JP7234472B2 - curtain fabric - Google Patents

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JP7234472B2
JP7234472B2 JP2019136641A JP2019136641A JP7234472B2 JP 7234472 B2 JP7234472 B2 JP 7234472B2 JP 2019136641 A JP2019136641 A JP 2019136641A JP 2019136641 A JP2019136641 A JP 2019136641A JP 7234472 B2 JP7234472 B2 JP 7234472B2
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sheath
fabric
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JP2021021154A (en
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宏一 手島
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Kuraray Trading Co Ltd
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本発明は、防炎性、撥水性、審美性に優れたカーテン用織編物に関する。 TECHNICAL FIELD The present invention relates to a woven or knitted fabric for curtains which is excellent in flame resistance, water repellency and aesthetics.

カーテンには用途や目的に応じ、様々な素材、様々な機能などを選択し作製された生地が用いられる。求められている機能の一つに撥水性があり、その撥水性は主にフッ素系樹脂、シリコン樹脂などの表面張力を下げる効果のある樹脂によりなされている。しかしながら、これらのフッ素系樹脂、シリコン樹脂などは、経時的に撥水性の効果が小さくなったり、法律で定められているホテルなどのシャワーカーテンなどの用途で求められる防炎性能を付与しようにも樹脂の存在が繊維を芯としたろうそく現象のため防炎性能を阻害してしまい、撥水性と防炎性を同時に達成することが困難であった。 Curtains are made of fabrics that are made by selecting various materials and functions according to the application and purpose. One of the required functions is water repellency, and the water repellency is mainly achieved by resins that have the effect of lowering the surface tension, such as fluorine-based resins and silicon resins. However, these fluorine-based resins and silicone resins lose their water-repellent effect over time, and it is difficult to provide the fire-retardant performance required by law for applications such as hotel shower curtains. The existence of the resin impairs the flameproof performance due to the candle phenomenon with the fiber as the core, making it difficult to achieve both water repellency and flameproof property at the same time.

また、撥水性と防炎性を同時に達成するために塩化ビニル製などのフィルムを使用する場合があるが、色や柄に大きな制約をもち、カーテンの審美性の部分を大きく犠牲にしてしまうことになっている。 In some cases, vinyl chloride film is used to simultaneously achieve water repellency and flame resistance, but this has major restrictions on colors and patterns, and greatly sacrifices the aesthetics of curtains. It has become.

例えば、特許文献1(特開2013-155459号公報)では、撥水性と防炎性(難燃性)を同時に達成するため、非ハロゲン系難燃剤を含有するポリエステル繊維を50重量%以上使用して構成され、かつワックス系撥水剤が付着された生地のカーテンが開示されている。しかしながら、ワックス系撥水剤が付着されると生地が硬くなる傾向があり、また、耐洗濯性に劣るなど撥水性の耐久性に劣るため、撥水性の効果が必要な場所でのカーテンとしては不向きである。 For example, in Patent Document 1 (Japanese Patent Application Laid-Open No. 2013-155459), in order to achieve water repellency and flame resistance (flame retardancy) at the same time, 50% by weight or more of polyester fiber containing a non-halogen flame retardant is used. A fabric curtain is disclosed which is constructed of a woven fabric and to which a wax-based water repellent is applied. However, when a wax-based water repellent is attached, the fabric tends to harden, and the durability of the water repellency is poor, such as poor resistance to washing. unsuitable.

特開2013-155459号公報JP 2013-155459 A

本発明は、上記のような課題を解決するためになされたものであり、すなわち、リン成分を含み、鞘成分がポリプロピレン、芯成分がポリエステルである芯鞘型複合繊維を使用することで、耐久性のある防炎性と撥水性を同時に持ち、分散染料による審美性も表現でき、カーテン等に好適に用いることができる織編物を得ることを目的としている。 The present invention has been made to solve the above-described problems, that is, by using a core-sheath type composite fiber containing a phosphorus component, a polypropylene sheath component, and a polyester core component, a durable fiber can be obtained. To obtain a woven or knitted fabric which has flame retardancy and water repellency at the same time, can express aesthetics with disperse dyes, and can be suitably used for curtains and the like.

すなわち、本発明は、以下の好適な態様を提供するものである。
[1]芯成分がポリエステル、鞘成分がポリプロピレンで構成された芯鞘型複合繊維を含む織編物であって、前記芯鞘型複合繊維の少なくとも芯成分にリン成分を含み、前記芯鞘型複合繊維に含まれるリン成分の含有量が繊維全体の重量に対して5000~20000ppmであり、前記芯鞘型複合繊維が前記織編物全体の95重量%以上含むことを特徴とする、織編物。
[2]前記芯鞘型複合繊維において、芯成分のみにリン成分を含み、リン成分の含有量が芯成分の重量に対して8000~25000ppmであることを特徴とする、前記[1]に記載の織編物。
[3]前記芯鞘型複合繊維において、芯成分と鞘成分の比率が重量比で5/5~9/1であることを特徴とする、前記[1]または[2]に記載の織編物。
[4]さらに、繊維内に吸塵されるタイプの防炎剤を含むことを特徴とする、前記[1]~[3]のいずれかに記載の織編物。
[5]前記[1]~[4]のいずれかに記載の織編物を少なくとも一部に用いたカーテン。
That is, the present invention provides the following preferred aspects.
[1] A woven or knitted fabric containing a core-sheath type composite fiber having a core component of polyester and a sheath component of polypropylene, wherein at least the core component of the core-sheath type composite fiber contains a phosphorus component, and the core-sheath type composite A woven or knitted fabric, characterized in that the content of the phosphorus component contained in the fiber is 5000 to 20000 ppm with respect to the weight of the entire fiber, and the core-sheath type composite fiber comprises 95% by weight or more of the entire woven or knitted fabric.
[2] The above-mentioned [1], wherein the core-sheath type composite fiber contains a phosphorus component only in the core component, and the content of the phosphorus component is 8000 to 25000 ppm based on the weight of the core component. Woven and knitted fabrics.
[3] The woven or knitted fabric according to [1] or [2], wherein the weight ratio of the core component to the sheath component in the core-sheath type composite fiber is 5/5 to 9/1. .
[4] The woven or knitted fabric according to any one of the above [1] to [3], further comprising a flameproofing agent of a type that collects dust in the fibers.
[5] A curtain at least partly made of the woven or knitted fabric according to any one of [1] to [4].

本発明によれば、カーテン等に好適に用いることができる、防炎性、撥水性、審美性に優れた織編物を得ることができる。 According to the present invention, it is possible to obtain a woven or knitted fabric excellent in fire resistance, water repellency and aesthetics, which can be suitably used for curtains and the like.

本発明の実施形態に係る複合繊維の同心芯鞘タイプを示す概略断面図である。1 is a schematic cross-sectional view showing a concentric core-sheath type composite fiber according to an embodiment of the present invention; FIG. 本発明の実施形態に係る複合繊維の偏心芯鞘タイプを示す概略断面図である。1 is a schematic cross-sectional view showing an eccentric core-sheath type composite fiber according to an embodiment of the present invention. FIG. 本発明の実施形態に係る複合繊維の多芯芯鞘タイプを示す概略断面図である。1 is a schematic cross-sectional view showing a multicore core-sheath type composite fiber according to an embodiment of the present invention. FIG. 本発明の実施形態に係る複合繊維の異形鞘芯鞘タイプを示す概略断面図である。1 is a schematic cross-sectional view showing a deformed sheath-core-sheath type composite fiber according to an embodiment of the present invention. FIG. 本発明の実施形態に係る複合繊維の凹凸交互多角形芯芯鞘タイプを示す概略断面図である。1 is a schematic cross-sectional view showing a core-core-sheath type conjugated fiber having uneven alternating polygons according to an embodiment of the present invention. FIG.

以下、本発明について詳細に説明する。本発明でいうポリエステル、ポリプロピレンとはJIS L0204-2の用語、定義に従う。 The present invention will be described in detail below. The polyester and polypropylene referred to in the present invention conform to the terms and definitions of JIS L0204-2.

本発明の織編物を構成する芯鞘型複合繊維には、防炎性の観点からリン成分を含むことが重要である。前記リン成分は、添加剤として練りこまれていてもよく、モノマーとして使用され共重合としてポリマーの組成の一部としてもよく、その両方で含んでいてもよい。また、リン成分は芯成分のみに含まれてもよく、芯成分、鞘成分の両方に含まれてもよい。防炎性の観点からは、芯成分、鞘成分の両方に含まれることが好ましく、紡糸性、取り扱いのしやすさの観点からは、芯成分のみに含まれることが好ましい。 It is important that the core-sheath type conjugate fibers constituting the woven or knitted fabric of the present invention contain a phosphorus component from the viewpoint of flame resistance. The phosphorus component may be kneaded as an additive, may be used as a monomer and may be part of the polymer composition as a copolymer, or may be included in both. Also, the phosphorus component may be contained only in the core component, or may be contained in both the core component and the sheath component. From the viewpoint of flame resistance, it is preferably contained in both the core component and the sheath component, and from the viewpoints of spinnability and ease of handling, it is preferably contained only in the core component.

上記リン成分を添加剤として練り込む場合は、例えば赤リン系、リン酸エステル系、有機ホスホン酸系、有機ホスフィン酸系が挙げられ、白色であること、経時的安定性の観点から有機ホスホン酸系、有機ホスフィン酸系が好ましい。 When the phosphorus component is kneaded as an additive, for example, red phosphorus, phosphoric acid ester, organic phosphonic acid, and organic phosphinic acid can be mentioned, and from the viewpoint of whiteness and stability over time, organic phosphonic acid organic phosphinic acid systems are preferred.

上記リン成分がモノマーとして使用され共重合としてポリマーの組成の一部とする場合は、例えば有機ホスホン酸系、有機ホスフィン酸系が挙げられ、反応制御性観点から有機ホスフィン酸系が好ましい。 When the phosphorus component is used as a monomer and is part of the composition of the polymer as a copolymer, for example, organic phosphonic acids and organic phosphinic acids are exemplified, and organic phosphinic acids are preferred from the viewpoint of reaction controllability.

上記リン成分の含有量は、芯鞘型複合繊維全体の重量に対して5000~20000ppmであることが重要である。上記下限値より小さい場合は例え、染色加工工程で防炎剤を付与しても十分な防炎性が得られず不適であり、上記上限値より大きい場合は十分な紡糸性が得られず不適である。リン成分の含有量は、好ましくは8000~18000ppm、より好ましくは10000~15000ppmである。 It is important that the content of the phosphorus component is 5,000 to 20,000 ppm with respect to the total weight of the core-sheath type composite fiber. If it is less than the above lower limit, even if a flame retardant is added in the dyeing process, it is not suitable because sufficient flame resistance cannot be obtained. is. The content of the phosphorus component is preferably 8000-18000 ppm, more preferably 10000-15000 ppm.

芯成分のみにリン成分を含む場合のリン成分の含有量は、芯成分の重量に対して8000~25000ppmであることが好ましい。上記下限値より小さい場合は例え、染色加工工程で防炎剤を付与しても十分な防炎性が得られない場合があり、上記上限値より大きい場合は十分な紡糸性が得られない場合がある。芯成分のリン成分の含有量はより好ましくは10000~23000ppm、さらに好ましくは12000~20000ppmである。 When only the core component contains the phosphorus component, the content of the phosphorus component is preferably 8000 to 25000 ppm based on the weight of the core component. If it is less than the above lower limit, sufficient flame retardancy may not be obtained even if a flame retardant is added in the dyeing process, and if it is larger than the above upper limit, sufficient spinnability may not be obtained. There is The content of the phosphorus component in the core component is more preferably 10000-23000 ppm, more preferably 12000-20000 ppm.

本発明の織編物を構成する芯鞘型複合繊維において、鞘成分がポリプロピレンであることが重要である。ポリプロピレンはそれ自体が撥水性の機能を有しているため、撥水性を有する生地を得るためには繊維の表面全体をポリプロピレンで覆われた繊維を用いることで達成される。さらに、高水温中では分散染料、防炎剤を通過させることができる。それゆえ、芯鞘型複合繊維の鞘成分がポリプロピレンであることが重要である。 In the core-sheath type conjugate fiber constituting the woven or knitted fabric of the present invention, it is important that the sheath component is polypropylene. Since polypropylene itself has a water-repellent function, fabrics with water-repellency can be obtained by using fibers whose entire surfaces are covered with polypropylene. In addition, disperse dyes and flame retardants can pass through at high water temperatures. Therefore, it is important that the sheath component of the core-sheath type conjugate fiber is polypropylene.

また、本発明の織編物を構成する芯鞘型複合繊維において、芯成分がポリエチレンテレフタレートなどのポリエステルであることが重要である。ポリエステルは分散染料で染色させることができ、さらには染色加工工程により防炎剤を繊維内部に保持することができる。そのため、審美性に富む生地としたり、防炎性能を向上させるうえでも芯鞘型複合繊維の芯成分がポリエステルであることが重要である。 Moreover, in the core-sheath type conjugate fiber constituting the woven or knitted fabric of the present invention, it is important that the core component is a polyester such as polyethylene terephthalate. Polyester can be dyed with disperse dyes, and the dyeing process can retain the flame retardant inside the fibers. Therefore, it is important that the core component of the core-sheath type composite fiber is polyester in order to make the fabric rich in aesthetics and to improve flameproof performance.

本発明の織編物を構成する芯鞘型複合繊維において、芯成分と鞘成分の比率に特に制限はないが、芯/鞘の重量比が5/5~9/1であることが好ましい。芯成分の比率が上記上限値より大きいと紡糸性が困難となる場合があり、芯成分の比率が上記下限値より小さいと染料が入りにくくなり審美性が低下する場合があり、また、鞘成分のポリプロピレンの比率が高くなるため防炎性が低下する場合がある。芯/鞘の重量比はより好ましくは6/4~9/1であり、さらに好ましくは6/4~8/2である。 In the core-sheath type conjugate fiber constituting the woven or knitted fabric of the present invention, the ratio of the core component to the sheath component is not particularly limited, but the core/sheath weight ratio is preferably 5/5 to 9/1. If the ratio of the core component is higher than the above upper limit, spinnability may become difficult. Flame resistance may decrease due to the high proportion of polypropylene in The core/sheath weight ratio is more preferably 6/4 to 9/1, more preferably 6/4 to 8/2.

本発明の織編物を構成する芯鞘型複合繊維の断面形状は、芯部が鞘部に完全に覆われていればよく、それを満たしていれば形状は自由に選択できる。例えば、通常は図1のように芯部と鞘部が互いに同心円状であるが、図2のように互いの中心がずれている偏心状でも構わない。また図3のように芯部が複数あっても構わない。芯部の数に関しては、特に制限はないが、紡糸性の観点から芯が12個以下が好ましく、4個以下がより好ましい。また芯、鞘の形状としても特に制約がなく、例えば、図4のように鞘が三角断面、芯が丸断面、図5のように鞘が丸断面、芯が凹凸交互多角形断面などが挙げられる。特に図5のような芯部と鞘部の接触面積が大きい断面は、芯部と鞘部の剥離が起こりにくいという面において好ましい。 The cross-sectional shape of the core-sheath type conjugate fiber constituting the woven or knitted fabric of the present invention may be selected as long as the core is completely covered with the sheath, and the shape can be freely selected as long as it satisfies this condition. For example, the core portion and the sheath portion are usually concentric with each other as shown in FIG. 1, but they may be eccentric as shown in FIG. Moreover, as shown in FIG. 3, there may be a plurality of core portions. The number of cores is not particularly limited, but from the viewpoint of spinnability, the number of cores is preferably 12 or less, more preferably 4 or less. There are no particular restrictions on the shape of the core and sheath. For example, as shown in FIG. 4, the sheath has a triangular cross-section and the core has a circular cross-section, and as shown in FIG. be done. In particular, a cross-section with a large contact area between the core and the sheath, as shown in FIG. 5, is preferable in that separation between the core and the sheath is less likely to occur.

本発明の織編物を構成する芯鞘型複合繊維において、総繊度、フィラメント数に特に制限はないが、カーテン用に使用される糸としては、総繊度は30~350dtexが好ましく、50~250dtexがより好ましい。またフィラメント数は6~300フィラメントが好ましく、12~150フィラメントがより好ましい。 In the core-sheath type conjugate fiber constituting the woven or knitted fabric of the present invention, the total fineness and the number of filaments are not particularly limited. more preferred. The number of filaments is preferably 6 to 300 filaments, more preferably 12 to 150 filaments.

本発明の織編物において、上記芯鞘型複合繊維が織編物生地の95重量%以上含むことが重要である。防炎性を得るためには、生地成分の均一性が重要で、同じ繊維で生地を構成されることが好ましい。上記芯鞘型複合繊維の割合が上記下限値より小さい場合、染色加工工程で防炎剤を付与しても十分な防炎性が得られない。また、撥水性の観点においても、上記芯鞘型複合繊維でない部分は撥水性が得られないため、上記芯鞘型複合繊維が全体を占める量が多いことが好ましい。織編物における芯鞘型複合繊維の割合は、96重量%以上であることが好ましく、100重量%であることがより好ましい。 In the woven or knitted fabric of the present invention, it is important that the above-mentioned core-sheath type conjugate fiber accounts for 95% by weight or more of the woven or knitted fabric. In order to obtain flame resistance, the uniformity of the composition of the fabric is important, and it is preferable that the fabric is composed of the same fibers. If the proportion of the core-sheath type conjugate fiber is less than the above lower limit, sufficient flameproofness cannot be obtained even if a flameproofing agent is applied in the dyeing process. In addition, from the viewpoint of water repellency, it is preferable that the amount of the core-sheath type conjugate fiber occupying the entirety is large because water repellency cannot be obtained in the portion other than the core-sheath type conjugate fiber. The ratio of the core-sheath type conjugate fibers in the woven or knitted fabric is preferably 96% by weight or more, more preferably 100% by weight.

本発明の織編物において、目付に特に制限はないが、カーテン用途では30~400g/mが好ましい。防炎性能は目付が小さいほど得やすいため、30~300g/mがより好ましく、30~200g/mがさらに好ましい。 In the woven or knitted fabric of the present invention, the basis weight is not particularly limited, but is preferably 30 to 400 g/m 2 for curtain applications. Since flameproof performance is more likely to be obtained as the basis weight is smaller, 30 to 300 g/m 2 is more preferable, and 30 to 200 g/m 2 is even more preferable.

使用する分散染料量、生地の目付等により、防炎性が不足する場合、生地作製後、染色加工工程などで防炎剤を付与することが好ましい。その際、通常のDIP-NIP方式による防炎剤付与は生地が撥水性を有するため付着量や防炎剤固定が困難であることから、浴中処理によって繊維内に吸塵されるタイプの防炎剤を芯成分のポリエステル部に保持させることで付与することが好ましい。 If the flame retardancy is insufficient due to the amount of disperse dyes used, the basis weight of the fabric, etc., it is preferable to add a flame retardant during the dyeing process after fabric production. At that time, it is difficult to apply the flame retardant by the usual DIP-NIP method because the fabric has water repellency, so it is difficult to attach the amount of flame retardant and to fix the flame retardant. It is preferable to apply the agent by holding it in the polyester portion of the core component.

上記防炎剤としてはハロゲンを主体とする防炎剤、リンを主体とする防炎剤、ハロゲンとリンの両方を含んだ防炎剤が挙げられ、これらのうち1種類以上を用いることが好ましい。 Examples of the flame retardant include halogen-based flame retardants, phosphorus-based flame retardants, and flame retardants containing both halogen and phosphorus. It is preferable to use at least one of these. .

上記防炎剤は、処理する生地に対して、3~25%owfの量を高圧染色機などに付与し、浴比1:5~1:20で、処理温度100~135℃の条件で生地に防炎剤を吸塵、保持させることが好ましい。 The flame retardant is applied to a high-pressure dyeing machine or the like in an amount of 3 to 25% owf on the fabric to be treated, and the fabric is treated at a bath ratio of 1:5 to 1:20 and a treatment temperature of 100 to 135 ° C. It is preferable that the flameproof agent is sucked up and retained.

使用する防炎剤の量に特に制限はないが、通常3~25%owfとすることが好ましい。上記下限値未満であれば防炎効果の付与が小さい場合がある。また、上記上限値より大きいとポリエステルに吸塵されない防炎剤が増え、防炎剤が無駄になるだけでなく、防炎剤に起因した汚れが生地に付着する場合がある。 Although there is no particular limitation on the amount of the flame retardant used, it is usually preferred to use 3 to 25% owf. If the content is less than the above lower limit, the flame retardant effect may be small. On the other hand, if the above upper limit is exceeded, the amount of the flameproofing agent that is not absorbed by the polyester increases, and not only is the flameproofing agent wasted, but also stains caused by the flameproofing agent may adhere to the fabric.

また、浴中処理の浴比も特に制限はないが、通常1:5~1:20で行う。上記下限値未満であれば、均一な加工がしにくく、上記上限値より大きいと浴中処理を効率よく行えない場合がある。 Also, the bath ratio of the in-bath treatment is not particularly limited, but is usually 1:5 to 1:20. If it is less than the above lower limit, it is difficult to perform uniform processing, and if it is above the above upper limit, in-bath treatment may not be performed efficiently.

さらに、処理温度も特に制限がないものの、通常100~135℃で行う。上記下限値未満では防炎剤の吸塵が十分でなく効果が小さい場合があり、上記上限値より大きいと高圧染色機への負荷が大きくなるだけでなく、ポリエステルの加水分解が促進され劣化の一因となる場合がある。浴中処理を染色と同時にする場合は、分散染料の吸塵、保持のため、120~135℃であることが好ましい。 Furthermore, although the treatment temperature is not particularly limited, it is usually carried out at 100 to 135°C. If it is less than the above lower limit, the dust absorption of the flame retardant may not be sufficient and the effect may be small. may be the cause. When the in-bath treatment is performed at the same time as the dyeing, the temperature is preferably 120 to 135° C. for dust absorption and retention of disperse dyes.

以下、実施例をもって本発明を説明するが、これにより本発明の範囲が制限されるものではない。 The present invention will now be described with reference to Examples, which are not intended to limit the scope of the present invention.

なお、防炎性能はJIS L1091 A-1法の着炎3秒後の燃焼面積で評価した(単位:平方センチメートル)。ただし、測定前にJIS L0001 140法の洗濯方法に従い、10回洗濯したものを使用した。本実施例では30cm以下を防炎性大、30cm超過45cm以下を防炎性中、45cm超過を防炎性なしとした。 The flameproof performance was evaluated by the burning area (unit: square centimeter) after 3 seconds of ignition according to JIS L1091 A-1 method. However, before the measurement, according to the washing method of JIS L0001 140 method, the one washed 10 times was used. In this example, 30 cm 2 or less was rated as high flame resistance, over 30 cm 2 and up to 45 cm 2 as medium flame resistance, and over 45 cm 2 as low flame resistance.

撥水性はJIS L1092 撥水度試験にて評価した。ただし、測定前にJIS L0001 140法の洗濯方法に従い、10回洗濯したものを使用した。 The water repellency was evaluated by the JIS L1092 water repellency test. However, before the measurement, according to the washing method of JIS L0001 140 method, the one washed 10 times was used.

審美性は、ポリエステル部を分散染料で染色し、着色表現したものを審美性ありとした。 Aesthetics were evaluated by dyeing the polyester part with a disperse dye to express color.

(実施例1)
芯成分としてポリエチレンテレフタレート(クラレ製(防炎剤を含む前のポリマーの溶融粘度130Pa・s(290℃)))に防炎剤(DIC製 商品名「EXR3000」)を33重量%含む樹脂(リン成分濃度15000ppm)を使用し、鞘成分としてポリプロピレン(プライムポリマー製(溶融粘度62Pa・s(260℃)))を使用して、芯/鞘=8/2の重量比で溶融紡糸にて芯鞘型複合繊維84dtex/24フィラメントを作製した(断面形状:図1)。この複合繊維中のリン成分濃度は12000ppmであった。その後、この糸のみを用いてタテ105本/2.54cm、ヨコ95本/2.54cmの平織生地を作製し、生地精練の後、乾燥、仕上げセット加工を行った。この生地の防炎性能は35cmで、防炎性を示した。また、撥水性は4級であった。
(Example 1)
A resin (phosphorus component concentration 15000 ppm), polypropylene (made of prime polymer (melt viscosity 62 Pa s (260 ° C.))) is used as the sheath component, and the core/sheath is melt-spun at a weight ratio of core/sheath = 8/2. A type composite fiber 84 dtex/24 filament was produced (cross-sectional shape: FIG. 1). The phosphorus component concentration in this composite fiber was 12000 ppm. Thereafter, using only this yarn, a plain weave fabric having a length of 105 threads/2.54 cm and a width of 95 threads/2.54 cm was produced. The flameproof performance of this fabric was 35 cm 2 , indicating flameproof properties. Moreover, the water repellency was grade 4.

(実施例2)
実施例1で作製した仕上げセット加工後の生地を、一般的な青色分散染料2%owf、浴比1:8にて高圧染色機で130℃にて処理した。この生地は着色して審美性を持ち、さらに防炎性能は30cmで、高い防炎性を示した。また、撥水性は4級であった。
(Example 2)
The finished fabric produced in Example 1 was treated at 130° C. with a high-pressure dyeing machine using 2% owf of a common blue disperse dye and a liquor ratio of 1:8. This fabric was colored and had an aesthetic appearance, and had a flameproof performance of 30 cm 2 , demonstrating high flameproof performance. Moreover, the water repellency was grade 4.

(実施例3)
実施例1で作製した仕上げセット加工後の生地を、一般的な青色分散染料2%owf、臭素系防炎剤(丸菱油化工業製、商品名「UR7」)10%owf、浴比1:8にて高圧染色機で130℃にて処理した。この生地は着色して審美性を持ち、さらに防炎性能は10cmで、高い防炎性を示した。また、撥水性は4級であった。
(Example 3)
The fabric after the finish set processing produced in Example 1 was mixed with a general blue disperse dye 2%owf, a brominated flame retardant (manufactured by Marubishi Yuka Kogyo, trade name "UR7") 10%owf, and a bath ratio of 1 :8 in a high pressure dyeing machine at 130°C. This fabric was colored and had an aesthetic appearance, and had a flameproof performance of 10 cm 2 , demonstrating high flameproof performance. Moreover, the water repellency was grade 4.

(実施例4)
実施例1で作製した仕上げセット加工後の生地を、リン系防炎剤(丸菱油化工業製、商品名「R031-5」)3%owsの液にDIPし、それをローラー間でNIPしておよそ生地重量に対し80重量%の溶液を保持させた。その後乾燥、キュアし、さらに洗浄して乾燥、セットした。この生地の防炎性能は40cmで、防炎性を示したが、DIP-NIPで防炎剤を付与した効果は見られなかった。また、撥水性は3級であった。
(Example 4)
DIP the fabric after finishing set processing prepared in Example 1 in a 3% ows liquid of phosphorus flame retardant (manufactured by Marubishi Yuka Kogyo Co., Ltd., trade name "R031-5"), and NIP it between rollers to retain approximately 80% solution by weight to dough weight. It was then dried, cured, washed, dried and set. The flameproof performance of this fabric was 40 cm 2 , indicating flameproof properties, but the effect of adding a flameproof agent by DIP-NIP was not observed. Moreover, the water repellency was grade 3.

(実施例5)
実施例1で作製した仕上げセット加工後の生地を、一般的な青色分散染料2%owf、浴比1:8にて高圧染色機で130℃にて処理した。そして、リン系防炎剤(丸菱油化工業製、商品名「R031-5」)3%owsの液にDIPし、それをローラー間でNIPしておよそ生地重量に対し80重量%の溶液を保持させた。その後乾燥、キュアし、さらに洗浄して乾燥、セットした。この生地は着色して審美性を持ち、防炎性能は35cmで、防炎性を示したが、DIP-NIPで防炎剤を付与した効果は見られなかった。また、撥水性は3級であった。
(Example 5)
The finished fabric produced in Example 1 was treated at 130° C. with a high-pressure dyeing machine using 2% owf of a common blue disperse dye and a liquor ratio of 1:8. Then, the phosphorus-based flame retardant (manufactured by Marubishi Yuka Kogyo Co., Ltd., product name "R031-5") is dipped in a 3% ows liquid, and then NIPed between rollers to obtain a solution of about 80% by weight based on the weight of the fabric. was retained. It was then dried, cured, washed, dried and set. This fabric was colored and aesthetically pleasing, and had a flame retardant performance of 35 cm 2 , demonstrating flame retardant properties. Moreover, the water repellency was grade 3.

(実施例6)
芯成分としてポリエチレンテレフタレート(クラレ製(防炎剤を含む前のポリマーの溶融粘度130Pa・s(290℃)))に防炎剤(DIC製 商品名「EXR3000」)を33重量%含む樹脂(リン成分濃度15000ppm)を使用し、鞘成分としてポリプロピレン(プライムポリマー製(ポリマーの溶融粘度62Pa・s(260℃)))を使用して、芯/鞘=6/4の重量比で溶融紡糸にて芯鞘型複合繊維84dtex/24フィラメントを作製した(断面形状:図1)。この複合繊維中のリン成分濃度は9000ppmであった。その後、この糸のみを用いてタテ105本/2.54cm、ヨコ95本/2.54cmの平織生地を作製し、生地精練の後、乾燥、仕上げセット加工を行った。さらにこの生地を、一般的な青色分散染料2%owf、臭素系防炎剤(丸菱油化工業製、商品名「UR7」)10%owf、浴比1:8にて高圧染色機で130℃にて処理した。この生地は着色して審美性を持ち、さらに防炎性能は25cmで、高い防炎性を示した。また、撥水性は4級であった。
(Example 6)
A resin (phosphorus component concentration 15000 ppm), using polypropylene (made of prime polymer (polymer melt viscosity 62 Pa s (260 ° C.))) as a sheath component, using melt spinning at a weight ratio of core / sheath = 6/4 A core-sheath type composite fiber 84 dtex/24 filament was produced (cross-sectional shape: FIG. 1). The phosphorus component concentration in this composite fiber was 9000 ppm. Thereafter, using only this yarn, a plain weave fabric having a length of 105 threads/2.54 cm and a width of 95 threads/2.54 cm was produced. Furthermore, this fabric is treated with a general blue disperse dye 2% owf, a brominated flame retardant (manufactured by Marubishi Yuka Kogyo, trade name "UR7") 10% owf, and a bath ratio of 1:8 with a high-pressure dyeing machine. °C. This fabric was colored and had an aesthetic appearance, and had a flameproof performance of 25 cm 2 , demonstrating high flameproof performance. Moreover, the water repellency was grade 4.

(実施例7)
芯成分としてポリエチレンテレフタレート(クラレ製(防炎剤を含む前のポリマーの溶融粘度130Pa・s(290℃)))に防炎剤(DIC製 商品名「EXR3000」)を33重量%含む樹脂(リン成分濃度15000ppm)を使用し、鞘成分としてポリプロピレン(プライムポリマー製(防炎剤を含む前のポリマーの溶融粘度62Pa・s(260℃)))に防炎剤(DIC製 商品名「EXR3000」)を33重量%含む樹脂(リン成分濃度15000ppm)を使用して、芯/鞘=5/5の重量比で溶融紡糸にて芯鞘型複合繊維84dtex/24フィラメントを作製した(断面形状:図1)。この複合繊維中のリン成分濃度は15000ppmであった。その後、この糸のみを用いてタテ105本/2.54cm、ヨコ95本/2.54cmの平織生地を作製し、生地精練の後、乾燥、仕上げセット加工を行った。さらにこの生地を、一般的な青色分散染料2%owf、臭素系防炎剤(丸菱油化製 商品名UR7)10%owf、浴比1:8にて高圧染色機で130℃にて処理した。この生地は着色して審美性を持ち、さらに防炎性能は10cmで、高い防炎性を示した。また、撥水性は4級であった。
(Example 7)
A resin (phosphorus component concentration 15000 ppm), and as a sheath component polypropylene (made of prime polymer (melt viscosity of polymer before containing flame retardant: 62 Pa s (260 ° C))) flame retardant (DIC product name “EXR3000”) Using a resin containing 33% by weight of (phosphorus component concentration 15000 ppm), a core-sheath type composite fiber 84 dtex / 24 filament was produced by melt spinning at a weight ratio of core / sheath = 5/5 (cross-sectional shape: Fig. 1 ). The phosphorus component concentration in this composite fiber was 15000 ppm. Thereafter, using only this yarn, a plain weave fabric having a length of 105 threads/2.54 cm and a width of 95 threads/2.54 cm was produced. Furthermore, this fabric is treated with a general blue disperse dye 2% owf, a brominated flame retardant (product name UR7 manufactured by Marubishi Yuka) 10% owf, and a bath ratio of 1:8 with a high-pressure dyeing machine at 130 ° C. bottom. This fabric was colored and had an aesthetic appearance, and had a flameproof performance of 10 cm 2 , demonstrating high flameproof performance. Moreover, the water repellency was grade 4.

(実施例8)
芯成分としてポリエチレンテレフタレート(クラレ製(防炎剤を含む前のポリマーの溶融粘度130Pa・s(290℃)))に防炎剤(DIC製 商品名「EXR3000」)を33重量%含む樹脂(リン成分濃度15000ppm)を使用し、鞘成分としてポリプロピレン(プライムポリマー製(ポリマーの溶融粘度62Pa・s(260℃)))を使用して、芯/鞘=8/2の重量比で溶融紡糸にて芯鞘型複合繊維84dtex/24フィラメントを作製した(断面形状:図5)。この複合繊維中のリン成分濃度は12000ppmであった。その後、この糸のみを用いてタテ105本/2.54cm、ヨコ95本/2.54cmの平織生地を作製し、生地精練の後、乾燥、仕上げセット加工を行った。この生地の防炎性能は35cmで、防炎性を示した。また、撥水性は4級であった。
(Example 8)
A resin (phosphorus component concentration 15000 ppm), using polypropylene (made of prime polymer (polymer melt viscosity 62 Pa s (260 ° C.))) as a sheath component, using melt spinning at a weight ratio of core / sheath = 8/2 A core-sheath type composite fiber 84 dtex/24 filament was produced (cross-sectional shape: FIG. 5). The phosphorus component concentration in this composite fiber was 12000 ppm. Thereafter, using only this yarn, a plain weave fabric having a length of 105 threads/2.54 cm and a width of 95 threads/2.54 cm was produced. The flameproof performance of this fabric was 35 cm 2 , indicating flameproof properties. Moreover, the water repellency was grade 4.

(実施例9)
芯成分としてポリエチレンテレフタレート(クラレ製(防炎剤を含む前のポリマーの溶融粘度130Pa・s(290℃)))に防炎剤(DIC製 商品名「EXR3000」)を33重量%含む樹脂(リン成分濃度15000ppm)を使用し、鞘成分としてポリプロピレン(プライムポリマー製(ポリマーの溶融粘度62Pa・s(260℃)))を使用して、芯/鞘=8/2の重量比で溶融紡糸にて芯鞘型複合繊維84dtex/24フィラメントを作製した(断面形状:図5)。この複合繊維中のリン成分濃度は12000ppmであった。その後、この糸のみを用いてタテ105本/2.54cm、ヨコ95本/2.54cmの平織生地を作製し、生地精練の後、乾燥、仕上げセット加工を行った。そして、一般的な青色分散染料2%owf、浴比1:8にて高圧染色機で130℃にて処理した。この生地の防炎性能は30cmで、高い防炎性を示した。また、撥水性は4級であった。
(Example 9)
A resin (phosphorus component concentration 15000 ppm), using polypropylene (made of prime polymer (polymer melt viscosity 62 Pa s (260 ° C.))) as a sheath component, using melt spinning at a weight ratio of core / sheath = 8/2 A core-sheath type composite fiber 84 dtex/24 filament was produced (cross-sectional shape: FIG. 5). The phosphorus component concentration in this composite fiber was 12000 ppm. Thereafter, using only this yarn, a plain weave fabric having a length of 105 threads/2.54 cm and a width of 95 threads/2.54 cm was produced. Then, it was treated at 130° C. with a high-pressure dyeing machine using 2% owf of a common blue disperse dye and a liquor ratio of 1:8. The flameproof performance of this fabric was 30 cm 2 , indicating high flameproof performance. Moreover, the water repellency was grade 4.

(実施例10)
芯成分としてポリエチレンテレフタレート(クラレ製(防炎剤を含む前のポリマーの溶融粘度130Pa・s(290℃)))に防炎剤(DIC製 商品名「EXR3000」)を33重量%含む樹脂(リン成分濃度15000ppm)を使用し、鞘成分としてポリプロピレン(プライムポリマー製(ポリマーの溶融粘度62Pa・s(260℃)))を使用して、芯/鞘=8/2の重量比で溶融紡糸にて芯鞘型複合繊維84dtex/24フィラメントを作製した(断面形状:図5)。この複合繊維中のリン成分濃度は12000ppmであった。その後、この糸のみを用いてタテに105本/2.54cmの密度で、この糸とレギュラーポリエチレンテレフタレート84dtex/36フィラメントの糸を9:1の割合でヨコに95本/2.54cmの密度で使用して平織生地を作製し、生地精練の後、乾燥、仕上げセット加工を行った(複合繊維の使用比率:96重量%)。さらにこの生地を、一般的な青色分散染料2%owf、臭素系防炎剤(丸菱油化工業製、商品名「UR7」)15%owf、浴比1:8にて高圧染色機で130℃にて処理した。この生地は着色して審美性を持ち、さらに防炎性能は30cmで、高い防炎性を示した。また、撥水性は4級であった。
(Example 10)
A resin (phosphorus component concentration 15000 ppm), using polypropylene (made of prime polymer (polymer melt viscosity 62 Pa s (260 ° C.))) as a sheath component, using melt spinning at a weight ratio of core / sheath = 8/2 A core-sheath type composite fiber 84 dtex/24 filament was produced (cross-sectional shape: FIG. 5). The phosphorus component concentration in this composite fiber was 12000 ppm. After that, using only this thread at a density of 105 / 2.54 cm in the warp, this thread and a regular polyethylene terephthalate 84 dtex / 36 filament thread at a ratio of 9: 1 at a density of 95 / 2.54 cm in the weft A plain weave fabric was produced using the fabric, and after fabric scouring, drying and finish setting processing were performed (ratio of composite fiber used: 96% by weight). Furthermore, this fabric is treated with a general blue disperse dye 2% owf, a brominated flame retardant (manufactured by Marubishi Yuka Kogyo, trade name "UR7") 15% owf, and a bath ratio of 1:8 with a high-pressure dyeing machine. °C. This fabric was colored and had an aesthetic appearance, and had a flameproof performance of 30 cm 2 , demonstrating high flameproof performance. Moreover, the water repellency was grade 4.

(実施例11)
芯成分としてポリエチレンテレフタレート(クラレ製(防炎剤を含む前のポリマーの溶融粘度130Pa・s(290℃)))に防炎剤(DIC製 商品名「EXR3000」)を22重量%含む樹脂(リン成分濃度10000ppm)を使用し、鞘成分としてポリプロピレン(プライムポリマー製(ポリマーの溶融粘度62Pa・s(260℃)))を使用して、芯/鞘=6/4の重量比で溶融紡糸にて芯鞘型複合繊維84dtex/24フィラメントを作製した(断面形状:図1)。この複合繊維中のリン成分濃度は6000ppmであった。その後、この糸のみを用いてタテ105本/2.54cm、ヨコ95本/2.54cmの平織生地を作製し、生地精練の後、乾燥、仕上げセット加工を行った。さらにこの生地を、一般的な青色分散染料2%owf、臭素系防炎剤(丸菱油化工業製、商品名「UR7」)10%owf、浴比1:8にて高圧染色機で130℃にて処理した。この生地は着色して審美性を持ち、さらに防炎性能は30cmで、高い防炎性を示した。また、撥水性は4級であった。
(Example 11)
A resin (phosphorus component concentration 10000 ppm), using polypropylene (made of prime polymer (polymer melt viscosity 62 Pa s (260 ° C.))) as a sheath component, using melt spinning at a weight ratio of core / sheath = 6/4 A core-sheath type composite fiber 84 dtex/24 filament was produced (cross-sectional shape: FIG. 1). The phosphorus component concentration in this composite fiber was 6000 ppm. Thereafter, using only this yarn, a plain weave fabric having a length of 105 threads/2.54 cm and a width of 95 threads/2.54 cm was produced. Furthermore, this fabric is treated with a general blue disperse dye 2% owf, a brominated flame retardant (manufactured by Marubishi Yuka Kogyo, trade name "UR7") 10% owf, and a bath ratio of 1:8 with a high-pressure dyeing machine. °C. This fabric was colored and had an aesthetic appearance, and had a flameproof performance of 30 cm 2 , demonstrating high flameproof performance. Moreover, the water repellency was grade 4.

(実施例12)
芯成分としてポリエチレンテレフタレート(クラレ製(防炎剤を含む前のポリマーの溶融粘度130Pa・s(290℃)))に防炎剤(DIC製 商品名「EXR3000」)を44重量%含む樹脂(リン成分濃度20000ppm)を使用し、鞘成分としてポリプロピレン(プライムポリマー製(防炎剤を含む前のポリマーの溶融粘度62Pa・s(260℃)))に防炎剤(DIC製、商品名「EXR3000」)」を33重量%含む樹脂(リン成分濃度15000ppm)を使用して、芯/鞘=8/2の重量比で溶融紡糸にて芯鞘型複合繊維84dtex/24フィラメントを作製した(断面形状:図1)。この複合繊維中のリン成分濃度は19000ppmであった。その後、この糸のみを用いてタテ105本/2.54cm、ヨコ95本/2.54cmの平織生地を作製し、生地精練の後、乾燥、仕上げセット加工を行った。さらにこの生地を、一般的な青色分散染料2%owf、臭素系防炎剤(丸菱油化製 商品名UR7)10%owf、浴比1:8にて高圧染色機で130℃にて処理した。この生地は着色して審美性を持ち、さらに防炎性能は10cmで、高い防炎性を示した。また、撥水性は4級であった。
(Example 12)
A resin (phosphorus component concentration of 20000 ppm), and polypropylene (made of prime polymer (melt viscosity of the polymer before containing the flame retardant: 62 Pa s (260 ° C))) as a sheath component and a flame retardant (manufactured by DIC, trade name “EXR3000”) )” (concentration of phosphorus component: 15,000 ppm) was used to prepare a core-sheath type composite fiber 84 dtex/24 filament by melt spinning at a weight ratio of core/sheath = 8/2 (cross-sectional shape: Figure 1). The phosphorus component concentration in this composite fiber was 19000 ppm. Thereafter, using only this yarn, a plain weave fabric having a length of 105 threads/2.54 cm and a width of 95 threads/2.54 cm was produced. Furthermore, this fabric is treated with a general blue disperse dye 2% owf, a brominated flame retardant (product name UR7 manufactured by Marubishi Yuka) 10% owf, and a bath ratio of 1:8 with a high-pressure dyeing machine at 130 ° C. bottom. This fabric was colored and had an aesthetic appearance, and had a flameproof performance of 10 cm 2 , demonstrating high flameproof performance. Moreover, the water repellency was grade 4.

(比較例1)
芯成分としてポリエチレンテレフタレート(クラレ製(ポリマーの溶融粘度130Pa・s(290℃)))を使用し、鞘成分としてポリプロピレン(プライムポリマー製(防炎剤を含む前のポリマーの溶融粘度62Pa・s(260℃)))に防炎剤(DIC製、商品名「EXR3000」)」を33重量%含む樹脂(リン成分濃度15000ppm)を使用して、芯/鞘=8/2の重量比で溶融紡糸にて芯鞘型複合繊維84dtex/24フィラメントを作製した(断面形状:図1)。この複合繊維中のリン成分濃度は3000ppmであった。その後、この糸のみを用いてタテ105本/2.54cm、ヨコ95本/2.54cmの平織生地を作製し、生地精練の後、乾燥、仕上げセット加工を行った。この生地の防炎性能は60cmで、防炎性はなかった。撥水性は4級であった。
(Comparative example 1)
Polyethylene terephthalate (manufactured by Kuraray (polymer melt viscosity 130 Pa s (290 ° C))) is used as the core component, and polypropylene (prime polymer product (polymer melt viscosity 62 Pa s before containing flame retardant) is used as the sheath component. 260 ° C.))) and flame retardant (manufactured by DIC, trade name “EXR3000”)” using a resin (phosphorus concentration 15000 ppm) containing 33% by weight, melt spinning at a core / sheath = 8/2 weight ratio A core-sheath type composite fiber 84 dtex/24 filament was produced (cross-sectional shape: FIG. 1). The phosphorus component concentration in this composite fiber was 3000 ppm. Thereafter, using only this yarn, a plain weave fabric having a length of 105 threads/2.54 cm and a width of 95 threads/2.54 cm was produced. The flameproof performance of this fabric was 60 cm 2 and was not flameproof. The water repellency was grade 4.

(比較例2)
芯成分としてポリエチレンテレフタレート(クラレ製(防炎剤を含む前のポリマーの溶融粘度130Pa・s(290℃)))に防炎剤(DIC製 商品名「EXR3000」)を55重量%含む樹脂(リン成分濃度25000ppm)を使用し、鞘成分としてポリプロピレン(プライムポリマー製(防炎剤を含む前のポリマーの溶融粘度62Pa・s(260℃)))に防炎剤(DIC製、商品名「EXR3000」)」を55重量%含む樹脂(リン成分濃度25000ppm)を使用して、芯/鞘=5/5の重量比で溶融紡糸にて芯鞘型複合繊維84dtex/24フィラメントを作製しようと試みた(断面形状:図1)。しかし、良好な紡糸工程性が得られなかった。
(Comparative example 2)
A resin (phosphorus component concentration of 25000 ppm), and polypropylene (made of prime polymer (melt viscosity of polymer before containing flame retardant: 62 Pa s (260 ° C))) as a sheath component, flame retardant (manufactured by DIC, trade name “EXR3000”) )” (concentration of phosphorus component: 25,000 ppm) was used to melt-spun a core/sheath = 5/5 weight ratio to prepare a core-sheath type composite fiber 84 dtex/24 filament ( Cross-sectional shape: Fig. 1). However, good spinning processability was not obtained.

(比較例3)
芯成分としてポリエチレンテレフタレート(クラレ製(防炎剤を含む前のポリマーの溶融粘度130Pa・s(290℃)))に防炎剤(DIC製 商品名「EXR3000」)を33重量%含む樹脂(リン成分濃度15000ppm)を使用し、鞘成分としてポリプロピレン(プライムポリマー製(ポリマーの溶融粘度62Pa・s(260℃)))を使用して、芯/鞘=8/2の重量比で溶融紡糸にて芯鞘型複合繊維84dtex/24フィラメントを作製した(断面形状:図5)。この複合繊維中のリン成分濃度は12000ppmであった。その後、この糸のみを用いてタテに105本/2.54cmの密度で、この糸とレギュラーポリエチレンテレフタレート84dtex/36フィラメントの糸を4:1の割合でヨコに95本/2.54cmの密度で使用して平織生地を作製し、生地精練の後、乾燥、仕上げセット加工を行った(複合繊維の使用比率:92重量%)。さらにこの生地を、一般的な青色分散染料2%owf、臭素系防炎剤(丸菱油化製 商品名UR7)15%owf、浴比1:8にて高圧染色機で130℃にて処理した。この生地は着色して審美性を持つが、防炎性能は50cmで、防炎性はなかった。また、撥水性は3級であった。
(Comparative Example 3)
A resin (phosphorus component concentration 15000 ppm), using polypropylene (made of prime polymer (polymer melt viscosity 62 Pa s (260 ° C.))) as a sheath component, using melt spinning at a weight ratio of core / sheath = 8/2 A core-sheath type composite fiber 84 dtex/24 filament was produced (cross-sectional shape: FIG. 5). The phosphorus component concentration in this composite fiber was 12000 ppm. After that, using only this thread, the density is 105 threads / 2.54 cm in the vertical direction, and this thread and the regular polyethylene terephthalate 84 dtex / 36 filament thread are used in a ratio of 4: 1 to 95 threads / 2.54 cm in the horizontal direction. A plain weave fabric was produced using this fabric, and after fabric scouring, drying and finish setting processing were performed (ratio of composite fiber used: 92% by weight). Furthermore, this fabric is treated with a general blue disperse dye 2% owf, a brominated flame retardant (product name UR7 manufactured by Marubishi Yuka) 15% owf, and a bath ratio of 1:8 with a high-pressure dyeing machine at 130 ° C. bottom. This fabric was colored and had an aesthetic appearance, but had a flameproof performance of 50 cm 2 and was not flameproof. Moreover, the water repellency was grade 3.

Figure 0007234472000001
Figure 0007234472000001

比較例1は得られた複合繊維中のリン成分が少ないため、それを使用した織物に十分な防炎性能を付与できなかった。比較例2は繊維を紡糸するためのポリマー構成においてリン成分が多いため、十分な紡糸工程性が得られなかった。比較例3は製織した織物において、リン成分を含む複合繊維の使用比率が低いため、十分な防炎性能を付与できなかった。 Since the composite fiber obtained in Comparative Example 1 contained a small amount of phosphorus, the fabric using the composite fiber could not be provided with sufficient flameproof performance. In Comparative Example 2, sufficient spinning processability could not be obtained because the polymer composition for fiber spinning contained a large amount of phosphorus. In the woven fabric of Comparative Example 3, the use ratio of the composite fiber containing the phosphorus component was low, so that sufficient flameproof performance could not be imparted.

本発明の織編物は、ホテルなどの宿泊施設で使用されるシャワーカーテンなどに好適に利用できる。 The woven or knitted fabric of the present invention can be suitably used for shower curtains and the like used in lodging facilities such as hotels.

1:芯鞘型複合繊維
2:芯成分
3:鞘成分
1: Core-sheath type composite fiber 2: Core component 3: Sheath component

Claims (5)

芯成分がポリエステル、鞘成分がポリプロピレンで構成された芯鞘型複合繊維を含む織編物であって、前記芯鞘型複合繊維の少なくとも芯成分にリン成分を含み、前記芯鞘型複合繊維に含まれるリン成分の含有量が繊維全体の重量に対して5000~20000ppmであり、前記芯鞘型複合繊維が前記織編物全体の95重量%以上含むことを特徴とする、織編物。 A woven or knitted fabric containing a core-sheath type conjugate fiber having a core component made of polyester and a sheath component made of polypropylene, wherein at least the core component of the core-sheath type conjugate fiber contains a phosphorus component, and the core-sheath type conjugate fiber contains a phosphorus component. A woven or knitted fabric, wherein the content of the phosphorus component contained in the woven or knitted fabric is 5000 to 20000 ppm based on the weight of the entire fiber, and the core-sheath type composite fiber contains 95% by weight or more of the entire woven or knitted fabric. 前記芯鞘型複合繊維において、芯成分のみにリン成分を含み、リン成分の含有量が芯成分の重量に対して8000~25000ppmであることを特徴とする、請求項1に記載の織編物。 The woven or knitted fabric according to claim 1, wherein the core-sheath type composite fiber contains a phosphorus component only in the core component, and the content of the phosphorus component is 8000 to 25000 ppm based on the weight of the core component. 前記芯鞘型複合繊維において、芯成分と鞘成分の比率が重量比で5/5~9/1であることを特徴とする、請求項1または請求項2に記載の織編物。 The woven or knitted fabric according to claim 1 or 2, characterized in that the weight ratio of the core component to the sheath component in the core-sheath type conjugate fiber is 5/5 to 9/1. さらに、繊維内に吸塵されるタイプの防炎剤を含むことを特徴とする、請求項1~請求項3のいずれか一項に記載の織編物。 The woven or knitted fabric according to any one of claims 1 to 3, further comprising a flame retardant of the type that is dust-absorbed into the fibers. 請求項1~請求項4のいずれか一項に記載の織編物を少なくとも一部に用いたカーテン。
A curtain at least partly made of the woven or knitted fabric according to any one of claims 1 to 4.
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000345434A (en) 1999-06-08 2000-12-12 Toyobo Co Ltd Conjugate binder fiber having antimicrobial property
JP2006104606A (en) 2004-10-04 2006-04-20 Nippon Ester Co Ltd Conjugated fiber and nonwoven fabric using conjugated fiber
WO2014192976A1 (en) 2013-05-31 2014-12-04 Es Fibervisions Co., Ltd. Heat-bondable conjugate fiber with excellent softness and nonwoven fabric using the same

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000345434A (en) 1999-06-08 2000-12-12 Toyobo Co Ltd Conjugate binder fiber having antimicrobial property
JP2006104606A (en) 2004-10-04 2006-04-20 Nippon Ester Co Ltd Conjugated fiber and nonwoven fabric using conjugated fiber
WO2014192976A1 (en) 2013-05-31 2014-12-04 Es Fibervisions Co., Ltd. Heat-bondable conjugate fiber with excellent softness and nonwoven fabric using the same
JP2014234559A (en) 2013-05-31 2014-12-15 Esファイバービジョンズ株式会社 Heat-adhesive composite fiber excellent in flexibility and nonwoven fabric comprising the same
CN105283589A (en) 2013-05-31 2016-01-27 Es飞博比琼斯株式会社 Heat-bondable conjugate fiber with excellent softness and nonwoven fabric using the same

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