KR20050065793A - Method for surface- hardening in the interior and exterior parts to austenite steel - Google Patents

Method for surface- hardening in the interior and exterior parts to austenite steel Download PDF

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KR20050065793A
KR20050065793A KR1020030096684A KR20030096684A KR20050065793A KR 20050065793 A KR20050065793 A KR 20050065793A KR 1020030096684 A KR1020030096684 A KR 1020030096684A KR 20030096684 A KR20030096684 A KR 20030096684A KR 20050065793 A KR20050065793 A KR 20050065793A
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nitride
minutes
stainless steel
interior
hardening
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이영규
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이영규
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/08Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
    • C23C8/24Nitriding
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/80After-treatment

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  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)

Abstract

본 발명은 스테인리스강의 표면경화방법에 관한 것으로, 특히 오스테나이트계강의 내,외장부품의 디자인이 완성된 부품을 질화로의 온도가 570℃ ~ 580℃ 상태에서 120분 내지 180분을 충전시킨 후 표면이 약간 거칠어진 상태의 내,외장부품의 질화물을 광택 연마하여 제품화하는 것으로, 표면 경화처리된 부품은 텅스텐 제품과 유사한 강도와 스테인리스강의 내식성을 유지하며 질화표면의 색상은 진한 검정색으로 고품격의 색상을 띄며, 수요자의 요구에 부응하도록 건식도금으로 다양한 색상을 가질 수 있으며, 건식도금 후에도 표면의 흠 또는 파손이 전혀 없고 자체중량의 가벼움과 동시에 경제성과 생산성이 우수한 효과가 있음.The present invention relates to a surface hardening method of stainless steel, and in particular, the surface of the austenitic steel after completion of the design of the interior and exterior parts is filled with a temperature of 570 ° C. to 580 ° C. for 120 minutes to 180 minutes. The product is made by polishing and polishing the nitride of internal and external parts that are slightly roughened, and the surface hardened parts maintain strength similar to tungsten products and corrosion resistance of stainless steel, and the color of the nitrided surface is dark black with high quality color. It can have various colors by dry plating to meet the demands of consumers, and there is no flaw or damage on the surface even after dry plating, and it is light in weight and has excellent economic and productivity effects.

Description

오스테나이트계강의 내,외장부품 표면경화 방법 { Method for surface- hardening in the interior and exterior parts to austenite steel }Surface hardening method of austenitic steel {Method for surface- hardening in the interior and exterior parts to austenite steel}

본 발명은 스테인리스강의 표면경화 방법에 관한 것으로, 특히 오스테나이트계강의 내,외장부품의 디자인이 완성된 부품을 질화로의 온도가 570℃ ~ 580℃ 상태에서 120분 내지 180분을 충전시킨 후 표면이 약간 거칠어진 상태의 내,외장부품의 질화물을 광택 연마하여 제품화하는 오스테나이트계강의 내,외장부품 표면경화 방법에 관한 것이다.The present invention relates to a method of hardening the surface of stainless steel, and in particular, the surface of the austenitic steel after completion of the design of the internal and external parts is filled with a temperature of 570 ° C to 580 ° C for 120 minutes to 180 minutes. The present invention relates to a method for surface hardening of internal and external parts of austenitic steel, which is produced by polishing and polishing a nitride of internal and external parts in a slightly rough state.

일반적으로 내,외장부품은 치수안정성, 실용성, 외관성 등이 중요한 요소로서 작용하고 그 재질로는 스테인리스, 황동, 티타늄, 텅스텐 등의 초경합금이나 스텔라이트 상당합금이 많이 사용되고 있다.In general, the interior and exterior parts act as important factors such as dimensional stability, practicality, appearance, and the like, and carbide materials such as stainless steel, brass, titanium, tungsten, or equivalent alloys of stellite are frequently used.

여기서 스테인리스강은 가공성이나 생산성이 매우 좋고 쉽게 깨지지 않으며, 경제성을 갖추고 있으며, 디자인이 다채로워 일반적인 내,외장부품으로서 좋은 자격 요건을 갖추고 있다.Here, stainless steel has very good workability and productivity, is not easily broken, has economical efficiency, and has a variety of designs, and has good qualification as general internal and external parts.

그러나, 결정적으로 강도가 약하여 사용이 선택적이라는 결점이 있다.However, it is crucially weak in strength that its use is selective.

텅스텐강은 스테인리스강보다 약 5~6배의 강도를 갖고 있으며, 흠이 발생하는 일이 없으나, 상대적으로 가격이 고가이고, 작은 충격에도 쉽게 깨지는 성질이 있으며, 중량이 또한 무겁고, 단위 생산비가 높고 디자인이 단순하다는 결점이 있다.Tungsten steel is about 5 ~ 6 times stronger than stainless steel, and it does not cause any scratches, but it is relatively expensive, easily broken even by small impact, heavy weight, high unit production cost, and The drawback is that the design is simple.

따라서 본 발명은 상기의 결점을 적게 하기 위한 것으로, 디자인이 완성된 스테인리스강의 내,외장부품을 질화로 온도가 570℃ ~ 580℃ 상태에서 120분 내지 180분 충전시켜 표면경화하여 텅스텐과 유사한 강도의 질화물의 부품인 오스트나이트계강의 내,외장부품의 표면경화 방법을 제공하고자 함에 있다. Accordingly, the present invention is intended to reduce the above-mentioned drawbacks, nitrided internal and external parts of the finished stainless steel by nitriding the surface of the stainless steel in the temperature of 570 ℃ ~ 580 ℃ 120 minutes to 180 minutes to surface hardening nitride The purpose of the present invention is to provide a method of hardening the surface of internal and external parts of austenitic steel, which is a component of a.

이하, 본 발명의 바람직한 실시예에 따른 구성 및 작용을 첨부된 도면을 참조하여 설명하면 다음과 같다.Hereinafter, with reference to the accompanying drawings, the configuration and operation according to a preferred embodiment of the present invention will be described.

스테인리스강의 내,외장부품의 표면경화 방법은 스테인리스강을 질화하는 방법을 이용하는 것으로써 장점을 살리고 단점을 보완하는 것을 특징으로 한다.Surface hardening method of the internal and external parts of the stainless steel is characterized by utilizing the method of nitriding stainless steel to take advantage of the advantages and to compensate for the disadvantages.

질화의 처리 과정을 살펴보면 먼저 내,외장 디자인이 완성된 스테인리스강 부품을 570℃ ~ 580℃의 질화로에서 120분 내지 180분간 충전시키게 된다.Looking at the process of nitriding, first, the interior and exterior design of the stainless steel component is completed in a 570 ℃ ~ 580 ℃ nitriding furnace for 120 minutes to 180 minutes to fill.

여기에서 사용되는 스테인리스강은 오스테나이트계강이며, 질화로는 특별한 제약없이 일반적인 것을 사용할 수 있으며 질화로의 온도는 570℃ ~ 580℃가 바람직하다.The stainless steel used herein is austenitic steel, and can be used as a nitriding without particular limitation, the temperature of the nitriding furnace is preferably 570 ℃ ~ 580 ℃.

이때 온도가 너무 높으면 질화로 내의 부품이 손상될 우려가 있으며 반대로 온도가 너무 낮은 경우에는 충분한 경화 효과를 얻을 수 없게 된다.At this time, if the temperature is too high, there is a risk that the parts in the nitriding furnace are damaged. On the contrary, if the temperature is too low, a sufficient curing effect cannot be obtained.

이와 같은 질화로의 온도에서 충전시간은 120분 내지 180분이 적당하다.At this temperature of the nitriding furnace, the filling time is suitably 120 minutes to 180 minutes.

충전시간이 상기 시간보다 짧게 되면 충전이 충분하지 않게 되며, 반대로 시간이 너무 길게되면 응력부식균열이 발생하여 경화 효과를 얻을 수 없게 된다.If the filling time is shorter than the above time, the filling is not sufficient, on the contrary, if the time is too long, a stress corrosion cracking occurs and a hardening effect is not obtained.

이와 같은 소정의 질화 충전 공정을 거치고 나면 표면이 약간 거칠어진 상태의 내,외장부품의 질화물을 얻게 되며, 간단한 연마로 진한 검정색의 질화 표면처리된 내,외장부품을 얻게 된다.After the predetermined nitriding filling process, nitride of internal and external parts having a slightly roughened surface is obtained, and internal and external parts having a dark black nitrided surface treatment are obtained by simple grinding.

한편, 상기 공정을 통해 완성된 내,외장부품에 건식도금을 처리하므로서 내,외장부품의 외관을 개선하여 다양한 수요자의 요구에 응할 수 있게 된다.On the other hand, by processing the dry plating on the interior and exterior parts completed through the above process, it is possible to meet the needs of various consumers by improving the appearance of the interior and exterior parts.

도 1은 본 발명에 따른 오스트나이트계강의 내,외장부품의 표면경화 공정단계를 나타낸 순서도이다.1 is a flow chart showing the surface hardening process step of the interior and exterior parts of austenitic steel according to the present invention.

먼저 70℃ ~ 80℃에서 목적물의 표면 오염원을 제거하는 탈지 작업을 수행한 후 상기 목적물의 응력 제거 및 질화로의 온도 변화를 최소화하기 위하여 350℃ ±10℃에서 10분 내지 20분 정도의 예열 과정을 거친다.First, degreasing is performed to remove surface contaminants of the target at 70 ℃ ~ 80 ℃, and then preheating process is performed for 10-20 minutes at 350 ℃ ± 10 ℃ to minimize the stress removal and temperature change of the target. Rough

계속해서 본로의 온도를 목적물의 두께 및 디자인의 특징에 따라 120분 내지 180분 정도의 시간 내에서 570℃ ~ 580℃ 사이의 온도를 조정하여 처리작업을 수행한다.Subsequently, the temperature of the furnace is controlled by adjusting the temperature between 570 ° C. and 580 ° C. within a time of 120 minutes to 180 minutes depending on the thickness of the object and the characteristics of the design.

상기 작업에 따라 발생하는 질화물을 냉각하고 표면 오염원을 제거한 후에 정확한 표면경도 및 질화층(10) 두께를 측정, 검사한다.After cooling the nitride generated according to the operation and removing the surface contamination source, the accurate surface hardness and the thickness of the nitride layer 10 are measured and inspected.

도 2는 도 1의 후속 공정단계를 나타낸 순서도로써, 상기 도 1의 포면경화 공정을 거쳐서 완료된 질화물은 연마를 수행하게 되는데, 도 4에서와 같이 냉각시 발생된 슬러지(40) 및 흑층(20)의 7~8u의 1/2 정도를 연마한다.FIG. 2 is a flowchart illustrating a subsequent process step of FIG. 1, in which the nitride completed through the surface hardening process of FIG. 1 is polished, and the sludge 40 and the black layer 20 generated during cooling as shown in FIG. 4. Grind about 1/2 of 7-8u.

상기 연마를 수행하고 나면 질화물의 표면 색상은 진한 검정색으로 나타나게 된다.After the polishing is performed, the surface color of the nitride is dark black.

상기 연마를 수행하고 표면 색상을 검사한 후에 질화물의 표면 오염원을 제거하는 탈지 작업을 수행하며, 최종적으로 질화물의 표면조도 및 표면색상, 표면경도를 검사한다.After performing the polishing and inspecting the surface color, a degreasing operation is performed to remove the surface contamination source of the nitride, and finally the surface roughness, surface color, and surface hardness of the nitride are examined.

도 3은 수요자의 요구에 의한 건식도금 공정단계을 나타낸 순서도로써, 먼저 건식도금 전에 질화물의 오염원을 제거하는 탈지작업을 수행한다.3 is a flowchart illustrating a dry plating process step required by a consumer, and first, a degreasing operation is performed to remove a contaminant of nitride before dry plating.

상기 수행에 따라 오염원이 제거된 질화물은 CVD/PVD/IP 등에 따라 건식도금을 실시한다.Nitride, from which the pollutant is removed, is subjected to dry plating in accordance with CVD / PVD / IP.

상기 건식도금이 수행된 질화물이 내식성을 갖추고 있는지, 정확한 색깔을 띄고 있는지 검사를 한 후에 포장한다.The dry plated nitride is packaged after being inspected for corrosion resistance and correct color.

도 4는 본 발명에 따른 표면경화의 측정내역을 나타낸 측면도로써, 질화(화합물)층(10)이 50 ~ 60u가 되는데, 이때 백층(30)은 Cr탄화물이며, 흑층(20)은 Cr질화물로 7 ~ 8u이며 표면경도는 Hmv/100g:1200-1250)이 된다.Figure 4 is a side view showing the measurement history of the surface hardening according to the present invention, the nitride (compound) layer 10 is 50 ~ 60u, wherein the white layer 30 is Cr carbide, the black layer 20 is Cr nitride 7 ~ 8u and the surface hardness is Hmv / 100g: 1200-1250).

즉, 디자인이 완성된 스테인리스강의 내,외장부품을 570℃ ~ 580℃의 질화로에서 120분 내지 180분을 충전시켜 표면경화를 시키고 이렇게 질화처리를 하게 되면 표면경도가 비커스경도(Hmv/100g:1200-1250)의 질화물을 얻게 된다.That is, the internal and external parts of the finished stainless steel are filled in the nitriding furnace of 570 ° C. to 580 ° C. for 120 minutes to 180 minutes to harden the surface. When the nitriding treatment is performed, the surface hardness is Vickers hardness (Hmv / 100g: 1200 -1250).

상기 질화물은 표면이 약간 거칠어진 상태를 보이는데 이것을 다시 내면 및 외면을 연마하면 매끄럽고 최상의 광택을 갖게 된다.The nitride shows a slightly roughened surface, which is polished on the inner and outer surfaces to give a smooth and best gloss.

상기의 과정을 거쳐 스테인리스강의 표면은 약 50~60u 정도 두께의 질화 표면처리된 내,외장부품을 얻게 되며, 이때 이 내,외장부품은 가벼우면서도 진한 검정색의 고품격 생각을 지니며 표면에는 전혀 흠이 발생하지 않고 가격적인 측면, 즉 경제성에서도 텅스텐의 1/3 정도의 생산비용이 들게 된다.Through the above process, the surface of stainless steel is obtained internal and external parts with nitrided surface treatment of about 50 ~ 60u thickness. At this time, the internal and external parts are light and have high quality of dark black. It does not occur and costs about one third of tungsten in terms of cost, namely economics.

이상 설명한 바와 같이 본 발명을 통해 텅스텐 제품과 동일한 정도의 경도로서 진한 검정색의 고품격 색상을 갖으며 다양한 수요자의 요구에 응할 수 있도록 건식도금을 통해 색상의 다변화를 꾀할 수 있고, 동시에 사용할 때는 표면에 흠이나 파손이 없으며, 자체중량 또한 가볍고 경제성과 생산성에서도 우수한 효과가 있다.As described above, the present invention has the same degree of hardness as tungsten products, has a high-quality color of dark black, and can diversify the color through dry plating to meet the demands of various consumers, and at the same time, scratches on the surface There is no damage, its own weight is also light, it has an excellent effect in economics and productivity.

따라서 손목시계 외장품, 전자제품내의 내,외장품, 자동차 실내,외 장식품 및 액세서리 등 텅스텐 및 세라믹 등 응용관련 분야에의 이용이나 응용을 기대할 수 있다.Therefore, it can be expected to be used or applied in application-related fields such as tungsten and ceramics such as watch exterior products, interior and exterior products in electronic products, interiors and exteriors of automobiles, and accessories.

도 1은 본 발명에 따른 표면경화의 공정단계를 나타낸 순서도1 is a flow chart showing the process step of the surface hardening according to the present invention

도 2는 도 1의 후속 공정단계를 나타낸 순서도2 is a flow chart showing the subsequent process steps of FIG.

도 3은 수요자의 요구에 의한 건식도금 공정단계를 나타낸 순서도Figure 3 is a flow chart showing the dry plating process step according to the request of the consumer

도 4는 본 발명에 따른 표면경화의 측정내역을 나타낸 측면도Figure 4 is a side view showing the measurement history of the surface hardening according to the present invention

* 도면의 주요부분에 대한 부호의 설명 *Explanation of symbols on main parts of drawing

10 : 질화(화합물)층 20 : 흑층(Cr질화물)10: nitride (compound) layer 20: black layer (Cr nitride)

30 : 백층(Cr탄화물) 40 : 슬러지30: white layer (Cr carbide) 40: sludge

Claims (1)

목적물의 오염원을 제거하는 탈지작업을 수행하는 단계와;Performing a degreasing operation to remove the pollutant of the object; 상기 목적물의 응력제거 및 질화로의 온도변화를 최소화하기 위한 예열작업을 수행하는 단계와;Performing a preheating operation to minimize the stress of the target and change the temperature of the nitriding furnace; 상기 목적물의 두께 및 디자인의 특징에 따라 상기 질화로의 온도 및 시간을 조절하는 단계와;Adjusting the temperature and time of the nitriding furnace according to the thickness of the object and the characteristics of the design; 상기 목적물을 냉각한 후 표면 오염원을 제거하는 단계와;Removing surface contaminants after cooling the object; 상기 냉각물의 표면 경도 및 질화층의 두께를 측정하는 단계와;Measuring the surface hardness and the thickness of the nitride layer; 상기 측정된 질화물의 냉각시 발생된 슬러지 및 흑층의 1/2을 연마하는 단계와;Grinding half of the sludge and the black layer generated during cooling of the measured nitride; 상기 연마된 질화물의 표면 오염원을 제거하고 질화물의 표면조도 및 표면색상, 표면경도를 검사하는 단계로 구성되는 것을 특징으로 하는 오스테나이트계강의 내,외장부품 표면경화 방법.Removing the surface contamination source of the polished nitride and inspecting the surface roughness, surface color and surface hardness of the nitride.
KR1020030096684A 2003-12-24 2003-12-24 Method for surface- hardening in the interior and exterior parts to austenite steel KR20050065793A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100919827B1 (en) * 2009-07-23 2009-10-01 강원대학교산학협력단 Device for polishing sample

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100919827B1 (en) * 2009-07-23 2009-10-01 강원대학교산학협력단 Device for polishing sample

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