KR20040107365A - The generation method of electricity utilizing the salt water - Google Patents

The generation method of electricity utilizing the salt water Download PDF

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KR20040107365A
KR20040107365A KR1020040040204A KR20040040204A KR20040107365A KR 20040107365 A KR20040107365 A KR 20040107365A KR 1020040040204 A KR1020040040204 A KR 1020040040204A KR 20040040204 A KR20040040204 A KR 20040040204A KR 20040107365 A KR20040107365 A KR 20040107365A
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electricity
electrolyte
salt water
electrode plate
generated
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Korean (ko)
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정병윤
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파인웰빙 주식회사
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
    • H01M4/8652—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites as mixture
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
    • C25B11/069—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of at least one single element and at least one compound; consisting of two or more compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B5/00—Electrogenerative processes, i.e. processes for producing compounds in which electricity is generated simultaneously
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/133—Renewable energy sources, e.g. sunlight

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Hybrid Cells (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

PURPOSE: To provide a method for producing electricity using salt water, wherein electricity can be obtained only by chemical reaction without using of general electricity, storage battery or dry battery and without charging using solar energy or other general charging so that the obtained electricity is used in various application fields. CONSTITUTION: The method for producing electricity using salt water is characterized in that an anode plate manufactured of a metal oxidizer mixture(Ca+Mg+Al+Zr+Zn or Mg+copper(Cu)+brass(P+Cu)) and a cathode plate manufactured of an inorganic reductant mixture(TiO2+BaO+Al2O3+MgO2+ZrO2+NiO+K2O+CuO) are used as electrodes, and salt water is used as an electrolyte, wherein a power supply terminal is connected to the cathode plate(4) that is a reductant compound and the anode plate(3) that is an oxidizer compound, salt water in which water is mixed with salt in a certain mixing ratio or seawater as the electrolyte(6) is inputted into an electrolyte container(2), the salt water(seawater) that is the electrolyte is chemically reacted with the anode plate to generate cations and chemically reacted with the cathode plate to generate anions, electricity is generated by movements of the cations and the anions, the generated electricity is obtained through a power supply part(1), and hydrogen gas generated by the chemical reaction is ejected through a hydrogen gas outlet(7) formed on an upper part of a container cover(5).

Description

소금물을 이용한 전기 생산 방법{The generation method of electricity utilizing the salt water}The generation method of electricity utilizing the salt water}

본 발명은 일반 전기나 축전지, 건전지를 사용하지 않을 뿐만 아니라 태양에너지를 이용한 충전 및 기타 일반적인 충전을 하지 않고 단지 화학반응에 의하여 전기를 얻을 수 있는 소금물을 이용한 전기 생산 방법에 관한 것으로, 좀 더 구체적으로는 금속산화제 혼합물(Ca + Mg + Al + Zr + Zn 또는 Mg + 동(Cu) + 황동(P+Cu))로 제조된 양극판(플러스(+)극판)과 무기물 환원제 혼합물(TiO2+ BaO + Al2O3+ MgO2+ ZrO2+ NiO + K2O + CuO)로 제조된 음극판(마이너스(-)극판)을 전극으로 사용하고 전해질로서 소금물을 이용함으로써 전해질을 통한 음극판과 양극판의 전기화학반응에 의하여 전기를 생산할 뿐만 아니라 부수적으로 수소가스를 얻음으로서 라디오, 텔레비젼 등의 전원용, 일반 조명용, 다용도의 비상용, 이동이 필요한 곳에서의 사용 등으로 광범위하게 사용될 수 있어 섬 지방 소형 어선에 특히 적합한 전기 생산 방법에 관한 것이다.The present invention relates to a method of producing electricity using brine that can obtain electricity only by chemical reactions without using general electricity, storage batteries or batteries, as well as charging with solar energy and other general charging. For example, a positive electrode plate (plus (+) plate) made of a metal oxidant mixture (Ca + Mg + Al + Zr + Zn or Mg + copper (Cu) + brass (P + Cu)) and an inorganic reducing agent mixture (TiO 2 + BaO) + Electrodes of negative electrode plate and positive electrode plate through electrolyte by using negative electrode plate (negative electrode plate) made of Al 2 O 3 + MgO 2 + ZrO 2 + NiO + K 2 O + CuO as electrode and using brine as electrolyte In addition to producing electricity by chemical reactions and acquiring hydrogen gas incidentally, it can be widely used for power supply such as radio and TV, general lighting, multi-purpose emergency use, and where it is necessary to move. The present invention relates to a method of producing electricity, which is particularly suitable for island fishing boats.

일반적으로 전기는 수력발전, 화력발전, 원자력 발전 등과 같이 각종 에너지원을 이용하여 생성하고 이를 각종 용도에 맞게 조절하여 소비자에게 제공하여 사용하여 오고 있지만, 전기를 공급하기 위해서는 전선을 반드시 통하여야 하므로 전선을 연결하기 어려운 벽지 또는 섬 지방이라든지 이동하는 물체에는 전기의 공급이 용이하지 못한 단점이 있다.In general, electricity has been generated by using various energy sources such as hydroelectric power, thermal power, nuclear power, etc. and adjusted to suit various purposes, and provided to consumers.However, in order to supply electricity, electricity must be provided through electric wires. It is difficult to connect the wallpaper or island, or the moving object is difficult to supply electricity.

이러한 단점을 극복하기 위하여 건전지, 축전지 등과 같이 어느 곳에서나 전기를 발생시키는 수단을 별도로 사용하고 있지만, 전기 발생량이 작아 소량의 전력량이 필요한 경우에만 한정 적용되는 큰 단점뿐만 아니라 각종 환경 오염을 유발하고 대용량을 전력을 발생시키기 위해서는 부피가 무척 커져 실제적으로 상용화가 곤란하였으며, 발전기를 이용할 경우에는 에너지원이 항상 필수적이기 때문에 사용 시간에 제한을 받는 등의 문제점이 있어 소량의 전기를 원하는 경우에는 축전지가가장 효과적으로 사용되고 있다.In order to overcome these disadvantages, a separate means of generating electricity is used anywhere, such as batteries and accumulators, but it is not only a big disadvantage that is applied only when a small amount of electricity is needed because of the small amount of electricity, but also causes various environmental pollution and In order to generate power, the volume is so large that it is practically difficult to commercialize. When using a generator, energy sources are always essential, which limits the usage time. It is used effectively.

축전지는 양과 음의 전극판과 전해액으로 구성되어 있어, 화학작용에 의해 직류기전력을 생기게 하여 전원으로 사용할 수 있는 장치를 말하는 것으로, 화학에너지를 전기에너지로 변화시킬 수가 있는데, 이 상태를 방전이라 하고, 다른 전원으로부터 전기에너지를 공급하여 화학에너지로 변화시켜 축적할 수 있는데, 이 상태를 충전이라 하며, 이와 같이 충전과 방전이 반복되는 전지를 축전지 또는 2차전지라고 한다. 건전지는 충전과 방전이 반복되지 않는 것이며, 이것은 1차전지의 하나이다. 축전지로는 1859년 프랑스의 R.L.G.플랑테가 고안한 납축전지가 가장 널리 사용되며, 그밖에 알칼리 축전지가 있다.A storage battery is composed of positive and negative electrode plates and electrolytes, and it is a device that can generate direct current electromotive force by chemical action and can be used as a power source. It can change chemical energy into electrical energy. By supplying electrical energy from another power source and converting it into chemical energy, it can be accumulated. This state is called charging. A battery in which charging and discharging are repeated is called a storage battery or a secondary battery. The battery is not repeated charging and discharging, which is one of the primary battery. The lead acid battery, designed by R.L.G. Plante of France in 1859, is the most widely used, and there are also alkaline batteries.

납축전지는 양극에 과산화납, 음극에 해면상의 납을 사용하고 비중이 1.2 ~ 1.3인 황산을 넣은 것으로, 실제로는 극판면적의 증가를 위하여 많은 양극과 음극의 극판이 병렬로 연결되어 있으며, 또 각 극판 사이에는 절연물로 만든 격리판이 들어 있다. 충전된 상태에서는 양극은 이산화납, 음극은 납이지만 방전을 계속하면 양극과 음극은 다같이 황산납으로 되며, 동시에 물이 생기게 되므로 전해액의 비중이 저하한다. 또, 충전된 상태에서 양극은 다갈색, 음극은 납색으로, 방전을 계속하면 양극이 다같이 회백색으로 된다. 납축전지의 기전력은 약 2V이지만, 방전하는 사이에 서서히 저하하여 1.8V정도까지 저하하면 다시 충전을 시켜야 한다.Lead-acid batteries use lead peroxide for the cathode and sea-level lead for the cathode, and sulfuric acid with a specific gravity of 1.2 to 1.3. Actually, many anode and cathode plates are connected in parallel to increase the pole area. Between the plates is a separator made of insulation. In the charged state, the positive electrode is lead dioxide and the negative electrode is lead, but if discharge is continued, both the positive electrode and the negative electrode are both lead sulfate, and at the same time water is generated, so that the specific gravity of the electrolyte decreases. In the charged state, the positive electrode is dark brown, the negative electrode is lead color, and when discharge is continued, the positive electrode becomes gray white together. The electromotive force of the lead acid battery is about 2V, but when the discharge gradually decreases to about 1.8V, it needs to be charged again.

축전지는 크기에 관계없이 기전력은 같으나, 극판 면적을 증가하여 전지의 조를 크게 하면 용량이 증가해서 많은 전류를 흐르게 할 수 있다. 충전은 전지의 양 단자에 전원의 양 단자를 연결하고 규정의 전류값를 유지하면서 계속한다. 충전이 진행되는데 따라 양극판은 다갈색으로, 음극판은 납색으로 변화하며, 충전전류를 흘리는 상태에서 전압이 2.7 ~ 2.8V로 높아지며, 전해액의 비중이 서서히 증가하여 1.26 정도로 되면 충전종료로 보아도 된다.A storage battery has the same electromotive force regardless of its size, but if the size of the battery is increased by increasing the pole plate area, the capacity can be increased to allow a large current to flow. Charging continues by connecting both terminals of the power supply to both terminals of the battery and maintaining the specified current value. As charging progresses, the positive electrode plate is dark brown, and the negative electrode plate is changed to lead color. In the state of flowing the charging current, the voltage is increased to 2.7 to 2.8 V, and the specific gravity of the electrolyte gradually increases to about 1.26.

충, 방전의 반복회수는 많은 것에서는 1,000회 이상이 되며, 내용연수는 긴 것은 몇 년이나 되고, 축전지의 효율은 충, 방전할 때의 암페어시(Ah) 또는 와트시(Wh)의 비를 취하여, 각각 암페어시 효율, 와트시 효율이라고 한다. 전자는 대개 90%, 후자는 일반적으로 75%이다. 축전지의 기전력은 주위온도가 변화해도 거의 변화하지 않는다고 볼 수 있으나, 30℃ 정도의 저온에서는 성능이 저하한다. 용도는 가솔린 자동차의 점화용 전원, 전기기관차·전동차·잠수함의 동력, 교통신호, 열차내 전등용, 직류전원 등에 사용된다.The number of repetition cycles of charging and discharging is more than 1,000 times in many cases, and the useful life is many years, and the efficiency of the battery is determined by taking the ratio of ampere hour (Ah) or watt hour (Wh) when charging and discharging. , Ampere-hour efficiency and watt-hour efficiency, respectively. The former is usually 90% and the latter is generally 75%. The electromotive force of the battery is hardly changed even when the ambient temperature changes, but the performance decreases at a low temperature of about 30 ° C. It is used for ignition power of gasoline cars, power of electric locomotives, electric cars, submarines, traffic signals, lights for trains, direct current power, etc.

알칼리 축전지는 양극에 수산화니켈, 음극에 카드뮴, 전해액으로는 알칼리 용액을 사용한 것을 융너(Jungner)식 알칼리 축전지라 하며, 음극에 철을 사용하고 다른 것은 융너식과 같은 것을 에디슨(Edison)식 알칼리 축전지라 하고, 일반적으로 융너식 알칼리 축전지가 널리 사용되고 있다.Alkaline accumulators use nickel hydroxide for the positive electrode, cadmium for the negative electrode, and alkaline solutions for the electrolyte. These are called alkaline type alkaline batteries. In general, a melter type alkaline storage battery is widely used.

기전력은 약 1.2V인데, 방전종료시에는 1.1V로 된다. 암페어시 효율은 약 85%, 와트시 효율은 약 80%이며, 알칼리 축전지는 진동에 견디며, 자기방전이 적고 평균수명이 길어 7~25년 사용할 수 있으며, 또 20~45℃의 넓은 온도범위에서 사용할 수 있다. 알칼리 축전지 중에서 극판에 니켈·카드뮴을 사용한 것은 극판의 제법에 소결법을 사용한 것이 있다.The electromotive force is about 1.2V, and at the end of discharge, it becomes 1.1V. The ampere-hour efficiency is about 85% and the watt-hour efficiency is about 80%. Alkaline batteries withstand vibrations, have a low self-discharge and have a long average life, which can be used for 7 to 25 years, and can be used in a wide temperature range of 20 to 45 ℃. Can be. Among the alkaline storage batteries, nickel cadmium is used for the electrode plates, and some of them use the sintering method for producing the electrode plates.

이것은 내부저항이 작고 완전한 밀봉식으로 만들어져서 소형경량화되며, 저온시의 특성이 좋다. 또 산화은 분말을 은망에 도포해서 굳힌 것을 양극판으로 하고, 수산화아연을 음극판으로 하여 전해액으로는 가성칼리(수산화칼륨) 용액을 사용한 알칼리 축전지가 있다. 방전 중의 전압은 1.2 ~ 1.5 V, 소중량으로 대용량이 만들어지고 급격한 대전류가 흐를 수 있는 등의 특징이 있기 때문에, 가격은 비싸지만 통신병기나 로켓의 전원으로서 주목되고 있다.It is made of small internal resistance and completely sealed, so it is compact and lightweight, and has good characteristics at low temperatures. There is also an alkaline storage battery in which a silver oxide powder is coated on a silver network and hardened to serve as a positive electrode plate, zinc hydroxide as a negative electrode plate, and a caustic (potassium hydroxide) solution is used as an electrolyte. Since the voltage during discharge is 1.2 to 1.5 V, a small weight makes a large capacity, and a rapid large current flows, it is expensive, but it is attracting attention as a power source for communication weapons and rockets.

그러나, 대부분의 축전지들은 인체에 유해할 뿐만 아니라 환경오염 문제를 유발하는 화학물질들을 사용하는 단점이 있고, 인체에 유해한 전해액을 사용하고 있기 때문에 전해액의 교체가 거의 불가능한 상태이며, 극판을 교체할 수가 없기 때문에 수명이 짧으며, 요구 전류를 마음대로 조절할 수 없이 고정적이라는 문제점이 있었다.However, most batteries have a disadvantage of using chemicals that are not only harmful to the human body but also cause environmental pollution problems. Since the electrolyte is harmful to the human body, it is almost impossible to replace the electrolyte. There is a problem that the life is short because there is no, the fixed current can not be adjusted arbitrarily.

따라서, 본 발명의 목적은 일반 전기나 축전지, 건전지를 사용하지 않을 뿐만 아니라 태양에너지를 이용한 충전 및 기타 일반적인 충전을 하지 않고 단지 화학반응에 의하여 전기를 얻을 수 있어 라디오, 텔레비젼 등의 전원용, 일반 조명용, 다용도의 비상용, 이동이 필요한 곳에서의 사용 등으로 광범위하게 사용될 수 있는 소금물을 이용한 전기 생산 방법을 제공하는 데 있다.Accordingly, an object of the present invention is not only to use general electricity, storage batteries, batteries, but also to obtain electricity only by chemical reaction without charging with solar energy and other general charging, for power supply of radio, TV, etc., for general lighting In addition, the present invention provides a method of producing electricity using brine, which can be widely used for various purposes such as emergency use and use where it is necessary to move.

상기 목적뿐만 아니라 용이하게 표출될 수 있는 다른 목적을 달성하기 위하여 본 발명에서는 금속산화제 혼합물(Ca + Mg + Al + Zr + Zn 또는 Mg + 동(Cu) +황동(P+Cu))로 제조된 양극판(플러스(+)극판)과 무기물 환원제 혼합물(TiO2+ BaO + Al2O3+ MgO2+ ZrO2+ NiO + K2O + CuO)로 제조된 음극판(마이너스(-)극판)을 전극으로 사용하고 전해질로서 소금물을 이용함으로써 전해질을 통한 음극판과 양극판의 전기화학반응에 의하여 전기를 생산하므로서 일반적인 충전을 하지 않고 광범위하게 사용될 수 있는 효과를 얻을 수 있었다.In order to achieve the above object as well as other objects that can be easily expressed in the present invention prepared with a metal oxidant mixture (Ca + Mg + Al + Zr + Zn or Mg + copper (Cu) + brass (P + Cu)) A negative electrode plate (negative electrode plate) made of a positive electrode plate (plus electrode plate) and an inorganic reducing agent mixture (TiO 2 + BaO + Al 2 O 3 + MgO 2 + ZrO 2 + NiO + K 2 O + CuO) By using and using brine as the electrolyte to produce electricity by the electrochemical reaction of the negative electrode plate and the positive electrode plate through the electrolyte it was possible to obtain an effect that can be widely used without general charging.

도 1은 본 발명에 따른 전기 생산 방법을 나타내는 모식도이다.1 is a schematic diagram showing a method for producing electricity according to the present invention.

*도면의 주요부분에 대한 부호의 설명** Description of the symbols for the main parts of the drawings *

1. 전원부 2. 전해질 용기1. Power Supply Unit 2. Electrolyte Container

3. 양극판 4. 음극판3. positive plate 4. negative plate

5. 용기 덮개 6. 전해질5. Container cover 6. Electrolyte

7. 수소가스 분출구7. Hydrogen gas outlet

이하 첨부된 도면에 의해 본 발명을 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.

본 발명에 따른 소금물을 이용한 전기 생산 방법은 도 1에 도시된 바와 같이 금속산화제 혼합물(Ca + Mg + Al + Zr + Zn 또는 Mg + 동(Cu) + 황동(P+Cu))로 제조된 양극판(플러스(+)극판)과 무기물 환원제 혼합물(TiO2+ BaO + Al2O3+ MgO2+ ZrO2+ NiO + K2O + CuO)로 제조된 음극판(마이너스(-)극판)을 전극으로 사용하고 전해질로서 소금물을 이용하는 것으로 특징지워진다.Electric production method using the brine according to the present invention is a positive electrode plate made of a metal oxidant mixture (Ca + Mg + Al + Zr + Zn or Mg + copper (Cu) + brass (P + Cu)) as shown in FIG. A negative electrode plate (minus electrode plate) made of (plus (+) plate) and inorganic reducing agent mixture (TiO 2 + BaO + Al 2 O 3 + MgO 2 + ZrO 2 + NiO + K 2 O + CuO) as an electrode And salt water as electrolyte.

먼저, 환원제 화합물인 음극판(4)과 산화제 화합물인 양극판(3)에 전원 단자를 연결하고, 전해질 용기(2) 속에 전해질(6)로서 일정비율로 물과 소금을 혼합한 소금물을 투입하거나, 바닷물을 넣는다.First, a power supply terminal is connected to the negative electrode plate 4, which is a reducing agent compound, and the positive electrode plate 3, which is an oxidizing agent compound, and salt water mixed with water and salt at a predetermined ratio as an electrolyte 6 is introduced into the electrolyte container 2, or seawater is used. Put it.

이러한 상태에서 전해질(6)인 소금물(바닷물)은 양극판(3)과 화학반응을 일으켜 양이온을 발생시키고, 음극판(4)과 화학반응을 일으켜 음이온을 발생시키게 된다.In this state, the salt water (sea water), which is the electrolyte 6, generates a positive ion by chemical reaction with the positive electrode plate 3, and generates a negative ion by chemical reaction with the negative electrode plate 4.

이때 양이온과 음이온의 이동에 의하여 전기가 발생되고 발생된 전기는 전원부(1)를 통하여 얻을 수 있게 되고, 화학반응에 의해 발생되는 수소가스는 용기 덮개(5) 상단부에 형성된 수소가스분출구(7)로 분출되게 된다.At this time, electricity is generated by the movement of cations and anions, and the generated electricity can be obtained through the power supply unit 1, and the hydrogen gas generated by the chemical reaction is the hydrogen gas outlet 7 formed at the upper end of the container cover 5. Will be ejected.

전력의 용량은 양극판(3)과 음극판(4)의 크기와 전해질인 소금물의 량과 농도에 따라 달라지게 되며, 이들 양쪽 극을 서로 같은 극끼리 병렬로 연결하면 1개의 극판에서 얻을 수 있는 전기에 연결한 극의 수를 곱한 만큼의 전기를 생산할 수 있다.The capacity of the electric power depends on the size of the positive electrode plate 3 and the negative electrode plate 4 and the amount and concentration of the brine as an electrolyte, and when the two poles are connected in parallel with each other in parallel, You can produce as much electricity as the number of poles connected.

소금물의 농도는 얻고자 하는 전력량에 따라 적절히 조절할 수 있으며, 금속화합물로 된 양극판(3)은 전자 소멸 전극(electron sink electrode)으로서 한정된 시간이 지나게 되면 교체를 하여야 하며, 음극판(4)도 한정된 시간은 있으나 통상 양극판(3)의 수명보다 약 30배정도 길다.The concentration of the brine can be properly adjusted according to the amount of power to be obtained. The positive electrode plate 3 made of a metal compound is an electron sink electrode, and should be replaced after a limited time, and the negative electrode plate 4 is also limited time. Although there is usually about 30 times longer than the life of the positive electrode plate (3).

또한, 소금물도 시간이 지날수록 양극판(3) 및 음극판(4)과의 화학반응으로 인하여 이온의 발생량이 저하되므로 일정량씩 소금물을 계속적으로 투입하면서 투입된 양만큼 배출시키는 방법이 지속적으로 전기를 얻는 데 효과적이지만, 설비가 복잡해지기 때문에 소금물의 농도가 저하되거나 얻고자 하는 전력량을 얻기가 어려울 경우에는 소금물을 교체하는 것이 바람직하다.In addition, since the amount of generated ions decreases due to a chemical reaction with the positive electrode plate 3 and the negative electrode plate 4 as time passes, the method of continuously discharging the salt water by a predetermined amount to discharge the input amount is used to continuously obtain electricity. It is effective, but it is desirable to replace the brine when the concentration of the brine is reduced or it is difficult to obtain the amount of power to be obtained because of the complicated equipment.

전기를 생산하기 위하여 소금물을 투입시 1.2ℓ의 물에 40 ~ 220g의 소금을 용해한 것을 전해질 용액으로 사용하되, 1A 미만의 전류가 필요할 경우에 1.2ℓ의 물에 40 ~ 60g의 소금을 용해한 것을, 1 ~ 2A의 전류가 필요할 경우에 1.2ℓ의 물에 100 ~ 120g의 소금을 용해한 것을, 2A 이상의 전류가 필요할 경우에 1.2ℓ의 물에 150 ~ 220g의 소금을 용해한 것을 사용하는 것이 바람직하다.To produce electricity, 40 to 220 g of salt was dissolved in 1.2 L of water when the brine was added. When less than 1A of current is needed, 40 to 60 g of salt is dissolved in 1.2 L of water. It is preferable to use 100-120 g of salt dissolved in 1.2 L of water when a current of 1 to 2 A is required, and 150 to 220 g of salt dissolved in 1.2 L of water when a current of 2 A or more is required.

12V의 전압이 방전될 때까지 전해액을 넣지만, 9V의 전압이 필요한 경우에는 각각 9개의 음극판(4) 및 양극판(3)만이 필요하고, 사용 초기에는 방전 전압이 높기 때문에 적당한 개수의 양극판과 음극판을 적절히 삽입하여 사용할 수 있으며, 사용 중에 수소 가스가 발생될 우려가 있으므로 실외에서 사용하거나 실내일 경우에는 통풍장치가 되어 있는 곳에서 사용하여야 하고, 장시간 사용 시에 전해질 용기(2)속의 불순물을 제거하는 것이 바람직하며, 전지 접촉 부분의 산화물은 100 ~ 150시간 사용 후 한번씩 세척하여 제거하여야 하며, 세척 후에는 윤활유를 바르는 것이 효과적이다.The electrolyte is added until the voltage of 12V is discharged. However, when 9V is required, only nine negative electrode plates 4 and positive electrode plates 3 are needed, respectively, and since the discharge voltage is high at the beginning of use, an appropriate number of positive electrode plates and negative electrode plates are required. It can be used by inserting it properly, and there is a danger of generating hydrogen gas during use, so it should be used outdoors or indoors when it is ventilated, and remove impurities in the electrolyte container (2) during long time use. Preferably, the oxide in the battery contact portion should be removed by washing once after 100 to 150 hours of use, and it is effective to lubricate after washing.

8시간 이상 사용하지 않을 경우에는 전해액을 제거하고 전극판에 붙은 불순물을 깨끗이 제거하며, 각각의 극판은 사용시간이 길어질수록 견고성이 저하되고 녹는 현상이 발생하므로 수명이 다하기 전에 교체하는 것이 바람직하다.If not used for more than 8 hours, the electrolyte solution is removed and impurities attached to the electrode plate are removed cleanly. Each electrode plate is recommended to be replaced before the end of life because the durability decreases and melts as the use time increases. .

상기와 같은 본 발명의 방법에 의하여 생산되는 전기는 전압이 12V이고, 최종 방전 전압은 10V이며, 전해질(소금물)의 교체시까지 축전지로서의 용량(암페어시 Ah)은 5이고, 전해질(소금물)의 교체시까지 사용시간은 1A의 전류일 경우 5시간 이상, 5A의 전류일 경우 0.9 ~ 1시간 정도이며, 전류의 크기와 전해질 용액 등 다른 요인에 영향을 받기는 하지만 양극세트의 사용시간은 1A의 전류일 경우 40시간 이상, 5A의 전류일 경우 8시간 정도이고, 작동 최소 온도는 -10℃이며, 최소 수명은 600시간이었다.The electricity produced by the method of the present invention as described above has a voltage of 12V, the final discharge voltage is 10V, the capacity (Ah at ampere) as the battery until replacement of the electrolyte (salt) is 5, the replacement of the electrolyte (salt) The operating time until 1A current is 5 hours or more for 1A current and 0.9 ~ 1 hour for 5A current.However, the usage time of the positive electrode set is 1A current although it is affected by other factors such as the magnitude of the current and electrolyte solution. For example, 40 hours or more, 8 hours for 5A current, the minimum operating temperature is -10 ℃, the minimum life was 600 hours.

좀 더 음극판(4)과 양극판(3)에 대하여 설명하면, 금속 산화제혼합물(Ca+Mg+Al+Zr+Zn또는 Mg+동(Cu)+황동(P+Cu))인 플러스극판(+)과 무기물 환원제 혼합물(TiO2+BaO+Al2O3+MgO2+ZrO2+NiO+K2O+CuO)인 마이너스극판(-)으로 구성하되, 출력(W) 및 전압(V), 전류(Ah)의 세기는 마이너스극판의 면적단위 구성과 플러스극판의 화합 조성물 비율에 따라 전기적 에너지 공급 효율성을 높일 수 있게 된다.The negative electrode plate 4 and the positive electrode plate 3 will be described in detail with the positive electrode plate (+), which is a metal oxidant mixture (Ca + Mg + Al + Zr + Zn or Mg + copper (Cu) + brass (P + Cu)). Consists of a negative electrode plate (-), which is an inorganic reducing agent mixture (TiO 2 + BaO + Al 2 O 3 + MgO 2 + ZrO 2 + NiO + K 2 O + CuO), with output (W) and voltage (V) and current ( Ah) strength can increase the electrical energy supply efficiency according to the area unit configuration of the negative electrode plate and the ratio of the compound composition of the positive electrode plate.

금속산화제 및 무기물 환원제는 전기전도도를 향상시킬 수 있는 즉, 이온교환성능이 우수한 것이라면 어떠한 것이라도 사용이 가능하지만, 양극판(3)에 사용되는 금속 산화제로는 소금물에서 발생되는 Cl-이온이나 OH-이온과의 반응성이 우수한 것을 사용하는 것이 효과적이며, 음극판(4)에 사용되는 무기물 환원제는 소금물에서 발생되는 양이온(Na+, H+)과의 반응성이 우수한 것을 사용하는 것이 바람직하다.The metal oxidant and the inorganic reducing agent can improve the electrical conductivity, that is, any one can be used as long as it has excellent ion exchange performance, but the metal oxidant used in the positive electrode plate 3 is Cl - ions or OH - generated in salt water. It is effective to use the one having excellent reactivity with ions, and the inorganic reducing agent used for the negative electrode plate 4 is preferably one having excellent reactivity with cations (Na + , H + ) generated in salt water.

본 발명에서는 반복 실험을 통하여 금속 산화제 혼합물로는 Ca+Mg+Al+Zr+Zn 또는 Mg+동(Cu)+황동(P+Cu)를. 무기물 환원제 혼합물로는 TiO2+BaO+Al2O3+MgO2+ZrO2+NiO+K2O+CuO를 사용하는 것이 바람직함을 알 수 있었으며, 정량분석치로는 Ca 0 ~ 20% + Mg 80 ~ 100% + Al 0 ~ 20% + Zr 0 ~ 20% + Zn 0 ~ 20%이거나 Mg 94 ~ 100% + 동(Cu) 0 ~ 6% + 황동(P+Cu) 0 ~ 6%가 효과적이고, Ti, Ba, Al, Mg, Zr, Ni, K, Cu 각각 10 ~ 30%인 것이 바람직하였다.In the present invention, as a metal oxidant mixture through repeated experiments, Ca + Mg + Al + Zr + Zn or Mg + copper (Cu) + brass (P + Cu). It was found that TiO 2 + BaO + Al 2 O 3 + MgO 2 + ZrO 2 + NiO + K 2 O + CuO is preferable as the inorganic reducing agent mixture, and Ca 0-20% + Mg as a quantitative analysis value. 80 to 100% + Al 0 to 20% + Zr 0 to 20% + Zn 0 to 20% or Mg 94 to 100% + Copper 0 to 6% + Brass (P + Cu) 0 to 6% Ti, Ba, Al, Mg, Zr, Ni, K, Cu is preferably 10 to 30%, respectively.

이상에서 설명된 바와 같이 금속산화제 혼합물(Ca + Mg + Al + Zr + Zn 또는 Mg + 동(Cu) + 황동(P+Cu))로 제조된 양극판(플러스(+)극판)과 무기물 환원제 혼합물(TiO2+ BaO + Al2O3+ MgO2+ ZrO2+ NiO + K2O + CuO)로 제조된 음극판(마이너스(-)극판)을 전극으로 사용하고 전해질로서 소금물을 이용함으로써 전해질을 통한 음극판과 양극판의 전기화학반응에 의하여 전기를 생산할 뿐만 아니라 부수적으로 수소가스를 얻음으로서 라디오, 텔레비젼 등의 전원용, 일반 조명용, 다용도의 비상용, 이동이 필요한 곳에서의 사용 등으로 광범위하게 사용될 수 있어 섬 지방 소형 어선에 특히 적합한 전기 생산 방법으로 효과적이었다.As described above, a positive electrode plate (plus (+) electrode plate) made of a metal oxidant mixture (Ca + Mg + Al + Zr + Zn or Mg + copper (Cu) + brass (P + Cu)) and an inorganic reducing agent mixture ( Cathode plate through electrolyte by using negative electrode plate (minus plate) made of TiO 2 + BaO + Al 2 O 3 + MgO 2 + ZrO 2 + NiO + K 2 O + CuO as electrode and using brine as electrolyte As well as producing electricity by the electrochemical reaction of the anode plate and the anode plate, by acquiring hydrogen gas incidentally, it can be widely used for power supply such as radio and TV, general lighting, multi-purpose emergency use, and where it is necessary to move. It was an effective way of producing electricity, especially for small fishing boats.

또한, 전기를 발생시키지 않을 경우에는 전해질(소금물)을 비운상태에서는 장기간 보관이 가능하고, 환경오염물질도 발생되지 않는 효과가 있다.In addition, when no electricity is generated, the electrolyte (salt) can be stored for a long time in an empty state, and environmental pollutants are not generated.

Claims (1)

금속산화제 혼합물(Ca + Mg + Al + Zr + Zn 또는 Mg + 동(Cu) + 황동(P+Cu))로 제조된 양극판과 무기물 환원제 혼합물(TiO2+ BaO + Al2O3+ MgO2+ ZrO2+ NiO + K2O + CuO)로 제조된 음극판을 전극으로 사용하고 전해질로서 소금물을 이용함을 특징으로 하는 소금물을 이용한 전기 생산 방법.A positive electrode plate made of a metal oxidant mixture (Ca + Mg + Al + Zr + Zn or Mg + copper (Cu) + brass (P + Cu)) and an inorganic reducing agent mixture (TiO 2 + BaO + Al 2 O 3 + MgO 2 + ZrO 2 + NiO + K 2 O + CuO) using a negative electrode plate as an electrode and using brine as an electrolytic production method using brine, characterized in that.
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