KR20170069455A - Functional construction material composion and manufacturing method of tile using the same - Google Patents

Functional construction material composion and manufacturing method of tile using the same Download PDF

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KR20170069455A
KR20170069455A KR1020150176655A KR20150176655A KR20170069455A KR 20170069455 A KR20170069455 A KR 20170069455A KR 1020150176655 A KR1020150176655 A KR 1020150176655A KR 20150176655 A KR20150176655 A KR 20150176655A KR 20170069455 A KR20170069455 A KR 20170069455A
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weight
parts
raw material
building material
functional building
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KR1020150176655A
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Korean (ko)
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KR101805269B1 (en
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김준수
양철진
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미케노 주식회사
(주)아시아특수재료
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    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/02Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
    • E04C2/26Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00Producing shaped prefabricated articles from the material
    • B28B1/24Producing shaped prefabricated articles from the material by injection moulding
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B16/00Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B16/04Macromolecular compounds
    • C04B16/06Macromolecular compounds fibrous
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/02Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
    • E04C2/04Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of concrete or other stone-like material; of asbestos cement; of cement and other mineral fibres
    • E04C2/06Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of concrete or other stone-like material; of asbestos cement; of cement and other mineral fibres reinforced
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/44Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by the purpose
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/02Flooring or floor layers composed of a number of similar elements
    • E04F15/10Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials
    • E04F15/102Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials of fibrous or chipped materials, e.g. bonded with synthetic resins

Abstract

The present invention relates to a functional building material composition and a method of manufacturing a tile using the functional building material, wherein the functional building material composition is prepared by mixing the raw material prepared by mixing the loess powder, the elm boiled water, the salt and the alum, .

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a functional building material composition,

The present invention relates to a functional building material composition, which is produced by mixing dough fiber and 1,2-hexanediol into a raw material prepared by mixing loess powder, elm boiled water, salt and alum, To a method of manufacturing a tile.

Generally, bricks used as construction materials are provided with cement bricks cemented with cement and sand, and fired bricks (e. G., Red bricks) fired in soil (such as clay). Cement bricks which are relatively inexpensive are mainly used for building walls and the like, while plastic bricks having strong strength, excellent durability and beautiful colors are used as interior and exterior materials of buildings. These conventional architectural tiles and bricks have excellent effects on the physical properties such as aesthetics and durability of buildings, but they are not compatible with modern societies requiring various functions, aesthetics and differentiation.

In modern society, there is a lot of investment in improving the beauty of the city by giving various color and design to the standardization of the gray one side of the various civil and architectural structures, As the national interest and demands for sports, leisure, and sports in everyday life are soaring, the demand for paint materials such as various colored and shaped sidewalk blocks, bicycle roads, bus lanes, coastal embankments and facilities, and park trails facilities is growing rapidly . In addition, wallpaper or tile which expresses a pattern is installed and installed in the wall of the house or the interior of the building or the partition wall.

On the other hand, when taking a sleep or taking a rest in a building made of concrete, the toxicity that occurs in cement induces adult disease, fatigue does not easily loosen, and pain such as shoulder stiffness is caused. In cement and wallpaper and flooring using various adhesives As the "Sick House Syndrome" caused by formaldehyde is becoming more and more popular, there has been a growing interest in building materials using natural ingredients, and a variety of products such as goosomes, bricks and mortars have been developed using loess which is well known for its efficacy.

Recently, yellow clay tiles made by mixing yellow clay with clay and minerals have been spreading.

The loess is chemically an amorphous aluminum silicate containing iron oxide hydrate. The loess used for the building material is obtained by mining and crushing the yellow soil containing iron oxide and then putting it in water and stirring to leave large particles submerged on the floor, Is dispersed in water. The suspension in which the fine particles are dispersed is collected, dried and crushed.

Hwangto has the ability to regulate moisture, which absorbs moisture when moisture content is high, and emits moisture when the surrounding environment is dry, and also accumulates hydration heat, which occurs during the curing process, As the temperature is lowered, it gradually releases heat to reduce the tensile stress. In addition, it emits far-infrared rays useful for the human body and does not cause environmental pollution at the time of disposal, so that it has a feature of suppressing the generation of construction waste, so that the utilization rate of various functional materials including building materials is increasing.

As described above, the yellow clay is useful as a building material, and in order to be used as a building material such as tile or brick, a high-temperature firing process at a temperature of 1000 ° C or more is required to give sufficient strength to the green body. There is a problem that the construction is difficult and careful to use as a flooring material, a wall, or a ceiling material due to limitations due to the characteristics of loess powder or charcoal powder itself having weak strength.

Korean Patent Registration No. 10-0467204 (Antimicrobial Gypsum Board) Korean Registered Patent No. 10-1478637 (Green Panel and Method for Producing Green Panel Using Loess)

Disclosure of the Invention The present invention has been made in order to solve the above-mentioned problems, and it is an object of the present invention to provide a method for producing a pesticide which is produced through environmentally friendly raw materials such as yellow loam, The present invention also provides a functional building material composition which can be used as a building material.

In order to achieve the above-mentioned object, the present invention is characterized in that the raw material prepared by mixing the loess powder, the elm boiled water, the salt and the alum is mixed with the dodecafil and the 1,2-hexanediol.

In the present invention, the raw material is prepared by mixing 50 to 70% by weight of loess powder, 20 to 40% by weight of elm boiled water, 2 to 5% by weight of salt and 2 to 5% by weight of alum .

In addition, the present invention is characterized in that 2 to 10 parts by weight of fiber and 1 to 5 parts by weight of 1,2-hexanediol are mixed with 100 parts by weight of the raw material.

Also, the present invention is characterized in that 1.5 to 1.9 parts by weight of carbon fiber scrap or bazaart fiber is mixed with 100 parts by weight of the functional building material composition.

Further, the present invention relates to a method for producing a raw material, comprising the steps of: preparing a raw material by mixing loess powder, elm boiled water, salt and alum; Removing water contained in the raw material, and then mixing the dodecafil and 1,2-hexanediol to prepare a mixture; And injecting the mixture into a mold, drying the mixture, and then removing the mixture to produce a tile.

The present invention as described above is to provide a functional building material (and a tile manufactured using the same) made of an environmentally friendly raw material such as yellow loam, duck fiber, grapefruit extract oil and the like by the various beneficial effects contained in the loess, And it is possible to create a more pleasant indoor environment in addition to deodorization, insect proof, moisture proof, and the like.

In addition, since dodecafil, grapefruit extract oil, and basalt fiber (or carbon fiber scrap) are added, it has excellent properties such as durability, flexibility and anti-scuffing property, and has an advantage of preventing invasion of insects and insect pests.

BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a process flow diagram for the manufacture of a functional building material composition according to the present invention.
Figure 2 is a manufacturing process for manufacturing a tile using a functional building material composition according to an embodiment of the present invention.
Fig. 3 shows the formula of 1,2 hexanediol used in the present invention.
4 to 5 are results of measuring the breaking strength in the transverse direction of the tile manufactured through the embodiment of the present invention.
FIG. 6 is a table summarizing the results of FIGS.

Hereinafter, a functional building material composition according to the present invention and a method for manufacturing a tile using the same will be described in detail with reference to the accompanying drawings.

The present invention relates to a functional building material composition which is prepared by mixing a raw material prepared by mixing loess powder, elm boiled water, salt and alum, and extracting oil of mulberry fiber and grapefruit seed.

In the present invention, the raw material may be prepared by mixing 50 to 70% by weight of loess powder, 20 to 40% by weight of elm boiled water, 2 to 5% by weight of salt and 2 to 5% by weight of alum.

In the present invention, 2 to 10 parts by weight of the dough fiber and 1 to 5 parts by weight of 1,2-hexanediol may be mixed with 100 parts by weight of the raw material.

The present invention may further comprise 1.5 to 1.9 parts by weight of carbon fiber scrap or basalt fiber per 100 parts by weight of the functional building material composition.

In addition, the present invention can prepare the tile by putting the above-mentioned functional building material composition into a mold, drying it, and then demolding it.

Hwangto isolates various harmful substances generated in the residential space. It has characteristics of far-infrared radiation and nonflammable material including deodorizing and purifying action such as detoxifying power, decomposition power, dehumidifying power and moisturizing power by inherent function. The enzyme component has the functionality of four kinds of enzyme components such as catalase, Diphenol Oxydase, Saccharase and Protease. The catalase acts to remove the toxin, hydrogen peroxide. The toxins generated in the metabolic process in the human body cause aging phenomenon, and the strong absorbing power of the soil prevents the aging phenomenon in which the peroxidized lipid peroxidation is neutralized or diluted. Diphenol Oxydase acts to catalyze the oxidation reaction that takes place with oxygen on the molecule. It is essential to obtain the energy necessary for the synthesis of life and biocomponents, and the redox of various organic / inorganic compounds is made in vivo. Saccharase Saccharase is an enzyme that hydrolyzes sucrose to produce crocosose (glucose) and fructose. Protease hydrolyzes proteins into amino acids when the protein nitrogen is mineralized. It can quickly destroy and destroy other corrupt cells such as unnecessary cancer that are not immunity. The yellow loess with these enzymes generates far infrared rays, promotes blood flow, promotes sweating, excretes waste accumulated in the living body, releases heavy metals, and produces molds with antimicrobial and insecticidal effects. There is an excellent advantage of preventing dehumidification. In addition, it has the function of purifying air pollution which is the cause of chemical and electric radioactive materials, and it has the advantage of being able to purify harmful substances such as formalin, remove tobacco smoke and odor, block harmful electromagnetic waves, filter and control humidity.

In addition, as the particle size of the yellow loam becomes finer, the surface area per unit volume increases, which can maximize the characteristics of the loess such as plasticity, adsorption, absorption and dehydration, suspension and ion exchangeability. As for the method of separating the loess from the extracted loess, it is possible to separate the loose powder by sieving the loess or to mix the loess and the sodium carbonate in the water, and after stirring sufficiently, the large particles are settled on the bottom, The particles are dispersed in water, and the suspension in which the loess fine particles are dispersed is collected, dried and crushed to obtain fine loess.

The present invention can maximize the functionality by taking advantage of the inherent advantages of the loess by using the loess powder having various effects as described above. The above-mentioned loess powder is mixed in an amount of 50 to 70 parts by weight based on 100 parts by weight of the raw material. When the content is less than 50 parts by weight, various effects of the loess can not be exhibited due to the content of the loess.

Next, the elm boiled water is water that is poured into clean water and boiled with elm bark. It not only catalyzes the hardening of the raw material but also prevents the ocher from being scattered and dried after being dried in the form of tiles , And the elm wood component gives off the smell and the waterproof effect can be obtained at the same time.

The elm boiled water is mixed in an amount of 20 to 40 parts by weight based on 100 parts by weight of the raw material, because the curing speed varies depending on the amount of the elm boiled water. The reason for controlling the curing rate is to remove bubbles remaining in the molding die when the mixture formed through the raw materials is poured sequentially into a plurality of molding dies in the form of tiles and if the hardening speed is too high, Can not be removed, so that defective products may occur.

Next, the salt plays a role of rapidly solidifying the yellow loam mixed with the boiled water and enhancing the strength of the loess, and the white lobster effectively blocks and repels insects and insects so that they do not approach each other.

2 to 5 parts by weight of the salt and the alumina are mixed in an amount of 2 to 5 parts by weight with respect to 100 parts by weight of the raw material. If the salt and alumina are mixed in an amount of less than 2 parts by weight, the effect of salt and alum can not be exhibited.

The raw material is aged at room temperature for 12 to 14 hours to remove moisture at a clay level, and 1 to 5 parts by weight of dodecafil and 1 to 5 parts by weight of 1,2-hexanediol are mixed with the raw material to form a mixture.

Duck fiber is a raw material of Korean paper. It is excellent in moldability and environmental friendliness. It can improve the interior function to improve the feeling of Korean paper, improve the humidity control ability, and improve the resistance of environmental skin diseases such as atopy. In the present invention, it is preferable that 2 to 10 parts by weight of the ground fiber is mixed with 100 parts by weight of the raw material. When the dough fiber is mixed in an amount of less than 2 parts by weight, the ability to control the humidity is deteriorated. When the dough fiber is added in an amount of more than 10 parts by weight, excessive molding may not be performed.

The 1,2-hexanediol is an organic compound having a structural formula shown in FIG. The 1,2-hexanediol has hydroxy groups at the 1,2-positions and is used as a moisturizing agent for cosmetics. In addition, it has excellent compatibility with alcohol and the like, has good formability, has high utilization, and is excellent in water solubility. The present invention can produce a dehumidifying power, a moisturizing power and an antibacterial effect of a loess, which is produced through a raw material containing a large amount of loess powder. However, when the loess Therefore, 1,2-hexanediol is added to the raw material. For example, the characteristic of a wall of yellow clay wall is to breathe, but when the wallpaper is blocking the pore, the grass is corrupted and the mold is bloomed. The 1,2-hexanediol is mixed in an amount of 1 to 5 parts by weight based on 100 parts by weight of the raw material. When the content of the 1,2-hexanediol is less than 1 part by weight, the desired preservative effect can not be obtained.

In the present invention, grapefruit seed oil may be used instead of 1,2-hexanediol. Grapefruit is a fruit of a grapefruit tree belonging to the genus Citrus, which has a grape-like flavor and runs like a cluster of grapes. Tangerine-like, round, 10-15 cm in diameter. The crust is leathery and the surface is smooth and yellow. The skin is thin and soft. The flesh is pale yellow, rich in juice, strong in taste, and slightly bitter. The seeds have an antiseptic effect, an antioxidant effect, a deodorizing action and a convergence, and extracts (oils) having preservative ability from such grapefruit seeds.

Next, the present invention may further comprise from 1.8 to 1.9 parts by weight of the basalt fiber or carbon fiber scrap with respect to 100 parts by weight of the functional building material composition.

Basalt fiber is a fibrous natural basalt fiber. It has excellent tensile strength, low density, low thermal expansion, heat resistance, chemical stability, self-lubricating property, elasticity and sound absorption. It is strong against fire and has high tensile strength. . The above-mentioned basalt fibers are superior to conventional glass fibers and are eco-friendly, which is advantageous for interior finishing materials. When the blend is blended in an amount of less than 2 parts by weight, heat resistance and strength are lowered. On the other hand, when the blending ratio is more than 10 parts by weight, There is a problem that molding can not be performed.

Carbon fiber scrap refers to carbon fiber filaments generated during the manufacture of carbon fiber finished products. Carbon fiber is a fiber made by heating and carbonizing organic fiber in an inert gas. Its weight is one quarter of that of iron, its strength is 10 times, its elasticity is 7 times, and we are familiar with acrylic resin It is a fibrous carbon material with a fine graphite crystal structure which is made by making organic materials such as pitch, obtained from petroleum and coal, and then performing a special heat treatment process. These materials are widely used as structural materials by forming composites with so-called matrix materials such as resins and metals. They are generally made of CFRP (carbon fiber reinforced plastics) using thermoplastic and curable resins as a matrix. The carbon fiber scrap is mixed in an amount of 2 to 10 parts by weight based on 100 parts by weight of the functional building material composition. If the carbon fiber scrap is mixed with less than 2 parts by weight, it is difficult to increase the strength due to the content of the carbon fiber scrap. If the amount exceeds 10 parts by weight, There is a problem that it is not possible.

The present invention can be manufactured in the form of a tile by dipping the functional building material composition prepared as described above into a mold and curing it. The surface of the thus-produced tile is filled with a carbon nanotube melt Spray spray coating or silver nano coating.

Carbon nanotubes are formed by combining one carbon with other carbon atoms in a hexagonal honeycomb pattern, and the diameter of the tube is extremely small to the nanometer level and thus exhibits unique electrochemical characteristics. Carbon nanotubes have excellent mechanical properties, electrical selectivity, and excellent field emission properties. When such a carbon nanotube is formed of a thin conductive film, it has antistatic effect because it has high conductivity. In the present invention, the carbon nanotube melt is injected onto the surface of the tile, thereby exhibiting high conductivity of the carbon nanotubes on the surface of the tile, thereby preventing the accumulation of dust on the surface or the burning of the surface due to the antistatic effect.

For coating, it is recommended to dilute the carbon nanotube melt in water to 1/5000 ~ 1 / 20,000 before use. The carbon nanotube melt is a black colored liquid. When the concentration is too high, the color of the tile becomes black rather than the ocher color. If the concentration is too much, the strength enhancement effect and antistatic effect can not be obtained .

In addition, silver has been known to have anti-propagation and bactericidal effects against about 650 kinds of bacteria, bacteria and fungi. Silver nano coating has excellent antimicrobial effect, deodorizing effect, water resistance, durability and abrasion resistance. It has the advantage of extending the life span. The present invention can increase the effects of antibacterial action, deodorization effect, waterproofness and the like by applying silver nano coating on the surface of the produced tile and prolong the life of the product, thereby relieving the burden on maintenance or repurchase of the product .

Meanwhile, in the production of the raw material, 1 to 2 parts by weight of one adhesive paste selected from glutinous rice paste, daphnia, seaweed paste or starch paste is further mixed with 100 parts by weight of the total composition to increase binding force of the loess powder, It is possible to have a more excellent strength when it is produced in the form of

A method of making a tile using the functional building material composition according to the present invention is described in Example 1 below.

Example 1.

70% by weight of loess powder, 25% by weight of elm boiled water, 3% by weight of salt and 2% by weight of alum were mixed to prepare a raw material. Then, the raw material was aged at 25 캜 for 14 hours at room temperature to remove moisture, 10 parts by weight of dodecafil and 3 parts by weight of 1,2-hexanediol were mixed with 100 parts by weight of the composition, and 1.9 parts by weight of carbon fiber scrap was mixed with 100 parts by weight of the entire composition to prepare a functional building material composition according to the present invention.

The following Table 1 shows various examples of the functional building material composition according to the present invention. Examples 2 to 3 and Comparative Examples 1 to 4 shown in Table 1 were prepared in the same manner as in Example 1 above.

4 to 6 are the results of measurement of the transverse rupture strength in the transverse direction of the tiles produced through the functional building material composition prepared in Examples 1 to 3 and Comparative Examples 1 to 4.

division Example Comparative Example 1 (C1) 2 (C2) 3 (C3) 1 (G1) 2 (G2) 3 (G3) 4 (G4) Loess powder 70 63 55 73 45 75 40 Elm
Boiled water
25 30 40 21 45 20 55
Salt 3 4 3 4 5 - 5 Alpine 2 3 2 2 5 5 - Duck fiber 10 5 7 2 5 10 3 Grapefruit
Extraction oil
3 One 2 One 3 One 5
Carbon fiber
scrap
1.9 1.9 1.8 - One 0.3 0.5

As can be seen from Tables 1 and 6, the tiles produced through the functional building material composition (Example 1) produced according to the preferred embodiment of the present invention were found to have excellent fracture strength, It can be seen that the tear strength of the tile prepared from the mixture prepared as a result of the deviation of the reference value (content ratio) of the present invention as shown in Fig.

As described above, the present invention can obtain the effect of enhancing human health by various beneficial effects contained in loess, and can provide a more pleasant indoor environment in addition to deodorization, insect repellence, moisture proof, and the like. (Such as carbon fiber scraps) are added to the surface of the carbon nanotubes, so that the physical properties such as durability, flexibility and anti-scratch property are excellent, and invasion of insects and insect pests can be prevented. In addition, the surface of the tile is coated with the carbon nanotube melt so that dust can be prevented from accumulating on the surface due to the prevention of static electricity.

Claims (5)

Wherein the functional building material composition is prepared by mixing duck fiber and 1,2-hexanediol in a raw material prepared by mixing loess powder, elm boiled water, salt and alum.
The method according to claim 1, wherein the raw material is prepared by mixing 50 to 70% by weight of loess powder, 20 to 40% by weight of elm boiled water, 2 to 5% by weight of salt and 2 to 5% Functional building material composition.
[2] The functional building material composition according to claim 1, wherein 2 to 10 parts by weight of dodecafil and 1 to 5 parts by weight of 1,2-hexanediol are added to 100 parts by weight of the raw material.
4. The functional building material composition according to claim 3, wherein 1.5 to 1.9 parts by weight of carbon fiber scrap or basalt fiber is mixed with 100 parts by weight of the functional building material composition.
Mixing the loess powder, the elm boiled water, the salt and the alum to prepare a raw material;
Removing water contained in the raw material, and then mixing the dodecafil and 1,2-hexanediol to prepare a mixture; And
Adding the mixture to a mold, drying the mixture, and then removing the mixture to prepare a tile;
≪ RTI ID = 0.0 > 1, < / RTI >
KR1020150176655A 2015-12-11 2015-12-11 Functional construction material composion and manufacturing method of tile using the same KR101805269B1 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102042779B1 (en) * 2019-03-12 2019-11-08 에코엔텍주식회사 The soil fill materials enhanced strength and manufacturing method of the same
KR20210097943A (en) * 2020-01-31 2021-08-10 고영호 Method for manufacturing of vesicular korea paper tile, and the vesicular korea paper tile manufactured by the method

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100833898B1 (en) * 2007-12-05 2008-06-02 고영진 Method of manufacturing a loess finishing board of construction
KR101420649B1 (en) * 2014-02-07 2014-07-17 (주)삼화케익블럭 Method of manufacturing Natural Pulp Board

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102042779B1 (en) * 2019-03-12 2019-11-08 에코엔텍주식회사 The soil fill materials enhanced strength and manufacturing method of the same
KR20210097943A (en) * 2020-01-31 2021-08-10 고영호 Method for manufacturing of vesicular korea paper tile, and the vesicular korea paper tile manufactured by the method

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