KR20030079373A - The far infra red ray emissive deodorant ceramics and a method for its preparation - Google Patents

The far infra red ray emissive deodorant ceramics and a method for its preparation Download PDF

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KR20030079373A
KR20030079373A KR1020020018348A KR20020018348A KR20030079373A KR 20030079373 A KR20030079373 A KR 20030079373A KR 1020020018348 A KR1020020018348 A KR 1020020018348A KR 20020018348 A KR20020018348 A KR 20020018348A KR 20030079373 A KR20030079373 A KR 20030079373A
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ceramics
weight
far
deodorization
kiln
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나창호
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반석제로파 주식회사
나창호
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
    • C04B35/18—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
    • C04B35/195—Alkaline earth aluminosilicates, e.g. cordierite or anorthite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/64—Burning or sintering processes
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40—Porous or lightweight materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
    • C04B2235/602—Making the green bodies or pre-forms by moulding

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Cold Air Circulating Systems And Constructional Details In Refrigerators (AREA)

Abstract

PURPOSE: A method for producing for emission of far infrared ray and deodorization is provided to remove the odors of various foods in a refrigerator and to maintain the freshness of the foods. CONSTITUTION: The method comprises the steps of: mixing 10 wt% of a dolomite, 60 wt% of a zeolite, 25 wt% of a clay, 3 wt% of titanium dioxide(TiO2) and 2 wt% of silver chloride(AgCl), adding water to the mixed powdery composition and mixing them uniformly; screening the mixture to obtain the powder having the size of 80-90 mesh; molding the powder in a mold having a desired shape under the pressure of 1,000 to 1,200 kg/cm2 to obtain a shaped body; drying the shaped body at room temperature for 24 hours and trimming it; loading the shaped body in a baking furnace, baking it at 800-1000 deg.C for 1 to 5 hours, and then cooling it.

Description

원적외선 방사와 탈취용 세라믹스의 제조 방법 { The far infra red ray emissive deodorant ceramics and a method for its preparation }The far infra red ray emissive deodorant ceramics and a method for its preparation}

우리의 생활에서 냉장고는 없어서는 안되는 필수품이 된지 오래이다.The refrigerator has long been an indispensable necessity in our lives.

우리에게 언제나 신선한 식품을 제공하게 되고 낭비를 막아 줌으로써, 가계에 이바지 하는 바 가 크다. 그러나 현대의 주택 구조가 주방이 별도로 분리되어 있지않고 생활의 같은 공간에 마련되어 있는 관계로 냉장고 문을 열때마다 발산되는 식품의 냄새는 그 공간에서 생활하는 사람들을 불쾌하게한다. 뿐만 아니라 상쾌해야할 실내 공기가 식품의 냄새로 오염되게 되어 우리 삶에 불쾌감을 가져오게 한다. 이에 본 발명은 원적외선을 방사하는 탈취용 세라믹스를 냉장고에 설치 하여 냉장고내에 저장된 각종 식품으로부터 발산 하는 냄새를 흡수 제거함은 물론 원적외선을 방사하는 탈취용 세라믹스에서 식품에 유익한 생육광선인 원적외선의 발산으로 인해 식품의 신선도를 오래 유지 하여 좀더 쾌적한 생활을 영위하려는데에 그 목적이 있다.We have always contributed to our households by providing us with fresh food and preventing waste. However, as the modern house structure is not separated from the kitchen but is provided in the same space of life, the smell of food emitted every time the refrigerator door is opened is displeased to people living in the space. In addition, the indoor air, which should be refreshed, is contaminated by the smell of food, which causes discomfort in our lives. Therefore, the present invention is installed by the deodorizing ceramics radiating far-infrared rays in the refrigerator to absorb and remove the smell emitted from various foods stored in the refrigerator, as well as the food due to the emission of far-infrared rays which is beneficial to food in the deodorizing ceramics radiating far infrared rays The purpose is to maintain a freshness of life and lead a more pleasant life.

냉장고는 현대를 살아가는 사람들의 생활에 없어서는 안되는 생활 필수품이 되었다. 더욱이 냉장고가 가정 경제에 큰 도움을 주고 있다는 사실은 다 아는바이다. 그러나 현대인의 생활공간이 개방되어 있지 않고 밀폐되어 있는 관계로 때로는 냉장고에 저장되어 있는 식품, 특히 한국 사람들의 식탁에 없어서는 안되는 김치와 같은 발효식품에서 냉장고 문을 개방할때 마다 풍겨 나오는 냄새는 일정 시간 실내에 남아 있어 그 공간에서 생활하는 사람들에게 불편을 주고 있다.Refrigerators have become an indispensable necessity in the lives of people living in modern times. Moreover, it is well known that refrigerators are a great help to the home economy. However, because the living space of modern people is not open and closed, sometimes the smell that comes out every time the refrigerator door is opened in food stored in the refrigerator, especially fermented food such as kimchi, which is indispensable on the table of Korean people It stays indoors, causing inconvenience to people living in the space.

또한, 식품의 신선한 상태를 유지하기 위해 냉장고에 보관하게 되지만, 그 또한 오래 가지 못하고 시들거나 부패하여 경제적 손실을 가져오게 된다.In addition, the food is stored in the refrigerator to maintain the fresh state, but it also does not last long, wither or rot, resulting in economic losses.

따라서, 상기와 같은 문제점들을 해결할 목적으로 창안된 것으로는 달걀 모양의 플라스틱케이스의 상단에 구멍을 내놓고 내부에 방향제를 넣어 냉장고에 투입함으로써, 플라스틱케이스에서 발산하는 방향제가 식품에서 발산하는 냄새와 합쳐져서 중화 시킨다는 원리로 되어있으나, 방향제에서 발산하는 물질이 식품에 부착되게 되므로 방향제가 부착된 식품을 먹게 되는 것이다.그리고 냉장고에 저장되는 식품의 종류가 한두가지가 아니며, 예를들면 발효식품, 육류, 생선, 기타음식등 다양하다. 이런것들에서 발산하는 냄새를 모두 중화 시킨다는 것이 그리 쉬운 문제는 아니다. 또한 방향제로서는 발산하는 냉장고내의 냄새를 흡수 제거할수 없을뿐 아니라 식품의 신선도를 유지 할수가 없슴을 알수 있다.Therefore, the invention was made for the purpose of solving the above problems by putting a hole in the top of the egg-shaped plastic case and put the fragrance inside into the refrigerator, the fragrance emitted from the plastic case is combined with the smell emitted from the food to neutralize It is based on the principle, but the substance emitted from the fragrance is attached to the food, so the food with the fragrance is eaten, and there are not one or two kinds of food stored in the refrigerator, for example, fermented food, meat, and fish. And other foods. Neutralizing all of these odors is not an easy problem. In addition, it can be seen that the fragrance cannot absorb and remove the smell in the emitting refrigerator and maintain the freshness of the food.

본 발명은 상기와 같은 종래 기술의 문제점을 해결하기 위하여 창안된 것으로써, 본 발명의 목적은 냉장고내에 저장된 식품에서 풍겨나오는 각종 식품의 냄새를 흡수 제거하고 아울러 식품에 유익한 생육광선인 원적외선을 방사하는 세라믹을 제공함에 있다. 상기 목적을 달성 달성하기 위하여 본 발명이 시도하는 바는 다공질의 세라믹 물질로 냉장고내에 저장 되어 있는 각종 음식물에서 발산 되는 냄새를 효율적으로 흡수함은 물론 동시에 생유광선인 원적외선을 방사하여 식품의 신선도를 유지 하려는 것이다.The present invention has been made to solve the problems of the prior art as described above, the object of the present invention is to absorb and remove the smell of various foods from the food stored in the refrigerator and to emit far-infrared rays, which are beneficial growth light to food In providing a ceramic. In order to achieve the above object, the present invention attempts to efficiently absorb the odor emitted from various foods stored in the refrigerator as a porous ceramic material, and at the same time to maintain the freshness of food by radiating far infrared rays, which are raw glows. I will.

원적외선 방사와탈취용 세라믹스Far Infrared Radiation and Deodorization Ceramics

본 발명은 높은 흡수율과 동시에 고효율의 원적외선 방사와 강한 원적외선 방사에너지를 방출 하는 다공질 세라믹스로서, 이 세라믹스의 주 조성물이 돌로마이트(백운석) 10중량%와 제오라이트(비석) 60중량%, 클레이(점토) 25중량%, 산화티탄(TiO2) 3중량%, 산화은(AgCl) 2중량%의 분체로 조성 되었으며, 이분체의 총 중량에 대해 9%의 물을 넣은 다음 고루 혼합하고 80 ~ 90매쉬로 입자화 시킨후 원하는 형에 맞추어 제작된 금형에서 1,000 ∼ 1,200kg/㎠의 압력으로 성형된 성형체를 실온에서 24시간 건조 시킨다음 외형을 다듬고 나서 소성로에 적재하고 800℃ ~ 1,000℃의 로내 온도에서 1 ~ 5 시간 소성하여 고효율의 냄새 흡수는 물론이고, 고효율의 원적외선 방사와 강도 높은 원적외선 에너지를 방출 하는 세라믹스를 만든다. 본 발명에 형성된 몸체가 소성로에서 가열되는 동안 소성로내에 불활성가스(질소 ) 를 유입한다. 로내에 유입된불활성 가스는 로내 온도가 500℃에 상승되면, 그때부터 불활성 가스를 주입하여 소성로내 온도가 냉각 되기 시작하여 소성로내 온도가 200℃에 도달하면 소성로내에 유입되는 불활성가스를 차단하고 소성로의 문을열고 소결된 세라믹을 주위의 공기 온도에서 서서히 냉각 시킨다.The present invention is a porous ceramics that emit high absorption and high efficiency far infrared radiation and strong far infrared radiation energy. It is composed of a powder by weight, titanium oxide (TiO 2 ) 3% by weight, silver oxide (AgCl) 2% by weight, 9% of water is added to the total weight of the powder and mixed evenly and granulated with 80 to 90 mesh. After drying the molded body at a pressure of 1,000 to 1,200kg / ㎠ for 24 hours at room temperature for 24 hours in the mold manufactured according to the desired mold, trimming the appearance and then loaded into a firing furnace 1 ~ 5 at the furnace temperature of 800 ℃ ~ 1,000 ℃ By firing for a long time, high-efficiency odor absorption, as well as high-efficiency far-infrared radiation and high-intensity far-infrared energy are produced. Inert gas (nitrogen) is introduced into the kiln while the body formed in the present invention is heated in the kiln. When the inert gas flows into the furnace, the temperature in the furnace rises to 500 ° C. Inert gas is then injected into the furnace, and the temperature inside the furnace starts to cool. When the temperature inside the furnace reaches 200 ° C, the inert gas that flows into the furnace is shut off. Open the door and slowly cool the sintered ceramic at ambient air temperature.

본 발명의 원적외선을 방사하는 다공질 세라믹스는 높은 흡수율을 갖고 있으며, 고효율의 원적외선 방사와 강한 원적외선 에너지를 방출 한다. 따라서 본 발명의 다공질 세라믹스는 각종식품 또는 음식물에서 방출 되는 냄새를 흡수 하여 실내 공기를 쾌적하게 유지 하며, 아울러 각종 식품에 유익한 생육광선인 원적외선의 방사로 인해 식품의 장시간 저장을 가능하게 하는 효과를 보게 된다.Porous ceramics emitting far-infrared rays of the present invention have a high absorption rate and emit high-infrared radiation and strong far-infrared energy. Therefore, the porous ceramics of the present invention absorb the odor emitted from various foods or foods to keep the indoor air pleasant, and also the effect of enabling long-term storage of foods due to the radiation of far-infrared rays, which are beneficial to various foods. do.

본 발명의 냉장고내의 냄새 흡수및 원적외선을 방사하는 다공질 세라믹스의 조성물 특성은 계속되는 구체적인 실시예를 통해서 좀더 확실하게 설명 될것이다.The characteristics of the composition of porous ceramics that absorb odor absorption and far-infrared rays in the refrigerator of the present invention will be more clearly explained through the following specific examples.

[실시예 1]Example 1

분체의 혼합은 돌로마이트(백운석) 10중량%와 제오라이트(비석) 60중량%, 클레이(점토) 25중량%, 산화티탄(TiO₂) 3중량%, 산화은(AgCl) 2중량%의 비율로 조성되어있으며, 이분체의 총 중량에 대해 9%의 물을 넣은 다음 고루 혼합하고 80 ∼ 90 매쉬로 입자화 시킨후 원하는 형에 맞추어 제작된 금형에서 1,000 ∼ 1,200kg/㎠의 압력으로 성형된 성형체를 실온에서 24시간 건조 시킨다음 외형을 다듬고 나서 소성로에 적재하고 800℃ ∼ 1,000℃의 로내 온도에서 1 ∼ 5 시간 소성한 다음 냉각시켜 얻어진 세라믹스 물체를 만든다. 본 발명에서 형성된 물체가 소성로에서 가열되는 동안 소성로내에 불활성가스( 질소 ) 를 유입한다. 로내에 유입되는 불활성 가스는 로내 온도가 500℃에 상승되면, 그때부터 불활성 가스를 주입하여 소성로내 온도가 냉각 되기 시작하여 소성로내 온도가 200℃에 도달하면 소성로내에 유입되는 불활성가스를 차단하고 소성로의 문을 열고 소결된 세라믹을 주위의 공기 온도에서 서서히 냉각 시켜 얻어진 본 발명의 원적외선 방사와 탈취용 세라믹스는 FT - 1R 스펙트로메타를 사용 하여 흑체와 비교하여 원적외선 방사 출력을 측정한 결과는 다음과 같다.The powder is composed of 10% by weight dolomite (dolomite), 60% by weight zeolite (stone), 25% by weight clay, 3% by weight titanium oxide (TiO₂) and 2% by weight silver oxide (AgCl). , 9% water to the total weight of the fine powder, and then evenly mixed and granulated into 80 ~ 90 mesh and molded at a pressure of 1,000 ~ 1,200kg / ㎠ in a mold manufactured according to the desired mold at room temperature After drying for 24 hours, the appearance is trimmed, loaded into a kiln, fired at a furnace temperature of 800 ° C to 1,000 ° C for 1 to 5 hours, and then cooled to form a ceramic object. Inert gas (nitrogen) is introduced into the kiln while the object formed in the present invention is heated in the kiln. When the inert gas flowing into the furnace rises to 500 ℃, the inert gas is injected from that time, and the temperature inside the kiln starts to cool. When the temperature inside the kiln reaches 200 ℃, the inert gas entering the kiln is blocked and the kiln is fired. The far-infrared radiation and deodorization ceramics of the present invention obtained by slowly cooling the sintered ceramics at ambient air temperature were measured by using the FT-1R spectrometer and the far-infrared radiation output was measured as follows. .

1, 원적외선의 방사율과 방사출력1, emissivity and radiation output of far infrared

2, 실시 예 1의 방식으로 얻어진 원적외선 방사와 탈취용 세라믹스를 KF1A-F1-1004의 방법으로 암모니아 가스의 탈취 시험을 실시한 결과는 다음과 같다.2, The results of the deodorization test of ammonia gas by the method of KF1A-F1-1004 for the far-infrared radiation and deodorization ceramics obtained in the manner of Example 1 are as follows.

Claims (2)

원적외선 방사와 탈취용 세라믹스의 조성물이 돌로마이트(백운석) 10중량%와 제오라이트(비석) 60중량%, 클레이(점토) 25중량%, 산화티탄(TiO2) 3중량%, 산화은(AgCl) 2중량%의 분체를 혼합하여 이루어 지는 원적외선 방사와 탈취용 세라믹스의 분말 조성물The composition of ceramics for far-infrared radiation and deodorization is 10% by weight dolomite (dolomite), 60% by weight zeolite (zeolite), 25% by weight clay (clay), 3% by weight titanium oxide (TiO 2 ) and 2% by weight silver oxide (AgCl) Powder composition of ceramics for far-infrared radiation and deodorization made by mixing powders of 청구항 1의 분말 조성물의 총 중량에 대해 9%의 물을 넣은 다음 고루 혼합하고 80 ∼ 90매쉬로 입자화 시킨후 원하는 형에 맞추어 제작된 금형에서 1,000 ~ 1,200kg/㎠의 압력으로 성형된 성형체를 실온에서 24시간 건조 시킨다음 외형을 다듬고 나서 소성로에 적재하고 불활성 가스(질소) 분위기에서 800℃ ∼ 1,000℃의 로내 온도에서 1 ∼ 5 시간 소성하고 소성로내 온도가 200℃에 도달할때 까지 서서히 냉각 시킨 다음 소성로내 온도가 200℃에 이르면 소성로의 문을 열고 실온에서 서서히 냉각 시켜 만들어 지는 원적외선 방사와 탈취용 세라믹스의 제조 방법.9% water is added to the total weight of the powder composition of claim 1, and then mixed evenly and granulated into 80 to 90 mesh, and the molded article is molded at a pressure of 1,000 to 1,200 kg / cm 2 in a mold manufactured according to a desired mold. After drying at room temperature for 24 hours, the appearance was refined and loaded into a kiln, and then fired in an inert gas (nitrogen) atmosphere at a furnace temperature of 800 ° C. to 1,000 ° C. for 1 to 5 hours and gradually cooled until the temperature in the furnace reached 200 ° C. The method for producing ceramics for far-infrared radiation and deodorization is made by opening the door of the kiln and slowly cooling it at room temperature when the temperature in the kiln reaches 200 ° C.
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KR20040000273A (en) * 2002-06-24 2004-01-03 이찬연 Deordant characterized by pyroxene diabase contacted with titanium oxide
KR101532937B1 (en) * 2013-10-01 2015-07-03 조재근 Refrigerator deodorizer and the method of manufacturing the same

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JPH01146554A (en) * 1987-12-03 1989-06-08 Akiyoshi Takeda Deodorizer and its preparation
KR910009596A (en) * 1989-11-10 1991-06-28 정성우 Ceramic material with adsorption, deodorization, sterilization and decomposition
JPH0826851A (en) * 1994-07-08 1996-01-30 Ohbayashi Corp Sepiolite porous sintered body and its production
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KR19980066651A (en) * 1997-01-28 1998-10-15 김광호 Mixed multistage vacuum apparatus and method
KR20010060424A (en) * 1999-12-22 2001-07-07 김무강 The manufactured goods and production a method opposition a furgus abiochemistry many faclty catalytic a light
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Publication number Priority date Publication date Assignee Title
JPH01146554A (en) * 1987-12-03 1989-06-08 Akiyoshi Takeda Deodorizer and its preparation
KR910009596A (en) * 1989-11-10 1991-06-28 정성우 Ceramic material with adsorption, deodorization, sterilization and decomposition
JPH0826851A (en) * 1994-07-08 1996-01-30 Ohbayashi Corp Sepiolite porous sintered body and its production
JPH1085312A (en) * 1996-09-12 1998-04-07 Nippon Mizushiyori Giken:Kk Powdery ceramics deodorant
KR19980016204U (en) * 1996-09-16 1998-06-25 황길성 Far Infrared Radiation Ceramic
KR19980066651A (en) * 1997-01-28 1998-10-15 김광호 Mixed multistage vacuum apparatus and method
KR20010060424A (en) * 1999-12-22 2001-07-07 김무강 The manufactured goods and production a method opposition a furgus abiochemistry many faclty catalytic a light
JP2001261426A (en) * 2000-03-22 2001-09-26 Daiwa Ceramic Kk Far infrared ray radiating ceramic

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20040000273A (en) * 2002-06-24 2004-01-03 이찬연 Deordant characterized by pyroxene diabase contacted with titanium oxide
KR101532937B1 (en) * 2013-10-01 2015-07-03 조재근 Refrigerator deodorizer and the method of manufacturing the same

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