KR20070000735A - Sidewall insert and bead rubber composition for runflat tire - Google Patents
Sidewall insert and bead rubber composition for runflat tire Download PDFInfo
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- KR20070000735A KR20070000735A KR1020050056308A KR20050056308A KR20070000735A KR 20070000735 A KR20070000735 A KR 20070000735A KR 1020050056308 A KR1020050056308 A KR 1020050056308A KR 20050056308 A KR20050056308 A KR 20050056308A KR 20070000735 A KR20070000735 A KR 20070000735A
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- polybutadiene
- rubber composition
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C2001/0033—Compositions of the sidewall inserts, e.g. for runflat
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C2001/005—Compositions of the bead portions, e.g. clinch or chafer rubber or cushion rubber
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/80—Technologies aiming to reduce greenhouse gasses emissions common to all road transportation technologies
- Y02T10/86—Optimisation of rolling resistance, e.g. weight reduction
Abstract
Description
본 발명은 런플랫 타이어용 싸이드월 인써트 및 비드 고무 조성물에 관한 것으로, 더욱 상세하게는 신디오태틱 1,2-폴리부타디엔을 포함하는 폴리부타디엔을 일정 함량으로 포함하여 타이어의 내구성 및 회전저항을 향상시킨 런플랫 타이어용 싸이드월 인써트 및 비드 고무 조성물에 관한 것이다. The present invention relates to a run-wall tire sidewall insert and bead rubber composition, and more particularly, to include a polybutadiene containing syndiotactic 1,2-polybutadiene in a predetermined amount to improve the durability and rolling resistance of the tire. It relates to a sidewall insert and bead rubber composition for run flat tires.
종래 런플랫 타이어의 싸이드월부의 강성을 향상시켜 런플랫 성능 확보에 필요한 강도를 얻기 위해서는 보강성 필러를 증량하여 사용하거나 가류제를 증량하여 사용하였다. 이러한 경우에 보강성 필러의 비중이 1.8~2.0 정도로 고무제품의 비중을 높이는 주 원인으로 작용하며, 중량을 낮추지 못하여 타이어 경량화에 많은 문제가 있었다. In order to improve the rigidity of the sidewall portion of the conventional run flat tire to obtain the strength required to secure the run flat performance, the reinforcing filler was used in an increased amount or a vulcanizing agent was used in an increased amount. In this case, the specific gravity of the reinforcing filler acts as a main cause of increasing the specific gravity of the rubber product to about 1.8 to 2.0, and there are many problems in reducing the weight of the tire because the weight cannot be lowered.
또한 내피로성, 내크랙성, 내발열성이 불리해져 요구되는 런플랫 성능을 유지하지 못하고 고무의 파괴로 이어졌다. 특히 셀프 써어포트형 런플랫 타이어는 인써트의 보강으로 인한 중량 증가를 막을 수 없었다. In addition, fatigue resistance, crack resistance, and heat resistance were disadvantageous, which resulted in the destruction of rubber without maintaining the required run flat performance. In particular, self-supported run-flat tires could not prevent weight gain due to insert reinforcement.
오늘날 타이어 요구성능은 다양한 소비자들의 기호에 맞게 타이어를 제조하여 공급하는 것으로 안정성을 가장 중시한 형태로써 타이어의 내부 압력 손실시 차량의 하중을 지지하며 일정한 속도와 거리를 안전하게 주행할 수 있어야 한다. Today's tire demand performance is to manufacture and supply tires according to the preferences of various consumers. The most important form of stability is to support the load of the vehicle when the internal pressure of the tire is lost and to be able to safely drive a certain speed and distance.
보강성 필러의 비중은 1.8~2.0로서, 사용되는 조건에 맞게 충진할 경우 고무조성물의 중량에 가장 큰 영향을 미치는 인자이다. 따라서, 보강성 필러의 함량을 줄이면 고무 조성물의 중량감소를 얻을 수 있는 장점이 있다. 그러나 이를 줄일 수 없는 것은 요구되는 물성 수준 때문으로, 만일 물성 수준만 만족된다면 보강성 필러의 양을 줄여 가벼운 고무 조성물을 만들 수 있다. 즉, 보강성 필러의 역할을 해 줄 수 있는 개체가 필요하며, 이러한 개체가 있다면 강도를 유지하며 가벼운 고무 조성물의 제조가 가능하게 된다. The specific gravity of the reinforcing filler is 1.8 to 2.0, which is the most influential factor in the weight of the rubber composition when it is filled according to the conditions used. Therefore, reducing the content of the reinforcing filler has an advantage of obtaining a weight reduction of the rubber composition. However, this cannot be reduced because of the required level of physical properties, and if only the level of physical properties is satisfied, the amount of reinforcing filler can be reduced to make a light rubber composition. That is, there is a need for an individual that can serve as a reinforcing filler, and if such an individual is present, it is possible to manufacture a light rubber composition while maintaining strength.
또한, 가류제의 증량을 통한 강성을 높일 경우 현장 가공 중에 분산의 불충분으로 인하여 균일한 물성 확보가 어려우며 스코치 등 현장 가공성이 안 좋아지고 타이어의 내부 압력 손실시 요구되는 런플랫 성능에서 내피로성과 내크랙성이 매우 불리해져 일정량 이상을 사용하는 데는 문제점이 있었다. In addition, if the stiffness is increased by increasing the amount of vulcanizing agent, it is difficult to secure uniform properties due to insufficient dispersion during on-site processing. Cracking is very disadvantageous, there was a problem in using more than a certain amount.
따라서, 본 발명은 런플랫 타이어용 싸이드월 인써트 및 비드 고무의 런플랫 성능을 향상시키고, 보강성 필러의 역할을 수행할 수 있는 대체 물질을 찾아 상기한 문제들을 해결하기 위한 것으로서 통상의 런플랫 타이어용 싸이드월 인서트 및 비드 고무 조성물에서, 원료고무로서 천연고무와 신디오태틱 1,2-폴리부타디엔 을 포함하는 폴리부타디엔을 적용함으로써 과도한 가류제의 사용을 피하며 일정 수준의 가류제를 사용하므로써 런플랫 성능에 부합되는 물성을 만족하는 고무 조성물을 제조할 수 있어, 내피로성, 내크랙성, 내발열성이 향상되며 동등 수준의 경도와 인장강도 물성을 유지할 수 있음을 확인하였다. Accordingly, the present invention is to improve the run flat performance of the sidewall insert and bead rubber for run flat tires, and to solve the above problems in search of alternative materials that can serve as a reinforcing filler. For sidewall inserts and bead rubber compositions, the application of polybutadiene, including natural rubber and syndiotactic 1,2-polybutadiene, as raw material rubber, avoids the use of excessive vulcanizing agents, It was confirmed that the rubber composition satisfying the physical properties according to the flat performance can be prepared, so that fatigue resistance, crack resistance, and heat resistance can be improved and hardness and tensile strength properties of the same level can be maintained.
따라서 본 발명의 목적은 런플랫 타이어용 싸이드월 인써트 및 비드 고무의 런플랫 성능 및 회전 저항을 향상시키기 위해 내피로성, 내크랙성, 내발열성이 향상되고 비중이 낮은 런플랫 타이어용 싸이드월 인써트 및 비드 고무 조성물을 제공하는 데 있다. Accordingly, an object of the present invention is to improve the fatigue resistance, crack resistance, heat resistance and low weight of run-flat tires to improve run-flat performance and rolling resistance of the run-wall tire sidewall inserts and bead rubbers. It is to provide a bead rubber composition.
이러한 본 발명의 목적을 달성하기 위한 런플랫 타이어용 싸이드월 인써트 및 비드 고무조성물은 런플랫 타이어용 싸이드월 인써트 및 비드 고무 조성물에 있어서, 원료고무는 천연고무 20~80중량% 및 신디오태틱 1,2-폴리부타디엔을 포함한 폴리부타디엔 20~80중량%를 포함하는 것을 그 특징으로 한다. In order to achieve the object of the present invention, the run-wall tire sidewall insert and bead rubber composition for run-flat tire sidewall insert and bead rubber composition, the raw material rubber is 20 to 80% by weight of natural rubber and syndiotactic 1 It is characterized by comprising 20 to 80% by weight of polybutadiene including, 2-polybutadiene.
이하, 본 발명을 더욱 상세하게 설명하면 다음과 같다. Hereinafter, the present invention will be described in more detail.
본 발명은 통상의 런플랫 타이어용 싸이드월 인써트 및 비드 고무조성물에서, 원료고무로 천연고무 20~80중량%와 신디오택틱 1,2-폴리부타디엔이 잘 분산되어 있는 폴리부타디엔 20~80중량%를 포함하며, 여기에 추가로 부타디엔 고무를 50중량% 이내로 포함시킨 것을 사용한다. The present invention is 20 to 80% by weight of polybutadiene, which is well dispersed in 20 to 80% by weight of natural rubber and syndiotactic 1,2-polybutadiene as a raw material rubber in the common run flat tire sidewall insert and bead rubber composition. It includes, in addition to using butadiene rubber contained within 50% by weight.
본 발명의 런플랫 타이어용 싸이드월 인서트 및 비드 고무조성물은 신디오 택틱 1,2-폴리부타디엔(Syndiotactic 1,2-Polybutadiene)을 포함하는 폴리부타디엔을 일정 함량으로 포함함으로써, 상기 포함된 신디오택틱 1,2-폴리부타디엔 고무가 기존의 고무 조성물에 보강 역할을 하는 보강성 필러의 역할을 해주어 보강성 필러로 인한 타이어의 중량 증가를 방지하고, 내피로성, 내크랙성, 내발열성 등이 우수하다. The run-wall tire sidewall insert and the bead rubber composition of the present invention comprises a syndiotactic 1,2-polybutadiene (Syndiotactic 1,2-Polybutadiene) by containing a predetermined amount, the included syndiotactic 1,2-polybutadiene rubber acts as a reinforcing filler that reinforces the existing rubber composition, preventing the weight increase of the tire due to the reinforcing filler, and is excellent in fatigue resistance, crack resistance, and heat resistance. .
상기와 같은 신디오택틱 1,2-폴리부타디엔 고무를 포함한 폴리부타디엔의 함량은 전체 원료고무 중 20 내지 80중량%의 범위로 포함되는 것이 바람직한 바, 20중량% 미만일 경우 신디오택틱 1,2-폴리부타디엔에 의한 보강성 필러의 역할이 적어 원하는 모둘러스 수준 확보가 어려우며, 또한 80중량%를 초과할 경우 부타디엔 및 신디오택틱 1,2-폴리부타디엔 함량이 너무 높아 혼합 및 압출 가공성의 저하, 내크랙성 및 발열 성능이 저하된다. The content of the polybutadiene including the syndiotactic 1,2-polybutadiene rubber as described above is preferably included in the range of 20 to 80% by weight of the total raw rubber, if less than 20% by weight of the syndiotactic 1,2- The role of the reinforcement filler by polybutadiene is difficult to secure the desired level of modulus, and when it exceeds 80% by weight, the content of butadiene and syndiotactic 1,2-polybutadiene is too high, reducing the mixing and extrusion processability, and Cracking property and heat generation performance are reduced.
또한, 상기 신디오택틱 1,2-폴리부타디엔 고무를 포함한 폴리부타디엔 중의 신디오택틱 1,2-폴리부타디엔 고무는 전체 폴리부타디엔 중 3 내지 35중량%로 포함되는 것이 바람직하다. 신디오택틱 1,2-폴리부타디엔 고무의 함량이 3% 미만의 경우 보강성 필러로서의 역할을 할 수 없어 일반 부타디엔고무와 큰 성능차를 얻을 수 없으며, 35중량%를 초과할 경우 모둘러스 급상승으로 적정 수준의 성능을 얻을 수 없다. 가장 바람직하기는 10~20중량% 사용시 가장 적절한 성능을 얻을 수 있다. In addition, the syndiotactic 1,2-polybutadiene rubber in the polybutadiene including the syndiotactic 1,2-polybutadiene rubber is preferably included in 3 to 35% by weight of the total polybutadiene. If the content of syndiotactic 1,2-polybutadiene rubber is less than 3%, it cannot play a role as a reinforcing filler, and thus, a big difference in performance from general butadiene rubber can not be obtained. No level of performance can be achieved. Most preferably, 10 to 20% by weight of the most appropriate performance can be obtained.
또한, 본 발명의 원료고무는 상기 성분 이외에 추가로 부타디엔 고무를 전체 원료고무 중 50중량% 이내로 포함시킬 수도 있다. In addition, the raw material rubber of the present invention may further contain butadiene rubber within 50% by weight of the total raw material rubber in addition to the above components.
한편, 본 발명의 런플랫 타이어용 싸이드월 인써트 및 비드 고무조성물은 상기 원료고무 100 중량부에 대하여 충진제 20~70중량부, 가류제로 유황 0.5~6중량부, 가류촉진제로 설펜아마이드계 0.5~4 중량부, 열화방지제로 0.5~5 중량부를 포함하며, 이러한 첨가제들은 통상 타이어 제조에서 사용되는 것으로서 특별히 한정되지 않는다. On the other hand, the run-flat tire sidewall insert and bead rubber composition of the present invention is 20 to 70 parts by weight of the filler, 0.5 to 6 parts by weight of sulfur as a vulcanizing agent, and sulfenamide 0.5 to 4 as a vulcanization accelerator, based on 100 parts by weight of the raw material rubber. By weight, 0.5 to 5 parts by weight as a deterioration inhibitor, and these additives are not particularly limited as used in the production of tires in general.
이하 본 발명을 다음의 실시예와 시험예로 설명하고자 하며 이들이 본 발명의 기술적 범위를 한정하는 것은 아니다. Hereinafter, the present invention will be described in the following Examples and Test Examples, which do not limit the technical scope of the present invention.
실시예 1 및 비교예 1 내지 3 Example 1 and Comparative Examples 1 to 3
다음 표 1과 같은 조성으로 배합된 고무조성물을 160℃에서 20분간 가류시켰으며, 가류된 쉬트에 대해 ASTM 규정에 의거 인장 특성, Tanδ, 내피로성, 내크랙성, 내발열성, 비중을 다음과 같이 측정하였으며, 그 결과를 다음 2에 나타내었다. Next, the rubber composition blended in the composition shown in Table 1 was vulcanized at 160 ° C. for 20 minutes, and the tensile properties, Tanδ, fatigue resistance, crack resistance, heat resistance, and specific gravity of the vulcanized sheet were as follows. It measured, and the result is shown in the following 2.
1. 인장 물성 : 인장시험기(ASTM D 638)를 이용하여 모듈러스, 신장율, 인장 강도를 평가하였다.1. Tensile Properties: Modulus, elongation, and tensile strength were evaluated using a tensile tester (ASTM D 638).
2. 내피로성 : FF 시험기를 이용하여 피로 수명(50% 잔존율)을 측정하였다. 2. Fatigue resistance: Fatigue life (50% residual rate) was measured using an FF tester.
3. 내크랙성 : Demattia 시험기를 이용하여 일정 싸이클 후의 크랙 길이를 측정하여 성장 속도를 구하였다. 3. Crack resistance: The growth rate was determined by measuring the crack length after a certain cycle using a Demattia tester.
4. tanδ : 점탄성시험기를 이용하여 측정하였다. 4. tan δ: was measured using a viscoelastic tester.
5. 비중 : 자동비중계를 이용하여 측정하였다. 5. Specific gravity: It was measured by using an automatic hydrometer.
(표 1) Table 1
(표 2) Table 2
상기 표 2의 결과에서 확인할 수 있는 바와 같이, 본 발명과 같이 종래 런플랫 타이어용 싸이드월 인써트 및 비드 고무 조성물의 원료고무로서 신디오택틱 1,2-폴리부타디엔을 포함하는 부타디엔을 일정함량으로 포함시킨 경우, 신디오택틱 1,2-폴리부타디엔을 포함하는 폴리부타디엔 고무를 포함하지 않은 비교예에 비해 인장물성 및 내피로성 내크랙성 등 대부분의 물성이 우수한 것으로 보아, 첨가된 신디오택틱 1,2-폴리부타디엔이 보강성 필러 역할을 수행함으로써 고무의 중량을 증가시켜 비중이 낮고, 인장 물성, 내피로성, 내크랙성, 내발열성이 등이 우수하다. As can be seen from the results of Table 2, as the present invention, butadiene including syndiotactic 1,2-polybutadiene as a raw material rubber of the conventional run-flat tire sidewall insert and bead rubber composition is contained in a predetermined amount. In this case, it is considered that the physical properties such as tensile properties and fatigue resistance crack resistance are superior to the comparative examples without polybutadiene rubber containing syndiotactic 1,2-polybutadiene. 2-polybutadiene acts as a reinforcing filler, thereby increasing the weight of the rubber to lower specific gravity, and excellent tensile properties, fatigue resistance, crack resistance, and heat resistance.
한편, 런플랫 내구 성능과 회전저항을 측정하기 위하여, 런플랫 내구성능의 경우 타이어를 림 조립 후 내압 2.5kg/㎠상태로 38℃에서 24시간 방치 후 밸브를 빼고 내압을 대기압 상태로 조정하여 하중 400kg, 속도 80km/h로 드럼(직경 1.7m)에서 주행하여 고장 발생시까지의 시간이며 실시예를 콘트롤로 100으로 하여 지수화하였다. On the other hand, in order to measure run flat durability performance and rolling resistance, in the case of run flat durability performance, the tire is left at 2.5 kg / cm 2 of internal pressure after rim assembly for 24 hours at 38 ° C, and the valve is removed and the internal pressure is adjusted to atmospheric pressure. It was the time until the failure occurred by running in a drum (diameter 1.7 m) at 400 kg and a speed of 80 km / h.
또한, 회전저항의 경우 타이어를 림 조립 후 코스트 다운(Coast Down SAE J2452) 시험법을 이용하여 실시후 실시예를 콘트롤로 100으로 지수화하여 나타내었다. In addition, in the case of the rolling resistance, the tire after the rim assembly (Coast Down SAE J2452) test method using the test after the embodiment was shown to be indexed to 100 by the control.
상기 런플랫내구성능과 회전저항 값을 다음 표 3에 나타내었다. The run flat durability and rotational resistance values are shown in Table 3 below.
(표 3) Table 3
상기 표 3에서 확인할 수 있는 바와 같이, 본 발명에 따라 신디오택틱 1,2-폴리부타디엔을 포함하는 폴리부타디엔 고무를 종래 런플랫 타이어용 싸이드월 인서트 및 비드 고무 조성물의 원료고무에 포함시킨 결과, 첨가된 신디오택틱 1,2-폴리부타디엔이 보강 필러의 역할을 수행하여 내구성이 우수하고, 가벼운 고무 조성물로 중량 감소 역할을 통하여 회전저항을 줄여 연비를 향상할 수 있다. As can be seen in Table 3, as a result of including the polybutadiene rubber containing syndiotactic 1,2-polybutadiene in the raw material rubber of the conventional run-wall tire sidewall insert and bead rubber composition according to the present invention, The added syndiotactic 1,2-polybutadiene serves as a reinforcing filler and has excellent durability, and can improve fuel economy by reducing rotational resistance through a weight reduction role with a light rubber composition.
이상에서 상세히 설명한 바와 같이, 본 발명은 런플랫타이어의 성능 향상을 목적으로 하여 보강성 필러의 함량을 줄이고 이를 신디오태틱 1,2-폴리부타디엔으로 보강역할을 함으로써 고무의 중량부를 증가시켜 비중이 낮으면서 동일 경도 및 모듈러스에서 인장 특성, 내피로성, 내크랙성, 내발열성이 향상된 싸이드월 인써트 고무 및 비드의 고무 조성물로 런플랫 내구 특성을 만족시키며 중량 증가를 막아 연비 성능을 향상시키는 고무 조성물을 제공한다. As described in detail above, the present invention reduces the content of the reinforcing filler for the purpose of improving the performance of the run flat tire and increases the weight part of the rubber by increasing the weight part of the rubber by acting as a reinforcement with syndiotactic 1,2-polybutadiene. The rubber composition of the sidewall insert rubber and the bead which improves the tensile properties, fatigue resistance, crack resistance, and heat resistance at the same hardness and modulus at low but satisfies the run flat endurance characteristics and prevents the weight increase to improve the fuel efficiency performance to provide.
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KR100871809B1 (en) * | 2007-11-13 | 2008-12-03 | 한국타이어 주식회사 | Bead rubber composition for high stiffness tire |
KR100886249B1 (en) * | 2008-03-07 | 2009-02-27 | 금호타이어 주식회사 | Insert rubber composition to reinforce the sidewall of run-flat tire |
US20130292023A1 (en) * | 2010-09-30 | 2013-11-07 | Michelin Recherche Et Technique S.A. | Rubber composition with low surface area carbon black |
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KR101153402B1 (en) * | 2009-12-23 | 2012-06-07 | 한국타이어 주식회사 | Sidewall insert rubber composition for runflat tire and tire manufactured by using the same |
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CA1333468C (en) * | 1988-09-14 | 1994-12-13 | Richard Martin Scriver | Pneumatic tire containing syndiotactic 1,2-polybutadiene |
KR100303887B1 (en) | 1999-05-17 | 2001-10-18 | 조충환 | Rubber composition suitable for tire sidewall with lightweight and low fuel consumption properties |
US6807994B2 (en) | 2001-03-13 | 2004-10-26 | The Goodyear Tire & Rubber Company | Pneumatic tire having a rubber component containing a rubber gel and syndiotatic 1,2-polybutadiene |
JP2004059740A (en) * | 2002-07-29 | 2004-02-26 | Yokohama Rubber Co Ltd:The | Rubber composition and pneumatic tire |
KR100560164B1 (en) | 2003-07-26 | 2006-03-10 | 주식회사 보스산업 | A composition of the Rubber Foamed Outsoles for T'aekwondo Shoes |
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KR100871809B1 (en) * | 2007-11-13 | 2008-12-03 | 한국타이어 주식회사 | Bead rubber composition for high stiffness tire |
KR100886249B1 (en) * | 2008-03-07 | 2009-02-27 | 금호타이어 주식회사 | Insert rubber composition to reinforce the sidewall of run-flat tire |
US20130292023A1 (en) * | 2010-09-30 | 2013-11-07 | Michelin Recherche Et Technique S.A. | Rubber composition with low surface area carbon black |
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