KR20070025614A - Manufacturing method of activated minerals from the deep sea water and the deep sea rock floor water - Google Patents

Abstract

A method for manufacturing activated minerals from deep sea water or deep sea rock floor water is provided to produce uniform activated minerals compared with natural activated minerals. A deep sea water or deep sea rock floor water is collected to be heated at a temperature of 20-30 degrees. The deep sea water or deep sea rock floor water is filtered through sand filtering, micro filtering, and ultra filtering. A first pH of the deep sea water or deep sea rock floor water is adjusted into weak acid of 4.5-6.5. A salt water is concentrated in a reverse osmosis filtering process. The concentrated salt water is filtered in a nano filtering process for concentrating divalent minerals. The concentrated mineral water is neutralized. The neutralized concentrated mineral water is evaporated and concentrated. Magnetized and activated minerals are generated from the evaporated and concentrated mineral water and salty water discharged from a table salt factory.

Description

Manufacturing method of activated minerals from the deep sea water and the deep sea rock floor water}

1 is a process chart for preparing active minerals by nanofiltration after reverse osmosis filtration from deep sea water or deep sea bedrock.

Figure 2 is a process chart for producing active minerals by nanofiltration from deep seawater or deep sea bedrock

3 is a process chart for producing activated minerals by neutralization, evaporative concentration, magnetization and active mineral generation reaction and magnetization by the process of evaporative concentration by air in the atmosphere.

Figure 4 is a process diagram for producing active minerals by neutralization, evaporation concentration, magnetization and active mineral generation reaction, magnetization by the process of evaporative concentration in the evaporation tower for supplying the heating air

5 is a precipitation rate of various salts according to the change in specific gravity of seawater at 35 ℃

6 is a precipitation rate of various salts according to the change in specific gravity of seawater at 80 ℃

<Explanation of symbols for main parts of drawing>

1: Chinese Tanker 2: Chinese Tanker

3: concentrated mineral water transfer pump 4: concentration tank

5: Thickener Lake 6: Evaporation Tower

7: Fan Nozzle 8: Spray Nozzle

9: concentrated mineral water storage tank 10: concentrated mineral water return pump

11: Magnetization and active mineral production reactor

12: Magnetization and Active Mineral Production Reactor Agitator

13: magnetizer circulation pump 14: magnetizer

15: Evaporation tower 16: Demister supplying heated air

17: Burner 18: Blower

19: Filter M: Motor

N: North Pole S: South Pole

pHIS: pH indicating switch

BIS: Baume indicating switch

The present invention is to collect the deep seawater (sea marine deep seawater) or deep sea bed rock water of 200m or less depth sand (sand filter), microfiltration, ultrafiltration (Ultra filter) After removing the suspended solids (SS) in water by adjusting the pH to 4.5-6.5, the concentrated brine by RO filter was subjected to nano-filtration through nanofiltration. The present invention relates to a method of producing active minerals by neutralizing concentrated mineral water with concentrated components and injecting and magnetizing organic acids that produce mineral complex salts into the brine discharged from the salt production process.

Table 1 Analysis table of deep seawater and surface seawater

            Item   Deep ocean water     Surface seawater General item Water temperature （℃） 9 16.5-24.0 pH 7.80 8.15 DO dissolved oxygen (mg / L) 7.80 8.91 TOC Organic Carbon (mg / L) 0.962 1.780 Soluble evaporation residue (mg / L) 40750 37590 M-alkalido (mg / L) 114.7 110.5 Major element Cℓ chloride ion (wt%) 2.237 2.192 Na sodium (wt%) 1.080 1.030 Mg magnesium (wt%) 0.130 0.131 Ca Calcium (mg / L) 456 441 K potassium (mg / L) 414 399 Br cancel (mg / L) 68.8 68.1 Sr Strontium (mg / L) 7.77 7.61 B boron (mg / L) 4.44 4.48 Ba barium (mg / L) 0.044 0.025 F Fluorine (mg / L) 0.53 0.56 SO₄ (mg / L) 2833 2627 Nutrients NH₄ ammonia nitrogen (mg / L) 0.05 0.03 NO₃Nitrate Nitrate (mg / L) 1.158 0.081 PO₄ Phosphate (mg / L) 0.177 0.028 Si silicon (mg / L) 1.89 0.32 Trace elements Pb lead (μg / L) 0.102 0.087 Cd Cadmium (μg / L) 0.028 0.008 Cu copper (μg / L) 0.153 0.272 Fe iron (μg / L) 0.217 0.355 Mn Manganese (μg / L) 0.265 0.313 Ni nickel (μg / L) 0.387 0.496 Zn Zinc (μg / L) 0.624 0.452 As Arsenic (μg / L) 1.051 0.440 Mo molybdenum (μg / L) 5.095 5.555 Number of bacteria Viable count (pcs / ml) 10² 10³ to 10⁴

※ The above analysis table analyzes the deep seawater and surface seawater of 374m below the east side of Murodo Lighthouse in Kouchi Prefecture, Japan.

Deep seawater and surface seawater with a depth of 200 m or less have similar concentrations of salinity (NaCl) and most mineral concentrations as shown in Table 1, "Analysis Table of Deep Sea Water and Surface Seawater", but nutrients (nitrogen nitrogen, Phosphoric acid, silicon), viable cell number, and water temperature are significantly different.

The water temperature of deep ocean water is almost constant throughout the year, and the surface water temperature of sea surface water is 16 ℃ ~ 28 ℃, but the water temperature of 374m deep water is 9 ℃, which shows low temperature stability and is low in plankton, microorganisms, especially pathogenic bacteria. There is cleanliness.

Deep seawater was not detected in the test of 10 kinds of bacteria including pathogenic Escherichia coli and pathogenic virus. The total viable count is clean water from 1/10 to 100% of surface water.

In addition, deep sea water contains about 5 to 10 times more inorganic nutrients than surface water, and contains more than 70 kinds of minerals, which are necessary for humans. Deep mineral water, which has a very small amount, has a deep relationship to human health, such as copper and zinc, which are essential trace elements.

In the case of seabed rocks (also referred to as seawater, 海洋 深層 巖 盤 水 or 海底 深層 化石 海水), excavated less than 200m of rock in the island or coastal areas, the seawater penetrates into the rock or soil. vary slightly depending on the rock and the aqueous phase of the soil, but Na ⁺ ion, Mg ^{2 +} ions and the like while as substituted and rock or calcium (Ca) of a soil concentration of Na ⁺ ions and Mg ^{2 +} ions is slightly away Ca ^{2 +} ions Except for this increased phenomenon, it has almost the same characteristics as the deep seawater, and the component analysis of mineral content of 260m undersea seawater in Youngdo, Busan is shown in Table 2.

Table 2 Analysis Table of Mineral Contents of 260m Subsea Rock and Water

      ingredient     Undersea rock    K (potassium) (mg / L)         175.5    Ca (calcium) (mg / L)       11185    Na (sodium) (mg / ℓ)        1827    Mg (magnesium) (mg / ℓ)         518.4

Generally, the characteristics of deep seawater and deep sea bedrock refers to low temperature safety, cleanliness, eutrophicity, mineral properties, and maturation. The characteristics of the active minerals are as follows.

1. It is very clean and contains various minerals necessary for the growth of animals and plants.

The deep sea contains various minerals necessary for the growth of animals and plants, and it is clean and free of contaminants such as domestic wastewater and environmental hormones, with little or no pathogenic microorganisms in low temperature and high pressure without sunlight being transmitted. 물) It is water in a state.

2. Deep ocean waters and deep sea bedrock can produce high-quality active minerals in a sanitary manner, with an infinite amount of mineral water and river waters.

3. It has been shown to activate the proliferation of macrophage.

4. Since most minerals are dissolved in water (soluble minerals), they can be easily prepared as active minerals.

5. Compared with surface water, deep water has a large amount of divalent trivalent iron (II 價-三 價 鐵) while repeating the oxidation-reduction reaction, so that the treatment efficiency is improved when the magnetization treatment is performed.

Therefore, deep ocean waters or deep sea bedrock can produce high quality active minerals by only removing salts properly.

The prior art of producing active minerals from deep ocean waters and deep sea bedrock has not been investigated, and Unzen volcanoes of Shimahara Peninsula in Nagasaki Prefecture, Japan, where active minerals are excavated from nature. Marine diatoms, plankton, animal and plant fluids in volcanic eruptions of Dacite, magnetized divalent and trivalent iron (Magnetite) is mixed and deposited to pH 2 ~ 3, and pulvic acid (Fulvic acid) in the corrosive substance is induced in the free state, and is excavated in the form of chelate-type fulbrate mineral complex salt. There is a serious problem in performance and content depending on the location and location, and mining is restricted due to the wetland protection policy of the administrative authorities. , And in the circumstances that it uses fairly expensive imports like water conditioner, microbial culture.

In the present invention, the Bomedo (° Be) of the Baume's hydrometer representing the specific gravity of the seawater is expressed as a numerical value of the scale when the Bomeviometer floated on the liquid to measure the specific gravity of the liquid, Heavy bomedoes for heavy liquids and light bomedoes for light liquids that are lighter than the specific gravity of water, among which heavy liquids are pure water. It is ° Be, 15% saline is 15 ° Be, and the division is divided into 15 equal parts. For the liquid solution, 10% saline is 0 ° Be, and pure water is 10 ° Be. The scale is divided into 15 equal parts between them, and BOME (° Be) is widely used as a measure of concentration because seawater approximates salt concentration (wt%).

The relationship between the Bume (° Be) and the specific gravity (d) of the liquid is

For heavy media that has a specific gravity of liquid greater than that of water

d = 144.3 / (144.3-Be). … … … … … … … … … … … … … … … … … ①

In the case of an alarm field where the specific gravity of the liquid is lower than the specific gravity of the water

d = 144.3 / (134.3 + Be)... … … … … … … … … … … … … … … … … … ②

It is an object of the present invention to provide a method for artificially manufacturing active minerals from deep ocean water or deep sea bedrock to solve the above problems.

In order to achieve the above object, the present invention is to take the deep seawater or seabed deep seawater with a depth of 200m or less and warm it to 20 ~ 30 ℃, sand filtration-microfiltration-ultrafiltration pretreatment by ultrafiltration, l primary pH Adjusting to weak acidity of 4.5 to 6.5, concentrating the brine in the reverse osmosis filtration process, concentrating the brine in the reverse osmosis filtration process in the nanofiltration process, concentrating the divalent or more minerals, nano Neutralizing the concentrated mineral water concentrated in the filtration process. Evaporating and concentrating the neutralized concentrated mineral water, magnetizing and generating active minerals from the evaporated and concentrated mineral water and salt water discharged from the salt factory, and packing and inspecting the active mineral.

Although activated minerals are minerals that can be dissolved in water in minerals, some scholars believe that the minerals dissolved in water react with organic acids to form chelated organic acid mineral complex salts. Says minerals.

Deep seawater below 200m or deep sea bedrock do not penetrate sunlight and photosynthesis does not occur, and it is low temperature and has low microbial concentration, high concentration of nutrients such as nitrate, phosphate, and silicon, and various minerals. Since the component is dissolved in water, it has the property of making active mineral easily.

Hereinafter, the contents of the present invention will be described in detail with reference to the drawings.

In Figure 1, the deep sea water intake method is to take the pipe down to 200m or less from the bottom of the ship, or to install the pipe to the seabed depth of 200m or less, with a pump (Pump), or to install a pipe to the seabed 200m or less Intake wells are installed below sea level and are ingested according to the siphon principle.

In case of infiltration of deep sea bedrock, there is a possibility that the surface water contaminated by the intake well may flow, so the piping of the well should be installed up to 200m below the seabed so that the inlet well should not be introduced.

Deep seawater or seabed deep seawater collected in the sump is warmed to 20 ~ 30 ℃ because of its low viscosity and high filtration efficiency.

The warming method may be supplied with heat from a boiler, or may use sea surface water in summer.

For warmed deep seawater or deep seabed rock, sand filtration (Sand filter), micro filtration, and ultra filtration alone or a combination of two or more of them (Nano filter and Reverse Osmosis filter) is a pretreatment filtration process to remove suspended solids (SS) that can cause fouling.

At this time, the filtration pressure is determined in consideration of the pressure loss of the filter and the pressure loss of the pipe according to the operating conditions.In the case of sand filtration, the filtration speed is 6-10 m / hour, and the effective diameter of the filter sand Is 0.3 to 0.45 mm, the uniformity factor is 2.0 or less, and the thickness of a fibrous layer is 0.5 to 1.0 m.

Microfiltration and ultrafiltration are independent of the type of filtration membrane, and the supply pressure is determined in consideration of the filtration rate and the pressure loss according to the specifications of the vendor.

In the pretreatment filtration process, the deep seawater or subsea deep rock water from which suspended solids have been removed is sent to the pH adjustment process to adjust the pH to 4.5-6.5 so that no scale is produced in the nanofiltration membrane or the reverse osmosis membrane. As an adjusting agent, 5-10 wt% hydrochloric acid (HCl) aqueous solution is used in an inorganic acid.

The pH adjustment method is performed by injecting a pH adjuster into the pre-filtered deep seawater or the deep sea bedrock while stirring the agitation time (retention time) for 15 to 30 minutes with a propeller agitator of 180 to 360 RPM (rotational speed). Adjust to 4.5 ~ 6.5 and send to reverse osmosis filtration process.

Membrane modules of the nano filter and reverse osmosis filter used are tubular, hollow fiber, spiral, and spiral. It does not matter which form is used, such as wound or plate and frame, and the material of the film is not particularly limited.

When the pH is adjusted to 4.5 to 6.5 in the pH adjustment process and supplied to the reverse osmosis filtration process, the operating pressure is supplied to the filtration membrane at 50 to 60 atmospheres (atm), and the membrane permeation amount is 0.5 to 0.8 ㎥ / m2 When it is operated to work, the salinity is removed in the range of 99.0 ~ 99.85wt%, demineralized salt is sent to the drinking water manufacturing process, and the brine is sent to the nanofiltration process.

In the nano filtration process, the supply pressure is 15 to 25 atmospheres so that monovalent salts such as NaCl and KCl in brine and more than 90 wt% of divalent or more minerals such as CaCO ₃ , CaSO ₄ , MgCl ₂ , and MgSO ₄ are separated. Atm, and in the case of spiral, the membrane permeation amount is 0.7 to 1.4 m 3 / m 2 · day, where the membrane permeation amount is 80 to 90% of the inflow.

In the nanofiltration process, concentrated mineral water concentrated with divalent or more minerals such as CaCO ₃ , CaSO ₄ , MgCl ₂ , and MgSO ₄ is sent to the neutralization process, and a large amount of NaCl, a demineralized brine from which the divalent or higher minerals are removed, is removed. The brine contained is sent to the salt production process.

And in the pH adjustment process after pre-treatment as shown in Figure 2 sent the deep seawater or seabed deep rock water adjusted to pH 4.5 ~ 6.5 to the nanofiltration process, the demineralized brine is sent to reverse osmosis filtration process to send the demineralized water to the drinking water production process, Concentrated brine is sent to the salt production process, while concentrated mineral water from which monovalent salts such as NaCl and KCl are removed from the nanofiltration process is sent to the neutralization process.

When concentrated mineral water discharged from the nanofiltration process flows into the neutralization tank (1) of the neutralization process, neutralization is carried out by supplying one kind of aqueous solution among Ca (OH) ₂ , CaO, NaOH, NaHCO ₃ and Na ₂ CO _{3 as a} neutralizing agent. While stirring with a co-stirrer (2), the pH was neutralized in the range of 6.5 to 7.5, and the concentrated mineral water transfer pump (3) was fed to the upper portion of the evaporation tower (6) of the evaporation and concentration process together with the concentrated mineral water return water. And spray through a spray nozzle (8).

As in the pH adjustment process, the neutralization process is also carried out with a neutralizer while stirring with a propeller stirrer of 180 to 360 RPM (rotational speed) for 15 to 30 minutes to adjust the pH to 6.5 to 7.5. .

When the neutralized concentrated mineral water is sprayed together with the concentrated mineral water return water through the spray nozzle 8 at the top of the evaporation tower 6 in the evaporation and concentration process, the evaporation tower fan 7 installed at the top of the evaporation tower 8 is used. The concentrated mineral water is in countercurrent contact with the air while the air in the air is sucked out from the bottom of the evaporation tower 8 and discharged to the upper portion.

When the solids (CaCO ₃ , CaSO ₄ ..., Etc.) precipitated as the water is evaporated and concentrated in the evaporation tower 6 are precipitated to the bottom of the concentration tank 4, the cone bottom of the concentration tank 4 by the concentration tank rake 5. Condensate into the concentrated and concentrated mineral storage tank (9) and return it to the concentrated mineral storage tank (9). The short-selling weight ratio is conveyed to the upper part of the evaporation tower 6 by the pump 10, and the "deposition rate of various salts according to the change of specific gravity of seawater" in FIGS. 5 and 6 and "deposition rate in evaporative concentration of seawater" of Table 3 As can be seen from more than 30 bome (Be) MgSO ₄ , MgCl ₂ , KCl… Since the precipitates in large quantities, the magneto- and active mineral reaction tanks of the magnetization and active mineral reaction processes are operated by operating the solenoid valve by the BME (Baume indicating switch) installed in the concentrated mineral water reservoir (9). Send to).

The shape and structure of the evaporation tower 6 is the same as the structure of the cooling tower for cooling the cooling water of a general industrial factory, the concentration tank 4 is the same structure as the concentration tank used for sewage and wastewater treatment, the material of the evaporation tower (6) Silver flameproof material is used.

The thickening tank (4) and concentrated mineral water storage tank (9) are made of reinforced concrete with epoxy coating or titanium or SUS-316L or steel plate with FRP resin or epoxy resin lining or coating. .

The diameter of the concentration tank 4 is in the range of 15-30 m 3 / m 3 · day of surface water load of the water, the depth is 3-4 m, the slope of the bottom bottom is a gradient of 1.5 / 10 to 2.5 / 10 range 설계) designed to be.

                  Table 3 Precipitation Rate (g / ℓ) in Seawater Evaporative Concentration

Specific gravity (° Be)  Volume (cc) Fe ₂ O ₃ CaCO ₃ CaSO ₄ MgSO ₄ MgCℓ ₂ NaCℓ MgBr ₂ KCℓ 3.4 1,000 7.1 533 0.0030 0.0642 11.5 316 Trace 14.0 245 Trace 16.75 190 0.0530 0.5600 20.60 145.5 0.5020 22.00 131.0 0.1600 25.00 112.0 0.1508 26.25 95.0 0.1476 0.0040 0.0078 3.2614 27.0 64.0 0.1440 0.0130 0.0356 9.6500 28.50 39.0 0.0700 0.0260 0.0437 7.8960 0.0728 32.30 30.0 0.0144 0.0174 0.0150 2.6240 0.0358 32.40 23.0 0.0254 0.0240 2.2720 0.0518 35.0 16.2 0.5382 0.0274 1.4040 0.0620 Total precipitation   - 0.0030 0.1172 1.7488 0.6240 0.1535 27.1074 0.2224 Remaining water   - 1.8548 3.1640 0.5885 0.3300 0.5335 Sum   - 0.0030 0.1172 1.7488 2.4788 3.3175 27.6959 0.5524 0.5335

The concentrated mineral water storage tank 9 has a residence time of 30 to 60 minutes, and the capacity of the concentrated mineral water return pump is about 2 to 4 times the amount of the inflow water (the flow rate of the neutralized concentrated mineral water). Let flow rate.

In addition, the process of preparing active minerals by neutralization, evaporative concentration, magnetization and active mineral generation reaction and magnetization by the process of evaporative concentration by air in the air of FIG. In the case of i) or rainy season, since evaporation and concentration hardly occur, evaporation is carried out to evaporation tower 15 for supplying heating air instead of evaporation tower 6 for supplying air in the atmosphere and evaporation. Water is evaporated and concentrated by the process of producing active minerals by neutralization, evaporative concentration, magnetization and active mineral generation reaction and magnetization.

When the evaporation is concentrated in the evaporation tower 15 for supplying the heated air, the neutralized concentrated mineral water and the concentrated mineral water return water are sent to the upper part of the evaporation tower 15 for supplying the heated air together with the compressed air and spray nozzles ( When the hot air heated by the burner 17 is sprayed through the air supplied by the blower 18 while being sprayed through 18) and is supplied downward through the filter 19, the water evaporated while being countercurrently in contact with the hot air air. Silver is released to the atmosphere through a demister (16), and the evaporated and concentrated water is sent to the concentration tank (4), and when the precipitated salt precipitates, the salt is collected by the salt concentration lake (5) and intermittently magnetized. And the concentrated mineral water discharged to the active mineral production reaction tank (11), and the upstream of the concentrated tank (4) is sent to the concentrated mineral storage tank (9) and returned to the upper part of the evaporation tower (6) by the concentrated mineral water return pump (10). While the short-selling weight ratio 6 As shown in the "deposition rate of various salts according to the change of specific gravity of seawater" and "deposition rate table in evaporative concentration of seawater" of Table 3, when MgSO ₄ , MgCl ₂ , KCl. The precipitates in large quantities are sent to the magnetization and active mineral reaction tank 11 of the magnetization and active mineral reaction process by the operation of the electron valve by the BME (Baume indicating switch) installed in the concentrated mineral water storage tank 9.

As the material of the evaporation tower 15 for supplying the heating air, it is preferable to use titanium or SUS-316L, which is flame-resistant. However, in consideration of economic efficiency, FRP (Fiber reinforced plastics) resin or epoxy resin is used on the steel sheet. You can also use lining or coating of epoxy resin.

In the part nozzle 8 of the evaporation tower 15 for supplying the heated air, the mass ratio of air and liquid at a pressure of 1 to 6 atm on the upstream side of the compressed air to improve spraying efficiency. Is supplied at a ratio of 1.1 to 1.2.

The heating of the hot air air supplied from the blower 18 may use heavy oil or light oil in the burner 17, but may use natural gas (LNG) or liquid petroleum gas (LPG). The temperature of the wet air discharged to the atmosphere through the demister 16 is set to 400 ° C and 60 ° C to 80 ° C.

In the evaporation tower 15 for supplying the heating air, the evaporation proceeds only with the constant drying, so that the temperature of the evaporated and concentrated mineral water discharged from the lower part to the concentration tank 4 is low. The height of the tower should be designed to be below 80 ° C so as not to decompose.

The flow rate of the water flowing from the concentrate tank 4 into the concentrated mineral water storage tank 9 and returned to the evaporation tower 15 which supplies the heated air by the concentrated mineral water transfer pump 10 is equal to the inflow amount of the concentrated mineral water. The flow rate is 2 to 4 times.

The flow rate of the hot air air supplied from the blower 18 is determined in consideration of the heat loss of 10% to the value obtained from the enthalpy and the material balance of the device entrance.

When the flow rate of the hot wind air supplied from the blower 18 is determined, the top diameter of the evaporation tower 15 for supplying the heated air is designed such that the flow rate of the hot air air is in the range of 3 to 5 m / sec.

The angle α of the lower cone of the evaporation tower 15 for supplying the heated air is 10 ° ≦ α ≦ 60 °, and the diameter D of the discharge portion and the diameter D of the evaporation tower 6 are shown. The ratio of is designed in the range of 0.3≤D。 / D≤0.7.

When concentrated mineral water is supplied to the magnetization and mineral production reactor (11) with the brine discharged from the salt manufacturing process, citric acid, tartaric acid, succinic acid, malic acid, Fulvic acid… The amount of total solids (total solids) contained in concentrated mineral water and brine among the organic acids such as single or mixed two or more kinds is 0.4 to 1.2 by weight based on dry weight (total solids / organic acid). The magnetic field of the magnetizer 14 is transferred to the magnetizer circulation pump 13 while stirring with a magnetization and active mineral generation reactor stirrer 12 to produce a chelate organic acid mineral complex salt while being injected in the range of. Through the magnetization treatment while returning to the magnetization and mineral production reaction tank (11) to produce an active mineral.

Activated minerals are sent to the packaging process, packaged, and then shipped to the product after inspection.

The capacity of the magnetization and activation mineral generation reactor 11 is 40 to 120 minutes, the material is the same as the concentrated mineral water storage tank (9), and the magnetization and activation mineral generation reactor stirrer (12) is 180 to 360 RPM Stir with a propeller stirrer at (speed).

The magnetizer 5 installed on the discharge side of the magnetizer circulation pump 13 has a permanent magnet magnetized in the range of 12,000 to 15,000 G (Gauss) or synthetic resin (PVC, PE, styrene resin). Etc.), a coil applied to a cylindrical conductive tube of insulating material such as Ebonyite, FRP, Bakelite, etc., and a low voltage of 0.5 to 5 V is applied to the inside of the coil. A constant voltage conductive tube magnetizer is used in which a magnetic field is formed.

As described above, the active mineral prepared in the present invention is expected to be widely used as an alternative to the active mineral produced naturally because the quality of the product is uniform as compared to the purified purified natural mineral. .

Claims (4)

After warming up to 20 ~ 30 ℃ of deep seawater or subsea deep rock water taken below 200m, pretreatment of sand, microfiltration and ultrafiltration alone or in combination of two or more types After injection, adjust pH to 4.5 ~ 6.5, send to reverse osmosis filtration process, send demineralized water to drinking water manufacturing process, send brine to nanofiltration process, send demineralized salt to saline manufacturing process, concentrated mineral with divalent or higher mineral content The water was sent to a neutralization process, and the pH was adjusted to 6.5-7.5 while stirring with a neutralization tank stirrer (2) while supplying one kind of aqueous solution from Ca (OH) ₂ , CaO, NaOH, NaHCO ₃ , Na ₂ CO ₃ as a neutralizing agent. Neutralization treatment to a range by sending the concentrated mineral water transfer pump (3) to the top of the evaporation tower (6) of the evaporation and concentration process with the concentrated mineral water return water and sprayed through the spray nozzle (8) At the top Concentrated mineral water vaporizes moisture by countercurrent contact with air while inhaling air in the atmosphere from the lower part of the evaporation tower 8 by the installed evaporation tower fan 7 and discharging it to the upper part. When the solid precipitated (CaCO ₃ , CaSO ₄ ) precipitated in the bottom of the thickening tank 4 is collected by the thickening tank rake 5 into the bottom cone of the thickening tank 4, it is intermittently magnetized and activated. The concentrated mineral water discharged to the mineral production reaction tank (11) and overflowed to the upper part of the concentration tank (4) is sent to the concentrated mineral storage tank (9), and the upper part of the evaporation tower (6) by the concentrated mineral water return pump (10). When the short-selling weight is more than 30 beams (Be) while returning to water, the BEM (Baume indicating switch) installed in the concentrated mineral water storage tank (9) operates the electronic valve and discharges it from the salt production process. When supplied to the magnetization and mineral production reactor (11) together Citric acid, tartaric acid, succinic acid, malic acid, fulvic acid, or a mixture of two or more of them in a total weight ratio (total solid) Solids / organic acid) is injected into the range of 0.4 to 1.2, and stirred with a magnetization and active mineral production reactor stirrer 12 to produce chelate organic acid mineral complex salts, while 12,000 to 15,000 with a magnetizer circulation pump 13 A low voltage of AC or DC in the range of 0.5 to 5 V is applied to a permanent magnet magnetizer 14 magnetized in the G (Gauss) range or a coil wound around a cylindrical conductive tube of insulating material. Through the magnetic field of the constant-voltage conductive tube magnetizer, in which a magnetic field is formed inside the coil, it is magnetized while being returned to the magnetization and mineral generation reactor 11 Process for preparing activated minerals. According to claim 1, in the pH adjustment process after pre-treatment, the deep seawater or subsea deep rock water with pH adjusted to 4.5-6.5 is sent to the nanofiltration process, demineralized brine is sent to the reverse osmosis filtration process, the demineralized water is sent to the drinking water production process, Concentrated brine is sent to the salt production process, the concentrated mineral water from which monovalent salts (NaCl, KCl) are removed in the nanofiltration process is sent to the neutralization process to produce activated minerals. The method of claim 1, wherein in the case of winter or rainy season with low atmospheric temperature, the evaporation concentration is carried out by an evaporation tower which supplies heating air instead of the evaporation tower 6 which supplies air in the atmosphere and evaporates. The neutralized treated concentrated mineral water and concentrated mineral water returned water are sent to the upper part of the evaporation tower 15 which supplies the compressed air together with the compressed air to the evaporation tower 15 for supplying the heating air. When the hot air heated by the burner 17 is supplied to the lower portion through the filter 19 while the air supplied from the blower 18 is sprayed through, the water vaporized while countercurrently contacting the hot air air is demister. (Demister; 16) is released to the atmosphere, and the evaporated function is sent to the concentration tank (4), and when the precipitated salt precipitates, it is collected by the salt concentration lake (5) to the lower center cone intermittently to generate magnetization and active minerals. Discharged into the reactor (11), The concentrated mineral water flowing into the upper part of the tank (4) is sent to the concentrated mineral storage tank (9) and returned to the upper part of the evaporation tower (6) by the concentrated mineral water return pump (10). A method for producing active minerals by operating an electron valve by a BME (Baume indicating switch) installed in a concentrated mineral water storage tank (9) and sending the magnetization and active mineral reaction processes to a magnetization and active mineral reaction tank (11). . According to claim 2, in the case of winter or rainy season with low atmospheric temperature, the evaporation concentration is carried out by an evaporation tower which supplies heating air instead of the evaporation tower 6 which supplies air in the atmosphere and evaporates it. The neutralized treated concentrated mineral water and concentrated mineral water returned water are sent to the upper part of the evaporation tower 15 which supplies the compressed air together with the compressed air to the evaporation tower 15 for supplying the heating air. When hot air heated by the burner 17 is supplied to the lower portion through the filter 19 while the air supplied from the blower 18 is sprayed through the water, the water vaporized while countercurrently contacting the hot air air is demister. (Demister; 16) is released to the atmosphere, and the evaporated function is sent to the concentration tank (4), and when the precipitated salt precipitates, it is collected by the salt concentration lake (5) to the lower center cone intermittently to generate magnetization and active minerals. Discharged into the reactor (11), The concentrated mineral water flowing into the upper part of the tank (4) is sent to the concentrated mineral storage tank (9) and returned to the upper part of the evaporation tower (6) by the concentrated mineral water return pump (10). A method for producing active minerals by operating an electron valve by a BME (Baume indicating switch) installed in a concentrated mineral water storage tank (9) and sending the magnetization and active mineral reaction processes to a magnetization and active mineral reaction tank (11). .

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