KR20060098710A - Sampling method of matter which releases far infrared ray, minus ion, plastic worked material, composite and food container thereof - Google Patents
Sampling method of matter which releases far infrared ray, minus ion, plastic worked material, composite and food container thereof Download PDFInfo
- Publication number
- KR20060098710A KR20060098710A KR1020050018605A KR20050018605A KR20060098710A KR 20060098710 A KR20060098710 A KR 20060098710A KR 1020050018605 A KR1020050018605 A KR 1020050018605A KR 20050018605 A KR20050018605 A KR 20050018605A KR 20060098710 A KR20060098710 A KR 20060098710A
- Authority
- KR
- South Korea
- Prior art keywords
- anion
- infrared
- far
- plastic
- emitting material
- Prior art date
Links
Images
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/1336—Illuminating devices
- G02F1/133602—Direct backlight
- G02F1/133603—Direct backlight with LEDs
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/0001—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
- G02B6/0011—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
- G02B6/0013—Means for improving the coupling-in of light from the light source into the light guide
- G02B6/0023—Means for improving the coupling-in of light from the light source into the light guide provided by one optical element, or plurality thereof, placed between the light guide and the light source, or around the light source
- G02B6/0025—Diffusing sheet or layer; Prismatic sheet or layer
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/0001—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
- G02B6/0011—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
- G02B6/0033—Means for improving the coupling-out of light from the light guide
- G02B6/0058—Means for improving the coupling-out of light from the light guide varying in density, size, shape or depth along the light guide
- G02B6/0061—Means for improving the coupling-out of light from the light guide varying in density, size, shape or depth along the light guide to provide homogeneous light output intensity
-
- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04M—TELEPHONIC COMMUNICATION
- H04M1/00—Substation equipment, e.g. for use by subscribers
- H04M1/02—Constructional features of telephone sets
- H04M1/22—Illumination; Arrangements for improving the visibility of characters on dials
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Nonlinear Science (AREA)
- Engineering & Computer Science (AREA)
- Signal Processing (AREA)
- Mathematical Physics (AREA)
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
본 발명은 원적외선,음이온 방출물질에 관한 것으로서, 특히 이온화방법으로 원적외선,음이온 방출 기능성 분말에서 음이온물질을 추출하여 다공질 플라스틱 가공원료(발포 실리케이트)에 흡착시키는 등의 방법을 사용함으로써, 기능성 분말의 분산성과 혼합성의 한계를 극복하여 다량의 원적외선,음이온이 방출되도록 할 뿐만 아니라 투명성도 우수한 원적외선,음이온 방출물질 추출방법 및 이를 이용한 플라스틱 가공재료, 조성물 및 식품용기에 관한 것이다.The present invention relates to far-infrared, anion-releasing material, in particular, by using an ionization method such as extracting anion material from the far-infrared, anion-releasing functional powder and adsorbing to a porous plastic processing material (foaming silicate), dispersion of the functional powder The present invention relates to a method of extracting far-infrared and anion-releasing materials having excellent transparency as well as allowing a large amount of far-infrared rays and anions to be released by overcoming limitations of performance and mixing, and plastic processing materials, compositions, and food containers using the same.
본 발명은 원적외선,음이온 방출 기능성 분말을 물에 분산시키고 인산염을 첨가하여 층간경계를 일으켜서 pH를 중성으로 조성하는 제1단계; 상기 기능성 분말 분산액에서 공형분 및 부유 불순물을 제거하여 상등액을 얻는 제2단계; 상기 상등액에 알카리성 물질을 첨가하여 음이온 물질을 염의 형태로 추출하는 제3단계; 및 상기 추출된 물질에서 공형분을 제거하여 추출액을 얻는 제4단계를 포함한다.The present invention comprises the first step of dispersing far-infrared, anion-releasing functional powder in water and adding a phosphate to create an interlayer boundary to form a neutral pH; A second step of removing supernatant and floating impurities from the functional powder dispersion to obtain a supernatant; A third step of extracting an anionic substance in the form of a salt by adding an alkaline substance to the supernatant; And a fourth step of removing an extract from the extracted material to obtain an extract.
원적외선, 음이온, 방출, 이온화, 추출, 플라스틱, 식품용기 Far Infrared, Anion, Emission, Ionization, Extraction, Plastic, Food Container
Description
도 1은 본 발명에 따른 원적외선,음이온 방출물질 추출방법을 나타내는 흐름도,1 is a flow chart showing a method for extracting far-infrared, anion-emitting material according to the present invention;
도 2는 본 발명에 따른 원적외선,음이온 방출물질이 함유된 플라스틱 가공재료의 제조과정을 나타내는 흐름도이다.Figure 2 is a flow chart showing the manufacturing process of the plastic material containing far-infrared, anion-emitting material according to the present invention.
본 발명은 원적외선,음이온 방출물질에 관한 것으로서, 더욱 상세하게는 기능성 분말의 분산성과 혼합성을 높일 수 있는 원적외선,음이온 방출물질 추출방법 및 이를 이용한 플라스틱 가공재료, 조성물 및 식품용기에 관한 것이다.The present invention relates to far-infrared, anion-releasing material, and more particularly to a method for extracting the far-infrared, anion-releasing material that can increase the dispersibility and mixing of the functional powder, and a plastic processing material, a composition and a food container using the same.
최근 들어 생활수준이 향상됨에 따라 실내에서 사용하는 여러 가지 식품용기의 편의성과 더불어, 사용자의 인체나 저장되는 식품에 유익한 기능을 하여 각종 질병을 미연에 예방할 수 있는 식품용기의 제조에 대한 관심이 높아지고 있다.In recent years, as the standard of living has improved, the interest in the production of food containers that can prevent various diseases in advance, as well as the convenience of various food containers used indoors and the user's body or stored food, have.
그리고, 일반적으로 냄비, 밥그릇, 찻잔 등의 플라스틱 식품용기는 대부분 성형틀을 이용한 성형제품으로서, 그 재질에 따라 다양하게 분류된다.In general, plastic food containers such as pots, rice bowls, tea cups, etc. are mostly molded products using a molding mold, and are classified into various types according to their materials.
이들 중에서 재질이 가진 특성으로 인해 고가로 거래되는 제품들을 살펴보면 제품 성형시 플라스틱 용액과 석분을 주성분으로 하며, 여기에 원하는 색상의 안료와 경화제를 적정비율로 투입하여 제조한다.Looking at products that are expensively traded due to the characteristics of the material, the main components are plastic solution and stone powder when forming products, and the pigments and hardeners of the desired color are added at the proper ratio.
한편, 황토, 옥, 토르말린 등의 기능성 분말은 원적외선과 음이온을 방출하는 것으로 알려져 있으며, 원적외선은 혈액순환과 노폐물 배출을 촉진하여 건강을 증진시키며, 음식물 내부까지 침투하여 음식물이 변질되는 것을 방지하는 효과가 있다.On the other hand, functional powders such as ocher, jade, and tourmaline are known to emit far infrared rays and anions, and far infrared rays promote health by circulating blood and discharging wastes, and penetrate into food to prevent food from being deteriorated. There is.
그리고, 음이온은 각종 오염으로부터 생활주변에 방출된 양이온을 흡착, 중화시켜 음식물이 부패되는 것을 방지하며, 신체의 신진대사를 원활하게 해준다.In addition, the negative ions absorb and neutralize the cations released around the living environment from various pollutions, thereby preventing food from decaying and smoothing the body's metabolism.
예를 들어, 황토는 석영 40~80%, 장석과 운모 10~20%, 탄산염 광물 5~35%, 실트 2~4% 등의 조성으로 이루어진 광물로 붉은 색을 띄고 있고, 화학성분은 실리카 50~60%, 알루미나 8~12%, 3가 산화철 2~4%, 2가 산화철 0.8~1%, 산화칼슘 4~16%, 산화마그네슘 2~6%로 구성된다.For example, ocher is red with minerals composed of 40 to 80% quartz, 10 to 20% feldspar and mica, 5 to 35% carbonate mineral, and 2 to 4% silt. 60%, 8-12% alumina, 2-4% trivalent iron oxide, 0.8-1% divalent iron oxide, 4-16% calcium oxide, and 2-6% magnesium oxide.
여기에 약 0.5%의 산화티탄과 산화망간 및 수분 10~15%이 함유되어 있으며, 상기 열거한 여러 가지 무기질 이외에도 유기물질인 다양한 종류의 미생물과 효소들이 함께 존재하고 있고, 원적외선을 다량 흡수하고 있어서 원적외선 방사효과, 실내온도와 습도 조절작용, 항균과 방취작용, 중금속 흡착작용을 하는 것으로 알려져 있다.It contains about 0.5% of titanium oxide, manganese oxide, and 10 ~ 15% of moisture, and in addition to the various minerals listed above, various kinds of microorganisms and enzymes, which are organic substances, are present together, and they absorb far infrared rays. It is known to have far-infrared radiation effect, room temperature and humidity control, antibacterial and deodorization, and heavy metal adsorption.
따라서, 최근에는 이러한 황토 등의 다양한 기능성 분말의 유익함을 일상생 활에서 손쉽게 접할 수 있도록 기본적인 생활용품에 접목시켜 기능성 분말에 의한 건강증진 효과를 꾀하려는 다양한 시도가 이루어지고 있다.Therefore, in recent years, various attempts have been made to combine the benefits of various functional powders, such as loess, with basic daily necessities so as to be easily accessible in daily life.
대한민국 특허등록 제2002-321290호에서는 플라스틱 성형재료에 황토를 5~20중량% 혼합하여 제조한 플라스틱 식품용기가 개시되어 있는데, 이것은 천연상태의 황토를 그대로 사용하는 방법이다.Korean Patent Registration No. 2002-321290 discloses a plastic food container prepared by mixing 5 to 20% by weight of ocher in a plastic molding material, which is a method of using natural loess as it is.
그러나, 황토 등의 기능성 분말 중에 포함된 실리카, 탄산칼슘 등은 결정구조가 치밀하기 때문에 원적외선 흡수가 낮아 방사에너지의 발산량이 상대적으로 적기 때문에 이를 정제해서 제거하는 것이 바람직하다.However, since silica, calcium carbonate, and the like contained in functional powders such as ocher have a dense crystal structure, absorption of far-infrared rays is relatively low due to the low absorption of far-infrared rays.
또한, 기능성 분말 중에 포함된 원적외선 방사물질은 극소량으로 포함된 금속성분 및 미네랄 성분으로서, 원하는 원적외선,음이온 방출효과를 얻기 위해서 다량의 기능성 분말을 플라스틱에 혼합하는 경우 기능성 분말의 혼합성 및 분산성이 문제가 되었다.In addition, the far-infrared radiation substance contained in the functional powder is a metal and mineral component contained in a very small amount, and when mixing a large amount of the functional powder in plastic to obtain the desired far infrared, anion release effect, the blendability and dispersibility of the functional powder It was a problem.
이러한 기능성 분말의 분산성 및 혼합성 문제로 인하여 기능성 분말의 첨가량을 소량으로 한정시킬 수밖에 없었으며, 따라서 식품용기의 원적외선,음이온 방출효과의 극대화를 기대하기는 어려운 실정이었다.Due to such dispersibility and mixing problems of the functional powder it was bound to limit the amount of the functional powder to a small amount, and therefore it was difficult to expect to maximize the far-infrared, anion release effect of the food container.
본 발명은 상기와 같은 종래 기술의 문제점을 해결하기 위하여 안출된 것으로서, 기능성 분말 중에 포함된 원적외선 방출량이 적은 고결정성의 실리카, 탄산칼슘 등의 물질을 미리 정제하여 제거한 후 기능성 분말의 층간에 포함된 음이온물질만을 이온분리하는 원적외선,음이온 방출물질 추출방법을 제공하는데 그 목적이 있다.The present invention has been made in order to solve the problems of the prior art as described above, after removing the high-purity silica, calcium carbonate, and the like, the amount of far-infrared radiation contained in the functional powder in advance to remove it contained in the interlayer of the functional powder It is an object of the present invention to provide a method for extracting far-infrared and anion emitters that ionically separates only anion materials.
그리고, 기능성 분말 그대로를 직접 플라스틱(칩)에 첨가하지 않으므로 첨가되는 기능성 분말의 양을 줄이고, 플라스틱 중에서의 기능성 분말의 무기질 성분의 분산성 및 혼합성을 높여서 흡착시킨 원적외선,음이온 방출물질이 함유된 플라스틱 가공재료를 제공하는데 목적이 있다.In addition, since the functional powder is not directly added to the plastic (chip), the amount of the functional powder added is reduced, and the far-infrared and anion-releasing material adsorbed by increasing the dispersibility and mixing properties of the inorganic components of the functional powder in the plastic is contained. It is an object to provide plastic processing materials.
한편, 본 발명의 다른 목적은 상기 플라스틱 가공재료를 이용하여 원적외선,음이온 방출효과가 우수한 원적외선,음이온 방출물질이 함유된 플라스틱 조성물 및 식품용기를 제공하는데 있다.On the other hand, another object of the present invention to provide a plastic composition and a food container containing far-infrared, anion-releasing material excellent in the far infrared, anion release effect using the plastic processing material.
이와 같은 목적을 달성하기 위한 본 발명의 원적외선,음이온 방출물질 추출방법은Far infrared, anion emitting material extraction method of the present invention for achieving the above object
원적외선,음이온 방출 기능성 분말을 물에 분산시키고 인산염을 첨가하여 층간경계를 일으켜서 pH를 중성으로 조성하는 제1단계;A first step of dispersing far-infrared and anion-releasing functional powder in water and adding a phosphate to generate an interlayer boundary to neutralize the pH;
상기 기능성 분말 분산액에서 공형분 및 부유 불순물을 제거하여 상등액을 얻는 제2단계;A second step of removing supernatant and floating impurities from the functional powder dispersion to obtain a supernatant;
상기 상등액에 알카리성 물질을 첨가하여 음이온 물질을 염의 형태로 추출하는 제3단계; 및A third step of extracting an anionic substance in the form of a salt by adding an alkaline substance to the supernatant; And
상기 추출된 물질에서 공형분을 제거하여 추출액을 얻는 제4단계를 포함하는 것을 특징으로 한다.And a fourth step of obtaining an extract by removing the eutectic content from the extracted material.
그리고, 상기 원적외선,음이온 방출 기능성 분말은 황토, 옥, 금, 은, 토르 말린, 귀양석, 맥반석, 거정석, 조개껍질, 삼베, 녹차, 어성초, 솔잎, 인삼, 가시오가피, 엄나무 및 감초 중에서 선택된 1종 이상의 분말인 것을 특징으로 하고, 상기 제1단계에서 첨가되는 인산염은 NaH3CO3인 것을 특징으로 하며, 상기 제3단계에서 첨가되는 알카리성 물질은 NaCl이나 Na2CO3인 것을 특징으로 한다.In addition, the far-infrared, anion-emitting functional powder is selected from ocher, jade, gold, silver, tourmaline, yangyang, ganban stone, giant stone, shells, burlap, green tea, eochocho, pine needles, ginseng, thorny oak, oak and licorice It is characterized in that the powder of the species or more, the phosphate added in the first step is characterized in that NaH 3 CO 3 , the alkaline material added in the third step is characterized in that the NaCl or Na 2 CO 3 .
또한, 본 발명의 원적외선,음이온 방출물질이 함유된 플라스틱 가공재료는 양이온성 성분을 갖는 다공질 플라스틱 가공원료의 양이온성 성분에 상기 추출방법들에 의해 추출된 원적외선,음이온 방출물질을 흡착시킨 것을 특징으로 한다.In addition, the plastic processing material containing the far-infrared, anion-emitting material of the present invention is characterized by adsorbing the far-infrared, anion-emitting material extracted by the extraction methods to the cationic component of the porous plastic processing material having a cationic component. do.
이것은 원적외선,음이온 방출물질 추출액에 양이온성 성분을 갖는 다공질 플라스틱 가공원료를 투입, 교반 및 분산시키는 단계;This comprises the steps of adding, stirring and dispersing the porous plastic processing material having a cationic component into the far-infrared, anion-releasing material extract;
상기 분산액을 여과, 침강이나 원심분리하여 상등액을 제거하는 단계;Filtering, settling or centrifuging the dispersion to remove the supernatant;
상기 단계에서 원적외선,음이온 방출물질이 흡착된 다공질 플라스틱 가공원료를 진공건조하는 단계; 및Vacuum-drying the porous plastic processing material adsorbed the far-infrared and anion-emitting material in the step; And
상기 다공질 플라스틱 가공원료를 500~600℃로 가열하여 이온결합을 강화해서 원적외선,음이온 방출물질을 고착시키는 단계를 포함하여 제조되는 것을 특징으로 한다.It is characterized in that it is prepared by heating the porous plastic processing raw material to 500 ~ 600 ℃ to strengthen the ionic bonds to fix the far infrared, anion emitting material.
그리고, 상기 양이온성 성분을 갖는 다공질 플라스틱 가공원료는 발포 실리케이트인 것을 특징으로 하고, 상기 원적외선, 음이온 방출물질을 고착시키는 단계 후 볼밀분쇄기에 의해 분말화하는 단계를 더 포함하여 제조된다.And, the porous plastic processing material having the cationic component is characterized in that the foam silicate, and further comprising the step of powdering by a ball mill grinder after the step of fixing the far-infrared, anion-emitting material.
한편, 본 발명의 원적외선,음이온 방출물질이 함유된 플라스틱 조성물은 플 라스틱에 상기 원적외선,음이온 방출물질들이 함유된 플라스틱 가공재료를 1~15중량% 포함하는 것을 특징으로 하고, 가소제, 착색제, CaCO3, TiO2 및 은나노입자 중에서 선택된 1종 이상의 첨가제를 더 포함하는 것을 특징으로 한다.On the other hand, the plastic composition containing the far-infrared, anion-emitting material of the present invention is characterized in that the plastic containing 1 to 15% by weight of the plastic processing material containing the far-infrared, anion-emitting material, plasticizer, colorant, CaCO 3 It is characterized in that it further comprises one or more additives selected from T i O 2 and silver nanoparticles.
또한, 본 발명의 원적외선,음이온 방출물질이 함유된 플라스틱 식품용기는 상기 플라스틱 조성물들과 합성수지를 일정한 비율로 혼합하여 펠렛화한 후 성형하여 제조되는 것을 특징으로 하고, 상기 플라스틱 조성물들로 제조한 펠렛 및 마스터배치 1~15중량%와 합성수지 85~99중량%로 구성되는 것을 특징으로 한다.In addition, the plastic food container containing the far-infrared, anion-releasing material of the present invention is characterized in that the plastic composition and the synthetic resin is produced by mixing and pelletizing after molding in a certain ratio, pellets made of the plastic compositions And it is characterized by consisting of 1 to 15% by weight of the master batch and 85 to 99% by weight of the synthetic resin.
이하, 본 발명의 바람직한 실시예를 첨부된 도면을 참조하여 상세히 설명하면 다음과 같다.Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.
도 1은 본 발명에 따른 원적외선,음이온 방출물질 추출방법을 나타내는 흐름도이고, 도 2는 본 발명에 따른 원적외선,음이온 방출물질이 함유된 플라스틱 가공재료의 제조과정을 나타내는 흐름도이다.1 is a flowchart showing a method for extracting far infrared rays and anion emitting materials according to the present invention, and FIG. 2 is a flowchart showing a manufacturing process of a plastic processing material containing far infrared rays and anion emitting materials according to the present invention.
도시된 바와 같이, 본 발명의 원적외선,음이온 방출물질 추출방법은 원적외선,음이온 방출 기능성 분말(황토 등)을 물에 분산시키고 인산염을 첨가하여 층간경계를 일으켜서 pH를 중성으로 조성하는 제1단계를 거친다(S100).As shown, the method for extracting far-infrared and anion-releasing material of the present invention is a first step of dispersing far-infrared, anion-releasing functional powder (such as ocher) in water and adding a phosphate to create an interlayer boundary to form a neutral pH. (S100).
추출방법의 상기 제1단계(S100)에서는 물 1ℓ에 황토 등의 기능성 분말을 약 40~100g의 비율로 분산시키는 것이 바람직하며, 분산은 교반기가 설치된 통상의 혼합용기에서 수행된다.In the first step (S100) of the extraction method, it is preferable to disperse functional powders such as ocher in a ratio of about 40 to 100 g in 1 L of water, and the dispersion is performed in a conventional mixing vessel equipped with a stirrer.
이 때 기능성 분말 입자의 층간 스웰링(Swelling) 효과를 증진시키기 위하여 인산염, 예를 들어 NaH3PO4(Sodium Phosphate)를 첨가하여 pH를 중성으로 조성한다.At this time, in order to enhance the interlayer swelling effect of the functional powder particles, the pH is neutralized by adding phosphate, for example, NaH 3 PO 4 (Sodium Phosphate).
그리고, 상기 기능성 분말 분산액에서 공형분 및 부유 불순물을 제거하여 상등액을 얻는 제2단계(S200)를 거친다.In addition, a second step (S200) of obtaining a supernatant by removing the co-content and suspended impurities from the functional powder dispersion.
제2단계(S200)에서는 상기 기능성 분말 분산액으로부터 공형분 등을 제거하게 되는데, 이것은 여과, 침강, 원심분리 또는 기타 공지된 통상의 방법에 의해 수행될 수 있다.In the second step (S200) to remove the powder and the like from the functional powder dispersion, which can be carried out by filtration, sedimentation, centrifugation or other known conventional methods.
예를 들어, 기능성 분말 분산액을 24시간 동안 정체시켜 고형분을 침강시키고 상등액만을 분리할 수 있다. 이 때 고형분 외의 부유 불순물은 체로 걸러내는 등 공지의 방법으로 용이하게 제거할 수 있다.For example, the functional powder dispersion can be held for 24 hours to settle the solids and separate only the supernatant. At this time, the floating impurities other than the solid content can be easily removed by a known method such as sieving.
다음으로, 상기 상등액에 알카리성 물질을 첨가하여 음이온 물질을 염의 형태로 추출하는 제3단계(S300)를 거친다.Next, an alkaline substance is added to the supernatant, followed by a third step (S300) of extracting an anionic substance in the form of a salt.
제3단계(S300)에서는 상기 제2단계(S200)에서 분리한 상등액에 NaCl, Na2CO3 등 알카리성 물질을 투입, 교반함으로써, 상등액 속에 존재하는 음이온물질을 염의 형태로 추출한다.In the third step (S300), by adding and stirring an alkaline material such as NaCl, Na 2 CO 3 to the supernatant separated in the second step (S200), anion substances present in the supernatant are extracted in the form of salt.
마지막으로, 상기 추출된 물질에서 공형분을 제거하여 추출액을 얻는 제4단계(S400)를 거친다.Finally, a fourth step (S400) of removing the content from the extracted material to obtain an extract.
제4단계(S400)에서는 상기 제2단계(S200)와 마찬가지의 방법으로 공형분 등을 제거하여 순도높은 최종적인 추출액을 얻는다.In the fourth step (S400) it is removed in the same manner as the second step (S200) to obtain a final high purity extract liquid.
그리고, 본 발명의 원적외선,음이온 방출물질이 함유된 플라스틱 가공재료는 양이온성 성분을 갖는 다공질 플라스틱 가공원료의 양이온성 성분에 상기 추출방법들에 의해 추출된 물질을 흡착하여 제조된다.And, the plastic processing material containing the far-infrared, anion-releasing material of the present invention is prepared by adsorbing the material extracted by the above extraction methods to the cationic component of the porous plastic processing material having a cationic component.
예를 들어, 기공이 형성된 발포 실리케이트의 양이온성 성분에 상기 추출된 물질을 이온흡착(염착)시켜 제조된 플라스틱 가공재료를 사용함으로써, 종래 기능성 분말을 직접 플라스틱에 혼합할 때 혼합성 및 분산성이 불량한 문제점을 해결할 수 있다.For example, by using a plastic processing material prepared by ion adsorption (dying) the extracted material in the cationic component of the foamed silicate formed pores, the mixing and dispersibility of the conventional functional powder directly into the plastic Poor problem can be solved.
이러한 흡착과정을 구체적으로 살펴보면, 원적외선,음이온 방출물질 추출액에 양이온성 성분(Site)을 갖는 다공질 플라스틱 가공원료(발포 실리케이트)를 투입, 교반 및 분산시키는 단계(S100')를 거친다.Looking specifically at this adsorption process, a porous plastic processing raw material (foaming silicate) having a cationic component (Site) to the far-infrared, anion-releasing material extract is subjected to a step (S100 ') of stirring.
예를 들어, 먼저 발포 실리케이트 75g을 용량이 약 1ℓ이고 길이가 약 40cm인 흡착칼럼에 투입한 후 기능성 분말 수용액 400mℓ(고형분의 함량 30중량%)를 주입하고, 4~5시간 동안 흡착시킨다.For example, 75 g of foamed silicate is first introduced into an adsorption column having a capacity of about 1 L and a length of about 40 cm, and then injected with 400 ml of a functional powder aqueous solution (30 wt% of solids), and adsorbed for 4 to 5 hours.
그리고, 상기 분산액을 여과, 침강이나 원심분리하여 상등액을 제거하는 단계(S200') 및 상기 단계에서 원적외선,음이온 방출물질이 흡착된 다공질 플라스틱 가공원료(발포 실리케이트)를 진공건조하는 단계(S300')를 거친다.And, the step of removing the supernatant by filtration, sedimentation or centrifugation of the dispersion (S200 ') and vacuum drying the porous plastic processing material (foaming silicate) adsorbed far-infrared, anion-emitting material in the step (S300') Go through.
기능성 분말에 포함된 원적외선,음이온 방출물질은 음이온성을 가지고 있고, 이러한 물질의 담체로 이용되는 플라스틱 가공원료는 양이온성을 가지고 있어서, 상호 이온결합에 의해 매우 용이하고 견고하게 흡착될 수 있다.Far-infrared and anion emitters contained in the functional powders have anionic properties, and plastic processing materials used as carriers of these materials have cationic properties, and can be adsorbed very easily and firmly by mutual ion bonding.
마지막으로, 상기 다공질 플라스틱 가공원료를 500~600℃로 가열하여 이온결합을 강화해서 원적외선,음이온 방출물질을 고착시키는 단계(S400')와 볼밀분쇄기 (400~500 메쉬)에 의한 분말화 단계(S500')를 거침으로써 제조가 완료된다.Finally, by heating the porous plastic processing raw material to 500 ~ 600 ℃ to strengthen the ionic bonds to fix the far infrared, anion emitting material (S400 ') and the powdering step by the ball mill grinder (400 ~ 500 mesh) (S500 The manufacturing is completed by passing through ').
즉, 흡착이 완료되면 흡착칼럼 하단의 밸브를 열어 여액을 제거하고 고형분만을 분리하며, 기능성 물질이 흡착(합침)된 발포 실리케이트 슬러리를 건조기에 투입하여 건조시키고, 마지막으로 볼밀분쇄기(400~500 메쉬)로 미세하게 분쇄함으로써 플라스틱 가공재료를 완성한다.That is, when the adsorption is completed, open the valve at the bottom of the adsorption column to remove the filtrate, and separate only the solid content, and the foam silicate slurry in which the functional material is adsorbed (incorporated) is put into the dryer and dried, and finally the ball mill grinder (400-500 mesh) Finely pulverized into) to complete the plastic processing material.
발포 실리케이트는 필름형태로 성형시 적외선을 조사하면 흡수에너지가 800~400λ-1의 높은 특성을 나타내며, 방사에너지 또한 우수하여 여기에 기능성 분말의 음이온물질을 이온흡착(염착)시켜 사용하는 경우에 천연재료를 사용하는 것보다 우수한 음이온 발산효과를 얻을 수 있다.Foam silicates show high absorption energy of 800 ~ 400λ -1 when irradiated with infrared rays when forming into a film form, and also have excellent radiation energy. Better anion dissipation effect can be obtained than using materials.
또한, 본 발명의 원적외선,음이온 방출물질이 함유된 플라스틱 조성물은 플라스틱에 상기 원적외선,음이온 방출물질이 함유된 플라스틱 가공재료를 1~15중량% 포함한다.In addition, the plastic composition containing the far-infrared, anion-emitting material of the present invention comprises 1 to 15% by weight of the plastic processing material containing the far-infrared, anion-emitting material in the plastic.
이 때 가소제, 착색제, CaCO3, TiO2 및 은나노입자 중에서 선택된 1종 이상의 첨가제를 더 포함할 수 있다. 특히, 은나노입자가 첨가되는 경우에는 항균성이 더욱 우수해진다.At this time, it may further include at least one additive selected from a plasticizer, a colorant, CaCO 3, T i O 2 and silver nanoparticles. In particular, when silver nanoparticles are added, antimicrobial activity becomes further excellent.
즉, PP, PE, PET, ABS 등의 플라스틱에 원적외선,음이온 방출물질을 흡착시킨 플라스틱 가공재료 1~15중량%를 포함시키며, 기타 통상의 플라스틱 가공재료인 가소제, 착색제 등을 필요에 따라 적정량을 배합하여 추가로 포함시켜 제조한다.That is, it contains 1 to 15% by weight of plastic processing materials adsorbing far-infrared and anion-releasing materials to plastics such as PP, PE, PET, ABS, and other suitable plastic processing materials such as plasticizers and colorants, if necessary. It is prepared by blending it further.
한편, 본 발명의 원적외선,음이온 방출물질이 함유된 플라스틱 식품용기는 플라스틱 조성물(발포 실리케이트)과 합성수지(PP, PE, ABS, PC, PS 등)를 일정한 비율로 혼합하여 펠렛화한 후 성형하여 제조되거나, 상기 플라스틱 조성물로 제조한 펠렛 및 마스터배치 1~15중량%와 합성수지 85~99중량%로 구성되며, 압출, 사출 등의 방법에 의해 제조된다.On the other hand, the plastic food container containing the far-infrared, anion-releasing material of the present invention is produced by mixing the plastic composition (foaming silicate) and synthetic resin (PP, PE, ABS, PC, PS, etc.) at a predetermined ratio, pelletized and molded Or it is composed of 1-15% by weight of the pellet and the masterbatch and 85-99% by weight of the synthetic resin prepared from the plastic composition, and is produced by a method such as extrusion, injection.
플라스틱 가공원료로 이용되는 발포 실리케이트는 합성수지의 소강제 역할을 하는 것으로서, 합성수지와의 혼합성이 우수하고 실리케이트 주변에서 결정이 성장하면서 핵제(Nucleating Agent)의 역할을 하여 플라스틱 용기의 투명성을 더욱 향상시킨다.Foamed silicates used as plastic processing raw materials play a role as a stiffener for synthetic resins, and have excellent mixing properties with synthetic resins, and as crystals grow around silicates, they act as nucleating agents to further improve the transparency of plastic containers. .
이와 같이 구성된 본 발명의 원적외선,음이온 방출물질 추출방법 및 이를 이용한 플라스틱 가공재료, 조성물 및 식품용기는 기능성 분말 중에서 음이온 분말의 분산성과 혼합성을 높여서 다량의 원적외선,음이온이 방출되도록 함은 물론 투명성 및 항균성도 우수한 유용한 효과를 발휘한다.The far-infrared, anion-releasing material extraction method and plastic processing materials, compositions and food containers using the same of the present invention configured as described above increase the dispersibility and blendability of the anion powder in the functional powder to release a large amount of far-infrared and anion, as well as transparency and The antibacterial effect also shows excellent useful effects.
Claims (12)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020050018605A KR20060098710A (en) | 2005-03-07 | 2005-03-07 | Sampling method of matter which releases far infrared ray, minus ion, plastic worked material, composite and food container thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020050018605A KR20060098710A (en) | 2005-03-07 | 2005-03-07 | Sampling method of matter which releases far infrared ray, minus ion, plastic worked material, composite and food container thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
KR20060098710A true KR20060098710A (en) | 2006-09-19 |
Family
ID=37630090
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020050018605A KR20060098710A (en) | 2005-03-07 | 2005-03-07 | Sampling method of matter which releases far infrared ray, minus ion, plastic worked material, composite and food container thereof |
Country Status (1)
Country | Link |
---|---|
KR (1) | KR20060098710A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100715378B1 (en) * | 2006-08-03 | 2007-05-07 | 전기곤 | Anion generating composition using vegetable material as main ingredient |
KR100715396B1 (en) * | 2006-08-03 | 2007-05-07 | 전기곤 | Method of preparing anion generating composition using vegetable material as main ingredient |
KR100807239B1 (en) * | 2007-02-28 | 2008-02-28 | 고상남 | Plastic resin composition for producing food and beverage container with emission of infrared light and anion |
-
2005
- 2005-03-07 KR KR1020050018605A patent/KR20060098710A/en active IP Right Grant
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100715378B1 (en) * | 2006-08-03 | 2007-05-07 | 전기곤 | Anion generating composition using vegetable material as main ingredient |
KR100715396B1 (en) * | 2006-08-03 | 2007-05-07 | 전기곤 | Method of preparing anion generating composition using vegetable material as main ingredient |
KR100807239B1 (en) * | 2007-02-28 | 2008-02-28 | 고상남 | Plastic resin composition for producing food and beverage container with emission of infrared light and anion |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR100924914B1 (en) | Slow release granules including natural plant extracts and the preparation of the same | |
CN103566874A (en) | Silkworm excrement modified porous active carbon and preparation method thereof | |
CN106219720B (en) | Improve water quality, strengthen immunity, beneficial to composite mineral substance crystal of cardiovascular and cerebrovascular disease and preparation method thereof | |
KR100686616B1 (en) | Preparing method of natural binder for preparing ink | |
KR20060098710A (en) | Sampling method of matter which releases far infrared ray, minus ion, plastic worked material, composite and food container thereof | |
KR101720662B1 (en) | A method for preparing eco-friendly waterproof paint composit | |
KR20160061723A (en) | Method for preparation of wall finishing material | |
KR101658156B1 (en) | Adsorbent-deodorant composition comprising powdered red shale and methyl sulfonyl methane and manufacturing method thereof | |
KR20190009647A (en) | Eco-friendly art materials and method for preparing the same | |
KR20170019132A (en) | Method for manufacturing cosmetic case and cosmetic case manufactured by the same | |
KR102288485B1 (en) | Antibacterial shrinkable tube material and antibacterial shrinkable tube manufactured using the same | |
KR101491470B1 (en) | Manufacturing method of massage ball | |
KR101977102B1 (en) | A manufacturing method of a deodorant containing Boryeong O-stone and Boryeong San mud | |
KR102295706B1 (en) | Manufacturing method for antibiotic shoes insole and antibiotic shoes insole manufactured by the same | |
KR200302464Y1 (en) | The food tool | |
KR20120041488A (en) | Method for improving soil using granite waste powder | |
KR20180060074A (en) | Wall attached type finishing material of interior and manufacturing method thereby | |
CN105418152A (en) | Weather-proof self-cleaning water permeable brick and manufacturing method thereof | |
KR20170069455A (en) | Functional construction material composion and manufacturing method of tile using the same | |
KR102468663B1 (en) | Organic fertilizer manufacturing method using pig hair | |
CN105439611A (en) | Freezing resistant self-cleaning water permeable bricks and preparation method thereof | |
JP2001079567A (en) | Member for water quality improvement | |
KR20030012511A (en) | A method of manufacturing plastic goods including charcoal and goods thereof | |
KR101727304B1 (en) | Composition of synthetic resine pellet having sericite and method of preparing the same | |
KR100787816B1 (en) | Anti-bacteria shock absorber for helmet |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A201 | Request for examination | ||
E902 | Notification of reason for refusal | ||
E902 | Notification of reason for refusal | ||
E701 | Decision to grant or registration of patent right | ||
NORF | Unpaid initial registration fee |