KR200391920Y1 - Fabricating fiber comprising silver or germanium - Google Patents

Fabricating fiber comprising silver or germanium Download PDF

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Publication number
KR200391920Y1
KR200391920Y1 KR20-1999-0009701U KR19990009701U KR200391920Y1 KR 200391920 Y1 KR200391920 Y1 KR 200391920Y1 KR 19990009701 U KR19990009701 U KR 19990009701U KR 200391920 Y1 KR200391920 Y1 KR 200391920Y1
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germanium
silver
dyeing
particles
fibers
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KR20-1999-0009701U
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Korean (ko)
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KR20010000100U (en
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안정오
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안정오
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/02Processes in which the treating agent is releasably affixed or incorporated into a dispensing means
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/13Physical properties anti-allergenic or anti-bacterial
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/16Physical properties antistatic; conductive

Abstract

본 고안은, 은, 게루마늄 함유 가공 섬유에 관한 것으로서, 섬유가 갖는 피부보호, 온도유지 기능외에 항균력을 갖는 은, 게루마늄 함유 가공 섬유를 얻기 위한 것인바 은, 게루마늄 함유 가공 섬유는 섬유의 침염이나 날염시 CMC(Carboxy methyl cellulose), 가공 보조제, 매염제, 수지가공제, 호제 또는 염색조제를 사용하여 염색시 안료 수용액을 증류수로 사용하여 0.005~1 미크론 크기의 30ppm 이상 은 입자와 50 ppm 이상의 게루마늄 입자를 비금속인 프라스틱 통속에서 교반 착색을 이루게 하고, 고압 열처리로 후처리로 완성케 하는 염색과정에서 은입자, 게루마늄 입자를 고착케 하여 은의 특성으로 항균 작용과 정전기 방지 및 게르마늄의 특성을 살린 뛰어난 효과가 있다.The present invention relates to silver and germanium-containing processed fibers, and to obtain silver and germanium-containing processed fibers having antibacterial activity in addition to skin protection and temperature retention function of the fibers. When dyeing or printing fiber using CMC (Carboxy methyl cellulose), processing aid, mordant, resin processing agent, lubricating agent or dyeing aid, dye solution is used as distilled water. Aggregate silver particles and germanium particles in the dyeing process to make 50% or more of germanium particles in a non-metallic plastic bucket and to be finished by post-treatment by high-pressure heat treatment. And excellent effect utilizing the characteristics of germanium.

Description

은, 게루마늄 함유 가공섬유{Fabricating fiber comprising silver or germanium}Fabrication fiber comprising silver and germanium {Fabricating fiber comprising silver or germanium}

본 고안은 은, 게루마늄 함유 가공 섬유에 관한 것으로서, 더욱 상세하게는 섬유가 갖는 피부보호, 온도유지 기능 외에 항균력을 갖는 은, 게루마늄 함유 가공 섬유에 관한 것이다.The present invention relates to silver and germanium-containing processed fibers, and more particularly, to silver and germanium-containing processed fibers having antibacterial activity in addition to skin protection and temperature retention functions of the fibers.

종래의 섬유에 염색방법에 있어서 폴리아마이드, 폴리에스테르 직물의 염색방법에 관한 선행기술로, 일본 특개소 57-116868호 등에는 말레인산 중합체염을 첨가하여 전처리 공정에서 평할제 처리를 한 후 안료와 포상 조성물로 이루어진 착색제를 처리하여 100~220℃에서 열고정하는 방법으로 무늬를 발현시키는 직물의 염색방법을 개시하고 있다.그러나 이 방법의 문제점으로는 첫째 안료로 탄화수소계 경정유를 사용하여 유화 분산시 분산액내에서 안료의 불균일 분산에 의한 침전현상이 발생하므로 이를 직물에 처리하는 경우에 균일성 및 재현성이 저하되는 단점이 있다. 둘째, 2가지 이상의 색상을 발현하기 위하여 서로 다른 색상의 염료를 균일 분산시킨 후 롤러 또는 스크린 프린팅 효과를 내기 때문에 작업이 복잡하고 준비 공정에 많은 시간이 소요되며, 셋째, 롤러 또는 스크린 제작에 많은 비용이 들고 롤러 또는 스크린의 제작 후에는 다양한 무늬 패턴의 변화를 주기 어려운 단점이 있다.일본특허 제4024292호에는 직물을 포개서 접은 후 여러 부분을 묶어서 염색을 행하여 스톤워시(Stonewash) 효과를 부여할 수 있는 방법이 소개 되어 있다. 그러나 이러한 방법은 첫째 염색후 직물의 접힘이나 구김이 잘 펴지지 않아 직물의 품위를 떨어뜨리고 둘째, 염색준비 공정시간이 많이 소요되어 생산량이 저하되는 등의 문제점이 있다. 또한 셋째로 직물의 얼룩 형태가 매우 불규칙하고 얼룩무늬의 형태나 크기를 조절하기 힘들다는 단점이 있다. 상기한 바와 같은 단점을 극복하기 위한 것으로, 폴리에스테르 또는 폴리아마이드 성분이 포함된 직물을 균일하고 재현성이 좋은 다양한 무늬 패턴을 가지고 평활성이 좋은 직물이 되도록 염색하는 방법을 사용하고 있다. 또한 폴리아마이드, 폴리에스테르가 포함된 직물의 염색에 있어서, 염색 전에 증정제, 염색촉진제, 가교제, 이소프로필알콜이 포함된 처리액으로 처리하여 150~180℃에서 30~90초간 열처리한 후 염색하였다.폴리에스테르, 폴리아마이드가 포함된 직물의 염색에 있어서 정련 후 탈수 건조한 직물에 증정제, 1가 및 2가 아민화합물이 포함된 염색 촉진제, 가교제 및 이소프로필알콜이 포함된 처리액을 스프레이 또는 로울러 프린팅으로서 처리한 후, 150℃~190℃에서 30~90초간 열고정한다. 이어서 PH를 4.0~5.0으로 조정한 용액에 분산염료 산성염료 직접염료 등을 투입하여 적절한 레벨링 시간을 줌으로써 염색을 완료한다. 염색이 끝나면 소핑과 수세를 2회 반복하여 색조의 선명성과 염색 견뢰도를 증진시킨다. 이후 열고정 가공을 하여 농담의 무늬가 고르게 분포된 직물을 제조한다. 증정제로는 소듐알지네이트, CMC(Carboxy methyl cellulose), 로커스트, 콩껌, 게러껌, PVA, 메이프로껌을 사용하여 처리액의 점도를 1000~8000CPS로 조정한다.또한, 일반 섬유는 일반적으로 피부에서 발생하는 땀, 피지 등의 배출물은 속옷에 흡수되는데 이에 세균이 발생하여 위생상 좋지 못하고 세균이 서식하는 과정에서 악취를 내뿜게 된다. 또한, 섬유재질과 상태에 염색하는 방법를 달리하여 따라 침적, 날염 염색으로 섬유에 색상을 주도록 했다.이러한 문제점을 해결하기 위한 본 고안은 섬유가 갖는 피부보호, 온도유지 기능외에 항균력을 갖는 은, 게루마늄 함유 가공 섬유를 제공하는데 있다.As a prior art relating to the method of dyeing polyamide and polyester fabrics in conventional textile dyeing methods, Japanese Patent Application Laid-Open No. 57-116868, etc., adds maleic acid polymer salts and then performs a flattening treatment in a pretreatment step to form pigments and foams. Disclosed is a method of dyeing a fabric that expresses a pattern by treating a colorant composed of a composition and heat-setting at 100 to 220 ° C. However, a problem with this method is that a dispersion liquid when emulsified and dispersed using a hydrocarbon light oil as a first pigment. Precipitation phenomenon due to non-uniform dispersion of pigments in the inside has a disadvantage in that uniformity and reproducibility are lowered when the fabric is treated. Second, since the dyes of different colors are uniformly dispersed in order to express two or more colors, and the roller or screen printing effect is produced, the work is complicated and the preparation process takes a lot of time. After the fabrication of the holding roller or screen, there is a disadvantage that it is difficult to change various pattern patterns. Japanese Patent No. 4024292 folds fabrics, folds them, binds them together, and dyes them to give a Stonewash effect. The method is introduced. However, this method has a problem such that the folding or wrinkle of the fabric is not spread well after the first dyeing to reduce the quality of the fabric and secondly, the production time is reduced due to a lot of dye preparation process. Third, there is a disadvantage that the irregular shape of the fabric is very irregular and it is difficult to control the shape or size of the uneven pattern. In order to overcome the drawbacks described above, a method of dyeing a fabric containing a polyester or polyamide component is made to have a smooth smooth fabric with various pattern patterns having good uniformity and reproducibility. In addition, in the dyeing of the fabric containing polyamide, polyester, before treatment, the treatment solution containing a presenting agent, a dyeing accelerator, a crosslinking agent, and isopropyl alcohol was heat treated at 150 to 180 ° C. for 30 to 90 seconds, and then dyed. In dyeing fabrics containing polyesters and polyamides, spray or rollers are treated with dehydrating and drying fabrics containing dyeing accelerators, crosslinking agents, and isopropyl alcohols. After treating as printing, heat setting is performed at 150 ° C to 190 ° C for 30 to 90 seconds. Subsequently, the dye is prepared by dispersing acidic dyes, direct dyes, etc. into a solution having a pH of 4.0 to 5.0, and giving an appropriate leveling time. After dyeing, repeat soaping and washing twice to increase the color clarity and color fastness. After the heat-setting process to produce a fabric with evenly distributed pattern of shades. As a presenting agent, sodium alginate, CMC (Carboxy methyl cellulose), locust, soy gum, guerrilla gum, PVA, maypro gum are used to adjust the viscosity of the treatment solution to 1000-8000 CPS. Emissions such as sweat and sebum are absorbed into the underwear, and bacteria are generated, which is not good for hygiene and emits odors during the incubation of bacteria. In addition, by different methods of dyeing on the fiber material and condition, the color is given to the fiber by deposition and printing dyeing. It is to provide a chromium-containing processed fiber.

이러한 본 고안의 은, 게루마늄 함유 가공 섬유는 섬유의 침엽이나 날염시 CMC(Carboxy methyl cellulose)를 포함하는 가공 보조제, 매염제, 수지가공제, 호제, 염색조제를 사용하여 염색시 안료 수용액을 증류수로 사용하여 0.005~1 미크론 크기의 30ppm 이상 은 입자와 50ppm 이상의 게루마늄 입자를 비금속인 프라스틱 통속에서 교반 착색을 이루게 하고, 고압 열처리로 후처리로 완성케 하는 염색과정에서 은입자, 게루마늄 입자를 고착케 하여 달성하였다.The silver and germanium-containing processed fiber of the present invention is distilled water from the aqueous pigment solution at the time of dyeing using a processing aid, a mordant, a resin processing agent, a coating agent, a dyeing aid containing CMC (Carboxy methyl cellulose) when the fiber is coniferous or printed. Silver particles and germanium in the dyeing process of 30ppm or more silver particles and 50ppm or more germanium particles of 0.005 ~ 1 micron size in a non-metallic plastic barrel are stirred and colored by a high pressure heat treatment. Achieved by sticking the particles.

삭제delete

이하, 본 고안의 은, 게루마늄 함유 가공 섬유를 도면을 참조하여 상세히 설명한다. 도 1과 도 2에 도시한 바와 같이 본 고안의 섬유의 침염이나 날염시 CMC(Carboxy methyl cellulosc)를 포함하는 가공 보조제, 매염제, 수지가공제, 호제, 염색조제를 사용하여 염색시 안료 수용액을 증류수로 사용하여 0.005~1 미크론 크기의 30ppm 이상 은 입자와 50ppm이상의 게루마늄 입자를 비금속인 프라스틱 통속에서 교반 착색을 이루게 하고, 고압 열처리로 후처리로 완성케 하는 염색과정에서 섬유(1.1' )에 은입자(2,2' )와 게루마늄입자(3,3' )를 고착케 하는 것으로 이루어지게 한 특징이 있다.Hereinafter, the silver and germanium containing processed fiber of this invention are demonstrated in detail with reference to drawings. As shown in FIGS. 1 and 2, the dye aqueous solution is distilled when dyeing using a processing aid, a mordant, a resin processing agent, a coating agent, a dyeing aid, including CMC (Carboxy methyl cellulosc) when the fiber is infiltrated or printed. 30ppm or more silver particles and 50ppm or more germanium particles with a size of 0.005 ~ 1 micron are agitated and colored in non-metallic plastic barrels, and the fibers (1.1 ') are dyed in the dyeing process. The silver particles (2, 2 ') and the germanium particles (3, 3') is characterized by being made to adhere.

은이나 게루마늄 무기물은 섬유자체에 잘 고착되지 않았다. 이런 점을 매염제나 염색조제와 0.005~1 미크론 크기의 은이나 게루마늄 입자를 섞게 하여 침적이나 날염을 한 후 고압의 열처리를 하는 과정에서 사용되는 물을 증류수 또는 정제수를 사용하고 섬유착색용기를 비금속 프라스틱재질 등을 사용하도록 하여 염색하였다.Silver and germanium minerals did not adhere well to the fibers themselves. This is done by mixing mordant or dyeing aid with 0.005 ~ 1 micron size silver or germanium particles, distilling or printing, and then using distilled or purified water in the process of high pressure heat treatment. It was dyed by using a nonmetallic plastic material or the like.

이상과 같이 본 고안은 은의 특성으로 항균 작용과 정전기 방지 및 게르마늄의 특성을 살린 뛰어난 효과가 있는 매우 유용한 고안인 것이다.As described above, the present invention is a very useful design having excellent effects utilizing antibacterial and antistatic and germanium properties as silver properties.

도 1은 본 고안의 바람직한 실시예인 은, 게루마늄 함유 가공 섬유을 도시한 정면도.1 is a front view showing a silver, germanium-containing processed fiber which is a preferred embodiment of the present invention.

도 2는 본 고안의 은, 게루마늄 함유 가공 섬유를 도시한 단면도이다.2 is a cross-sectional view showing the silver and germanium-containing processed fiber of the present invention.

* 도면의 주요부분에 대한 부호설명 ** Code description for main part of drawing *

1, 1' : 섬유 2, 2' : 은입자3,3' : 게루마늄1, 1 ': fiber 2, 2': silver particles 3, 3 ': germanium

Claims (1)

섬유의 침염이나 날염시 가공 보조제, 매염제, 수지가공제 및 염색조제로 이루어진 그룹 중에서 선택되는 어느 하나 이상의 것을 사용하여 염색시 안료 수용액을 증류수로 사용하여 0.005~1미크론 크기의 은입자 30ppm 및 게르마늄입자 50ppm을 비금속인 프라스틱 통속에서 교반 착색을 이루게 하고, 고압 열처리로 후처리하여 완성케 하는 염색과정에서 섬유에 은입자와 게루마늄입자를 고착 시키는 것을 특징으로 하는 은, 게루마늄 함유 가공섬유.30ppm silver and germanium particles with 0.005 ~ 1 micron size using pigment aqueous solution as distilled water when dyeing using any one or more selected from the group consisting of processing aid, mordant, resin processing agent and dyeing aid during textile dyeing or printing Silver and germanium-containing processed fiber, characterized in that the silver particles and the germanium particles are fixed to the fibers during the dyeing process to achieve 50ppm by stirring in a non-metallic plastic barrel, and finished by high-temperature heat treatment.
KR20-1999-0009701U 1999-06-02 1999-06-02 Fabricating fiber comprising silver or germanium KR200391920Y1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016010343A1 (en) * 2014-07-14 2016-01-21 안지영 Silver nonwoven fabric and production method for same

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020065139A (en) * 2001-02-05 2002-08-13 안정오 Antibacterial wool treatment method
KR20010091023A (en) * 2001-03-20 2001-10-22 안정오 Silver particle-containing nonwoven

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016010343A1 (en) * 2014-07-14 2016-01-21 안지영 Silver nonwoven fabric and production method for same

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