KR20030059030A - The method of production the electricity with use the salt-water and sea-water - Google Patents

The method of production the electricity with use the salt-water and sea-water Download PDF

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KR20030059030A
KR20030059030A KR1020030038454A KR20030038454A KR20030059030A KR 20030059030 A KR20030059030 A KR 20030059030A KR 1020030038454 A KR1020030038454 A KR 1020030038454A KR 20030038454 A KR20030038454 A KR 20030038454A KR 20030059030 A KR20030059030 A KR 20030059030A
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Prior art keywords
water
electricity
chemical reaction
salt
positive
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KR1020030038454A
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Korean (ko)
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정병윤
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주식회사 메이플윈
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Priority to KR1020030038454A priority Critical patent/KR20030059030A/en
Publication of KR20030059030A publication Critical patent/KR20030059030A/en
Priority to KR1020040040204A priority patent/KR20040107365A/en

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
    • H01M4/8652—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites as mixture
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
    • C25B11/069—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of at least one single element and at least one compound; consisting of two or more compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B5/00—Electrogenerative processes, i.e. processes for producing compounds in which electricity is generated simultaneously
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/133—Renewable energy sources, e.g. sunlight

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Hybrid Cells (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

PURPOSE: A method for producing electricity by putting electrolyte, that is, salt water(sea water) into positive plate consisted of metal compounds only and negative plate consisted of inorganic compounds only, thereby generating chemical reaction without charging of electricity or solar energy or using lead storage battery or battery. CONSTITUTION: The method comprises the processes of connecting a power terminal to a negative plate(4) that is reductant compound and a positive plate(3) that is oxidizer compound; mixing water and salt to a certain mixing ratio in an electrolyte container(2), or pouring sea water into the electrolyte container(2); and causing chemical reaction between salt water or sea water with the positive plate(3) to produce positive ions, and causing chemical reaction between salt water or sea water with the negative plate(4) to produce negative ions, wherein required electricity is obtained at power supply part(1), hydrogen gas generated by chemical reaction is emitted through gas exhaust nozzle formed on the upper part of electrolyte container cover(5), the oxidizer positive plate is consisted of metallic compound (Ca+Mg+Al+Zr+Zn or Mg+copper(Cu)+brass(P+Cu)), the negative plate is consisted of inorganic reductant mixture (TiO2+BaO+Al2O3+MgO2+ZrO2+NiO+K2O+CuO), and power capacity is varied depending on size of the positive and negative plates(3,4) and amount and concentration of salt water that is electrolyte.

Description

소금물(바닷물)을 사용하여 전기를 생산하는 방법{The method of production the electricity with use the salt-water and sea-water}The method of production the electricity with use the salt-water and sea-water}

본 발명은 전기 또는 Solar의 충전 , 납 축전지, 건전지사용 방법에 의하지 않고 단지 금속 화합물로 구성된 플러스극판 과 무기물 화합물로 구성된 마이너스극판에 전해질인 소금물(바닷물)을 넣어 화학반응을 일으켜 전기를 생성하는 방법인 것이다.The present invention does not depend on the method of charging electricity, solar battery, battery, or the use of electricity, but it is a method of generating electricity by adding a salt water (sea water) as an electrolyte to a positive electrode plate composed of only a metal compound and a negative electrode plate composed of an inorganic compound to generate a chemical reaction. It is

종래에는 물론 현재에 이르기까지 국내에서는 이러한 방법을 이용하여 전기를 생성하는 제품(기기)이 출시되어 오지 못하였으며, 또한 이 분야에 대한 연구실적도 전무한 상태에 놓여있다.Conventionally, up to now, domestically produced products (devices) using this method have not been released, and there is no research in this field.

본 발명은 대체에너지 및 친 환경제품, 비상용 전원의 일환으로 획기적으로 실용화시킬 수 있는 방법을 제시하고자 한다.The present invention is to propose a method that can be practically applied as a part of alternative energy, environmentally friendly products, emergency power.

전해질을 수용할 수 있는 용기로서의 기능성 구조 및 무기 화합물로 구성된 마이너스(-)극판과 물리적 화학반응이 일어날 수 있는 플러스(+)극판을 필연적 구성 요소에 장치되도록 하여 목적한 바의 전기를 순조롭게 생산해 낼 수 있는 장치 구성을 제공하고자 한다.A negative electrode plate composed of a functional structure and an inorganic compound as a container that can accommodate an electrolyte, and a positive electrode plate capable of causing a physical chemical reaction are installed on the necessary components to smoothly produce the desired electricity. To provide a device configuration that can be.

본 발명은 플러스(+)극판 및 마이너스(-)극판에 관한 화학적 혼합물에 대한 세부 비율의 설명은 축소되며 다만 혼합물의 구성요소 와 전해질 용기의 기능 및 구성장치에 관한 범위 내에서 본 발명에 대하여 설명 하고자 한다.The present invention is reduced in the description of the specific ratio of the chemical mixture with respect to the positive (+) plate and the negative (-) plate, but the present invention is described within the scope of the components of the mixture and the function and device of the electrolyte container. I would like to.

[도1]은 각 부분별 구성에 대한 도면1 is a diagram for the configuration of each part

[도2]는 전기를 생산하는 전체 구성에 대한 도면2 is a diagram of the overall configuration of producing electricity

도면의 부문별 명칭Departmental Names in Drawings

1. 전원부 2. 전해질 용기. 3. 플러스극판1. Power supply section 2. Electrolyte container. 3. Plus plate

4. 마이너스극판 5. 전해질용기 덮개4. Negative electrode plate 5. Electrolytic container cover

이하 첨부된 도면에 의해 상세히 설명하면 다음과 같다.Hereinafter, described in detail by the accompanying drawings as follows.

도 2는 환원제 화합물인 마이너스 극판과 산화제 화합물인 플러스 극판에 전원 단자를 연결하고, 7의 전해질 용기 속에 일정비율의 물과 소금을 혼합하거나, 바닷물을 넣는다.Figure 2 is connected to the power terminal to the negative electrode plate of the reducing compound and the positive electrode plate of the oxidant compound, mixed a certain proportion of water and salt in the electrolyte container of 7, or put the seawater.

이러한 상태에서 소금물(바닷물)은 3의 플러스극과 화학반응을 일으켜 플러스 이온을 발생시키고, 4의 마이너스극과 화학반응을 일으켜 마이너스 이온을 발생시키게 된다.In this state, salt water (sea water) generates a chemical reaction with a positive electrode of 3 to generate positive ions and a chemical reaction with a negative electrode of 4 to generate negative ions.

이때 1의 전원부에서는 필요한 전기를 얻을 수 있게 되고, 화학반응에 의해 발생되는 수소가스는 5의 덮게 상단부에 표시된 가스분출구로 분출되게 된다.At this time, the power supply unit of 1 can obtain the required electricity, and the hydrogen gas generated by the chemical reaction is ejected to the gas outlet shown in the upper end of the cover.

전력의 용량은 플러스극판과 마이너스극판의 크기와 전해질인 소금물의 량과 농도에 따라 달라지게 되며, 이들 양쪽 극을 서로 같은 극끼리 병렬로 연결하면 1개의 극판에서 얻을 수 있는 전기를 연결한 극의 수만큼의 전기를 생산할 수 있다.The capacity of the power depends on the size of the positive and negative plates and the amount and concentration of the salt water, which is the electrolyte.If the poles are connected in parallel with each other in parallel, It can produce as much electricity.

그리고, 금속화합물로 된 플러스극판은 전자 소멸 전극(electron sink electrode)으로서 한정된 시간이 지나게 되면 교체를 하여야 하며, 마이너스극판도 한정된 시간은 있으나 통상 플러스극판의 수명보다 약30배정도 길다.In addition, the positive electrode plate made of a metal compound is an electron sink electrode and needs to be replaced after a limited time. The negative electrode plate also has a limited time, but is generally about 30 times longer than the life of the positive electrode plate.

좀더 마이너스극판과 플러스극판에 대한 혼합물질을 간단하게 설명하면, 금속 산화제 혼합물(Ca+Mg+Al+Zr+Zn 또는 Mg+동(Cu)+황동(P+Cu))인 플러스극판(+)과 무기물 환원제 혼합물(TiO2+BaO+Al2O3+Mgo2+ZrO2+NiO+K2O+CuO)인 마이너스극판(-) 으로 구성되어 있으며 출력(W) 및 전압(V), 전류(A'h)의 세기는 마이너스극판의 면적단위 구성과 플러스극판의 화합 조성물 비율에 따라 전기적 에너지 공급 효율성을 높일 수 있게 된다.To further explain the mixture of negative and positive plates, the positive electrode plate (+), which is a metal oxidant mixture (Ca + Mg + Al + Zr + Zn or Mg + copper (Cu) + brass (P + Cu)), Consists of negative electrode plate (-), which is an inorganic reducing agent mixture (TiO 2 + BaO + Al 2 O 3 + Mgo 2 + ZrO 2 + NiO + K 2 O + CuO), and has the output (W), voltage (V), and current ( The intensity of A'h) can increase the electrical energy supply efficiency according to the area unit configuration of the negative electrode plate and the ratio of the compound composition of the positive electrode plate.

이상에서 설명된 바와 같이 소금물(바닷물)을 사용한 전기 생산 장치는 일반적으로 사용되고 있는 납 축전지, 전기 및 Solar충전에 의한 축전지와는 달리 소금물(바닷물) 전해질을 이용한 화학반응만으로 전력을 얻게 됨은 물론, 별도의 충전 시간과 장치가 필요 없이 이와 같은 장치만으로 전기를 바로 얻을 수 있으므로 비상시나 전기 공급이 어려운 섬 지방, 소형어선 등 우리 생활에 다양하게 적용할 수 있다.As described above, the electricity producing device using the salt water (sea water) is different from the lead-acid battery, the electricity and solar charging battery, which is generally used, the power is obtained only by the chemical reaction using the salt water (sea water) electrolyte, Electricity can be directly obtained with such a device without the need for charging time and equipment. Therefore, it can be applied in various ways to our lives, such as islands and small fishing boats, which are difficult to supply electricity in case of emergency.

또한 장치를 사용하지 않을 경우에는 전해질(소금물)을 비운상태에서는 장기간 보관이 가능하고, 환경오염물질도 발생되지 않으므로 전력이 부족한 현실에서는 다양한 분야에 적용 가능하리라 본다.In addition, when the device is not used, it can be stored for a long time when the electrolyte (salt water) is empty and no environmental pollutants are generated.

Claims (3)

금속화합물(Ca+Mg+Al+Zr+Zn 또는 Mg+동(Cu)+황동(P+Cu))로 구성된 산화제 플러스극판 제조방법.A method for producing an oxidant plus electrode plate composed of a metal compound (Ca + Mg + Al + Zr + Zn or Mg + copper (Cu) + brass (P + Cu)). 무기물 환원제 혼합물Inorganic reducing agent mixture (TiO2+BaO+Al2O3+Mgo2+ZrO2+NiO+K2O+CuO)로 구성된 마이너스극판 제조방법.Method for manufacturing a negative electrode plate consisting of (TiO 2 + BaO + Al 2 O 3 + Mgo 2 + ZrO 2 + NiO + K 2 O + CuO). 청구항 1의 플러스극판과 청구항 2의 마이너스극판에 전해질인 소금과 물의 혼합물(소금물) 또는 바닷물을 사용하여 서로 화학반응을 일으켜 전기 및 수소가스를 생산하는 방법.A method of producing electricity and hydrogen gas by chemically reacting each other using a mixture of salt and water (salt water) or seawater as electrolytes in a positive electrode plate of claim 1 and a negative electrode plate of claim 2.
KR1020030038454A 2003-06-13 2003-06-13 The method of production the electricity with use the salt-water and sea-water KR20030059030A (en)

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KR1020040040204A KR20040107365A (en) 2003-06-13 2004-06-03 The generation method of electricity utilizing the salt water

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR200450448Y1 (en) * 2007-02-16 2010-10-04 샤먼 이노베이션 메탈 프로덕츠 코., 엘티디. Top support mechanism for tent
US8268139B2 (en) 2008-04-30 2012-09-18 Hyundai Motor Company Hydrogen generation apparatus
WO2013017901A1 (en) 2011-08-02 2013-02-07 Imk Greenpower Kft. System and method for producing electrical energy

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR200450448Y1 (en) * 2007-02-16 2010-10-04 샤먼 이노베이션 메탈 프로덕츠 코., 엘티디. Top support mechanism for tent
US8268139B2 (en) 2008-04-30 2012-09-18 Hyundai Motor Company Hydrogen generation apparatus
WO2013017901A1 (en) 2011-08-02 2013-02-07 Imk Greenpower Kft. System and method for producing electrical energy

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