KR20030079359A - Method for manufacturing the bottom material using the used urethane bumper - Google Patents
Method for manufacturing the bottom material using the used urethane bumper Download PDFInfo
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- KR20030079359A KR20030079359A KR1020020018327A KR20020018327A KR20030079359A KR 20030079359 A KR20030079359 A KR 20030079359A KR 1020020018327 A KR1020020018327 A KR 1020020018327A KR 20020018327 A KR20020018327 A KR 20020018327A KR 20030079359 A KR20030079359 A KR 20030079359A
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- waste urethane
- urethane bumper
- manufacturing
- flooring
- particle size
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
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- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
Abstract
Description
본 발명은 폐우레탄 범퍼를 이용한 바닥재 제조 방법에 관한 것으로서, 특히 폐우레탄 범퍼를 이용함으로써 자원의 재활용과 환경을 보존할 수 있는 폐우레탄 범퍼를 이용한 바닥재 제조 방법에 관한 것이다.The present invention relates to a flooring manufacturing method using waste urethane bumpers, and more particularly, to a flooring manufacturing method using waste urethane bumpers that can be used to recycle resources and to preserve the environment by using waste urethane bumpers.
일반적으로, 지구온난화, 산성비, 오존층파괴 등 지구규모에서의 환경문제는 21세기를 시작하는 시점에서 해결해야할 중요한 과제이며, 동시에 우리들 자신의 문제라는 것은 명백한 사실이다. 지구환경문제 특히 이산화탄소문제를 생각할 때 표면화되는 큰 문제는 자원ㆍ에너지문제, 그리고 폐기물 문제이다.In general, it is clear that environmental problems at global scale, such as global warming, acid rain and ozone depletion, are both important challenges to be solved at the beginning of the 21st century and at the same time our own problems. The big problems that surface when considering the global environmental problem, especially the carbon dioxide problem, are the resource, energy and waste problems.
고도경제성장의 영향으로 폐기되어지는 플라스틱 양 또한 매년 증가하고 있으며 이들의 처리는 매립처분 및 소각 처분하는 것이 현 실정이며. 이 경우 내분비계 교란물질 등의 첨가제가 용출해 지하수 및 하천의 오염, 매립지의 부족 뿐만 아니라 폐기가스, 폐수처리 등 여러 가지 문제가 있다.The amount of plastic discarded due to the high economic growth is also increasing every year, and their disposal is currently disposed of landfill and incineration. In this case, additives such as endocrine disrupting substances are eluted, and there are various problems such as waste gas and wastewater treatment as well as contamination of groundwater and rivers and lack of landfill.
따라서 재자원화에 대한 요구가 강하게 대두되고 있으며 이들을 재활용하는 방법에는 물성적(Material), 화학적(Chemical), 열(Thermal or Energy)으로 재활용으로 나눌 수가 있다.Therefore, there is a strong demand for recycling, and there are two ways to recycle them: physical, chemical, and thermal or energy.
물성적 재활용이란, 폐기되어진 재료를 다시 이용하는 기술이다. 회수되어진 폐 플라스틱은 재생처리설비에 운반되어져 먼저 금속, 수지별로 선별을 하고, 재차 금속 등을 제거하여, 계속해서 세척, 이물분리, 건조 및 조립화(pellet),하는 것이다.Physical property recycling is a technique of reusing waste material. The recovered waste plastic is transported to a regeneration treatment facility, and then sorted by metals and resins first, and then metals are removed again, followed by washing, foreign material separation, drying and pelletization.
화학적 재활용이란, 플라스틱을 열분해 또는 화학처리하여 저분자화하여 화학원료 및, 연료로 이용하는 방법으로 그 예로는 열분해 유화, 고온가스화등의 방법이 있다.Chemical recycling is a method in which plastic is thermally decomposed or chemically treated to make low molecular weight and used as a chemical raw material and a fuel. Examples thereof include pyrolysis emulsification and hot gasification.
열적 재할용이란, 폐 플라스틱을 파쇄, 조립 후 고로에서 연료화하는 방식이다.Thermal recycling is a method in which waste plastic is crushed and assembled into fuel in a blast furnace.
하지만, 폐플라스틱들의 재활용이라는 문제는, 경제성과 경쟁력이라는 현실적인 어려움들로 인하여 사실상 활성화되지 못하는 것이 현실이다.However, the problem of recycling waste plastics is not actually activated due to the practical difficulties of economics and competitiveness.
본 발명은 상기한 종래 기술에 따른 제반 문제점을 해결하기 위하여 안출한 것으로, 본 발명의 목적은 폐 플라스틱중에서도 매년 막대한 양의 폐기물로 사장되어지는 폐우레탄 범버를 접착재료 또는 바닥재료 등의 용도로 재자원화 함으로써, 폐 자원의 재활용 및 환경 보존, 생태계보전에 긍정적인 효과를 이룰수있는 폐우레탄 범퍼를 이용한 바닥재 제조 방법을 제공함에 있다.The present invention has been made in order to solve the above problems according to the prior art, the object of the present invention is to recycle waste urethane bumper, which is dead every year in a huge amount of waste plastics, such as adhesive material or flooring material. By recycling, the present invention provides a method for manufacturing flooring using waste urethane bumpers that can achieve a positive effect on recycling waste resources, preserving the environment, and preserving the ecosystem.
상기한 목적을 달성하기 위한 본 발명에 따른 폐우레탄 범퍼를 이용한 바닥재 제조 방법은Flooring manufacturing method using the waste urethane bumper according to the present invention for achieving the above object is
a)자동차의 폐우레탄 범퍼를 일정크기의 입도로 분쇄하여 수집하는 단계,a) collecting the waste urethane bumper of the car by crushing to a certain size particle size,
b)상기 수집된 분쇄물을 폴리올(Polyol)과 이소시아네이트(Isocianate)와 함께 물리적 혼합에 의해 교반하는 단계, 및b) stirring the collected milled product with physical mixing with polyol and isocyanate, and
c)상기 교반된 혼합물을 금형에 주입하여 소정의 시간이 지난후 폴리우레탄폼을 탈형시켜 완전경화키는 단계를 포함하며,c) injecting the stirred mixture into a mold and demolding the polyurethane foam after a predetermined time to completely cure the mold;
d)상기 b)단계에 있어서 혼합을 위한 온도는 58~62℃로 하는 폐우레탄 범퍼를 이용한 바닥재 제조 방법이다.d) The temperature for mixing in step b) is a flooring manufacturing method using a waste urethane bumper to 58 ~ 62 ℃.
본 발명의 시료로서는 폐우레탄 범퍼를 파쇄하여, 입도(Waste Polyurethane Granule, 이하 'PUG'라 한다) 의 크기를 1.0~1.5mm (이하 'A'라 한다), 1.0~0.5mm (이하 'B'라 한다), 0.5mm이하 (이하 'C'라 한다)로 3종류로 나누어 사용하였으며,원추사분법에 의해 시료를 채취한다.As the sample of the present invention, the waste urethane bumper is crushed, and the particle size (Waste Polyurethane Granule, hereinafter referred to as 'PUG') is 1.0 to 1.5 mm (hereinafter referred to as 'A') and 1.0 to 0.5 mm (hereinafter referred to as 'B'). ) And 0.5mm or less (hereinafter referred to as 'C'), which is divided into three types, and samples are collected by the cone quarter method.
상기 채취한 각 입도별시료를 폴리올(Polyol : PPG-7850 system),과 이소시아네이트(Isocianate : NS-595 : DOW사 제품)와 함께 물리적 혼합에 의해 교반한 후, 교반된 혼합물을 금형에 주입한다. 소정의 시간이 지난후 금형에서 폴리우레폼을 탈형시켜 완전경화(가교)가 끝난 바닥재용 시편의 물성을 측정한다.The sample for each particle size collected is stirred by physical mixing with polyol (Polyol: PPG-7850 system) and isocyanate (Isocianate: NS-595: manufactured by DOW), and then the stirred mixture is injected into a mold. After a predetermined time, the mold is demoulded and the physical properties of the flooring specimens for complete hardening (crosslinking) are measured.
여기에서 교반조건은 다음과 같다. 혼합시간은 7초, 혼합속도는 5000rpm, 온도는 상온(23~25℃), 폴리올과 이소시아네이트의 온도는 22~25℃, 혼합타입은 IKKA RE66-1로 한다.Here, the stirring conditions are as follows. The mixing time is 7 seconds, the mixing speed is 5000rpm, the temperature is room temperature (23-25 ℃), the temperature of polyol and isocyanate is 22-25 ℃, and the mixing type is IKKA RE66-1.
한편, 폴리올과 이소시아네이트와의 교반시, PUG함량을 10중량%로 고정한 상태에서 시료A,B,C의 각각에 대해 교반하였으며, 시료 B에 대해서는 PUG함량을 5중량%, 10중량%, 15중량% 로 각각 조절하여 바닥재용 시편을 만들어 물성조사한다.On the other hand, while stirring the polyol and the isocyanate, it was stirred for each of Samples A, B, and C while the PUG content was fixed at 10% by weight, and for the sample B, the PUG content was 5% by weight, 10% by weight, and 15% by weight. Each of them is adjusted to% to make specimens for flooring and to investigate their properties.
성형되어진 시편은 다음과 같은 조건으로 제작하기로 한다. PUG의 크키는 A시료는 1.0~1.5mm, B시료는 1.0~0.5mm, C시료는 0.5mm이하로 하고, PUG의 함량은 5중량%, 10중량%, 15중량%로 하고, 시제품 제작을 위한 금형의 크기는 200㎜*200㎜*10㎜로 하고, 금형의 온도는 60℃ ± 2 이며, 금형에서는 3 분 ± 1 내에 탈형시킨다.The molded specimens shall be manufactured under the following conditions. The size of PUG is 1.0 ~ 1.5mm, B sample is 1.0 ~ 0.5mm, C sample is 0.5mm or less, and PUG content is 5%, 10%, 15% by weight The mold size is 200 mm * 200 mm * 10 mm, the temperature of the mold is 60 ° C ± 2, demolding in 3 minutes ± 1 in the mold.
상기의 조건으로 성형되어진 시제품의 물성은 다음과 같다. 0.5~1.0mm입도(B)로 조절한 시료로 바닥재용의 시편을 만들었을 경우 PUG함량별로서 테스트하여 본 결과 다음 표 1과 같은 결과를 얻을 수가 있다.The physical properties of the prototype molded under the above conditions are as follows. When the specimen for flooring was made from the sample adjusted to 0.5 ~ 1.0mm particle size (B), the result of the test by PUG content can be obtained as shown in Table 1 below.
PUG를 10중량%로 고정시키고 입자크기(A,B,C)별로 케스트하여 본 결과 다음 표 2와 같은 결과치를 얻을 수가 있다.The PUG is fixed at 10% by weight and casted for each particle size (A, B, C). As a result, the result shown in Table 2 can be obtained.
상기과 같이 폐우레탄 범퍼를 이용하여 물성적으로 재활용하여 바닥재용 시제품을 제작한 결과, 바닥재의 용도로서 기존의 제품과 비교하였을 경우에 물성치의 차이는 거의 없으며, 상기의 조건별 시제품들이 모두 비슷한 결과를 얻을 수 있다.As a result of using the waste urethane bumper as the above, the prototype of the flooring material was produced. As a result of the use of the flooring material, there is almost no difference in physical properties when compared to the existing product. You can get it.
본 발명은 종래 소각 처리 또는 매립처리되던 우레탄 범퍼를 수거하여, 분쇄, 혼합, 성형과정을 거쳐서 재활용된 바닥재는 기존의 제품과 비교하였을 경우에 물성치의 차이는 거의 없으므로, 자원재활용을 통한 공해의 감소와 폐자재의 재활용으로 원가의 혁신적인 감소가 가능하게 되었으며, 자원보존, 환경보전이라는 큰 명제에도 부합한다.The present invention collects urethane bumpers, which have been incinerated or landfilled in the prior art, and recycled flooring materials, which are recycled through crushing, mixing, and molding, have little difference in physical properties when compared to conventional products, thereby reducing pollution through resource recycling. Recycling and recycling of waste materials has led to innovative reductions in costs, and is in line with the big propositions of resource conservation and environmental conservation.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6833434B2 (en) * | 2003-05-02 | 2004-12-21 | Samki Entech Co., Ltd. | Noctilucent polyurethane chips and methods of manufacturing the same |
KR101888332B1 (en) | 2018-02-26 | 2018-08-13 | 강성호 | Manufacturing equipment of floor mat for automobile |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07108531A (en) * | 1993-10-13 | 1995-04-25 | Okamura Corp | Recycling method for flexible urethane foam |
KR20010008243A (en) * | 2000-11-17 | 2001-02-05 | 이종철 | The method and its products of used polyuretane foam |
JP2002069291A (en) * | 2000-08-24 | 2002-03-08 | Mitsui Takeda Chemicals Inc | Rigid urethane resin composition for coated flooring |
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2002
- 2002-04-03 KR KR1020020018327A patent/KR20030079359A/en not_active Application Discontinuation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07108531A (en) * | 1993-10-13 | 1995-04-25 | Okamura Corp | Recycling method for flexible urethane foam |
JP2002069291A (en) * | 2000-08-24 | 2002-03-08 | Mitsui Takeda Chemicals Inc | Rigid urethane resin composition for coated flooring |
KR20010008243A (en) * | 2000-11-17 | 2001-02-05 | 이종철 | The method and its products of used polyuretane foam |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6833434B2 (en) * | 2003-05-02 | 2004-12-21 | Samki Entech Co., Ltd. | Noctilucent polyurethane chips and methods of manufacturing the same |
KR101888332B1 (en) | 2018-02-26 | 2018-08-13 | 강성호 | Manufacturing equipment of floor mat for automobile |
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