KR20080095335A - Manufacturing method of nozzle of inkjet head - Google Patents

Manufacturing method of nozzle of inkjet head Download PDF

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Publication number
KR20080095335A
KR20080095335A KR1020070039613A KR20070039613A KR20080095335A KR 20080095335 A KR20080095335 A KR 20080095335A KR 1020070039613 A KR1020070039613 A KR 1020070039613A KR 20070039613 A KR20070039613 A KR 20070039613A KR 20080095335 A KR20080095335 A KR 20080095335A
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South Korea
Prior art keywords
nozzle
water repellent
water
inkjet head
ink
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KR1020070039613A
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Korean (ko)
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KR100897556B1 (en
Inventor
유영석
정재우
박창성
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삼성전기주식회사
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Priority to KR1020070039613A priority Critical patent/KR100897556B1/en
Publication of KR20080095335A publication Critical patent/KR20080095335A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet
    • B41J2/135Nozzles
    • B41J2/16Production of nozzles
    • B41J2/162Manufacturing of the nozzle plates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet
    • B41J2/135Nozzles
    • B41J2/14Structure thereof only for on-demand ink jet heads
    • B41J2/1433Structure of nozzle plates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet
    • B41J2/135Nozzles
    • B41J2/16Production of nozzles
    • B41J2/1621Manufacturing processes
    • B41J2/1623Manufacturing processes bonding and adhesion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet
    • B41J2/135Nozzles
    • B41J2/16Production of nozzles
    • B41J2/1621Manufacturing processes
    • B41J2/1626Manufacturing processes etching
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet
    • B41J2/135Nozzles
    • B41J2/16Production of nozzles
    • B41J2/1621Manufacturing processes
    • B41J2/164Manufacturing processes thin film formation

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Particle Formation And Scattering Control In Inkjet Printers (AREA)

Abstract

A method of manufacturing a nozzle of an ink-jet head is provided to smoothly form the meniscus of ink by depositing a water-repellent layer only on the nozzle surface of the ink-jet head with physical vapor deposition such as evaporation. A method of manufacturing a nozzle of an ink-jet head comprises a step(100) of preparing the ink-jet head structure in which a nozzle is punched on the nozzle surface; a step(110) of determining the deposition time in order to deposit a water-repellent material on the inside of the nozzle below the critical thickness to have water repellency; and a step(120) of depositing the water-repellent material on the ink-jet head structure for a predetermined deposition time by using physical vapor deposition having the directivity towards the nozzle surface.

Description

잉크젯 헤드의 노즐 제조방법{Manufacturing method of nozzle of inkjet head}Manufacturing method of nozzle of inkjet head

도 1, 도 2는 종래기술에 따른 발수층 제조공정을 나타낸 흐름도.1 and 2 is a flow chart showing a water repellent layer manufacturing process according to the prior art.

도 3은 잉크젯 헤드용 노즐에 발수층이 증착된 상태를 나타낸 단면도.3 is a cross-sectional view showing a state in which a water repellent layer is deposited on an inkjet head nozzle.

도 4는 본 발명의 바람직한 실시예에 따른 잉크젯 헤드의 노즐 제조방법을 나타낸 순서도.Figure 4 is a flow chart showing a nozzle manufacturing method of the ink jet head according to a preferred embodiment of the present invention.

도 5는 본 발명의 바람직한 실시예에 따른 증착공정을 나타낸 개요도.5 is a schematic view showing a deposition process according to a preferred embodiment of the present invention.

도 6은 본 발명의 바람직한 실시예에 따른 잉크젯 헤드의 노즐을 나타낸 단면도.6 is a cross-sectional view showing a nozzle of an ink jet head according to a preferred embodiment of the present invention.

<도면의 주요 부분에 대한 부호의 설명><Explanation of symbols for the main parts of the drawings>

1 : 잉크젯 헤드 3 : 소스1: inkjet head 3: source

120 : 노즐면 121 : 노즐의 안쪽120: nozzle surface 121: the inside of the nozzle

122 : 노즐 141 : 발수층122: nozzle 141: water repellent layer

본 발명은 잉크젯 헤드의 노즐 제조방법에 관한 것이다.The present invention relates to a method for producing a nozzle of an inkjet head.

산업용 및 프린터용으로 사용되고 있는 잉크젯 헤드에 있어서, 잉크는 액적의 형태로 분사되며 잉크젯 헤드의 인쇄 성능을 높이기 위해서는 잉크가 완전한 액적 형태로 안정하게 분사되어야 한다. 이를 위해서는 노즐 부위를 발수(Hydrophobicity) 처리하여 잉크의 매니스커스(Meniscus)가 원활히 형성이 되도록 해야 한다.In inkjet heads used in industrial and printer applications, ink is ejected in the form of droplets, and ink must be stably ejected in the form of complete droplets in order to increase the printing performance of the inkjet head. To this end, the nozzle area should be water-repelled (Hydrophobicity) so that the meniscus of the ink can be smoothly formed.

잉크젯 헤드의 노즐의 발수 처리를 위해 종래에는 전주 도금법에 의하여 노즐을 형성하는 방법과 마이크로 펀칭과 연마 공정에 의하여 노즐을 형성하는 방법이 사용되어 왔다. 이러한 방법들에 의하여 제조되는 노즐의 출구 부위는 잉크젯 헤드에서 분사되는 잉크 액적의 크기, 잉크의 분사 성능, 잉크 분사의 안정성과 연속 분사에 중요한 영향을 미치는 인자이다. 그러나, 전술한 방법들은 공정이 복잡하여 공정 조건을 관리하기 어렵고, 다양한 형상의 노즐에는 적용되지 못한다는 문제점이 있다.Conventionally, a method of forming a nozzle by electroplating and a method of forming a nozzle by micro punching and polishing processes have been used for the water repellent treatment of a nozzle of an inkjet head. The outlet portion of the nozzle manufactured by these methods is an important factor in the size of the ink droplets ejected from the inkjet head, the ink ejection performance, the ink ejection stability, and the continuous ejection. However, the above-described methods have a problem that the process is complicated and difficult to manage process conditions, and does not apply to nozzles of various shapes.

노즐의 표면이 발수성을 가지지 못하는 경우에는 잉크의 분사가 반복됨에 따라 노즐 표면이 젖게 되는 웨팅(wetting) 현상이 발생하게 된다. 이러한 웨팅 현상이 발생하면 토출되는 잉크가 노즐면에 젖어있는 잉크와 덩어리를 형성하게 되어 토출되는 잉크가 완전한 액적의 형태를 가지지 못한 채 흘러내리는 방식으로 분사되게 되며, 그 결과 인쇄상태가 나쁘고 잉크의 분사 후 형성되는 매니스커스도 불안정하게 된다. 즉, 잉크젯 헤드의 신뢰성을 확보하기 위해서는 노즐면을 발수 처리하는 것이 필수적이라 할 수 있다.If the surface of the nozzle does not have water repellency, wetting occurs that the surface of the nozzle becomes wet as the jet of ink is repeated. When such a wetting phenomenon occurs, the ejected ink forms lumps with the wet ink on the nozzle surface, and the ejected ink is ejected in such a manner that the ejected ink flows down without having a perfect droplet form. The meniscus formed after the injection is also unstable. In other words, in order to secure the reliability of the inkjet head, it is essential to water repellent the nozzle surface.

잉크젯 프린터 헤드의 노즐면을 반영구적으로 발수 처리하기 위해 종래에는 발수성 물질을 일정 조건의 전장이 걸린 도금조에서 도금처리하는 방법을 사용해 왔다. 발수성 물질로는 테플론계 물질이 주로 사용되며, 테플론계 물질 중 대표적인 것은 PTFE(Polytetrafluroethylene)이다. 이러한 PTFE를 사용하여 노즐면을 발수처리하기 위해서는 일정 조건의 전장이 걸린 도금조에서 PTFE 복합 도금 처리하는 방법이 사용된다.In order to semi-permanently regenerate the nozzle surface of the inkjet printer head, conventionally, a method of plating a water repellent material in a plating bath in which a predetermined length is applied is used. Teflon-based materials are mainly used as the water repellent material, and a typical one of the Teflon-based materials is PTFE (Polytetrafluroethylene). In order to use the PTFE for water repellent treatment of the nozzle surface, a PTFE composite plating process is used in a plating bath in which electric field is applied under a certain condition.

그러나, 이러한 복합 도금에 의한 발수처리 방법은 방향성이 없으므로 발수층이 형성되어야 할 노즐면뿐만 아니라 발수층이 형성되어서는 안 될 노즐의 안쪽까지 도금되어 발수층이 형성된다. 따라서 복합 도금법에 의하여 발수 처리를 하는 경우에는 노즐의 안쪽에 발수층이 형성되는 것을 방지하기 위한 전처리가 추가로 필요하게 된다.However, since the water repellent treatment method by the composite plating is not directed, the water repellent layer is formed by plating not only the nozzle surface on which the water repellent layer should be formed, but also the inside of the nozzle where the water repellent layer should not be formed. Therefore, when the water repellent treatment is performed by the composite plating method, a pretreatment for preventing the water repellent layer from forming inside the nozzle is further required.

종래에는, 도 1에 도시된 것과 같이, 노즐면에만 발수 처리가 되도록 하기 위해 노즐의 안쪽에 부도체로 절연막(12)을 형성한 후 발수층(14)을 도금함으로써 노즐의 안쪽에 발수층이 형성되지 않도록 하는 방법이 사용되었다. 이때 절연막(12)으로 사용되는 대표적인 물질은 포토레지스터이며, 도 1에 도시된 것과 같이 노즐면에 발수 처리를 하기 전에 먼저 노즐의 후면에 포토레지스터를 스크린 프린팅 등의 방법으로 도포하여 절연막(12)을 형성한 후, 일반적인 방법인 복합 도금 처리공정에 의하여 PTFE 등의 발수층(14)를 노즐의 표면에 형성하였다.Conventionally, as shown in Fig. 1, in order to make the water repellent treatment only on the nozzle surface, after forming the insulating film 12 with a non-conductor inside the nozzle, the water repellent layer 14 is plated to form a water repellent layer inside the nozzle. The method of avoiding this was used. At this time, a representative material used as the insulating film 12 is a photoresist, and as shown in FIG. 1, before the water repellent treatment is applied to the nozzle surface, the photoresist is first applied to the rear surface of the nozzle by a method such as screen printing. After the formation, the water repellent layer 14 such as PTFE was formed on the surface of the nozzle by a composite plating treatment step which is a general method.

또한, 도 2에 도시된 것과 같이, 노즐의 후면에 진공 증착법의 직진성을 이용하여 균일한 부도체 박막(32)을 형성하고 노즐 전면에 전체적으로 발수 물질을 도금하는 방법이 사용되었다. 즉, 도 2에 도시된 것과 같이 노즐에 발수처리를 하 기 전에 노즐의 후면에 진공 증착법에 의하여 부도체 박막(32)을 형성하고, 노즐면에 테플론계 발수 물질을 도금하여 발수층(34)을 형성하고, 노즐을 열처리하여 노즐의 발수처리를 완료하는 것이다.In addition, as shown in FIG. 2, a method of forming a uniform non-conductive thin film 32 on the back of the nozzle by using the straightness of vacuum deposition and plating the water repellent material on the entire surface of the nozzle was used. That is, as shown in FIG. 2, before the water repellent treatment is performed on the nozzle, the non-conductive thin film 32 is formed on the rear surface of the nozzle by vacuum deposition, and the Teflon-based water repellent material is plated on the nozzle surface to form the water repellent layer 34. It is formed, and the nozzle is heat treated to complete the water repellent treatment of the nozzle.

이와 같이 잉크젯 헤드의 노즐에 발수층을 형성하기 위하여 전술한 방법들이 사용되고 있으나 이러한 방법들로는 노즐 후면에 발수층이 증착되는 것을 완전히 방지하기 곤란하고, 모든 노즐을 균일한 깊이로 발수 처리하는 것이 어렵다. 이에 따라 발수 처리 후 액적 분사시 액적 크기가 균일하지 못하거나 반복 인쇄의 신뢰성이 저하되는 문제가 있다.As described above, the above-described methods are used to form the water repellent layer on the nozzle of the inkjet head. However, it is difficult to completely prevent the water repellent layer from being deposited on the back of the nozzle, and it is difficult to water repellent the nozzles with uniform depth. Accordingly, there is a problem that the droplet size is not uniform or the reliability of the repeated printing is lowered when the droplet is sprayed after the water repellent treatment.

본 발명은 방향성을 갖는 물리적 증착방법으로 잉크젯 헤드의 노즐면에만 선택적으로 발수층을 증착하여 공정을 단순화한 잉크젯 헤드의 노즐 제조방법을 제공하는 것이다.The present invention provides a nozzle manufacturing method of an ink jet head which simplifies the process by selectively depositing a water repellent layer only on the nozzle surface of the ink jet head by a directional physical vapor deposition method.

본 발명의 일 측면에 따르면, 노즐면에 노즐이 천공된 잉크젯 헤드 구조를 제공하는 단계, 및 노즐면을 향하여 방향성을 갖는 물리적 증착방법을 이용하여 잉크젯 헤드 구조에 소정의 증착시간 동안 발수물질을 증착하는 단계를 포함하되, 증착시간은 노즐의 안쪽에 증착된 발수물질이, 발수력을 가지는 임계두께 보다 얇게 증착되도록 결정되는 것을 특징으로 하는 잉크젯 헤드의 노즐 제조방법이 제공된다.According to an aspect of the present invention, by depositing a water-repellent material in the ink jet head structure for a predetermined deposition time using a step of providing an ink jet head structure in which the nozzle is perforated on the nozzle surface, and a physical vapor deposition method having a direction toward the nozzle surface Including the step of, the deposition time is provided a nozzle manufacturing method of the inkjet head, characterized in that the water-repellent material deposited inside the nozzle is determined to be deposited thinner than the critical thickness having a water repellent.

잉크젯 헤드 구조는 실리콘 기판을 식각하여 형성된 복수의 기판을 접합하여 제조될 수 있다. 증착방법은 이베포레이션(evaporation) 방법일 수 있다. 발수물질은 F계 또는 Si계 고분자 물질로 이루어지며, 임계두께는 발수물질의 재질에 상응하여 미리 설정된 값일 수 있으며, 예를 들면 40 옹스트롬일 수 있다.The inkjet head structure may be manufactured by bonding a plurality of substrates formed by etching a silicon substrate. The deposition method may be an evaporation method. The water repellent material may be formed of an F-based or Si-based polymer material, and the critical thickness may be a preset value corresponding to the material of the water repellent material, for example, 40 angstroms.

전술한 것 외의 다른 측면, 특징, 잇점이 이하의 도면, 특허청구범위 및 발명의 상세한 설명으로부터 명확해질 것이다.Other aspects, features, and advantages other than those described above will become apparent from the following drawings, claims, and detailed description of the invention.

이하, 본 발명에 따른 잉크젯 헤드의 노즐 제조방법의 바람직한 실시예를 첨부도면을 참조하여 상세히 설명하기로 하며, 첨부 도면을 참조하여 설명함에 있어, 동일하거나 대응하는 구성 요소는 동일한 도면번호를 부여하고 이에 대한 중복되는 설명은 생략하기로 한다.Hereinafter, a preferred embodiment of the nozzle manufacturing method of the inkjet head according to the present invention will be described in detail with reference to the accompanying drawings, in the following description with reference to the accompanying drawings, the same or corresponding components are given the same reference numerals and Duplicate description thereof will be omitted.

도 3은 잉크젯 헤드용 노즐에 발수층이 증착된 상태를 나타낸 단면도이고, 도 4는 본 발명의 바람직한 실시예에 따른 잉크젯 헤드의 노즐 제조방법을 나타낸 순서도이고, 도 5는 본 발명의 바람직한 실시예에 따른 증착공정을 나타낸 개요도이고, 도 6은 본 발명의 바람직한 실시예에 따른 잉크젯 헤드의 노즐을 나타낸 단면도이다. 도 5 및 도 6을 참조하면, 잉크젯 헤드(1), 소스(3), 노즐면(120), 노즐의 안쪽(121), 노즐(122), 발수층(141)이 도시되어 있다.3 is a cross-sectional view showing a state in which a water repellent layer is deposited on the nozzle for the ink jet head, Figure 4 is a flow chart showing a nozzle manufacturing method of the ink jet head according to a preferred embodiment of the present invention, Figure 5 is a preferred embodiment of the present invention Figure 6 is a schematic diagram showing a deposition process according to, Figure 6 is a cross-sectional view showing a nozzle of the ink jet head according to a preferred embodiment of the present invention. 5 and 6, an inkjet head 1, a source 3, a nozzle face 120, an inner side 121 of the nozzle, a nozzle 122, and a water repellent layer 141 are illustrated.

잉크젯 헤드용 노즐(122)의 발수층(141)은 도 3에 도시된 것과 같이 형성된다. 즉, 발수물질이 증착됨으로써 형성되는 발수층(141)이 노즐(122) 입구 및 노즐의 안쪽(121)으로 수 마이크로미터까지 적층되는 것이 보통이다. 본 실시예는 이베 포레이션(evaporation)과 같은 방향성을 가진 물리적 증착방법을 이용하여, 완성된 노즐면(120)에 발수층(141)을 증착함으로써 노즐(122)의 발수 처리를 용이하게 하고 노즐(122) 간 균일도를 향상시킴으로써 수율을 높인 것을 특징으로 한다.The water repellent layer 141 of the ink jet head nozzle 122 is formed as shown in FIG. That is, the water repellent layer 141 formed by depositing the water repellent material is usually stacked up to several micrometers by the nozzle 122 inlet and the inside 121 of the nozzle. The present embodiment facilitates the water repellent treatment of the nozzle 122 by depositing a water repellent layer 141 on the completed nozzle surface 120 using a physical vapor deposition method having an orientation such as evaporation. It is characterized by improving the yield by improving the uniformity between (122).

발수물질을 증착하여 발수층(141)을 형성하는 데에 있어서는 노즐면(120)에만, 또는 노즐면(120)으로부터 적당한 깊이까지만 선택적으로 발수층(141)이 코팅되도록 하는 것이 중요하다. 발수층(141)은 잉크젯 헤드(1) 구조를 형성한 이후에 형성되는 것이기 때문에, 포토리소그래피(photolithography) 공정이나 클리닝(cleaning) 공정 등이 진행되면 헤드 내부에 이물질이 들어갈 수 있어 헤드의 수율을 저하시키게 된다.In forming the water repellent layer 141 by depositing a water repellent material, it is important to selectively coat the water repellent layer 141 only on the nozzle face 120 or only to a suitable depth from the nozzle face 120. Since the water repellent layer 141 is formed after the inkjet head 1 structure is formed, foreign matter may enter the inside of the head when the photolithography process or the cleaning process is performed, thereby improving the yield of the head. Is degraded.

발수층(141)의 선택적 코팅에 있어서는, 첫째, 실리콘을 접합하여 제조된 헤드의 경우 접합 온도가 높아서 접합 공정 이후에 발수층(141) 증착이 가능하고, 둘째, 접합 이후 발수층(141) 증착 과정에서 습식(wet) 공정으로 인한 클리닝 공정이 추가로 필요하지 않아야 하며, 셋째, 발수층(141)이 증착된 위치가 정확히 노즐(122) 끝부분에 위치하고 또한 균일성을 유지해야 하고, 넷째, 충분한 발수력을 가진 발수물질을 사용하여 코팅해야 한다는 조건들을 만족시켜야 한다.In the selective coating of the water repellent layer 141, first, in the case of a head manufactured by bonding silicon, the bonding temperature is high, so that the water repellent layer 141 may be deposited after the bonding process, and second, the water repellent layer 141 is deposited after the bonding process. In the process, the cleaning process due to the wet (wet) process should not be additionally required. Third, the position where the water repellent layer 141 is deposited should be located exactly at the end of the nozzle 122 and also maintain the uniformity. The conditions for coating with sufficient water repellent should be met.

본 실시예에 따라, 위와 같은 조건들을 만족시키는 잉크젯 헤드용 노즐(122)을 제조하기 위해서는, 먼저 노즐면(120)에 노즐(122)이 천공된 잉크젯 헤드(1) 구조를 제공한다(100). 예를 들어 반도체 공정을 적용하여 실리콘 기판을 식각함으로써 잉크젯 헤드(1)를 제조할 경우, 챔버가 가공되는 상부 기판, 리스트릭터와 잉크유로가 가공되는 중간 기판, 노즐(122)이 천공되는 하부 기판을 제작하여 실리콘 다이렉트 본딩으로 접합함으로써 헤드 구조를 제조할 수 있다. 설계에 따라서는 보다 많은 수의 기판을 가공하여 접합하거나, 상, 하부 기판만을 가공하여 접합할 수도 있으며, 실리콘 기판이 아닌 스테인레스 등 메탈 기판을 가공하여 헤드구조를 형성할 수도 있음은 물론이다.According to the present embodiment, in order to manufacture the nozzle 122 for the inkjet head satisfying the above conditions, first, the nozzle surface 120 is provided with the inkjet head 1 structure in which the nozzle 122 is perforated (100). . For example, when the inkjet head 1 is manufactured by etching a silicon substrate using a semiconductor process, an upper substrate on which the chamber is processed, an intermediate substrate on which the restrictor and the ink flow path are processed, and a lower substrate on which the nozzle 122 is drilled The head structure can be manufactured by fabricating and bonding to silicon direct bonding. Depending on the design, a larger number of substrates may be processed and bonded, or only upper and lower substrates may be processed and bonded. Alternatively, a head structure may be formed by processing a metal substrate such as stainless rather than a silicon substrate.

다음으로, 잉크젯 헤드(1)의 노즐면(120)을 향하여, 이베포레이션 등 방향성을 갖는 물리적 증착방법으로 발수물질을 증착하여 발수층(141)을 형성한다(120). 즉, 잉크젯 헤드(1)의 구조가 완성된 상태에서 F계나 Si계의 발수물질을 증착하는 것이다. 도 5는 이베포레이션에 의한 증착공정을 나타낸 모식도이다.Next, the water repellent layer 141 is formed by depositing a water repellent material toward the nozzle surface 120 of the inkjet head 1 by a physical vapor deposition method such as evaporation. That is, the F- or Si-based water repellent material is deposited in a state where the structure of the inkjet head 1 is completed. 5 is a schematic diagram showing a deposition process by evaporation.

이베포레이션 방식은 물리적 증착 방법의 하나로서, 증착될 물질을 소스(Source)(3)에 담아서 진공상태에서 증발시켜 피증착체인 헤드의 노즐면(120)에 증착되도록 하는 방법이다. 일반적으로 물리적 증착방법은 화학적 증착방법(CVD, Chemical Vapor Deposition)과 달리 스텝 커버리지(step coverage)가 좋지 않다. 스텝 커버리지란 각종 박막이 코팅될 때 평평한 부분에 대한 경사진 단차(step)부분의 코팅된 정도의 비율을 지칭하며, 일반적인 반도체 공정에서는 스텝 커버리지를 높이기 위하여 화학적 증착방법이 적용되는 실정이다. The evaporation method is a method of physical vapor deposition, in which a material to be deposited is contained in a source 3 and evaporated in a vacuum so as to be deposited on the nozzle face 120 of the head to be deposited. In general, the physical vapor deposition method has a poor step coverage, unlike chemical vapor deposition (CVD). Step coverage refers to the ratio of the coated degree of the inclined step portion to the flat portion when various thin films are coated, and in a general semiconductor process, a chemical vapor deposition method is applied to increase the step coverage.

그러나, 본 실시예에서는 노즐면(120)에만 선택적으로 발수층(141)이 코팅되도록 하기 위하여 스텝 커버리지가 좋지 않은 물리적 증착방법, 예를 들면 이베포레이션 방식을 적용하였다. 이와 같이 물리적 증착 방법을 사용하면 도 6에 도시된 것과 같이 소스(3)에 대향하는 부분, 즉 노즐면(120)에는 발수층(141)이 균일하게 증착되는 반면, 노즐의 안쪽(121)에는 노즐면(120)만큼 발수층(141)이 증착되지 않 은 것을 볼 수 있다. 이와 같이 물리적 증착방법의 스텝 커버리지 특성을 이용하여 본 실시예에서는 노즐면(120)에만 발수층(141)이 증착되고 노즐의 안쪽(121)에는 발수층(141)이 증착되지 않도록 한 것이다.However, in the present embodiment, in order to selectively coat the water repellent layer 141 only on the nozzle surface 120, a physical vapor deposition method having a poor step coverage, for example, an evaporation method, is applied. When the physical vapor deposition method is used, as shown in FIG. 6, the water repellent layer 141 is uniformly deposited on the portion facing the source 3, that is, the nozzle surface 120, while the inside 121 of the nozzle is not formed. It can be seen that the water repellent layer 141 is not deposited as much as the nozzle surface 120. As described above, the water repellent layer 141 is deposited only on the nozzle surface 120 and the water repellent layer 141 is not deposited on the inside 121 of the nozzle using the step coverage characteristic of the physical vapor deposition method.

이베포레이션으로 일정 시간동안 발수물질을 증착하게 되면, 노즐면(120)에 소정 두께의 발수물질이 증착되어 발수력을 가지게 되며, 이로써 발수층(141)이 형성되게 된다. 따라서, 본 실시예에 따라 노즐면(120)에만 선택적으로 발수층(141)이 증착되도록 하는 것은, 노즐면(120)에만 발수물질이 증착되어 발수층(141)으로서 기능하도록 하는 것뿐만 아니라, 노즐의 안쪽(121)에 발수물질이 증착되더라도 발수력을 가질 수 있는 임계두께 보다 얇게 증착되도록 조절(110)하는 것까지 포함하는 개념이다. 즉, 이베포레이션 시간을 조절하여 노즐면(120)에는 임계두께 이상의 발수물질이 증착되도록 하고 노즐의 안쪽(121)에는 발수물질이 증착되지 않거나, 증착되더라도 임계두께보다 얇도록 하는 것이다.When the water repellent material is deposited for a predetermined time by evaporation, a water repellent material having a predetermined thickness is deposited on the nozzle surface 120 to have water repellency, thereby forming a water repellent layer 141. Therefore, according to the present embodiment, selectively depositing the water repellent layer 141 only on the nozzle surface 120 not only causes the water repellent material to be deposited on the nozzle surface 120 to function as the water repellent layer 141. Even if the water repellent material is deposited on the inside 121 of the nozzle, the concept includes including adjusting 110 to be thinner than a critical thickness that may have water repellency. That is, by controlling the evaporation time, the water repellent material is deposited on the nozzle surface 120 or more above the critical thickness, and the water repellent material is not deposited on the inside 121 of the nozzle or thinner than the critical thickness even when deposited.

예를 들어, 발수물질로서 F나 Si이 함유된 고분자 물질을 크루서블(crucible)이나 이빔(e-beam)으로 가열되는 도가니에 수용하고, 10-6 torr 이상의 높은 진공 상태에서 증발시키면 발수물질이 노즐면(120)에 증착된다. F계 또는 Si계 고분자 물질은 최소 40 옹스트롬 이상의 두께에서 발수력을 가진다고 할 때, 이베포레이션 시간을 조절하여 노즐면(120)에 적층되는 발수물질의 증착 두께를 40 옹스트롬으로 제어하게 되면, 노즐의 안쪽(121)에 발수물질이 증착되지 않도록 하거나, 발수물질이 증착되더라도 발수성을 가지지 않도록 할 수 있다.For example, a polymer material containing F or Si as a water repellent material is accommodated in a crucible heated by crucible or e-beam and evaporated in a high vacuum of 10 -6 torr or higher to obtain a water repellent material. It is deposited on the nozzle face 120. When the F- or Si-based polymer material has water repellency at a thickness of at least 40 angstroms or more, when the evaporation time is controlled to control the deposition thickness of the water-repellent material deposited on the nozzle surface 120 to 40 angstroms, the nozzle It is possible to prevent the water repellent material is deposited on the inner 121 of, or even if the water repellent material is deposited.

이로써, 잉크젯 헤드(1)의 노즐면(120)에만 선택적으로 발수층(141)이 형성되도록 할 수 있게 된다. 전술한 예에서 발수물질이 발수성을 갖게 되는 두께, 즉 임계두께는 발수물질의 재질에 따라 달라질 수 있음은 물론이다.As a result, the water repellent layer 141 may be selectively formed only on the nozzle surface 120 of the inkjet head 1. In the above example, the thickness of the water repellent material, that is, the critical thickness, may vary depending on the material of the water repellent material.

전술한 실시예 외의 많은 실시예들이 본 발명의 특허청구범위 내에 존재한다.Many embodiments other than the above-described embodiments are within the scope of the claims of the present invention.

상술한 바와 같이 본 발명의 바람직한 실시예에 따르면, 이베포레이션(Evaporation) 등 스텝 커버리지(step coverage) 효과가 낮은 방향성을 갖는 물리적 증착방법으로 잉크젯 헤드의 발수층을 증착함으로써 노즐면에만 선택적으로 발수층이 증착되도록 할 수 있으며, 우수한 발수(Hydrophobicity) 처리가 가능하여 잉크의 매니스커스(Meniscus) 형성을 원활하게 할 수 있다.As described above, according to a preferred embodiment of the present invention, by selectively depositing the water repellent layer of the inkjet head by a physical vapor deposition method having a low directional step coverage effect such as evaporation (evaporation) to selectively repel water The layer may be deposited, and excellent hydrophobicity treatment may be performed to facilitate the meniscus formation of the ink.

또한, 선택적인 발수층 증착을 위하여 종래에 사용된 포토리소그래피(Photo lithography) 방식과 여러 단계의 패터닝(patterning) 공정이 생략될 수 있어 공정시간과 비용이 감소하고, 여러 가지 화학 액체 속에 담가서 작업하는 습식(wet) 공정이 생략되므로 노즐의 안쪽으로 여러 가지 액체가 유입되어 불필요한 클리닝(cleaning) 공정이 추가되는 것을 방지할 수 있다.In addition, the conventional photolithography method and the multi-step patterning process can be omitted for selective water repellent layer deposition, thereby reducing the processing time and cost, and working in various chemical liquids. Since the wet process is omitted, various liquids can be introduced into the nozzle to prevent unnecessary cleaning processes from being added.

Claims (5)

노즐면에 노즐이 천공된 잉크젯 헤드 구조를 제공하는 단계; 및Providing an inkjet head structure in which the nozzle is perforated on the nozzle face; And 상기 노즐면을 향하여 방향성을 갖는 물리적 증착방법을 이용하여 상기 잉크젯 헤드 구조에 소정의 증착시간 동안 발수물질을 증착하는 단계를 포함하되,And depositing a water-repellent material on the inkjet head structure for a predetermined deposition time by using a physical vapor deposition method having a direction toward the nozzle surface. 상기 증착시간은 상기 노즐의 안쪽에 증착된 발수물질이, 발수력을 가지는 임계두께 보다 얇게 증착되도록 결정되는 것을 특징으로 하는 잉크젯 헤드의 노즐 제조방법.Wherein the deposition time is determined so that the water repellent material deposited inside the nozzle is deposited to be thinner than a critical thickness having water repellency. 제1항에 있어서,The method of claim 1, 상기 잉크젯 헤드 구조는 실리콘 기판을 식각하여 형성된 복수의 기판을 접합하여 제조되는 것을 특징으로 하는 잉크젯 헤드의 노즐 제조방법.The inkjet head structure is a nozzle manufacturing method of the inkjet head, characterized in that the manufacturing by bonding a plurality of substrates formed by etching the silicon substrate. 제1항에 있어서,The method of claim 1, 상기 증착방법은 이베포레이션(evaporation) 방법인 것을 특징으로 하는 잉크젯 헤드의 노즐 제조방법.The deposition method is a nozzle manufacturing method of the ink jet head, characterized in that the evaporation (evaporation) method. 제1항에 있어서,The method of claim 1, 상기 발수물질은 F계 또는 Si계 고분자 물질로 이루어지며, 상기 임계두께는 상기 발수물질의 재질에 상응하여 미리 설정된 값인 것을 특징으로 하는 잉크젯 헤드의 노즐 제조방법.The water-repellent material is made of an F-based or Si-based polymer material, the critical thickness is a nozzle manufacturing method of the inkjet head, characterized in that the preset value corresponding to the material of the water-repellent material. 제1항에 있어서,The method of claim 1, 상기 임계두께는 40 옹스트롬인 것을 특징으로 하는 잉크젯 헤드의 노즐 제조방법.And the critical thickness is 40 angstroms.
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