KR200431146Y1 - A ink-jet output material possilble to output double-face - Google Patents

A ink-jet output material possilble to output double-face Download PDF

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KR200431146Y1
KR200431146Y1 KR2020060022377U KR20060022377U KR200431146Y1 KR 200431146 Y1 KR200431146 Y1 KR 200431146Y1 KR 2020060022377 U KR2020060022377 U KR 2020060022377U KR 20060022377 U KR20060022377 U KR 20060022377U KR 200431146 Y1 KR200431146 Y1 KR 200431146Y1
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ink
printing
coating
output
double
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KR2020060022377U
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Korean (ko)
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이경환
우견윤
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(주)티피엠케미컬
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52Macromolecular coatings
    • B41M5/529Macromolecular coatings characterised by the use of fluorine- or silicon-containing organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J3/00Typewriters or selective printing or marking mechanisms characterised by the purpose for which they are constructed
    • B41J3/60Typewriters or selective printing or marking mechanisms characterised by the purpose for which they are constructed for printing on both faces of the printing material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/0041Digital printing on surfaces other than ordinary paper
    • B41M5/0047Digital printing on surfaces other than ordinary paper by ink-jet printing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials

Abstract

본 고안은 양면출력이 가능한 잉크젯 출력용 소재에 관한 것으로서, 기존의 유용성, 수용성의 잉크흡수성 코팅액이 원단에 구성되어진 출력용 소재의 경우 한측의 단면에만 코팅되어 짐으로 양면코팅이 불가능하였다.The present invention relates to a material for inkjet output capable of double-sided printing, in the case of the output material composed of the existing useful, water-soluble ink-absorbing coating liquid in the fabric was coated on only one side of the coating was not possible to double-side coating.

이에 본 고안은 각 코팅액에 따른 코팅방법을 적용함으로 양면 출력이 가능한 잉크젯 출력용 소재를 제공하는 것에 관한 것이다. In this regard, the present invention relates to providing a material for inkjet output capable of printing on both sides by applying a coating method according to each coating liquid.

잉크젯출력용 소재, 양면출력 Inkjet printing material, duplex printing

Description

양면 출력이 가능한 잉크젯 출력용 소재{A ink-jet output material possilble to output double-face}A ink-jet output material possilble to output double-face}

도 1은 실시예 1, 2, 3, 4의 원단 구성 단면도 및 종래의 원단 구성 단면도1 is a cross-sectional view of the original fabric configuration of the first, second, third, and fourth embodiments of the present invention

도 2는 실시예 1, 2, 3의 작업공정도 및 실시예 4의 작업공정도2 is a work flow chart of Examples 1, 2, 3 and a work flow chart of Example 4

도 3은 종래의 작업공정도3 is a conventional working process diagram

본 고안은 organic solvent based ink를 사용한 양면 잉크젯 출력용 소재에 관한 것으로, 이것은 고분자수지와 충진제, 첨가제로 이루어진 코팅액을 천연 또는 합성섬유의 양면에 나이프코팅이나 롤코팅, 콤마코팅 또는 딥핑조에서 함침하여 압축롤러를 통과하고 건조하여 구성된다.The present invention relates to a double-sided inkjet printing material using an organic solvent based ink, which is compressed by impregnating a coating solution composed of a polymer resin, a filler, and an additive on both sides of natural or synthetic fibers in a knife coating, roll coating, comma coating, or dipping tank. It is constructed by passing through a roller and drying.

일반적인 잉크젯용 출력 소재는 출력 시 잉크가 번지지 않고 피딩에 문제가 없어야 하며 소재에 curl이 없어야 한다. 또한 출력 후 건조가 빨라야 하며 색상이 선명해야 하고 우수한 내수성과 내구성, 내후성, 내마모성을 가져야 한다.In general, the inkjet output material should not have ink bleeding during printing, and there should be no problem in feeding, and there should be no curl in the material. In addition, it should be quick to dry after printing, have a clear color, and have excellent water resistance, durability, weather resistance and abrasion resistance.

종래의 solvent based ink를 사용하여 출력하는 잉크젯용 소재는 고분자수지, 충진제, 첨가제로 이루어진 코팅액을 섬유의 단면에만 코팅하여 사용해왔다. 이러한 단점들을 보완하고자 고안한 것으로, 특히 현수막은 양면으로 출력을 하게 되면 앞뒤가 구분이 가지 않으며 양방향에서 두 배의 광고 효과를 기대할 수 있다. 따라서, 양면출력이 가능한 원단의 개발이 절실히 필요한 실정이다.The inkjet material for output using conventional solvent based ink has been used by coating the coating liquid consisting of a polymer resin, a filler, an additive only on the end face of the fiber. It is designed to make up for these shortcomings. Especially, if the banner is printed on both sides, there is no distinction between front and back, and you can expect double advertisement effect in both directions. Therefore, the development of a double-sided fabric is urgently needed.

본 고안의 목적은 양면출력이 가능한 잉크젯 출력용 소재에 관한 것으로서, 이 소재는 양면 출력이 가능하고, 출력 시 잉크가 번지지 않으며, 원단의 피딩이 순조로우며, 출력 후 소재에 curl이 발생하지 않는 특징을 가져야한다. 또한 출력 후 잉크의 건조가 빠르고 색상이 선명하며 우수한 내수성과 내구성을 가지는 동시에 출력 후 재 접착이 일어나지 않으며, 박리현상 또한 전혀 일어나지 않아야한다.The object of the present invention relates to a material for inkjet output capable of printing on both sides, this material is capable of printing on both sides, the ink does not bleed when printing, the feeding of the fabric is smooth, the curl does not occur after printing Should have In addition, after drying, the ink dries quickly, the color is clear, it has excellent water resistance and durability, and re-adhesion does not occur after printing, and peeling does not occur at all.

종래에는 PVC(폴리염화비닐수지)수지를 용융하여 필름으로 만드는 후렉스(제품명)라는 제품이 사용되고 있다. 하지만 이 제품은 무겁고 단단하고 두꺼워서 작업하기가 어렵고 장기간 보관 시에는 원단말림현상(curl)현상이 생기는 단점이 있다. 이러한 단점을 보완하고자 원단에 코팅액을 양면코팅 또는 함침(딥핑) 가공하여 원단처럼 가볍고 견고하면서 양면에 출력할 수 있는 원단을 만드는 것이 본 고안의 궁극적인 목적이다.Conventionally, a product called FLEX (product name) is used to melt PVC (polyvinyl chloride resin) resin to make a film. However, this product is heavy, hard and thick, which makes it difficult to work and has a disadvantage of curling in long-term storage. In order to make up for these drawbacks, it is the ultimate purpose of the present invention to produce a fabric that can be printed on both sides by coating or impregnating (dripping) the coating solution on the fabric.

본 고안은 solvent based ink를 사용하여 양면 출력하는 잉크젯 출력용 소재에 관한 것으로 그 구성은 아래와 같다.The present invention relates to a material for ink jet printing using both solvent based ink and the configuration is as follows.

코팅액의 주성분은 고분자수지와 용제, 충진제, 첨가제로 구성되어져있다. 먼저 고분자수지는 solvent based ink의 주 용제에 적당히 용해되는 잉크적성이 우수한 고분자수지를 선택한다. 종류로는 폴리우레탄수지, 폴리비닐클로라이드수지, 폴리비닐알콜수지, 폴리에스테르수지, 아크릴 에멀젼수지, 아크릴수지 등이 있으며 단독 또는 혼합하여 사용할 수 있다. 고분자수지는 잉크젯 플로터에서 분사된 잉크를 흡수하여 그 표면에 화상을 형성하는 중요한 조성물로, 출력 시 잉크를 용해한 solvent에 의해 일시적으로 용해되지만 solvent에 의한 수축이 적어 화상의 변화를 방지할 수 있다. 용제는 고분자수지를 잘 용해시키는 것으로서 고분자수지의 종류에 따라 사용이 가능하다. 유용성일 경우에는 톨루엔, 아세톤, MEK, DMF, ANON, 메탄올을 사용할 수 있고, 수용성일 경우에는 증류수, 메탄올, DMF를 사용할 수 있다. 충진제에는 이산화티탄늄, 이산화규소, 탄산칼슘, 탈크, 황산바륨 등을 사용할 수 있다. 충진제의 역할은 발색을 향상시키고, 제조 원가를 떨어뜨리며 내구성을 향상시킨다. 또한 원단의 백색도를 향상시켜 빛의 투과도를 조정할 수 있다. 잉크 중에 포함된 solvent를 흡수하여 잉크의 번짐을 방지하고 코팅층의 물리적 강도를 향상시키는 역할을 한다. 그러나 적정한 양이 아닌 지나치게 양이 많이 들어갔을 경우에는 발색을 저하시키고 내구성을 저하시킨다. 첨가제는 수지의 종류에 따라 가소제, 오일류, 활제, UV흡수제, 산화방지제, 석유계 탄화수소, 지방산, 소포제, 레벨링제가 첨가될 수 있다. The main component of the coating solution consists of polymer resin, solvent, filler and additives. First of all, the polymer resin is selected to have a good ink suitability that is appropriately dissolved in the main solvent of solvent based ink. Types include polyurethane resins, polyvinyl chloride resins, polyvinyl alcohol resins, polyester resins, acrylic emulsion resins, acrylic resins, etc., which may be used alone or in combination. Polymer resin is an important composition that absorbs the ink ejected from the inkjet plotter and forms an image on the surface thereof. The polymer resin is temporarily dissolved by a solvent in which the ink is dissolved during printing, but there is little shrinkage caused by the solvent to prevent the change of the image. The solvent dissolves the polymer resin well and can be used depending on the type of the polymer resin. Toluene, acetone, MEK, DMF, ANON, methanol can be used in the case of oil solubility, and distilled water, methanol, DMF can be used in the case of water solubility. Titanium dioxide, silicon dioxide, calcium carbonate, talc, barium sulfate and the like can be used as the filler. The role of fillers improves color development, lowers manufacturing costs and improves durability. In addition, the transmittance of light can be adjusted by improving the whiteness of the fabric. Absorbs the solvent contained in the ink to prevent the spread of the ink and to improve the physical strength of the coating layer. However, if the amount is excessively large, rather than the proper amount, the color deterioration and durability is reduced. Additives may be added plasticizers, oils, lubricants, UV absorbers, antioxidants, petroleum hydrocarbons, fatty acids, antifoaming agents, leveling agents depending on the type of resin.

석유계 탄화수소 조성물과 지방산은 그 조성비에 따라 출력 후의 건조속도를 지연시킬 수 있지만 적정량을 첨가하면 수지층에 안착한 안료입자의 표면을 둘러싸 출력물의 색상을 선명하게 하는 중요한 역할을 한다. The petroleum-based hydrocarbon composition and fatty acid may delay the drying speed after output depending on the composition ratio, but when an appropriate amount is added, the petroleum hydrocarbon composition surrounds the surface of the pigment particle seated on the resin layer and plays an important role of sharpening the color of the output.

대표적인 실시예는 아래와 같다.Representative examples are as follows.

실시예 1. 혼합기에 메틸에틸케톤 33wt%를 넣고 폴리우레탄수지 55wt%를 천천히 투입한다. 저속으로 교반하면서 폴리우레탄수지에 미리 분산시켜놓은 지당(TiO2)을 0.6wt%를 넣고 고속 교반하여 지당을 분산시킨다. 이후 실리카(SiO2)를 3.6wt%른 투입하여 백색도와 점도를 조정한다. 이후 석유계 탄화수소 7.0wt%, 자외선흡수제 0.3wt%, 산화방지제0.3wt%, 형광증백제0.2wt%를 투입하여 잉크젯 출력용 소재의 코팅제를 완성한다. 완성된 코팅액을 발수 처리된 원단에 나이프 코팅법이나 콤마코팅법의 선택된 방법으로 양면에 코팅하여 이루어지는 잉크젯 양면 출력용 소재에 관한 것이다. Example 1. 33 wt% of methyl ethyl ketone was added to a mixer, and 55 wt% of a polyurethane resin was slowly added thereto. While stirring at a low speed, 0.6 wt% of the pre-dispersed liposaccharide (TiO 2) was previously added to the polyurethane resin, and the liposaccharide was dispersed by high speed stirring. Thereafter, 3.6 wt% of silica (SiO2) was added to adjust whiteness and viscosity. Since the petroleum hydrocarbon 7.0wt%, UV absorber 0.3wt%, antioxidant 0.3wt%, fluorescent brightener 0.2wt% was added to complete the coating material of the inkjet output material. The present invention relates to a material for inkjet duplex printing, in which a finished coating solution is coated on both surfaces by a knife coating method or a comma coating method on a water-repellent treated fabric.

실시예 2. 혼합기에 물을 15wt%를 투입 후 아크릴수지 70wt%를 넣고 미리 아크릴수지에 분산시킨 지당(TiO2)을 3.0wt%를 넣고 교반하면서 실리카(SiO2)를 3.0wt%를 투입하고 고속으로 교반하여 실리카를 분산시킨다. 이후 석유계 탄화수소 화합물을 6.0wt%를 투입한다. 첨가제로 소포제, 레벨링제, 형광증백제, 자외선흡수 제, 산화방지제등을 혼합하여 3wt%를 투입하여 잉크젯 출력용 소재의 코팅제를 완성한다. 완성된 코팅액을 발수 처리된 원단에 나이프 코팅법이나 콤마코팅법의 선택된 방법으로 양면에 코팅하여 이루어지는 잉크젯 양면 출력용 소재에 관한 것이다. Example 2 15wt% of water was added to the mixer, and 70wt% of acrylic resin was added, and 3.0wt% of silica (TiO2), which was previously dispersed in acrylic resin, was added, and 3.0wt% of silica (SiO2) was added thereto at high speed. Stir to disperse the silica. Since 6.0wt% of a petroleum hydrocarbon compound is added. As an additive, 3 wt% of antifoaming agent, leveling agent, fluorescent brightener, ultraviolet absorber, antioxidant, etc. is mixed to complete coating of inkjet printing material. The present invention relates to a material for inkjet duplex printing, in which a finished coating solution is coated on both surfaces by a knife coating method or a comma coating method on a water-repellent treated fabric.

실시예 3. 혼합기에 메틸에틸케톤, 톨루엔 혼합용매를 45wt%를 넣고 폴리비닐클로라이드수지 20wt%를 천천히 투입한다. 고속으로 교반하면서 폴리비닐클로라이드수지를 용해한다. 지당(TiO2) 6.0wt%와 DOP(가소제) 15wt%를 넣고 고속교반하여 지당을 분산시킨다. 이후 실리카(SiO2)를 4.0wt%른 투입하여 백색도와 점도를 조정한다. 이후 석유계 탄화수소 8.0wt%, 자외선흡수제 1.0wt%, 산화방지제0.5wt%, 형광증백제0.5wt%를 투입하여 잉크젯 출력용 소재의 코팅제를 완성한다. Example 3. 45 wt% of methyl ethyl ketone and toluene mixed solvent were added to the mixer, and 20 wt% of polyvinyl chloride resin was slowly added thereto. The polyvinyl chloride resin is dissolved while stirring at high speed. 6.0 wt% of lipo sugar (TiO2) and 15 wt% of DOP (plasticizer) are added to the liquor to stir at high speed to disperse the sugar. Thereafter, 4.0 wt% of silica (SiO 2) was added to adjust whiteness and viscosity. Thereafter, 8.0 wt% of petroleum hydrocarbon, 1.0 wt% of UV absorber, 0.5 wt% of antioxidant, and 0.5 wt% of fluorescent brightener are added to complete the coating material of the inkjet output material.

완성된 코팅액을 발수 처리된 원단에 나이프 코팅법이나 콤마코팅법의 선택된 방법으로 양면에 코팅하여 최종적으로 도 1과 같은 구조로 이루어진 잉크젯 양면 출력용 소재를 구성하게 되는 것이다. The finished coating solution is coated on both sides by a knife coating method or a comma coating method on the water-repellent fabric to finally form an inkjet duplex printing material having a structure as shown in FIG. 1.

실시예 4. 혼합기에 물을 35wt%를 투입 후 아크릴수지 50wt%를 넣고 미리 아크릴수지에 분산시킨 지당(TiO2)을 3.0wt%를 넣고 교반하면서 실리카(SiO2)를 3.0wt%를 투입하고 고속으로 교반하여 실리카를 분산시킨다. 이후 석유계 탄화수소 화합물을 6.0wt%를 투입한다. 첨가제로 소포제, 레벨링제, 형광증백제, 자외선흡수제, 산화방지제등을 혼합하여 3wt%를 투입하여 잉크젯 출력용 소재의 코팅제를 완 성한다. 완성된 코팅액을 원단에 딥핑 코팅법이나 함침코팅법의 선택된 방법으로 양면에 코팅하여 도 2와 같은 잉크젯 양면 출력용 소재가 구성되는 것이다. Example 4 After adding 35wt% of water to the mixer, 50wt% of acrylic resin was added, 3.0wt% of TiO2 dispersed in acrylic resin was added, and 3.0wt% of silica (SiO2) was added while stirring. Stir to disperse the silica. Since 6.0wt% of a petroleum hydrocarbon compound is added. As an additive, 3 wt% is added by mixing an antifoaming agent, a leveling agent, a fluorescent brightener, an ultraviolet absorber, and an antioxidant to complete a coating material for inkjet printing. The finished coating solution is coated on both sides of the fabric by a dipping coating method or a method of impregnation coating to fabricate an inkjet double-sided output material as shown in FIG. 2.

상기 실시예와 같이 유용성, 수용성 잉크흡수성 코팅액을 사용한 양면 출력이 가능한 잉크젯 출력용 소재가 제공 가능한 것이다. As in the above embodiment, it is possible to provide a material for inkjet output capable of double-sided printing using an oil-soluble, water-soluble ink-absorbing coating solution.

본 고안에서 구성한 양면출력이 가능한 잉크젯 출력용 소재는 종래의 후렉스 원단에 비해 인쇄적성이 우수하고 원단의 무게를 현저히 감소시켰다. 후렉스에 비해 원단 두께가 얇아서 잉크젯 출력용 소재로서 적합하다고 할 수 있다. 이 원단은 양면에 코팅이 되어있기 때문에 curl이 발생하지 않으며, 출력 시에도 잉크가 번지지 않고, 원단의 피딩에도 전혀 문제가 없다. 또한 출력 후, 건조가 빠르고 색상이 선명하며, 우수한 내수성과 내구성을 나타내었다. 따라서 후렉스를 대체할 수 있으며 가격이 저렴하여 현수막으로도 사용이 가능하다. 현수막으로 사용 시에는 양면 광고효과가 기대되고 내후성이 우수하여 장기간 사용이 가능하므로 그 효과가 다대하다고 할 수 있다.The ink-jet printing material capable of printing on both sides of the present invention has superior printability and significantly reduces the weight of the fabric compared to the conventional FLEX fabric. Its thickness is thinner than FLEX, making it suitable for inkjet printing. Since the fabric is coated on both sides, curl does not occur, and ink does not spread even during printing, and there is no problem in feeding of the fabric. In addition, after printing, the drying was fast, the color was clear, and it showed excellent water resistance and durability. Therefore, it can replace FLEX and can be used as a banner because of its low price. When used as a banner, it is expected to have a double-sided advertising effect and excellent weather resistance, so it can be used for a long time.

Claims (2)

유용성의 잉크흡수성 코팅액을 천연섬유 또는 합성섬유에 하단 및 상단부에 각각 코팅함으로 구성되는 양면 출력이 가능한 잉크젯 출력용 소재Inkjet printing material capable of double-sided printing consisting of coating a water-soluble ink-absorbing coating solution on the lower and upper portions of natural or synthetic fibers, respectively. 수용성의 잉크흡수성 코팅액을 천연섬유 또는 합성섬유에 딥핑 코팅법이나 함침코팅법을 적용하여 원단의 하단 및 상단부에 코팅액이 구성되어 양면 출력이 가능한 잉크젯 출력용 소재 Water-based ink-absorbing coating solution is applied to natural fiber or synthetic fiber by applying dipping coating method or impregnating coating method.
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