 공기정화(항균), 강결성부여, 해독작용 등의 주거환경에 유익한 친환경 건축자재를 제조하므로 웰빙 주거환경을 제공하고자 한다. In particular, these natural minerals are intended to provide a well-being residential environment by manufacturing environmentally friendly building materials that are beneficial to the living environment, such as far-infrared radiation, improving the human body, air purification (antibacterial), imparting strength and detoxification.

상기 자연친화적인 천연광물질은 비중이 무겁고 제품가격이 고가임으로 지금까지 대중적으로 사용하기에는 어려움이 있었다. Naturally friendly natural minerals have a heavy specific gravity and are expensive to use, and thus have been difficult to use publicly.

이에, 본 발명은 상기한 바와 같은 제반문제점을 해결하기 위해 안출된 것으로서, 천연광물질(맥반석, 흑운모, 거장석, 화강암, 석영, 장석 등 규산염광물)을 이용하여 친환경성 건축자재로 개발하여 원적외선 방사, 인체의 체질개선, 공기정화(항균). 강건성 부여, 해독작용 등을 제공하는 웰빙의 친환경 건축자재로서 규산질 천연광물질을 이용한 친환경 건축자재 제조방법을 제공하는데 그 목적이 있다.Therefore, the present invention has been devised to solve the above problems, and developed as an environmentally friendly building material using natural minerals (macbanite, biotite, maestro, granite, quartz, feldspar, etc.) to produce far-infrared radiation , Body constitution improvement, air purification (antibacterial). Its purpose is to provide environmentally friendly building materials manufacturing methods using siliceous natural minerals as well being environmentally friendly building materials that provide robustness and detoxification.

상기한 목적을 달성하기 위한 본 발명에 따른 규산질 천연광물질을 이용한 친환경 건축자재 제조방법은 천연광물질과 석회를 300 mesh 이상으로 분쇄하여 천연광물질 50~80 중량%와 석회 20~50중량%를 혼합하고, 식물성 및 동물성 기포제를 첨가하고, 균열방지와 부착성이 유지되도록 친환경 천연소재인 라텍스 혹은 해초물을 배합하여 혼합된 천연광물질을 요구되는 건축자재의 다공체에 따라 팽창시켜 발포, 건조, 조성하여 친환경 건축자재를 제조함을 특징으로 한다.Environment-friendly building materials manufacturing method using the siliceous natural mineral according to the present invention for achieving the above object is to crush the natural mineral and lime to 300 mesh or more to mix 50 to 80% by weight of natural mineral and 20 to 50% by weight of lime By adding vegetable and animal foaming agents and mixing latex or seaweed, which is an eco-friendly natural material, to prevent cracking and adhesion, it expands the mixed natural minerals according to the porous material of the required building materials, foaming, drying, and composition It is characterized by the manufacture of building materials.

이상에서 설명한 바와 같이, 본 발명에 따른 규산질 천연광물질을 이용한 친환경 건축자재 제조방법은 천연광물질 다공체로 성형하여 건축자재를 제조, 경량화함으로써 시공이 간편하고, 원자재 비용의 절감과 외장성 내구성이 우수한 건축자 재를 제조할 수 있으며, 최근의 사회적으로 문제가 되고 있는 환경적 문제를 해결하고 국민의 인체기능 활성화에 크게 기여하는 이점이 있다. As described above, the eco-friendly construction material manufacturing method using the siliceous natural mineral according to the present invention is easy to construct by manufacturing and lightening the building material by molding into a natural mineral porous body, the construction cost is excellent and the exterior durability is excellent construction Material can be manufactured, and it has the advantage of contributing to solving the recent environmental problems that are socially problematic and greatly contributing to the activation of human function of the people.

이하, 본 발명을 첨부한 예시도면을 참조하여 상세히 설명한다. Hereinafter, with reference to the accompanying drawings, the present invention will be described in detail.

도 1은 본 발명에 따른 천연광물질을 이용한 건축자재 제조공정을 도시한 공정도이다.1 is a process chart showing a building material manufacturing process using a natural mineral according to the present invention.

이 도면에 도시된 바와 같이, 본 발명에 따른 규산질 천연광물질을 이용한 건축자재 제조방법은 천연광물질과 석회를 300mesh 이상으로 분쇄하여 천연광물질 50~80중량%와 석회 20~50중량%를 혼합하고, 식물성 및 동물성 기포제를 첨가하고, 균열방지와 부착성이 유지되도록 천연소재인 라텍스 혹은 해초물을 배합하고, 요구되는 건축자재의 다공체에 따라 혼합된 천연광물질의 부피를 팽창시켜 발포, 건조, 소성하여 친환경 건축자재를 제조한다.As shown in this figure, the building material manufacturing method using a siliceous natural mineral according to the present invention by grinding the natural mineral and lime to 300 mesh or more to mix the natural mineral 50 to 80% by weight and lime 20 to 50% by weight, Adding vegetable and animal foaming agents, blending latex or seaweed with natural materials to prevent cracking and adhesion, and expanding, foaming, drying and firing the volume of mixed natural minerals according to the porous material of building materials required. Manufacture environmentally friendly building materials.

여기서, 상기 천연광물질은 맥반석, 흑운모, 거정석, 화강암, 석영, 장석으로 이루어지는 규산염광물 중에서 어느 하나를 선택적으로 사용한다.Here, the natural mineral is selectively used any one of silicate mineral consisting of elvan, biotite, macrorite, granite, quartz, feldspar.

또한, 상기 천연광물질을 거푸집에 넣고 발포 팽창하여 케이크 모양으로 굳었을 때 꺼내 형상을 잘라 고압소독기 내에서 적정온도인 170~200℃, 10기압으로 양생한다.In addition, when the natural mineral is placed in a formwork and foamed and expanded to harden into a cake shape, the shape is taken out and cured at a proper temperature of 170 to 200 ° C. and 10 atm in a high pressure sterilizer.

그리고, 상기 식물성 및 동물성 기포제는 식물성 단백질과 동물성 단백질(소발톱, 돼지발톱, 소뿔 등)으로 이루어진다.In addition, the vegetable and animal foaming agent is composed of a vegetable protein and an animal protein (cow claws, pig claws, horns, etc.).

즉, 본 발명에 따른 규산질 천연광물질을 이용한 친환경 건축자재 제조방법 은 건축자재의 대부분이 미세한 기포(습도조절능력)로 구성되어 있으며, 원료 1㎥로 요구되는 건축자재의 특성에 따라 규산질 다공체를 제조할 수 있는 특징이 있다.In other words, the method for manufacturing eco-friendly building materials using the siliceous natural mineral according to the present invention is composed of the most of the building materials are composed of fine bubbles (humidity control ability), and produce a siliceous porous body according to the characteristics of the building material required as the raw material 1㎥ There are features that can be done.

규산질 다공체의 제조과정은 친환경적이다.The manufacturing process of siliceous porous body is environmentally friendly.

고압소독기(Autoclave) 양생시 적정온도는 170~200℃이며, 가장 바람직한 온도는 180℃이며, 증기양생시간은 2~3 시간이며, 증기양생과정에서 사용되는 수증기는 여러 번 재사용되며, 이와 같은 증기양생방법은 인간이 거주하는 모든 환경조건에 유해한 어떤 물질도 발생하지 않는다.When curing autoclave, the optimum temperature is 170 ~ 200 ℃, the most preferable temperature is 180 ℃, steam curing time is 2 ~ 3 hours, and steam used in steam curing process is reused several times. Curing methods do not produce any substances that are harmful to all environmental conditions in which humans live.

다음은 고압소독기로 양생한 경량 기포제로 실리카(SiO2)가 많이 들어있는 천연광물질(맥반석, 흑운모, 거정석, 화강암, 석영, 장석으로 일어지는 규산염광물)과 석회를 주원료로 제조한다.The following is a lightweight foaming agent cured by high-pressure sterilizer to produce natural minerals (silicates composed of ganbanite, biotite, macrorite, granite, quartz, feldspar) and lime containing a lot of silica (SiO 2 ).

천연광물질(맥반석, 흑운모, 거정석, 화강암, 석영, 장석으로 이루어지는 규산염광물)등을 거푸집에 넣고 발포 팽창하여 케이크 모양으로 굳었을 때 꺼내 형상을 잘라 고압소독기 내에서 180℃, 10기압으로 양생한다.Natural minerals (silicate minerals consisting of elvan, biotite, macrorite, granite, quartz, and feldspar) are placed in the formwork and foamed and expanded to remove the cake when it hardens into a cake shape. .

비중은 0.5~0.9로서 흡수 건조할 때 용적변형이 다공성(공극율 80% 이상)이어서 건축자재의 경량화로서 시공성이 용이한 다공체의 친환경 건축자재가 된다. Specific gravity is 0.5 ~ 0.9. When absorbed and dried, the volumetric deformation is porous (more than 80% of porosity), so it is light weight of building materials, making it an eco-friendly building material of porous body that is easy to construct.

또한, 상기 수분흡수 규산질 다공체는 천연광물질(맥반석, 흑운모, 거정석, 화강암, 석영, 장석 등 규산염 광물)을 이용하므로 값이 저렴하여 건축시공시 원가절감의 친환경자재로 대체될 수 있다. In addition, the water-absorbing siliceous porous body is made of natural minerals (macbanite, biotite, macrorite, granite, quartz, feldspar, silicate minerals), so it can be replaced with environmentally-friendly materials of low cost during construction.

이러한 천연광물질의 규산질 다공체 성분 분석은 아래와 같다.The siliceous porous component analysis of such natural mineral is as follows.

1) 규산질 다공체의 성분분석1) Component analysis of siliceous porous body

성분ingredient SiO2 SiO 2 Al2O3 Al 2 O 3 Fe2O3 Fe 2 O 3 CaOCaO MgOMgO K2OK 2 O Na2ONa 2 O TiO2 TiO 2 P2O5 P 2 O 5 MnOMnO IglossIgloss %% 60.860.8 8.118.11 1.971.97 19.9019.90 0.430.43 3.483.48 1.611.61 0.310.31 0.150.15 0.030.03 3.013.01

2) 맥반석 성분분석2) Elvan component analysis

성분ingredient SiO2 SiO 2 Al2O3 Al 2 O 3 Fe2O3 Fe 2 O 3 CaOCaO MgOMgO Na2ONa 2 O K2OK 2 O %% 68.468.4 15.615.6 3.073.07 1.771.77 0.590.59 5.045.04 3.673.67

3) 흑운모 성분분석3) Biotite component analysis

성분ingredient SiO2 SiO 2 Al2O3 Al 2 O 3 Fe2O3 Fe 2 O 3 CaOCaO MgOMgO K2OK 2 O Na2ONa 2 O TiO2 TiO 2 P2O5 P 2 O 5 MnOMnO IglossIgloss %% 68.2668.26 14.8314.83 4.054.05 1.881.88 0.070.07 6.506.50 2.822.82 0.440.44 0.320.32 0.030.03 0.730.73

4) 규산질 다공체 원적외선 방사율4) siliceous porous body far-infrared emissivity

방사율 (5~20㎛)Emissivity (5 ~ 20㎛) 방사에너지(W/㎡㎛,40℃)Radiation energy (W / ㎡㎛, 40 ℃) 0.930.93 3.74 × 102 3.74 × 10 2

시험가스명 : 암모니아Test gas name: Ammonia

Blank는 시료를 넣지 않은 상태에서 측정한 것임.Blank is measured with no sample.

5) 규산질 다공체 항곰팡이시험5) siliceous porous body antifungal test

시료명Sample Name 시험항목Test Items 배양시험기간Culture test period 규산질 다공체Siliceous porous body 함곰팡이 시험Ham fungus test 1주후1 week later 2주후after 2 weeks 3주후3 weeks later 4주후4 weeks later

곰팡이균주 : 혼합균주Fungal strains: Mixed strains

6) 대장균, 녹농균에 의한 항균시험6) Antibacterial test by Escherichia coli and Pseudomonas aeruginosa

시험항목Test Items 시료구분Sample classification 초기농도 (개/㎖)Initial concentration (dog / ml) 6시간후 (개/㎖)After 6 hours (dog / ml) 24시간 후 (개/㎖)After 24 hours (pcs / ml) 세균감소율 (%)Bacterial Reduction Rate (%) 대장균에 의한 시험Test by E. coli BlankBlank 126126 125125 120120 4.84.8 규산질 다공체Siliceous porous body 121121 5454 44 96.796.7 녹장균에 의한 시험Test by E. coli BlankBlank 6363 6060 5959 6.36.3 규산질 다공 Siliceous porous sieve 5959 2424 88 86.486.4

도 1은 본 발명에 따른 천연광물질을 이용한 건축자재의 규산질 다공체 제조공정을 도시한 공정도이다.1 is a process chart showing a siliceous porous body manufacturing process of building materials using natural minerals according to the present invention.

Claims (4)

천연광물질과 석회를 300 mesh 이상으로 분쇄하여 천연광물질 50~80 중량%와 석회 20~50중량%를 혼합하고, 식물성 및 동물성 기포제를 첨가하고, 균열방지와 부착성이 유지되도록 친환경 천연소재인 라텍스 혹은 해초물을 배합하여 혼합된 천연광물질을 요구되는 건축자재의 다공체에 따라 팽창시켜 발포, 건조, 조성하여 친환경 건축자재를 제조함을 특징으로 하는 규산질 천연광물질을 이용한 건축자재 제조방법.Natural mineral and lime are pulverized to 300 mesh or more to mix 50 to 80% by weight of natural mineral and 20 to 50% by weight of lime, add vegetable and animal foaming agents, and eco-friendly natural latex to prevent cracking and adhesion Or by mixing seaweeds to expand and expand the mixed natural minerals according to the porous material of the required building materials, and to foam, dry, and formulate them to produce eco-friendly building materials. 제 1항에 있어서, The method of claim 1, 상기 천연광물질은 맥반석, 흑운모, 거정석, 화강암, 석영, 장석으로 이루어지는 규산염광물 중에서 어느 하나를 선택적으로 사용함을 특징으로 하는 규산질 천연광물질을 이용한 건축자재 제조방법.The natural mineral is a building material manufacturing method using a siliceous natural mineral, characterized in that any one selected from the silicate mineral consisting of magnesite, biotite, macrorite, granite, quartz, feldspar. 제 1항에 있어서, The method of claim 1, 상기 천연광물질을 거푸집에 넣고 발포 팽창하여 케이크 모양으로 굳었을 때 꺼내 형상을 잘라 고압소독기 내에서 적정온도인 170~200℃, 10기압으로 양생함을 특징으로 하는 규산질 천연광물질을 이용한 건축자재 제조방법.Method of manufacturing building materials using siliceous natural minerals, characterized in that the natural minerals are put in a form and expanded and foamed to solidify into a cake shape, cut out, and cured at an appropriate temperature of 170-200 ° C. and 10 atm in a high-pressure sterilizer. . 제 1항에 있어서, The method of claim 1, 상기 식물성 및 동물성 기포제는 식물성 단백질과 동물성 단백질로 이루어짐을 특징으로 하는 규산질 천연광물질을 이용한 건축자재 제조방법.The vegetable and animal foaming agent manufacturing method using a siliceous natural mineral, characterized in that consisting of vegetable protein and animal protein.
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101540754B1 (en) * 2013-07-12 2015-07-31 에코힐링 주식회사 Natural Finishing Composition and Production Method Thereof
KR20150145410A (en) * 2014-06-19 2015-12-30 임복임 Exterior panels using a natural composition
KR20160057881A (en) * 2014-11-14 2016-05-24 임복임 An ornament for indoors having humidity control and anion release
KR20160066961A (en) * 2014-12-03 2016-06-13 임복임 Composition of Plaster for Expressing Surface Texture of Korean Traditional Paper

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR0152464B1 (en) * 1995-11-20 1998-10-15 김병곤 Process for the preparation of autoclaved lightweight concrete
DE19909077A1 (en) 1999-03-02 2000-09-14 Peter Niedner Mineral foam-like building and structural material and method for producing a mineral foam and device for carrying out the method
JP4331829B2 (en) 1999-07-02 2009-09-16 黒崎播磨株式会社 Cement-based fired plate-shaped building material

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101540754B1 (en) * 2013-07-12 2015-07-31 에코힐링 주식회사 Natural Finishing Composition and Production Method Thereof
KR20150145410A (en) * 2014-06-19 2015-12-30 임복임 Exterior panels using a natural composition
KR20160057881A (en) * 2014-11-14 2016-05-24 임복임 An ornament for indoors having humidity control and anion release
KR20160066961A (en) * 2014-12-03 2016-06-13 임복임 Composition of Plaster for Expressing Surface Texture of Korean Traditional Paper

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