KR20040024268A - Hair Care Composition Containing Pseudo-Multi Emulsion Drop and Method for Manufacturing the Same - Google Patents

Abstract

PURPOSE: Provided is a hair care composition which contains pseudo multi emulsion drops, and simultaneously performs the cleaning and the styling functions with excellent conditioning effect. CONSTITUTION: The hair care composition comprises pseudo multi emulsion drops where hair styling polymers are contained in the circular drops of organic silicon and variants thereof or synthetic polymer. The circular drop has a size of 2-100 micrometers. The organic silicon and the variants thereof are selected from the group consisting of polydimethylsiloxanes, phenyl siloxanes, alkyl methyl siloxanes, dimethicone copolyols, trimethyl amodimethicones, and a mixture thereof. The synthetic polymer is selected from the group consisting of hydrogenated polydecene, hydrogenated C6-14 olefin polymer, polydecene, pentaerythrityl adipate/carprate/caprylate/heptanoate, and mixtures thereof. The hair styling polymer is selected from the group consisting of anionic polymers such as methacryloylethyl betaine/methacrylate polymer, cationic polymers such as polyquaternium-16, and mixtures thereof.

Description

Hair Care Composition Containing Similar Multi-emulsion Particles And Manufacturing Method Thereof {Hair Care Composition Containing Pseudo-Multi Emulsion Drop and Method for Manufacturing the Same}

The present invention relates to a hair care composition containing pseudo-emulsion particles and a method for manufacturing the same, and more particularly, to prepare a circular silicone particle (Drop) containing a styling polymer in the form of small particles therein, and the conventional shampoo Or it relates to a haircare composition containing a similar multi-emulsion particles that can provide styling and conditioning functions to the hair at the same time by adding to the haircare composition and a method for producing the same.

Hair cosmetics, which are used to remove contamination of hair and scalp and keep them clean and beautiful, are used for various purposes such as styling, hair trimming, hair conditioning, damage prevention, dandruff prevention, and hair protection in addition to cleaning functions. However, recently, methods for obtaining the functions of washing and styling conditioning at the same time by an easy method have been steadily researched, and several related companies have recently applied for a number of patents related to styling shampoos having a washing function and a styling function at the same time.

There are two main ways to create and maintain styles. First, it is semi-permanent by changing the binding position of the hair in a chemical method commonly called 'perm'. Secondly, it is in the form of a temporary change in a way by physical change, which can be removed by water or sampu. Temporary style changes are generally made by applying the styling product to the hair after using the shampoo. Raw materials used to provide style retention have generally been applied in the form of gels, mousses and sprays with resins or gums. However, these styling products present several disadvantages to the user. First, it is cumbersome to apply styling products separately after using shampoo. Secondly, since the hands are used to apply the styling product to the hair, there is a hassle to wash the hands after applying to the hair. Third, the hair tends to be stiff and stiff after application of the styling product.

Recently, Procter & Gamble uses styling polymers while simultaneously using cationic materials of US patent US6248317, organic oil of US patent US6248315, solid particles of US patent US6177390, Patents related to enhancing the styling effect by enhancing the hair deposition of the styling polymer by simultaneously containing the crystalline hydroxy (Stabilizing Agent) containing the stabilizer of US Pat. There is a limit to the amount of polymer and silicon, and it is difficult to balance the styling effect and the conditioning effect due to the increased adsorption of the strong component among these two components.

Thus, no hair care composition has been developed to provide hair styling and conditioning at the same time.

Accordingly, the present invention is provided to more efficiently solve the problems of the prior art as described above,

It is an object of the present invention to provide a haircare composition comprising similar multi-emulsion particles having a multi-emulsion form by including a hair styling polymer component in the circular particles of organic silicon and their modified or synthetic polymers.

Another object of the present invention comprises (1) preparing a circular emulsion particle and (2) mixing the haircare composition with the circular emulsion particle, wherein the haircare contains pseudo multi-emulsion particles. It is to provide a method for preparing the composition.

1 is a photograph showing pseudo-multiple emulsion particles prepared by Example 4 of the present invention (x400).

In order to achieve the above object, the hair care composition containing the pseudo-multiple emulsion particles according to the present invention includes the hair styling polymer component in the circular particles of organic silicone and its modified or synthetic polymers to include particles in the form of a multi-emulsion. Is done.

The circular particles have a size of at least 2㎛ 100㎛.

The organosilicon and its modifications are polydimethylsiloxanes (dimethicone), phenyl siloxanes (Phenyl Siloxanes), alkyl methyl siloxanes (Alkyl Methyl Siloxanes), dimethicone polycopolyols It is selected from the group consisting of silicone variants collectively called Dimethicone Copolyols, Trimethyl Amodimethicones, Amodimethicones, and mixtures thereof.

The synthetic polymer may be hydrogenated polydecene, hydrogenated carbon 6-14 olefin polymer (Hydrogenated C 6-14 Olefin Polymer), polydecene, pentaerytyl adipet / Caprate / caprylate / heptanoate (Pentaerythrityl adipate / carprate / caprylate / heptanoate) and mixtures thereof.

The hair styling polymer is methacryloylethyl Betaine / Methacrylate Copolymer, Octylacrylamide / Acrylate / Butylaminoethyl Methacrylate Copolymer (Octylacrylamide / Acrylates / Butylaminoethyl Methacrylate) Amphoteric styling polymers such as Copolymer or Polyvinylpyrrolidone, PVP / VA Copolymer, PVP / Dimethylaminoethylmethacrylate Copolymer (PVP / Dimethylaminoethylmethacrylate Copolymer) Nonionic styling polymers such as) and PVM / MA copolymers, ethyl or butyl esters of FMB / MA copolymers, and acrylates. Acrylate Methacrylate Copolymer, V / Crotonate / Vinyl Neodecanoate Copolymer (VA / Crotonates) Anionic styling polymers such as / Vinyl Neodecanoate Copolymer, Dimethicone / Acrylate Copolymer, and Polyquaternium-11, Polyquaternium-16, Polyquater Cationic styling polymers such as Polyquaternium-44, Polyquaternium-46, or mixtures thereof.

The haircare composition according to the invention is applied to any one of a shampoo, rinse, treatment or lotion.

The organosilicon and variants thereof are chosen to have a viscosity of 300,000cs at 25 ° C and over 350cs.

The synthetic polymer is selected to have a viscosity of 150 cPs to 150,000 cPs at 20 ° C.

In the method for producing a haircare composition containing pseudo-multiple emulsion particles according to the present invention, (1) mixing the hair styling polymer with organic silicone and its modified or synthetic polymer, condensation of the mixture by physical stirring Preparing a circular emulsion particle which comprises a step of forming silicon particles by stirring with water containing water and a hydrophilic nonionic surfactant; And (2) mixing the haircare composition with the circular emulsion particles in an amount of 0.01% to 20% by weight of the pseudomultiple emulsion particles with respect to the total weight of the haircare composition. Method for producing a hair care composition containing.

The hair styling polymer and the organic silicon and its modified or synthetic polymers have a weight ratio of the hair styling polymer and the organic silicon and their modified or the synthetic polymer in a ratio of 0.01: 99.99 to 50: 50.

Hereinafter, the present invention will be described in detail.

Haircare compositions containing pseudomultiple emulsion particles according to the present invention are prepared by containing pseudomultiple emulsion particles in conventional shampoos or haircare compositions. Pseudo-multi-emulsion particles are composed of a polymer having a styling effect and a silicone or a synthetic polymer having a conditioning effect, and they are first agitated with a strong physical stirring force of 500 rpm to 1500 rpm, and the styling polymer forms a circular small particle on an amorphous silicon continuous phase. After making it form, circular silicon particles (Drop) containing styling polymer in the form of small particles by adding water containing hydrophilic nonionic surfactant at 0.1% to 90% by weight and stirring at 300rpm. The obtained particles were defined as Pseudo Multi Emulsion Drop in the present invention. This particle has both conditioning and styling effects simultaneously, so it can show both hair styling and conditioning effects with excellent styling retention, and when producing styling shampoos using water-soluble styling polymers, In the case of manufacturing by simply dissolving in the components of the shampoo, due to the water solubility of the styling polymer, almost all of the styling polymer after washing is washed away from the hair, so that the amount of the styling polymer that is substantially adsorbed to the hair is very low. While it is difficult to anticipate the styling effect, in the case of the application of pseudo-multi-emulsion particles, the amount of the styling polymer adsorbed to the hair after washing may be due to the presence of the styling polymer in the water-insoluble silicone or the synthetic polymer. As you can increase, the styling effect can also be increased significantly.

The polymer used in the present invention is methacryloylethyl Betaine / methacrylate copolymer (Methacryloylethyl Betaine / Methacrylate Copolymer), octyl acrylamide / acrylate / butylaminoethyl methacrylate copolymer (Octylacrylamide / Acrylates / Amphoteric styling polymers such as Butylaminoethyl Methacrylate Copolymer, or Polyvinylpyrrolidone, PVP / VA Copolymer, PVP / Dimethylaminoethylmethacrylate Copolymer (PVP / Nonionic styling polymers such as dimethylaminoethylmethacrylate Copolymer and PVM / MA Copolymer, Ethyl or Butyl ester of PVM / MA Copolymer, Acrylate Methacrylate Copolymer, V / Crotonate / Vinyl Neodecanoate Copolymer (VA / C anionic styling polymers such as rotonates / Vinyl Neodecanoate Copolymer, Dimethicone / Acrylate Copolymer, and Polyquaternium-11, Polyquaternium-16, Poly A variety of styling polymers known as styling ingredients that have the effect of fixing the hair, such as cationic styling polymers such as Quaternium-44 and Polyquaternium-46, Styling polymers dissolved in the same hydrophilic solvent in a weight ratio of at least 2:98 to 98: 2 may be used alone or in combination. In this case, when a mixture of cationic polymer and anionic polymer is used, a complex related to ionicity may be formed depending on the content ratio between the two ionic polymers and the combination ratio of surfactants. In combination, it should be used in a small amount of less than 5% by weight in the proportion of the cationic or anionic polymer.

In addition, as a medium for stably maintaining these styling polymers in a disperse phase in pseudo-multi-emulsion particles and acting as a continuous phase in the system, the viscosity at 25 ° C. is 300,000 or more at 350 cs (molecular weight of about 14,000 or more and Dow Corning's glass capillary viscosity measurement). Hereinafter, preferably, hydrogen having a viscosity of 150 cPs or more and 150,000 cPs (test method: ASTM D445) at 20 ° C. is preferably organic silicone having a viscosity of 10,000 cs to 80,000 cs, more preferably 30,000 cs to 50,000 cs, or a variant thereof or 20 ° C. Hydrogenated Polydecene, Hydrogenated Carbon 6-14 Olefin Polymer, Polydecene, Pentaerytyl Adipite / Caprate / Caprylate Synthetic polymers such as pentaerythrityl adipate, carprate, caprylate and heptanoate may be used alone or in combination, and may be combined with these silicones. It is already known that sex polymers provide conditioning effects to hair.

Herein, the organosilicon resin and its variants have the structure shown in the following formula (1).

Wherein n is an integer from about 10 to 8000

Polydimethylsiloxanes, collectively called Dimethicone, and their variants, phenyl siloxanes, Alkyl Methyl Siloxanes, Dimethicone Copolyols, and trimethylsilyl Silicone modifications, collectively known as trimethyl amodimethicones and amodimethicones, may be used alone or in combination. In addition, when the viscosity of the silicone or silicone derivative is 300,000 or more and the viscosity of the synthetic polymer such as Hydrogenated Polydecene is 300,000 or more, cyclome is solved to solve the problem caused by high viscosity in the preparation of pseudo-multiple emulsion particles. Cyclo Methicones, low viscosity Dimethicones with molecular weight less than 350 cs or low viscosity Hydrogenated Polydecenes: Puresyn 2, Puresyn 4, Puresyn 6, Puresyn 8, from Mobil Chemical Commercialized under the brand name Puresyn 10) can be used by adjusting and mixing to 30,000cs to 50,000cs viscosity. In this case, or when using low-viscosity silicone or synthetic polymer alone, if the viscosity is lower than 350cs or less, the styling polymer is easily eluted from the pseudo-multi-emulsion particles, resulting in a problem of inability to obtain a desired effect due to poor stability. do.

Preparation of pseudo-multi-emulsion particles is performed by mixing the styling polymer and the silicones acting like a continuous phase or the above-mentioned synthetic polymer in a weight ratio of 0.01: 99.99 to 50:50, depending on the position and type of the stirring blade, but usually 500 rpm It can be prepared by stirring in accordance with the general method as strongly as 1500rpm (Fig. 1).

The nonionic surfactants used to maintain the prepared multi-emulsion emulsion more stably and form a perfect form are polyoxyethylene alkylphenyl ethers, polyoxyethylene octylphenol ethers. 0.1 weight% to nonionic surfactant generally used in manufacture of cosmetics, such as polyoxyethylene alkyl ethers, polyoxyethylene glycol fatty acid esters, and the like After dissolving alone or mixed at 15% by weight, water and surfactant dissolved in the prepared multi-emulsion emulsion particles may be prepared by adding 0.1% to 90% by weight of the total amount of the composition and stirring it at about 300 rpm. . The particles thus prepared are contained in the manufacturing process of the shampoo or hair care composition, as a raw material, so that they remain dispersed in the product at least 2 micrometers to 100 micrometers of particles in the product. Products that have both styling and conditioning functions can be obtained, and these similar multi-emulsion particles can be used in hair care products such as shampoos, rinses, treatments, lotions, etc. in an amount of 0.01% to 20% by weight, preferably 0.5% based on the total amount of the composition. It may be used in an amount of 10 wt% to 10 wt%, more preferably 1 wt% to 3 wt%.

First, the styling polymer uses 0.01% to 10% by weight, preferably 0.1% to 5% by weight, more preferably 0.5% to 3% by weight relative to the total amount of the shampoo composition. Silicones or synthetic polymers, which act as continuous phases in the system and have a conditioning effect while maintaining the dispersion of the styling polymer, are used in a mixing ratio of the styling polymer in a weight ratio of 0.01: 99.99 to 50: 50. In addition, in the case of shampoos, anionic and nonionic surfactants are used so that the total amount of the two surfactants is 5% by weight to 50% by weight, and other hair conditioners, pigments, flavors, preservatives, pH adjusters, and viscosity adjusters , Stabilizers, water, etc. can be used in an appropriate amount, and the above raw material components can be used in a hair care product such as rinse, treatment, lotion and the like for a general purpose. At this time, if it is used at 0.01% by weight or less based on the styling polymer, there is little styling effect, and when it is used at 10% by weight or more, there is a problem in the physical properties of the product and the feeling of use such as stickiness after use and also affects the stability of the product. Go crazy.

On the other hand, the surfactant used in the shampoo in the present invention is generally a mixture of anionic surfactants and nonionic surfactants used in the shampoo or can be used alone, the total amount of the selected surfactant as 5% to 50% by weight, preferably Preferably from 10% to 25% by weight.

Wherein the anionic surfactant has a structure of formula (2).

Wherein R is alkyl having 8 to 20 carbon atoms, n is an integer of 0 to 4, and M is selected from sodium, potassium, magnesium, triethanolamine, and ammonium ion.

Representative compounds of Formula 2 include sodium lauryl sulfate, lauryl ammonium sulfate, magnesium lauryl sulfate, triethanolamine lauryl sulfate, sodium polyoxyethylene lauryl sulfate, polyoxyethylene lauryl sulfate, etc. Used for the purpose of cleaning various wastes.

In addition, the nonionic surfactant has a structure of Formulas 3 to 5.

In Formula 3, R1 is alkyl having 8 to 20 carbon atoms, R2, R3 has an alkyl chain having 1 to 3 carbon atoms, and typical examples thereof include lauryldimethylamine oxide, palm oil alkyldimethylamine oxide, and the like. In Formula 4, R 4 CO group is alkoxy having 8 to 20 carbon atoms, n is 0 or 1, and representative examples thereof include lauryl acid diethanolamide, palm oil fatty acid diethanolamide, and palm oil fatty acid monoethanolamide. In Formula 5, R5 is alkyl having 8 to 20 carbon atoms or alkyl phenyl having 8 to 20 carbon atoms, m is an integer of 3 to 50. Representative examples thereof include polyoxyethylene lauryl ether and polyoxyethylene nonylphenyl ether. In the composition of the present invention, one or two or more types of nonionic surfactants of Formulas 3 to 5 may be mixed or used alone, which additionally impart viscosity increase, auxiliary cleaning, solubilizing efficacy, and the like to the composition.

On the other hand, optional components used in the present invention include preservatives, thickeners and viscosity regulators, pH regulators, flavoring agents, dyes, and conditioning agents commonly used in the detergent composition to maintain basic physical properties and quality as the detergent composition. As a preservative, a mixture of methyl paraoxybenzoate, methylchloroisothiazolinone and methyl isothiazolinone (trade name: Kathon CG, manufactured by Rohm & Haas, USA) is used, and hydroxypropylmethyl is used as a thickener and a viscosity modifier. Cellulose, hydroxymethylcellulose, sodium chloride, ammonium chloride, propylene glycol, hexylene glycol are used, citric acid, sodium hydroxide, triethanolamine is used as a pH adjuster, water-soluble tar is used as a dye, and hydro is used as a conditioning agent. Common hair conditioning ingredients such as carbon oil (Hydrocarbon Oil), alkyl or benzyl esters, extracts, proteins and protein variants, chitosan and chitosan derivatives, Fatty Acid, etc. Fragrances may also be used.

Hereinafter, the present invention will be described in detail by way of examples. However, the following examples are merely to illustrate the invention, but the content of the present invention is not limited to the following examples.

[Examples 1-3 and Comparative Examples 1 and 2]

After adding 30% sodium lauryl sulfate, 30% polyoxyethylene lauryl sulfate, palm oil fatty acid diethanolamide to water at the composition ratio as shown in Table 1, warming it to 60 ° C, and stirring for 30 minutes while maintaining the temperature. After stirring and cooling to 45 ° C., isopropyl myristate and hydroxypropyl chitosan were added and stirred until complete dissolution. The mixture was stirred for 30 minutes by adding a pigment, preservative, fragrance and citric acid, and then the styling polymer and dimethicone were added. Comparative Example 1 was prepared. In Comparative Example 2, anionic styling polymer, PVM / MA Copolymer (PVM / MA Copolymer), dimethicone, and polyoxyethylene oleyl ether were prepared as pseudo-emulsion emulsion particles. It was simply added to the composition sequentially without the first, in the case of Examples 1 to 3 first to the fib Am / M anionic styling polymer Using this copolymer (PVM / MA Copolymer), dimethicone and polyoxy ethylene oleyl ether, plural pseudo-emulsion particles were prepared in advance for each content and added to the composition to prepare a shampoo containing an anionic styling polymer.

[Test Example 1]: Style holding force measurement for the shampoo compositions of Examples 1 to 3 and Comparative Examples 1 and 2

The style retention was tested for the Examples and Comparative Examples prepared according to the composition of Table 1 below and the results are shown in Table 2 below.

The evaluation of the style holding power was carried out by immersing a hairpin of 20 cm in length and 0.8 g in a 5% polyoxyethylene lauryl ether solution for 5 minutes, rinsing with running water for 1 minute, and leaving it at 25 ° C. and 50% relative humidity for 24 hours. . Thereafter, the hair stalks were immersed in a 5% solution of the shampoo composition of Table 1 for 5 minutes, rinsed with running water for 1 minute, and left to stand for 30 minutes in a constant temperature and humidity chamber (25 ° C, 50RH%) to remove moisture. Dry the hair squeezed hair in spiral spiral and dry it in a constant temperature and humidity chamber (25 ℃, 30RH%) for 5 hours, and carefully remove the dried hair from the spiral and put it in the constant temperature and humidity chamber (25 ℃, 50RH%). The effect of styling retention was compared by the conventional curl retention method, which compares the degree of curling over time for 3 hours (J. Soc. Cosmetic Chemists. Dec 9 , 1968), the equation used to calculate the Curl Retention (%) is as follows (Equation 1). In this case, the larger the value, the better the retention of style. The results of Table 2 are shown in Table 2 below.

[Calculation 1]

Raw material name Comparative Example 1 Comparative Example 2 Example 1 Example 2 Example 3 Nalauryl sulfate (30%) 20.0 20.0 20.0 20.0 20.0 Sodium polyoxyethylene lauryl sulfate (30%) 20.0 20.0 20.0 20.0 20.0 Palm oil fatty acid diethanolamide 3.0 3.0 3.0 3.0 3.0 Isopropyl myristate 1.0 1.0 1.0 1.0 1.0 Hydroxypropylchitosan 0.5 0.5 0.5 0.5 0.5 Pigment 0.0001 0.0001 0.0001 0.0001 0.0001 antiseptic 0.2 0.2 0.2 0.2 0.2 Spices 0.4 0.4 0.4 0.4 0.4 Citric acid 0.01 0.01 0.01 0.01 0.01 FMB / MA Copolymer - 0.5 0.1 0.5 1.0 Dimececon - 2.0 2.0 2.0 1.0 Polyoxyethylene oleyl ether 0.2 0.2 0.2 0.2 0.2 water 54.6899 52.1899 52.5899 52.1899 52.6899 Comparative Example 2 PVM / MA Copolymer (PVM / MA Copolymer) and Dimethicone Directly Insert Example 2: PVM / MA Copolymer (PVM / MA Copolymer) and Dimethicone Manufactured and put

division Style Retention (Curl Retention%) Comparative Example 1 28 Comparative Example 2 56 Example 1 64 Example 2 72 Example 3 83

[Examples 4 to 6 and Comparative Example 3]

30% sodium lauryl sulfate, 30% polyoxyethylene lalauryl sulfate, and palm oil fatty acid diethanolamide were added to water at a composition ratio as shown in Table 3, followed by warming to 60 ° C., followed by stirring for 30 minutes while maintaining the temperature. After stirring and cooling to 45 ℃ and isopropyl myristate, hydroxypropyl chitosan was added and stirred until completely dissolved, and the mixture was stirred for 30 minutes by adding a dye, preservative, flavor and citric acid, in Comparative Example 3 Polyquaternium-16, dimethicone, and polyoxy ethylene oleyl ether, which were sex styling polymers, were simply added to the composition sequentially without preparing similar multi-emulsion particles. Polyquaternium-16, a styling polymer, dimethicone and polyoxyethylene oleyl ether, Four multi-emulsion particles were prepared previously and added to the composition to prepare a shampoo containing the cationic styling polymer.

Raw material name Comparative Example 3 Example 4 Example 5 Example 6 Sodium Lauryl Sulfate (30%) 20.0 20.0 20.0 20.0 Sodium polyoxyethylene lauryl sulfate (30%) 20.0 20.0 20.0 20.0 Palm oil fatty acid diethanolamide 3.0 3.0 3.0 3.0 Isopropyl myristate 1.0 1.0 1.0 1.0 Hydroxypropylchitosan 0.5 0.5 0.5 0.5 Pigment 0.0001 0.0001 0.0001 0.0001 antiseptic 0.2 0.2 0.2 0.2 Spices 0.4 0.4 0.4 0.4 Citric acid 0.01 0.01 0.01 0.01 Polyquaternium-16 0.5 0.1 0.5 1.0 Dimececon 2.0 2.0 2.0 1.0 Polyoxyethylene oleyl ether 0.2 0.2 0.2 0.2 water 52.1899 52.5899 52.1899 52.6899 Comparative Example 3: Polyquaternium-16 and Dimethicone were directly added Example 5: Polyquaternium-16 and Dimethicone were first added to prepare similar multi-emulsion emulsion particles

[Test Example 2]: The style holding force of the shampoo compositions of Examples 4 to 6 and Comparative Example 3 was measured.

Examples and comparative examples prepared according to the composition of Table 3 was tested for the style retention by the method described in Test Example 1 and the results are shown in Table 4 below.

division Style Retention (Curl Retention%) Comparative Example 3 40 Example 4 45 Example 5 53 Example 6 61

[Examples 7 to 9 and Comparative Example 4]

After adding 30% sodium lauryl sulfate, 30% polyoxyethylene lalauryl sulfate, and palm oil fatty acid diethanolamide to water at a composition ratio as shown in Table 5, the mixture was warmed up to 60 ° C. and stirred for 30 minutes while maintaining the temperature. After stirring and cooling to 45 DEG C, isopropyl myristate and hydroxypropyl chitosan were added and stirred until complete dissolution. The mixture was stirred for 30 minutes by adding a dye, preservative, fragrance, and citric acid. The styling polymer methacryloylethylbetaine / Methacrylate Copolymer and dimethicone and polyoxyethylene oleyl ether were simply added to the composition sequentially without making similar multi-emulsion particles. For Examples 7-9, first, methacryloylethylbetaine / methacryl, an amphoteric styling polymer Sites were prepared copolymers and dimethicone and polyoxyethylene oleyl using ether containing amphoteric styling polymer prior to preparing a similar multi-emulsion particles by introducing the composition for each content shampoo.

Raw material name Comparative Example 4 Example 7 Example 8 Example 9 Sodium Lauryl Sulfate (30%) 20.0 20.0 20.0 20.0 Sodium polyoxyethylene lauryl sulfate (30%) 20.0 20.0 20.0 20.0 Palm oil fatty acid diethanolamide 3.0 3.0 3.0 3.0 Isopropyl myristate 1.0 1.0 1.0 1.0 Hydroxypropylchitosan 0.5 0.5 0.5 0.5 Pigment 0.0001 0.0001 0.0001 0.0001 antiseptic 0.2 0.2 0.2 0.2 Spices 0.4 0.4 0.4 0.4 Citric acid 0.01 0.01 0.01 0.01 Methacryloylethylbetaine / methacrylate copolymer 0.5 0.1 0.5 1.0 Dimececon 2.0 2.0 2.0 1.0 Polyoxyethylene oleyl ether 0.2 0.2 0.2 0.2 water 52.1899 52.5899 52.1899 52.6899 Comparative Example 4 The Methacryloyl Ethylbetaine / methacrylate Copolymer and Dimethicone Directly Inserted Example 8 Similar to the Methacryloyl Ethylbetaine / Methacrylate Copolymer and Dimethicone First Prepare and add multiple emulsion particles

[Test Example 3]: The style holding force of the shampoo composition of Examples 7 to 9 and Comparative Example 4 was measured

Examples and comparative examples prepared according to the composition of Table 5 was tested for the style holding power by the method described in Test Example 1 and the results are shown in Table 6 below.

division Style Retention (Curl Retention%) Comparative Example 4 53 Example 7 60 Example 8 69 Example 9 79

[Examples 10 to 12 and Comparative Example 5]

After adding 30% sodium lauryl sulfate, 30% sodium polyoxyethylene lauryl sulfate, palm oil fatty acid diethanolamide to the composition ratio as shown in Table 7 and warming to 60 ° C., the mixture was stirred for 30 minutes while maintaining the temperature. After stirring and cooling to 45 DEG C, isopropyl myristate and hydroxypropyl chitosan were added and stirred until completely dissolved, and the mixture was stirred for 30 minutes by adding a dye, preservative, flavor and citric acid, and then, in Comparative Example 5, nonionic The styling polymer PVP / VA Copolymer (PVP / VA Copolymer) and dimethicone and polyoxy ethylene oleyl ether were simply added to the composition sequentially without making pseudo multi-emulsion particles, and in Examples 10 to 12. First, PVP / VA Copolymer (non-ionic styling polymer), dimethicone and polyoxyethylene It prepared using the rail ether followed a similar multiple emulsion particle for each content to prepare a shampoo containing an amphoteric styling polymers were charged into a composition.

Raw material name Comparative Example 5 Example 10 Example 11 Example 12 Sodium Lauryl Sulfate (30%) 20.0 20.0 20.0 20.0 Sodium polyoxyethylene lauryl sulfate (30%) 20.0 20.0 20.0 20.0 Palm oil fatty acid diethanolamide 3.0 3.0 3.0 3.0 Isopropyl myristate 1.0 1.0 1.0 1.0 Hydroxypropylchitosan 0.5 0.5 0.5 0.5 Pigment 0.0001 0.0001 0.0001 0.0001 antiseptic 0.2 0.2 0.2 0.2 Spices 0.4 0.4 0.4 0.4 Citric acid 0.01 0.01 0.01 0.01 FV / V Copolymer 0.5 0.1 0.5 1.0 Dimececon 2.0 2.0 2.0 1.0 Polyoxyethylene oleyl ether 0.2 0.2 0.2 0.2 water 52.1899 52.5899 52.1899 52.6899 Comparative Example 5: Directly inserting the VBP / V copolymer and dimethicone Example 11: Firstly preparing similar multi-emulsion emulsion particles with the VBP / V copolymer and dimethicone

[Test Example 4]: Style holding force of the shampoo compositions of Examples 10 to 12 and Comparative Example 5

The Examples and Comparative Examples prepared according to the composition of Table 7 was tested for the style retention by the method described in Test Example 1 and the results are shown in Table 8 below.

division Style Retention (Curl Retention%) Comparative Example 5 43 Example 10 48 Example 11 57 Example 12 65

[Examples 13 to 16 and Comparative Example 6]

30% sodium lauryl sulfate, 30% polyoxyethylene lalauryl sulfate, and palm oil fatty acid diethanolamide were added to water at a composition ratio as shown in Table 9, and then heated to 60 ° C., followed by stirring for 30 minutes while maintaining the temperature. After stirring and cooling to 45 ° C, isopropyl myristate and hydroxypropylchitosan were added and stirred until completely dissolved, and the mixture was stirred for 30 minutes by adding a dye, preservative, fragrance and citric acid, and then Comparative Examples 6 to 9 Is an anionic styling collimer (PVM / MA Copolymer) or a cationic styling polymer (Polyternium-16) or an amphoteric styling polymer (methacryloylethylbetaine / methacrylate). FV / B copolymers, which are copolymers or nonionic styling polymers, and hydrogenated polydecen and polyox Ethylene oleyl ether was simply added to the composition in sequence without making similar multi-emulsion particles, and in Examples 13 to 16, each ionic styling polymer was first reacted with hydrogenated polyde Similar multi-emulsion particles were prepared previously using sane and polyoxy ethylene oleyl ether and added to the composition to prepare a shampoo.

Raw material name Comparative Example 6 Comparative Example 7 Comparative Example 8 Comparative Example 9 Example 13 Example 14 Example 15 Example 16 Sodium Lauryl Sulfate (30%) 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 Sodium polyoxyethylene lauryl sulfate (30%) 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 Palm oil fatty acid diethanolamide 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 Isopropyl myristate 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 Hydroxypropylchitosan 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Pigment 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001 antiseptic 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Spices 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 Citric acid 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 FMB / MA copolymer 0.5 - - - 0.5 - - - Polyquaternium-16 - 0.5 - - - 0.5 - - Methacryloylethylbetaine / methacrylate copolymer - - 0.5 - - - 0.5 - FV / V Copolymer - - - 0.5 - - - 0.5 Hydrogenated Polydecane 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 Polyoxyethylene oleyl ether 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 water 52.1899 52.1899 52.1899 52.1899 52.1899 52.1899 52.1899 52.1899 Comparative Examples 6 to 9: simple addition to the composition sequentially. Example 11 Preparatively prepared pseudomultiple emulsion particles were added to the composition.

[Test Example 5]: The style holding force of the shampoo compositions of Examples 13 to 16 and Comparative Examples 6 to 9 was measured.

Examples and comparative examples prepared according to the composition of Table 9 was tested for the style retention by the method described in Test Example 1 and the results are shown in Table 10 below.

division Style Retention (Curl Retention%) Comparative Example 6 52 Comparative Example 7 38 Comparative Example 8 49 Comparative Example 9 43 Example 13 70 Example 14 51 Example 15 66 Example 16 55

[Test Example 6]: Evaluation of the hair conditioning (softness, smoothness) effect of Examples 1 to 3 and Comparative Examples 1 and 2

Examples 1 to 3 and anionic styling polymer when pre-manufactured pseudo-multiple emulsion particles using FMB / A copolymer and silicone, an anionic styling polymer that showed the greatest styling retention effect, and silicone In the shampoo of Comparative Example 2, in which the VAM / A copolymer and the silicone were immediately added without prior preparation of pseudo multi-emulsion particles, and the VB / A copolymer and the styling polymer, Comparative Example 1, which did not contain silicone. Thirty females were randomly selected as the test subjects, and five of the Comparative Examples 1 to 2 and the Examples 1 to 3 shampoos of Table 1 were allowed to use for two weeks, and then the hair softness and Conditioning effect was evaluated with the emphasis on smoothness, and the results are shown in Table 11.

The evaluation of the hair conditioning effect was averaged after the subject gave a subjective score on the 5-point scale based on the following evaluation criteria.

[Evaluation standard]

division grade Very good conditioning effect 5 Excellent conditioning effect 4 is average 3 Almost no conditioning effect 2 No conditioning effect One

division Comparative Example 1 Comparative Example 2 Example 1 Example 2 Example 3 Conditioning effect 2.2 2.8 3.8 4.0 3.5

As can be seen from the styling retention measurement and the evaluation of the hair conditioning effect for the above examples and comparative examples, the various ionic styling polymers according to the present invention are prepared in advance using pseudo-emulsion particles using silicon (Dimethicone). Example 1 to Example 12 were applied to show excellent hair style retention and conditioning effect compared to Comparative Example 1 does not contain a styling polymer and silicone, and compared the similar multi-emulsion particles directly added without prior preparation Compared with Examples 2 to 5, excellent hair style retention and conditioning effects were shown. In addition, in the case of Examples 13 to 16, which is a case of preparing a shampoo by preparing similar multi-emulsion particles using hydrogenated polydecane instead of silicone, and then adding it to the composition, hair superior to Comparative Example 1 It showed a style holding power and a conditioning effect, and compared to the case of Comparative Examples 6 to 9 directly injected without preparing similar multi-emulsion particles, it showed excellent hair style holding power and conditioning effect. The effect and conditioning effect appeared to be somewhat inferior.

The present invention is a conventional shampoo or rinse, treatment, hair lotion, and the like in the hair care composition such as styling effect with hair styling and conditioning effect with a pre-manufactured styling polymer and silicone or synthetic polymer (pseudo) -Multi Emulsion Drop, which is a composition for hair care, which provides both cleaning and styling functions at once, economical in terms of time, and does not make hair stiff or stiff. In addition, the styling and conditioning effects are also very superior to conventional simple blended preparations.

While the invention has been described in detail above with reference to the described embodiments, it will be apparent to those skilled in the art that various modifications and variations are possible within the scope and spirit of the invention, and such modifications and variations fall within the scope of the appended claims. It is also natural.

Claims (10)

A hair care composition comprising pseudo multi-emulsion particles, characterized in that it comprises a multi-emulsion type particle comprising a hair styling polymer component in a circular particle of organic silicone and its modified or synthetic polymer. The method of claim 1, The circular particles are characterized in that having a size of at least 2 ㎛ to 100 ㎛ Haircare compositions containing pseudo multi-emulsion particles. The method of claim 1, The organosilicon and its modifications are polydimethylsiloxanes (dimethicone), phenyl siloxanes (Phenyl Siloxanes), alkyl methyl siloxanes (Alkyl Methyl Siloxanes), dimethicone polycopolyols Containing pseudo-multi-emulsion particles, characterized in that it is selected from the group consisting of silicone variants collectively referred to as Dimethicone Copolyols, Trimethyl Amodimethicones, Amodimethicones, and mixtures thereof. Hair Care Composition. The method of claim 1, The synthetic polymer is (synthetic polymer-deleted) hydrogenated polydecene (Hydrogenated Polydecene), hydrogenated carbon 6-14 olefin polymer (Hydrogenated C 6-14 Olefin Polymer), polydecene (Polydecene) , Hair containing similar multi-emulsion particles, characterized in that it is selected from the group consisting of pentaerythyl adipate / caprate / caprylate / heptanoate (Pentaerythrityl adipate / carprate / caprylate / heptanoate) and mixtures thereof Care composition. The method of claim 1, The hair styling polymer is methacryloylethyl Betaine / methacrylate copolymer (Methacryloylethyl Betaine / Methacrylate Copolymer), octyl acrylamide / acrylate / butylaminoethyl methacrylate copolymer (Octylacrylamide / Acrylates / Butylaminoethyl Methacrylate Amphoteric styling polymers such as Copolymer or Polyvinylpyrrolidone, PVP / VA Copolymer, PVP / Dimethylaminoethylmethacrylate Copolymer (PVP / Dimethylaminoethylmethacrylate Copolymer) Nonionic styling polymer and PVM / MA Copolymer (PVM / MA Copolymer), Ethyl or Butyl ester of PVM / MA Copolymer, Acrylate Acrylate Methacrylate Copolymer, V / Crotonate / Vinyl Neodecanoate Copolymer (VA / Crotonate) anionic styling polymers such as s / VinylNeodecanoate Copolymer, Dimethicone / Acrylate Copolymer, and Polyquaternium-11, Polyquaternium-16, Polyquater A haircare composition containing pseudo multi-emulsion particles, characterized in that it is selected from the group consisting of cationic styling polymers such as Polyquaternium-44, Polyquaternium-46 or mixtures thereof. The haircare composition of claim 1, wherein the haircare composition comprises shampoos, rinses, treatments or lotions. The method of claim 3, The organosilicon and its variants are hair care compositions containing similar multiple emulsion particles, characterized in that the viscosity is 350cs to 300,000cs at 25 ℃. The method of claim 4, wherein The synthetic polymer is a hair care composition containing multiple emulsion particles, characterized in that the viscosity is 150cPs to 150,000cPs at 20 ℃. In the method for producing a hair care composition containing pseudo multi-emulsion particles, (1) mixing the hair styling polymer with organic silicon and their modified or synthetic polymers, condensing the mixture by physical stirring, and stirring the silicon particles with water containing a hydrophilic nonionic surfactant Preparing a circular emulsion particle consisting of a forming step; And (2) mixing the haircare composition and the circular emulsion particles in an amount of 0.01% to 20% by weight of similar multi-emulsion particles with respect to the total weight of the haircare composition; Method for producing a hair care composition containing similar multi-emulsion particles, characterized in that consisting of. The method of claim 9, The hair styling polymer and the organic silicon and its modified or synthetic polymers have a weight ratio of the hair styling polymer and the organic silicon and their modified or the synthetic polymer to have a mixing ratio of 0.01: 99.99 to 50: 50. A method of making a haircare composition containing multiple emulsion particles.