KR20050079896A - Method of preparing fabric - Google Patents
Method of preparing fabric Download PDFInfo
- Publication number
- KR20050079896A KR20050079896A KR1020050000422A KR20050000422A KR20050079896A KR 20050079896 A KR20050079896 A KR 20050079896A KR 1020050000422 A KR1020050000422 A KR 1020050000422A KR 20050000422 A KR20050000422 A KR 20050000422A KR 20050079896 A KR20050079896 A KR 20050079896A
- Authority
- KR
- South Korea
- Prior art keywords
- phthalate
- fibers
- fabric
- coating
- flame retardant
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 47
- 239000004744 fabric Substances 0.000 title claims abstract description 29
- 239000000835 fiber Substances 0.000 claims abstract description 33
- 238000000576 coating method Methods 0.000 claims abstract description 22
- 239000011248 coating agent Substances 0.000 claims abstract description 19
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 claims abstract description 17
- 239000004014 plasticizer Substances 0.000 claims abstract description 17
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000009941 weaving Methods 0.000 claims abstract description 15
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000001361 adipic acid Substances 0.000 claims abstract description 9
- 235000011037 adipic acid Nutrition 0.000 claims abstract description 9
- 239000003063 flame retardant Substances 0.000 claims abstract description 9
- 239000008199 coating composition Substances 0.000 claims abstract description 7
- 238000004804 winding Methods 0.000 claims abstract description 6
- 239000002952 polymeric resin Substances 0.000 claims description 12
- 229920003002 synthetic resin Polymers 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 9
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 7
- 239000004800 polyvinyl chloride Substances 0.000 claims description 7
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 claims description 4
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 4
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 claims description 4
- JQCXWCOOWVGKMT-UHFFFAOYSA-N diheptyl phthalate Chemical compound CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC JQCXWCOOWVGKMT-UHFFFAOYSA-N 0.000 claims description 4
- 239000012796 inorganic flame retardant Substances 0.000 claims description 4
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 claims description 3
- 229920000388 Polyphosphate Polymers 0.000 claims description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 3
- 239000001205 polyphosphate Substances 0.000 claims description 3
- 235000011176 polyphosphates Nutrition 0.000 claims description 3
- BAZVBVCLLGYUFS-UHFFFAOYSA-N 1-o-butyl 2-o-dodecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC BAZVBVCLLGYUFS-UHFFFAOYSA-N 0.000 claims description 2
- ALKCLFLTXBBMMP-UHFFFAOYSA-N 3,7-dimethylocta-1,6-dien-3-yl hexanoate Chemical compound CCCCCC(=O)OC(C)(C=C)CCC=C(C)C ALKCLFLTXBBMMP-UHFFFAOYSA-N 0.000 claims description 2
- GPZYYYGYCRFPBU-UHFFFAOYSA-N 6-Hydroxyflavone Chemical compound C=1C(=O)C2=CC(O)=CC=C2OC=1C1=CC=CC=C1 GPZYYYGYCRFPBU-UHFFFAOYSA-N 0.000 claims description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000007983 Tris buffer Substances 0.000 claims description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical group CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 2
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical group FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 claims description 2
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 claims description 2
- 229960001826 dimethylphthalate Drugs 0.000 claims description 2
- DROMNWUQASBTFM-UHFFFAOYSA-N dinonyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCC DROMNWUQASBTFM-UHFFFAOYSA-N 0.000 claims description 2
- YCZJVRCZIPDYHH-UHFFFAOYSA-N ditridecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCCCC YCZJVRCZIPDYHH-UHFFFAOYSA-N 0.000 claims description 2
- QQVHEQUEHCEAKS-UHFFFAOYSA-N diundecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCC QQVHEQUEHCEAKS-UHFFFAOYSA-N 0.000 claims description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 2
- 239000000347 magnesium hydroxide Substances 0.000 claims description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- -1 polyethylene Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- HQUQLFOMPYWACS-UHFFFAOYSA-N tris(2-chloroethyl) phosphate Chemical compound ClCCOP(=O)(OCCCl)OCCCl HQUQLFOMPYWACS-UHFFFAOYSA-N 0.000 claims description 2
- GTRSAMFYSUBAGN-UHFFFAOYSA-N tris(2-chloropropyl) phosphate Chemical compound CC(Cl)COP(=O)(OCC(C)Cl)OCC(C)Cl GTRSAMFYSUBAGN-UHFFFAOYSA-N 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims 1
- UCVPKAZCQPRWAY-UHFFFAOYSA-N dibenzyl benzene-1,2-dicarboxylate Chemical compound C=1C=CC=C(C(=O)OCC=2C=CC=CC=2)C=1C(=O)OCC1=CC=CC=C1 UCVPKAZCQPRWAY-UHFFFAOYSA-N 0.000 claims 1
- 230000002496 gastric effect Effects 0.000 claims 1
- 229920000728 polyester Polymers 0.000 abstract description 16
- 229920005989 resin Polymers 0.000 abstract description 15
- 239000011347 resin Substances 0.000 abstract description 15
- 239000003086 colorant Substances 0.000 abstract description 9
- 239000011521 glass Substances 0.000 abstract description 4
- 238000002834 transmittance Methods 0.000 abstract description 4
- 210000002784 stomach Anatomy 0.000 abstract description 2
- 239000003365 glass fiber Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 4
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- 229920000092 linear low density polyethylene Polymers 0.000 description 2
- 239000004707 linear low-density polyethylene Substances 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61H—PHYSICAL THERAPY APPARATUS, e.g. DEVICES FOR LOCATING OR STIMULATING REFLEX POINTS IN THE BODY; ARTIFICIAL RESPIRATION; MASSAGE; BATHING DEVICES FOR SPECIAL THERAPEUTIC OR HYGIENIC PURPOSES OR SPECIFIC PARTS OF THE BODY
- A61H33/00—Bathing devices for special therapeutic or hygienic purposes
- A61H33/06—Artificial hot-air or cold-air baths; Steam or gas baths or douches, e.g. sauna or Finnish baths
- A61H33/066—Cabins therefor
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61H—PHYSICAL THERAPY APPARATUS, e.g. DEVICES FOR LOCATING OR STIMULATING REFLEX POINTS IN THE BODY; ARTIFICIAL RESPIRATION; MASSAGE; BATHING DEVICES FOR SPECIAL THERAPEUTIC OR HYGIENIC PURPOSES OR SPECIFIC PARTS OF THE BODY
- A61H33/00—Bathing devices for special therapeutic or hygienic purposes
- A61H33/06—Artificial hot-air or cold-air baths; Steam or gas baths or douches, e.g. sauna or Finnish baths
- A61H33/063—Heaters specifically designed therefor
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61H—PHYSICAL THERAPY APPARATUS, e.g. DEVICES FOR LOCATING OR STIMULATING REFLEX POINTS IN THE BODY; ARTIFICIAL RESPIRATION; MASSAGE; BATHING DEVICES FOR SPECIAL THERAPEUTIC OR HYGIENIC PURPOSES OR SPECIFIC PARTS OF THE BODY
- A61H33/00—Bathing devices for special therapeutic or hygienic purposes
- A61H33/60—Components specifically designed for the therapeutic baths of groups A61H33/00
- A61H33/6005—Special constructive structural details of the bathtub, e.g. of the walls or supporting structure
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61H—PHYSICAL THERAPY APPARATUS, e.g. DEVICES FOR LOCATING OR STIMULATING REFLEX POINTS IN THE BODY; ARTIFICIAL RESPIRATION; MASSAGE; BATHING DEVICES FOR SPECIAL THERAPEUTIC OR HYGIENIC PURPOSES OR SPECIFIC PARTS OF THE BODY
- A61H33/00—Bathing devices for special therapeutic or hygienic purposes
- A61H33/06—Artificial hot-air or cold-air baths; Steam or gas baths or douches, e.g. sauna or Finnish baths
- A61H2033/061—Artificial hot-air baths
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61H—PHYSICAL THERAPY APPARATUS, e.g. DEVICES FOR LOCATING OR STIMULATING REFLEX POINTS IN THE BODY; ARTIFICIAL RESPIRATION; MASSAGE; BATHING DEVICES FOR SPECIAL THERAPEUTIC OR HYGIENIC PURPOSES OR SPECIFIC PARTS OF THE BODY
- A61H2201/00—Characteristics of apparatus not provided for in the preceding codes
- A61H2201/02—Characteristics of apparatus not provided for in the preceding codes heated or cooled
- A61H2201/0207—Characteristics of apparatus not provided for in the preceding codes heated or cooled heated
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61H—PHYSICAL THERAPY APPARATUS, e.g. DEVICES FOR LOCATING OR STIMULATING REFLEX POINTS IN THE BODY; ARTIFICIAL RESPIRATION; MASSAGE; BATHING DEVICES FOR SPECIAL THERAPEUTIC OR HYGIENIC PURPOSES OR SPECIFIC PARTS OF THE BODY
- A61H2201/00—Characteristics of apparatus not provided for in the preceding codes
- A61H2201/10—Characteristics of apparatus not provided for in the preceding codes with further special therapeutic means, e.g. electrotherapy, magneto therapy or radiation therapy, chromo therapy, infrared or ultraviolet therapy
Landscapes
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Epidemiology (AREA)
- Pain & Pain Management (AREA)
- Physical Education & Sports Medicine (AREA)
- Rehabilitation Therapy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
본 발명은 유리섬유(Glass fiber) 또는 폴리에스테르 섬유에 고분자 물질을 코팅하는 제조 방법에 관한 것으로서, 이 제조 방법은 경사용(유리, 폴리에스테르)섬유 및 위사용(유리, 폴리에스테르)섬유에 고분자 수지(프탈산계 또는 아디픽산계 가소제 및 난연제를 포함하는 코팅 조성물)를 코팅하고; 상기 코팅된 경사용 섬유를 권취 및 정경하고; 상기 정경된 경사용 섬유와 상기 위사용 섬유를 제직하고; 상기 제직된 생성물을 텐타(tenter)하는 공정을 포함한다.The present invention relates to a manufacturing method for coating a polymeric material on glass fibers or polyester fibers, the manufacturing method is a polymer for warp (glass, polyester) fibers and stomach use (glass, polyester) fibers Coating a resin (a coating composition comprising a phthalic acid or adipic acid based plasticizer and a flame retardant); Winding and mirroring the coated warp fibers; Weaving the regular warp fibers and the weft fibers; And tentering the woven product.
본 발명의 제조 방법은 실 자체에 수지 코팅을 실시할 수 있어, 원하는 밝기의 빛의 투과율을 조절할 수 있고, 수지 코팅이 균일한 실로 직물을 제조할 수 있어 고급 제품 생산이 가능하며, 원하는 무늬를 직물 제작시 여러가지 색상 및 모양으로 표현할 수 있고, 공정이 간단하여 경제적이다.The production method of the present invention can be applied to the resin coating on the yarn itself, it is possible to adjust the transmittance of light of the desired brightness, to produce a fabric with a uniform resin coating can be produced a high-quality product, the desired pattern The fabric can be expressed in various colors and shapes, and the process is simple and economical.
Description
[산업상 이용 분야][Industrial use]
본 발명은 직물의 제조 방법에 관한 것으로서, 더욱 상세하게는 실에 직접 수지 코팅하여 원하는 밝기의 투과율을 조절할 수 있는 직물의 제조 방법에 관한 것이다.The present invention relates to a fabrication method, and more particularly, to a fabrication method capable of adjusting the transmittance of the desired brightness by resin coating directly on the yarn.
[종래 기술][Prior art]
폴리에스테르 섬유는 탄성이 우수하고, 주름이 잘 잡히지 않으며, 형태 견지성과 고강도를 가진 탁월한 특성들을 많이 지녔으며, 이러한 특성들 때문에 의복용 섬유로서 널리 사용되고 있다.Polyester fibers are excellent in elasticity, poorly wrinkled, have a lot of excellent properties of shape retention and high strength, and because of these properties, they are widely used as garment fibers.
이러한 폴리에스테르 섬유는 일반적으로 수지 가공을 하여 사용하며, 폴리에스테르 섬유 수지 가공은 폴리에스테르 섬유로 정경(세로 방향), 제직(베를 짜는 과정) 과정을 통하여 원단을 제조하고, 여기에 폴리비닐클로라이드 등의 필름을 적층하여 원단전체를 코팅한다. 그러나 이와 같이 원단을 제조한 후, 수지 코팅을 실시하는 경우, 빛의 투과량을 조절할 수 없고, 무늬를 표현하기 위해서는 제직시 표현할 수 없고, 수지 코팅시 색상을 넣을 수 있어 무늬를 표현하는데 인쇄만으로 가능하여, 섬세하고 정교한 무늬 표현이 어렵다.These polyester fibers are generally used by resin processing, and polyester fiber resin processing is made of polyester fiber to prepare a fabric through a regular (vertical), weaving (weaving) process, and polyvinyl chloride The entire fabric is coated by laminating such films. However, after manufacturing the fabric in this way, when the resin coating is applied, it is not possible to control the amount of light transmission, and in order to express the pattern can not be expressed when weaving, the color can be put in the resin coating can be printed only to express the pattern This makes it difficult to express delicate and sophisticated patterns.
이러한 문제점을 해결하고자 유리 또는 폴리에스테르 섬유 자체에 코팅하기 위한 시도가 있었으나, 이 경우 코팅이 잘 되지 않고, 균일하게 둥근 상태의 우수한 품질의 코팅사가 얻어지지 않고, 납작한 코팅사가 얻어져 실제 적용하기는 불가능한 품질의 실이 얻어졌다.In order to solve this problem, there have been attempts to coat the glass or polyester fiber itself, but in this case, the coating is not good, and a good quality coating yarn of a uniformly rounded state is not obtained, and a flat coating yarn is obtained, so that the actual application is not possible. A thread of impossible quality was obtained.
본 발명은 상술한 문제점을 해결하기 위한 것으로서, 본 발명의 목적은 실 자체에 수지 코팅을 실시할 수 있어 고품질의 유리 또는 폴리에스테르 직물을 제조할 수 있는 직물의 제조 방법을 제공하는 것이다.SUMMARY OF THE INVENTION The present invention has been made to solve the above problems, and an object of the present invention is to provide a method for producing a fabric which can apply a resin coating to the yarn itself to produce a high quality glass or polyester fabric.
상기 목적을 달성하기 위하여, 본 발명은 경사용 섬유 및 위사용 섬유에 고분자 수지, 프탈산계 또는 아디픽산계 가소제 및 난연제를 포함하는 코팅 조성물로 코팅하고; 상기 코팅된 경사용 섬유를 권취 및 정경하고; 상기 정경된 경사용 섬유와 상기 위사용 섬유를 제직하고; 상기 제직된 생성물을 텐타하는 공정을 포함하는 직물의 제조 방법을 제공한다.In order to achieve the above object, the present invention is coated with a coating composition comprising a polymeric resin, a phthalic acid or adipic acid-based plasticizer and a flame retardant on the warp fiber and the stomach fiber; Winding and mirroring the coated warp fibers; Weaving the regular warp fibers and the weft fibers; It provides a method for producing a fabric comprising the step of tenting the woven product.
이하 본 발명을 더욱 상세하게 설명한다.Hereinafter, the present invention will be described in more detail.
본 발명은 원사에 직접 수지 가공을 실시하여, 고품질의 원사를 제조하는 방법에 관한 것이다.TECHNICAL FIELD This invention relates to the method of manufacturing a high quality yarn by giving resin processing directly to a yarn.
본 발명의 제조 방법은 먼저, 경사(세로실)용 섬유 및 위사(가로실)용 섬유를 고분자 수지, 프탈산계 또는 아디픽산계 가소제 및 난연제를 포함하는 코팅 조성물로 코팅한다. In the production method of the present invention, first, the warp (vertical yarn) fibers and the weft yarn (garden yarn) fibers are coated with a coating composition containing a polymer resin, a phthalic acid or adipic acid plasticizer, and a flame retardant.
상기 고분자 수지로는 폴리비닐 클로라이드, 폴리우레탄, 폴리에틸렌 또는 폴리올레핀 등을 사용 할 수 있다. 상기 폴리비닐 클로라이드 수지를 사용하는 경우 중합도가 800 내지 3000인 것을 사용하는 것이 바람직하다. 폴리비닐 클로라이드 수지의 중합도가 3000보다 크면 내열성이나 내노후성은 증가하나 가공성이 떨어지며, 폴리비닐 클로라이드 코팅 온도가 상승됨에 따라 작업이 어려워지는 문제점이 있다. 또한, 상기 중합도가 800보다 낮으면 가공성과 표면은 좋아지나, 내열성과 내후성이 떨어지는 문제점이 있다. As the polymer resin, polyvinyl chloride, polyurethane, polyethylene or polyolefin may be used. When using the polyvinyl chloride resin, it is preferable to use a polymerization degree of 800 to 3000. When the degree of polymerization of the polyvinyl chloride resin is greater than 3000, heat resistance or aging resistance is increased, but workability is decreased, and as the polyvinyl chloride coating temperature is increased, the operation becomes difficult. In addition, when the degree of polymerization is lower than 800, workability and surface are improved, but heat resistance and weather resistance are poor.
또한 상기 폴리에틸렌 수지를 사용하는 경우 선형저밀도 폴리에틸렌(LLDP), 저밀도 폴리에틸렌(LDPE), 고밀도 폴리에틸렌(HDPE) 모두 사용 가능하다. 상기 가소제는 프탈산계 가소제나, 아디픽산계 가소제를 사용하며, 프탈산계 가소제로는 디옥틸 프탈레이트, 디부틸 프탈레이트, 디메틸 프탈레이트, 디에틸 프탈레이트, 디헵틸 프탈레이트, 디노닐 프탈레이트, 디이소데실 프탈레이트, 디운데실 프탈레이트, 디트리데실 프탈레이트, 부틸벤질 프탈레이트, 부틸라우릴 프탈레이트 또는 이들의 혼합물을 사용할 수 있고, 상기 프탈산계 가소제의 사용량은 상기 고분자 수지 100 중량부당 15 내지 60 중량부가 바람직하고, 30 내지 50 중량부가 더욱 바람직하다.In addition, when using the polyethylene resin, both linear low density polyethylene (LLDP), low density polyethylene (LDPE), high density polyethylene (HDPE) can be used. The plasticizer may be a phthalic acid plasticizer or an adipic acid plasticizer, and the phthalic acid plasticizer may be dioctyl phthalate, dibutyl phthalate, dimethyl phthalate, diethyl phthalate, diheptyl phthalate, dinonyl phthalate, diisodecyl phthalate, di- Undecyl phthalate, ditridecyl phthalate, butylbenzyl phthalate, butyllauryl phthalate or a mixture thereof may be used, and the amount of the phthalic acid-based plasticizer is preferably 15 to 60 parts by weight per 100 parts by weight of the polymer resin, and 30 to 50 The weight part is more preferable.
상기 아디픽산계 가소제로는 디옥틸 아디페이트, 디이소노닐 아디페이트, 디이소데실 아디페이트 또는 이들의 혼합물을 사용할 수 있고, 그 사용량은 상기 고분자 수지 100 중량부당 15 내지 60 중량부가 바람직하고, 30 내지 50 중량부가 더욱 바람직하다. 아디픽산계 가소제의 사용량이 상기 고분자 수지 100 중량부당 60 중량부를 초과하면 난연성이 떨어지며, 내이행성이 좋지 않고, 15 중량부보다 적으면 제품이 너무 경질화되고 신율이 좋지 않아 코팅 후 제직에 문제가 있다.As the adipic acid-based plasticizer, dioctyl adipate, diisononyl adipate, diisodecyl adipate, or a mixture thereof may be used, and the amount of the adipic acid plasticizer is preferably 15 to 60 parts by weight per 100 parts by weight of the polymer resin. 50 weight part is more preferable. If the amount of the adipic acid-based plasticizer exceeds 60 parts by weight per 100 parts by weight of the polymer resin, the flame retardancy is poor. The performance is poor, and if the amount is less than 15 parts by weight, the product is too hard and the elongation is not good. have.
사용된 난연제로는 무기계 난연제 또는 할로겐계 및 인계 난연제가 사용되며, 상기 무기계 난연제로는 수산화 마그네슘, 수산화 알루미늄, 삼산화 안티몬 또는 이들의 혼합물을 하나 또는 하나 이상 혼합하여 사용하며, 상기 할로겐계 및 인계 난연제로는 트리스(2,4-디클로로프로필)포스페이트, 트리스(2-클로로프로필)포스페이트, 트리스(2-크로로에틸)포스페이트, 염소화 폴리포스페이트 또는 이들의 혼합물의 염소화 유기 폴리포스페이트를 사용하며, 그 사용량은 고분자 수지 100 중량부 당 3 내지 100 중량부가 바람직하고, 더욱 바람직하게는 10 내지 30 중량부가 바람직하다. 난연제의 사용량이 고분자 수지 100 중량부 당 3 중량부보다 적으면 난연성이 떨어지고, 100 중량부보다 크면 내한성이 떨어지고 가공성이 떨어져 바람직하지 않다.As the flame retardant used, an inorganic flame retardant or a halogen-based and phosphorus-based flame retardant may be used. The inorganic flame retardant may include one or more mixtures of magnesium hydroxide, aluminum hydroxide, antimony trioxide, or a mixture thereof. The furnace uses chlorinated organic polyphosphate of tris (2,4-dichloropropyl) phosphate, tris (2-chloropropyl) phosphate, tris (2-chloroethyl) phosphate, chlorinated polyphosphate or mixtures thereof, 3-100 weight part is preferable per 100 weight part of silver polymer resin, More preferably, it is 10-30 weight part. If the amount of the flame retardant is less than 3 parts by weight per 100 parts by weight of the polymer resin, the flame retardancy is inferior, and if it is greater than 100 parts by weight, the cold resistance is poor and the workability is poor, which is not preferable.
또한 상기 코팅 조성물에 폴리에스테르 섬유 제조시 일반적으로 사용되는 첨가제, 예를 들어 아조계, 시아닌계 학책제 및 이미다졸계 항균제 등을 더욱 첨가할 수도 있다. 이는 당해 분야에 널리 알려진 내용이므로 본 명세서에서 자세한 설명은 생략하기로 한다.In addition, additives generally used in the preparation of polyester fibers, such as azo, cyanine, and imidazole antibacterial agents, may be further added to the coating composition. Since this is well known in the art, detailed description thereof will be omitted.
상기 코팅 공정은 130℃ 내지 190℃에서 실시한다. 코팅 공정의 온도가 130℃ 미만이 되면 코팅사의 표면이 거칠어지고, 190℃를 초과하면 황변 현상 및 동심도 유지가 안되어 바람직하지 않다.The coating process is carried out at 130 ℃ to 190 ℃. If the temperature of the coating process is less than 130 ℃ rough surface of the coating yarn, if it exceeds 190 ℃ yellowing phenomenon and concentricity is not maintained is not preferable.
상기 코팅된 경사용 섬유를 권취 및 정경한다. 권취 공정이란 경사를 정경 공정을 실시할 수 있도록 준비하는 공정을 의미한다. 상기 정경 공정이란 직물 제조 공정에서 경사(세로실)를 설계된 직물의 길이, 밀도, 폭 등에 맞도록 빔(beam)에 감는 작업을 말하며, 필요에 따라 원하는 실의 가닥수, 원하는 길이만큼 감는 작업을 의미한다.The coated warp fibers are wound and polished. A winding process means the process of preparing an inclination to perform a regular process. The canon process refers to a process of winding an inclined (vertical thread) to a beam to match the length, density, width, etc. of a designed fabric in a fabric manufacturing process, and to wind the work by the desired number of strands and a desired length as needed. it means.
상기 정경된 경사용 섬유와 상기 코팅된 위사용 섬유를 제직한다. 제직 공정이란 상기 경사에 대하여 직각으로 위사를 일정한 규칙에 따라 경사 1가닥 또는 2가닥마다 아래 위로 서로 교차시켜 직물을 만드는 공정을 말한다. 이 공정에서 원하는 무늬를 표현할 수 있다. 즉, 종래 공정에서는 직물을 제조한 후, 필름 라미네이팅을 실시하므로, 원하는 무늬에 따라 제직하여도 라미네이팅 공정을 실시하는 과정에서 그 무늬가 거의 나타나지 않게 되는 단점이 있었으나, 본 발명의 공정에서는 그러한 단점이 없다.Weaving the warp inclined fibers and the coated weft fibers. The weaving process refers to a process of weaving the weft yarns at a right angle to the warp by crossing each other up and down every one or two warps according to a predetermined rule. In this process, a desired pattern can be expressed. That is, in the conventional process, since the film is laminated after manufacturing the fabric, there is a disadvantage in that the pattern is hardly shown in the process of performing the laminating process even if weaving according to the desired pattern. none.
상기 제직된 생성물을 텐타(tenter)하여 직물을 제조한다. 텐타 공정이란 직물, 즉 원단 제조시 마무리 공정 단계의 하나로서, 텐타기를 사용하여 직물의 폭을 일정하게 고정시켜주는 공정으로서, 텐타기에서 직물의 양쪽 변사 부분을 핀이나 클립으로 잡아서 위사 방향으로 일정 폭을 유지하는 상황에서 텐타의 온도를 약 180 내지 약 200℃까지 승온하여 고정시키는 공정을 말한다. 즉, 이 공정은 제직된 생성물에 열을 가하여 고착화하는 공정으로서, 실이 밀리는 현상을 방지하기 위하여 붙이는 작업을 말한다.The woven product is tentered to produce a fabric. Tenta process is a process of finishing the fabric, that is, the process of finishing the fabric.It is a process to fix the width of the fabric uniformly using a tenter. It refers to a process of raising the temperature of the tenter to about 180 to about 200 ° C and fixing it in a situation of maintaining a constant width. That is, this step is a step of fixing the woven product by applying heat to fix it, and refers to an operation for pasting in order to prevent the thread from being pushed.
상기 제직 공정 이후, 상기 텐타 공정 전에 제직된 생성물을 검사하고 세척하는 생지 검단 공정을 더욱 실시할 수도 있다.After the weaving process, a dough screening process of inspecting and washing the product woven before the tenter process may be further performed.
이러한 본 발명의 제조 방법은 실에 직접 코팅하므로 원하는 밝기의 빛의 투과율을 조절하여 제품 생산이 가능하며, 코팅된 실 한가닥 한가닥 코팅 상태가 둥글게 되어 고급 제품을 생산할 수 있고, 위사의 권취 공정을 실시할 필요가 없어 공정이 간단하다. 제조된 직물은 사무용 롤 블라인드, 노천 카페의 그늘막, 해변 의자 등 다양한 용도로 사용될 수 있다.Since the manufacturing method of the present invention is directly coated on the yarn, it is possible to produce the product by adjusting the light transmittance of the desired brightness, and the coated state of the single strand of the coated yarn can be rounded to produce a high-quality product, and the winding process of the weft is performed. There is no need to do so the process is simple. Fabrics can be used for a variety of applications, such as office roll blinds, shades of open air cafes, beach chairs.
본 발명의 바람직한 실시예 및 비교예를 기재한다. 그러나 하기한 실시예는 본 발명의 바람직한 일 실시예일 뿐 본 발명이 하기한 실시예에 한정되는 것은 아니다.Preferred examples and comparative examples of the present invention are described. However, the following examples are only one preferred embodiment of the present invention and the present invention is not limited to the following examples.
(실시예 1)(Example 1)
폴리에스테르 섬유를 코팅 조성물로 170℃에서 코팅하였다. 이 코팅 조성물은 중합도 1,000의 폴리비닐클로라이드 수지 62 중량%에 프탈산계 가소제인 디이소데실 프탈레이트 26 중량% 및 무기계 난연제인 수산화알루미늄 2 중량%를 첨가하고, 아조계 착색제 및 이미다졸계 항균제의 첨가제를 10 중량% 첨가하여 제조하였다. Polyester fibers were coated at 170 ° C. with the coating composition. The coating composition was added to 62% by weight of polyvinyl chloride resin having a degree of polymerization of 1,000, and 26% by weight of diisodecyl phthalate as a phthalic plasticizer and 2% by weight of aluminum hydroxide as an inorganic flame retardant, and an additive of an azo colorant and an imidazole antibacterial agent. It was prepared by adding 10% by weight.
상기 코팅된 폴리에스테르 섬유를 권취 및 정경하고, 제직하고 생지 검단 공정을 실시한 후, 180℃의 열을 가하는 텐타 공정을 실시하여 폴리에스테르 코팅 직물을 제조하였다. 상기 제직 공정은 실 교차가 촘촘하게 되도록 실시하였다.The coated polyester fibers were wound and polished, weaved and subjected to a dough screening process, followed by a tenter process of applying a heat of 180 ° C. to prepare a polyester coated fabric. The weaving process was carried out so that the thread crossing was denser.
(실시예 2)(Example 2)
제직 공정을 실 교차가 다소 느슨하게 되도록 실시한 것을 제외하고는 상기 실시예 1과 동일하게 실시하였다.The weaving process was carried out in the same manner as in Example 1 except that the yarn crossing was somewhat loosened.
상기 공정에서 착색제 종류를 다양하게 변경하여 다양한 색상의 폴리에스테르 코팅 직물을 제조하였으며, 그 결과를 도 1 내지 도 4에 각각 나타내었다. 도 1 내지 도 4에 나타낸 것과 같이, 본 발명의 실시예의 공정에 따라 다양한 무늬를 갖는 직물을 제조할 수 있다. 또한 착색제 종류를 다양하게 사용하여 두가지 색상을 나타내는 섬유를 제조한 결과를 도 5 내지 도 7에 각각 나타내었다. 도 5 내지 도 7에 나타낸 것과 같이, 종래 공정으로는 불가능하였던 본 발명의 공정은 두 가지 색상을 나타내는 섬유를 제조할 수 있다.Various kinds of colorants were changed in the above process to prepare polyester coated fabrics of various colors, and the results are shown in FIGS. 1 to 4, respectively. As shown in Figures 1 to 4, it is possible to produce a fabric having a variety of patterns according to the process of the embodiment of the present invention. In addition, the results of preparing fibers showing two colors using various kinds of colorants are shown in FIGS. 5 to 7, respectively. 5-7, the process of the present invention, which was not possible with conventional processes, can produce fibers that exhibit two colors.
아울러, 상기 실시예 1 및 2와 기존에 시판되는 폴리에스테르 코팅 직물의 공극율을 측정한 결과 실시예 1은 공극율 0%, 실시예 2는 5.5%였으며, 기존에 시판되는 폴리에스테르 코팅 직물의 공극율은 0%였다. 즉, 본 발명의 공정은 직물을 제직하는 공정 전에 코팅 공정을 실시하므로 공극율은 소비자가 원하는 대로 맞추어 조절할 수 있으나, 종래 공정은 제직 공정을 실시한 후, 코팅 필름을 부착시킴에 따라 공극율을 조절할 수가 없음을 알 수 있다.In addition, as a result of measuring the porosity of the polyester coating fabrics commercially available in Examples 1 and 2, Example 1 was a porosity of 0%, Example 2 was 5.5%, the porosity of the conventional polyester coating fabric is 0%. That is, the process of the present invention is carried out before the process of weaving the fabric, so that the porosity can be adjusted according to the consumer's desire, but the conventional process is not able to adjust the porosity by attaching the coating film after the weaving process. It can be seen.
상술한 것과 같이, 본 발명의 제조 방법은 실 자체에 수지 코팅을 실시할 수 있어, 원하는 밝기의 빛의 투과율을 조절할 수 있고, 수지 코팅이 균일한 실로 직물을 제조할 수 있어 고급 제품 생산이 가능하며, 원하는 무늬를 직물 제작시 여러가지 색상 및 모양으로 표현할 수 있고, 공정이 간단하여 경제적이다. As described above, the production method of the present invention can be applied to the resin coating on the yarn itself, it is possible to adjust the transmittance of light of the desired brightness, to produce a fabric with a uniform resin coating can be produced high-quality products In addition, the desired pattern can be expressed in various colors and shapes during fabric production, and the process is simple and economical.
도 1 내지 도 4는 본 발명의 실시예에 따라 제조된 다양한 모양을 나타내는 직물을 나타내는 사진.1 to 4 is a photograph showing a fabric representing a variety of shapes made in accordance with an embodiment of the present invention.
도 5 내지 도 7은 본 발명의 실시예에 따라 제조된 두 가지 색상을 나타내는 섬유를 나타낸 사진. 5 to 7 is a photograph showing a fiber representing two colors produced according to an embodiment of the present invention.
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KR100888808B1 (en) * | 2008-08-04 | 2009-03-13 | 에코얀주식회사 | Polyester yarn fiber coating composition |
EP2562208A1 (en) | 2011-08-25 | 2013-02-27 | Alkenz Co., Ltd. | Environmentally friendly coated yarn and coating compostion therefor |
KR20150053116A (en) | 2013-11-07 | 2015-05-15 | 주식회사 알켄즈 | Fabric woven from extruded yarn and anti-fuzzing flooring material comprising same |
KR20170137458A (en) | 2016-06-03 | 2017-12-13 | 김기혁 | High elasticity coated yarn using elastomer resin and manufacturing methods of thereof |
KR20200079137A (en) | 2018-12-24 | 2020-07-02 | 다이텍연구원 | Eco-friendly coating yarn, preparation method thereof, and woven fabric therefrom |
WO2020228255A1 (en) * | 2019-05-10 | 2020-11-19 | 宁波先锋新材料股份有限公司 | High thermal-insulation and flame-retardant fiber thread, manufacturing method therefor, and high thermal-insulation and flame-retardant sunshade fabric based on fiber thread |
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KR101957749B1 (en) | 2017-01-12 | 2019-03-14 | 삼성교역(주) | Method for manufacturing high stretch coating yarn |
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JPH04370278A (en) * | 1991-06-13 | 1992-12-22 | Unitika Ltd | Production of resin-coated sheet |
KR950009259B1 (en) * | 1993-08-19 | 1995-08-18 | 주식회사경인 | A manufacturing method of excellent weather and soil resistance fabric for placard |
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KR100888808B1 (en) * | 2008-08-04 | 2009-03-13 | 에코얀주식회사 | Polyester yarn fiber coating composition |
EP2562208A1 (en) | 2011-08-25 | 2013-02-27 | Alkenz Co., Ltd. | Environmentally friendly coated yarn and coating compostion therefor |
KR101286628B1 (en) * | 2011-08-25 | 2013-07-22 | 주식회사 알켄즈 | Environmentally friendly coating yarn, preparation method thereof, woven fabrics therefrom and coating composition used therefor |
KR20150053116A (en) | 2013-11-07 | 2015-05-15 | 주식회사 알켄즈 | Fabric woven from extruded yarn and anti-fuzzing flooring material comprising same |
KR20170137458A (en) | 2016-06-03 | 2017-12-13 | 김기혁 | High elasticity coated yarn using elastomer resin and manufacturing methods of thereof |
KR20200079137A (en) | 2018-12-24 | 2020-07-02 | 다이텍연구원 | Eco-friendly coating yarn, preparation method thereof, and woven fabric therefrom |
WO2020228255A1 (en) * | 2019-05-10 | 2020-11-19 | 宁波先锋新材料股份有限公司 | High thermal-insulation and flame-retardant fiber thread, manufacturing method therefor, and high thermal-insulation and flame-retardant sunshade fabric based on fiber thread |
KR102190365B1 (en) | 2020-08-11 | 2020-12-11 | 주식회사 대웅에프엔티 (F.N.T) | Polyolefin-based flame retardant yarn |
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