KR20050046311A - Water-based foam wallpaper using natural materials - Google Patents

Water-based foam wallpaper using natural materials Download PDF

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KR20050046311A
KR20050046311A KR1020030080370A KR20030080370A KR20050046311A KR 20050046311 A KR20050046311 A KR 20050046311A KR 1020030080370 A KR1020030080370 A KR 1020030080370A KR 20030080370 A KR20030080370 A KR 20030080370A KR 20050046311 A KR20050046311 A KR 20050046311A
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wallpaper
water
aqueous
flame
retardant
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KR1020030080370A
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KR100639120B1 (en
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전효철
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전효철
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/18Paper- or board-based structures for surface covering
    • D21H27/20Flexible structures being applied by the user, e.g. wallpaper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/50Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
    • D21H21/56Foam
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/02Patterned paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H5/00Special paper or cardboard not otherwise provided for
    • D21H5/0082Wall papers
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H5/00Special paper or cardboard not otherwise provided for
    • D21H5/02Patterned paper

Abstract

본 발명은 천연소재와 수성발포제를 이용한 수성발포 벽지에 관한 것이다.The present invention relates to an aqueous foam wallpaper using a natural material and an aqueous foaming agent.

Description

천연소재를 이용한 수성발포 벽지{omitted}Waterborne foam wallpaper using natural materials {omitted}

본 발명은 천연소재와 수성발포재를 이용한 수성발포 벽지에 관한 것이다.The present invention relates to an aqueous foam wallpaper using a natural material and an aqueous foam material.

기존의 천연소재를 응용한 벽지(특, 공개번호 1998-0019564)는 본인이 개발하여 생산하여 본 결과 여러가지 문제점이 발생하여 새로운 개념의 생산 방법을 제시하고져 한다.As a result of developing and producing the wallpaper using the existing natural materials (Special Publication No. 1998-0019564), various problems occur and suggest a new concept of production method.

기존의 생분해성 벽지는 벽지원지-접착제-생분해성 미장재-탑코팅층 등으로 구성되어 있다.Existing biodegradable wallpaper is composed of wallpaper paper-adhesive-biodegradable plaster-top coating layer.

이와같이 구성될 경우 일반벽지와 비교시 차이점을 인쇄작업의 불가,(표면의 요철현상이 심하여 불가능) 앰보싱 작업의 불가(천연소재류는 복원력이 강하여 압력을 가하여도 압착 될 수 있는 성분이 없음) 벽지시공시 후면에 풀칠 작업시 다량의 수분이 천연소재쪽으로 전이되어 물녹임 작업시간을 장시간(보통벽지의 물녹임시간은 4∼12시간 정도로 가능하지만 천연소재류를 사용한 벽지일 경우 30분∼2시간이내 벽지를 시공함이 적정하며 그 이상의 시간이 경과 할때는 벽지가 수분에 약하여 찢겨지는 현상이 발생하거나 풀칠된 배접면이 서로 밀착하여 물녹임 작업시 접착면에 건조현상 (풀에 함유된 수분이 천연소재쪽으로 전이되어 풀의 수분이 없어진 형태)이 발생하여 벽지 시공이 불가능한 상태 등의 범용화에 한계점으로 작용하고 있다.In this way, it is impossible to print the difference in comparison with the general wallpaper (not possible due to the roughness of the surface), and the impossibility of the embossing work (natural materials have strong restoring force and there is no component that can be compressed even under pressure) When painting on the back during construction, a large amount of water is transferred to the natural material, so that the water dissolving work can be performed for a long time (usually, the water dissolving time is 4 to 12 hours, but within 30 minutes to 2 hours for wallpaper using natural materials) When the wallpaper is suitable, if the time elapses, the wallpaper is weak due to moisture and tearing occurs, or the glued back contact surfaces adhere to each other and dry on the adhesive surface during water dissolving work. It is a limiting point for the generalization of the state where the wallpaper construction is impossible due to the transfer of water to the grass).

합성수지류에 수성발포제를 첨가하여 엠보싱 작업시 압력에 의한 압착층을 형성하고 표면상부의 평활도를 형성시켜 인쇄적성을 개량하여 새로운 형태의 벽지를 제공하고져 한다.An aqueous foaming agent is added to the synthetic resin to form a compressed layer under pressure during embossing and to form flatness on the surface to improve printability to provide a new type of wallpaper.

본 발명의 실시예에 첨부된 도면에 따라 상세히 설명하면 다음과 같다.When described in detail with reference to the accompanying drawings an embodiment of the present invention.

도 1의 도시된 바와같이 벽지원지에 수성발포제가 첨가된 접착제와 기존제품(생분해성 벽지)의 접착제 사용시의 차이점으로는 기존제품의 접착제는 아크릴, PE, EVA계통의 접착제 중 어느 하나를 1㎥당 30∼50g정도를 도포하여 천연소재류를 접착시켜 건조 시킨다.As shown in Figure 1, the difference between the adhesive when the water-based foaming agent is added to the wallpaper base material and the adhesive of the existing product (biodegradable wallpaper), the adhesive of the existing product is any one of acrylic, PE, EVA-based adhesive 1㎥ Apply about 30-50g of sugar and dry natural materials.

이와같이 단순히 일반 접착제를 사용할 경우 제품 완성후 벽지 시공시 벽지 후면에 풀칠하여 물녹임 작업시 상기와 같은 현상이 발생한다.As such, when the general adhesive is used, the above phenomenon occurs when the water is melted by pasting the back of the wallpaper during the construction of the product after the completion of the product.

이같은 현상은 일반 접착제는 벽지원지에 도포된 후 건조하여도 완전히 필림으로 형성되지 못하여 수분의 투과가 쉬우며 또한 너무 필림이 형성되면 수분이 투과되지 못하면 시공시 물녹임 작업이 불가능하여 벽지시공이 힘들어진다. 또한 엠보싱 작업시 압력에 의한 압착층이 없기 때문에 엠보 성형성이 없다.Such a phenomenon is that general adhesive is not completely formed into film even after it is applied to wallpaper paper and dried, so it is easy to permeate moisture. Also, if film is formed too much, water cannot be melted during construction, which makes it difficult to install wallpaper. Lose. In addition, since there is no pressing layer due to pressure during embossing, there is no embossability.

본 발명에서는 적당한 수분 통과와 엠보싱 작업시 압착 될 수 있는 발포층을 형성시켜 이와같은 문제점을 해결하고져 아크릴계, EVA계, 수성우레탄계통의 접착제 등 어느하나 또는 혼합하여 20∼50 중량%, 물5∼10 중량%, 메탄올 및 알코올 5∼10 중량%, 수성발포제 2∼7 중량%, 유화제 0.1∼0.5 중량%, Ca Co3 20∼40 중량%, 탈크 및 편운모분 5∼10 중량%, TiO2 2∼5 중량%, 옥등 원적외선 방사물질 2∼5 중량%, 암모니아수 0.1∼0.1 중량%, 증점제 0.1∼0.2 중량%, 분산제 0.1∼0.5 중량%, 소포제 0.1∼0.5 중량% 등을 고루게 혼합하여 벽지원지에 콤마코타 및 그라비아 동판, 로타리 스크린 방법 등으로 1㎡당 50∼150g (고형분 기준) 정도를 도포한다.In the present invention solves this problem by forming a foam layer that can be compressed during proper water passage and embossing work, any one or a mixture of acrylic, EVA, water-based urethane-based adhesive or 20 to 50% by weight, water 5 ~ 10% by weight, 5-10% by weight methanol and alcohol, 2-7% by weight aqueous foaming agent, 0.1-0.5% by weight emulsifier, 20-40% by weight of Ca Co3, 5-10% by weight of talc and mica, TiO2 2 ~ 5% by weight, 2-5% by weight of far-infrared ray emitting material, 0.1-0.1% by weight of ammonia water, 0.1-0.2% by weight of thickener, 0.1-0.5% by weight of dispersant, 0.1-0.5% by weight of antifoaming agent, etc. Apply about 50 ~ 150g (solid content) per 1㎡ by comma-cotta, gravure copper plate and rotary screen method.

이때 상기 배합에서 메탄을 및 알코올 사용은 벽지원지에 접착제의 침투 속도를 조절 효과 및 건조 속도를 향상시키기 위해 사용하며, 유화제 사용을 수성발포제를 첨가하여 겔링작업(건조시)시 및 배합시 액상의 유동성을 향상시키기 위해 사용하며 비이온 유화제 및 음이온 유화제 양이온 유화제, 양쪽성 유화제 중 어느쪽을 사용하여도 무방하며, 수성발포제는 이소부탄, 이소, 펜탄 등의 GAS가 충진된 수성발포제를 사용하며 옥등 원적외선 방사물질 사용은 수성발포 토나를 벽지원지에 콤마코타 및 그라비아롤, 로타리스크린 등으로 도포 후 겔링 작업시 건조오븐의 고온의 열기로 인해 수성발포 토나의 표면만 건조가 먼저 일어나 코팅면의 균열현상 및 코팅면이 이상적으로 부풀어 오르거나, 수성발포제의 발포 불균일성 등이 발생한다.At this time, the use of methane and alcohol in the formulation is used to control the penetration rate of the adhesive to the wallpaper base material and to improve the drying speed, and the use of emulsifier to add the aqueous foaming agent during the gelling operation (drying) and during the mixing of liquid It is used to improve the fluidity. It can be used either of nonionic emulsifier, anionic emulsifier, cationic emulsifier or amphoteric emulsifier. Aqueous foaming agent uses aqueous foaming agent filled with GAS such as isobutane, iso, pentane, etc. The use of far-infrared radiation materials is applied to the wallpaper base with comma-cotta, gravure roll, rotary screen, etc., and then the surface of the water-based foam tona is dried first due to the high temperature heat of the drying oven during gelling operation. And the coating surface is swelled ideally, or the foaming nonuniformity of the aqueous foaming agent occurs.

이와같은 현상은 표면만 건조가 먼저 일어나 내부의 수분이 미쳐 증발할 수 없어서 일어나는 현상이다. 본 발명에서는 이와같은 현상을 해결하기 위해 일라이트, 옥, 맥반석, 세라믹, 장석, 제오라이트, 게르마늄 등 원적외선 방사물질을 첨가하여 방사물질의 복사열을 이용하여 수성발포 토나 도포층의 내부건조 촉진을 향상시켜 건조의 균일성을 주고져 한다. 또한 암모니아수 사용은 수성발포 토나 배합시 원료들간의 PH를 조절하여 배합시 쇼킹현상을 방지하며 배합 후 PH를 7∼8사이의 중성을 유지하기 위해 사용한다.This phenomenon occurs because only the surface is dried first and the moisture inside can not evaporate. In the present invention, in order to solve such a phenomenon by adding far-infrared radiation materials such as elite, jade, banban, ceramic, feldspar, zeolite, germanium to improve the internal drying of the aqueous foamed soil or coating layer by using the radiant heat of the radiation material The uniformity of drying should be given. In addition, the use of ammonia water is used to maintain the pH between 7 and 8 after mixing to prevent shock phenomenon during mixing by adjusting the pH between the raw materials in aqueous foaming soil or blending.

또한 상기 배합에서 사용되는 소포제는 실리콘계 및 비실리콘계를 사용하며 증점제는 Collulose Type계 및 아크릴계. 분산제는 특수음이온, 음이온 복화물, 특수비이온 복화물 등 어느계통을 사용하여도 무방하다.In addition, the antifoaming agent used in the formulation uses a silicone-based and non-silicone-based thickener is Collulose Type-based and acrylic. The dispersant may be any system such as special anion, anion complex, and special nonionic complex.

이와같이 벽지원지에 상기 배합으로 혼합된 수성발포 토나를 일정량 도포한 후 천연소재류인 목분, 왕계분, 녹화분, 쑥분, 건초분, 건수초분 및 무기질인 숯분, 열팽탕된 질석 등의 소재를 일정한 입도로 분리하여(40∼60매쉬, 60∼80매쉬, 80∼100매쉬, 100∼120매쉬 등으로 분류하여 사용함)정전기 대전방식(일명: 섬유에서 후로킹 공법으로 사용되고 있음) 즉 고압의 전류(약60,000W정도)를 정전기를 발생시켜 수성발포 토나 상부에 천연소재류가 정전기의 자성에 의해 접착될 수 있도록 하거나 (이때 접착되는 천연소재는 1㎡당 50∼150g/㎡ 정도임)로타리 스크린, 고압의 분사방식, 스케트링 방법 등으로 접착시킨 후 그 상부에 다시 상기의 수성발포토나를 50∼300g/㎡(고형분 기준)정도를 콤마코타로 도포하여 겔링작업(150∼200℃ 사이)-인쇄공정-탑코팅 작업을 실시한 후 엠보싱 작업을 한다. 이때 천연소재류 상부에 수성발포 토나를 재코팅하는 이유는 인쇄작업을 가능할수 있도록 평활도를 형성하고져 하며 엠보싱 작업시 엠보 성형성을 향상 시키고져 한다.In this way, after applying a certain amount of water-foamed tona mixed with the above-mentioned mixture to the wallpaper base material, materials such as wood flour, royal chicken powder, green powder, mugwort powder, hay powder, dry water grass powder, mineral charcoal powder, and thermally swelled vermiculite, etc. Separation (Used by dividing into 40 to 60 mesh, 60 to 80 mesh, 80 to 100 mesh, 100 to 120 mesh, etc.) Electrostatic charging method (aka: used as flocking method in fiber), that is, high voltage current (about 60,000 W To generate static electricity, so that natural materials can be adhered to the water-based foam or the upper part by the magnetic of static electricity (50-150g / m2 per 1m2). , After bonding by the squetling method or the like, to the upper part of the aqueous balcona again by applying a comma coat about 50 to 300 g / m 2 (based on solid content), and gelling work (between 150 and 200 ° C.)-printing process-top coating work Thread After the time is embossed. At this time, the reason of recoating aqueous foam tona on top of natural materials is to form smoothness to enable printing work and to improve the embossability during embossing work.

또한 탑코팅 작업을 벽지의 내오염성 방지 및 인쇄피막을 보호하고져 실시되며 탑코팅제는 아크릴계 및 우레탄계통의 수지에 수성왁스(고온용파라핀계, PE계, 카르나바 왁스등 사용) 및 수성메라민 수지, 수성에폭시수제, 실리콘계통의 발수제중 어느 하나 또는 이종이상으로 혼합하여 2∼15 중량부의 % 첨가하여 고형분 기분으로 10∼50g/㎡ 를 도포(고형분 기준)한다. (이때 천연소재류는 단독 또는 2종 등으로 혼합하여 사용할수 있다)In addition, the top coating is carried out to prevent the fouling resistance of the wallpaper and to protect the print film. The top coating agent is an aqueous wax (using high temperature paraffin, PE, carnava wax, etc.) and an aqueous meramine resin, in an acrylic or urethane resin. One to two or more parts by weight of aqueous epoxy and silicone water-repellents are mixed or added, and 10 to 50 g / m 2 is applied in a solid content mood (solid content basis). (At this time, natural materials can be used singly or in mixture of two kinds.)

또한 도 2에 도시된 방법을 벽지원지에 상기의 수성발포 토나를 100∼300g/㎡(고형분 기준)를 도포한 후 천연소재류를 그 상부에 접착시킨 후 상기의 탑코팅액을 증점제를 사용하여 점도 2,000∼4,000 C.P.S 정도를 상승시켜 콤마코타 작업-건조-엠보싱 작업 순으로 행하여 진다.In addition, the method shown in FIG. 2 is coated with 100 to 300 g / m 2 (based on solids) of the aqueous foam toner on a wallpaper base material, and then the natural material is adhered to the upper portion thereof. It raises about -4,000 CPS, and is performed in the order of comma kota work-drying-embossing work.

이때 탑코팅액에 수성 발포제를 첨가하여 (2-5% 중량%) 엠보싱 성형성을 부여할 수도 있다.At this time, an aqueous blowing agent may be added to the top coating liquid (2-5% by weight) to impart embossing moldability.

이때 벽지에 난연성을 부여하고져 할때는 일반적으로 난연 처리된 벽지원지를 사용하며 난연제를 수산화 알루미늄계통의 무기 난연제를 사용한다.In this case, when the flame retardancy is given to the wallpaper, the flame retardant treated wallpaper is generally used, and the flame retardant is an inorganic flame retardant of aluminum hydroxide.

이때 혼합비율은 아크릴계, EVA계, 수성우레탄계통의 수지를 단독 또는 혼합하에 20∼50 중량 %, 물 5∼10 중량 %, 메탄올 및 알코올 5∼10 중량 %, TiO2 2∼5 중량 %, 이소부탄 및 이소펜탄계통의 수성발포제 2∼7 중량%, 유화제 1∼0.5 중량 %, 탈크 및 편운모분 5∼10 중량 %, 옥등 원적외선 방사물질 2∼5 중량 %, 수산화 알루미늄계통의 난연제 20∼30 중량 %, 암모니아수 0.01∼0.1 중량 % 증점제 0.1∼0.2 중량 %, 분산제 0.1∼0.5 중량 %, 소포제 0.1∼0.5 중량 % 등으로 배합되는 난연제 조성물을 갖는 난연 벽지의 생산방법.At this time, the mixing ratio is 20 to 50% by weight, 5 to 10% by weight of water, 5 to 10% by weight of methanol and alcohol, 2 to 5% by weight of TiO2, isobutane under single or mixed acrylic, EVA and aqueous urethane resins. And 2 to 7 wt% of an isopentane based aqueous foaming agent, 1 to 0.5 wt% of an emulsifier, 5 to 10 wt% of talc and soft mica, 2 to 5 wt% of far-infrared radiant such as jade, and 20 to 30 wt% of aluminum hydroxide based flame retardant. %, Ammonia water 0.01 to 0.1% by weight thickener 0.1 to 0.2% by weight, dispersant 0.1 to 0.5% by weight, antifoaming agent 0.1 to 0.5% by weight and the like.

본 발명은 합성수지류에 수성발포제를 첨가하여 벽지원지에 수성발포 토나 및 상기의 천연소재류를 적층으로 도포되는 친환경 벽지를 제공하고져 하는데 있다.The present invention is to provide an eco-friendly wallpaper that is applied by laminating the aqueous foaming tona and the above natural materials to the wallpaper paper by adding an aqueous foaming agent to the synthetic resin.

도 1은 천연소재를 이용한 본 발명의 제 1실시예의 수성발포 벽지의 단면도1 is a cross-sectional view of the aqueous foam wallpaper of the first embodiment of the present invention using a natural material

도 2는 동 제2실시예의 단면도.2 is a sectional view of the second embodiment;

〈도면의 주요 부분에 대한 부호의 설명〉<Explanation of symbols for main parts of drawing>

도 1의 1 : 벽지원지 2 : 수성발포 접착제 3 : 천연소재층1, 1: wallpaper base 2: aqueous foaming adhesive 3: natural material layer

4 : 수성발포층 5 : 인쇄층 6 : 탑코팅층       4: aqueous foaming layer 5: printed layer 6: top coating layer

도 2의 1 : 벽지원지 2 : 수성발포 접착제 3 : 천연소재층2, 1: wallpaper base 2: aqueous foaming adhesive 3: natural material layer

4 : 탑코팅층       4: Top Coating Layer

Claims (2)

소정의 넓이로 이루어진 벽지원지에 상기에 명시된 수성발포제와 수용성 합성수지류의 배합된 액상을 콤마코타 및 그라비아 방식으로 일정한 두께로 도포한 후 그 상부에 천연소재류를 정전기 방식 및 스케트링 방식 등으로 접착시킨 후 다시 그 상부에 상기의 수성발포 토나를 도포한 후 겔링 - 인쇄 - 탑코팅 - 엠보싱 작업 및 벽지원지에 수성발포 토나 도포 - 천연소재류 접착 - 겔링 - 탑코팅 - 엠보싱 작업으로 생산할 수 있는 천연소재류를 이용한 수성발포 벽지.Apply the liquid mixture of the above-mentioned water-based foaming agent and water-soluble synthetic resin to a predetermined thickness in a comma-cota and gravure method on the wallpaper paper of a predetermined width, and then attach natural materials to the upper part by the electrostatic method or the squetling method. After coating the above water-based foamed tona again on top of it, gelling-printing-top coating-embossing and wallpaper coating water-based foaming tona-natural material adhesion-gelling-top coating-embossing Water-based foam wallpaper. 제 1항에 있어서 난연처리된 벽지원지에 상기 명시된 난연제가 혼합된 수성 발포 토나를 일정두께로 도포한 후 천연소재류의 접착-다시 난연제가 혼합된 수성 발포 토나를 도포-겔링 - 인쇄 - 탑코팅 - 엠보싱 작업 순 및 난연처리된 벽지원지에 난연제가 혼합된 수성발포 토나 도포 - 천연소재류 접착 - 탑코팅 - 엠보싱 작업 순으로 생산할 수 있는 천연소재류를 이용한 난연 처리된 수성발포 벽지.The flame-retardant wallpaper base material is coated with an aqueous foamed toner mixed with the flame retardant specified above to a predetermined thickness, and then coated with an aqueous-based foamed toner mixed with a natural flame-retardant-gelling-printing-top coating- Flame-retardant water-based foam wallpaper using natural materials that can be produced in order of embossing work and flame retardant-treated wallpaper papers mixed with flame retardant-natural material adhesion-top coating-embossing work.
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Cited By (2)

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KR100680575B1 (en) * 2005-04-08 2007-02-08 장철환 Biodegradable aqueous coating sol composition
KR100767014B1 (en) * 2005-10-17 2007-10-15 전효철 Aqueous foam wallpaper for improving embossable plasticity and Method for manufacturing thereof

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Publication number Priority date Publication date Assignee Title
KR101060225B1 (en) 2008-06-10 2011-08-30 제이씨코리아 주식회사 Wallpaper and its manufacturing method
KR101066031B1 (en) 2009-12-17 2011-09-20 주식회사 보루네오가구 Eco-frendly finished surfaces of furniture materials
KR101657568B1 (en) 2015-04-22 2016-09-19 (주) 숲으로벽지 Aqueous foam wallpaperusing natural meterials with improved fouling and wear resistance
KR102624776B1 (en) * 2021-11-26 2024-01-11 (주)엘엑스하우시스 Wallpaper and manufacturing method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100680575B1 (en) * 2005-04-08 2007-02-08 장철환 Biodegradable aqueous coating sol composition
KR100767014B1 (en) * 2005-10-17 2007-10-15 전효철 Aqueous foam wallpaper for improving embossable plasticity and Method for manufacturing thereof

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